184.- -,. MVOC MVOC MVOC MVOC MVOC MVOC MVOC MVOC MVOC MVOC + + +330 +- TVOC :,. + Damp Dampness WHO, Volatile Organic Compounds : VOC VOC VOC MVOC : Microbial Volatile Organic Compounds +/, 2//,, +, + E-mail : kagi.n.aa@m.titech.ac.jp
J. Japan Association on Odor Environment Vol..- No. -,*+, 185 lium chrysogenum, Aspergillus versicolor, Aspergillus MVOC fumigatus, Aspergillus niger, Cladosporiumu cladosporoides MVOC SPME GC/MS, -, MVOC Pentanol,,-Pentanone VOC VOC MVOC + MVOC VOC MVOC VOC / MVOC J.L. Kim MVOC MVOC MVOC 0 MVOC R. Wålinder,* /. MVOC --Methyl furan MVOC --Methyl furan - Aspergillus sp., Penicillium sp., Cladosporium sp., Alternaria sp. VOC A. Araki MVOC + -Octen---ol 1. S. Matysik Penicillium expansum, Penicil- + MVOC Ethanol, + -Butanol, + -Pentanol,,-Pentanol, + -Hexanol,,- Propanol, --Octanol,,-Ethyl-+-hexanol,,-Methyl-+-butanol, -- Methyl-+ -butanol, + -Octen---ol,,-Octen-+-ol Acetone,,-Butanone,,-Heptanone,,-Pentanone, --Octanone,.-Methyl-,-pentanone, Methyl isobutyl ketone,-methyl furan, --Methyl furan,-methyl butane, Heptane, Isoprene Limonene, Pinene Acetaldehyde, Benzaldehyde, Formaldehyde Acetic acid, Hexanoic acid Acetophenone, Benzene, Butylatedhydroxytoluene, Styrene, o-xylene, m-xylene, p-xylene, Phenol Dimethyl disulfide, Dimethyl trisulfide, Dimethyl tetrasulfide
186.- -,. ++ MVOC VOC MVOC MVOC MVOC MVOC 2 - MVOC -+ MVOC MVOC MVOC MVOC +- K. Wilkins MVOC MVOC 3 - +. MVOC JIS A +3*+,* L MVOC MVOC MVOC MVOC +* MVOC Cla- MVOC dosporium cladosporioides NBRC0-.2 Penicillium pinophilum NBRC 0-./ Aspergillus niger NBRC 0-.+ PDA DG+2 MVOC - Penicillium commune, P. chrysogenum, Aspergillus versicolor SPME Solid Phase Microextraction,* /** ml +, MVOC MVOC
J. Japan Association on Odor Environment Vol..- No. -,*+, 187 + /- + MVOC, VOC -,. - 1 VOC C. cladosporioides VOC C. cladosporioides 1* 3*,/ --Methyl-+-butanol PDA - DG+2 +. Tenax. P. pinophilum 1 + -Octen--- DNPH Tenax 0* +* ol,-octanone --Octanol L DNPH 3* +/ L GC/MS A. niger,-methyl-+-propanol --Methyl- HPLC + -butanol - -, + /- PDA MVOC DG+2, P. pinophilum P. pinophilum -. Acetaldehyde --Methyl-+- P. pinophilum 1 butanol C. cla-, MVOC Acet- dosporioides P. pinophilum aldehyde --Methyl-+-butanol - A. niger +. Acetone -,. DG+2 DG+2 1 PDA A. niger + -Octen---ol 1 DG+2 P. pinophilum, -- MVOC MVOC, MVOC Acetaldehyde, Acetone --Methyl-+-butanol +/ PDA C. cladosporioides - MVOC --Methyl---buten-+-ol A.niger --Methyl---buten-+- ol,-methyl furan P. pinophilum --Methyl-+- buten-+ -ol DG+2 A. niger + -Octen- --ol,--octanone,--octanol MVOC +, MVOC C. cladosporioides P. pinophilum A. niger Mix PDA DG+2 PDA DG+2 PDA DG+2 PDA DG+2 +- Acetaldehyde Acetone,-Methyl furan,-methyl-+-propanol --Methyl---buten-+-ol --Methyl-+-butanol --Methyl-,-buten-+-ol + -Octen---ol,-Octanone --Octanone --Octanol,-Octanol
188.- -,. + MVOC C. cladosporioides, P. pinophilum, A. niger :PDA :DG+2 +-. MVOC, MVOC MVOC MVOC MVOC MVOC MVOC +
J. Japan Association on Odor Environment Vol..- No. -,*+, 189 MVOC VOC :, MVOC - MVOC MVOC MVOC +- + : +1 http://www.mlit.go.jp/ kisha/kisha *0/*1/*1++-*_.html,,**0. ++., WHO Europe : Dampness and Mould, WHO Guidelines for Indoor Air Quality, (,**3). - : //,.-.2,(,**,).. Silke Matysik, Olf Herbarth, Andrea Mueller : Determination of volatile metabolites originating from mould growth on wall paper and synthetic media, Journal of Microbiological Methods, 1/, +2, +21, (,**2). / J.L. Kim, L. Elfman, Y. Mi, G. Wieslander, G. Smedje, D. Norbäck : Indoor molds, bacteria, microbial volatile organic compounds and plasticizers in schools associations with asthma and respiratory symptoms in pupils, Indoor Air, +1, +/- +0-, (,**1). 0 Robert Wålinder, Lena Ernstgård, Gunnar Johanson, Dan Norbäck, Per Venge, Gunilla Wieslander : Acute E# ects of a Fungal Volatile Compound, Environmental Health Perspectives, ++-( +, ), (,**/). 1 Atsuko Araki, Toshio Kawai, Yoko Eitaki, Ayako Kanazawa, Kanehisa Morimoto, Kunio Nakayama, Eiji Shibata, Masatoshi Tanaka, Tomoko Takigawa, Takesumi Yoshimura, Hisao Chikara, Yasuaki Saijo, Reiko Kishi : Relationship between selected indoor volatile organic compounds, so-called microbial VOC, and the prevalence of mucous membrane symptoms in single family homes, Science of the Total Environment,.*2,,,*2,,+/,(,*+*). 2 : 0. -,0(), 3 /,+ /,/,( +332). 3 K. Wilkins, M. Ntelsen, P. Wolko # : Patterns in Volatile Organic Compounds in Dust from Moldy Buildings, Indoor Air, 1, +,2 +-., ( +331). +* Martyna Kuske, Anne-Claude Romain, Jacques Nicolas : Microbial volatile organic compounds as indica-
190.- -,. tors of fungi. Can an electronic nose detect fungi in ation of MVOCs from moldy building materials, Jourindoor environments?, Building and Environment,.*, nal of Microbiological Methods, /,, -,/ --,, (,**-). 2,. 2-+,(,**/). +- : MVOC ++ Stéphane Moularat, Enric Robine, Olivier Ramalho, 213 22*, Mehmet A. Oturan : Detection of fungal development (,**2). in a closed environment through the identification of specific VOC : Demonstration of a specific VOC finge- +. : MVOC rprint for fungal development, Science of the Total Environment, 23/ 230,.1, +-3 +.0, (,**2). (,**0). +, Loay Wady, Annicka Bunte, Christina Pehrson, Len- +/ : nart Larsson : Use of gas chromatography-mass spec- MVOC trometry/solid phase microextraction for the identific- 231232, (,**0). Microbial Volatile Organic Compounds in Indoor Environments Naoki KAGI Tokyo Institute of Technology, +, +, Ookayama,, Meguro-ku, Tokyo +/, 2//,, Japan Abstract This report presented the outline and the previous researches for microbial volatile organic compounds (MVOC) emitted from fungi in indoor environments. The research introduced about the emission patterns of MVOCs as fungal growth processes. The relationships between the growth of the fungal thread and sporule, and MVOC emitting rates were investigated. Fungi could not be visible, however invisible fungi emit MVOCs such as acetaldehyde, acetone,,-methyl-+- propanol and etc. When the fungi grew with their sporule and changed their color, other MVOCs such as --Methyl-+-butanol, + -Octen---ol were emitted until about, weeks. Then as stopping growing, MVOC emissions decreased. Key words : Volatile organic compounds, Fungi, Indoor air quality