1 3 -β -D- a = b = 1. 5 nm c = 0. 6 nm %

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2011 10 20 27 5 Pharm J Chin PLA Vol. 27 No. 5 Oct 20 2011 451 12 3 R979. 1R979. 5 DOI10. 3969 /j. issn. 1008-9926. 2011. 05. 025 A 1008-9926201105-0451-05 1 6-β -D 1 Surenjav 2 X 20 a = b = 1. 5 nm c = 0. 6 nm 60 13 C NMR 4 1 3-β -D Zhang 3 1. 49 10 6 180 49. 5% 1 50. 5% 1. 1 12. 3% 4 α β 1. 2 1 5 1 3-β -D- 6 4 5 1 200433 521 3 100071 2 137001 Tel 01066949080E-mailcaohong6699@ sina. com β 7 6 Tomati 8

452 2011 10 20 27 5 Pharm J Chin PLA Vol. 27 No. 5 Oct 20 2011 1 DNA 2 1. 3 40 ~200 2. 1 11 GPC 2. 1. 1 9 GPC 34 808 34 168 T 99. 96% 95. 57% GPC 12 Hou 13 Moradali 14 2 2. 1. 2 HIV Wang 15 Low 10 1 180 3-β -D DNA Feng 16

2011 10 20 27 5 Pharm J Chin PLA Vol. 27 No. 5 Oct 20 2011 453 2 Kupfahl 22 2. 2 Zhou 23 1987 Ito 17 2. 4 18 Murata 24 Drandarska 25 Guo 19 Wang 20 2. 3 2. 5 Markova 21 Yamada 26 Yu 27

454 2011 10 20 27 5 Pharm J Chin PLA Vol. 27 No. 5 Oct 20 2011 28 zhang 34 H 2 O 2 - - - - - 29 CO 2 Wang 30 4 31 12. 9% 32 β -D 224. 86 mg /g 223. 61 mg /g 3. 1. 2 33 9. 46% 35 60 88. 7% 3. 2 3 3. 1 4 36 45% 81% 3. 1. 1 90. 9% 89. 7% - 1Zhang YY Xu XJ Zhang LN. Gel formation and low-temperature intramolecular conformation transition of a triple-helical polysaccharide lentinan in waterj. Biopolymers 2008 89 10 852-

2011 10 20 27 5 Pharm J Chin PLA Vol. 27 No. 5 Oct 20 2011 455 861 2Surenjav U Zhang L Xu Xet al. Effects of molecular structure on antitumor activities of 1-> 3-beta-d-glucans from different Lentinus Edodes J. Carbohyd Polym 2006 631 97-104 3Zhang LN Li XL Xu XJ et al. Correlation between antitumor activitymolecular weightand conformation of lentinan J. Carbohyd Res 2005 3408 1515-1521 J. 2007 193 369-373 5. blood-stage infection by evoking adaptive immune-responsesj. J. 1999 311 48-52 6. 24Murata T Hatayama I Kakizaki I et al. Lentinan enhances sensitivity of mouse colon 26 tumor to J. 2005 272 71-74 cis-diamminedichloroplatinum 7. IIand decreases glutathione transferase expressionj. Jpn J J. 2006 284 276-278 8Tomati U Belardinelli M Galli Eet al. NMR characterization of the polysaccharidic fraction from Lentinula edodes grown on olive mill waste waters J. Carbohydr Res 2004 3396 1129-1134 9. GPC 795-803 J. 2009 254 458-460 10Low SY Hill JE Peccia J. DNA aptamers bind specifically and selectively to 1--> 3-beta-d-glucansJ. Biochem Bioph Res Co 2009 3784 701-705 11. J. 2009 212 183-188 12Zhang YY Li SWang XHet al. Advances in lentinanisolationstructurechain conformation and bioactivitiesj. Food Hydrocolloid 2011 252 196-206 13Hou XJ Chen W. Optimization of extraction process of crude polysaccharides from wild edible BaChu mushroom by response surface methodology J. Carbohyd Polym 2008 721 67-74 14Moradali MFMostafavi H Ghods Set al. Immunomodulating and anticancer agents in the realm of macromycetes fungi macrofungi J. Int Immunopharmacol 2007 76 701-724 15Wang XH Zhang LN. Physicochemical properties and antitumor activities for sulfated derivatives of lentinan J. Carbohydr Res 2009 344162209-2216 16Feng YL Li WQ Wu XQ et al. Rapid and efficient microwaveassisted sulfate modification of lentinan and its antioxidant and antiproliferative activities in vitroj. Carbohyd Polym2010 823 605-612 17Ito M Baba M Sato A et al. Inhibitory effect of dextran sulfate and heparin on the replication of human immunodeficiency virus HIVin vitro J. Antiviral Res 1987 76 361-367 18. 123-128 J. 1999 315 594-597 19Guo ZH Hu YL Wang DY et al. Sulfated modification can enhance the adjuvanticity of lentinan and improve the immune effect of ND vaccine J. Vaccine 2009 275 660-665 20Wang DY Guo ZH Ma X et al. Effects of sulfated lentinan on cellular infectivity of avian infectious bronchitis virus J. Carbohyd Polym 2010 792 461-465 21Markova N Kussovski V Drandarska Iet al. Protective activity of Lentinan in experimental tuberculosis J. Int Immunopharmacol 2003 310-111557-1562 22Kupfahl C Geginat G Hof H. Lentinan has a stimulatory effect on innate and adaptive immunity against murine Listeria monocytogenes infectionj. Int Immunopharmacol2006 6 4 686-696 4. 23Zhou LD Zhang QH Zhang Y et al. The shiitake mushroom-derived immuno-stimulant lentinan protects against murine malaria Int Immunopharmacol 2009 94 455-462 Cancer Res 1996 87111171-1178 25Drandarska I Kussovski V Nikolaeva S et al. Combined immunomodulating effects of BCG and Lentinan after intranasal application in guinea pigsj. Int Immunopharmacol 2005 54 26Yamada J Hamuro J Hatanaka Het al. Alleviation of seasonal allergic symptoms with superfine beta-1 3-glucanA randomized study J. J Allergy Clin Immun 2007 1195 1119-1126 27Yu ZH LiHua Y Qian Y et al. Effect of Lentinus edodes polysaccharide on oxidative stress immunity activity and oral ulceration of rats stimulated by phenol J. Carbohyd Polym 2009 75 1 115-118 28. J. 2011 31 4 613-615 29. J. 2009 1407X52-55 30Wang XH Xu XJ Zhang LN. Thermally induced conformation transition of triple-helical lentinan in NaCl aqueous solution J. J Phys Chem B 2008 1123310343-10351 31. J. 2007 289 199-202 32. J. 2009 319 20-22 33. J. 2010 313 14-17 34Zhang M Zhang LN Cheung PCKet al. Molecular weight and anti-tumor activity of the water-soluble polysaccharides isolated by hot water and ultrasonic treatment from the sclerotia and mycelia of Pleurotus tuber-regium J. Carbohyd Polym2004 562 35. J. 2010 312 10-14 36. J. 2007 345 531-534 2011-01-24 2011-05-18