A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
|
|
|
- Μνημοσύνη Αγγελοπούλου
- 7 χρόνια πριν
- Προβολές:
Transcript
1 Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes Jie Sheng, a Congbin Fan, a and Jie Wu*,ab a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai , China b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai , China jie_wu@fudan.edu.cn Supporting Information 1. General experimental methods (S2). 2. General experimental procedure and characterization data (S2-S9) F, 1 H and 13 C NMR spectra of compound 3 (S10-S69). 1
2 General Materials and Methods: Unless otherwise stated, all commercial reagents were used as received. All solvents were dried and distilled according to standard procedures. Flash column chromatography was performed using silica gel (60-Å pore size, 32 63µm, standard grade). Analytical thin layer chromatography was performed using glass plates pre-coated with 0.25 mm mesh silica gel impregnated with a fluorescent indicator (254 nm). Thin layer chromatography plates were visualized by exposure to ultraviolet light. Organic solutions were concentrated on rotary evaporators at ~20 Torr at C. Nuclear magnetic resonance (NMR) spectra are recorded in parts per million from internal tetramethylsilane on the δ scale. 1 H and 13 C NMR spectra were recorded in CDCl 3 on a Bruker DRX-400 spectrometer operating at 400 MHz and 100 MHz, respectively. All chemical shift values are quoted in ppm and coupling constants quoted in Hz. High resolution mass spectrometry (HRMS) spectra were obtained on a microtof II Instrument. General procedure for the synthesis of 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes. R 1 XMe H BiCl X 3 (2.0 equiv) + N R Ph 1 SCF3 DCE, 85! C R 2 air SCF X = O, S 3 R 2 Trifluoromethanesulfanylamide 2 (0.22 mmol, 42.5 mg) was added to a solution of compound 1 (0.2 mmol) and BiCl 3 (0.4 mmol, mg) in DCE (2.0 ml), and the solution was stirred at 85 C for hours. After completion of the reaction as indicated by TLC, the reaction mixture was filtered by silica gel and washed by CH 2 Cl 2 (3 5.0 ml). The solution was concentrated in vacuo and the residue was purified by column chromatography on silica gel to provide the product 3. O SCF 3 2
3 2-Phenyl-3-(trifluoromethylthio)benzofuran (3a) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), (m, 4H), (m, 1H), 8.20 (d, J = 7.2 Hz, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 97.5, 111.4, 120.2, 124.1, 125.7, 128.0, 128.7, 128.9, (q, J = Hz), 130.2, 130.9, 153.7, 160.1; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 9 F 3 OS: (M + ), found: O O SCF 3 2-(4-Methoxyphenyl)-3-(trifluoromethylthio)benzofuran (3b) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 3.92 (s, 3H), 7.06 (d, J = 8.9 Hz, 2H), (m, 2H), (m, 1H), (m, 1H), 8.23 (d, J = 8.9 Hz, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 55.4, 95.6, 111.2, 114.1, 119.9, 121.5, 123.9, 125.2, (q, J = Hz), 129.5, 131.1, 153.4, 160.2, 161.1; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 O 2 S: (M + ), found: O SCF 3 2-p-Tolyl-3-(trifluoromethylthio)benzofuran (3c) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 2.41 (s, 3H), 7.29 (d, J = 8.1 Hz, 2H), (m, 2H), (m, 1H), (m, 1H), 8.10 (d, J = 8.2 Hz, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 21.4, 96.5, 111.2, 119.9, 123.9, 125.4, 126.0, 127.7, , (q, J = Hz), 140.4, 153.5, 160.3; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 OS: (M + ), found: O Cl SCF 3 2-(4-Chlorophenyl)-3-(trifluoromethylthio)benzofuran (3d) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), 3
4 7.47 (dd, J 1 = 1.8 Hz, J 2 = 6.9 Hz, 2H), (m, 1H), (m, 1H), 8.23 (dd, J 1 = 1.8 Hz, J 2 = 6.9 Hz, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 97.8, 111.3, 120.1, 124.1, 125.9, 127.2, 128.9, 129.0, (q, J = Hz), 130.6, 136.2, 153.5, 158.7; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 8 ClF 3 OS: (M + ), found: O F SCF 3 2-(4-Fluorophenyl)-3-(trifluoromethylthio)benzofuran (3e) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 7.22 (t, J = 8.4 Hz, 2H), (m, 2H), (m, 1H), 7.76 (d, J = 7.9 Hz, 1H), 8.23 (dd, J 1 = 5.5 Hz, J 2 = 7.8 Hz, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 97.2, 111.4, (d, 2 J CF = 21.8 Hz), 120.2, 124.2, 125.1, 125.8, (q, J = Hz), (d, 3 J CF = 8.4 Hz), 130.8, 153.6, 159.1, (d, 1 J CF = Hz); 19 F NMR (378 MHz, CDCl 3 ) δ (s), (s); HRMS (EI) calcd for C 15 H 8 F 4 OS: (M + ), found: O SCF 3 2-Cyclopropyl-3-(trifluoromethylthio)benzofuran (3f) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), (m, 2H), (m, 1H), (m, 2H), 7.37 (d, J = 7.8 Hz, 1H), 7.58 (d, J = 7.3 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 8.3, 8.6, 96.7, 111.0, 118.8, 123.7, 124.3, (q, J = Hz), 130.1, 153.2, 167.0; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 12 H 9 F 3 OS: (M + ), found: O SCF 3 2-tert-Butyl-3-(trifluoromethylthio)benzofuran (3g) Colorless oil; 1 H NMR (400 MHz, CDCl 3 ) δ 1.57 (s, 9H), (m, 2H), (m, 1H), (m, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 29.7, 31.9, 4
5 95.9, 111.0, 119.7, 123.5, 124.7, (q, J = Hz), 152.9, 171.3; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 13 H 13 F 3 OS: (M + ), found: O Cl SCF 3 5-Chloro-2-phenyl-3-(trifluoromethylthio)benzofuran (3i) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 7.32 (dd, J 1 = 2.1 Hz, J 2 = 8.7 Hz, 1H), 7.45 (d, J = 8.7 Hz, 1H), (m, 3H), 7.69 (d, J = 1.3 Hz, 1H), (m, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 97.0, 112.5, 119.8, 126.0, 127.9, 128.4, 128.7, (q, J = Hz), 130.0, 130.5, 132.3, 152.0, 161.4; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 8 ClF 3 OS: (M + ), found: O O 2 N SCF 3 5-Nitro-2-phenyl-3-(trifluoromethylthio)benzofuran (3j) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 3H), 7.62 (d, J = 9.0 Hz, 1H), (m, 2H), 8.10 (dd, J 1 = 2.1 Hz, J 2 = 9.0 Hz, 1H), 8.61 (s, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 98.3, 112.0, 116.6, 121.4, 125.2, 128.0, , , (q, J = Hz), 131.2, 145.2, 156.2, 163.1; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 8 F 3 NO 3 S: (M + ), found: O O SCF 3 6-Methoxy-2-phenyl-3-(trifluoromethylthio)benzofuran (3k) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 3.96 (s, 3H), (m, 3H), 7.56 (d, J = 8.6 Hz, 1H), 8.10 (dd, J 1 = 1.6 Hz, J 2 = 8.6 Hz, 1H), (m, 2H), 8.44 (s, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 52.2, 98.0, 111.3, 122.4, 126.6, 127.4, 127.9, 128.7, (q, J = Hz), 130.6, 130.9, 156.1, 161.4, 5
6 166.7; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 O 2 S: (M + ), found: O O SCF 3 4-Methoxy-2-phenyl-3-(trifluoromethylthio)benzofuran (3l) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 3.97 (s, 3H), 6.76 (d, J = 8.0 Hz, 1H), 7.17 (d, J = 8.2 Hz, 1H), 7.29 (t, J = 8.2 Hz, 1H), (m, 3H), (m, 2H); 13 C NMR (100 MHz, CDCl 3 ) δ 55.7, 96.6, 104.4, 105.0, 114.6, 119.4, 126.2, 128.1, 128.5, (q, J = Hz), 129.0, 129.9, 154.9, 155.0; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 O 2 S: (M + ), found: S SCF 3 2-Phenyl-3-(trifluoromethylthio)benzo[b]thiophene (3m) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 5H), (m, 2H), 7.87 (d, J = 8.0 Hz, 1H), 8.10 (d, J = 8.1 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 111.1, 122.1, 123.7, , , 128.5, 129.3, (q, J = Hz), 130.2, 132.6, 137.9, 141.3, 154.3; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 9 F 3 S 2 : (M + ), found: S Cl SCF 3 2-(4-Chlorophenyl)-3-(trifluoromethylthio)benzo[b]thiophene (3n) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 3H), (m, 1H), 7.59 (d, J = 8.0 Hz, 2H), 7.85 (d, J = 7.9 Hz, 1H), 7.07 (d, J = 8.0 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 103.2, 122.1, 123.7, 125.6, 125.7, 128.8, (q, J = Hz), 131.0, 131.4, 135.6, 137.8, 141.2, 152.7; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 15 H 8 ClF 3 S 2 : (M + ), found:
7 S SCF 3 2-p-Tolyl-3-(trifluoromethylthio)benzo[b]thiophene (3o) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 2.45 (s, 3H), 7.31 (d, J = 7.1 Hz, 2H), (m, 1H), (m, 1H), 7.58 (d, J = 7.1 Hz, 2H), 7.85 (d, J = 7.8 Hz, 1H), 8.09 (d, J = 7.8 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 21.3, 110.6, 122.1, 123.5, , , (q, J = Hz), , 129.7, 130.0, 137.8, 139.5, 141.4, 154.5; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 S 2 : (M + ), found: S O SCF 3 2-(4-Methoxyphenyl)-3-(trifluoromethylthio)benzo[b]thiophene (3p) Yellow solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 3.87 (s, 3H), (m, 2H), (m, 1H), (m, 1H), (m, 2H), 7.83 (d, J = 7.9 Hz, 1H), 8.05 (d, J = 8.1 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 55.3, 110.1, 114.0, 122.0, 123.5, 124.9, 125.3, 125.4, (q, J = Hz), 131.4, 137.6, 141.4, 154.2, 160.5; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 16 H 11 F 3 OS 2 : (M + ), found: S F SCF 3 2-(4-Fluorophenyl)-3-(trifluoromethylthio)benzo[b]thiophene (3q) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), (m, 2H), (m, 2H), (m, 1H), (m, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 111.3, (d, 2 J CF = 21.8 Hz), 122.1, 123.7, , , 128.6, (q, J = Hz), (d, 3 J CF = 7.8 Hz), 137.8, 141.2, 153.0, (d, 1 J CF = Hz); 19 F NMR (378 MHz, CDCl 3 ) δ (s), (s); HRMS (EI) calcd for C 15 H 8 F 4 S 2 : (M + ), found:
8 S SCF 3 2-Cyclopropyl-3-(trifluoromethylthio)benzo[b]thiophene (3r) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), (m, 2H), (m, 1H), (m, 1H), (m, 1H), 7.72 (d, J = 8.0 Hz, 1H), 7.91 (d, J = 8.0 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 11.9, 12.2, 111.0, 122.0, 122.2, 124.6, 125.2, (q, J = Hz), 135.6, 141.3, 161.5; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 12 H 9 F 3 S 2 : (M + ), found: S SCF 3 2-tert-Butyl-3-(trifluoromethylthio)benzo[b]thiophene (3s) White solid; mp: C; 1 H NMR (400 MHz, CDCl 3 ) δ 1.63 (s, 9H), (m, 1H), (m, 1H), 7.79 (d, J = 8.0 Hz, 1H), 8.00 (d, J = 8.1 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 31.7, 36.7, 109.3, 121.7, 122.7, 124.7, 124.9, (q, J = Hz), 135.7, 142.3, 166.3; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 13 H 13 F 3 S 2 : (M + ), found: S SCF 3 2-Butyl-3-(trifluoromethylthio)benzo[b]thiophene (3t) Colorless oil; 1 H NMR (400 MHz, CDCl 3 ) δ 0.97 (t, J = 7.1 Hz, 3H), (m, 2H), (m, 2H), 3.18 (t, J = 7.6 Hz, 2H), 7.35 (t, J = 7.4 Hz, 1H), (m, 1H), 7.78 (d, J = 8.0 Hz, 1H), 7.95 (d, J = 8.0 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 13.8, 22.4, 29.4, 33.4, 111.1, 122.2, 122.7, 124.8, 125.1, (q, J = Hz), 137.3, 140.7, 158.4; 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 13 H 13 F 3 S 2 : (M + ), found:
9 S TMS SCF 3 Trimethyl(3-(trifluoromethylthio)benzo[b]thiophen-2-yl)silane (3u) Yellow oil; 1 H NMR (400 MHz, CDCl 3 ) δ 0.50 (s, 9H), 7.43 (dd, J 1 = 0.8 Hz, J 2 = 8.0 Hz, 2H), (m, 1H), 7.88 (d, J = 7.9 Hz, 1H), 8.06 (d, J = 8.2 Hz, 1H); 13 C NMR (100 MHz, CDCl 3 ) δ 0.1, 12.9, 122.2, 123.0, 124.3, 125.0, 125.1, 125.6, 125.8, (q, J = Hz); 19 F NMR (378 MHz, CDCl 3 ) δ (s); HRMS (EI) calcd for C 12 H 13 F 3 S 2 Si: (M + ), found:
10 10
11 11
12 12
13 13
14 14
15 15
16 16
17 17
18 18
19 19
20 20
21 21
22 22
23 23
24 24
25 25
26 26
27 27
28 28
29 29
30 30
31 31
32 32
33 33
34 34
35 35
36 36
37 37
38 38
39 39
40 40
41 41
42 42
43 43
44 44
45 45
46 46
47 47
48 48
49 49
50 50
51 51
52 52
53 53
54 54
55 55
56 56
57 57
58 58
59 59
60 60
61 61
62 62
63 63
64 64
65 65
66 66
67 67
68 68
69 69
Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic
Supporting Information
Supporting Information Lewis acid catalyzed ring-opening reactions of methylenecyclopropanes with diphenylphosphine oxide in the presence of sulfur or selenium Min Shi,* Min Jiang and Le-Ping Liu State
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information 1. General experimental methods (S2). 2. Table 1: Initial studies (S2-S4).
Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces
Highly enantioselective cascade synthesis of spiropyrazolones Alex Zea a, Andrea-Nekane R. Alba a, Andrea Mazzanti b, Albert Moyano a and Ramon Rios a,c * Supporting Information NMR spectra and HPLC traces
Copper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2016 Supporting information Copper-Catalyzed Oxidative Dehydrogenative - Bond Formation
Supporting Information
Supporting Information Copper/Silver Cocatalyzed Oxidative Coupling of Vinylarenes with ICH 2 CF 3 or ICH 2 CHF 2 Leading to β-cf 3 /CHF 2 -Substituted Ketones Niannian Yi, Hao Zhang, Chonghui Xu, Wei
Supporting Information
Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General
Supporting Information One-Pot Approach to Chiral Chromenes via Enantioselective Organocatalytic Domino Oxa-Michael-Aldol Reaction
Supporting Information ne-pot Approach to Chiral Chromenes via Enantioselective rganocatalytic Domino xa-michael-aldol Reaction Hao Li, Jian Wang, Timiyin E-Nunu, Liansuo Zu, Wei Jiang, Shaohua Wei, *
Supporting Information
Supporting Information for Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Chun-Huan Jiang, Xiantao Lei,
Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines
![Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines](/thumbs/87/95187440.jpg "Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines")
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines Min Jiang, Ting Li, Linghua Meng, Chunhao Yang,* Yuyuan Xie*, and Jian Ding State Key Laboratory of
Supporting Information for
Supporting Information for An atom-economic route to densely functionalized thiophenes via base-catalyzed rearrangement of 5-propargyl-2H-thiopyran-4(3H)-ones Chunlin Tang a, Jian Qin b, Xingqi Li *a a
Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3
Supporting Information Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Shohei Shimokawa, Yuhsuke Kawagoe, Katsuhiko Moriyama, Hideo Togo* Graduate
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization
Facile construction of the functionalized 4H-chromene via tandem. benzylation and cyclization. Jinmin Fan and Zhiyong Wang*
Facile construction of the functionalized 4H-chromene via tandem benzylation and cyclization Jinmin Fan and Zhiyong Wang* Hefei National Laboratory for Physical Science at Microscale, Joint- Lab of Green
Supporting Information
Supporting Information Ceric Ammonium Nitrate (CAN) catalyzed efficient one-pot three component aza-diels-alder reactions for a facile synthesis of tetrahydropyranoquinoline derivatives Ravinder Goud Puligoundla
Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:
Electronic Supplementary Information
Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan
Supporting Information. Asymmetric Binary-acid Catalysis with Chiral. Phosphoric Acid and MgF 2 : Catalytic
Supporting Information Asymmetric Binary-acid Catalysis with Chiral Phosphoric Acid and MgF 2 : Catalytic Enantioselective Friedel-Crafts Reactions of β,γ- Unsaturated-α-Ketoesters Jian Lv, Xin Li, Long
Supporting Information
Supporting Information for AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds Qiuping Ding 1, Dan Wang 1, Puying Luo* 2, Meiling Liu 1, Shouzhi Pu* 3 and
Supporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Anhydrous solvents were transferred by
Supporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process
Supporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process Jincan Zhao 1, Hong Fang 1, Jianlin Han* 1,2 and Yi Pan* 1
Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information
![Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information](/thumbs/64/50937700.jpg "Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information")
Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans Liang Yun, Shi Tang, Xu-Dong Zhang, Li-Qiu Mao, Ye-Xiang Xie and Jin-Heng Li* Key Laboratory
Eco-friendly synthesis of diverse and valuable 2-pyridones by catalyst- and solvent-free thermal multicomponent domino reaction
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 SUPPRTIG IFRMATI Eco-friendly synthesis of diverse and valuable 2-pyridones by catalyst-
Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes
Supporting Information for Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes Changkun Li and Jianbo Wang* Beijing National Laboratory
Hiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl
Hiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl Philippe Pierrat, Philippe Gros* and Yves Fort Synthèse Organométallique
Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran
1 Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran Munawar Hussain, a Rasheed Ahmad Khera, a Nguyen Thai Hung, a Peter Langer* a,b a Institut für Chemie, Universität Rostock,
Enantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Enantioselective Organocatalytic Michael Addition of Isorhodanines to α,
Supporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Proton nuclear magnetic resonance ( 1
Divergent synthesis of various iminocyclitols from D-ribose
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 205 Divergent synthesis of various iminocyclitols from D-ribose Ramu Petakamsetty,
Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone.
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone. Won-Suk Kim, Hyung-Jin Kim and Cheon-Gyu Cho Department of Chemistry, Hanyang University, Seoul 133-791, Korea Experimental Section
Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2006
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2006 1 A Facile Way to Synthesize 2H-Chromenes: Reconsideration of the Reaction Mechanism between Salicylic Aldehyde and
and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol
FeCl 3 6H 2 O-Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol Jialiang Wang, Wen Huang, Zhengxing Zhang, Xu
Vilsmeier Haack reagent-promoted formyloxylation of α-chloro-narylacetamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Vilsmeier aack reagent-promoted formyloxylation of α-chloro-arylacetamides by formamide Jiann-Jyh
Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate
upporting Information Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate Jing-Yu Wu, Zhi-Bin Luo, Li-Xin Dai and Xue-Long Hou* a tate Key Laboratory of Organometallic
The Free Internet Journal for Organic Chemistry
The Free Internet Journal for Organic Chemistry Paper Archive for Organic Chemistry Arkivoc 2018, part iii, S1-S6 Synthesis of dihydropyranones and dihydropyrano[2,3- d][1,3]dioxine-diones by cyclization
First DMAP-mediated direct conversion of Morita Baylis. Hillman alcohols into γ-ketoallylphosphonates: Synthesis of
Supporting Information File 1 for First DMAP-mediated direct conversion of Morita Baylis Hillman alcohols into γ-ketoallylphosphonates: Synthesis of γ-aminoallylphosphonates Marwa Ayadi 1,2, Haitham Elleuch
Supporting information
Electronic upplementary Material (EI) for New Journal of Chemistry. This journal is The Royal ociety of Chemistry and the Centre National de la Recherche cientifique 7 upporting information Lipase catalyzed,-addition
Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3- Oxyfluorination and 1,3-Difluorination
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supporting Information Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine
Supporting Information
Electronic Supplementary Material (ESI) for rganic Chemistry Frontiers. This journal is the Partner rganisations 2018 Palladium-catalyzed direct approach to α-cf 3 aryl ketones from arylboronic acids Bo
Supporting information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting information Copper-catalysed intramolecular O-arylation: a simple
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Silver or Cerium-Promoted Free Radical Cascade Difunctionalization
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A. new Entry to N-Carbamate Protected Arylamines
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A new Entry to N-Carbamate Protected Arylamines Bing Zhou,* Juanjuan Du, Yaxi Yang,* Huijin Feng, Yuanchao Li Shanghai Institute of Materia Medica,
Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of. 1,2,3-Triazole Synthesis
Supporting Information for: Intramolecular Hydrogen Bonding-Assisted Cyclocondensation of α-diazoketones with Various Amines: A Strategy for Catalytic Wolff 1,2,3-Triazole Synthesis Zikun Wang, a Xihe
Aminofluorination of Fluorinated Alkenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Synthesis of ɑ CF 3 and ɑ CF 2 H Amines via Aminofluorination of Fluorinated Alkenes Ling Yang,
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols. Support Information
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols Dr. Xiao un Tang and Prof. Qing un Chen* Key Laboratory of Organofluorine Chemistry,
Supporting Information
Supporting Information Regioselective Reversal in the Cyclization of 2-Diazo-3,5-dioxo-6-ynoates (ynones, ynamide): Construction of -Pyrones and 3(2H)-Furanones Starting from Identical Materials Feng Wang,
Electronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Electronic Supplementary Information (ESI) For Iron-Catalysed xidative Amidation of Alcohols with Amines Silvia Gaspa, a Andrea
Free Radical Initiated Coupling Reaction of Alcohols and. Alkynes: not C-O but C-C Bond Formation. Context. General information 2. Typical procedure 2
Free Radical Initiated Coupling Reaction of Alcohols and Alkynes: not C-O but C-C Bond Formation Zhongquan Liu,* Liang Sun, Jianguo Wang, Jie Han, Yankai Zhao, Bo Zhou Institute of Organic Chemistry, Gannan
Experimental procedure
Supporting Information for Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide Sébastien Alazet 1,2, Kevin Ollivier 1 and Thierry Billard* 1,2 Address: 1 Institute
Supporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds
Supporting Information for Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds Zhongxue Fang, a Yongquan Ning, a Pengbing Mi, a Peiqiu Liao, a Xihe Bi* a,b a Department of Chemistry,
The N,S-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H. Carbonylation using Langlois Reagent as CO Source. Supporting Information.
Electronic upplementary Material (EI) for rganic & Biomolecular Chemistry. This journal is The Royal ociety of Chemistry 2018 The,-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H Carbonylation using
Supporting Information
Supporting Information An Approach to 3,6-Disubstituted 2,5-Dioxybenzoquinones via Two Sequential Suzuki Couplings. Three-step Synthesis of Leucomelone Xianwen Gan, Wei Jiang, Wei Wang,,,* Lihong Hu,,*
Supporting Information. Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles
Supporting Information for Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles Angélica de Fátima S. Barreto*, Veronica Alves dos Santos, and Carlos
Room Temperature Highly Diastereoselective Zn-Mediated. Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled
Supporting Information for: Room Temperature Highly Diastereoselective Zn-Mediated Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled Stereoselectivity Reversal
multicomponent synthesis of 5-amino-4-
Supporting Informartion for Molecular iodine-catalyzed one-pot multicomponent synthesis of 5-amino-4- (arylselanyl)-1h-pyrazoles Camila S. Pires 1, Daniela H. de Oliveira 1, Maria R. B. Pontel 1, Jean
Ligand-free Cu(II)-mediated aerobic oxidations of aldehyde. hydrazones leading to N,N -diacylhydrazines and 1,3,4-oxadiazoles
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Ligand-free Cu(II)-mediated aerobic oxidations of aldehyde hydrazones leading
Supporting Information for Synthesis of Fused N-Heterocycles via Tandem C-H Activation
This journal is The Royal Society of Chemistry 212 Supporting Information for Synthesis of Fused -Heterocycles via Tandem C-H Activation Ge Meng, Hong-Ying iu, Gui-Rong Qu, John S. Fossey, Jian-Ping Li,*
Rhodium-Catalyzed Oxidative Decarbonylative Heck-type Coupling of Aromatic Aldehydes with Terminal Alkenes
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Rhodium-Catalyzed Oxidative Decarbonylative Heck-type
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%. S1 Supplementary Figure S2. Single X-ray structure 5a at probability ellipsoids of 20%. S2 H 15 Ph Ac Ac I AcH Ph Ac
Supporting information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 204 Supporting information Palladium nanoparticles supported on triazine functionalised mesoporous
ESI for. A simple and efficient protocol for the palladium-catalyzed. ligand-free Suzuki reaction at room temperature in aqueous DMF.
ESI for A simple and efficient protocol for the palladium-catalyzed ligand-free Suzuki reaction at room temperature in aqueous DMF Chun Liu,* Qijian i, Fanying Bao and Jieshan Qiu State Key Laboratory
Zuxiao Zhang, Xiaojun Tang and William R. Dolbier, Jr.* Department of Chemistry, University of Florida, Gainesville, FL
Photoredox-Catalyzed Intramolecular Difluoromethylation of -Benzylacrylamides Coupled with a Dearomatizing Spirocyclization: Access to CF2H Containing 2- Azaspiro[4.5]deca-6,9-diene-3,8-diones. Zuxiao
Supporting Information
Supporting Information Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao
9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer
Supporting Information
Supporting Information Metal-catalyzed Stereoselective and Protecting-group-free Synthesis of 1,2-cis-Glycosides Using 4,6-Dimethoxy-1,3,5-triazin-2-yl Glycosides as Glycosyl Donors Tomonari Tanaka,* 1
Supporting Information
Supporting Information Wiley-VC 007 9 Weinheim, Germany ew ear Infrared Dyes and Fluorophores Based on Diketopyrrolopyrroles Dipl.-Chem. Georg M. Fischer, Dipl.-Chem. Andreas P. Ehlers, Prof. Dr. Andreas
Supporting Information
Supporting Information Gold-catalyzed Cycloisomerization of 1,6-Diyne-4-en-3-ols to form Naphthyl Ketone Derivatives. Jian-Jou Lian and Rai-Shung Liu* Department of Chemistry, National Tsing-Hua University,
Supporting Information
Supporting Information Lewis Acid Mediated [2,3]-Sigmatropic Rearrangement of Allylic α-amino Amides. Jan Blid, Peter Brandt, Peter Somfai*, Department of Chemistry, rganic Chemistry, Royal Institute of
Supporting Information
Supporting Information Transition-metal-free Ring Expansion Reactions of Indene-1,3-dione: Synthesis of Functionalized Benzoannulated Seven-Membered Ring Compounds Qiyi Yao, Lingkai Kong, Mengdan Wang,
Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-
Supporting Information for A catalyst-free multicomponent domino sequence for the diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- (arylamino)allyl]chromen-4-ones Pitchaimani Prasanna 1, Pethaiah
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Facile diverted synthesis of pyrrolidinyl triazoles
Supplementary Information for
Supplementary Information for Organocatalytic Asymmetric Intramolecular [3+2] Cycloaddition: A Straightforward Approach to Access Multiply Substituted Hexahydrochromeno[4,3-b]pyrrolidine Derivatives in
Supporting Information for
Supporting Information for A ovel Synthesis of luorinated Pyrazoles via Gold(I)-Catalyzed Tandem Aminofluorination of Alkynes in the Presence of Selectfluor Jianqiang Qian, Yunkui Liu,* Jie Zhu, Bo Jiang,
Supplementary information
Electronic Supplementary Material (ESI) for MedChemComm. This journal is The Royal Society of Chemistry 2015 Supplementary information Synthesis of carboxyimidamide-substituted benzo[c][1,2,5]oxadiazoles
Supporting Information
Supporting Information Wiley-VCH 2014 69451 Weinheim, Germany Copper-Catalyzed Coupling of Oxime Acetates with Sodium Sulfinates: An Efficient Synthesis of Sulfone Derivatives** Xiaodong Tang, Liangbin
SUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 SUPPORTIG IFORMATIO Visible light-mediated decarboxylative amination of indoline-2- carboxylic
Supporting Information. Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors
Supporting Information Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors Frédéric Pin, a Frédéric Buron, a Fabienne Saab, a Lionel Colliandre,
gem-dichloroalkenes for the Construction of 3-Arylchromones
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Pd(OAc)2/S=PPh3 Accelerated Activation of gem-dichloroalkenes for the Construction of 3-Arylchromones
Oxyhalogenation of thiols and disulfides into sulfonyl chlorides/ bromides in water using oxone-kx(x= Cl or Br)
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Oxyhalogenation of thiols and disulfides into sulfonyl chlorides/ bromides in water using
Synthesis of novel 1,2,3-triazolyl derivatives of pregnane, androstane and D-homoandrostane. Tandem Click reaction/cu-catalyzed D-homo rearrangement
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of novel 1,2,3-triazolyl derivatives of
Supporting Information. Microwave-assisted construction of triazole-linked amino acid - glucoside conjugates as novel PTP1B inhibitors
Supporting Information Microwave-assisted construction of triazole-linked amino acid - glucoside conjugates as novel PTP1B inhibitors Xiao-Peng He, abd Cui Li, d Xiao-Ping Jin, b Zhuo Song, b Hai-Lin Zhang,
Supporting Information for
Supporting Information for Palladium-Catalyzed C-H Bond Functionalization of C6-Arylpurines Hai-Ming Guo,* Wei-Hao Rao, Hong-Ying iu, Li-Li Jiang, Ge ng, Jia-Jia Jin, Xi-ing Yang, and Gui-Rong Qu* College
Cu-Catalyzed/Mediated Synthesis of N-Fluoroalkylanilines from Arylboronic Acids: Fluorine Effect on the Reactivity of Fluoroalkylamines
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 S1 Cu-Catalyzed/Mediated Synthesis of N-Fluoroalkylanilines from Arylboronic
Supporting Information
Electronic upplementary Material (EI) for Green Chemistry. This journal is The Royal ociety of Chemistry 204 upporting Information ynthesis of sulfonamides via I 2 -mediated reaction of sodium sulfinates
Supporting Information. Table of Contents. II. Experimental procedures. II. Copies of 1H and 13C NMR spectra for all compounds
Electronic upplementary Material (EI) for rganic & Biomolecular Chemistry. This journal is The Royal ociety of Chemistry 2017 Laboratoire de Méthodologie et ynthèse de Produit aturels. Université du Québec
SUPPORTING INFORMATION. Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts
S1 SUPPORTING INFORMATION Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts Hao Yu, Zhen Li, and Carsten Bolm* Institute of Organic Chemistry, RWTH Aachen University
Supporting Information
Supporting Information Selective Synthesis of xygen-containing Heterocycles via Tandem Reactions of 1,2-Allenic Ketones with Ethyl 4-Chloroacetoacetate Qiang Wang, a, b Zhouqing Xu b and Xuesen Fan a *
D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical and experimental study
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical
Kishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng Wu*
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 204 Kishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng
Copper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds. in Aromatic Amides
Supporting Information for Copper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds in Aromatic Amides Feifan Wang, Qiyan Hu, Chao Shu, Zhiyang Lin, Dewen Min, Tianchao Shi and Wu Zhang* Key Laboratory
Chiral Brønsted Acid Catalyzed Enantioselective Intermolecular Allylic Aminations. Minyang Zhuang and Haifeng Du*
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Chiral Brønsted Acid Catalyzed Enantioselective Intermolecular Allylic
Supporting Information
1 upporting Information Rhodium(III)-Catalyzed rtho Halogenations of N-Acylsulfoximines and ynthetic Applications toward Functionalized ulfoximine Derivatives Ying Cheng, Wanrong Dong, Kanniyappan Parthasarathy,
SUPPORTING INFORMATION. 1. General... S1. 2. General procedure for the synthesis of compounds 3 and 4 in the absence of AgOAc...
SUPPORTING INFORMATION Table of contents 1. General.... S1 2. General procedure for the synthesis of compounds 3 and 4 in the absence of AgOAc... S2 3. General procedure for the synthesis of compounds
Synthesis and evaluation of novel aza-caged Garcinia xanthones
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Synthesis and evaluation of novel aza-caged Garcinia xanthones Xiaojin Zhang, a,1 Xiang Li, a,1 Haopeng Sun, * b Zhengyu Jiang,
A straightforward metal-free synthesis of 2-substituted thiazolines in air
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Supporting Information for A straightforward metal-free synthesis of 2-substituted thiazolines
Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes
![Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes](/thumbs/61/45469742.jpg "Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes")
Supporting Information for Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes Yibiao Li* 1, Liang Cheng 1, Xiaohang Liu
Selective mono reduction of bisphosphine
Griffith Research Online https://research-repository.griffith.edu.au Selective mono reduction of bisphosphine oxides under mild conditions Author etersson, Maria, Loughlin, Wendy, Jenkins, Ian ublished
Construction of Cyclic Sulfamidates Bearing Two gem-diaryl Stereocenters through a Rhodium-Catalyzed Stepwise Asymmetric Arylation Protocol
Supporting Information for: Construction of Cyclic Sulfamidates Bearing Two gem-diaryl Stereocenters through a Rhodium-Catalyzed Stepwise Asymmetric Arylation Protocol Yu-Fang Zhang, Diao Chen, Wen-Wen
Supplementary!Information!
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015! Synthesis)and)characterisation)of)an)open1cage) fullerene)encapsulating)hydrogen)fluoride! Supplementary!Information!