Data Repository. Figure DR1. Seismic reflection profile of Fig. 2 before being depth-converted.

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GSA Data Repository Item 2018298 Lucca, A., Storti, F., Molli, G., Muchez, P., Schito, A., Artoni, A., Balsamo, F., Corrado, S., and Salvioli Mariani, E., 2018, Seismically enhanced hydrothermal plume advection through the process zone of the Compione extensional Fault, Northern Apennines, Italy: GSA Bulletin, https://doi.org/10.1130/b32029.1. Data Repository Figure DR1. Seismic reflection profile of Fig. 2 before being depth-converted. Figure DR2. (A-B) Outcrop pictures of coarse sandstones strata in footwall damage zone Site 5. White dotted lines represent bedding, white lines are conjugate extensional shear veins and fractures with σ 1 orthogonal to bedding, black dashed lines are late-stage extensional shear fractures and red dashed lines indicate strike-slip shear veins and fractures. White arrows indicate pre-bedding rotation kinematics while black arrows indicate kinematics after bedding rotation. (C) Stained hand specimen of footwall fault-related shear vein; black dotted lines separate different opening events. (D) XPL image showing, as in C, multiple openings (separated by white dotted lines), of which some interested by shearing and quartz recrystallization. (E) PPL image of vein showing both MC1A and MC2 replacive calcite crystals along with quartz and rhombohedric MC1A. (F-G-H) CL images showing progressive prehnite dissolution and replacement by MC calcites. Figure DR3. Fluid inclusion assemblage in quartz of footwall damage zone fault-related shear veins showing aqueous inclusion (white), gaseous CH4 inclusions (black) and an inclusion containing liquid H2O and gaseous CH4 (black and white). In (A) at 20 C and in (B) at -100 C.

0 D.P. 800 m a.s.l. (sec. TWT) 1 2 3 5 km Figure S1. Seismic reflection profile of Fig. 2 before being depth-converted CMP 13 20 CMP 12 CMP 11 CMP 10 15 CMP 9 CMP 8 CMP 7 10 CMP 6 CMP 5 CMP 4 5 CMP 3 CMP 2 0 CMP 1 SW NE

NNE SSW A NNE SSW B ed Be dd in g B di ng 1m E D C MC1A rep Qz MC2 rep 1 mm MC1A rep Qz F Qz G Prh 250 µm 5 mm H Qz MC2 rep MC1A rep MC1A rho MC1A rep MC1B rho Prh 250 µm 250 µm Figure S2. (A-B) Outcrop pictures of coarse sandstones strata in footwall damage zone Site 5. White dotted lines represent bedding, white lines are conjugate extensional shear veins and fractures with σ1 orthogonal to bedding, black dashed lines are late-stage extensional shear fractures and red dashed lines indicate strike-slip shear veins and fractures. White arrows indicate pre-bedding rotation kinematics while black arrows indicate kinematics after bedding rotation. (C) Stained hand specimen of footwall fault-related shear vein; black dotted lines separate different opening events. (D) XPL image showing, as in C, multiple openings (separated by white dotted lines), of which some interested by shearing and quartz recrystallization. (E) PPL image of vein showing both MC1A and MC2 replacive calcite crystals along with quartz and rhombohedric MC1A. (F-G-H) CL images showing progressive Prehnite dissolution and replacement by MC calcites.

A T = 20 C B T = -100 C Figure S3. Fluid inclusion assemblage in quartz of footwall damage zone fault-related shear veins showing aqueous inclusion (white), gaseous CH4 inclusions (black) and an inclusion containing liquid H2O and gaseous CH4 (black and white). In (A) at 20 C and in (B) at -100 C.

Structural sites and samples list Coordinates Site N. Sample N. Description Domain Strike Dip Pitch Vein & Fault Samples 44 19'27.39"N 10 3'14.29"E 1 1 Longitudinal antithetic vein-stylolites HW_DZ 355 32 1 2 Longitudinal synthetic vein-stylolites HW_DZ 307 65 44 19'27.77"N 10 3'19.43"E 2 1 Longitudinal synthetic vein-stylolites HW_DZ 320 80 2 2 Fault core calcite concretion HW_DZ 2 3 Obliquely sheared vein HW_DZ 290 50 2 4 Bed parallel vein-stylolites HW_DZ 76 16 2 5 Longitudinal synthetic shear vein HW_DZ 60 23 120 44 19'30.72"N 10 3'21.57"E 3 1A Fault core Breccia HW_FC 3 1B Fault core Breccia HW_FC 3 1C Fault core Breccia HW_FC 3 2 Bed parallel vein-stylolites HW_DZ-FC transition 118 60 3 3 Transversal vein-stylolites HW_DZ-FC transition 196 67 3 4 Fault core calcite concretion HW_DZ-FC transition 126 65 3 5 Transversal vein-stylolites HW_DZ-FC transition 196 67 3 6 Longitudinal antithetic shear vein HW_DZ-FC transition 309 64 100 44 19'40.65"N 10 3'30.93"E 4 1 Transversal shear vein FW_DZ 230 85 4 2 Transversal vein FW_DZ 0 75 4 3 Longitudinal shear vein FW_DZ 305 47 4 4 Transversal slip surface FW_DZ 236 83 25 4 5 Transversal shear vein FW_DZ 0 61 4 6 Vein in clay bed FW_DZ 276 45 44 19'37.98"N 10 3'28.42"E 5 1 Antithetic slip surface FW_DZ 299 51 130 5 2 Transversal shear vein FW_DZ 195 86 5 3 Transversal vein FW_DZ 205 69 5 4 Antithetic slip surface FW_DZ 200 36 5 5 Longitudinal synthetic vein FW_DZ 334 70 5 6 Longitudinal synthetic vein FW_DZ 334 70 5 7 Oblique shear vein FW_DZ 351 55 5 8 Oblique shear vein FW_DZ 40 46 5 9 Oblique shear vein FW_DZ 66 54 44 19'42.06"N 10 3'4.34"E 6 1 Fault core synthetic slip surface FW_DZ-FC transition 150 60 6 2 Vein in clay bed FW_DZ-FC transition 330 45 6 3 Vein in silt bed FW_DZ-FC transition 330 45 6 4 Synthetic shear vein FW_DZ-FC transition 80 50 120 6 5 Transversal shear vein FW_DZ-FC transition 233 84 10 44 20'4.01"N 10 2'20.67"E 7 1 Transversal vein FW_DZ 230 80 7 2 Transversal shear vein FW_DZ 230 80 7 3 Transversal vein FW_DZ 230 80 7 4 Transversal shear vein FW_DZ 230 80 44 19'50.13"N 10 2'38.41"E 8 1 Fault core calcite concretion HW_DZ-FC transition 135 76 8 2 Longitudinal antithetic breccia-vein HW_DZ-FC transition 336 86 8 3 Fault core S-C HW_DZ-FC transition 156 23 8 4 Fault core S-C HW_DZ-FC transition 156 23 44 19'42.26"N 10 2'38.35"E 9 1 Thrust R' vein HW_DZ 323 40 9 2 Transversal vein HW_DZ 238 76 9 3 Bed parallel vein-stylolites HW_DZ 127 56 44 19'38.33"N 10 2'54.02"E 10 1 Thrust footwall vein-stylolites HW_DZ 134 70 10 2 Thrust hangingwall vein-stylolites HW_DZ 332 64 44 19'0.16"N 10 3'13.04"E 11 1 Longitudinal synthetic vein HW_BG 280 50 44 19'33.34"N 10 4'43.09"E 12 1 Transversal vein FW_BG 254 72 44 24'51.31"N 9 57'4.64"E 13 1 Fault Core Breccia FW_DZ NW tip

Oxygen and carbon stable isotopes contents Calcite Type Macigno Host Rock MC1 (A & B) Calcite MC2 Calcite Ottone HR OC1 Calcite OC2 Calcite Site/ Sample 13 C (V-PDB) 18 O (V-PDB) 18 O (V-SMOW) 4/6-3,1-16,1 14,2 4/6-2,6-16,4 13,9 6/2-0,7-14,4 16,0 4/1-1,0-17,6 12,8 4/2-2,7-18,5 11,8 4/3-1,2-16,5 13,8 4/3 Replacive -1,6-17,0 13,4 4/5-1,5-17,4 12,9 4/6-1,3-17,7 12,7 5/2 Replacive -4,4-16,9 13,4 5/2 Replacive -4,3-17,0 13,3 5/3-4,3-17,3 13,0 5/3 Replacive -4,6-17,1 13,3 5/4-5,7-17,0 13,4 5/4 Replacive -5,7-17,1 13,3 5/6-4,9-17,1 13,2 5/7-4,8-17,8 12,5 5/7 Replacive -4,4-18,2 12,1 5/8-5,6-18,0 12,3 5/9-5,0-17,7 12,6 6/2-2,3-17,2 13,2 6/2 Replacive -2,1-16,5 13,9 6/3-0,9-16,4 13,9 7/1-1,3-16,4 14,0 NWtip -0,6-14,9 15,5 NWtip Replacive -0,8-13,7 16,7 4/1-1,5-14,4 16,0 4/2-2,1-15,9 14,4 4/2 Replacive -1,8-14,6 15,8 4/3-1,2-14,8 15,7 4/5-1,5-15,8 14,5 4/6-1,6-13,4 17,0 5/6-4,8-14,8 15,6 5/7-3,8-14,5 15,9 5/8-6,1-13,2 17,2 5/8-7,1-15,7 14,6 5/9-4,3-16,5 13,9 5/9 Replacive -5,3-14,0 16,5 6/1-1,2-12,6 17,9 6/1-0,4-13,0 17,5 6/2-1,4-14,9 15,5 6/2-1,2-14,5 15,9 6/3-1,3-16,9 13,4 7/1-1,5-14,3 16,2 NWtip -0,5-10,7 19,8 10/2 1,8-3,5 27,2 9/2 1,9-3,2 27,5 1/2 1,7-3,8 27,0 3/5 2,0-3,8 26,9 10/1 1,9-4,8 25,9 10/1 2,1-4,7 26,0 10/2 2,0-4,8 25,9 9/2 1,9-5,1 25,6 9/2 1,8-4,5 26,2 9/3 1,8-5,0 25,7 9/3 1,6-5,5 25,2 1/1 2,2-4,5 26,2 1/1 2,3-4,7 26,0 1/2 2,4-5,7 25,0 1/2 1,9-4,4 26,3 1/2 2,1-3,9 26,9 2/1 2,0-5,1 25,6 2/1 1,8-5,0 25,7 2/3 1,8-4,3 26,4 2/4 1,7-5,4 25,3 2/4 1,9-5,7 25,0 2/4 1,8-5,0 25,7 2/5 1,9-5,0 25,7 2/5 1,7-5,6 25,1 2/5 2,0-4,4 26,3 3/3 1,8-7,1 23,5 3/3 2,0-5,8 24,9 3/4 2,0-4,2 26,6 3/5 2,1-5,3 25,4 3/6 2,0-4,7 26,0 10/1 1,3-12,6 17,9 10/2 1,4-14,3 16,1

9/3 Replacive -0,5-15,3 15,0 8/1 2,1-15,4 15,0 8/1 1,9-14,4 16,0 1/1 2,1-13,6 16,8 2/1 2,0-14,0 16,5 2/3 2,0-14,0 16,4 3/2 1,7-17,3 13,1 3/2 2,1-15,1 15,3 3/3 2,1-13,4 17,1 3/3 2,1-14,0 16,5 3/4 2,1-13,8 16,6 3/5 2,1-12,4 18,1 3/5 2,1-11,9 18,6 3/6 2,0-10,9 19,7

Fluid inclusions microthermometry Inclusion Type Site/ FIA Thtot Tfm Tmice Sample Quartz 1 Biphase 4/3 A 151-6.5 Acqueous 4/3 A 151-7.8 4/3 A 151-49.8-6.5 4/3 A 151-49.8-11.4 4/3 A 151-49.8-4.8 4/3 A 156-50.1-6.6 4/3 I 215-45.5-7.2 4/3 I 127-6.9 Quartz 2 Monophase 4/3 A -83 CH 4 4/3 A -83 4/3 A -84 13/1 A -87 13/1 B -89 13/1 B -89 13/1 B -89 13/1 B -88 13/1 B -89 13/1 B -88 13/1 B -88 13/1 B -89 13/1 B -88 13/1 B -88 MC1A Calcite 4/2 A 183-2 4/2 A 198-2.8 4/5 A 190-2.6 4/5 A 190-3 4/5 A 190-1.9 5/2 A 188-18.4-2.9 5/2 A 198-21.4-3 5/2 A 198-21.4-2.7 5/2 A 198-17.4-4.9 5/3 A 183-2 5/3 A 183-2 5/3 A 178 5/6 I 183-1.5 5/9 I 194-0.8 7/1 A 180-6 7/1 A 180-6.2 13/1 A 186 13/1 A 191 13/1 A 186-1.8 13/1 A 191-0.9 13/1 A 191 13/1 I 191-0.8 MC1B Calcite 4/1 A 140-5.5 4/1 A 155-19.9-3.4 5/2 A 149-8.2-2.1 5/2 A 149-8.6-2 5/2 A 149-8 -2 5/9 A 140-11.9-6 5/9 A 155-12.1-6.2 5/9 A 150-3.7 5/9 A 150-5.4 5/9 B 150-2 5/9 B 150-31.5-9.7 5/9 B 140-31.5-10 5/9 B 140-31.5-17.2 5/9 B 155-31.5-14 13/1 A 156-1 13/1 A 156-1 13/1 A 156-0.8 13/1 A 161-1 13/1 A 161-1 MC2 Calcite 4/1 A 115-27.3-20.7 4/1 A 115 4/5 A 69-1.7 4/5 A 69-1.5 5/8 A 70-27.9-19.8 5/8 A 70-27.8-19.8 5/8 B 89-34.5-18.9 5/8 B 99-34.4-18.6 5/8 B 114-34.1-16.7

5/9 A 80-1.8 5/9 A 70-1.9 5/9 A 70-1.5 5/9 A 70-1.3 7/1 A 90-17.8-5.3 7/1 A 90-5.3 7/1 A 90-5.8 7/1 A 90-9.7 7/1 A 90-2.5 13/1 I 108-12.3 13/1 I 108-0.7 OC1 Calcite 10/1 A 90 10/1 A 90 10/1 I 90 10/1 I 90-0.5 10/1 I 100 10/1 I 100-0.1 10/2 A 90-1.5 10/2 A 100 10/2 I 100 9/1 A 100 9/1 A 100 9/1 A 100 9/1 A 105 8/2 A 78 8/2 A 78 8/2 A 113 8/2 A 113 2/4 A 100-0.2 2/4 A -0.1 3/4 A 95 3/4 A 105-1.6 3/4 I 100-1.5 OC2 Calcite 10/1 A 60-6.9 10/1 A 65-6.5 10/1 A -6.3 10/1 A -5.9 10/1 A -5.2 10/1 A -3.4 10/1 A -2 10/2 A 110-1.9 10/2 A 110-1.3 10/2 A 110 10/2 A 110 10/2 A 110 10/2 A 110 10/2 A 110 10/2 A 115 8/2 I 74-4.4

SEM-EDS prehnite major elements contents Al 2O 3 SiO 2 CaO FeO 25.32 45.40 27.67-25.17 45.30 27.78-25.14 44.86 27.90-24.95 45.23 27.78 0.46 25.27 45.24 27.96-25.32 45.44 27.72-25.31 45.21 27.89-25.14 45.21 27.41-24.80 44.74 28.10-24.75 45.02 27.66 0.37 24.81 44.91 27.73 0.29 24.79 44.77 28.94-25.33 44.76 27.77-25.02 45.29 28.09-24.91 45.20 27.98 0.44 24.77 44.74 27.45 0.57 25.00 44.68 27.93 0.39 25.33 45.00 27.84-24.99 44.80 27.76 0.35 25.10 45.22 27.72-25.11 45.34 27.96-24.97 45.27 27.60 0.48 25.02 44.92 27.86-25.03 44.81 27.90-24.56 44.90 27.60 0.52 24.98 44.94 27.72-25.00 45.24 27.71 0.33 25.05 45.08 27.49 0.40 25.15 44.98 27.62-25.06 44.83 27.75-25.01 45.07 27.78 0.52 24.89 45.28 27.78-24.98 44.88 27.67-25.00 45.13 27.75 0.50 25.03 44.84 27.83 0.28 25.19 44.99 28.05-25.22 44.97 27.69 0.35 25.27 45.19 27.76 0.33 25.13 45.01 27.38-24.83 45.20 27.79 0.42 24.92 45.26 27.70-25.31 45.01 27.85-25.48 45.24 27.69-25.11 45.09 27.76 0.31 24.94 44.94 27.66 0.35 25.28 44.87 27.59-25.04 45.34 27.42-25.30 45.02 27.64-25.02 44.73 27.59 0.43 25.41 44.82 27.47-25.22 45.16 27.76-25.02 44.94 27.80 -