Electronic Supporting Information. 3-Aminothiophenecarboxylic acid (3-Atc)-induced folding in peptides

Μέγεθος: px
Εμφάνιση ξεκινά από τη σελίδα:

Download "Electronic Supporting Information. 3-Aminothiophenecarboxylic acid (3-Atc)-induced folding in peptides"

Transcript

1 Electronic Supplementary Material (ESI for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information 3-Aminothiophenecarboxylic acid (3-Atc-induced folding in peptides Tukaram S. Ingole, a Amol S. Kotmale, b Rupesh L. Gawade, c Rajesh G. Gonnade, c Pattuparambil R. Rajamohanan b and Gangadhar J. Sanjayan *a Contents HRMS spectra of compounds S1 S2-S4 1 H NMR spectra of compounds S-S7 13 C and DEPT-13 spectra of compounds S8-S13 DMSO-d 6 titration of compounds of 2, 3, 1 Variable Temperature studies of compounds of 2, 3, 1 2D TOCSY, COSY, HSQC, HMBC and NOESY spectra of 2 2D COSY and NOESY spectra of 3 2D TOCSY, COSY, HSQC, HMBC and NOESY spectra of 1 X-ray crystallographic data of tripeptide 2 Molecular dynamics study of 1 CD spectra of Gly-3-Atc-Pro oligomers S14-S16 S17-S19 S20-S23 S23-S24 S2-S28 S29-S30 S31 S32 S1

2 HRMS 4a HRMS 2 S2

3 TUKA-4-TRINHME #884 RT: 3.94 AV: 1 NL: 1.14E9 T: FTMS + p ESI Full ms [ ] HRMS R=3707 C18 H26 O N4 Na S = Relative Abundance R=007 C18 H27 O N4 S = R= R= R=2707 C18 H26 O4 N4 Na S2 = R=400 C16 H22 O N6 Na S2 = m/z HRMS S3

4 TUKA-3-HEX-PRV #961 RT: 4.28 AV: 1 NL:.3E8 T: FTMS + p ESI Full ms [ ] Relative Abundance HRMS R=40207 C36 H43 O9 N6 S2 = R=40207 C36 H42 O9 N6 Na S2 = R= R= R=38807 R= R= R= m/z HRMS 1 S4

5 H NMR (400 MHz, CDCl 3 4a CDCl H NMR (00 MHz, CDCl 3 2 S

6 H NMR (00 MHz, CDCl DMSO-d H NMR (400 MHz, DMSO-d 6 S6

7 H NMR (400 MHz, CDCl CDCl H NMR (700 MHz, CDCl 3 1 S7

8 CDCl C NMR (100 MHz, CDCl 3 4a DEPT-13 (100 MHz, CDCl 3 4a S8

9 CDCl C NMR (12 MHz, CDCl DEPT-13 (12 MHz, CDCl 3 2 S9

10 CDCl C NMR (12 MHz, CDCl DEPT-13 (12 MHz, CDCl 3 3 S10

11 CDCl 3 13 C NMR (100 MHz, CDCl 3 DEPT-13 (100 MHz, CDCl 3 S11

12 CDCl C NMR (100 MHz, CDCl DEPT-13 (100 MHz, CDCl 3 6 S12

13 CDCl C NMR (176 MHz, CDCl 3 1 DEPT-13 (176 MHz, CDCl 3 1 S13

14 Table S1. Titration study of 2 in CDCl 3 ( mm, 400 MHz with DMSO-d 6 (Volume of DMSO- d 6 added at each addition = μl No Volume of DMSO-d6 (µl Chemical Shift ( NH1 NH Chemical Shift in NH1 NH Volume of DMSO-d 6 added ( L S14

15 Table S2. Titration study of 3 in CDCl 3 ( mm, 400 MHz with DMSO-d 6 (Volume of DMSO- d 6 added at each addition = μl No Volume of DMSO-d6 (µl Chemical Shift ( NH1 NH2 NH Chemical Shift ( NH1 NH2 NH Volume of DMSO-d 6 added ( L S1

16 Table S3. Titration study of 1 in CDCl 3 ( mm, 400 MHz with DMSO-d 6 (Volume of DMSO- d 6 added at each addition = μl No Volume of Chemical Shift ( DMSO-d6 (µl NH1 NH2 NH3 NH4 NH Chemical Shift in NH1 NH2 NH3 NH4 NH Volume of DMSO-d 6 added ( L S16

17 Table S4. Variable temperature study of 2 ( mm, 400 MHz, CDCl 3 No Temperature (K Chemical Shift in NH1 NH Chemical Shift in NH1 NH Temperature (K S17

18 Table S. Variable temperature study of 3 ( mm, 400 MHz, CDCl 3 No Temperature (K Chemical Shift in NH1 NH2 NH Chemical Shift in NH1 NH2 NH Temperature (K S18

19 Table S6. Variable temperature study of 1 ( mm, 400 MHz, CDCl 3 No Temperature Chemical Shift in (K NH1 NH2 NH3 NH4 NH Chemical Shift in NH1 NH2 NH3 NH4 NH Temperature (K S19

20 (a (b C6H C16,C17,C18, C19,C20H C7H C16,C17,C18, C19,C20H (c NH1 C14Ha C14Hb C9H C12Ha,C2Ha C12Hb,C2Hb C14Hb NH1.2 C14Ha C11H Boc C10H Figure S1: TOCSY full spectrum (a of 2 (2 mm, 00 MHz, CDCl 3, 298 K; aromatic (b and aliphatic (c regions shown separately. S20

21 (a C6H C16,C17, C18,C19, C20H C7H (b NH1 C14Ha C14Hb C9H C12Ha, C2Ha C12Hb, C2Hb C10H C11H Boc Figure S2: Partial COSY spectra of 2 (2 mm, 00 MHz, CDCl 3, 298 K; aromatic (a and aliphatic (b regions shown separately. S21

22 (a C6H C7H C16,C17, C14Hb C18,C19, C20H NH1 C14Ha C9H C12Ha, C2Ha C12Hb, C2Hb C10H C11H Boc (b NH2 C6H C7H C16,C17, C18,C19, C20H C14Hb NH1 C14Ha C9H C12Ha, C2Ha C12Hb, C2Hb C10H C11H Boc Figure S3: HSQC (a and HMBC (b full spectra of 2 (2 mm, 00 MHz, CDCl 3, 298 K. S22

23 10 C14Hb NH1 C14Ha Boc NH2 NH2/NH C16.17,18, 19, 20H Boc 1. Boc C14Hb Figure S4: 2D NOESY full spectrum and excerpts of 2 (2 mm, 00 MHz, CDCl 3, 298 K. NH C9H Figure S: COSY full spectrum (a of 3 (2 mm, 00 MHz, CDCl 3, 298 K. S23

24 (a C6H C7H (b NH3 NH1 C2H C9H C12Ha C12Hb C14H C10Ha C11H C10Hb Boc Figure S6: Partial COSY spectra of 3 (2 mm, 00 MHz, CDCl 3, 298 K; aromatic (a and aliphatic (b regions shown separately C14H NH1 NH Boc C9H 1.4 Boc Figure S7: 2D NOESY full spectrum and excerpts of 3 (2 mm, 00 MHz, CDCl 3, 298 K. S24

25 (a (b C7H, C18H NH3 C7H, C18H (c NH3 C12Ha C2Ha C14Hb C14Ha C9H C21H C12Hb C24H C2Hb C26H C11Ha C22Hb C22Ha C10Ha C10Hb C23H C11Hb Figure S8: TOCSY full spectrum (a of 1 (6 mm, 700 MHz, CDCl 3, 328 K; aromatic (b and aliphatic (c regions shown separately. S2

26 (a 10 (b C7H, C18H C7H, C18H NH3 7. (c C2Ha C14Hb C14Ha C21H C9H C12Ha C12Hb C24H C2Hb C26H C10Ha C10Hb C22Ha C22Hb C11Ha C23H, C11Hb Boc Figure S9. COSY full spectrum (a of 1 (23 mm, 700MHz, CDCl 3, 298 K; aromatic (b and aliphatic (c regions shown separately. 4 (a (b C7H, C18H NH3 C7H, C18H (c C21H C9H C2Ha C14Hb C14Ha C12Ha C12Hb C24H C2Hb C26H C22Ha C10Ha C10Hb C22Hb C11Ha C23H, C11Hb Boc Figure S10. HSQC full spectrum (a of 1 (23 mm, 700MHz, CDCl 3, 298 K; aromatic (b and aliphatic (c regions shown separately. S26 60

27 (a C7H, C18H (b NH3 C7H, C18H 120 (c C21H C9H C2Ha C14Hb C14Ha C12Ha C12Hb C24H C2Hb C26H C10Ha C10Hb C22Ha C22Hb C11Ha C23H, C11Hb Boc Figure S11. HMBC full spectrum (a of 1 (23 mm, 700MHz, CDCl 3, 298 K; aromatic (b and aliphatic (c regions shown separately Figure S12. NOESY full spectrum of 1 (6 mm, 700MHz, CDCl 3, 328 K. S27

28 C24H C2Hb C12Hb C2Ha C14Hb C12Ha C14Ha NH4 NH2 NH2/ C2Hb NH2/ C2Ha NH4/C14Hb NH4/C14Ha NH1 4.0 NH4 NH2 NH2/NH NH1 NH4 NH2 C2Ha C2Hb NH3 NH4/NH NH3 NH NH C9H C26H C21H Figure S13. 2D NOESY extracts of 1 (6 mm, 700MHz, CDCl 3, 328 K. S28

29 X-ray Crystallography: Single crystal structure of compound 2 was determined by measuring X-ray intensity data on a Bruker SMART APEX II single crystal X- ray CCD diffractometer having graphite-monochromatised (Mo-Kα = Å radiation. The X-ray generator was operated at 0 kv and 30 ma. A preliminary set of cell constants and an orientation matrix were calculated from total 36 frames. The optimized strategy used for data collection consisted different sets of and scans with 0. steps in /. Data were collected keeping the sample-todetector distance fixed at.00 cm. The X-ray data acquisition was monitored by APEX2 program suit. All the data were corrected for Lorentz-polarization and absorption effects using SAINT and SADABS programs integrated in APEX2 package. The structures were solved by direct methods and refined by full matrix least squares, based on F 2, using SHELX-97. Molecular diagrams were generated using ORTEP-3 and Mercury programs. Geometrical calculations were performed using SHELXTL and PLATON. Table 7: X-ray crystallographic data of trimer 2. Crystal Data 2 Formula C 24 H 29 N 3 O 6 S M r Crystal Size, mm Temp. (K 10(2 Crystallizing solvent Ethyl acetate-petroleum ether Crystal Syst. Orthorhombic Space Group P a/å 8.866(3 b/å ( c/å (9 / 0 90 / 0 90 / 0 90 V/Å (16 Z 4 D calc /g cm μ/mm F( Ab. Correct. multi-scan 2 max 0 Total reflns unique reflns h, k, l (min, max (-10,10,(-1,1,(-23,26 R int S29

30 No. of para 311 R1 [I> 2σ(I] wr2[i> 2σ(I] R1 [all data] wr2 [all data] goodness-of-fit Δ max,δ min (eå , CCDC no S30

31 Table 8: noe-derived distance constraints used in molecular modeling for structural elucidation of oligomer 1. Atom I Atom II Chemical Chemical Shift I Shift II Upper Bound Lower Bound C19H NH NH3 NH NH1 NH C14Ha NH C14Hb NH C2Ha NH C2Hb NH C9H NH C14Ha NH C14Hb NH C21H NH C2Ha NH C2Hb NH C26H NH C10Ha C9H C23H C21H Boc NH Boc NH S31

32 Figure S14. CD spectra of (Gly-3-Atc-Pro n oligomers; tripeptides 2, 3 and hexapeptide 1 at a concentration of 0.1 mm. All CD spectra were recorded in trifluoroethanol at 298 K. S32

Enantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes

Enantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Enantioselective Organocatalytic Michael Addition of Isorhodanines to α,

Διαβάστε περισσότερα

Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes

Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes SUPPORTING INFORMATION Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes Eric J. Uzelac, Casey B. McCausland, and Seth C. Rasmussen*

Διαβάστε περισσότερα

Supporting Information. Palladium Complexes with Bulky Diphosphine. Synthesis of (Bio-) Adipic Acid from Pentenoic. Acid Mixtures.

Supporting Information. Palladium Complexes with Bulky Diphosphine. Synthesis of (Bio-) Adipic Acid from Pentenoic. Acid Mixtures. Supporting Information Palladium Complexes with Bulky Diphosphine Ligands as Highly Selective Catalysts for the Synthesis of (Bio-) Adipic Acid from Pentenoic Acid Mixtures. Choon Heng Low, James D. Nobbs,*

Διαβάστε περισσότερα

Supplementary information

Supplementary information Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary information Hybrids of acylated homoserine lactone and nitric

Διαβάστε περισσότερα

Synthesis of New Heteroscorpionate Iridium(I) and Iridium(III) Complexes

Synthesis of New Heteroscorpionate Iridium(I) and Iridium(III) Complexes Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 ELECTRONIC SUPPORTING INFORMATION For Synthesis of New Heteroscorpionate Iridium(I)

Διαβάστε περισσότερα

Supporting Information. Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the. Synthesis of Heteroaromatic Biaryls

Supporting Information. Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the. Synthesis of Heteroaromatic Biaryls Supporting Information Pd()-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the Synthesis of Heteroaromatic Biaryls Debkumar andi, Yang-Ming Jhou, Jhen-Yi Lee, Bing-Chiuan

Διαβάστε περισσότερα

Table of Contents 1 Supplementary Data MCD

Table of Contents 1 Supplementary Data MCD Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information for Magnetic circular dichroism and density functional theory

Διαβάστε περισσότερα

Supporting Information File 2. Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ;

Supporting Information File 2. Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ; Supporting Information File 2 Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ; Preparation, structures and host guest chemistry of fluorinated syn-bisquinoxaline molecular tweezers

Διαβάστε περισσότερα

Novel electroluminescent donor-acceptors based on dibenzo[a,c]phenazine as

Novel electroluminescent donor-acceptors based on dibenzo[a,c]phenazine as Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Novel electroluminescent donor-acceptors

Διαβάστε περισσότερα

Patrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.

Patrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data. ; doi:10.3390/molecules22020254 S1 of S23 Supplementary Materials: Reaction of 3-Amino-1,2,4-Triazole with Diethyl Phosphite and Triethyl Orthoformate: Acid-Base Properties and Antiosteoporotic Activities

Διαβάστε περισσότερα

Supporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds

Supporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds Supporting Information for Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds Zhongxue Fang, a Yongquan Ning, a Pengbing Mi, a Peiqiu Liao, a Xihe Bi* a,b a Department of Chemistry,

Διαβάστε περισσότερα

Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond

Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond Ken-ichi Yamashita, Kei-ichi Sato, Masaki Kawano and Makoto Fujita* Contents; Figure S1.

Διαβάστε περισσότερα

Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes

Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes Supplementary information Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes Marcos A. P. Martins 1 *, Alexandre R. Meyer 1, Paulo R. S. Salbego

Διαβάστε περισσότερα

Supplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3

Supplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3 Supplementary Information Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3 Lewis Pairs: Structures of Intermediates, Kinetics, and Mechanism Qianyi Wang, Wuchao Zhao,

Διαβάστε περισσότερα

Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings

Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings ickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings Braulio M. Puerta Lombardi, Rudy M. Braun, Chris Gendy, Chia Yun Chang,

Διαβάστε περισσότερα

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) CPh 3 as a functional group in P-heterocyclic

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information Molecular Cage Impregnated Palladium Nanoparticles: Efficient, Additive-Free Heterogeneous Catalysts for Cyanation of Aryl Halides. Bijnaneswar Mondal, Koushik Acharyya, Prodip Howlader

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information Vinylogous elimination/heck coupling/allylation domino reactions: access to 2- substituted 2,3-dihydrobenzofurans and indolines Jianguo Yang, *, Hanjie Mo, Xiuxiu Jin, Dongdong Cao,

Διαβάστε περισσότερα

Supporting Information for Substituent Effects on the Properties of Borafluorenes

Supporting Information for Substituent Effects on the Properties of Borafluorenes Supporting Information for Substituent Effects on the Properties of Borafluorenes Mallory F. Smith, S. Joel Cassidy, Ian A. Adams, Monica Vasiliu, Deidra L. Gerlach, David Dixon*, Paul A. Rupar* Department

Διαβάστε περισσότερα

Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid

Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid Taotao Ling, a Chinmay Chowdhury, a Bryan A. Kramer, a Binh G. Vong, a Michael A. Palladino b and Emmanuel A. Theodorakis a

Διαβάστε περισσότερα

College of Life Science, Dalian Nationalities University, Dalian , PR China.

College of Life Science, Dalian Nationalities University, Dalian , PR China. Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 Postsynthetic modification

Διαβάστε περισσότερα

Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information

Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information Aluminum Complexes of N 2 O 2 3 Formazanate Ligands Supported by Phosphine Oxide Donors Ryan R. Maar, Amir Rabiee Kenaree, Ruizhong Zhang, Yichen Tao, Benjamin D. Katzman, Viktor

Διαβάστε περισσότερα

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Cyclopentadienyl iron dicarbonyl (CpFe(CO) 2 ) derivatives

Διαβάστε περισσότερα

Supporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory

Supporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory Supporting Information Dysiherbols A C and Dysideanone E, Cytotoxic and NF-κB Inhibitory Tetracyclic Meroterpenes from a Dysidea sp. Marine Sponge Wei-Hua Jiao,, Guo-Hua Shi,, Ting-Ting Xu,, Guo-Dong Chen,

Διαβάστε περισσότερα

Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide

Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic

Διαβάστε περισσότερα

Zebra reaction or the recipe for heterodimeric zinc complexes synthesis

Zebra reaction or the recipe for heterodimeric zinc complexes synthesis Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 05 Supporting Information Zebra reaction or the recipe for heterodimeric zinc complexes synthesis

Διαβάστε περισσότερα

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Crotonols A and B, Two Rare Tigliane Diterpenoid

Διαβάστε περισσότερα

SUPPLEMENTARY MATERIAL. A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine Hybrids

SUPPLEMENTARY MATERIAL. A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine Hybrids 10.1071/CH17272_AC CSIRO 2017 Australian Journal of Chemistry 2017, 70(12), 1285-1290 SUPPLEMENTARY MATERIAL A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine

Διαβάστε περισσότερα

Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles

Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles X-Ray crystallographic data tables for paper: Supplementary Material (ESI) for Organic & Biomolecular Chemistry Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically

Διαβάστε περισσότερα

Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand

Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate

Διαβάστε περισσότερα

C H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged

C H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged Supporting Information C H Activation of Cp* Ligand Coordinated to Ruthenium Center: Synthesis and Reactivity of a Thiolate-Bridged Diruthenium Complex Featuring Fulvene-like Cp* Ligand Xiaoxiao Ji, Dawei

Διαβάστε περισσότερα

Synthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions

Synthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions This journal is The Royal Society of Chemistry 213 Synthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions Wenjing Cui, a Bao Zhaorigetu,* a Meilin Jia, a and Wulan

Διαβάστε περισσότερα

IV. ANHANG 179. Anhang 178

IV. ANHANG 179. Anhang 178 Anhang 178 IV. ANHANG 179 1. Röntgenstrukturanalysen (Tabellen) 179 1.1. Diastereomer A (Diplomarbeit) 179 1.2. Diastereomer B (Diplomarbeit) 186 1.3. Aldoladdukt 5A 193 1.4. Aldoladdukt 13A 200 1.5. Aldoladdukt

Διαβάστε περισσότερα

chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX

chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX σ-donor/acceptor confused ligands: The case of a chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX 77843-3255. *To whom correspondence

Διαβάστε περισσότερα

Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads for low-energy photosensitization

Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads for low-energy photosensitization Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads

Διαβάστε περισσότερα

Supporting Information

Supporting Information SUPPORTING INFORMATION FOR: Trialkylstibine complexes of boron, aluminium, gallium and indium trihalides: synthesis, properties and bonding Victoria K. Greenacre, William Levason and Gillian Reid Chemistry,

Διαβάστε περισσότερα

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Domino reaction of cyclic sulfamidate imines with

Διαβάστε περισσότερα

Supporting Information. Experimental section

Supporting Information. Experimental section Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Proton nuclear magnetic resonance ( 1

Διαβάστε περισσότερα

Supplementary Material

Supplementary Material Supplementary Material Synthesis of bis-oxathiaaza[3.3.3]propellanes via nucleophilic addition of (1,ω-alkanediyl)bis(N'-organylthioureas) on dicyanomethylene-1,3-indanedione Alaa A. Hassan, a * Kamal

Διαβάστε περισσότερα

Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4

Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4 Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting information An unusual bifunctional Tb-MOF for highly sensing

Διαβάστε περισσότερα

Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides

Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:

Διαβάστε περισσότερα

Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-

Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- Supporting Information for A catalyst-free multicomponent domino sequence for the diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- (arylamino)allyl]chromen-4-ones Pitchaimani Prasanna 1, Pethaiah

Διαβάστε περισσότερα

Supporting Information for

Supporting Information for Supporting Information for An atom-economic route to densely functionalized thiophenes via base-catalyzed rearrangement of 5-propargyl-2H-thiopyran-4(3H)-ones Chunlin Tang a, Jian Qin b, Xingqi Li *a a

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General

Διαβάστε περισσότερα

Supporting Information

Supporting Information One-Pot, Three-Component Assembly of Indoloquinolines: Total Synthesis of Isocryptolepine Alexander V. Aksenov,* Dmitrii A. Aksenov, Naila A. Orazova, Nicolai A. Aksenov, Georgii D. Griaznov, Annelise

Διαβάστε περισσότερα

Divergent synthesis of various iminocyclitols from D-ribose

Divergent synthesis of various iminocyclitols from D-ribose Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 205 Divergent synthesis of various iminocyclitols from D-ribose Ramu Petakamsetty,

Διαβάστε περισσότερα

Single Crystal X-Ray Structure Determination of Compounds 8a, 8b and 11a

Single Crystal X-Ray Structure Determination of Compounds 8a, 8b and 11a Single Crystal X-Ray Structure Determination of Compounds 8a, 8b and 11a General: Preliminary examination and data collection were carried out on an area detecting system (Kappa-CCD; Nonius) using graphite-monochromated

Διαβάστε περισσότερα

Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]

Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ] Supporting Information Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ] Eun Young Lee, Seung Yeon Jang, and Myunghyun Paik Suh* School of Chemistry,

Διαβάστε περισσότερα

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information 1,3,5-Triazapentadienes by Nucleophilic Addition to 1,3- and 1,4-Dinitriles - Sterically Constrained Examples by Incorporation into Cyclic Peripheries: Synthesis, Aggregation and

Διαβάστε περισσότερα

9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts

9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer

Διαβάστε περισσότερα

Copper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones

Copper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2016 Supporting information Copper-Catalyzed Oxidative Dehydrogenative - Bond Formation

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information Chloroyttrium 2-(1-(arylimino)alkyl)quinolin-8-olate Complexes: Synthesis, Characterization, and Catalysis of the Ring-Opening Polymerization (ROP) of ε- Caprolactone (ε-cl) Wenjuan

Διαβάστε περισσότερα

Malgorzata Korycka-Machala, Marcin Nowosielski, Aneta Kuron, Sebastian Rykowski, Agnieszka Olejniczak, Marcin Hoffmann and Jaroslaw Dziadek

Malgorzata Korycka-Machala, Marcin Nowosielski, Aneta Kuron, Sebastian Rykowski, Agnieszka Olejniczak, Marcin Hoffmann and Jaroslaw Dziadek Molecules 2017, 21, 154; doi:10.3390/molecules22010154 Supplementary Materials: Naphthalimides Selectively Inhibit the Activity of Bacterial, Replicative DNA Ligases and Display Bactericidal Effect against

Διαβάστε περισσότερα

SUPPORTING INFORMATION

SUPPORTING INFORMATION SUPPORTING INFORMATION Heronamides A C, new polyketide macrolactams from an Australian marine-derived Streptomyces sp. A biosynthetic case for synchronized tandem electrocyclization. Ritesh Raju, Andrew

Διαβάστε περισσότερα

Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity

Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity Jian-Long Li 1,a, Wei Zhao 1,a, Chen Zhou 1,a, Ya-Xuan

Διαβάστε περισσότερα

SUPPLEMENTARY MATERIAL

SUPPLEMENTARY MATERIAL 10.1071/CH16014_AC The Authors 2016 Australian Journal of Chemistry 2016, 69(9), 1049-1053 SUPPLEMENTARY MATERIAL A Green Approach for the Synthesis of Novel 7,11-Dihydro-6H-chromeno[3,4- e]isoxazolo[5,4-b]pyridin-6-one

Διαβάστε περισσότερα

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Abnormal N-Heterocyclic Carbene Based Nickel Complex for Catalytic

Διαβάστε περισσότερα

Synthesis, structural studies and stability of the model, cysteine containing DNA-protein cross-links

Synthesis, structural studies and stability of the model, cysteine containing DNA-protein cross-links Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 ELECTRONIC SUPPLEMENTARY INFORMATION

Διαβάστε περισσότερα

Fused Bis-Benzothiadiazoles as Electron Acceptors

Fused Bis-Benzothiadiazoles as Electron Acceptors Fused Bis-Benzothiadiazoles as Electron Acceptors Debin Xia, a,b Xiao-Ye Wang, b Xin Guo, c Martin Baumgarten,*,b Mengmeng Li, b and Klaus Müllen*,b a MIIT Key Laboratory of ritical Materials Technology

Διαβάστε περισσότερα

Supplementary Information

Supplementary Information Electronic upplementary Material (EI) for Photochemical & Photobiological ciences. This journal is The Royal ociety of Chemistry and wner ocieties 214 upplementary Information elective and sensitive fluorescence-shift

Διαβάστε περισσότερα

Bloco A, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ, Brazil. Contents Pages

Bloco A, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ, Brazil. Contents Pages Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information Copper(II) Catalyzed Synthesis of Novel Helical

Διαβάστε περισσότερα

Electronic Supplementary Information. Carbon dioxide as a reversible amine-protecting

Electronic Supplementary Information. Carbon dioxide as a reversible amine-protecting Electronic Supplementary Information Carbon dioxide as a reversible amine-protecting agent in selective Michael additions and acylations Annelies Peeters, Rob Ameloot and Dirk E. De Vos * Centre for Surface

Διαβάστε περισσότερα

Table S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.

Table S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h. Supporting Information [NH 3 CH 3 ] [In SbS 9 SH]: A novel methylamine-directed indium thioantimonate with Rb + ion-exchange property Kai-Yao Wang a,b, Mei-Ling Feng a, Jian-Rong Li a and Xiao-Ying Huang

Διαβάστε περισσότερα

Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces

Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces Highly enantioselective cascade synthesis of spiropyrazolones Alex Zea a, Andrea-Nekane R. Alba a, Andrea Mazzanti b, Albert Moyano a and Ramon Rios a,c * Supporting Information NMR spectra and HPLC traces

Διαβάστε περισσότερα

difluoroboranyls derived from amides carrying donor group Supporting Information

difluoroboranyls derived from amides carrying donor group Supporting Information The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group Supporting Information Anna Maria Grabarz a Adèle D. Laurent b, Beata Jędrzejewska

Διαβάστε περισσότερα

E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations

E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations Nemanja Đorđević, Rakesh Ganguly, Milena Petković, and Dragoslav Vidović Email: drasko.vidovic@monash.edu

Διαβάστε περισσότερα

ANNEXE 2 : SPECTRES DE RÉSONANCE MAGNÉTIQUE NUCLÉAIRE

ANNEXE 2 : SPECTRES DE RÉSONANCE MAGNÉTIQUE NUCLÉAIRE ANNEXE 2 : SPECTRES DE RÉSONANCE MAGNÉTIQUE NUCLÉAIRE 175 4-Oxopentyl acetate (1-9) 27.56 17.91 63.49 39.76 29.86 22.66 2.82 2. 1.97 2.91 2.96 2.9 4. 3.98 3.96 2.47 2.44 2.42 2.7 1.95 1.86 1.84 1.82 1.79

Διαβάστε περισσότερα

Supporting Information Synthesis of cyclometalated 1,3,5-triphenylpyrazole palladium dimer and its activity towards cross coupling reactions

Supporting Information Synthesis of cyclometalated 1,3,5-triphenylpyrazole palladium dimer and its activity towards cross coupling reactions Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 215 Supporting Information Synthesis of cyclometalated 1,3,5-triphenylpyrazole palladium

Διαβάστε περισσότερα

SUPPORTING INFORMATION. Diastereoselective synthesis of nitroso acetals from (S,E)- -aminated

SUPPORTING INFORMATION. Diastereoselective synthesis of nitroso acetals from (S,E)- -aminated SUPPORTING INFORMATION for Diastereoselective synthesis of nitroso acetals from (S,E)- -aminated nitroalkenes via multicomponent [4 + 2]/[3 + 2] cycloadditions promoted by LiCl or LiClO 4 Leandro Lara

Διαβάστε περισσότερα

Synthesis and Biological Evaluation of Novel Acyclic and Cyclic Glyoxamide derivatives as Bacterial Quorum Sensing and Biofilm Inhibitors

Synthesis and Biological Evaluation of Novel Acyclic and Cyclic Glyoxamide derivatives as Bacterial Quorum Sensing and Biofilm Inhibitors Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Synthesis and Biological Evaluation of Novel Acyclic and Cyclic Glyoxamide

Διαβάστε περισσότερα

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization

Διαβάστε περισσότερα

Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of. 1,2,3-Triazole Synthesis

Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of. 1,2,3-Triazole Synthesis Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of α-diazoketones with Various Amines: A Strategy for Catalytic Wolff 1,2,3-Triazole Synthesis Zikun Wang, a Xihe

Διαβάστε περισσότερα

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information NbCl 3 -catalyzed [2+2+2] intermolecular cycloaddition of alkynes and alkenes to 1,3-cyclohexadiene derivatives Yasushi Obora,* Keisuke Takeshita and Yasutaka Ishii*

Διαβάστε περισσότερα

Supporting Information

Supporting Information Chloromethylhalicyclamine B, a Marine-Derived Protein Kinase CK1δ/ε Inhibitor Germana Esposito, Marie-Lise Bourguet-Kondracki, * Linh H. Mai, Arlette Longeon, Roberta Teta, Laurent Meijer, Rob Van Soest,

Διαβάστε περισσότερα

Controlling Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties

Controlling Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties Supporting Information Controlling Growth of Molecular Crystal Aggregates with Distinct Linear and Nonlinear Optical Properties Yusen Luo,,,# Chunqing Yuan,,# Jialiang Xu*, Yongjun Li*, Huibiao Liu, Sergey

Διαβάστε περισσότερα

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information The preferred all-gauche conformations in 3-fluoro-1,2-propanediol Laize A. F. Andrade, a Josué M. Silla, a Claudimar J. Duarte, b Roberto Rittner, b Matheus P. Freitas*,a

Διαβάστε περισσότερα

Heterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics

Heterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics Supporting Information (SI) Heterobimetallic Pd-Sn Catalysis: Michael Addition Reaction with C-, N-, -, S- Nucleophiles and In-situ Diagnostics Debjit Das, a Sanjay Pratihar a,b and Sujit Roy c * a rganometallics

Διαβάστε περισσότερα

Supplementary Materials for. Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides

Supplementary Materials for. Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides Supplementary Materials for Kinetic and Computational Studies on Pd(I) Dimer- Mediated Halogen Exchange of Aryl Iodides Indrek Kalvet, a Karl J. Bonney, a and Franziska Schoenebeck a * a Institute of Organic

Διαβάστε περισσότερα

Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008

Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008 Supporting Information Copyright Wiley-VC Verlag Gmb & Co. KGaA, 69451 Weinheim, 2008 Copper Complexes of Mono- and Ditopic [(Methylthio)methyl]borates: Missing Links and Linked Systems En Route to Copper

Διαβάστε περισσότερα

Supporting Information. Experimental section

Supporting Information. Experimental section Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Anhydrous solvents were transferred by

Διαβάστε περισσότερα

New Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp.

New Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp. SUPPLEMENTARY MATERIAL New Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp. Mohamed-Elamir F. Hegazy a,*, Amira M. Gamal-Eldeen b, Tarik A. Mohamed a, Montaser A. Alhammady c, Abuzeid A.

Διαβάστε περισσότερα

Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes

Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes 1 Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes Gonzalo Blay, Isabel Fernández, Alícia Marco-Aleixandre, and José R. Pedro Departament de Química Orgànica, Facultat de Química,

Διαβάστε περισσότερα

Electronic Supporting Information

Electronic Supporting Information Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information robing steric influences on electrophilic phosphonium

Διαβάστε περισσότερα

Supporting Information. Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on

Supporting Information. Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on Supporting Information for Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on folding and bioactivity Marta De Zotti 1, Barbara Biondi 1, Cristina Peggion 1, Matteo De Poli 1, Haleh

Διαβάστε περισσότερα

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Silver or Cerium-Promoted Free Radical Cascade Difunctionalization

Διαβάστε περισσότερα

(M = Mn, Fe, Co, Ni, Cu and Zn)----Mimicking the M II - Substituted Quercetin 2,3-Dioxygenase

(M = Mn, Fe, Co, Ni, Cu and Zn)----Mimicking the M II - Substituted Quercetin 2,3-Dioxygenase Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 215 Supplementary material Catalytic Dioxygenation of Flavonol by M II Complexes (M = Mn,

Διαβάστε περισσότερα

Direct metallation of thienopyrimidines using a mixed lithium-cadmium base and antitumor activity of functionalized derivatives

Direct metallation of thienopyrimidines using a mixed lithium-cadmium base and antitumor activity of functionalized derivatives Direct metallation of thienopyrimidines using a mixed lithium-cadmium base and antitumor activity of functionalized derivatives Katia négaroff, a Frédéric Lassagne, a Ghenia Bentabed-Ababsa, a,b Ekhlass

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information For A Highly Sensitive ESIPT Based Ratiometric Fluorescence Sensor for Selective Detection of Al 3+ Sanghamitra Sinha, Bijit Chowdhury and Pradyut Ghosh* Department of Inorganic

Διαβάστε περισσότερα

Experimental. Crystal data

Experimental. Crystal data organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Terephthalic acid 2,2 0 -dimethyl-1,1 0 - (butane-1,4-diyl)dibenzimidazole (2/3) Hui Jiang and Xian-Wu Dong* Department

Διαβάστε περισσότερα

Supporting Information. Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid

Supporting Information. Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 16 Supporting Information Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid

Διαβάστε περισσότερα

NH-Type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications

NH-Type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications Supporting Information NH-Type of chiral Ni(II) complexes of glycine Schiff base: design, structural evaluation, reactivity and synthetic applications Mackenzie Bergagnini, a Kazunobu Fukushi, b Jianlin

Διαβάστε περισσότερα

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information for Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Chun-Huan Jiang, Xiantao Lei,

Διαβάστε περισσότερα

Supporting information

Supporting information Electronic upplementary Material (EI) for New Journal of Chemistry. This journal is The Royal ociety of Chemistry and the Centre National de la Recherche cientifique 7 upporting information Lipase catalyzed,-addition

Διαβάστε περισσότερα

Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3

Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Supporting Information Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Shohei Shimokawa, Yuhsuke Kawagoe, Katsuhiko Moriyama, Hideo Togo* Graduate

Διαβάστε περισσότερα

Phenylpropanoids, Sesquiterpenoids and Flavonoids from Pimpinella tragium Vill. subsp. lithophila (Schischkin) Tutin

Phenylpropanoids, Sesquiterpenoids and Flavonoids from Pimpinella tragium Vill. subsp. lithophila (Schischkin) Tutin Supporting Information Rec. Nat. Prod. 10:2 (2016) 207-213 Phenylpropanoids, Sesquiterpenoids and Flavonoids from Pimpinella tragium Vill. subsp. lithophila (Schischkin) Tutin Hilal Özbek 1, Zühal Güvenalp

Διαβάστε περισσότερα

Supporting Information

Supporting Information Supporting Information rigin of the Regio- and Stereoselectivity of Allylic Substitution of rganocopper Reagents Naohiko Yoshikai, Song-Lin Zhang, and Eiichi Nakamura* Department of Chemistry, The University

Διαβάστε περισσότερα

Supporting information

Supporting information Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 204 Supporting information Palladium nanoparticles supported on triazine functionalised mesoporous

Διαβάστε περισσότερα