Supporting Information
|
|
- Ὀφιοῦχος Ζωγράφος
- 5 χρόνια πριν
- Προβολές:
Transcript
1 Supporting Information For A Highly Sensitive ESIPT Based Ratiometric Fluorescence Sensor for Selective Detection of Al 3+ Sanghamitra Sinha, Bijit Chowdhury and Pradyut Ghosh* Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Kolkata , India. icpg@iacs.res.in Contents Page no. 1. Figure S1: 1 H-NMR spectrum of 1H in DMSO-d Figure S2: : 1 H- 1 H COSY-NMR spectrum of 1H in DMSO-d Figure S3: 13 C-NMR spectrum of 1H in DMSO-d Figure S4: : 1 H- DEPT-135 HSQC-NMR spectrum of 1H in DMSO-d Figure S5: ESI-MS of 1H 4 6. Scheme S1. Synthetic scheme of 1 Me 5 7. Figure S6: 1 H-NMR spectrum of 1 Me in DMSO-d Figure S7: ESI-MS of 1 Me 6 9. Figure S8: 3-D crystal packing of 1H (ethyl acetate) Table S1: List of crystallographic parameter details of ligand 1H Figure S9: UV-vis and PL spectra of 1 Me and in presence of Al Chart S1: Schematic representation of ESIPT mechanism Figure S10: Qualitative UV-vis spectra of 1H in acetonitrile Figure S11: Fluorescence titration profile for 1H (2.5 µm) with Cr Figure S12: Plot for quantum yield measurement Figure S13: UV-vis titration data of 1H with Al 3+ in acetonitrile Figure S14: Fluorescence Job s plot for 1H (2.5 µm) with Al 3+ in acetonitrile Figure S15: Selectivity and detection limit of 1H for Al 3+ in acetonitrile Table S2, S3 and Figure S16. Time-resolved luminescence data for 1H Figure S17: UV-vis and fluorescence spectra of 1H in H 2 O/acetonitrile (9:1 v/v) Figure S18, S19: UV-vis titration and Job s plot for 1H with Al Figure S20: Fluorescence equivalent plot for 1H with Al Figure S21: Benesi-Hildebrand plot and detection limit of 1H with Al Figure S22: Fluorescence decay profile of 1H with Al 3+ in H 2 O/acetonitrile (9:1 v/v) Figure S23. 1 H-NMR titration spectra of 1H with Al 3+ in D 2 O/CD 3 CN (1:1 v/v) Figure S24. 1 H-NMR spectrum of [Al(1)(OH)] 2+ 2 in DMSO-d Figure S25 and S26: ESI-MS spectra of the Al 3+ adduct of 1H Figure S27: DFT optimized structures of S 0 and S 1 states of [Al(1)(OH)] Figure S28: Selected MOs of 1H(enol), 1H(keto) and [Al(1)(OH)] Figure S29. Theoretical/experimental UV-vis spectra of 1H and [Al(1)(OH)] Table S4. Main calculated optical transitions for 1H and [Al(1)(OH)] Table S5. Main geometric parameters for S 0 and S 1 states of [Al(1)(OH)] Table S6: Cartesian coordinates of 1H(enol), 1H(keto) and [Al(1)(OH)]
2 Figure S1: 1 H-NMR (300 MHz) spectrum of 1H in DMSO-d 6. 2
3 Figure S2: 1 H- 1 H COSY-NMR (400 MHz) spectrum of 1H in DMSO-d 6. Figure S3: 13 C-NMR (100 MHz) spectrum of 1H in DMSO-d 6. 3
4 Figure S4: 1 H-DEPT-135 HSQC-NMR (400 MHz) spectrum of 1H in DMSOd 6. Figure S5: ESI-MS spectrum of 1H. 4
5 Scheme S1. Synthetic scheme of 1 Me. Figure S6: 1 H-NMR (500 MHz) spectrum of 1 Me in DMSO-d 6. 5
6 Figure S7: ESI-MS spectrum of 1 Me. Figure S8: A slice of three-dimensional (3-D) crystal packing of 1H obtained from ethyl acetate, along the crystallographic c axis. 6
7 Table S1: List of crystallographic parameter details of ligand 1H. Compound reference 1H Chemical formula C 29 H 31 N 3 O 3 Formula Mass Crystal system Orthorhombic a/å 20.07(3) b/å (16) c/å 20.36(3) α/ β/ γ/ Unit cell volume/å (12) Temperature/K 150(2) Space group Pbca No. of formula units per unit cell, Z 8 Radiation type MoKα Absorption coefficient, μ/mm No. of reflections measured No. of independent reflections 2661 R int Final R 1 values (I > 2σ(I)) Final wr(f 2 ) values (I > 2σ(I)) Final R 1 values (all data) Final wr(f 2 ) values (all data) Goodness of fit on F CCDC number
8 Figure S9: (a) UV-vis and PL spectra of 1 Me and (b) emission spectral changes of 1 Me in presence of Al 3+ in acetonitrile at room temperature. Chart S1: Schematic representation of ESIPT mechanism. Figure S10: Changes in absorption spectrum of 1H (20 µm) upon addition of various metal ions (10 equiv) in acetonitrile at room temperature. 8
9 Figure S11: Fluorescence titration profile for 1H (2.5 µm) with Cr 3+ acetonitrile at room temperature. in Figure S12: Plot of integrated emission intensity versus absorbance for calculation of quantum yield (ɸ f ) of 1H and its Al 3+ adduct in acetonitrile using quinine sulphate as standard (Considering the ɸ f of quinine sulphate in 0.1M H 2 SO 4 as 0.55 when the excitation wavelength is 366 nm). 9
10 Figure S13: (a) An equivalent plot from UV-vis titration data and (b) Jobs plot of 1H (20 µm) with Al 3+ (20 µm) in acetonitrile at room temperature. Figure S14. Fluorescence Jobs plot for 1H (2.5 µm) with Al 3+ (2.5 µm) in acetonitrile at room temperature. 10
11 Figure S15: (a) Selectivity graph of 1H with Al 3+ in presence of other metal ions in acetonitrile (λ em = 412 nm for Al 3+, Cr 3+, In 3+ and 445 nm for other metal ions). Orange bars represent the fluorescence intensities of 1H in presence of all metal ions (10 equiv) and green bars correspond to the same in presence of all metal ions and Al 3+. Codes used: (1) Only 1H (2) Mg 2+ (3) Ni 2+ (4) Mn 2+ (5) Cd 2+ (6) Pb 2+ (7) Zn 2+ (8) Co 2+ (9) Fe 3+ (10) Cu + (11) Ag + (12) Hg 2+ (13) In 3+ (14) Cr 3+ (15) Al 3+ and (b) the calibration curve for Al 3+ over the concentration range between 0 and 1.6 μm derived from the PL titration with 1H (2.5 μm) in acetonitrile at room temperature. Table S2: List of lifetimes of 1H (2.5 µm, λ em = 445 nm) and in presence of various metal ions (1 equiv) in acetonitrile. Entry Life Time (ns) Entry Life Time (ns) 1H H + 1 equiv Cd H + 1 equiv Al H + 1 equiv Cr H + 1 equiv Cu H + 1 equiv Fe H + 1 equiv Zn H + 1 equiv Mg H + 1 equiv Co H + 1 equiv Hg H + 1 equiv Ni H + 1 equiv Ag H + 1 equiv Pb
12 Figure S16: Time-resolved luminescence decays of 1H (2.5 µm) (a) at λ em = 412 nm and (b) at λ em = 525 nm, upon addition of increasing amount of Al 3+ in acetonitrile at room temperature. Table S3: List of lifetimes of 1H with increasing amount Al 3+. Equiv of Al 3+ λ em A 1 (%) t 1 (ns) A 2 (%) t 2 (ns) Ʈ avg (ns) χ equiv Al equiv Al equiv Al equiv Al equiv Al
13 Figure S17: UV-vis and fluorescence spectra of 1H, measured in H 2 O/acetonitrile (9:1 v/v) solvent at room temperature (concentrations: 20 µm and 2.5 µm respectively). Figure S18: UV-vis (a) titration profile and (b) corresponding equivalent plot for 1H (20 µm) with Al 3+ in H 2 O/acetonitrile (9:1 v/v) solvent at room temperature. 13
14 Figure S19: UV-vis Job s plot for 1H (20 µm) with Al 3+ H 2 O/acetonitrile (9:1 v/v) solvent at room temperature. (20 µm) in Figure S20: An equivalent plot from fluorescence titration data of 1H (2.5 µm) with Al 3+ in H 2 O/acetonitrile (9:1 v/v) solvent at room temperature. 14
15 Figure S21: (a) Benesi-Hildebrand Plot and (b) calibration curve for fluorescence titration of 1H with Al 3+ in H 2 O/acetonitrile (9:1 v/v) solvent at room temperature. Figure S22: Time-resolved luminescence decays of 1H (λ em = 465 nm) upon addition of increasing amount of Al 3+ in H 2 O/acetonitrile (9:1 v/v) at room temperature. 15
16 Figure S23: Changes in 1 H-NMR spectra (300 MHz) of 1H (8 mm) upon addition of increasing amounts of Al 3+ in D 2 O/CD 3 CN (1:1 v/v) solvent at room temperature. Figure S24: 1 H-NMR spectrum of [Al(1)(OH)] 2 2+ in DMSO-d 6 (300 MHz). 16
17 Figure S25: ESI-MS spectra of the Al 3+ adduct of 1H. Figure S26: Isotopic distribution pattern of (a) [Al(1)O] 2 K + and (b) [Al(1)(OH)] 2 2+ species (in the ESI-MS spectra of the isolated Al 3+ adduct of 1H) with its corresponding simulated pattern. 17
18 Figure S27. Theoretically (DFT B3LYP/6-311G(d); CPCM for acetonitrile) optimized structures of the ground state (S 0 ) and first excited state (S 1 ) of [Al(1)(OH)]
19 Figure S28. Selected MOs of 1H(enol), 1H(keto) and [Al(1)(OH)] 2+ 2 as obtained from the DFT B3LYP/6-311G(d) level of computation using CPCM model to encounter the solvent effect of acetonitrile [isovalue = 0.02]. 19
20 Figure S29: Theoretical (energy calculation by TD-DFT B3LYP/6-311G(d) level of computation (no of states = 26) using CPCM model for acetonitrile) and experimental UV-vis (20 µm) spectra of 1H and [Al(1)(OH)] Table S4. Main calculated optical transitions for 1H and [Al(1)(OH)] Entry Computed vertical excitation Experimentally observed transition Corresponding MOs Oscillator strength (f) Energy (ev) λ ex (nm) Energy (ev) λ ex (nm) 1H (enol) HOMO LUMO HOMO LUMO HOMO LUMO [Al(1)(OH)] HOMO LUMO HOMO-1 LUMO HOMO-1 LUMO
21 Table S5. The main geometric parameters for ground state (S 0 ) and first excited state (S 1 ) of [Al(1)(OH)] Entry Bond angles (degree) Bond lengths (Å) Entry S 0 S 1 S 0 S 1 Al1-O1-Al Al1-O Al1-O3-Al Al1-O O1-Al1-O Al1-O O1-Al2-O Al2-O H1-O1-Al Al2-O H2-O3-Al Al2-O O2-Al1-N O1-H O4-Al2-N O3-H O2-Al1-O N2-H O2-Al1-O N4-H O4-Al2-O N1-Al O4-Al2-O N3-Al N1-Al1-O N1-Al1-O N3-Al2-O N3-Al2-O
22 Table S6: The (x,y,z) Cartesian coordinates of 1H(enol), 1H(keto) and 2+ [Al(1)(OH)] 2 calculated from Gaussian-09 at B3LYP/6-311G(d) computational level using CPCM for acetonitrile. 1H (enol) Atom Coordinates (Angstroms) Coordinates (Angstroms) Atom x y z x y z C C C C C C C H C H C H N H C H C H C H C H O H C H N H C H C H N H C H C H C H C H C H C H C H C H C H
23 1H (keto) Atom Coordinates (Angstroms) Coordinates (Angstroms) Atom x y z x y z C C C C C C C H C H C H O H N H C H C H C H C H C H N H C H C H N H C H C H C H C H C H C H C H C H C H
24 2+ [Al(1)(OH)] 2 Atom Coordinates (Angstroms) Coordinates (Angstroms) Atom x y z x y z C C C C C Al C O C O C Al N C C C C C C C C C O C C N N C C C C C N C C O C C C N C C C C C N C C C C C C C C
25 C H C H C H C H C H C H C H C H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H
Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate
Διαβάστε περισσότεραSupporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting information An unusual bifunctional Tb-MOF for highly sensing
Διαβάστε περισσότεραSupporting Information for Substituent Effects on the Properties of Borafluorenes
Supporting Information for Substituent Effects on the Properties of Borafluorenes Mallory F. Smith, S. Joel Cassidy, Ian A. Adams, Monica Vasiliu, Deidra L. Gerlach, David Dixon*, Paul A. Rupar* Department
Διαβάστε περισσότεραPhoto-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond
Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond Ken-ichi Yamashita, Kei-ichi Sato, Masaki Kawano and Makoto Fujita* Contents; Figure S1.
Διαβάστε περισσότεραEnantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Enantioselective Organocatalytic Michael Addition of Isorhodanines to α,
Διαβάστε περισσότεραSupporting Information. Palladium Complexes with Bulky Diphosphine. Synthesis of (Bio-) Adipic Acid from Pentenoic. Acid Mixtures.
Supporting Information Palladium Complexes with Bulky Diphosphine Ligands as Highly Selective Catalysts for the Synthesis of (Bio-) Adipic Acid from Pentenoic Acid Mixtures. Choon Heng Low, James D. Nobbs,*
Διαβάστε περισσότεραElectronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads for low-energy photosensitization
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information Phosphorescent Pt(II) complexes bearing a monoanionic C^N^N luminophore
Διαβάστε περισσότεραSupporting Information
Supporting Information Molecular Cage Impregnated Palladium Nanoparticles: Efficient, Additive-Free Heterogeneous Catalysts for Cyanation of Aryl Halides. Bijnaneswar Mondal, Koushik Acharyya, Prodip Howlader
Διαβάστε περισσότεραdifluoroboranyls derived from amides carrying donor group Supporting Information
The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group Supporting Information Anna Maria Grabarz a Adèle D. Laurent b, Beata Jędrzejewska
Διαβάστε περισσότεραSupplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3
Supplementary Information Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3 Lewis Pairs: Structures of Intermediates, Kinetics, and Mechanism Qianyi Wang, Wuchao Zhao,
Διαβάστε περισσότεραEngineering Tunable Single and Dual Optical. Emission from Ru(II)-Polypyridyl Complexes. Through Excited State Design
Engineering Tunable Single and Dual Optical Emission from Ru(II)-Polypyridyl Complexes Through Excited State Design Supplementary Information Julia Romanova 1, Yousif Sadik 1, M. R. Ranga Prabhath 1,,
Διαβάστε περισσότεραPyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes
SUPPORTING INFORMATION Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes Eric J. Uzelac, Casey B. McCausland, and Seth C. Rasmussen*
Διαβάστε περισσότεραSupporting Information
SUPPORTING INFORMATION FOR: Trialkylstibine complexes of boron, aluminium, gallium and indium trihalides: synthesis, properties and bonding Victoria K. Greenacre, William Levason and Gillian Reid Chemistry,
Διαβάστε περισσότεραComputational study of the structure, UV-vis absorption spectra and conductivity of biphenylene-based polymers and their boron nitride analogues
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Computational study of the structure, UV-vis absorption spectra and conductivity of biphenylene-based
Διαβάστε περισσότεραFused Bis-Benzothiadiazoles as Electron Acceptors
Fused Bis-Benzothiadiazoles as Electron Acceptors Debin Xia, a,b Xiao-Ye Wang, b Xin Guo, c Martin Baumgarten,*,b Mengmeng Li, b and Klaus Müllen*,b a MIIT Key Laboratory of ritical Materials Technology
Διαβάστε περισσότεραHeavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2014 Supporting Information Heteroleptic Platinum(II) NHC Complexes with a C^C*
Διαβάστε περισσότεραchlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX
σ-donor/acceptor confused ligands: The case of a chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX 77843-3255. *To whom correspondence
Διαβάστε περισσότεραTable of Contents 1 Supplementary Data MCD
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information for Magnetic circular dichroism and density functional theory
Διαβάστε περισσότεραSupporting Information
Supporting Information Vinylogous elimination/heck coupling/allylation domino reactions: access to 2- substituted 2,3-dihydrobenzofurans and indolines Jianguo Yang, *, Hanjie Mo, Xiuxiu Jin, Dongdong Cao,
Διαβάστε περισσότεραButadiene as a Ligand in Open Sandwich Compounds
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2018 Butadiene as a Ligand in Open Sandwich Compounds Qunchao Fan, a Jia Fu, a Huidong
Διαβάστε περισσότεραEnantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid
Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid Taotao Ling, a Chinmay Chowdhury, a Bryan A. Kramer, a Binh G. Vong, a Michael A. Palladino b and Emmanuel A. Theodorakis a
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) CPh 3 as a functional group in P-heterocyclic
Διαβάστε περισσότεραA Selective, Sensitive, Colorimetric and Fluorescence Probe. for Relay Recognition of Fluoride and Cu (II) ions with
Supporting Information for A Selective, Sensitive, Colorimetric and Fluorescence Probe for Relay Recognition of Fluoride and Cu (II) ions with OFF-ON-OFF Switching in Ethanol-Water Solution Yu Peng,* Yu-Man
Διαβάστε περισσότεραNickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings
ickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings Braulio M. Puerta Lombardi, Rudy M. Braun, Chris Gendy, Chia Yun Chang,
Διαβάστε περισσότεραCycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles
X-Ray crystallographic data tables for paper: Supplementary Material (ESI) for Organic & Biomolecular Chemistry Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically
Διαβάστε περισσότεραSupporting Information. Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 16 Supporting Information Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid
Διαβάστε περισσότεραSupporting Information
Supporting Information On the Ambiguity of 1,3,2-Benzodiazaboroles as Donor/Acceptor unctionalities in Luminescent Molecules Lothar Weber *[a], Johannes Halama [a], Kenny Hanke [a], Lena Böhling [a], Andreas
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Cyclopentadienyl iron dicarbonyl (CpFe(CO) 2 ) derivatives
Διαβάστε περισσότεραPatrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.
; doi:10.3390/molecules22020254 S1 of S23 Supplementary Materials: Reaction of 3-Amino-1,2,4-Triazole with Diethyl Phosphite and Triethyl Orthoformate: Acid-Base Properties and Antiosteoporotic Activities
Διαβάστε περισσότεραC H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged
Supporting Information C H Activation of Cp* Ligand Coordinated to Ruthenium Center: Synthesis and Reactivity of a Thiolate-Bridged Diruthenium Complex Featuring Fulvene-like Cp* Ligand Xiaoxiao Ji, Dawei
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Abnormal N-Heterocyclic Carbene Based Nickel Complex for Catalytic
Διαβάστε περισσότεραTable S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.
Supporting Information [NH 3 CH 3 ] [In SbS 9 SH]: A novel methylamine-directed indium thioantimonate with Rb + ion-exchange property Kai-Yao Wang a,b, Mei-Ling Feng a, Jian-Rong Li a and Xiao-Ying Huang
Διαβάστε περισσότεραSupplementary materials
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supplementary materials Synthesis, Photophysical Properties and Application in Organic Light
Διαβάστε περισσότεραCollege of Life Science, Dalian Nationalities University, Dalian , PR China.
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 Postsynthetic modification
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) Lanthanide metal-organic frameworks constructed by asymmetric 2-nitro-biphenyl-4,4 -dicarboxylate ligand: syntheses, structures, luminescence and magnetic investigations
Διαβάστε περισσότεραHeterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics
Supporting Information (SI) Heterobimetallic Pd-Sn Catalysis: Michael Addition Reaction with C-, N-, -, S- Nucleophiles and In-situ Diagnostics Debjit Das, a Sanjay Pratihar a,b and Sujit Roy c * a rganometallics
Διαβάστε περισσότεραIV. ANHANG 179. Anhang 178
Anhang 178 IV. ANHANG 179 1. Röntgenstrukturanalysen (Tabellen) 179 1.1. Diastereomer A (Diplomarbeit) 179 1.2. Diastereomer B (Diplomarbeit) 186 1.3. Aldoladdukt 5A 193 1.4. Aldoladdukt 13A 200 1.5. Aldoladdukt
Διαβάστε περισσότεραSupporting Information. A single probe to sense Al(III) colorimetrically and. Cd(II) by turn-on fluorescence in physiological
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Supporting Information A single probe to sense Al(III) colorimetrically and Cd(II) by
Διαβάστε περισσότεραMultifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]
Supporting Information Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ] Eun Young Lee, Seung Yeon Jang, and Myunghyun Paik Suh* School of Chemistry,
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information Cucurbit[7]uril host-guest complexes of the histamine H 2 -receptor antagonist ranitidine Ruibing Wang and Donal H. Macartney* Department of Chemistry, Queen s University,
Διαβάστε περισσότεραSupporting Information
Supporting Information rigin of the Regio- and Stereoselectivity of Allylic Substitution of rganocopper Reagents Naohiko Yoshikai, Song-Lin Zhang, and Eiichi Nakamura* Department of Chemistry, The University
Διαβάστε περισσότεραDepartment of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Krzywoustego 4, Gliwice, Poland
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Tuning the photophysical properties of 4 -subsituted terpyridines - experimental
Διαβάστε περισσότεραSupporting Information
Supporting Information Aluminum Complexes of N 2 O 2 3 Formazanate Ligands Supported by Phosphine Oxide Donors Ryan R. Maar, Amir Rabiee Kenaree, Ruizhong Zhang, Yichen Tao, Benjamin D. Katzman, Viktor
Διαβάστε περισσότεραElectronic Supplementary Information for Dalton Transactions. Supplementary Data
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information for Dalton Transactions Supplementary Data Synthesis,
Διαβάστε περισσότεραSupplementary Information for
Supplentary Information for Aggregation induced blue-shifted ission molecular picture from QM/MM study Qunyan Wu, a Tian Zhang, a Qian Peng,* b Dong Wang, a and Zhigang Shuai* a a Key Loratory of Organic
Διαβάστε περισσότεραElectronic Supplementary Information:
Electronic Supplementary Information: 2 6 5 7 2 N S 3 9 6 7 5 2 S N 3 9 Scheme S. Atom numbering for thione and thiol tautomers of thioacetamide 3 0.6 0. absorbance 0.2 0.0 0.5 0.0 0.05 0.00 N 2 Ar km/mol
Διαβάστε περισσότεραCopper(II) complexes of salicylaldehydes and 2 hydroxyphenones: Synthesis, Structure,
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Copper(II) complexes of salicylaldehydes and 2 hydroxyphenones: Synthesis, Structure, Thermal
Διαβάστε περισσότεραSupplementary Information
Electronic upplementary Material (EI) for Photochemical & Photobiological ciences. This journal is The Royal ociety of Chemistry and wner ocieties 214 upplementary Information elective and sensitive fluorescence-shift
Διαβάστε περισσότεραSupporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory
Supporting Information Dysiherbols A C and Dysideanone E, Cytotoxic and NF-κB Inhibitory Tetracyclic Meroterpenes from a Dysidea sp. Marine Sponge Wei-Hua Jiao,, Guo-Hua Shi,, Ting-Ting Xu,, Guo-Dong Chen,
Διαβάστε περισσότεραZebra reaction or the recipe for heterodimeric zinc complexes synthesis
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 05 Supporting Information Zebra reaction or the recipe for heterodimeric zinc complexes synthesis
Διαβάστε περισσότεραElectronic Supporting Information. 3-Aminothiophenecarboxylic acid (3-Atc)-induced folding in peptides
Electronic Supplementary Material (ESI for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information
Διαβάστε περισσότεραTunable Ligand Emission of Napthylsalophen Triple-Decker Dinuclear Lanthanide (III) Sandwich Complexes
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supplemental Information Tunable Ligand Emission of Napthylsalophen Triple-Decker Dinuclear
Διαβάστε περισσότεραAvailable online at shd.org.rs/jscs/
J. Serb. Chem. Soc. 78 (1) S1 S8 (2013) Supplementary material SUPPLEMENTARY MATERIAL TO Metal complexes of N'-[2-hydroxy-5-(phenyldiazenyl)- benzylidene]isonicotinohydrazide. Synthesis, spectroscopic
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Crotonols A and B, Two Rare Tigliane Diterpenoid
Διαβάστε περισσότεραSupporting Information
Supporting Information for Pyrene nucleobase conjugates: synthesis, oligonucleotide binding and confocal bioimaging studies Artur Jabłoński 1, Yannic Fritz 2, Hans-Achim Wagenknecht 2, Rafał Czerwieniec
Διαβάστε περισσότεραSUPPLEMENTARY MATERIAL. In Situ Spectroelectrochemical Investigations of Ru II Complexes with Bispyrazolyl Methane Triarylamine Ligands
10.1071/CH16555_AC CSIRO 2017 Australian Journal of Chemistry 2017, 70(5), 546-555 SUPPLEMENTARY MATERIAL In Situ Spectroelectrochemical Investigations of Ru II Complexes with Bispyrazolyl Methane Triarylamine
Διαβάστε περισσότεραSupporting Information
One-Pot, Three-Component Assembly of Indoloquinolines: Total Synthesis of Isocryptolepine Alexander V. Aksenov,* Dmitrii A. Aksenov, Naila A. Orazova, Nicolai A. Aksenov, Georgii D. Griaznov, Annelise
Διαβάστε περισσότεραof the methanol-dimethylamine complex
Electronic Supplementary Information for: Fundamental and overtone virational spectroscopy, enthalpy of hydrogen ond formation and equilirium constant determination of the methanol-dimethylamine complex
Διαβάστε περισσότεραElectronic, Crystal Chemistry, and Nonlinear Optical Property Relationships. or W, and D = P or V)
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A 3 B 3 CD 2 O 14 Family (A = Sr, Ba or Pb; B = Mg or Zn; C = Te or W, and D = P or V) Hongwei Yu, Joshua Young,
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information The preferred all-gauche conformations in 3-fluoro-1,2-propanediol Laize A. F. Andrade, a Josué M. Silla, a Claudimar J. Duarte, b Roberto Rittner, b Matheus P. Freitas*,a
Διαβάστε περισσότεραand Trimethylene Carbonate
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2018 Supporting information for Preparation of Multiblock Copolymers via Step-wise Addition
Διαβάστε περισσότεραSupporting Information for. Department of Chemistry, Vanderbilt University, Nashville, TN 37235
Supporting Information for Functional Group Transformations in Derivatives of 1,4-Dihydrobenzo[1,2,4]triazinyl Radical Agnieszka Bodzioch, a, Minyan Zheng, a Piotr Kaszyński, a,b * Greta Utecht a a Organic
Διαβάστε περισσότεραSUPPLEMENTAL INFORMATION. Fully Automated Total Metals and Chromium Speciation Single Platform Introduction System for ICP-MS
Electronic Supplementary Material (ESI) for Journal of Analytical Atomic Spectrometry. This journal is The Royal Society of Chemistry 2018 SUPPLEMENTAL INFORMATION Fully Automated Total Metals and Chromium
Διαβάστε περισσότεραNovel electroluminescent donor-acceptors based on dibenzo[a,c]phenazine as
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Novel electroluminescent donor-acceptors
Διαβάστε περισσότεραSupporting Information
Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General
Διαβάστε περισσότεραAn experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH 3 NH 2, (CH 3 ) 2 NH, and (CH 3 ) 3 N
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 An experimental and theoretical study of the gas phase kinetics of atomic chlorine
Διαβάστε περισσότεραSwitching of the Photophysical Properties of. Bodipy-derived Trans Bis(tributylphosphine) Pt(II) bisacetylide Complexes with Rhodamine
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information for: Switching of the Photophysical Properties
Διαβάστε περισσότεραE-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations
E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations Nemanja Đorđević, Rakesh Ganguly, Milena Petković, and Dragoslav Vidović Email: drasko.vidovic@monash.edu
Διαβάστε περισσότεραSupporting Information. Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the. Synthesis of Heteroaromatic Biaryls
Supporting Information Pd()-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the Synthesis of Heteroaromatic Biaryls Debkumar andi, Yang-Ming Jhou, Jhen-Yi Lee, Bing-Chiuan
Διαβάστε περισσότεραSupporting Information
Supporting Information Tuning of Excited-State Intramolecular Proton Transfer (ESIPT) Fluorescence of Imidazo[1,2-a]pyridine in Rigid Matrices by Substitution Effect Toshiki Mutai,* irotaka Sawatani, Toshihide
Διαβάστε περισσότεραSynthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes
Supplementary information Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes Marcos A. P. Martins 1 *, Alexandre R. Meyer 1, Paulo R. S. Salbego
Διαβάστε περισσότεραSupplementary Materials for. Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides
Supplementary Materials for Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides Indrek Kalvet, a Karl J. Bonney, a and Franziska Schoenebeck a * a Institute of Organic
Διαβάστε περισσότεραSupplementary information
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary information Hybrids of acylated homoserine lactone and nitric
Διαβάστε περισσότεραSupporting Information
Supporting Information Mitochondria-Targeting Polydopamine Nanocomposites as Chemophotothermal Therapeutics for Cancer Zhuo Wang *,, Yuzhi Chen, Hui Zhang, Yawen Li, Yufan Ma, Jia Huang, Xiaolei Liu, Fang
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Sequentially palladium catalyzed coupling-cyclocondensation-coupling
Διαβάστε περισσότεραSynthesis, structural studies and stability of the model, cysteine containing DNA-protein cross-links
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 ELECTRONIC SUPPLEMENTARY INFORMATION
Διαβάστε περισσότεραSupplementary Material
Supplementary Material Synthesis of bis-oxathiaaza[3.3.3]propellanes via nucleophilic addition of (1,ω-alkanediyl)bis(N'-organylthioureas) on dicyanomethylene-1,3-indanedione Alaa A. Hassan, a * Kamal
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Cytotoxic and antimicrobial effects of indium(iii)
Διαβάστε περισσότεραSynthesis, Characterization, and Computational Study of Three-Coordinate SNS-Copper(I) Complexes Based on Bis-Thione Precursors
For Synthesis, Characterization, and Computational Study of Three-Coordinate SNS-Copper(I) Complexes Based on Bis-Thione Precursors John R. Miecznikowski a *; Matthew A. Lynn b ; Jerry P. Jasinski c ;
Διαβάστε περισσότερα9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer
Διαβάστε περισσότεραSupporting Information
Supporting Information 1,3,5-Triazapentadienes by Nucleophilic Addition to 1,3- and 1,4-Dinitriles - Sterically Constrained Examples by Incorporation into Cyclic Peripheries: Synthesis, Aggregation and
Διαβάστε περισσότεραAlkyl-functionalization of 3,5-bis(2-pyridyl)-1,2,4,6- thiatriazine
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information
Διαβάστε περισσότεραTable S1 Selected bond lengths [Å] and angles [ ] for complexes 1 8. Complex 1. Complex 2. Complex 3. Complex 4. Complex 5.
Table S1 Selected bond lengths [Å] and angles [ ] for complexes 1 8. Complex 1 Zn(1) O(1) 1.969(2) Zn(1) O(5) 1.989(3) Zn(1) O(6) 1.930(3) Zn(1) O(4) a 1.954(4) Zn(1) O(3) a 2.519(25) O(6) Zn(1) O(4) a
Διαβάστε περισσότεραSupplementary Materials: Development of Amyloseand β-cyclodextrin-based Chiral Fluorescent Sensors Bearing Terthienyl Pendants
S1 of S12 Supplementary Materials: Development of Amyloseand β-cyclodextrin-based Chiral Fluorescent Sensors Bearing Terthienyl Pendants Tomoyuki Ikai, Changsik Yun, Yutaka Kojima, Daisuke Suzuki, Katsuhiro
Διαβάστε περισσότερα10-π-electron arenes à la carte: Structure. Sr, Ba; n = 6-8) complexes
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 Supporting information 10-π-electron arenes à la carte: Structure and Bonding of
Διαβάστε περισσότεραSupporting Information File 2. Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ;
Supporting Information File 2 Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ; Preparation, structures and host guest chemistry of fluorinated syn-bisquinoxaline molecular tweezers
Διαβάστε περισσότεραMetal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:
Διαβάστε περισσότεραELECTRONIC SUPPLEMENTARY MATERIAL-RSC Adv.
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 ELECTRONIC SUPPLEMENTARY MATERIAL-RSC Adv. Studies of molecular structure, hydrogen bonding
Διαβάστε περισσότεραElectronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates
Electronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates Zhong-Ling Lang, Guo-Chun Yang, Na-Na Ma, Shi-Zheng Wen,
Διαβάστε περισσότεραSUPPORTING INFORMATION
SUPPORTING INFORMATION Heronamides A C, new polyketide macrolactams from an Australian marine-derived Streptomyces sp. A biosynthetic case for synchronized tandem electrocyclization. Ritesh Raju, Andrew
Διαβάστε περισσότεραManuscript submitted to the Journal of the American Society for Mass Spectrometry, September 2011.
The Early Life of a Peptide Cation-Radical. Ground and Excited-State Trajectories of Electron-Based Peptide Dissociations During the First 330 Femtoseconds Christopher L. Moss, Wenkel Liang, Xiaosong Li,*
Διαβάστε περισσότεραSupporting Information
Supporting Information Wiley-VCH 27 69451 Weinheim, Germany Supplementary Figure 1. Synthetic results as detected by XRD (Cu-Kα). Simulation pattern of MCM-68 Relative Intensity / a.u. YNU-2P Conventional
Διαβάστε περισσότεραSupporting Information. Halogen Photoelimination from Monomeric Ni(III) Complexes Enabled by the Secondary Coordination Sphere
Supporting Information Halogen Photoelimination from Monomeric Ni(III) Complexes Enabled by the Secondary Coordination Sphere Seung Jun Hwang, a Bryce L. Anderson, a David C. Powers, a Andrew G. Maher,
Διαβάστε περισσότεραSupporting Information
Supporting Information Chloroyttrium 2-(1-(arylimino)alkyl)quinolin-8-olate Complexes: Synthesis, Characterization, and Catalysis of the Ring-Opening Polymerization (ROP) of ε- Caprolactone (ε-cl) Wenjuan
Διαβάστε περισσότεραBloco A, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ, Brazil. Contents Pages
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information Copper(II) Catalyzed Synthesis of Novel Helical
Διαβάστε περισσότεραSUPPLEMENTARY MATERIAL
10.1071/CH16014_AC The Authors 2016 Australian Journal of Chemistry 2016, 69(9), 1049-1053 SUPPLEMENTARY MATERIAL A Green Approach for the Synthesis of Novel 7,11-Dihydro-6H-chromeno[3,4- e]isoxazolo[5,4-b]pyridin-6-one
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2018 Supporting Information Fluorine Substituent Effect on the Stereochemistry of Catalyzed
Διαβάστε περισσότεραDipole-Guided Electron Capture Causes Abnormal Dissociations of Phosphorylated Pentapeptides
Supplementary Material for Dipole-Guided Electron Capture Causes Abnormal Dissociations of Phosphorylated Pentapeptides Christopher L. Moss, a Thomas W. Chung, a Jean A. Wyer, b Steen Brøndsted Nielsen,
Διαβάστε περισσότερα