PROMEX Pyriproxyfen 100 g/l EC

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1 g Cheminova A/S Phone (+45) PROMEX 1 14 PROMEX Pyriproxyfen 100 g/l EC :. 1: / Pyriproxyfen 100 g/l EC PROMEX CHEMINOVA AGRO, S.A Paseo de la Castellana 257, 5º 28046, Madrid Spain buzon@cheminova.com (+30) (24 ; ) TMHMA 2: R-. CLP 1272/2008 : 1 (H304) / : 2A (H319) STOT SE: 3 (H336), : 1 (H 400) : 1 (H410) DPD. 1999/45/EC Xn;R65 R66 R67 R50/53... EU Reg. 1907/2006

. 14888 2015 PROMEX 2012 2 14 2.2. 1272/2008.

2 PROMEX / Pyriproxyfen 100 g/l EC (GHS07, GHS08, GHS09) H H H H EUH EUH : SP1 P102 P261 P270 P273 P280 P301+P310 P305+P351+P338. P331 P401 P ,.... (. ).. A /.,,.. /. :. :.,,...,. /. 2.3 PBT vpvb. EU Reg. 1907/2006

. 14888 2015 PROMEX 2012 3 14 3: / 3.1...., 3.2.... 16 R-. Pyriproxyfen... : 100 g/l CAS... 2-[1-methyl-2-(4-phenoxyphenoxy)ethoxy]pyridine CAS... 95737-68-1 IUPAC.

3 PROMEX : / , R-. Pyriproxyfen... : 100 g/l CAS... 2-[1-methyl-2-(4-phenoxyphenoxy)ethoxy]pyridine CAS IUPAC... 4-phenoxyphenyl (RS)- 2-(2-pyridyloxy) propyl ether Ethyl ISO/ EU... Pyriproxyfen EC no. (EINECS no.) DSD Xn;N CLP... Pyriproxyfen, Technical (% / ) CAS no EC no. (EINECS no.) DSD Xn; N; CLP Solvent naphtha (aromatic hydrocarbons, C10) Xn; R65,R66, R67 N; R51/53 : 1 (H304), ; (H336), : (H411). 4: ,,. :.. :... EU Reg. 1907/2006

4 PROMEX , ,,.....,.,, : ,. 5.2.,, ,..... EU Reg. 1907/2006

5 PROMEX : 6.1.,.. ( 10 ): 1., 8 2., ,,,, , GHS (Annex 4, Section 6).,,..., EU Reg. 1907/2006

6 PROMEX , ,., 8...,., ,.,,,,..,,., ( ).... 8: / 8.1. EU Reg. 1907/2006

.. DNEL,... DNEL,... DNEL,... DNEL,... 12.

5 ppm 8.2....,.,.,.,,.,.,,....,....... EU Reg.

7 PROMEX Pyriproxyfen DNEL,... DNEL,... DNEL,... DNEL,... DNEL,... naphtha DNEL,... DNEL,... DNEL,... DNEL,... DNEL, ppm 150 mg/m ppm 32 mg/m ppm ,.,.,.,,.,.,,...., EU Reg. 1907/2006

8 PROMEX ,, PE. PE. 9: ph... 1% : 6.09 /... Pyriproxyfen Purity 100%: ºC Solvent Naphtha:.... Pyriproxyfen Purity 99.7%: 318ºC C... ( / )... ( ) / Pyriproxyfen:... Pyriproxyfen : <1.33 x 10-5 Pa C Solvent Naphtha: 10hPa (25ºC) g/ml 20 C ( )... Pyriproxyfen 20 : n-heptane 25 to 29 g/l 1,2-Dichloroethane > 1000 g/l Methanol 25 to 29 g/l Acetone >1000 g/l p-xylene >1000 g/l Ethyl acetate >1000 g/l n- octanol/... Pyriproxyfen: KOW > 4.56 ( )... Pyriproxyfen: 400 ºC Solvent Naphtha: 400ºC... ( 10.2.) Pyriproxyfen: 318ºC N 2 20ºC: 1.56 mm2/s 20ºC1.37 mpa*s EU Reg. 1907/2006

9 PROMEX : , ,, : : ( ) - LD 50, oral, rat: > 5000 mg/kg (method OECD 423). - LD 50, dermal, rat: > 2000 mg/kg (method OECD LC 50, inhalation, rat: 2.44 mg/l (OECD 403). /..., (method OECD 404) /... 67/548/EC. 2 CLP 1272/2008 (method OECD 405).... (method OECD 406)...., Pyriproxyfen... 1, (H304).,,. : ( ) - LD 50, oral, rat: > 5000 mg/kg - LD 50, dermal, rat: > 2000 mg/kg - LC 50, inhalation, rat: > 1.3 mg/l/4 h EU Reg. 1907/2006

10 PROMEX /... / STOT... STOT... Solvent Naphtha... (M&K) :. :.,. : ( ) - LD 50, oral, rat: > 5000 mg/kg - LD 50, dermal, rat: > 2000 mg/kg - LC 50, inhalation, rat: > 4688 mg/l. /... / STOT... STOT... 3, (H336)... 1, (H304). 12: fosetyl-aluminium : - Rainbow trout (Oncorhynchus mykiss) h LC50: 620 µg../l EU Reg. 1907/2006

11 PROMEX Daphnids (Daphnia magna) h EC µg../l -... NOEC: 40 µg../l Pyriproxyfen MITI (< 1% 7 28 ). t 25ºC (ph , % oc), pyriproxyfen Pyriproxyfen Pyriproxyfen (Koc ml/g) PBT vpvb PBT vpvb : (2008/98/EC),.,,,.... ( ).,... 14: EU Reg. 1907/2006

12 PROMEX ADR/RID/IMDG/IATA/ICAO UN number UN,, n.o.s. (pyriproxifen) III II MARPOL 73/78 IBC. 15: /, 2 Seveso: :... CAS Chemical Abstracts Service CLP Classification, Labelling and Packaging; refers to EU regulation 1272/2008 as amended Dir. Directive DPD Dangerous Preparation Directive; refers to EU directive 1999/45/EC DSD Dangerous Substance Directive; refers to EU directive 67/548/EEC EC Emulsifiable Concentrate EC 50 50% Effect Concentration EINECS European Inventory of Existing Commercial Chemical Substances GHS Globally Harmonized classification and labelling System of chemicals, Fourth revised edition 2011 IBC International Bulk Chemical code IC50 50% Inhibition Concentration ISO International Organisation for Standardization IUPAC International Union of Pure and Applied Chemistry LC 50 50% Lethal Concentration 50% Lethal Dose LD 50 EU Reg. 1907/2006

13 PROMEX MARPOL Set of rules from the International Maritime Organisation (IMO) for prevention of sea pollution NOEC No Observed Effect Concentration N.o.s. Not otherwise specified OECD Organisation for Economic Cooperation and Development PBT Persistent, Bioaccumulative, Toxic Reg. Regulation PE Polyethylene PNEC Predicted No Effect Concentration PROC Process Category QSAR Quantitative Structure-Activity Relationship Reg. Regulation R-phrase Risk phrase SDS Safety Data Sheet SP Safety Precaution S-phrase Safety phrase STOT Specific Target Organ Toxicity TWA Time Weighed Average vpvb very Persistent, very Bioaccumulative WHO World Health Organisation : : - :, : R-... R65. R66. R67. R50/53,. R51/53,. CLP. H304. H319. H336. H400. H410,. H411, EU Reg. 1907/2006

14 PROMEX EUH066.. EUH , Cheminova A/S.. : Cheminova Agro, S.A Regulatory and Technical Department EU Reg. 1907/2006

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