19 1 2000 3 ROCK AND MIN ERAL ANAL YSIS Vol. 19,No. 1 March,2000 : 025425357 (2000) 0120032210, (,430074) :, 108 : ; : O657. 31 : A 30, Thomson T e n e ( AES) [6 ], Thomson Rayligh 27 MHz 40 MHz Ar [7 ICP ( T g ) T exc T e n ] [8 e ] AES Ar - ICP n e T e, ICP 1 ICP AES ICP, - ICP ICP n e T e, ICP ICP ( T) ( n e ) ICP L TE ( T e > ( T ion > T exc > T g ) ) L TE (Saha Boltzmam [1 ] [9,10, : ) ] ICP ( ( T exc ) [2,3 ], ), Ar - ICP n e ( ) [4 ],, L TE (L TE), ( PL TE) [11,12 ],Blades, [13 ] Sr Ca Mg Cd Zn [12 T exe n e H486. 32 ICP L TE b ] r nm Ar Stark n e,, Saha exp L TE L TE, ICP [14 T e (L TE), PL TE ] L TE, [15, HAr Stark n e [13 ] ] [5, ] exp L TE, ICP :1999209210 ; :1999210212 : (1962 - ),,,, 32
1 : 19 [16 L TE ] Monte Carlo, AES ICP, [17 -, ] AES [34, AES ] Karen [18 ] [35 ], Gaussian Lorentziam, Dubuisson [19 ],, AES Gaussian [20 ] t lg ( I x / I x ) Lorentziam,, AES [21 ] K, Na La Y Mg 17, [22 ], AES,, ICP AES,, [23 ] AES [36 AES ] [24 ] [37 ICP - ] [38 Kalman ] [39 AES, Kalman ] [40 ] Kalman [41 Ca Mg Al L TE non - L TE Kalman ],L TE,non - L TE,, AES,, Boumans [25 ],, [26 ] ( ) [27 ] [28 ], [29 ],,, Saxbery [30 ], [31 ] -,,,, [32 ], Kalman AES, AES,,, [33 ],,,,,, 33
1 19, 65,,, Boumans [42 ] : AES,,,/, AES,, Leeman Labs Jobin Yvon, Spectro Analytial, ICP WL Y 100 - ICP Υ WL SI - ICP 2 ς 90, ICP,,, ( PM T) AES,,, 2, Shimaozu ICPS - 7500 Ο Jobin Yvon J Y - 138 ICP, 56, Π Therme Jarrell - Ash Trace Scan, Advantage TM Θ, Ρ, ICP, 70, ( PDA),,,,,, ICP [43 ] 80 L EECO Hilger E984C ICP Σ Jobin Plasmarray ICP PDA Yvon J Y48 ICP Τ [44 ] PDA -, AES Ο Π Θ Ρ Σ Τ Υ ς 34 ICPS - 7500 ICP.. Jobin Yvon. J Y - 138 ICP... Trace Scan Advantage TM.. Jobin Yvon. J Y Ultima.. Hilger. E984C ICP.. Jobin Yvon. J Y48 ICP... WL Y 100 - ICP... WL SI - DICP..
1 : 19 (CTDs) [49 ] AES WP500-2A,, ( CCD) 200400 nm (CID) 200800 nm,, 3 ICP,,, [45 ] [46 ] CTDs, CCD CID, ICP, CID Mora [50 ] AES CCD, [51 ] CID,CID AES, TJA,23, 1/ 5 IRIS AP ICP Ο CID [52 1/ 20 ] PTFE,CID 26, 26 V,,, [53 ] V, 12 min Cameron [54 ] ICP AES ICP, 1 000 mg/ L - 12,,,, J Y IMA GE Navigator, Fraucesco [55 ] ICP, : [56 ] [57 ],,2 min 23,, Peter [58 ],, /,, - AES, AES H 2 ICP [47 ] [59 ] Ar Stark CCD - OES ICP [48 ] AES, Ο TJ Y. IRIS AP ICP.. 35
1 19,n e T e T exc, AES,,, [60, ] [61 ] [62 ] [63 ] 10-9 [64 ] 10-6 s, ETV Holak [65 ],,,,, NaBH 4 ( Gagean [72 ] KBH 4 ), AES Kennet h [66 ] [73 ] AES,, [67 ] [ 68 ] As Sb Bi, AES 10 ( ETAAS), ( ETV),,, ETV,,, ETV [69 ],, ICP (, [70 ) ], U Zr Ti Vahid [74 ] [75 ] AES [76 ] J T - V,, AES 11 ;, AES,,, [77 ] - ( AES [78 ) ], [79 ] [80 ] [81 ] [82 ] AES [71 ] AES, Ambrose AES,, 36
1 : 19 AES, Cu Fe Ca Ni (LC) AES,, [102 ] 200 YPA 4, [83 AES ] 1. 0 mol/ L HCl, Pt Pd ( HPLC) - AES Os,,ETV - [84,85 ] AES [ 103 ] -,HPLC - AES - ( M G) (CE) - AES, Pt Pd Rh Ir Au As AES Au 4 Pt Pd AES, [86, ] [87 ] [88 ] [89 ] [90 ] [91 ] (M IP - AES) [92 ] [93 ] [94 ] [95 ], AES [96 ], ICP Yamada [105 ] AES, AES [106 ( MS) ] [97 ],, ICP, AES [107 - AES 15, Mn ] NaNO 2 H 2 O 2 [98 ] Fe,, I - AES CeO 2, AES La Pr Nd Sn Gd Y, HNO 3, AES H 2 O 2,8 mol/ L HNO 3,, [108 ] Ce ( ) Ce ( ), P 204 / CCl 4 Ce ( ), La Pr Nd Y Ce ( ) 5,, 6 [1 ]. mol/ L HCl, HCl ICP [ M ]. :,1987. 3444.,CeO 2 [ 2 ] Uchida H, Kiyoshi Tanabe, Yukihiro Nojiri,et al. Spatial [99 ] Distribution of Metastable Argon, Temperature and Elec2 tron Number Density in an Inductively Coupled Argon AES Ho Dy Sm Y La Eu p H = 3,PMBP/, 0. 24 mol/ L HCl [100 ] D 238 AES 40B : 1539. [ 5 ] Raaijmakers I J M M, Mboumans P W, Der Sude, et al. 4N Cu Fe Ni Pb A Theoretical and Experimental Investigation of Non - 6 mol/ L HCl, 8 ml, p H 4, D 238, 6 mol/ L HNO 3,,2 mol/ L [104 AES ] Plasma[J ]. S pect rochimica Acta. 1981,36B :711. [3 ]. AES [J ].. 1991,7 (3) :143. Ca Mg Fe Zn [4 ] Caughlin B L, Blades M W. Analyte Ionization in Induc2 tively Coupled Plasma [J ]. S pect rochimica Acta. 1985, L TE Phenomena in an Inductively Coupled Argon Plas2 ma. Characterization of the Discharge[J ]. S pec2 t rochimica Acta. 1983,38B :697. HNO 3, AES [ 101 ][6 ] Huang Mao, Grary Hieftji. A New Procedure for Deter2 37
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1 : 19 [91 ],. - AES [J ].. 1996, 33 (4) : 419. [92 ],. [J ]. [J ].. 1996,15 (6) :268. [93 ],,,. [102 ],. / [J ].. 1996,5 :39. [94 ],,,. AES [J ].. 1996,13 (6) :18. [95 ],. [ 104 ] Su Zhi2xing, Buo Qiao - sheng, Lao Xing - yin, et al. Ti V Zr Mn Si Fe Mg[J ].. 1996,15 (4) :44. [96 ] Sen Gupta J G. Determination of Barium, Strontium and Nine Minor and Trace Elements in Impure Barite and Strontianite by Inductively Coupled Plasma Atomic Emission Spectrometry after Dissolution in Disodium Ethylendiaminetetraacetate [ J ]. Talanta. 1991, 38 (10) : 1087. [97 ],,. trometry[j ]. J A nal A t S pect rom. 1992,7 :661. [J ].. 1997, 16 (1) : 28. [98 ],. P 204 - ICP/ AES CeO 2 La Pr Nd Sm Gd Y[J ].. [107 ],. 1996, (3) : 63. [99 ],,. PMBP/. 1987,15 (12) :1062. [108 ],. AES [J ].. 1993, (1) :33. [100 ]. D 238 AES 4N Cu Fe Ni Pb [ J ].. 1992, 11 (3) : 58. [101 ],,.. 1996, (3) :75. ( ETV) - AES Pt Pd Os [J ].. 1997,16 (4) :5. [103 ],,. [J ].. 1996,15 (5) :63. Application of a Macro Porous Resin Containing Imida2 zolins Groups to Pre - concentration and Separation of Gold, Platinum and Pulleadium Prior to AES Determination[J ]. Talanta. 1995,43 :1127. [105 ] Kci Yamada, Cameron W M, Osamu Kujiral, et al. On Line Enrichment and Determination of Trace Sulfur in High - purity Iron Samples by Flow Injection and Inductively Coupled Plasma Atomic Emission Spec2 [106 ]. - [J ].. 1993,9 (3) :35. AES : [J ]. [J ].. 1996,15 (3) :68. The Development of Inductively Coupled Plasma Atomic Emission Spectrometry YA N G Xiang, J IN Ze2xiang ( Faculty of Material Science and Chemical Engine ering, China University of Geo sciences, Wuhan 430074, China) Abstract : A review on t he develop ment of inductively coupled plasma atomic emission spect romet ry including ba2 sis research, sampling techniques, application and inst rumentation develop ment is presented. 108 references are cited. Key words : inductively coupled plasma atomic emission spect romet ry ; review 41