LAMPIRAN 1. Perbandingan komposisi bahan LTO : PVDF : AB LTO : PVDF : AB = 85% : 10% : 5% Massa LTO = 10 gram 10% PVDF = 1,17 gram.

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1 LAMPIRAN 1 Perbandingan komposisi bahan LTO : PVDF : AB LTO : PVDF : AB = 85% : 10% : 5% Massa LTO = 10 gram 10% PVDF = 1,17 gram 85%. x = 10% x 10 gram 0,85. x = 0,1 x 10 gram 0,85 x = 1 gram x = 5% Acetylene Black = 0,59 gram = 1,17 gram 85%. x = 5% x 10 gram 0,85. x = 0,05 x 10 gram 0,85 x = 0,5 gram x = = 0,59 gram Perhitungan Massa Bahan Li 4 Ti 5 O 12 Persamaan Stokiometri : 4 LiOH.H 2 O + 5 TiO 2 Li 4 Ti 5 O H 2 O

2 Diketahui massa atom relative masing-masing unsur adalah : Ar Li = 6,941 Ar O = 16 Ar H = 1,008 Ar Ti = 47,87 Maka berat molekuldari masing-masing bahan adalah : Mr. LiOH.H 2 O = 41,9988 gr/mol Mr. TiO 2 = 79,997 gr/mol Mr. Li 4 Ti 5 O 12 = 459,9383 gr/mol Massa LTO = 10 gram Menghitung jumlah mol Li 4 Ti 5 O 12 0, mol Menghitung massa LiOH.H 2 O Perhitungan mol LiOH.H 2 O x Perhitungan massa x Mr mol x 41,9988

3 Menghitung Massa TiO 2 Perhitungan mol TiO 2 Mol TiO 2 = Mol TiO 2 = =0, mol Perhitungan massa TiO 2 x Mr mol x 79,997

4 LAMPIRAN 2 Menghitung Nilai Konduktivitas Sel Baterai c d 1 cm b a Dengan Keterangan : = konduktivitas sel baterai (1/ Ω cm atau S/cm) Re = hambatan elekronik (Ω) Rct = hambatan transfer muatan (Ω) A = luas permukaan persegi (cm 2 ) = tebal lembaran (cm) Z total = penjumlahan dari hambatan elektronik dan hambatan transfer muatan (Ω) M-1 (ketebalan 50 μm) Ω = Ω M-2 (ketebalan 80 μm) Ω = 3,66 Ω

5 M-4 (ketebalan 120 μm) Ω = 1,58 Ω Menghitung Energy Density ( ) M-1 (ketebalan 50 μm) M-2 (ketebalan 80 μm) M-4 (ketebalan 120 μm)

6 Menghitung Power Density ( ) M-1 (Ketebalan 50 μm) 0,0017 M-2 (Ketebalan 80 μm) 0,005 M-4 (Ketebalan 120 μm) 0,0067

7 LAMPIRAN 3 Gambar Bahan Serbuk LiOH.H 2 O Serbuk TiO 2 Serbuk PVDF Serbuk Karbon AB DMAC Aseton

11 Alat-alat Karakterisasi Penelitian Alat Uji CV/CD (WBCS 3000) Alat Uji XRD

12 Intensity (counts) Intensity (counts) LAMPIRAN 4 Analysis Results General Information Analysis date 2016/03/07 17:50:03 Sample name LTO Mia Measurement date File name LTO Mia.ras Operator Method Rietveld Measurement profile theta (deg)

14 Peak list No. 2-theta(deg) d(ang.) Height(cou nts) FWHM(deg) Int. I(counts deg) Int. W(deg) Asym. factor (3) (9) 336(18) 0.111(4) 52.8(12) 0.157(12) 0.57(5) (6) (7) 138(12) 0.084(7) 16.4(6) 0.119(15) 0.6(2) (6) (4) 159(13) 0.094(6) 19.2(7) 0.121(14) 1.3(3) (13) (8) 43(7) 0.158(16) 8.7(5) 0.20(4) 3.2(12) (5) (3) 19(4) 0.102(16) 2.3(3) 0.12(4) 4(6) (6) (3) 230(15) 0.099(5) 29.7(8) 0.129(12) 2.5(8) (17) (8) 40(6) 0.15(3) 8.4(6) 0.21(5) 0.9(4) (10) (4) 37(6) 0.052(18) 3.1(3) 0.08(2) 0.6(6) (8) (2) 64(8) 0.113(7) 8.2(4) 0.13(2) 1.3(4) (18) (5) 18(4) 0.106(14) 2.0(3) 0.11(4) 1.9(14) (10) (3) 62(8) 0.109(9) 8.5(4) 0.14(2) 1.4(6) (4) (9) 129(11) 0.095(6) 16.8(7) 0.130(17) 3.0(5) (12) (2) 38(6) 0.116(9) 4.7(4) 0.12(3) 1.4(6) (10) (17) 25(5) 0.091(11) 2.9(3) 0.12(4) 2.1(9) (4) (6) 26(5) 0.092(17) 4.2(3) 0.16(4) 0.6(4) (17) (2) 21(5) 0.108(15) 2.5(3) 0.12(4) 0.8(5) Parameters used for WPPF Profile parameters Common parameter Background Data LTO Mia Function name B-spline param param param param param param param param param param param param param param param param param node0 10

15 Common parameter Lithium Titanium Oxide node node node node node node node node node node node node node node14 90 Peak shift Function name Shift axial displacement param param1 0 param2 0 Scale factor S 4.99(6) FWHM U 0.015(6) V (6) W (13) Asym. factor A0-0.45(9) A1 1.2(3) Decay rate factor etal0/ml0 1.36(19) etal1/ml1 0.36(7) etal2/ml etah0/mh0 0.24(5) etah1/mh1 0.56(15) etah2/mh Preferred orientationmarch- H 0 K 0 L 0 March coefficient Rutile, syn Scale factor S 1.51(4) FWHM U 0.05(3) V -0.05(2) W 0.025(6) Asym. factor A0 0.36(17) A1 0.1(5) Decay rate factor etal0/ml0 0.27(10) etal1/ml1 0.0(3) etal2/ml etah0/mh0 0.39(14) etah1/mh1 0.0(5) etah2/mh Preferred orientationmarch- H 0 K 0 L 0 March coefficient

16 Structure parameters Data set name Phase Name Elem ent x y z Occu pancy Temperature factor LTO Mia LTO Mia Lithium Titanium Oxide Lithium Titanium Oxide Li O LTO Mia Lithium Titanium Oxide Li LTO Mia Lithium Titanium Oxide Ti LTO Mia Rutile, syn Ti LTO Mia Rutile, syn O Data set name Rwp Rp Re S LTO Mia Lattice constants Angular correction Analysis results Data set name a(a) b(a) c(a) alpha(deg) beta(deg) gamma(deg) LTO Mia (4) (4) (4) LTO Mia (5) (5) (4) Phase name a(a) b(a) c(a) alpha(deg) beta(deg) gamma(deg) V(A^3) Lithium Titanium Oxide Rutile, syn 2(4) (5) (4) (5) 2(4) (4) (5) (12)

17 Lattice constants (ang.) LTO Mia LTO Mia Data set a b c Crystal structure analysis results Indexing Phase name Formula Figure of merit Phase reg. detail DB card number Lithium Titanium Oxide Li1.33 Ti1.66 O ICDD (PDF RDB) Rutile, syn Ti O ICDD (PDF RDB) Quantitative analysis results Phase name Content(%) - Lithium Titanium Oxide 77.3(10) - Rutile, syn 22.7(6) Lattice information Phase name a(a) b(a) c(a) alpha(deg) beta( deg) gamma(deg) V(A^3) Lithium Titanium (4) (4) Oxide Rutile, syn (5) (5) 2(4) (4) (5) (1 2) Phase name Space group Z Z' Calc. density(g/cm^3) Lithium Titanium Oxide 227 : Fd-3m,choice Rutile, syn 136 : P42/mnm

18 Structure determination Refinement Measurement range: deg Refinement range: deg (1.09 A) Number of refined parameters: 41 Phase name Atomic cords # of indep. reflns Lithium Titanium Oxide Fractional cords 19 Rutile, syn Fractional cords 20 Rwp = 38.45% S =

19 Sampel M-1 LAMPIRAN 5 Measurement Time Frequency Z(ohm) deg(deg) Rs(ohm) X(ohm) Vmoni(V) Imoni(A) 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:21: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-04 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05 15:22: E E E E-05

20 V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL

21 Sampel M-2 Measurement Time Frequency Z(ohm) deg(deg) Rs(ohm) X(ohm) Vmoni(V) Imoni(A) 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:39: E E E E-04 17:40: E E E E-04 17:40: E E E E-05

22 V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL Cole-Cole Plot 4.00E E E E+02 X(ƒ ) 2.00E E E E E Rs(ƒ )

23 Sampel M-4 Measurement Time Frequency Z(ohm) deg(deg) Rs(ohm) X(ohm) Vmoni(V) Imoni(A) 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-04 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:09: E E E E-05 13:10: E E E E-05 13:10: E E E E-05 13:10: E E E E-05 13:10: E E E E-05

24 V 0.050V LIM OFF RANGE AUTO OPEN OFF SHORT OFF DELAY 1.00s AVE OFF SPEED NORMAL Cole-Cole Plot 1.40E E E+03 X(ƒ ) 8.00E E E E E ,000 1,200 1,400 Rs(ƒ )

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