Stereochemistry and mechanistic insight in the [2 k +2 i +2 i ] annulations of ketenes and imines
|
|
|
- Κλεισθένης Καλάρης
- 5 χρόνια πριν
- Προβολές:
Transcript
1 Stereochemistry and mechanistic insight in the [2 k +2 i +2 i ] annulations of ketenes and imines Zhanhui Yang, Wei He, Baoxiang Cheng and Jiaxi Xu* State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing , P. R. China, Tel./ fax: ; e mail: jxxu@mail.buct.edu.cn Contents 1. X ray crystal structure analysis... S H and 13 C NMR spectra of the [2 k +2 i +2 i ] products.... S9 1 H and 13 C NMR spectra of the [2 k +2 i ] products... S24 4. NOE spectra of the formal [2 k +2 i +2 i ] products (600 MHz).... S28 5. Computed energies of all stationary points... S42 6. Coordinates of all stationary points... S43 S1
2 1. X ray crystal structure analysis Fig S1. X Ray crystal structure of compound 4m (50% probability) side view Fig S2. X Ray crystal structure of compound 4m (50% probability) vertical view S2
3 Table 1: Crystal data and structure refinement for 4m Identification code exp_2697 Empirical formula C 21 H 19 N 3 O Formula weight Temperature / K 97.6 Crystal system monoclinic Space group P2 1 /n a / Å, b / Å, c / Å (10), (5), (14) α/, β/, γ/ 90.00, (10), Volume / Å (2) Z 4 ρ calc / mg mm μ / mm F(000) 696 Crystal size / mm Θ range for data collection 6 to 52 Index ranges -14 h 14, -10 k 6, -12 l 21 Reflections collected 7880 Independent reflections 3223[R(int) = (inf-0.9å)] Data/restraints/parameters 3223/0/226 Goodness-of-fit on F Final R indexes [I>2σ (I) i.e. F o >4σ (F o )] R 1 = , wr 2 = Final R indexes [all data] R 1 = , wr 2 = Largest diff. peak/hole / e Å / Flack Parameters N Completeness Table 2. Fractional Atomic Coordinates ( 10 4 ) and Equivalent Isotropic Displacement Parameters (Å ) for 4m. U eq is defined as 1/3 of of the trace of the orthogonalised U IJ tensor. Atom x y z U(eq) O (10) (13) 153.2(8) 29.4(3) N (11) (14) (8) 17.1(3) N (12) (15) (9) 23.4(3) C (14) (18) (11) 21.7(4) C (14) (18) -498(1) 20.2(4) C (14) (17) (11) 20.3(4) C (14) (17) (10) 19.1(4) C (14) (18) (10) 19.1(4) C (14) (17) (10) 17.3(4) S3
4 C (15) 457.1(18) (10) 21.9(4) C (15) (18) (11) 21.4(4) C (14) (18) 326.2(11) 22.3(4) C (14) (17) (10) 17.8(4) C (17) 2846(2) (12) 29.8(4) C (15) (18) (11) 24.0(4) C (15) (18) (11) 24.4(4) C (15) (18) (12) 25.5(4) C (15) (18) (11) 23.0(4) C (17) 1195(2) (12) 29.6(4) N (13) (17) 958.4(10) 31.5(4) C (15) 2991(2) (12) 31.2(4) C (15) 317.7(18) (11) 24.2(4) C (14) (17) (10) 19.8(4) C (16) 3708(2) (12) 31.2(5) C (17) 2049(2) (12) 32.0(5) Table 3 Anisotropic Displacement Parameters (Å ) for 4m. The Anisotropic displacement factor exponent takes the form: -2π 2 [h 2 a* 2 U hka b U 12 ] Atom U 11 U 22 U 33 U 23 U 13 U 12 O 25.3(7) 29.8(7) 30.1(7) -9.0(6) 3.8(6) -2.0(5) N2 18.7(7) 16.4(7) 18.8(7) 1.6(5) 9.6(6) 0.8(5) N3 18.1(7) 26.2(7) 27.8(8) -5.0(6) 9.6(7) -2.9(6) C7 21.8(9) 21.4(8) 22.7(9) 3.0(7) 7.7(8) 3.8(7) C2 22.6(9) 19.5(8) 19.2(9) -1.1(7) 7.2(7) 1.8(7) C (9) 16.0(8) 26.6(9) 3.4(7) 14.0(8) 4.8(7) C6 22.0(9) 15.2(8) 21.6(9) -3.2(7) 9.0(7) -0.6(7) C (9) 16.7(8) 23.6(9) -1.8(7) 8.9(7) -0.9(6) C5 20.8(9) 14.7(8) 17.7(9) -4.1(6) 7.8(7) -1.6(6) C9 28.4(9) 21.0(9) 17.9(9) -1.4(7) 9.3(8) -0.2(7) C1 22.4(9) 15.2(8) 25(1) -1.9(7) 4.7(8) 1.4(7) C3 20.2(9) 22.9(9) 22.6(10) -1.8(7) 4.6(8) 2.1(7) C4 20.9(9) 14.5(8) 18.9(9) 1.9(7) 7.4(7) 1.5(6) C (10) 23.5(9) 43.1(12) 9.2(9) 24.4(10) 6.0(8) C (10) 22.5(9) 26.5(10) 0.5(7) 15.2(8) 2.0(7) C (9) 24.7(9) 32.6(11) -7.5(8) 13.3(8) -3.5(7) C (10) 18.2(8) 36.3(11) 5.3(8) 16.3(9) 5.1(7) C (9) 20.5(9) 26.1(10) -2.5(7) 7.5(8) 1.9(7) C (11) 29(1) 27.1(10) 1.2(8) 15.2(9) 6.7(8) N (9) 38.9(9) 23.3(9) 0.1(7) 7.5(7) 1.7(7) S4
5 C (9) 37.7(11) 37.2(12) -7.3(9) 9.1(9) -3.9(8) C (10) 23.1(9) 25.7(10) -2.8(7) 18.2(8) -4.8(7) C8 23.3(9) 17.8(8) 20.3(9) 2.2(7) 9.7(7) 1.0(7) C (10) 28.1(10) 45.0(12) 1.1(9) 16.2(9) -3.9(8) C (12) 29.8(10) 31.9(11) 9.7(9) 24.7(10) 12.4(9) Table 4 Bond Lengths for 4m. Atom Atom Length/ Å Atom Atom Length/Å O C (2) C6 C (2) N2 C (19) C6 C (2) N2 C (19) C5 C (2) N2 C (19) C5 C (2) N3 C (2) C9 C (2) N3 C (2) C3 N (2) N3 C (2) C21 C (2) C7 C (2) C21 C (3) C7 C (2) C18 C (2) C2 C (2) C11 C (2) C2 C (2) C11 C (2) C2 C (2) C15 C (3) C14 C (2) C19 C (3) C14 C (2) C17 C (3) C14 C (2) Table 5 Bond Angles for 4m. Atom Atom Atom Angle/ Atom Atom Atom Angle/ C13 N2 C (13) C10 C9 C (16) C13 N2 C (12) O C1 N (15) C4 N2 C (12) O C1 C (15) C1 N3 C (13) N3 C1 C (14) C1 N3 C (14) N20 C3 C (18) C17 N3 C (13) N2 C4 C (12) C6 C7 C (14) N2 C4 C (13) C1 C2 C (13) C5 C4 C (12) C3 C2 C (14) C20 C21 C (16) C3 C2 C (13) C19 C18 C (16) C18 C14 C (14) C10 C11 C (16) C18 C14 C (16) C14 C15 C (17) C15 C14 C (16) C14 C15 C (16) C5 C6 C (14) C21 C15 C (15) S5
6 C5 C6 C (15) C11 C12 C (16) C12 C6 C (15) C20 C19 C (18) N2 C13 N (12) N3 C17 C (15) N2 C13 C (14) C9 C10 C (16) N3 C13 C (13) N2 C8 C (12) C6 C5 C (15) C15 C16 C (14) C6 C5 C (14) C21 C20 C (17) C9 C5 C (15) Table 6 Torsion Angles for 4m. A B C D Angle/ N3 C17 C16 C (19) C7 C6 C5 C (14) C7 C6 C5 C4 4.1(2) C7 C6 C12 C (15) C14 C18 C19 C20 1.1(2) C14 C15 C16 C (2) C6 C7 C8 N (18) C6 C5 C9 C10-1.9(2) C6 C5 C4 N (19) C6 C5 C4 C (17) C13 N2 C4 C (15) C13 N2 C4 C (12) C13 N2 C8 C (13) C13 N3 C1 O (15) C13 N3 C1 C2-17.9(2) C13 N3 C17 C (18) C13 C14 C18 C (15) C13 C14 C15 C (14) C13 C14 C15 C16-5.1(2) C5 C6 C12 C11-1.2(2) C5 C9 C10 C11 0.0(2) C9 C5 C4 N (13) C9 C5 C4 C (17) C1 N3 C13 N2 33.2(2) C1 N3 C13 C (14) C1 N3 C17 C (16) C1 C2 C3 N20-133(3) C1 C2 C4 N (17) C1 C2 C4 C (13) S6
7 C3 C2 C1 O -32.1(2) C3 C2 C1 N (14) C3 C2 C4 N (13) C3 C2 C4 C (17) C4 N2 C13 N (16) C4 N2 C13 C (12) C4 N2 C8 C (16) C4 C2 C1 O (14) C4 C2 C1 N (19) C4 C2 C3 N20-6(3) C4 C5 C9 C (14) C21 C15 C16 C (16) C18 C14 C13 N (18) C18 C14 C13 N (13) C18 C14 C15 C21-1.1(2) C18 C14 C15 C (15) C18 C19 C20 C21-1.4(3) C15 C14 C13 N (15) C15 C14 C13 N3 10.8(2) C15 C14 C18 C19 0.1(2) C15 C21 C20 C19 0.4(3) C12 C6 C5 C9 2.5(2) C12 C6 C5 C (14) C12 C11 C10 C9 1.2(2) C17 N3 C13 N (13) C17 N3 C13 C (18) C17 N3 C1 O 7.0(2) C17 N3 C1 C (14) C10 C11 C12 C6-0.6(2) C8 N2 C13 N (17) C8 N2 C13 C (17) C8 N2 C4 C (16) C8 N2 C4 C (16) C8 C7 C6 C5-14.1(2) C8 C7 C6 C (13) C20 C21 C15 C14 0.8(2) C20 C21 C15 C (16) S7
8 Table 7 Hydrogen Atom Coordinates (Å 10 4 ) and Isotropic Displacement Parameters (Å ) for 4m. Atom x y z U(eq) H7A H7B H H H H H H H H H H17A H17B H H8A H8B H16A H16B H Experimental Single crystals of C 21 H 19 N 3 O [4m] were recrystallized from [acetone] mounted in inert oil and transferred to the cold gas stream of the diffractometer. Crystal structure determination of [4m] Crystal Data. C 21 H 19 N 3 O, M =329.39, monoclinic, a = (10) Å, b = (5) Å, c = (14) Å, β = (10), U = (2) Å 3, T = 97.6, space group P2 1 /n (no. 14), Z = 4, μ(mo Kα) = 0.084, 7880 reflections measured, 3223 unique (R int = ) which were used in all calculations. The final wr(f 2 ) was (all data). S8
9 2. 1 H and 13 C NMR spectra of the [2 k +2 i +2 i ] products. Benzyl ((rel(4bs,5s,13br) 6 oxo 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquinoli n 5 yl)methyl)carbamate (4a) S9
10 2 ((rel(4bs,5s,13br) 6 Oxo 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquino lin 5 yl)methyl)isoindoline 1,3 dione (4b) S10
11 (4b,5) cis (4b,13b) syn 5 ethoxy 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diiso quinolin 6 one (4c) S11
12 (4b,5) cis (4b,13b) syn 5 (benzyloxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a'] diisoquinolin 6 one (4e) S12
13 rel(4br,5r,13br) 5 (Phenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoqu inolin 6 one (4fb) S13
14 rel(4br,5s,13br) 5 (Phenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoqu inolin 6 one (4fa) S14
15 rel(4br,5r,13br) 5 (4 Nitrophenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a'] diisoquinolin 6 one (4gb) S15
16 rel(4br,5r,13bs) 5 (4 Nitrophenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a'] diisoquinolin 6 one (4gc) S16
17 rel(4bs,5r,13br) 5 (Phenyl) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquin olin 6 one (4h) S17
18 ethyl rel(4br,5s,13bs) 4b,5,9,13b,15,16 Hexahydro 6 oxo 6H,8H pyrimido[2,1 a:4,3 a']diisoquinolin e 5 carboxylate (4i) S18
19 rel(4br,5r,13bs) N Methyl 4b,5,9,13b,15,16 hexahydro 6 oxo 6H,8H pyrimido[2,1 a:4,3 a']diis oquinoline 5 carboxamide (4j) S19
20 rel(4br,5r,13bs) N Methyl N phenyl 4b,5,9,13b,15,16 hexahydro 6 oxo 6H,8H pyrimido[2,1 a: 4,3 a']diisoquinoline 5 carboxamide (4ka) S20
21 (4bR,5R,13bS) N methyl 6 oxo N phenyl 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquinoline 5 carboxamide (Two inseparable rotamers) Minor rotamer:4kc S21
22 (4bR,5R,13bS) N methyl 6 oxo N phenyl 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquinoline 5 carboxamide (Two inseparable rotamers) Major rotamer: 4kb S22
23 (4bR,5R,13bS) 6 oxo 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquinoline 5 carbonitrile (4m) S23
24 3. 1 H and 13 C NMR spectra of the [2 k +2 i ] products. trans 1 Ethoxy 1,4,5,9b tetrahydro 2H azeto[2,1 a]isoquinolin 2 one (5c) S24
25 trans-1-isopropoxy-1,4,5,9b-tetrahydro-2h-azeto[2,1-a]isoquinolin-2-one (5d) S25
26 trans 1 (benzyloxy) 1,4,5,9b tetrahydro 2H azeto[2,1 a]isoquinolin 2 one (5e) S26
27 trans 1 Phenoxy 1,4,5,9b tetrahydro 2H azeto[2,1 a]isoquinolin 2 one (5f) S27
28 4. NOE spectra of the formal [2 k +2 i +2 i ] products (600 MHz). Benzyl ((rel(4bs,5s,13br) 6 oxo 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquinoli n 5 yl)methyl)carbamate (4a) S28
29 2 ((rel(4bs,5s,13br) 6 Oxo 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquino lin 5 yl)methyl)isoindoline 1,3 dione (4b) S29
30 S30
31 rel(4br,5s,13br) 5 Ethoxy 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquino lin 6 one (4c) S31
32 rel(4br,5s,13br) 5 (Benzyloxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoq uinolin 6 one (4e) S32
33 rel(4br,5s,13br) 5 (Phenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoqu inolin 6 one (4fa) S33
34 rel(4br,5r,13br) 5 (Phenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoqu inolin 6 one (4fb) S34
35 rel(4br,5r,13br) 5 (4 Nitrophenoxy) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a'] diisoquinolin 6 one (4gb) S35
36 rel(4bs,5r,13br) 5 (Phenyl) 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a:4,3 a']diisoquin olin 6 one (4h) S36
37 ethyl rel(4br,5s,13bs) 4b,5,9,13b,15,16 Hexahydro 6 oxo 6H,8H pyrimido[2,1 a:4,3 a']diisoquinolin e 5 carboxylate (4i) S37
38 rel(4br,5r,13bs) N Methyl 4b,5,9,13b,15,16 hexahydro 6 oxo 6H,8H pyrimido[2,1 a:4,3 a']diis oquinoline 5 carboxamide (4j) S38
39 rel(4br,5r,13bs) N Methyl N phenyl 4b,5,9,13b,15,16 hexahydro 6 oxo 6H,8H pyrimido[2,1 a: 4,3 a']diisoquinoline 5 carboxamide (4ka) S39
40 rel(4br,5r,13bs) N Methyl 6 oxo N phenyl 4b,5,9,13b,15,16 hexahydro 6H,8H pyrimido[2,1 a: 4,3 a']diisoquinoline 5 carboxamide (Two inseparable rotamers) S40
41 rel(4br,5r,13bs) 4b,5,9,13b,15,16 Hexahydro 6 oxo 6H,8H pyrimido[2,1 a:4,3 a']diisoquinolin e 5 carbonitrile (4m) S41
42 5. Computed energies of all stationary points m06 2x gd3/ g(d,p) b3lyp gd3/6 3 1g(d) PhO(smd,CH 2 Cl 2 ) E TCGqhc G/(kcal/mol) ΔG sol /(kcal/ mol) intermediate 6f imine 1a sum of 6f and 1a exo TS2 f endo TS1 f endo 4fa exo 4fa NO 2 PhO (smd,ch 2 Cl 2 ) intermediate 6g imine 1a sum of 6g and 1a exo TS2 g endo TS1 g endo 4gc exo 4gc Ph endo (2,4) cis (4,5) cis 4 h epi endo (2,4) cis (4,5) t rans 4h S42
43 6. Coordinates of all stationary points endo product: (2,4) cis (4,5) cis 4h O N C H C C H C C H C H C C H C H N C H C C C H C H C S43
44 H C H C H H C H H C H H C H H C C C C H C H C H H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S44
45 epi endo product: (2,4) cis (4,5) trans 4h O N C C C C C C C C C N C C C C C C C C C C C C C C S45
46 C C C H H H H H H H H H H H H H H H H H H H H H H H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S46
47 Imine 1a: N C H C C C H C H C H C H C H H C H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S47
48 Intermediate 6f: C C N C O O C C C C C C C C C C C C C C H H H S48
49 H H H H H H H H H H H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S49
50 endo TS1 f: O N C H C C H C C H C H C C H C H N C H C C C S50
51 H C H C H C H C H H C H H C H O C C C C H C H C H H H H C H H imaginary frequencies: 217 cm** 1 SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S51
52 exo TS2 f: O N C H C C H C C H C H C C H C H C H N C H C S52
53 C C H C H C H C H C H H C H H C H H H O C C C C H C H C H H H imaginary frequencies: 274 cm** 1 SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S53
54 endo product (2,4) cis (4,5) cis 4fa: O N C H C C H C C H C H C C H C H N C H C C C S54
55 H C H C H C H C H H C H H C H O C C C C H C H C H H H H C H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S55
56 exo product (2,4) trans (4,5) trans 4fa: O N C H C C H C C H C H C C H C H C H N C H C S56
57 C C H C H C H C H C H H C H H C H H H O C C C C H C H C H H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S57
58 Imine 1a: N C H C C C H C H C H C H C H H C H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S58
59 6g: C C N C O O H C C C C C C C C H C C C C C C N S59
60 O O H H H H H H H H H H H H SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S60
61 endo TS1 g: O N C C C C C C C C C N C C C C C C C C C C O S61
62 C C C C C C C H H H H H H H H H H H H H H H H H H H H H H H N O O imaginary frequencies: 267 cm** 1 SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S62
63 exo TS2 g: O N C H C C H C C H C H C C H C H C H N C H C S63
64 C C H C H C H C H C H H C H H C H H H O C C C C H C H C H H N O O imaginary frequencies: 304 cm** 1 SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S64
65 endo product (2,4) cis (4,5) cis 4gc: O N C H C C H C C H C H C C H C H N C H C C C S65
66 H C H C H C H C H H C H H C H O C C C C H C H C H H H C H H N O O SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S66
67 exo product (2,4) trans (4,5) trans 4gc: O N C H C C H C C H C H C C H C H C H N C H C S67
68 C C H C H C H C H C H H C H H C H H H O C C C C H C H C H H N O O SCF Done: hartree zero point correction: hartree quasiharmonic free energy correction: hartree S68
Supporting Information
Supporting Information Vinylogous elimination/heck coupling/allylation domino reactions: access to 2- substituted 2,3-dihydrobenzofurans and indolines Jianguo Yang, *, Hanjie Mo, Xiuxiu Jin, Dongdong Cao,
Supporting Information
One-Pot, Three-Component Assembly of Indoloquinolines: Total Synthesis of Isocryptolepine Alexander V. Aksenov,* Dmitrii A. Aksenov, Naila A. Orazova, Nicolai A. Aksenov, Georgii D. Griaznov, Annelise
Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles
![Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles](/thumbs/89/100111450.jpg "Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles")
X-Ray crystallographic data tables for paper: Supplementary Material (ESI) for Organic & Biomolecular Chemistry Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically
IV. ANHANG 179. Anhang 178
Anhang 178 IV. ANHANG 179 1. Röntgenstrukturanalysen (Tabellen) 179 1.1. Diastereomer A (Diplomarbeit) 179 1.2. Diastereomer B (Diplomarbeit) 186 1.3. Aldoladdukt 5A 193 1.4. Aldoladdukt 13A 200 1.5. Aldoladdukt
Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid
Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid Taotao Ling, a Chinmay Chowdhury, a Bryan A. Kramer, a Binh G. Vong, a Michael A. Palladino b and Emmanuel A. Theodorakis a
Electronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Cyclopentadienyl iron dicarbonyl (CpFe(CO) 2 ) derivatives
Supporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory
Supporting Information Dysiherbols A C and Dysideanone E, Cytotoxic and NF-κB Inhibitory Tetracyclic Meroterpenes from a Dysidea sp. Marine Sponge Wei-Hua Jiao,, Guo-Hua Shi,, Ting-Ting Xu,, Guo-Dong Chen,
Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings
ickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings Braulio M. Puerta Lombardi, Rudy M. Braun, Chris Gendy, Chia Yun Chang,
Electronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) CPh 3 as a functional group in P-heterocyclic
Patrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.
; doi:10.3390/molecules22020254 S1 of S23 Supplementary Materials: Reaction of 3-Amino-1,2,4-Triazole with Diethyl Phosphite and Triethyl Orthoformate: Acid-Base Properties and Antiosteoporotic Activities
chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX
σ-donor/acceptor confused ligands: The case of a chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX 77843-3255. *To whom correspondence
Enantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Enantioselective Organocatalytic Michael Addition of Isorhodanines to α,
Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond
Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond Ken-ichi Yamashita, Kei-ichi Sato, Masaki Kawano and Makoto Fujita* Contents; Figure S1.
Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]
![Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]](/thumbs/92/109256432.jpg "Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]")
Supporting Information Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ] Eun Young Lee, Seung Yeon Jang, and Myunghyun Paik Suh* School of Chemistry,
Cobalt-Catalyzed Selective Synthesis of Isoquinolines Using Picolinamide as a Traceless Directing Group
Supporting Information Cobalt-Catalyzed Selective Synthesis of Isoquinolines Using Picolinamide as a Traceless Directing Group Changsheng Kuai, Lianhui Wang, Bobin Li, Zhenhui Yang, Xiuling Cui* Engineering
ANNEXE 2 : SPECTRES DE RÉSONANCE MAGNÉTIQUE NUCLÉAIRE
ANNEXE 2 : SPECTRES DE RÉSONANCE MAGNÉTIQUE NUCLÉAIRE 175 4-Oxopentyl acetate (1-9) 27.56 17.91 63.49 39.76 29.86 22.66 2.82 2. 1.97 2.91 2.96 2.9 4. 3.98 3.96 2.47 2.44 2.42 2.7 1.95 1.86 1.84 1.82 1.79
Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads for low-energy photosensitization
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads
Tunable Ligand Emission of Napthylsalophen Triple-Decker Dinuclear Lanthanide (III) Sandwich Complexes
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supplemental Information Tunable Ligand Emission of Napthylsalophen Triple-Decker Dinuclear
SUPPORTING INFORMATION. Pyramidanes: The Covalent Form of the Ionic Compounds
SUPPORTING INFORMATION Pyramidanes: The Covalent Form of the Ionic Compounds Vladimir Ya. Lee, 1 * Olga A. Gapurenko, 2 Yuki Ito, 1 Takahiko Meguro, 1 Haruka Sugasawa, 1 Akira Sekiguchi, 1 *, Ruslan M.
Synthesis, Characterization, and Computational Study of Three-Coordinate SNS-Copper(I) Complexes Based on Bis-Thione Precursors
For Synthesis, Characterization, and Computational Study of Three-Coordinate SNS-Copper(I) Complexes Based on Bis-Thione Precursors John R. Miecznikowski a *; Matthew A. Lynn b ; Jerry P. Jasinski c ;
Supporting Information
Supporting Information for Pyrene nucleobase conjugates: synthesis, oligonucleotide binding and confocal bioimaging studies Artur Jabłoński 1, Yannic Fritz 2, Hans-Achim Wagenknecht 2, Rafał Czerwieniec
Supplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3
Supplementary Information Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3 Lewis Pairs: Structures of Intermediates, Kinetics, and Mechanism Qianyi Wang, Wuchao Zhao,
Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes
![Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes](/thumbs/92/108867714.jpg "Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes")
SUPPORTING INFORMATION Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes Eric J. Uzelac, Casey B. McCausland, and Seth C. Rasmussen*
Table S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.
Supporting Information [NH 3 CH 3 ] [In SbS 9 SH]: A novel methylamine-directed indium thioantimonate with Rb + ion-exchange property Kai-Yao Wang a,b, Mei-Ling Feng a, Jian-Rong Li a and Xiao-Ying Huang
C H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged
Supporting Information C H Activation of Cp* Ligand Coordinated to Ruthenium Center: Synthesis and Reactivity of a Thiolate-Bridged Diruthenium Complex Featuring Fulvene-like Cp* Ligand Xiaoxiao Ji, Dawei
Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes
Supplementary information Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes Marcos A. P. Martins 1 *, Alexandre R. Meyer 1, Paulo R. S. Salbego
Supporting Information. Palladium Complexes with Bulky Diphosphine. Synthesis of (Bio-) Adipic Acid from Pentenoic. Acid Mixtures.
Supporting Information Palladium Complexes with Bulky Diphosphine Ligands as Highly Selective Catalysts for the Synthesis of (Bio-) Adipic Acid from Pentenoic Acid Mixtures. Choon Heng Low, James D. Nobbs,*
NH-Type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications
Supporting Information NH-Type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications Mackenzie Bergagnini, a Kazunobu Fukushi, b Jianlin
Supplementary Material
Supplementary Material Synthesis of bis-oxathiaaza[3.3.3]propellanes via nucleophilic addition of (1,ω-alkanediyl)bis(N'-organylthioureas) on dicyanomethylene-1,3-indanedione Alaa A. Hassan, a * Kamal
Table of Contents 1 Supplementary Data MCD
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information for Magnetic circular dichroism and density functional theory
College of Life Science, Dalian Nationalities University, Dalian , PR China.
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 Postsynthetic modification
SUPPORTING INFORMATION. Diastereoselective synthesis of nitroso acetals from (S,E)- -aminated
SUPPORTING INFORMATION for Diastereoselective synthesis of nitroso acetals from (S,E)- -aminated nitroalkenes via multicomponent [4 + 2]/[3 + 2] cycloadditions promoted by LiCl or LiClO 4 Leandro Lara
Supporting information for
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting information for Palladium-Catalyzed Benzothieno[2,3-b]indole Formation via Dehydrative-Dehydrogenative
Zebra reaction or the recipe for heterodimeric zinc complexes synthesis
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 05 Supporting Information Zebra reaction or the recipe for heterodimeric zinc complexes synthesis
Four- and Five-membered Cobaltacycles by Regioselective Cyclometalation. of Benzylsulfide Derivatives via Co(V) intermediates
Electronic Supplementary Information for Dalton Transactions This journal is The Royal Society of Chemistry 2008 Supporting Information for: Four- and Five-membered Cobaltacycles by Regioselective Cyclometalation
Supporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Abnormal N-Heterocyclic Carbene Based Nickel Complex for Catalytic
Fused Bis-Benzothiadiazoles as Electron Acceptors
Fused Bis-Benzothiadiazoles as Electron Acceptors Debin Xia, a,b Xiao-Ye Wang, b Xin Guo, c Martin Baumgarten,*,b Mengmeng Li, b and Klaus Müllen*,b a MIIT Key Laboratory of ritical Materials Technology
SUPPLEMENTARY MATERIAL. A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine Hybrids
10.1071/CH17272_AC CSIRO 2017 Australian Journal of Chemistry 2017, 70(12), 1285-1290 SUPPLEMENTARY MATERIAL A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine
Supporting Information
Supporting Information 1,3,5-Triazapentadienes by Nucleophilic Addition to 1,3- and 1,4-Dinitriles - Sterically Constrained Examples by Incorporation into Cyclic Peripheries: Synthesis, Aggregation and
Supporting Information
Supporting Information rigin of the Regio- and Stereoselectivity of Allylic Substitution of rganocopper Reagents Naohiko Yoshikai, Song-Lin Zhang, and Eiichi Nakamura* Department of Chemistry, The University
Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative
Bloco A, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ, Brazil. Contents Pages
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information Copper(II) Catalyzed Synthesis of Novel Helical
Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting information An unusual bifunctional Tb-MOF for highly sensing
Supporting Information File 2. Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ;
Supporting Information File 2 Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ; Preparation, structures and host guest chemistry of fluorinated syn-bisquinoxaline molecular tweezers
Supporting Information
Supporting Information Chloroyttrium 2-(1-(arylimino)alkyl)quinolin-8-olate Complexes: Synthesis, Characterization, and Catalysis of the Ring-Opening Polymerization (ROP) of ε- Caprolactone (ε-cl) Wenjuan
Supplementary information
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary information Hybrids of acylated homoserine lactone and nitric
Supporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds
Supporting Information for Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds Zhongxue Fang, a Yongquan Ning, a Pengbing Mi, a Peiqiu Liao, a Xihe Bi* a,b a Department of Chemistry,
Practical Pd(II)-catalyzed C H Alkylation with Epoxides: One-step Syntheses of 3,4-Dihydroisocoumarins
Practical Pd(II)-catalyzed C H Alkylation with Epoxides: One-step Syntheses of 3,4-Dihydroisocoumarins Guolin Cheng, Tuan-Jie Li, and Jin-Quan Yu* Department of Chemistry, The Scripps Research Institute,
Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate
Synthesis and effects of oxadiazole derivatives on tyrosinase activity and SK-MEL-28 malignant melanoma cells
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 06 Synthesis and effects of oxadiazole derivatives on tyrosinase activity and human SK-MEL-8 malignant
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 [1,2-Bis(1H-benzimidazol-2-yl-jN 3 )- ethane]dichloridozinc(ii) Yan-Ling Zhou, a Ming-Hua Zeng a and Seik
Supporting Information. Generation Response. Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi , China. China , USA
Supporting Information Pb 3 B 6 O 11 F 2 : A First Noncentrocentric Lead Fluoroborate with Large Second Harmonic Generation Response Hongyi Li, a Hongping Wu, a * Xin Su, a Hongwei Yu, a,b Shilie Pan,
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships. or W, and D = P or V)
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A 3 B 3 CD 2 O 14 Family (A = Sr, Ba or Pb; B = Mg or Zn; C = Te or W, and D = P or V) Hongwei Yu, Joshua Young,
Supporting Information for Substituent Effects on the Properties of Borafluorenes
Supporting Information for Substituent Effects on the Properties of Borafluorenes Mallory F. Smith, S. Joel Cassidy, Ian A. Adams, Monica Vasiliu, Deidra L. Gerlach, David Dixon*, Paul A. Rupar* Department
Experimental. Crystal data
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Terephthalic acid 2,2 0 -dimethyl-1,1 0 - (butane-1,4-diyl)dibenzimidazole (2/3) Hui Jiang and Xian-Wu Dong* Department
Supplementary Material
Supplementary Material Efficient, mild synthesis of - unsubstituted 1,2,3- triazoles from methanolysis of 1-sulfonyl-1,2,3-triazoles Janeth Rodríguez-Florencio, Diego Martínez-tero, Marco A. García-Eleno,
Supporting Information-B. A Facile Iterative Synthesis of 2,5-Terpyrimidinylenes as Non-peptidic α-helical Mimics
Supporting Information-B A Facile Iterative Synthesis of 2,5-Terpyrimidinylenes as on-peptidic α-helical Mimics Laura Anderson, 1,2 Mingzhou Zhou, 1,2 Vasudha Sharma, 2 Jillian M. McLaughlin, 2 Daniel.
An experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH 3 NH 2, (CH 3 ) 2 NH, and (CH 3 ) 3 N
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 An experimental and theoretical study of the gas phase kinetics of atomic chlorine
Triclinic, P1 a = (2) Å b = (3) Å c = (4) Å = (1) = (1) = (1) Data collection.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Benzyl N 0 -(4,6-dimethoxy-2-methyl-3- phenyl-1h-indol-7-ylmethylene)- hydrazinecarbodithioate Hamid Khaldei,
Combined Spectroscopic and Quantum Chemical Study of [trans-ru(c CC 6 H 4 R 1 -
Combined Spectroscopic and Quantum Chemical Study of [trans-ru(c CC 6 H 4 R 1-4) 2 (dppe) 2 ] n+ and [trans-ru(c CC 6 H 4 R 1-4)(C CC 6 H 4 R 2-4)(dppe) 2 ] n+ (n = 0, 1) Complexes: Interpretations Beyond
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Domino reaction of cyclic sulfamidate imines with
Palladium-Catalyzed Direct ortho-sulfonylation of. Azobenzenes with Arylsulfonyl Chlorides via C H. Table of Contents
Electronic upplementary Material (EI) for RC Advances. This journal is The Royal ociety of Chemistry 205 upporting Information Palladium-Catalyzed Direct ortho-ulfonylation of Azobenzenes with Arylsulfonyl
Supporting Information
Supporting Information Gold-catalyzed Cycloisomerization of 1,6-Diyne-4-en-3-ols to form Naphthyl Ketone Derivatives. Jian-Jou Lian and Rai-Shung Liu* Department of Chemistry, National Tsing-Hua University,
of the methanol-dimethylamine complex
Electronic Supplementary Information for: Fundamental and overtone virational spectroscopy, enthalpy of hydrogen ond formation and equilirium constant determination of the methanol-dimethylamine complex
Supporting Information
Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General
Supporting Information
SUPPORTING INFORMATION FOR: Trialkylstibine complexes of boron, aluminium, gallium and indium trihalides: synthesis, properties and bonding Victoria K. Greenacre, William Levason and Gillian Reid Chemistry,
Supplementary Information for
Supplentary Information for Aggregation induced blue-shifted ission molecular picture from QM/MM study Qunyan Wu, a Tian Zhang, a Qian Peng,* b Dong Wang, a and Zhigang Shuai* a a Key Loratory of Organic
Supporting Information for
Supporting Information for An atom-economic route to densely functionalized thiophenes via base-catalyzed rearrangement of 5-propargyl-2H-thiopyran-4(3H)-ones Chunlin Tang a, Jian Qin b, Xingqi Li *a a
Electronic Supplementary Information:
Electronic Supplementary Information: 2 6 5 7 2 N S 3 9 6 7 5 2 S N 3 9 Scheme S. Atom numbering for thione and thiol tautomers of thioacetamide 3 0.6 0. absorbance 0.2 0.0 0.5 0.0 0.05 0.00 N 2 Ar km/mol
Synthesis and Biological Evaluation of Novel Acyclic and Cyclic Glyoxamide derivatives as Bacterial Quorum Sensing and Biofilm Inhibitors
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Synthesis and Biological Evaluation of Novel Acyclic and Cyclic Glyoxamide
Title N-H versus C-H Activation of a Pyrrole Imine at {Cp*Ir}: A Computational and Experimental Study
Supporting Information for: Title N-H versus C-H Activation of a Pyrrole Imine at {Cp*Ir}: A Computational and Experimental Study David L. Davies,* a Steven M. A. Donald, b Omar Al-Duaij, a John Fawcett,
Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2016 KPb 2 (PO 3 ) 5 : A Novel Nonlinear Optical Lead Polyphosphate with Short
Synthetic Control of Excited States in Cyclometalated Ir(III) Complexes using Ancillary Ligands
Synthetic Control of Excited States in Cyclometalated Ir(III) Complexes using Ancillary Ligands Jian Li, (a) Peter I. Djurovich, (a) Bert D. Alleyne, (a) Muhammed Yousufuddin, (a) Nam N. Ho, (a) J. Christopher
Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of. 1,2,3-Triazole Synthesis
Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of α-diazoketones with Various Amines: A Strategy for Catalytic Wolff 1,2,3-Triazole Synthesis Zikun Wang, a Xihe
Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008
Supporting Information Copyright Wiley-VC Verlag Gmb & Co. KGaA, 69451 Weinheim, 2008 Copper Complexes of Mono- and Ditopic [(Methylthio)methyl]borates: Missing Links and Linked Systems En Route to Copper
difluoroboranyls derived from amides carrying donor group Supporting Information
The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group Supporting Information Anna Maria Grabarz a Adèle D. Laurent b, Beata Jędrzejewska
Experimental. Crystal data. C 23 H 27 ClN 2 O M r = Triclinic, P1 a = (3) Å b = (6) Å c = (7) Å = (4) = 80.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 8-{(E)-[(4-Chlorophenyl)imino]methyl}- 1,1,7,7-tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-9-ol
Synthesis of New Heteroscorpionate Iridium(I) and Iridium(III) Complexes
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 ELECTRONIC SUPPORTING INFORMATION For Synthesis of New Heteroscorpionate Iridium(I)
The Free Internet Journal for Organic Chemistry
The Free Internet Journal for Organic Chemistry Paper Archive for Organic Chemistry Arkivoc 2018, part iii, S1-S6 Synthesis of dihydropyranones and dihydropyrano[2,3- d][1,3]dioxine-diones by cyclization
data reports 2-(4-Methylphenyl)-2-oxoethyl 3,4-dimethoxybenzoate Structure description Synthesis and crystallization Refinement
2-(4-Methylphenyl)-2-oxoethyl 3,4-dimethoxybenzoate ISSN 2414-3146 Shamantha Kumar, a Chandra, b B. M. Rajesh, c M. Mahendra b and B. H. Doreswamy a * Received 27 December 2016 Accepted 2 February 2017
Supporting Information. A Combined Crossed Molecular Beams and ab Initio Investigation on the Formation of Vinylsulfidoboron (C 2 H
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2014 Supporting Information for A Combined Crossed Molecular Beams and ab Initio Investigation
Supporting Information: Design principles for α-tocopherol analogues
Supplementary Material for Organic & Biomolecular Chemistry This journal is The Royal Society of Chemistry 2005 Supporting Information: Design principles for α-tocopherol analogues David Shanks,* a Håkan
Experimental. Crystal data. C 37 H 38 N 4 O 6 M r = Monoclinic, P2 1 a = (2) Å b = (7) Å c = (2) Å = 112.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Pheophorbide b ethyl ester from a chlorella vulgaris dietary supplement Experimental Crystal data C 37 H 38 N
Supporting Information
Supporting Information for AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds Qiuping Ding 1, Dan Wang 1, Puying Luo* 2, Meiling Liu 1, Shouzhi Pu* 3 and
Supporting Information One-Pot Approach to Chiral Chromenes via Enantioselective Organocatalytic Domino Oxa-Michael-Aldol Reaction
Supporting Information ne-pot Approach to Chiral Chromenes via Enantioselective rganocatalytic Domino xa-michael-aldol Reaction Hao Li, Jian Wang, Timiyin E-Nunu, Liansuo Zu, Wei Jiang, Shaohua Wei, *
Supporting Information
Supporting Information Molecular Cage Impregnated Palladium Nanoparticles: Efficient, Additive-Free Heterogeneous Catalysts for Cyanation of Aryl Halides. Bijnaneswar Mondal, Koushik Acharyya, Prodip Howlader
A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Controlling Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties
Supporting Information Controlling Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties Yusen Luo,,,# Chunqing Yuan,,# Jialiang Xu*, Yongjun Li*, Huibiao Liu, Sergey
E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations
E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations Nemanja Đorđević, Rakesh Ganguly, Milena Petković, and Dragoslav Vidović Email: drasko.vidovic@monash.edu
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Sequentially palladium catalyzed coupling-cyclocondensation-coupling
Electronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates
Electronic Supplementary Information DFT Characterization on the Mechanism of Water Splitting Catalyzed by Single-Ru-substituted Polyoxometalates Zhong-Ling Lang, Guo-Chun Yang, Na-Na Ma, Shi-Zheng Wen,
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Pentakis(2-oxo-2,3-dihydropyrimidin-1- ium) di-l 3 -chlorido-tri-l 2 -chlorido-hexachloridotricadmate(ii)
Supplementary Information
Supplementary Information Dieter Enders, Matthias R. M. Hüttl, Christoph Grondal & Gerhard Raabe Asymmetric rganocatalytic Domino Reactions. Control of Four Stereogenic Centres in a Triple Cascade Content:
Electronic Supplementary Information
Electronic Supplementary Information The preferred all-gauche conformations in 3-fluoro-1,2-propanediol Laize A. F. Andrade, a Josué M. Silla, a Claudimar J. Duarte, b Roberto Rittner, b Matheus P. Freitas*,a
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization
Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-
Supporting Information for A catalyst-free multicomponent domino sequence for the diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- (arylamino)allyl]chromen-4-ones Pitchaimani Prasanna 1, Pethaiah
Supporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2014 Supporting Information Heteroleptic Platinum(II) NHC Complexes with a C^C*
Electronic Supplementary Information
Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan
Manuscript submitted to the Journal of the American Society for Mass Spectrometry, September 2011.
The Early Life of a Peptide Cation-Radical. Ground and Excited-State Trajectories of Electron-Based Peptide Dissociations During the First 330 Femtoseconds Christopher L. Moss, Wenkel Liang, Xiaosong Li,*
Supporting Information for
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information for Catalytic Asymmetric Chemoselective 1,3-Dipolar Cycloadditions of Azomethine