9 4 2000 10 ( ) Journal of Yunnan Univerity of the Nationalitie(Natural cience Edition) Vol. 9 No. 4 ct. 2000 hiff Ξ (,,650031,,650011) - 1,3 - ( H 2 L),,UV,IR, 1 H NMR,M, (ML xh 2,M = o u,x = 1,2). hiff ; ; ; ; : 641. 4 : A : 1005-7188 (2000) 04-0206 - 04 0,. hiff, hiff, [1,2,3 ]., - 1,3 - (H 2 L),,UV,IR, 1 H NRM, M. 1 1. 1, (95 %), (85 %),,,,,. 1. 2 X4,, WYX - 420, U - 3400, IR440, Vanian XL - 200 NMR, VG707E,DD - 11A. 1. 3 [4 ] 1. 3. 1 33. 6g 200L 90 %, 30g, - 6, 45g 2,, 200L 40 %, 60g, 1h,,,,, 50 %, 123 125 ( ). 1. 3. 2 1,3 (H 2 L) 10g, 100L, 3. 6g, 0. 5h,,,,,, 74. 6 %, 184 186 ( ), DMF,,. 1. 3. 3-1,3-1g - 1,3-25L DMF, 0. 5g o Ξ :1999-12 - 07 : (1956 ),,,. 206
4 : hiff (H 3 ) 2 4H 2. 0. 5h,,,,, 0. 5g.. 1. 3. 4-1,3 - ( H 2 L) ol ul,,,,. 1 1. H 2 L ol ul ( %) H( %) N( %) ( %) M( %) ( %) H 2 L 184. 6 76 57. 69 57. 68 3. 85 3. 98 10. 77 10. 62 24. 62 24. 43 ol > 250 67. 8 48. 93 48. 72 3. 58 3. 10 9. 13 9. 16 20. 88 20. 70 9. 13 9. 61 ul > 250 59. 6 48. 62 48. 46 3. 56 3. 04 9. 07 8. 86 20. 74 20. 41 10. 29 9. 98,,. 125 127 ( [9 ], ), - 1,3-184 186 ( [ 4 ], ), ol ul 250,. 2 2. 1 H 2 L ol ul U - 3400, 2,, 243. 5 280. 0n = - 3 [6,7 ]. 341. 3 383. 7n n - 3 [6,7 ]. ul 484. 2 493. 1n d - d [4 ]. 2. H 2 L ol ul ( ax(n) ; = x10 3 1 ol - 1 c - 1 ) 2. 2 H 2 L 255. 7 (2. 4) 348. 5 (4. 3) 383. 7 (2. 6) ol 255 (38) 341. 3 (24) 383. 5 (26) ul 243. 5 (85) 280. 0 (58) 352. 3 (85) 484. 2 (27) 493. 1 (28) H 2 L ol ul IR440, 3. 3. H 2 L ol ul c - 1 ( - H) (N - H) ( = ) ( = N) ( = ) ( =, = N) (N - ) (M - N) H 2 L ol ul 3400 br, 3400 br, 3430, 3240, 1690 v 1690 br, 1725 v 1605 1595 1600 : -, v -, br -, - 1550 1560 1570 1450 br, 1490, 1450, 1490, 1450, H 2 L 3240c - 1 3430c - 1 N - H [4,7 ], ol. ul 3400c - 1 - H [4 ],H 2 L ol ul 1690c - 1 = 0, H 2 L ol, ul 1725c - 1. H 2 L 1605c - 1 = N [6,7 ], ol 1595c - 1, ul 1600c - 1, 470 490 560 br, 545 207
( ) 9 5-10c - 1, N,. H 2 L 1550c - 1 =, ol ul 1560c - 1 1570c - 1, H 2 L 1450c - 1 = = N. ol ul 1490c - 1 1450c - 1, ol ul 470 490c - 1 545 560c - 1 M - M - N [6,7,8 ]. 2. 3 H 2 L 1 H NMR H 2 L 1 H NMR Vanian XL - 200 NMR,Dl 3,TM,H 2 L 1 H NMR [2,4 ] 1,. 1. H 2 L 1 H NMR NH 6 H 5 H 2 H 2 13. 40-12. 64 7. 95-7. 25 4. 64-4. 49 1. 55-1. 23 (h,2h) (,14H) (d,h,3h) (h,1h) ( -, -, h -, d - ) 2. 4 H 2 L ol VG707E,. H 2 L ol 2. 2. H 2 L ol H 2 L ol 2H 2 W/ e R. I( %) W/ e R. I( %) 520 [ H 2 L ] + 613 5 [ 25 H 22 N 4 3 4 o ] + 429 [ H 2 L - - H 2 Ph] + 577 5 [ - 25 H 22 N 4 3 4 o - 2H 2 ] + 396 [ H 2 L - - HH 2 Ph] + 526 7 [ - 18 H 19 N 4 3 4 o ] + 363 [ H 2 L - - 2 HH 2 Ph] + 469 8 [ - 18 H 8 N 3 4 o ] + 324 [ H 2 L - - N 2 H 2 H 2 Ph] + 428 8 [ - 17 H 11 N 3 3 o + 292 [ H 2 L - - N 2 H 2 H 2 Ph - - ] + 371 10 [ - 10 H 6 N 3 0 4 o ] + 272 [ H 2 L - 2 - HH 2 Ph] + 333 11 [ - 19 H 17 N 4 ] + 232 [ H 2 L - - H 2 Ph - - N 2 HH 2 Ph] + 274 41 [ - 11 H 6 N 4 2 ] + 215 [ H 2 L - - N 2 HH 2 Ph - - H 2 Ph] + 218 30 [ - 13 H 6 N 4 ] + 187 [ H 2 L - - HN 2 HH 2 Ph - - N 2 HH 2 Ph] + 168 58 [ - 2 HH 2 Ph] + 154 [ - 2 HPh] + 127 48 [ - 9 H 3 ] + 124 18 [ - HH 2 Ph] + 92 82 [ - H 3 Ph] + 102 [ - HPh] + 57 100 [ - H - ] + 91 100 [ - H 2 Ph] + 77 3 [ Ph] + 65 10 [ - 2 H] + 45 6 [ - H] + 32 3 [ ] + H 2 L ol 2H 2,,H 2 L,,. ol 2H 2 613, H 2 L,, ol 2H 2... 208
4 : hiff ol 2H 2 ul H 2 DD - 11A,,.,H 2 L.,,. H 2 L ol 2H 2,uL H 2 ol 2H 2,. N N H N H N H 2 Ph H 2 Ph N N N N H 2 Ph H H H 2 Ph N N H 2 Ph o 2H 2 N N H 2 Ph 1. Akbar Ali M., Teoh.. G.. Magnetic and pectrocopic tudie on etal coplexex of oe oxygen - nitrogen and ulphur - nitrogen chelating agent. J. inorg. Nuch. he., 1978, 40 : 451 458 2. Lkander, M. F. El - ayed, L. El - toukhy A., hehata. A. K.. Reactivity of oe coordinated ligand containing culphur toward nucleophilic ubtitution reaction. PartI. Reaction of [ (ubtituted 1, 2 - ethanediylidene) bi ( - ethylhydrazinecarbodithioate) NN ( - 2) ] nickel ( II) and palladiu ( II) chelate with econdary aine. Inorganica hiica Acta, 1986, 123 : 19 3. ubhah Padhye George G. Kauffan. Tranition etal coplexe of eicarbazone and thioeicarbazone. oordination cheitry re2 view, 1985, 63 : 127 60 4.,. Fe ( III) o ( II) Ni ( II) u( II) Zn( II) chiff.,1988,9 :541 546 5. Akbar Ali, Boe. M. R.. Metal coplexe of chiff bae forward by condenation of 2 - ethoxybenzaldehyde and 2 - hydroxyben2 zaldehyde with - benzyldithiocarbazate. J. Inorg. Nucl. he., 1977, 39 : 265 269 6. Akbar Ali, Monir uddin,m. Nazi Uddin M., howdhuty - li D. A. Magnetic & pectrocopic tudie on etal coplexe of N donor ligand : Part II - nickel ( II) & copper ( II) coplexe of chiff bae fored by the condenation of 2 - hydroxybenzaldenyde with, - dibenzyldithiocarbazate & - Methyl - - benzyldithiocarbazate. Indian journal of cheitry, 1986, 25A : 238 242 7. Zhu Xinde, Wang henggang, Lu Zhiping, Le Zhifeng Wu Zihen. ynthei and biological activity of the chiff bae N, N - bi (al2 icylidene) thiourea and It coplexe of opper ( II), Nickel ( II) and Zinc ( II). ynth. react. Inorg. Met - org. he., 1996, 26 (6) : 955 966 8. Manouaki G. E. Bolo,. A.. ynthei and characterization of a erie of new ixed ligand coplexe of Manganee ( III), Iron ( III), Nickel ( II), opper ( II) and Zion( II) with ixed ligand coplexe of Manganee ( III), Iron ( III), Nickel ( II), opper ( II) ad Zion( II) with chiff bae of N, N - diethylaino - dithiocarbaate a ligand. Inorganica chiica with chiff bae of N, N - diethylaino - dithiocarbaate a ligand. Inorganica chiica acta, 1985, 108 : 215 220 9.,,. II. -. ( ),1986, 4 : 791 796 ( 224 ) 209
( ) 9 opount : = opount - 1 ; IF opount = 0 THEN Index- b : = i - t. curlen + 1 ; EXIT ;DitanceMatched : = i - i 1 ; IF kiptable[. ch[ i 1 ] ] < = DitanceMatched THEN kip : = 1 ELE kip : = kiptable [. ch [ i 1 ] ] - Di2 tancematched ; IF < kip > = Bufferlength) THEN Index- b : = 0 ; EXIT ; Bufferlength ; = Bufferlength - kip ; i : = i + kip ; END. 3,. n,, n/, 0 ( n/ ) ;, 0 ( n + ) ;,,. 0 ( n 3 ),,,,,. 1. Michael Abrah, [M]. :, 1998. 129 168 2.,. [ M]. :, 1997. 177 233. An Efficient Pattern Matching Method ZHU Qingxun (Qingdao TV Univerity, Qingdao, 266012) Abtract Thi paper preent the principle and particular algorith of an efficient pattern atching ethod Boy2 er-moore AR. Key Word pattern atching, ource tring, pattern ( 209 ) tudy on a helate of Ninhydrin - 1, 3 - bi( - benzyldithiocarbazate) and their Metal helate ZHA Jihou LI Wenjun 3 YAN Li (Departent of heitry, Yunnan Univerity of the Nationalit, Kuning, 650031) ( 3 Departent of traditional chinee pharacology, Kuning, 650031) Abtract A chelate of Ninhydrin - 1, 3 - bi( - benzyldithiocarbazate) (H 2 L) and their etal chelate were yntheied and haracterzed by eleental analyi, UV, IR, 1 H NMR, M and TGA. The reult howed the etal chelate that they will be able to poe the copation (ML xh 2, x = 1, 2) and tructure of four - coordination te2 trahedral geoetry. Key Word chiffbae containing urfur, Ninhydrin - 1, 3 - bi( - benzyldithiocarbazate), Ninhydrin, Metal helate, ynthee, haracterization 224