Electronic Supplementary Information
|
|
- Νατάσσα Μακρή
- 6 χρόνια πριν
- Προβολές:
Transcript
1 Electronic Supplementary Information The preferred all-gauche conformations in 3-fluoro-1,2-propanediol Laize A. F. Andrade, a Josué M. Silla, a Claudimar J. Duarte, b Roberto Rittner, b Matheus P. Freitas*,a a Department of Chemistry, Federal University of Lavras, P.O. Box 3037, , Lavras, MG, Brazil b Chemistry Institute, State University of Campinas, P.O. Box 6154, , Campinas, SP, Brazil * Corresponding author: matheus@dqi.ufla.br; Tel: ; Fax: Page S1. Figure S1. 1 H NMR spectrum for 3-fluoro-1,2-propanediol acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. Page S2. Figure S2. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H1a and H1b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. Page S3. Figure S3. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H2, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. Page S4. Figure S4. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H3a and H3b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. Page S5. Figure S5. 1 H NMR spectrum for 3-fluoro-1,2-propanediol acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. Page S6. Figure S6. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H1a and H1b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. Page S7. Figure S7. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H2, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. Page S8. Figure S8. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H3a and H3b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. Page S9. Figure S9. 1 H x 19 F HETCOR for 3-fluoro-1,2-propanediol in CDCl 3, at MHz for 1 H and MHz for 19 F, acquired in a Bruker Avance 500 spectrometer using ca. 20 mg ml -1 in CDCl 3 at 298K. Page S10. Optimized geometries for the 25 main conformers of compound 2 obtained at the B3LYP/ g(d,p) level. Page S19. Table S1. Conformers of 2 found at the B3LYP/ g(d,p) level, with respective relative energies (in kcal mol -1 ) and population (%) in the gas phase and solution (CHCl 3 and CH 3 CN implicit solvents). Page S27. Table S2. Calculated and experimental chemical shifts (in ppm, relative to TMS, using the calculated isotropic magnetic shielding tensor) and coupling constants (in Hz) for 2, in CHCl 3. Page S28. Table S2. Calculated and experimental chemical shifts (in ppm, relative to TMS, using the calculated isotropic magnetic shielding tensor) and coupling constants (in Hz) for 2, in CH 3 CN.
2 Figure S1. 1 H NMR spectrum for 3-fluoro-1,2-propanediol acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. 1
3 Figure S2. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H1a and H1b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. 2
4 Figure S3. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H2, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. 3
5 Figure S4. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H3a and H3b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CDCl 3 at 298K. 4
6 Figure S5. 1 H NMR spectrum for 3-fluoro-1,2-propanediol acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. 5
7 Figure S6. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H1a and H1b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. 6
8 Figure S7. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H2, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. 7
9 Figure S8. Expansion of the 1 H NMR spectrum for 3-fluoro-1,2-propanediol in the region of H3a and H3b, acquired in a Bruker Avance III 600 spectrometer operating at MHz, using ca. 20 mg ml -1 in CD 3 CN at 298K. 8
10 Figure S9. 1 H x 19 F HETCOR for 3-fluoro-1,2-propanediol in CDCl 3, at MHz for 1 H and MHz for 19 F, acquired in a Bruker Avance 500 spectrometer using ca. 20 mg ml -1 in CDCl 3 at 298K. 9
11 Optimized geometries for the 25 main conformers of compound 2 obtained at the B3LYP/ g(d,p) level. 2a Standard orientation: Rotational constants (GHZ): b Standard orientation: Rotational constants (GHZ): c Standard orientation: Rotational constants (GHZ):
12 2d Standard orientation: Rotational constants (GHZ): e Standard orientation: Rotational constants (GHZ): f Standard orientation: Rotational constants (GHZ):
13 2g Standard orientation: Rotational constants (GHZ): h Standard orientation: Rotational constants (GHZ): i Standard orientation: Rotational constants (GHZ):
14 2j Standard orientation: Rotational constants (GHZ): k Standard orientation: Rotational constants (GHZ): l Standard orientation: Rotational constants (GHZ):
15 2m Standard orientation: Rotational constants (GHZ): n Standard orientation: Rotational constants (GHZ): o Standard orientation: Rotational constants (GHZ):
16 2p Standard orientation: Rotational constants (GHZ): q Standard orientation: Rotational constants (GHZ): r Standard orientation: Rotational constants (GHZ):
17 2s Standard orientation: Rotational constants (GHZ): t Standard orientation: Rotational constants (GHZ): u Standard orientation: Rotational constants (GHZ):
18 2v Standard orientation: Rotational constants (GHZ): w Standard orientation: Rotational constants (GHZ): x Standard orientation: Rotational constants (GHZ):
19 2y Standard orientation: Rotational constants (GHZ):
20 Table S1. Conformers of 2 found at the B3LYP/ g(d,p) level, with respective relative energies (in kcal mol -1 ) and population (%) in the gas phase and solution (CHCl 3 and CH 3 CN implicit solvents). Structure Conformer E gas % gas E CHCl3 % CHCl3 E CH3CN % CH3CN 2a b c d e f g
21 2h i j k l m n o
22 2p q r s t u v w
23 2x y z aa ab ac ad
24 2ae af ag ah ai aj ak
25 2al am an ao ap aq ar
26 2as at au av aw ax ay
27 2az ba
28 Table S2. Calculated and experimental chemical shifts (in ppm, relative to TMS, using the calculated isotropic magnetic shielding tensor) and coupling constants (in Hz) for 2, in CHCl 3. Conformer δ H1a δ H1b δ H2 δ H3a δ H3b 2 J H1a,H1b 3 J H1a,H2 4 J H1a,F 3 J H1b,H2 4 J H1b,F 3 J H2,H3a 3 J H2,H3b 3 J H2,F 2 J H3a,H3b 2 J H3a,F 2a b c d e f g h i j k l m n o p q r s t u v w x y Exp. CDCl J H3b,F 27
29 Table S3. Calculated and experimental chemical shifts (in ppm, relative to TMS, using the calculated isotropic magnetic shielding tensor) and coupling constants (in Hz) for 2, in CH 3 CN. Conformer δ H1a δ H1b δ H2 δ H3a δ H3b 2 J H1a,H1b 3 J H1a,H2 4 J H1a,F 3 J H1b,H2 4 J H1b,F 3 J H2,H3a 3 J H2,H3b 3 J H2,F 2 J H3a,H3b 2 J H3a,F 2a b c d e f g h i j k l m n o p q r s t u v w x y Exp. CH3CN J H3b,F 28
Supplementary Information
9.4 6.60. 8.6 8.8 9.29 20.04 29.6 0.07 6. 40.92 4.64 06.0 6.29 6.0-0.00 Supplementary Information Conformational Analysis, Experimental and GIA-DFT C NMR Chemical Shift Calculation on 2 -Hydroxy-,4,-trimethoxy-chalcone
Διαβάστε περισσότεραHeterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics
Supporting Information (SI) Heterobimetallic Pd-Sn Catalysis: Michael Addition Reaction with C-, N-, -, S- Nucleophiles and In-situ Diagnostics Debjit Das, a Sanjay Pratihar a,b and Sujit Roy c * a rganometallics
Διαβάστε περισσότεραMetal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:
Διαβάστε περισσότεραA facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information NbCl 3 -catalyzed [2+2+2] intermolecular cycloaddition of alkynes and alkenes to 1,3-cyclohexadiene derivatives Yasushi Obora,* Keisuke Takeshita and Yasutaka Ishii*
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization
Διαβάστε περισσότεραHighly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces
Highly enantioselective cascade synthesis of spiropyrazolones Alex Zea a, Andrea-Nekane R. Alba a, Andrea Mazzanti b, Albert Moyano a and Ramon Rios a,c * Supporting Information NMR spectra and HPLC traces
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Crotonols A and B, Two Rare Tigliane Diterpenoid
Διαβάστε περισσότεραSynthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions
This journal is The Royal Society of Chemistry 213 Synthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions Wenjing Cui, a Bao Zhaorigetu,* a Meilin Jia, a and Wulan
Διαβάστε περισσότεραSupporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Proton nuclear magnetic resonance ( 1
Διαβάστε περισσότεραDipole-Guided Electron Capture Causes Abnormal Dissociations of Phosphorylated Pentapeptides
Supplementary Material for Dipole-Guided Electron Capture Causes Abnormal Dissociations of Phosphorylated Pentapeptides Christopher L. Moss, a Thomas W. Chung, a Jean A. Wyer, b Steen Brøndsted Nielsen,
Διαβάστε περισσότεραSupporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Anhydrous solvents were transferred by
Διαβάστε περισσότεραSupporting Information. A Combined Crossed Molecular Beams and ab Initio Investigation on the Formation of Vinylsulfidoboron (C 2 H
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2014 Supporting Information for A Combined Crossed Molecular Beams and ab Initio Investigation
Διαβάστε περισσότεραCarbohydrates in the gas phase: conformational preference of D-ribose and 2-deoxy-D-ribose
New J. Chem ELECTRONIC SUPPLEMENTARY INFORMATION Carbohydrates in the gas phase: conformational preference of D-ribose and 2-deoxy-D-ribose Luis Miguel Azofra,*, María Mar Quesada-Moreno, Ibon Alkorta,
Διαβάστε περισσότεραRegioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone.
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone. Won-Suk Kim, Hyung-Jin Kim and Cheon-Gyu Cho Department of Chemistry, Hanyang University, Seoul 133-791, Korea Experimental Section
Διαβάστε περισσότεραNickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings
ickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings Braulio M. Puerta Lombardi, Rudy M. Braun, Chris Gendy, Chia Yun Chang,
Διαβάστε περισσότερα9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer
Διαβάστε περισσότεραCopper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic
Διαβάστε περισσότεραSupporting Information for: electron ligands: Complex formation, oxidation and
Supporting Information for: The diverse reactions of PhI(OTf) 2 with common 2- electron ligands: Complex formation, oxidation and oxidative coupling Thomas P. Pell, Shannon A. Couchman, Sara Ibrahim, David
Διαβάστε περισσότεραSupplementary!Information!
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015! Synthesis)and)characterisation)of)an)open1cage) fullerene)encapsulating)hydrogen)fluoride! Supplementary!Information!
Διαβάστε περισσότεραManuscript submitted to the Journal of the American Society for Mass Spectrometry, September 2011.
The Early Life of a Peptide Cation-Radical. Ground and Excited-State Trajectories of Electron-Based Peptide Dissociations During the First 330 Femtoseconds Christopher L. Moss, Wenkel Liang, Xiaosong Li,*
Διαβάστε περισσότεραSupporting Information
Supporting Information Aluminum Complexes of N 2 O 2 3 Formazanate Ligands Supported by Phosphine Oxide Donors Ryan R. Maar, Amir Rabiee Kenaree, Ruizhong Zhang, Yichen Tao, Benjamin D. Katzman, Viktor
Διαβάστε περισσότεραCopper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds. in Aromatic Amides
Supporting Information for Copper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds in Aromatic Amides Feifan Wang, Qiyan Hu, Chao Shu, Zhiyang Lin, Dewen Min, Tianchao Shi and Wu Zhang* Key Laboratory
Διαβάστε περισσότεραCopper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2016 Supporting information Copper-Catalyzed Oxidative Dehydrogenative - Bond Formation
Διαβάστε περισσότεραSupporting Information for. Update of spectroscopic data for 4-hydroxyldictyolactone and dictyol E isolated from a Halimeda stuposa - Dictyota
1 Supporting Information for Update of spectroscopic data for 4-hydroxyldictyolactone and dictyol E isolated from a Halimeda stuposa - Dictyota sp. Assemblage Simon P. B. Ovenden, Jonathan L. Nielson,
Διαβάστε περισσότεραSupporting Information One-Pot Approach to Chiral Chromenes via Enantioselective Organocatalytic Domino Oxa-Michael-Aldol Reaction
Supporting Information ne-pot Approach to Chiral Chromenes via Enantioselective rganocatalytic Domino xa-michael-aldol Reaction Hao Li, Jian Wang, Timiyin E-Nunu, Liansuo Zu, Wei Jiang, Shaohua Wei, *
Διαβάστε περισσότεραSupporting Information
Supporting Information Lewis acid catalyzed ring-opening reactions of methylenecyclopropanes with diphenylphosphine oxide in the presence of sulfur or selenium Min Shi,* Min Jiang and Le-Ping Liu State
Διαβάστε περισσότεραTable of Contents 1 Supplementary Data MCD
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information for Magnetic circular dichroism and density functional theory
Διαβάστε περισσότεραFree Radical Initiated Coupling Reaction of Alcohols and. Alkynes: not C-O but C-C Bond Formation. Context. General information 2. Typical procedure 2
Free Radical Initiated Coupling Reaction of Alcohols and Alkynes: not C-O but C-C Bond Formation Zhongquan Liu,* Liang Sun, Jianguo Wang, Jie Han, Yankai Zhao, Bo Zhou Institute of Organic Chemistry, Gannan
Διαβάστε περισσότεραParts Manual. Trio Mobile Surgery Platform. Model 1033
Trio Mobile Surgery Platform Model 1033 Parts Manual For parts or technical assistance: Pour pièces de service ou assistance technique : Für Teile oder technische Unterstützung Anruf: Voor delen of technische
Διαβάστε περισσότερα10-π-electron arenes à la carte: Structure. Sr, Ba; n = 6-8) complexes
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 Supporting information 10-π-electron arenes à la carte: Structure and Bonding of
Διαβάστε περισσότεραELECTRONIC SUPPORTING INFORMATION
ELECTRONIC SUPPORTING INFORMATION Spectroscopic signatures of the carbon buckyonions C 60 @C 180 and C 60 @C 240 : a dispersion-corrected DFT study. Girolamo Casella, a Alessandro Bagno a and Giacomo Saielli*
Διαβάστε περισσότεραElectronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates
Electronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates Zhong-Ling Lang, Guo-Chun Yang, Na-Na Ma, Shi-Zheng Wen,
Διαβάστε περισσότεραSupplementary Materials for. Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides
Supplementary Materials for Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides Indrek Kalvet, a Karl J. Bonney, a and Franziska Schoenebeck a * a Institute of Organic
Διαβάστε περισσότεραDirect Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines Min Jiang, Ting Li, Linghua Meng, Chunhao Yang,* Yuyuan Xie*, and Jian Ding State Key Laboratory of
Διαβάστε περισσότεραSupporting Information
Supporting Information for AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds Qiuping Ding 1, Dan Wang 1, Puying Luo* 2, Meiling Liu 1, Shouzhi Pu* 3 and
Διαβάστε περισσότεραHeavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative
Διαβάστε περισσότεραElectronic Supplementary Information:
Electronic Supplementary Information: 2 6 5 7 2 N S 3 9 6 7 5 2 S N 3 9 Scheme S. Atom numbering for thione and thiol tautomers of thioacetamide 3 0.6 0. absorbance 0.2 0.0 0.5 0.0 0.05 0.00 N 2 Ar km/mol
Διαβάστε περισσότεραDirect Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3
Supporting Information Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Shohei Shimokawa, Yuhsuke Kawagoe, Katsuhiko Moriyama, Hideo Togo* Graduate
Διαβάστε περισσότεραSupporting Information. Route to benzo- and pyrido-fused 1,2,4-triazinyl radicals via N'-(het)aryl- N'-[2-nitro(het)aryl]hydrazides
Supporting Information Route to benzo- and pyrido-fused 1,2,4-triazinyl radicals via N'-(het)aryl- N'-[2-nitro(het)aryl]hydrazides Andrey A. Berezin, Georgia Zissimou, Christos P. Constantinides, Yassine
Διαβάστε περισσότεραSynthesis, structural studies and stability of the model, cysteine containing DNA-protein cross-links
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 ELECTRONIC SUPPLEMENTARY INFORMATION
Διαβάστε περισσότεραSupporting Information
Supporting Information Synthesis and Electroactive Properties of Poly(amidoamine) Dendrimers with an Aniline Pentamer Shell Wei-I Hung a, Chih-Bing Hung a, Ya-Han Chang a, Jiun-Kuang Dai a, Yan Li b, Hai
Διαβάστε περισσότεραΠΡΟΓΡΑΜΜΑ ΕΚΠΟΝΗΣΗΣ ΜΕΛΕΤΩΝ ΚΑΙ ΧΡΟΝΟΔΙΑΓΡΑΜΜΑ
ΕΛΛΗΝΙΚΗ ΔΗΜOΚΡΑΤΙΑ ΥΠΟΥΡΓΕΙΟ ΠΕΡΙΒΑΛΛΟΝΤΟΣ ΚΑΙ ΕΝΕΡΓΕΙΑΣ Γ.Γ. Χωρικού Σχεδιασμού & Αστικού Περιβάλλοντος Γεν. Δ/νση Χωρικού Σχεδιασμού Δ/νση Χωροταξικού Σχεδιασμού ΜΕΛΕΤΗ: ΧΡΗΜ/ΤΗΣΗ: Αξιολόγηση και αναθεώρηση
Διαβάστε περισσότεραΚίνηση σε Μονοδιάστατα Τετραγωνικά Δυναμικά
Κίνηση σε Μονοδιάστατα Τετραγωνικά Δυναμικά Δομή Διάλεξης Τετραγωνικό Πηγάδι Δυναμικού: Δέσμιες καταστάσεις - ιδιοτιμές Οριακές Περιπτώσεις: δ δυναμικό, άπειρο βάθος Σκέδαση σε μια διάσταση: Σκαλοπάτι
Διαβάστε περισσότεραComputational study of the structure, UV-vis absorption spectra and conductivity of biphenylene-based polymers and their boron nitride analogues
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Computational study of the structure, UV-vis absorption spectra and conductivity of biphenylene-based
Διαβάστε περισσότεραof the methanol-dimethylamine complex
Electronic Supplementary Information for: Fundamental and overtone virational spectroscopy, enthalpy of hydrogen ond formation and equilirium constant determination of the methanol-dimethylamine complex
Διαβάστε περισσότεραSupporting Information for. A New Diketopiperazine, Cyclo-(4-S-Hydroxy-R-Proline-R-Isoleucine), from an Australian Specimen of the Sponge
1 Supporting Information for A New Diketopiperazine, Cyclo-(4-S-Hydroxy-R-Proline-R-Isoleucine), from an Australian Specimen of the Sponge Stelletta Sp. Simon P. B. Ovenden, Jonathan L. Nielson, Catherine
Διαβάστε περισσότεραSupporting Information
Supporting Information for Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Chun-Huan Jiang, Xiantao Lei,
Διαβάστε περισσότεραMandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes
1 Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes Gonzalo Blay, Isabel Fernández, Alícia Marco-Aleixandre, and José R. Pedro Departament de Química Orgànica, Facultat de Química,
Διαβάστε περισσότεραTable S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.
Supporting Information [NH 3 CH 3 ] [In SbS 9 SH]: A novel methylamine-directed indium thioantimonate with Rb + ion-exchange property Kai-Yao Wang a,b, Mei-Ling Feng a, Jian-Rong Li a and Xiao-Ying Huang
Διαβάστε περισσότεραPyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes
SUPPORTING INFORMATION Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes Eric J. Uzelac, Casey B. McCausland, and Seth C. Rasmussen*
Διαβάστε περισσότεραdifluoroboranyls derived from amides carrying donor group Supporting Information
The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group Supporting Information Anna Maria Grabarz a Adèle D. Laurent b, Beata Jędrzejewska
Διαβάστε περισσότεραSupporting Information
Supporting Information Ceric Ammonium Nitrate (CAN) catalyzed efficient one-pot three component aza-diels-alder reactions for a facile synthesis of tetrahydropyranoquinoline derivatives Ravinder Goud Puligoundla
Διαβάστε περισσότεραMalgorzata Korycka-Machala, Marcin Nowosielski, Aneta Kuron, Sebastian Rykowski, Agnieszka Olejniczak, Marcin Hoffmann and Jaroslaw Dziadek
Molecules 2017, 21, 154; doi:10.3390/molecules22010154 Supplementary Materials: Naphthalimides Selectively Inhibit the Activity of Bacterial, Replicative DNA Ligases and Display Bactericidal Effect against
Διαβάστε περισσότεραVilsmeier Haack reagent-promoted formyloxylation of α-chloro-narylacetamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Vilsmeier aack reagent-promoted formyloxylation of α-chloro-arylacetamides by formamide Jiann-Jyh
Διαβάστε περισσότεραExtended dissolution studies of cellulose in imidazolium based ionic liquids
Electronic Supplementary Information Extended dissolution studies of cellulose in imidazolium based ionic liquids Jürgen Vitz, a,b Tina Erdmenger, a,b Claudia Haensch, a,b Stephanie Hornig # and Ulrich
Διαβάστε περισσότεραRhodium-Catalyzed Oxidative Decarbonylative Heck-type Coupling of Aromatic Aldehydes with Terminal Alkenes
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Rhodium-Catalyzed Oxidative Decarbonylative Heck-type
Διαβάστε περισσότεραΥΠΗΡΕΣΙΕΣ ΠΡΟΣΩΠΙΚΟΥ ΔΙΑΧΕΙΡΙΣΗ ΑΠΟΔΟΣΗΣ ΚΑΙ ΣΤΕΛΕΧΩΣΗ
ΥΠΗΡΕΣΙΕΣ ΠΡΟΣΩΠΙΚΟΥ ΔΙΑΧΕΙΡΙΣΗ ΑΠΟΔΟΣΗΣ ΚΑΙ ΣΤΕΛΕΧΩΣΗ ΚΑΤΑΛΟΓΟΣ ΑΠΟΤΕΛΕΣΜΑΤΩΝ ΗΛΕΚΤΡΟΝΙΚΟΥ ΤΕΣΤ ΙΚΑΝΟΤΗΤΩΝ ΓΙΑ ΤΙΣ ΘΕΣΕΙΣ ΩΡΟΜΙΣΘΙΟΥ ΠΡΟΣΩΠΙΚΟΥ ΒΟΗΘΟΙ ΤΗΛΕΞΥΠΗΡΕΤΗΣΗΣ (ΑΡ. ΠΡΟΚΗΡΥΞΗΣ: 2/2017) (ΛΕΥΚΩΣΙΑ
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Syntheses and structures of copper complexes of
Διαβάστε περισσότεραSynthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes
Supplementary information Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes Marcos A. P. Martins 1 *, Alexandre R. Meyer 1, Paulo R. S. Salbego
Διαβάστε περισσότεραNew Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp.
SUPPLEMENTARY MATERIAL New Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp. Mohamed-Elamir F. Hegazy a,*, Amira M. Gamal-Eldeen b, Tarik A. Mohamed a, Montaser A. Alhammady c, Abuzeid A.
Διαβάστε περισσότεραSupplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%. S1 Supplementary Figure S2. Single X-ray structure 5a at probability ellipsoids of 20%. S2 H 15 Ph Ac Ac I AcH Ph Ac
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information A Convenient and Efficient Synthesis of Glycals by Zinc Nanoparticles
Διαβάστε περισσότεραSupporting information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 204 Supporting information Palladium nanoparticles supported on triazine functionalised mesoporous
Διαβάστε περισσότεραFacile construction of the functionalized 4H-chromene via tandem. benzylation and cyclization. Jinmin Fan and Zhiyong Wang*
Facile construction of the functionalized 4H-chromene via tandem benzylation and cyclization Jinmin Fan and Zhiyong Wang* Hefei National Laboratory for Physical Science at Microscale, Joint- Lab of Green
Διαβάστε περισσότεραLewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes
Supporting Information for Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes Changkun Li and Jianbo Wang* Beijing National Laboratory
Διαβάστε περισσότεραAvailable online at shd.org.rs/jscs/
J. Serb. Chem. Soc. 78 (12) S131 S136 (2013) Supplementary material SUPPLEMENTARY MATERIAL TO New 9-aminoacridine derivatives as inhibitors of botulinum neurotoxins and P. falciparum malaria MIKLOŠ TOT
Διαβάστε περισσότεραChannels and Monomolecular Nanotubes
Supporting nformation Control of Helix Formation by (E)- and (Z)-Double Bonds in Vinylogous γ-peptides A Way to on Channels and Monomolecular Nanotubes Carsten Baldauf, Robert Günther and Hans-Jörg Hofmann*
Διαβάστε περισσότεραSupporting Information. Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on
Supporting Information for Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on folding and bioactivity Marta De Zotti 1, Barbara Biondi 1, Cristina Peggion 1, Matteo De Poli 1, Haleh
Διαβάστε περισσότεραThe Free Internet Journal for Organic Chemistry
The Free Internet Journal for Organic Chemistry Paper Archive for Organic Chemistry Arkivoc 2018, part iii, S1-S6 Synthesis of dihydropyranones and dihydropyrano[2,3- d][1,3]dioxine-diones by cyclization
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) CPh 3 as a functional group in P-heterocyclic
Διαβάστε περισσότεραSupplementary materials. Mode Analysis. Matthias M. N. Wolf, Christian Schumann, Ruth Groß, Tatiana Domratcheva 1 and Rolf. Diller
Supplementary materials Ultrafast Infrared Spectroscopy of Riboflavin: Dynamics, Electronic Structure, and Vibrational Mode Analysis Matthias M. N. Wolf, Christian Schumann, Ruth Groß, Tatiana Domratcheva
Διαβάστε περισσότεραSUPPORTING INFORMATION
SUPPRTING INFRMATIN Dihydroxylation of lefins Catalyzed by Zeolite-Confined smium Nanoclusters: A Novel, Effective, Reusable and Eco-Friendly Method for Preparation of 1,2-cis-Diols Önder Metin,*,a Nurdan
Διαβάστε περισσότεραSupporting Information. A single probe to sense Al(III) colorimetrically and. Cd(II) by turn-on fluorescence in physiological
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Supporting Information A single probe to sense Al(III) colorimetrically and Cd(II) by
Διαβάστε περισσότεραELECTRONIC SUPPLEMENTARY MATERIAL-RSC Adv.
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 ELECTRONIC SUPPLEMENTARY MATERIAL-RSC Adv. Studies of molecular structure, hydrogen bonding
Διαβάστε περισσότεραFluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3- Oxyfluorination and 1,3-Difluorination
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supporting Information Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine
Διαβάστε περισσότεραSUPPLEMENTARY MATERIAL. In Situ Spectroelectrochemical Investigations of Ru II Complexes with Bispyrazolyl Methane Triarylamine Ligands
10.1071/CH16555_AC CSIRO 2017 Australian Journal of Chemistry 2017, 70(5), 546-555 SUPPLEMENTARY MATERIAL In Situ Spectroelectrochemical Investigations of Ru II Complexes with Bispyrazolyl Methane Triarylamine
Διαβάστε περισσότεραPatrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.
; doi:10.3390/molecules22020254 S1 of S23 Supplementary Materials: Reaction of 3-Amino-1,2,4-Triazole with Diethyl Phosphite and Triethyl Orthoformate: Acid-Base Properties and Antiosteoporotic Activities
Διαβάστε περισσότεραIodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via
Διαβάστε περισσότεραSupporting Information. Asymmetric Binary-acid Catalysis with Chiral. Phosphoric Acid and MgF 2 : Catalytic
Supporting Information Asymmetric Binary-acid Catalysis with Chiral Phosphoric Acid and MgF 2 : Catalytic Enantioselective Friedel-Crafts Reactions of β,γ- Unsaturated-α-Ketoesters Jian Lv, Xin Li, Long
Διαβάστε περισσότεραEngineering Tunable Single and Dual Optical. Emission from Ru(II)-Polypyridyl Complexes. Through Excited State Design
Engineering Tunable Single and Dual Optical Emission from Ru(II)-Polypyridyl Complexes Through Excited State Design Supplementary Information Julia Romanova 1, Yousif Sadik 1, M. R. Ranga Prabhath 1,,
Διαβάστε περισσότεραSupporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-
Supporting Information for A catalyst-free multicomponent domino sequence for the diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- (arylamino)allyl]chromen-4-ones Pitchaimani Prasanna 1, Pethaiah
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information Palladium
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information Cucurbit[7]uril host-guest complexes of the histamine H 2 -receptor antagonist ranitidine Ruibing Wang and Donal H. Macartney* Department of Chemistry, Queen s University,
Διαβάστε περισσότεραAn experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH 3 NH 2, (CH 3 ) 2 NH, and (CH 3 ) 3 N
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 An experimental and theoretical study of the gas phase kinetics of atomic chlorine
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2017 Modular Synthesis of Propargylamine Modified Cyclodextrins by a Gold(III)-catalyzed Three Component
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Sequentially palladium catalyzed coupling-cyclocondensation-coupling
Διαβάστε περισσότεραParts Manual. Wide Transport Stretcher Model 738
Wide Transport Stretcher Model 738 Modèle 738 De Civière Large Pour Le Transport Breites Transport-Bahre-Modell 738 Breed Model 738 van de Brancard van het Vervoer Modello Largo 738 Della Barella Di Trasporto
Διαβάστε περισσότεραZebra reaction or the recipe for heterodimeric zinc complexes synthesis
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 05 Supporting Information Zebra reaction or the recipe for heterodimeric zinc complexes synthesis
Διαβάστε περισσότεραSupporting Information for Substituent Effects on the Properties of Borafluorenes
Supporting Information for Substituent Effects on the Properties of Borafluorenes Mallory F. Smith, S. Joel Cassidy, Ian A. Adams, Monica Vasiliu, Deidra L. Gerlach, David Dixon*, Paul A. Rupar* Department
Διαβάστε περισσότερα... 5 A.. RS-232C ( ) RS-232C ( ) RS-232C-LK & RS-232C-MK RS-232C-JK & RS-232C-KK
RS-3C WIWM050 014.1.9 P1 :8... 1... 014.0.1 1 A... 014.0. 1... RS-3C()...01.08.03 A.. RS-3C()...01.08.03 3... RS-3C()... 003.11.5 4... RS-3C ()... 00.10.01 5... RS-3C().008.07.16 5 A.. RS-3C().0 1.08.
Διαβάστε περισσότεραSupporting Information For: Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes
Supporting Information For: Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes Xiao-Hui Yang and Vy M. Dong* dongv@uci.edu Department of Chemistry, University
Διαβάστε περισσότεραComparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity
Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity Jian-Long Li 1,a, Wei Zhao 1,a, Chen Zhou 1,a, Ya-Xuan
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for rganic Chemistry Frontiers. This journal is the Partner rganisations 2018 Palladium-catalyzed direct approach to α-cf 3 aryl ketones from arylboronic acids Bo
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Polymer hemistry This journal is The Royal Society of hemistry 2011 Phosphoric and Phosphoramidic Acids as Bifunctional atalysts for the Ring-pening Polymerization
Διαβάστε περισσότεραSupporting Information. Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles
Supporting Information for Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles Angélica de Fátima S. Barreto*, Veronica Alves dos Santos, and Carlos
Διαβάστε περισσότεραSupporting Information for. Department of Chemistry, Vanderbilt University, Nashville, TN 37235
Supporting Information for Functional Group Transformations in Derivatives of 1,4-Dihydrobenzo[1,2,4]triazinyl Radical Agnieszka Bodzioch, a, Minyan Zheng, a Piotr Kaszyński, a,b * Greta Utecht a a Organic
Διαβάστε περισσότεραRh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A. new Entry to N-Carbamate Protected Arylamines
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A new Entry to N-Carbamate Protected Arylamines Bing Zhou,* Juanjuan Du, Yaxi Yang,* Huijin Feng, Yuanchao Li Shanghai Institute of Materia Medica,
Διαβάστε περισσότεραButadiene as a Ligand in Open Sandwich Compounds
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2018 Butadiene as a Ligand in Open Sandwich Compounds Qunchao Fan, a Jia Fu, a Huidong
Διαβάστε περισσότερα