: (2000) , ) :, 108 : O Thomson 30, ] ICP - AES. Rayligh 27 MHz 40 MHz Ar ICP ICP - AES.
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- Ἐπαφρόδιτος Αναστασιάδης
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1 ROCK AND MIN ERAL ANAL YSIS Vol. 19,No. 1 March,2000 : (2000) , (,430074) :, 108 : ; : O : A 30, Thomson T e n e ( AES) [6 ], Thomson Rayligh 27 MHz 40 MHz Ar [7 ICP ( T g ) T exc T e n ] [8 e ] AES Ar - ICP n e T e, ICP 1 ICP AES ICP, - ICP ICP n e T e, ICP ICP ( T) ( n e ) ICP L TE ( T e > ( T ion > T exc > T g ) ) L TE (Saha Boltzmam [1 ] [9,10, : ) ] ICP ( ( T exc ) [2,3 ], ), Ar - ICP n e ( ) [4 ],, L TE (L TE), ( PL TE) [11,12 ],Blades, [13 ] Sr Ca Mg Cd Zn [12 T exe n e H ICP L TE b ] r nm Ar Stark n e,, Saha exp L TE L TE, ICP [14 T e (L TE), PL TE ] L TE, [15, HAr Stark n e [13 ] ] [5, ] exp L TE, ICP : ; : : ( ),,,, 32
![( T) ( n e ) ICP L TE ( T e > ( T ion > T exc > T g ) ) L TE (Saha Boltzmam [1 ] [9,10, : ) ] ICP ( ( T exc ) [2,3 ], ), Ar - ICP n e ( ) [4 ],, L TE (L TE), ( PL TE) [11,12](/docs-images/45/23279431/images/page_1.jpg "],Blades, [13 ] Sr Ca Mg Cd Zn [12 T exe n e H486.")
2 1 : 19 [16 L TE ] Monte Carlo, AES ICP, [17 -, ] AES [34, AES ] Karen [18 ] [35 ], Gaussian Lorentziam, Dubuisson [19 ],, AES Gaussian [20 ] t lg ( I x / I x ) Lorentziam,, AES [21 ] K, Na La Y Mg 17, [22 ], AES,, ICP AES,, [23 ] AES [36 AES ] [24 ] [37 ICP - ] [38 Kalman ] [39 AES, Kalman ] [40 ] Kalman [41 Ca Mg Al L TE non - L TE Kalman ],L TE,non - L TE,, AES,, Boumans [25 ],, [26 ] ( ) [27 ] [28 ], [29 ],,, Saxbery [30 ], [31 ] -,,,, [32 ], Kalman AES, AES,,, [33 ],,,,,, 33
![AES ] [24 ] [37 ICP - ] [38 Kalman ] [39 AES, Kalman ] [40 ] Kalman [41 Ca Mg Al L TE non - L TE Kalman ],L TE,non - L](/docs-images/45/23279431/images/page_2.jpg "TE,, AES,, Boumans [25 ],, [26 ] ( ) [27 ] [28 ], [29 ],,, Saxbery [30 ], [31 ] -,,,, [32 ], Kalman AES, AES,,, [33")
3 1 19, 65,,, Boumans [42 ] : AES,,,/, AES,, Leeman Labs Jobin Yvon, Spectro Analytial, ICP WL Y ICP Υ WL SI - ICP 2 ς 90, ICP,,, ( PM T) AES,,, 2, Shimaozu ICPS Ο Jobin Yvon J Y ICP, 56, Π Therme Jarrell - Ash Trace Scan, Advantage TM Θ, Ρ, ICP, 70, ( PDA),,,,,, ICP [43 ] 80 L EECO Hilger E984C ICP Σ Jobin Plasmarray ICP PDA Yvon J Y48 ICP Τ [44 ] PDA -, AES Ο Π Θ Ρ Σ Τ Υ ς 34 ICPS ICP.. Jobin Yvon. J Y ICP... Trace Scan Advantage TM.. Jobin Yvon. J Y Ultima.. Hilger. E984C ICP.. Jobin Yvon. J Y48 ICP... WL Y ICP... WL SI - DICP..
![[43 ] 80 L EECO Hilger E984C ICP Σ Jobin Plasmarray ICP PDA Yvon J Y48 ICP Τ [44 ] PDA -, AES Ο Π Θ Ρ Σ Τ Υ ς 34 ICPS - 7500 ICP.. Jobin Yvon.](/docs-images/45/23279431/images/page_3.jpg "J Y - 138 ICP... Trace Scan Advantage TM.. Jobin Yvon. J Y Ultima.. Hilger. E984C ICP.. Jobin Yvon. J Y48 ICP... WL Y 100 - ICP... WL SI - DICP.")
4 1 : 19 (CTDs) [49 ] AES WP500-2A,, ( CCD) nm (CID) nm,, 3 ICP,,, [45 ] [46 ] CTDs, CCD CID, ICP, CID Mora [50 ] AES CCD, [51 ] CID,CID AES, TJA,23, 1/ 5 IRIS AP ICP Ο CID [52 1/ 20 ] PTFE,CID 26, 26 V,,, [53 ] V, 12 min Cameron [54 ] ICP AES ICP, mg/ L - 12,,,, J Y IMA GE Navigator, Fraucesco [55 ] ICP, : [56 ] [57 ],,2 min 23,, Peter [58 ],, /,, - AES, AES H 2 ICP [47 ] [59 ] Ar Stark CCD - OES ICP [48 ] AES, Ο TJ Y. IRIS AP ICP.. 35
![min Cameron [54 ] ICP AES ICP, 1 000 mg/ L - 12,,,, J Y IMA GE Navigator, Fraucesco [55 ] ICP, : [56 ] [57 ],,2](/docs-images/45/23279431/images/page_4.jpg "min 23,, Peter [58 ],, /,, - AES, AES H 2 ICP [47 ] [59 ] Ar Stark CCD - OES ICP [48 ] AES, Ο TJ Y. IRIS AP ICP.")
5 1 19,n e T e T exc, AES,,, [60, ] [61 ] [62 ] [63 ] 10-9 [64 ] 10-6 s, ETV Holak [65 ],,,,, NaBH 4 ( Gagean [72 ] KBH 4 ), AES Kennet h [66 ] [73 ] AES,, [67 ] [ 68 ] As Sb Bi, AES 10 ( ETAAS), ( ETV),,, ETV,,, ETV [69 ],, ICP (, [70 ) ], U Zr Ti Vahid [74 ] [75 ] AES [76 ] J T - V,, AES 11 ;, AES,,, [77 ] - ( AES [78 ) ], [79 ] [80 ] [81 ] [82 ] AES [71 ] AES, Ambrose AES,, 36
![ETAAS), ( ETV),,, ETV,,, ETV [69 ],, ICP (, [70 ) ], U Zr Ti Vahid [74 ] [75 ] AES [76 ] J T -](/docs-images/45/23279431/images/page_5.jpg "V,, AES 11 ;, AES,,, [77 ] - ( AES [78 ) ], [79 ] [80 ] [81 ] [82 ] AES [71 ] AES, Ambrose")
6 1 : 19 AES, Cu Fe Ca Ni (LC) AES,, [102 ] 200 YPA 4, [83 AES ] 1. 0 mol/ L HCl, Pt Pd ( HPLC) - AES Os,,ETV - [84,85 ] AES [ 103 ] -,HPLC - AES - ( M G) (CE) - AES, Pt Pd Rh Ir Au As AES Au 4 Pt Pd AES, [86, ] [87 ] [88 ] [89 ] [90 ] [91 ] (M IP - AES) [92 ] [93 ] [94 ] [95 ], AES [96 ], ICP Yamada [105 ] AES, AES [106 ( MS) ] [97 ],, ICP, AES [107 - AES 15, Mn ] NaNO 2 H 2 O 2 [98 ] Fe,, I - AES CeO 2, AES La Pr Nd Sn Gd Y, HNO 3, AES H 2 O 2,8 mol/ L HNO 3,, [108 ] Ce ( ) Ce ( ), P 204 / CCl 4 Ce ( ), La Pr Nd Y Ce ( ) 5,, 6 [1 ]. mol/ L HCl, HCl ICP [ M ]. :, ,CeO 2 [ 2 ] Uchida H, Kiyoshi Tanabe, Yukihiro Nojiri,et al. Spatial [99 ] Distribution of Metastable Argon, Temperature and Elec2 tron Number Density in an Inductively Coupled Argon AES Ho Dy Sm Y La Eu p H = 3,PMBP/, mol/ L HCl [100 ] D 238 AES 40B : [ 5 ] Raaijmakers I J M M, Mboumans P W, Der Sude, et al. 4N Cu Fe Ni Pb A Theoretical and Experimental Investigation of Non - 6 mol/ L HCl, 8 ml, p H 4, D 238, 6 mol/ L HNO 3,,2 mol/ L [104 AES ] Plasma[J ]. S pect rochimica Acta. 1981,36B :711. [3 ]. AES [J ] ,7 (3) :143. Ca Mg Fe Zn [4 ] Caughlin B L, Blades M W. Analyte Ionization in Induc2 tively Coupled Plasma [J ]. S pect rochimica Acta. 1985, L TE Phenomena in an Inductively Coupled Argon Plas2 ma. Characterization of the Discharge[J ]. S pec2 t rochimica Acta. 1983,38B :697. HNO 3, AES [ 101 ][6 ] Huang Mao, Grary Hieftji. A New Procedure for Deter2 37
![[94 ] [95 ], AES [96 ], ICP Yamada [105 ] AES, AES [106 ( MS) ] [97 ],, ICP, AES [107 - AES 15, Mn ] NaNO 2 H 2 O 2 [98 ] Fe,, I - AES CeO 2, AES La Pr Nd Sn Gd Y, HNO 3, AES H 2 O 2,8 mol/ L HNO 3,,](/docs-images/45/23279431/images/page_6.jpg "[108 ] Ce ( ) Ce ( ), P 204 / CCl 4 Ce ( ), La Pr Nd Y Ce ( ) 5,, 6 [1 ]. mol/ L HCl, HCl ICP [ M ]. :,1987. 3444.,CeO 2 [ 2 ] Uchida H, Kiyoshi Tanabe, Yukihiro Nojiri,et al.")
7 1 19 mination of Electron Temperature and Electron Concen2 trations by Thomson Scattering from Analytical Plasmas [J ]. S pect rochimica Acta. 1989,44B :291. [7 ] Huang Mao, Grary Hieftji. Simultaneous Measurement of Spatially Resolved Electron Temperatures, Electron Number Densities and Gas Temperatures by Laser Light Scattering from the ICP [ J ]. S pect rochimica Acta. 1989, 44B :739. [8 ],, , 18 (10) :902. [J ]. [22 ],,. AES. 1990,18 (4) :339. [9 ] Mermet J M. Ionic to Atomic Line Intensity Ratio and Residence Time in Inductively Coupled Plasma - Atomic Emission Spectrometry[J ]. S pect rochimica Acta. 1989, 44B : [10 ] Blades M W. Some Considerations Regarding Tempera2 ture, Electron Density and Ionization in the Argon In2 ductively Coupled Plasma [ J ]. 1982, 37B :869. S pect rochimica Acta. [11 ] Walker Z, Blades M W. Measurement of Excited State Level Population for Atomic and Ionic Iron in the Induc2 tively Coupled Plasma[J ]. S pect rochimica Acta. 1986, 41B :761. [12 ] Van der Mullen J A M, Laaijmakurs I J M, Van Lam2 meren A C A P, et al. On the Charge Transfer in an In2 ductively Coupled Argon Plasma [ J ]. Acta. 1987,42B :1039. S pect rochimica [ 13 ] Blades M W, Caughlin B L, Walker Z H, et al. Excita2 tion, Ionization and Spectral Line Emission in the In2 ductively Coupled Plasma[J ]. A nalyt S pect rosc. 1987, 10B :57. [14 ],,. Ar - ICP [29 ],,,. [J ]. AES [J ] ,16 (2) :16. [15 ],,,. AES [30 ] Saxbery B E H, Kowalski B R. Correction of Interfer2 [J ]. ences in Inductively Coupled Plasma Atomic Emission. 1991, 12 (8) : [16 ],. Monte Carlo AES. [J ]. [31 ],,, ,16 (1) :73. [17 ]. [ M ]. :, [18 ] Karen Hanlon O, Les Ebdon, Michael Foulkes. Effect of Easily Ionisable Elements on the Mass Transport Effi2 ciency of Solution and Slurries Used in Plasma Emission Spectrometry[J ]. J A nal A tom S pect romet ry. 1997, 12B :329. [19 ] Dubuisson C, Emmaanuelle Poussel, Jeanmichel Mer2 38 met. Comparison of Axially and Radically Viewed In2 ductively Coupled Plasma Atomic Emission Spectrometry in Terms of Signal - to - background Ratio and Matrix Effects[J ]. J A nal A tom S pect romet ry. 1997, 12B : 281. [20 ],. [J ] , 18 (12) : [21 ],. [J ]. [J ] ,8 (4) : 25. [23 ],,,.. [J ] ,26 (3) :317. [24 ],,,. AES [J ] ,16 (1) : 67. [ 25 ] Boumans P W J M. Corrections for Spectral Interference in Optical Emission Spectrometry with Special Reference to the RF Inductively Coupled Plasma[J ]. S pect rochim Acta. 1976,31B :147. [26 ],. AES [J ] ,14 (9) :703. [27 ] Hassan S M, Nich T Loux. Elimination of Spectral In2 terference in Inductively Coupled Plasma Atomic Emis2 sion Spectroscopy Using Orthogonal Polynomials [ J ]. S pect rochim Acta. 1990,45B :719. [28 ],,. AES [J ] , 9 (10) : ,18 (3) :329. Spectrometry by Generalized Standard Addition Method [J ]. A nal Chem. 1979,51 :1031. [J ] ,6 (2) :35. [32 ] Yang Jin2fu, Piao Zhe2xiu, Zeng Xian2jin. Improve2 ment of Selectivity with Numeral Derivative Technique in Inductively Coupled Plasma Atomic Emission Spec2 trometry[j ]. S pect rochim Acta. 1991,46B :953. [33 ],,. AES [J ] ,11 (4) :55. [34 ],. AES [J ] ,11 (1) :33.
![1989, 44B :739. [8 ],,.. 1990, 18 (10) :902. [J ]. [22 ],,. AES. 1990,18 (4) :339. [9 ] Mermet J M.](/docs-images/45/23279431/images/page_7.jpg "Ionic to Atomic Line Intensity Ratio and Residence Time in Inductively Coupled Plasma - Atomic Emission Spectrometry[J ]. S pect rochimica Acta. 1989, 44B : 1116. [10 ] Blades M W.")
8 1 : 19 [35 ],. AES ma Atomic Emission Spectrometry : Low - pressure Ver2 [J ] ,10 (3) :72. [36 ] Zhang Zhuo2yong, Piao Zhe2xiu, Zeng Xian2jin. Appli2 cation of Factor Analysis to Correction of Spectral Over2 lap Interference in Inductively Coupled Plasma Atomic Emission Spectrometry [ J ]. S pect rochim Acta. 1993, 48B :403. [37 ],,. [J ] ,4 :26. AES [J ] , [53 ],. AES 17 (5) : 77. [38 ] Van Veen E H, De Loos Velletregt M T C. Kalman Filtering of Data from Overlapping Lines in Inductively Coupled Plasma Atomic Emission Spectrometry [ J ]. S pect rochim Acta. 1990,45B :313. [39 ],,. A nal A t S pect rom. 1997,12 :725. [J ]. [ 55 ] Fraucesco P, Potrucci, Delle Feemmire, et al. A Simple. 1993, 21 (10) :1175. [40 ],,. ICP Microchim Acta. 1989, (1/ 2) :57. - AES [J ] ,16 [ 56 ] He Zhi2zhuang, Ramon M Barnes. Recycling Rebulizing (4) :45. [41 ],. - Kalman AES [J ] ,40B : , 16 (2) : 43. [ 42 ] Boumans P W J M. Some Recent Studies of Inductively Coupled Plasmas Involving the Measurement of Use of Physical Line Widths a Tutorial Discussion with Retro2 spects and Extensions [ J ]. S pect rochim Acta. 1989, 44B :1325. [ 43 ] Me George S M,Salin E P. Image Sensor Application in Analytical Atomic Spectrometry [J ]. t rosc. 1981,7 :387. Prog A nal S pec2 [44 ],,,. New Rebulizer - Hydride Generator System for Simulta2 [J ].. neous Multielement Inductively Coupled Plasma Atomic 1990, (4) :7. [45 ],,. 42B : 129. [J ] ,23 (8) : 960. [46 ],. (CTDs) Antimony, Bismuth, Selenium and Tellurium in Queues ( ) [J ] ,14 (5) :80. [47 ],,. CCD - OES [A ]. trometry[j ]. A nalyst. 1978,103 :568. [ C] ,40. [48 ],,,. AES [J ]. Generation : Application to On - Line Pre - reduction of. 1993,14 (11) :1506. [49 ],,,. AES [J ] ,31 (1) :71. [50 ] Mora J, Todoli J L, Canals A, et al. Comparative Study of Several Nebuliaers in Inductively Coupled Plas2 sus High - pressure Nebulization [J ]. J A nal A t S pec2 t rom. 1997, 12 :445. [51 ],,. [J ] ,18 (12) :1939. [52 ],. J T - V [J ] ,14 (5) :65. [54 ] Cameron D S, Eric D Salin. Axial Viewing and Modi2 fied Cup Desing for Direct Sample Insertion Inductively Coupled Plasma Atomic Emission Spectrometry [ J ]. Nebulization Reflux System for Use in AES[J ]. System for Milliliter Volume Samples with Inductively Coupled Plasma Spectrometry [ J ]. S pect rochim Acta. [57 ],,. AES [J ] ,13 (4) :49. [ 58 ] Peter A Vieira, He Zhi2zhuang, Chan Shi2kit, et al. E2 valuation of Recycling Cyclone Spray Chambers for ICP - AES[J ]. A ppl S pect rosc. 1986,40B :1141. [59 ],,,. AES [A ]. [ C] ,69. [60 ] Huang Ben2li, Zhang Zhuo2yong, Zeng Xian2jin. A Emission Spectrometry [ J ]. S pect rochim Acta. 1987, [61 ] Thompson M, Pahlavanpour B, Walter S J. Simultane2 ous Determination of Trace Concentrations of Arsenic, Solution by Introduction of the Gaseous Hydrides into an Inductively Coupled Plasma Source for Emission Spec2 [62 ] Brindie I D, Hosen Alarabi, Samir Karshman, et al. Combined Generator/ Separator for Continuous Hydride Arsenic( ) and Determination of Arsenic in Water by Atomic Emission Spectrometry [ J ]. A nalyst. 1992, 117 :407. [63 ] Garaia A M, Uria J E S, A Sanz - Medel. Determina2 tion of Arsenic in an Organic Phase by Coupling Contin2 uous Flow Extraction - hydride Generation with Induc2 39 J
![. 1992,4 :26. AES [J ].. 1997, [53 ],. AES 17 (5) : 77. [38 ] Van Veen E H, De Loos Velletregt M T C.](/docs-images/45/23279431/images/page_8.jpg "Kalman Filtering of Data from Overlapping Lines in Inductively Coupled Plasma Atomic Emission Spectrometry [ J ]. S pect rochim Acta. 1990,45B :313. [39 ],,. A nal A t S pect rom. 1997,12 :725. [J ].")
9 1 19 tively Coupled Plasma Atomic Emission Spectrometry [J ]. J A nal A t S pect romet ry. 1989,4 :581. [64 ] Cave M R, Green K. Feasibility Study of the Determi2 nation of Iodide, Tin, Arsenic, Selenium and Hydrogen Carbonation in Groundwater by Inductively Coupled Plasma Atomic Emission Spectrometry Using a Mem2 brane Gas - liquid Separator [ J ]. t romt ry. 1989,4 :223. J A nal A t S pec2 [65 ] Holak W. Gas - sampling Technique for Arsenic Deter2 mination by Atomic Absorption Spectrophotometry[J ]. A nal Chem. 1969,40 :1712. [66 ],,. [J ] ,14 (1) :77. [ 67 ] Aznarez J, Palacias F, Ortega M S, et al. Extraction - Atomic - Absorption Spectrophotometic Determination of Antimony by Generation of its Hydride in Non - aqueous Media[J ]. A nalyst. 1984,109 :123. [68 ],,. termination of Selenium in Geochemical Samples by - Flow Injection Hydride Generation Inductively Coupled [J ] ,15 (9) :801. [69 ], Fassel V A. - Line Removal of Iron Interference by Anion Exchange [J ]. [J ]. J A nal A t S pect rom. 1997,12B : ,6 (4) :6. [70 ] Reisch M, Nickel H, Mazarkiewcz M. Volatilization Studies for Fe and Cd in Their Direct Determination by Inductively Coupled Plasmas - Atomic Emission Spec2 trometry Using Direct Sample Insertion or External Electrothermal Evaporation of Powders [ J ]. S pec2 t rochim Acta. 1989,44B :307. [71 ] Marks J Y, Fornwdt D E, Yungle R E. Application of a Solid Sampling Device to the Analysis of High Tem2 perature Alloys by AES[J ]. 1983, 38B :107. S pect rochim Acta. [ 72 ] Gagean N, Mermet J M. Comparison of Ultraviolet Laser Ablation and Spark Ablation of Metals and Alloys for Analysis by Axially Viewed Inductively Coupled Plasma Atomic Emission Spectrometry [J ]. J A nal A t S pect rom. 1997,12 :189. [73 ] Kenneth K K, Chen W T. Novel Sampling Technique for AES[J ]. J A nal A t S pect rom. 1997,12 :7. [74 ] Vahid M, James A H. Error Analysis for Sampling of Slurries Sedimentation Error[J ]. S pect rochimica Acta. 1990, 45B (7) :753. [75 ] Ambrose A J, Ebdon L, Foulkes M E, et al. Direct Atomic Spectrometic Analysis by Slurry Atomization Part 8. Flow Injection Inductively Coupled Plasma Atomic Emission Spectrometry [ J ]. t rom. 1989,4 :219. J A nal A t S pec ,14 (3) :163. [77 ],,. - ICP [J ] ,15 (5) :66. [78 ],,,. / AES [J ] ,12 (3) :198. [79 ]. [J ] ,22 (6) :556. [80 ],,,. [J ] ,23 (11) :1319. [81 ],,. FI - AES [J ] ,11 (1) :58. [ 82 ] Martinez L D, Saidman E S, Marchevsky E, et al. De2 Plasma Atomic Emission Spectrometry Following On - [83 ],,,. - [J ] ,17 (1) :51. [84 ],,. AES [A ]. [ C] ,105. [85 ],, ,18 (3) :165. [86 ],,. / [J ] ,23 (1) :60. [87 ],,,. AES 17 [J ] ,9 (1) : [76 ],,. Drides into an Inductively Coupled Plasma Source for E2 40 [J ]. mission Spectrometry[J ]. A nalyst. 1978,103 : [88 ],,. [J ] ,30 (4) : 213. [89 ] [J ] ,3 (4) : 25. [90 ] Thompson M, Pahlavanpour B, Walton S J, et al. Si2 multaneous Determination of Trace Concentrations of Arsenic, Antimony, Bismuth, Selenium and Tellurium in Aqueous Solution by Introduction of the Gaseous by
![liquid Separator [ J ]. t romt ry. 1989,4 :223. J A nal A t S pec2 [65 ] Holak W. Gas - sampling Technique for Arsenic Deter2 mination by Atomic Absorption Spectrophotometry[J ]. A nal Chem.](/docs-images/45/23279431/images/page_9.jpg "1969,40 :1712. [66 ],,. [J ].. 1994,14 (1) :77. [ 67 ] Aznarez J, Palacias F, Ortega M S, et al.")
10 1 : 19 [91 ],. - AES [J ] , 33 (4) : 419. [92 ],. [J ]. [J ] ,15 (6) :268. [93 ],,,. [102 ],. / [J ] ,5 :39. [94 ],,,. AES [J ] ,13 (6) :18. [95 ],. [ 104 ] Su Zhi2xing, Buo Qiao - sheng, Lao Xing - yin, et al. Ti V Zr Mn Si Fe Mg[J ] ,15 (4) :44. [96 ] Sen Gupta J G. Determination of Barium, Strontium and Nine Minor and Trace Elements in Impure Barite and Strontianite by Inductively Coupled Plasma Atomic Emission Spectrometry after Dissolution in Disodium Ethylendiaminetetraacetate [ J ]. Talanta. 1991, 38 (10) : [97 ],,. trometry[j ]. J A nal A t S pect rom. 1992,7 :661. [J ] , 16 (1) : 28. [98 ],. P ICP/ AES CeO 2 La Pr Nd Sm Gd Y[J ].. [107 ],. 1996, (3) : 63. [99 ],,. PMBP/. 1987,15 (12) :1062. [108 ],. AES [J ] , (1) :33. [100 ]. D 238 AES 4N Cu Fe Ni Pb [ J ] , 11 (3) : 58. [101 ],, , (3) :75. ( ETV) - AES Pt Pd Os [J ] ,16 (4) :5. [103 ],,. [J ] ,15 (5) :63. Application of a Macro Porous Resin Containing Imida2 zolins Groups to Pre - concentration and Separation of Gold, Platinum and Pulleadium Prior to AES Determination[J ]. Talanta. 1995,43 :1127. [105 ] Kci Yamada, Cameron W M, Osamu Kujiral, et al. On Line Enrichment and Determination of Trace Sulfur in High - purity Iron Samples by Flow Injection and Inductively Coupled Plasma Atomic Emission Spec2 [106 ]. - [J ] ,9 (3) :35. AES : [J ]. [J ] ,15 (3) :68. The Development of Inductively Coupled Plasma Atomic Emission Spectrometry YA N G Xiang, J IN Ze2xiang ( Faculty of Material Science and Chemical Engine ering, China University of Geo sciences, Wuhan , China) Abstract : A review on t he develop ment of inductively coupled plasma atomic emission spect romet ry including ba2 sis research, sampling techniques, application and inst rumentation develop ment is presented. 108 references are cited. Key words : inductively coupled plasma atomic emission spect romet ry ; review 41
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