Supporting Information

Σχετικά έγγραφα
C H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged

Supporting Information

chlorostibine Iou-Sheng Ke and François P. Gabbai Department of Chemistry, Texas A&M University, College Station, TX

Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]

Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings

Photo-Induced Self-Assembly of Pt(II)-Linked Rings and Cages via the Photolabilization of a Pt(II) Pyridine Bond

Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand

Heavier chalcogenone complexes of bismuth(iii)trihalides: Potential catalysts for acylative cleavage of cyclic ethers. Supporting Information

Supporting Information

Supporting Information

Supporting Information. Palladium Complexes with Bulky Diphosphine. Synthesis of (Bio-) Adipic Acid from Pentenoic. Acid Mixtures.

SUPPLEMENTARY MATERIAL. A Facile and Convenient Approach for the Synthesis of Novel Sesamol-Oxazine and Quinoline- Oxazine Hybrids

Table of Contents 1 Supplementary Data MCD

Patrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.

Table S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.

Enantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes

Pyrrolo[2,3-d:5,4-d']bisthiazoles: Alternate Synthetic Routes and a Comparative Study to Analogous Fused-ring Bithiophenes

Supporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory

College of Life Science, Dalian Nationalities University, Dalian , PR China.

Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid

Electronic Supplementary Information (ESI)

IV. ANHANG 179. Anhang 178

Heterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics

Supporting Information

Synthesis, Crystal Structure and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5- yl)benzenes

Cycloaddition of Homochiral Dihydroimidazoles: A 1,3-Dipolar Cycloaddition Route to Optically Active Pyrrolo[1,2-a]imidazoles

Supplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3

Supporting Information for Substituent Effects on the Properties of Borafluorenes

Electronic Supporting Information

Supporting Information

Supporting information

Supporting Information. Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the. Synthesis of Heteroaromatic Biaryls

Novel electroluminescent donor-acceptors based on dibenzo[a,c]phenazine as

SUPPORTING INFORMATION

Supplementary Material

Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4

Zebra reaction or the recipe for heterodimeric zinc complexes synthesis

Supporting Information

Electronic Supporting Information. 3-Aminothiophenecarboxylic acid (3-Atc)-induced folding in peptides

Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces

Supporting Information

Supporting Information

Supporting Information

Supporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds

Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: -S-aromatic heterocyclic podophyllum derivatives display antitumor activity

Synthesis of Imines from Amines in Aliphatic Alcohols on Pd/ZrO 2 Catalyst at Ambient Conditions

SUPPLEMENTARY DATA. Waste-to-useful: Biowaste-derived heterogeneous catalyst for a green and sustainable Henry reaction

Supporting Information for

Bloco A, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ, Brazil. Contents Pages

SUPPORTING INFORMATION TO. On Two Alizarin Polymorphs

Electronic supplementary information (ESI) Bodipy functionalized ortho-carborane dyads for low-energy photosensitization

Supporting Information

Supporting Information

Tunable Ligand Emission of Napthylsalophen Triple-Decker Dinuclear Lanthanide (III) Sandwich Complexes

Electronic Supplementary Information (ESI)

Supporting Information. Introduction of a α,β-unsaturated carbonyl conjugated pyrene-lactose hybrid

SUPPORTING INFORMATION. Pyramidanes: The Covalent Form of the Ionic Compounds

and Trimethylene Carbonate

Table S1 Selected bond lengths [Å] and angles [ ] for complexes 1 8. Complex 1. Complex 2. Complex 3. Complex 4. Complex 5.

SUPPLEMENTARY MATERIAL

Phenylpropanoids, Sesquiterpenoids and Flavonoids from Pimpinella tragium Vill. subsp. lithophila (Schischkin) Tutin

Electronic Supplementary Information

Divergent synthesis of various iminocyclitols from D-ribose

Supporting Information. Generation Response. Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi , China. China , USA

Supporting Information

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

Supporting Information. Partial thioamide scan on the lipopeptaibiotic trichogin GA IV. Effects on

Supplementary information

SUPPLEMENTARY MATERIAL. In Situ Spectroelectrochemical Investigations of Ru II Complexes with Bispyrazolyl Methane Triarylamine Ligands

Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships. or W, and D = P or V)

Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-

E-H (E = B, Si, C) Bond Activation by Tuning Structural and Electronic Properties of Phosphenium Cations

10-π-electron arenes à la carte: Structure. Sr, Ba; n = 6-8) complexes

Fused Bis-Benzothiadiazoles as Electron Acceptors

Electronic Supplementary Information

Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.

Supporting Information. A single probe to sense Al(III) colorimetrically and. Cd(II) by turn-on fluorescence in physiological

9-amino-(9-deoxy)cinchona alkaloids-derived novel chiral phase-transfer catalysts

SUPPORTING INFORMATION

New Cytotoxic Constituents from the Red Sea Soft Coral Nephthea sp.

Supporting Information

Supporting Information

Supporting Information

Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes

Supporting Information

Supplementary material

Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes

difluoroboranyls derived from amides carrying donor group Supporting Information

Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide

Supporting Information

Electronic Supplementary Information

Supporting Information File 2. Crystallographic data of syn-bis-quinoxaline, 16c CH 3 CO 2 C 2 H 5 ;

Mean bond enthalpy Standard enthalpy of formation Bond N H N N N N H O O O

Electronic Supplementary Information:

Electronic Supplementary Information

Synthesis, Characterization, and Computational Study of Three-Coordinate SNS-Copper(I) Complexes Based on Bis-Thione Precursors

Supplementary Materials: Development of Amyloseand β-cyclodextrin-based Chiral Fluorescent Sensors Bearing Terthienyl Pendants

Cinchona-Alkaloids based Isoselenazolones: Synthesis and Their Catalytic Application in Asymmetric Bromolactonization of Alkenoic Acid

Electronic Supplementary Information

Supporting Information

Transcript:

Supporting Information Molecular Cage Impregnated Palladium Nanoparticles: Efficient, Additive-Free Heterogeneous Catalysts for Cyanation of Aryl Halides. Bijnaneswar Mondal, Koushik Acharyya, Prodip Howlader and Partha Sarathi Mukherjee* Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India. E-mail: psm@ipc.iisc.ernet.in. Fax: 91-80-2360-1552; Tel; 91-80-2293-3352. These authors contributed equally. Figure S1: 1 H NMR spectrum of aldehyde C recorded in CDCl 3. S1

Figure S2: 13 C NMR spectrum of aldehyde C recorded in CDCl 3. Figure S3: ESI-HRMS spectrum of aldehyde C recorded in CH 3 CN. S2

Figure S4: FTIR spectrum of aldehyde C. Figure S5: ORTEP diagram of aldehyde C. S3

Figure S6: Unit cell packing diagram of aldehyde C. Hydrogen atoms are omitted for clarity. Table S1: Crystallographic data and refinement parameters for aldehyde C. Empirical formula C 39 H 27 NO 3 Fw 557.62 T (K) 100 crystal system Triclinic space group P a/å 8.5877(10) b/å 12.6416(14) c/å 14.4046(16) α/deg 109.408(3) β/deg 101.699(3) γ/deg 100.565(3) V/Å 3 1390.1(3) Z 2 ρcalcd (g cm -3 ) 1.332 μ(mo K) (mm -1 ) 0.084 λ/å 0.71073 F (000) 584.25 unique reflns 6471 GOF (F 2 ) 0.871 a R 1 0.0421 b wr 2 0.1222 [a] R 1 = Σ F o F c / Σ F o. [b] wr 2 = [Σ{w(F 2 o F 2 c ) 2 }/Σ{w(F 2 o ) 2 }] 1/2 S4

Figure S7: 1 H NMR spectrum of the cage CC1 recorded in CDCl 3. Figure S8: 13 C NMR spectrum of the cage CC1 recorded in CDCl 3. S5

Figure S9: 1 H- 1 H COSY NMR spectrum of the cage CC1 recorded in CDCl 3 Figure S10: 1 H- 13 C HMQC NMR spectrum of the cage CC1 recorded in CDCl 3. S6

Figure S11: FTIR spectrum of CC1. Figure S12: ESI-HRMS spectrum of CC1 recorded in CHCl 3 -CH 3 CN (1:1, v/v). S7

Figure S13: 1 H NMR spectrum of the cage CC1 r recorded in CDCl 3. Figure S14: 13 C NMR spectrum of the cage CC1 r recorded in CDCl 3. S8

Figure S15: 1 H- 1 H COSY NMR spectrum of the cage CC1 r recorded in CDCl 3. Figure S16: 1 H- 13 C HMQC NMR spectrum of the cage CC1 r recorded in CDCl 3. S9

Figure S17: FTIR spectrum of CC1 r. Figure S18: Molecular dimensions of CC1 r based on DFT calculation. S10

Scheme S1: Synthesis of CC2 r from tris(4-formylphenyl)amine (E) with (S, S)-1, 2- diaminocyclohexane (D) by employing dynamic imine chemistry followed by imine bond reduction. S11

Figure S19: 1 H NMR spectrum of CC2 recorded in CDCl 3. Figure S20: ESI-HRMS spectrum of CC2 recorded in CHCl 3 -MeOH. S12

Figure S21: 1 H NMR spectrum of CC2 r recorded in CDCl 3. Figure S22: ESI-HRMS spectrum of CC2 r recorded in CHCl 3 -MeOH. S13

Figure S23: Visual color changes during cage supported nanoparticle synthesis. (a) Pd@CC1 r and (b) Pd@CC2 r. Figure S24: PXRD pattern of Pd@CC1 r and CC1 r. S14

Figure S25: (a) SEM, (b) TEM, (c) particle size distribution and (d) XPS spectrum of Pd@CC2 r. Figure S26: PXRD pattern of Pd@CC2 r and CC2 r. S15

Figure S27: TEM image of as synthesized PDNPs in absence of cage compounds. Figure S28: TEM image and particle size distribution of (a) Pd@CC1 r and (b) Pd@CC2 r after 5 cycles. S16

Scheme S2: Schematic illustration of preparation of heterogeneous catalyst Pd@CC2 r. Figure S29: 1 H NMR spectrum of 4-formylbenzonitrile recorded in CDCl 3. S17

Figure S30: 13 C NMR spectrum of 4-formylbenzonitrile recorded in CDCl 3. Figure S31: 1 H NMR spectrum of 4-nitrolbenzonitrile recorded in CDCl 3 S18

Figure S32: 13 C NMR spectrum of 4-nitrolbenzonitrile recorded in CDCl 3. Figure S33: 1 H NMR spectrum of 4-cyanoacetophenon recorded in CDCl 3. S19

Figure S34: 13 C NMR spectrum of 4-cyanoacetophenon recorded in CDCl 3. Figure S35: 1 H NMR spectrum of 4-cyanobenzoic acid recorded in CD 3 OD. S20

Figure S36: 13 C NMR spectrum of 4-cyanobenzoic acid recorded in CD 3 OD. Figure S37: 1 H NMR spectrum of 5-cyanopyrimidine recorded in CDCl 3. S21

Figure S38: 13 C NMR spectrum of 5-cyanopyrimidine recorded in CDCl 3. Figure S39: 1 H NMR spectrum of 1,4-dicyanobenzene recorded in CDCl 3. S22

Figure S40: 13 C NMR spectrum of 1,4-dicyanobenzene recorded in CDCl 3. Figure S41: 1 H NMR spectrum of benzonitrile recorded in CDCl 3. S23

Figure S42: 13 C NMR spectrum of benzonitrile recorded in CDCl 3. Figure S43: 1 H NMR spectrum of 4-pyridinecarbonitrile recorded in CDCl 3. S24

Figure S44: 13 C NMR spectrum of 4-pyridinecarbonitrile recorded in CDCl 3. Figure S45: 1 H NMR spectrum of 3-pyridinecarbonitrile recorded in CDCl 3. S25

Figure S46: 13 C NMR spectrum of 3-pyridinecarbonitrile recorded in CDCl 3. Figure S47: 1 H NMR spectrum of 1,3,5-tricyanobenzene recorded in CDCl 3. S26

Figure S48: 1 H NMR spectrum of 1,3,5-tricyanobenzene recorded in DMSO-d 6. CC1 --------------------------------------------------------------------- Center Atomic Atomic Coordinates (Angstroms) Number Number Type X Y Z --------------------------------------------------------------------- 1 6 0 2.286527 7.547349-2.145456 2 6 0 1.737593 6.289158-2.417467 3 6 0 2.545984 5.135163-2.434512 4 6 0 3.924638 5.288205-2.188424 5 6 0 4.478870 6.544000-1.894630 6 6 0 3.646662 7.679495-1.871724 7 6 0 1.939660 3.796410-2.648585 8 6 0 2.406686 2.669219-1.944026 9 6 0 1.781446 1.428593-2.057380 10 6 0 0.667866 1.265449-2.901790 11 6 0 0.218448 2.372943-3.644704 12 6 0 0.839519 3.613767-3.511051 13 7 0-0.015183 0.013304-2.983206 14 6 0-1.441239-0.021882-2.906802 15 6 0 0.728666-1.203629-2.902483 16 6 0 1.918548-1.362186-3.636801 17 6 0 2.685731-2.517836-3.500168 18 6 0 2.291806-3.565534-2.642897 19 6 0 1.075504-3.412803-1.947848 20 6 0 0.310206-2.253713-2.064607 S27

21 6 0-2.143681 0.863224-2.068392 22 6 0-3.530764 0.780714-1.957139 23 6 0-4.269376-0.193105-2.658084 24 6 0-3.556840-1.055647-3.516064 25 6 0-2.171851-0.969688-3.647357 26 6 0 3.152803-4.755702-2.424134 27 6 0-5.731511-0.343359-2.444459 28 6 0 5.919117 6.666152-1.599332 29 6 0 4.555820-4.625803-2.401546 30 6 0 5.375628-5.726246-2.127354 31 6 0 4.815374-6.973388-1.857769 32 6 0 3.416665-7.133505-1.886640 33 6 0 2.601600-6.029464-2.181383 34 6 0-6.557357 0.770315-2.195116 35 6 0-7.921217 0.616818-1.900647 36 6 0-8.484020-0.673647-1.880714 37 6 0-7.685809-1.781816-2.158373 38 6 0-6.322418-1.622638-2.430905 39 7 0 6.406978 7.732684-1.072672 40 6 0 7.597230 2.104421 2.142374 41 6 0 6.326002 1.586542 2.414801 42 6 0 5.192215 2.423058 2.433908 43 6 0 5.379225 3.797679 2.188305 44 6 0 6.648040 4.320851 1.893977 45 6 0 7.762914 3.460998 1.869834 46 6 0 3.839324 1.849969 2.649875 47 6 0 2.720862 2.350062 1.954310 48 6 0 1.465630 1.754633 2.068352 49 6 0 1.278283 0.639408 2.905393 50 6 0 2.377532 0.157525 3.640396 51 6 0 3.632641 0.748503 3.505592 52 7 0 0.010491-0.013825 2.985757 53 6 0-0.058669-1.438327 2.905818 54 6 0-1.189004 0.757805 2.904425 55 6 0-1.323129 1.947361 3.644398 56 6 0-2.460841 2.741080 3.507927 57 6 0-3.513729 2.374852 2.644865 58 6 0-3.386417 1.158869 1.944571 59 6 0-2.245643 0.366457 2.061905 60 6 0 0.808347-2.159513 2.064347 61 6 0 0.693358-3.544059 1.950512 62 6 0-0.296440-4.261232 2.651524 63 6 0-1.141168-3.530348 3.511710 64 6 0-1.022813-2.147971 3.645533 65 6 0-4.683690 3.262880 2.425886 66 6 0-0.479525-5.719386 2.436860 67 6 0 6.805178 5.757899 1.599286 68 6 0-4.521984 4.662579 2.403393 69 6 0-5.603769 5.506890 2.128886 70 6 0-6.863288 4.974920 1.859202 71 6 0-7.054821 3.580293 1.887662 72 6 0-5.969312 2.740479 2.182873 73 6 0 0.615633-6.570377 2.189213 74 6 0 0.431621-7.930637 1.895419 S28

75 6 0-0.871242-8.464270 1.875209 76 6 0-1.961325-7.640908 2.150286 77 6 0-1.771698-6.281228 2.421647 78 6 0-8.380491 3.001603 1.598801 79 7 0 7.884477 6.219754 1.075696 80 7 0 1.453953-9.950515 1.070708 81 7 0-9.321653 3.707902 1.081044 82 6 0 2.613823-10.794870 0.754144 83 6 0 2.888757-10.707301-0.781659 84 6 0 3.883463-11.792210-1.247351 85 6 0-10.733497 2.861832-0.751561 86 6 0-10.639576 3.130571 0.785023 87 6 0-11.704746 4.145270 1.255072 88 6 0-13.128890 3.776230 0.808972 89 6 0-13.190849 3.615631-0.720232 90 6 0-12.181609 2.556194-1.191486 91 6 0 7.838904 7.852509-0.767257 92 6 0 8.038746 7.648151 0.768918 93 6 0 9.453042 8.069003 1.223703 94 6 0 9.839116 9.484497 0.764894 95 6 0 9.718337 9.608055-0.764238 96 6 0 8.293567 9.256196-1.222812 97 6 0-8.749881 1.799531-1.599411 98 6 0 1.595642-8.786355 1.597183 99 7 0-9.916208 1.683683-1.071317 100 6 0 2.809055-8.446494-1.598449 101 7 0 3.493747-9.401122-1.076247 102 6 0 3.481690-13.208827-0.805296 103 6 0 2.273964-12.235748 1.192106 104 6 0 3.311250-13.269133 0.723125 105 1 0 1.643472 8.421840-2.131128 106 1 0 0.669496 6.194224-2.583448 107 1 0 4.575104 4.418570-2.224739 108 1 0 4.089316 8.640506-1.637921 109 1 0 3.237908 2.774313-1.254709 110 1 0 2.136888 0.591312-1.468542 111 1 0-0.621363 2.255284-4.320281 112 1 0 0.478828 4.449512-4.102052 113 1 0 2.239197-0.573602-4.308190 114 1 0 3.594286-2.618644-4.085022 115 1 0 0.749242-4.187628-1.261982 116 1 0-0.597179-2.147193-1.482136 117 1 0-1.599626 1.593246-1.480970 118 1 0-4.040371 1.448780-1.270587 119 1 0-4.096955-1.790029-4.104852 120 1 0-1.647135-1.639828-4.319081 121 1 0 6.543377 5.795345-1.846264 122 1 0 5.003495-3.650982-2.564809 123 1 0 6.453794-5.601106-2.108695 124 1 0 5.429433-7.834730-1.622866 125 1 0 1.524166-6.163416-2.223527 126 1 0-6.133182 1.770054-2.229669 127 1 0-9.536936-0.775190-1.645592 128 1 0-8.118127-2.777519-2.146816 S29

129 1 0-5.703354-2.497697-2.599540 130 1 0 8.455378 1.439726 2.126761 131 1 0 6.205237 0.520853 2.579324 132 1 0 4.526168 4.469679 2.225958 133 1 0 8.734245 3.880061 1.635144 134 1 0 2.843317 3.183637 1.270678 135 1 0 0.635208 2.134364 1.485028 136 1 0 2.242175-0.683530 4.311070 137 1 0 4.461304 0.363670 4.091227 138 1 0-0.529223 2.246460 4.319523 139 1 0-2.543892 3.648755 4.096958 140 1 0-4.166017 0.853274 1.254638 141 1 0-2.158916-0.541442 1.476791 142 1 0 1.550690-1.631557 1.477614 143 1 0 1.348938-4.067784 1.262590 144 1 0-1.886485-4.054221 4.101515 145 1 0-1.679395-1.609223 4.319472 146 1 0 5.949526 6.402884 1.845770 147 1 0-3.537357 5.088016 2.567393 148 1 0-5.454587 6.582016 2.110397 149 1 0-7.710346 5.608692 1.624720 150 1 0-6.127617 1.666298 2.224839 151 1 0 1.624759-6.169170 2.225727 152 1 0-0.996044-9.515108 1.641935 153 1 0-2.966578-8.050540 2.138057 154 1 0-2.632806-5.642488 2.588397 155 1 0-8.512443 1.937964 1.844300 156 1 0 3.528034-10.446079 1.264876 157 1 0 1.917684-10.835513-1.290507 158 1 0 4.869037-11.538587-0.834347 159 1 0 3.977116-11.734236-2.339029 160 1 0-10.363885 3.769327-1.259797 161 1 0-10.786934 2.160556 1.290900 162 1 0-11.429736 5.127879 0.848671 163 1 0-11.646461 4.231026 2.347372 164 1 0-13.832831 4.548118 1.145242 165 1 0-13.440205 2.835025 1.286452 166 1 0-12.970557 4.582415-1.197240 167 1 0-14.201861 3.330428-1.037867 168 1 0-12.453342 1.573998-0.781875 169 1 0-12.200206 2.455693-2.283916 170 1 0 8.434753 7.074875-1.275856 171 1 0 7.275682 8.262894 1.276994 172 1 0 10.164275 7.338023 0.816193 173 1 0 9.507687 7.983027 2.316190 174 1 0 10.861993 9.712405 1.090824 175 1 0 9.182679 10.226904 1.243251 176 1 0 10.444098 8.933060-1.242242 177 1 0 9.971071 10.624843-1.090700 178 1 0 7.580139 9.985042-0.815402 179 1 0 8.208727 9.312253-2.315305 180 1 0-8.308329 2.777887-1.837809 181 1 0 2.583505-8.366508 1.835643 182 1 0 1.743758-8.556709-1.847135 S30

CC1 r 183 1 0 4.240252-13.928973-1.137409 184 1 0 2.536851-13.499474-1.288670 185 1 0 1.286925-12.484231 0.779451 186 1 0 2.170176-12.253093 2.284285 187 1 0 4.280817-13.073336 1.205270 188 1 0 3.000091-14.273534 1.037362 --------------------------------------------------------------------- --------------------------------------------------------------------- Center Atomic Atomic Coordinates (Angstroms) Number Number Type X Y Z --------------------------------------------------------------------- 1 6 0-3.994694 6.844664-3.014561 2 6 0-3.566571 5.529636-3.222203 3 6 0-2.195841 5.207778-3.206539 4 6 0-1.272773 6.250612-2.980914 5 6 0-1.691933 7.568976-2.765751 6 6 0-3.066811 7.860975-2.779049 7 6 0-1.745565 3.804664-3.391827 8 6 0-0.618570 3.297192-2.713609 9 6 0-0.230886 1.963201-2.838437 10 6 0-0.958259 1.084298-3.661423 11 6 0-2.066733 1.585904-4.368073 12 6 0-2.451861 2.917312-4.229451 13 7 0-0.611286-0.298173-3.761105 14 6 0-1.651617-1.275425-3.673415 15 6 0 0.750476-0.704373-3.864111 16 6 0 1.678557 0.056869-4.600292 17 6 0 3.011421-0.342113-4.688487 18 6 0 3.473628-1.521800-4.070257 19 6 0 2.531622-2.279342-3.345487 20 6 0 1.202100-1.878601-3.231682 21 6 0-2.674481-1.138695-2.717656 22 6 0-3.691151-2.086999-2.629497 23 6 0-3.724113-3.212078-3.477846 24 6 0-2.692006-3.338780-4.429690 25 6 0-1.676886-2.388120-4.533801 26 6 0 4.892559-1.949985-4.174885 27 6 0-4.799736-4.228122-3.355574 28 6 0-0.688957 8.673158-2.489222 29 6 0 5.658688-1.665111-5.321756 30 6 0 6.997952-2.059718-5.401069 31 6 0 7.597294-2.755630-4.348099 32 6 0 6.851289-3.067789-3.199911 33 6 0 5.516459-2.652590-3.123067 34 6 0-6.113087-3.850020-3.007609 35 6 0-7.134965-4.794366-2.849779 36 6 0-6.841967-6.154064-3.047675 37 6 0-5.551298-6.547075-3.410604 38 6 0-4.537045-5.595878-3.561023 39 7 0-0.920563 9.255901-1.161851 S31

40 6 0 3.977399 6.857376 3.001982 41 6 0 3.553342 5.541141 3.210404 42 6 0 2.183359 5.215990 3.200147 43 6 0 1.256789 6.256731 2.979301 44 6 0 1.671829 7.576310 2.763575 45 6 0 3.046044 7.871591 2.771212 46 6 0 1.737253 3.811671 3.386312 47 6 0 0.610088 3.301322 2.710579 48 6 0 0.226167 1.966312 2.836182 49 6 0 0.957522 1.089293 3.657675 50 6 0 2.066268 1.593788 4.361891 51 6 0 2.447735 2.926148 4.222311 52 7 0 0.614140-0.293951 3.758335 53 6 0 1.656869-1.268776 3.671593 54 6 0-0.746523-0.703737 3.862115 55 6 0-1.676287 0.054950 4.598802 56 6 0-3.007997-0.347724 4.687745 57 6 0-3.467279-1.528698 4.069791 58 6 0-2.523582-2.283663 3.344532 59 6 0-1.195245-1.879228 3.229983 60 6 0 2.679164-1.130858 2.715401 61 6 0 3.698105-2.076830 2.628296 62 6 0 3.733920-3.200700 3.478130 63 6 0 2.702288-3.328681 4.430310 64 6 0 1.684941-2.380296 4.533400 65 6 0-4.884962-1.960810 4.175195 66 6 0 4.812040-4.214251 3.357119 67 6 0 0.665080 8.678276 2.492286 68 6 0-5.651245-1.678132 5.322507 69 6 0-6.989346-2.076514 5.402548 70 6 0-7.587339-2.774053 4.349883 71 6 0-6.841110-3.084019 3.201256 72 6 0-5.507496-2.665065 3.123674 73 6 0 6.124585-3.833269 3.009308 74 6 0 7.148851-4.775272 2.852819 75 6 0 6.859076-6.135476 3.051890 76 6 0 5.569213-6.531304 3.414648 77 6 0 4.552586-5.582447 3.563759 78 6 0-7.461126-3.878919 2.059224 79 7 0 0.885155 9.257866 1.161381 80 7 0 8.735103-4.624426 0.989907 81 7 0-8.785377-3.394881 1.688793 82 6 0 10.001200-4.183837 0.387215 83 6 0 9.868944-4.219484-1.163988 84 6 0 11.212948-3.839559-1.828029 85 6 0-9.988830-4.210452-0.384066 86 6 0-9.856466-4.245578 1.167124 87 6 0-11.201613-3.869884 1.831225 88 6 0-12.376455-4.735746 1.339578 89 6 0-12.491340-4.698871-0.195172 90 6 0-11.159658-5.099509-0.854949 91 6 0-0.130135 10.434733-0.764326 92 6 0 0.087817 10.433388 0.767789 93 6 0 0.788959 11.730132 1.231641 S32

94 6 0 0.057252 13.003024 0.770229 95 6 0-0.112802 13.004522-0.760536 96 6 0-0.837927 11.729019-1.225073 97 6 0-8.522532-4.362865-2.420102 98 6 0 8.535487-4.340701 2.423251 99 7 0-8.721601-4.647617-0.986888 100 6 0 7.472926-3.861013-2.057609 101 7 0 8.795012-3.372442-1.685505 102 6 0 12.390402-4.701857-1.336331 103 6 0 11.174527-5.069554 0.858099 104 6 0 12.505054-4.664836 0.198431 105 1 0-5.056549 7.071119-3.020693 106 1 0-4.300380 4.742728-3.362009 107 1 0-0.208705 6.031422-2.991197 108 1 0-3.393825 8.877379-2.587142 109 1 0-0.065173 3.942340-2.038861 110 1 0 0.620731 1.591586-2.279749 111 1 0-2.621391 0.925244-5.024807 112 1 0-3.298337 3.282767-4.801525 113 1 0 1.353356 0.964796-5.095174 114 1 0 3.707939 0.281873-5.238859 115 1 0 2.839597-3.205199-2.871069 116 1 0 0.506514-2.479822-2.658218 117 1 0-2.658934-0.295314-2.036777 118 1 0-4.449308-1.975275-1.861287 119 1 0-2.703629-4.174297-5.122205 120 1 0-0.903896-2.498415-5.286132 121 1 0-0.802918 9.473773-3.232375 122 1 0 0.337828 8.277819-2.616408 123 1 0 5.200506-1.152721-6.161323 124 1 0 7.572086-1.831115-6.294048 125 1 0 8.639629-3.051790-4.398252 126 1 0 4.956944-2.857463-2.214591 127 1 0-6.346611-2.796425-2.881504 128 1 0-7.624070-6.893503-2.907878 129 1 0-5.328215-7.598628-3.562969 130 1 0-3.530284-5.917763-3.807004 131 1 0-1.019272 8.553859-0.435726 132 1 0 5.038713 7.086428 3.003839 133 1 0 4.289576 4.755870 3.346639 134 1 0 0.193319 6.034856 2.994042 135 1 0 3.369851 8.888938 2.578814 136 1 0 0.053537 3.945141 2.037145 137 1 0-0.625667 1.592524 2.279286 138 1 0 2.624034 0.934627 5.017488 139 1 0 3.294582 3.293828 4.792423 140 1 0-1.353317 0.963786 5.093478 141 1 0-3.705937 0.274336 5.238493 142 1 0-2.829238-3.210397 2.870332 143 1 0-0.498282-2.478543 2.656194 144 1 0 2.661444-0.288411 2.033420 145 1 0 4.455877-1.964306 1.859820 146 1 0 2.716054-4.163293 5.123877 147 1 0 0.912363-2.491448 5.286028 S33

148 1 0-0.360154 8.281916 2.628643 149 1 0 0.783946 9.480931 3.232361 150 1 0-5.194052-1.164489 6.161847 151 1 0-7.563622-1.849557 6.295857 152 1 0-8.628809-3.073134 4.400527 153 1 0-4.947932-2.868267 2.214850 154 1 0 6.355566-2.779218 2.882309 155 1 0 7.643034-6.873157 2.913177 156 1 0 5.348643-7.583257 3.567909 157 1 0 3.546512-5.906534 3.809661 158 1 0-7.576535-4.928530 2.365463 159 1 0-6.732567-3.890071 1.224690 160 1 0 0.974838 8.553080 0.436580 161 1 0 7.939832-4.294395 0.449051 162 1 0-8.865000-2.403788 1.502171 163 1 0 10.233607-3.131059 0.667542 164 1 0 9.616084-5.253999-1.437787 165 1 0 11.421355-2.779127-1.613710 166 1 0 11.094300-3.921702-2.914742 167 1 0-10.224181-3.158345-0.664464 168 1 0-9.600208-5.279231 1.441039 169 1 0-11.413310-2.810092 1.616964 170 1 0-11.082597-3.951672 2.917919 171 1 0-13.312290-4.397767 1.803493 172 1 0-12.222155-5.775775 1.664825 173 1 0-12.770317-3.683364-0.515460 174 1 0-13.294295-5.365750-0.534646 175 1 0-10.911211-6.141035-0.606349 176 1 0-11.253960-5.050050-1.947224 177 1 0 0.876335 10.398434-1.227677 178 1 0-0.918531 10.390996 1.231396 179 1 0 1.810306 11.715254 0.827292 180 1 0 0.885252 11.715692 2.325231 181 1 0 0.609924 13.893028 1.097571 182 1 0-0.934111 13.055606 1.245500 183 1 0 0.878321 13.063314-1.235600 184 1 0-0.669943 13.892561-1.085641 185 1 0-1.859270 11.707994-0.820948 186 1 0-0.934040 11.716285-2.318701 187 1 0-8.666307-3.290703-2.660592 188 1 0-9.275754-4.915319-2.993105 189 1 0 9.289891-4.891795 2.995998 190 1 0 8.677007-3.268324 2.664162 191 1 0-7.927025-4.316256-0.445867 192 1 0 7.592371-4.910071-2.364208 193 1 0 6.743573-3.875168-1.223824 194 1 0 8.871659-2.380891-1.500280 195 1 0 13.325250-4.360990-1.800127 196 1 0 12.239283-5.742316-1.661697 197 1 0 10.929186-6.111780 0.609333 198 1 0 11.268659-5.019980 1.950384 199 1 0 12.780926-3.648540 0.518896 200 1 0 13.309997-5.329336 0.537863 --------------------------------------------------------------------- S34

CC2 r --------------------------------------------------------------------- Center Atomic Atomic Coordinates (Angstroms) Number Number Type X Y Z --------------------------------------------------------------------- 1 7 0 2.178733-5.068327-3.492327 2 7 0 10.728286 0.000264-1.391636 3 7 0 2.409579 5.470176-2.916158 4 7 0-2.827658 7.411521 5.265377 5 7 0 6.614253-3.408725-7.929823 6 7 0 8.480526-1.197560-7.340873 7 7 0 9.940319 6.087211 0.770214 8 7 0 7.956442 7.805683-0.564738 9 7 0 2.981390 2.335310-8.530365 10 7 0 0.807338 0.514175-9.194755 11 7 0-2.828630 9.290837-2.088949 12 7 0-5.289899 9.081451-0.381228 13 6 0 3.028589-4.441602-4.449308 14 6 0 4.277995-4.988950-4.796047 15 6 0 5.097335-4.360345-5.735890 16 6 0 4.689445-3.193663-6.399263 17 6 0 3.433884-2.659757-6.061011 18 6 0 2.623447-3.253976-5.093293 19 6 0 10.351270-0.547226-2.653953 20 6 0 11.096122-1.589886-3.238396 21 6 0 10.740133-2.094092-4.489654 22 6 0 9.633973-1.589678-5.195645 23 6 0 8.885509-0.563214-4.597019 24 6 0 9.237306-0.044814-3.348729 25 6 0 11.126141-0.856867-0.320155 26 6 0 12.289056-0.577596 0.423058 27 6 0 12.681281-1.422461 1.460507 28 6 0 11.927425-2.560002 1.801969 29 6 0 10.760242-2.821331 1.069532 30 6 0 10.366698-1.988789 0.017168 31 6 0 10.648984 1.414052-1.176046 32 6 0 11.268078 2.309154-2.068310 33 6 0 11.186997 3.684781-1.853576 34 6 0 10.481064 4.213644-0.757645 35 6 0 9.861117 3.314001 0.123398 36 6 0 9.948193 1.932725-0.076097 37 6 0 3.518224 5.896074-2.128663 38 6 0 3.331634 6.344547-0.805950 39 6 0 4.416809 6.786926-0.046082 40 6 0 5.725380 6.769037-0.556868 41 6 0 5.906399 6.304542-1.870125 42 6 0 4.826406 5.892300-2.650758 43 6 0 2.574471 4.514319-3.967871 44 6 0 3.376607 3.369770-3.799698 45 6 0 3.556374 2.471990-4.854641 S35

46 6 0 2.919213 2.661126-6.092476 47 6 0 2.093851 3.787319-6.241047 48 6 0 1.933188 4.707449-5.205056 49 6 0 1.129323 6.102073-2.773218 50 6 0-0.031490 5.315798-2.669721 51 6 0-1.288134 5.919469-2.608170 52 6 0-1.425521 7.317168-2.644889 53 6 0-0.260923 8.098203-2.715745 54 6 0 1.001550 7.501841-2.781611 55 6 0-3.445844 8.105313 4.185883 56 6 0-4.573097 7.560742 3.538416 57 6 0-5.150078 8.213466 2.448553 58 6 0-4.619004 9.419086 1.957038 59 6 0-3.515270 9.971089 2.626174 60 6 0-2.943901 9.340162 3.731947 61 6 0 5.563679-2.508467-7.439486 62 6 0 9.272003-2.158783-6.558387 63 6 0 12.398668-3.451849 2.943702 64 6 0 10.389802 5.720922-0.578528 65 6 0 6.903921 7.228595 0.286489 66 6 0 3.103212 1.666176-7.227623 67 6 0-2.810389 7.945122-2.670078 68 6 0-5.188142 10.071855 0.714260 69 6 0 7.602333-2.962103-8.928191 70 6 0 8.085719-1.506746-8.727039 71 6 0 9.207169-1.190810-9.756223 72 6 0 8.192458-2.809496-11.426110 73 6 0 7.102881-3.140422-10.389121 74 6 0 9.801049 7.509042 1.140419 75 6 0 9.174807 8.383443 0.026937 76 6 0 10.969963 9.589053 2.103601 77 6 0 11.143777 8.144817 1.597656 78 6 0 3.021475 1.572074-9.786815 79 6 0 2.150300 0.293631-9.757977 80 6 0 2.127350-0.343537-11.175018 81 6 0 3.541735-0.691039-11.677202 82 6 0 4.457974 1.202797-10.251924 83 6 0-4.003488 10.163151-2.294027 84 6 0-5.352136 9.560088-1.774916 85 6 0-6.510254 10.555859-1.979503 86 6 0-5.305899 11.578172-3.971503 87 6 0-4.134496 10.597071-3.769436 88 7 0-3.631554-8.752796 2.751832 89 7 0 4.838687-0.518868 5.991492 90 7 0 3.895503-10.217264-0.057051 91 7 0 2.339243-10.921342 2.361697 92 7 0-3.438260-3.857752 7.042249 93 7 0-0.875144-2.777307 8.208461 94 7 0 10.249791-3.935819 5.655456 95 7 0 11.540648-4.627381 3.132342 96 7 0 5.907171 5.885168 6.022574 97 7 0 3.672846 7.378904 4.846675 98 6 0 2.692214-5.971041-2.510838 99 6 0 2.015932-7.174909-2.240182 S36

100 6 0 2.521818-8.083409-1.310719 101 6 0 3.727799-7.838232-0.634010 102 6 0 4.389067-6.625685-0.891546 103 6 0 3.876361-5.695540-1.799105 104 6 0-2.441077-9.460194 2.357979 105 6 0-2.353658-10.853203 2.498634 106 6 0-1.156584-11.514910 2.205069 107 6 0-0.030457-10.810420 1.752609 108 6 0-0.147566-9.420357 1.564829 109 6 0-1.331970-8.749742 1.872339 110 6 0-4.851093-8.973591 2.054894 111 6 0-6.089176-8.933931 2.724483 112 6 0-7.279071-9.112963 2.018369 113 6 0-7.282136-9.363332 0.637154 114 6 0-6.041504-9.435249-0.020452 115 6 0-4.844877-9.240098 0.670231 116 6 0-3.551773-7.878360 3.876786 117 6 0-2.689683-8.182284 4.946990 118 6 0-2.597677-7.326039 6.044890 119 6 0-3.370799-6.158490 6.128412 120 6 0-4.222654-5.852977 5.053444 121 6 0-4.304575-6.688278 3.938544 122 6 0 3.479547-0.849149 6.296223 123 6 0 2.432376-0.385155 5.479349 124 6 0 1.106725-0.665483 5.810012 125 6 0 0.785721-1.412401 6.956289 126 6 0 1.835355-1.900198 7.748926 127 6 0 3.166738-1.624001 7.425779 128 6 0 5.835001-1.544576 5.995597 129 6 0 5.600327-2.772646 5.353314 130 6 0 6.596494-3.752857 5.321860 131 6 0 7.847210-3.538352 5.920364 132 6 0 8.066703-2.315996 6.579050 133 6 0 7.076251-1.336137 6.625543 134 6 0 5.198717 0.835532 5.733403 135 6 0 6.251161 1.148215 4.849261 136 6 0 6.616106 2.475625 4.627251 137 6 0 5.931601 3.536513 5.242847 138 6 0 4.869195 3.221160 6.103381 139 6 0 4.515496 1.895154 6.359887 140 6 0-1.412097 7.436105 5.449297 141 6 0-0.537617 7.490529 4.347106 142 6 0 0.841750 7.575009 4.537127 143 6 0 1.399505 7.569223 5.824465 144 6 0 0.527097 7.458798 6.919106 145 6 0-0.857513 7.407104 6.743044 146 6 0 4.303256-8.862146 0.334194 147 6 0 1.295824-11.503152 1.496547 148 6 0-8.582903-9.527070-0.119201 149 6 0-3.308399-5.285665 7.367123 150 6 0-0.671185-1.614306 7.342791 151 6 0 8.945409-4.587672 5.861123 152 6 0 6.324980 4.975055 4.948479 153 6 0 2.896213 7.740814 6.040298 S37

154 6 0 4.273200-11.394749 0.739963 155 6 0 3.740511-11.331884 2.203693 156 6 0 4.013591-12.683776 2.905003 157 6 0 6.084604-13.047040 1.463091 158 6 0 5.791904-11.713933 0.747370 159 6 0-3.423836-2.873025 8.142287 160 6 0-2.114734-2.895586 8.998392 161 6 0-2.167528-1.835476 10.120188 162 6 0-4.673068-3.016469 9.037559 163 6 0 11.486764-4.732119 5.638062 164 6 0 11.739618-5.503124 4.306533 165 6 0 13.119755-6.208258 4.352562 166 6 0 13.241360-7.151233 5.565998 167 6 0 11.588251-5.695231 6.837601 168 6 0 6.026705 7.342818 5.838866 169 6 0 5.061862 7.852685 4.725469 170 6 0 5.133030 9.391082 4.612764 171 6 0 7.533143 9.378143 5.455292 172 6 0 7.471503 7.843508 5.577383 173 7 0-5.064245 1.817956-6.836972 174 7 0-8.450669-0.123857 1.148770 175 7 0-4.157850-5.095254-5.185030 176 7 0-6.882334-3.962847-4.570170 177 7 0-7.761301 7.201583-4.301825 178 7 0-9.190740 4.777884-3.139422 179 7 0-10.349437-6.173431-0.349734 180 7 0-8.687466-8.533655-1.213793 181 7 0-7.919458 1.568584 7.383268 182 7 0-5.849568 2.923390 8.922125 183 6 0 0.749488-4.983498-3.630631 184 6 0 0.111643-5.340881-4.829640 185 6 0-1.284096-5.343951-4.913834 186 6 0-2.072412-4.996047-3.807181 187 6 0-1.426504-4.602598-2.622812 188 6 0-0.034047-4.594809-2.531086 189 6 0-5.676322 0.559462-6.572265 190 6 0-5.450436-0.525679-7.440675 191 6 0-6.021074-1.771196-7.180175 192 6 0-6.850469-1.979736-6.066661 193 6 0-7.078759-0.890492-5.205639 194 6 0-6.495118 0.355671-5.442255 195 6 0-3.786441 1.830035-7.501376 196 6 0-3.646486 2.417627-8.769205 197 6 0-2.418760 2.365978-9.432949 198 6 0-1.304292 1.737958-8.851153 199 6 0-1.448815 1.173799-7.572454 200 6 0-2.674799 1.217131-6.904367 201 6 0-5.706546 3.054903-6.552043 202 6 0-7.104900 3.199142-6.648682 203 6 0-7.707987 4.431080-6.386994 204 6 0-6.949927 5.563334-6.039452 205 6 0-5.554248 5.412246-5.963095 206 6 0-4.938751 4.183244-6.202351 207 6 0-8.459383 1.070286 0.366085 S38

208 6 0-7.526049 2.093312 0.621972 209 6 0-7.572440 3.287921-0.097610 210 6 0-8.535653 3.501136-1.097307 211 6 0-9.437067 2.462883-1.376709 212 6 0-9.407293 1.266522-0.656312 213 6 0-8.796338-1.379744 0.559866 214 6 0-8.233613-1.775998-0.668239 215 6 0-8.588884-2.993942-1.251147 216 6 0-9.512237-3.851302-0.625888 217 6 0-10.059164-3.459934 0.605829 218 6 0-9.709577-2.241570 1.193047 219 6 0-8.256825-0.035700 2.565076 220 6 0-7.409370-0.939875 3.230694 221 6 0-7.224319-0.846866 4.612596 222 6 0-7.873632 0.143846 5.367633 223 6 0-8.715682 1.044531 4.696096 224 6 0-8.909357 0.957411 3.316961 225 6 0-3.647382 6.637263 6.154881 226 6 0-3.477624 5.249655 6.262576 227 6 0-4.299178 4.499080 7.111171 228 6 0-5.294233 5.118202 7.881441 229 6 0-5.450553 6.512164 7.775373 230 6 0-4.646403 7.264386 6.920002 231 6 0-3.591113-5.111832-3.835221 232 6 0-7.451404-3.342527-5.797551 233 6 0 0.021893 1.689515-9.591436 234 6 0-7.592336 6.908269-5.745673 235 6 0-8.640389 4.855220-1.784141 236 6 0-9.930511-5.142710-1.309233 237 6 0-7.709309 0.205428 6.880585 238 6 0-6.217812 4.339354 8.807601 239 6 0-5.404265-5.831195-5.474896 240 6 0-6.616008-5.417997-4.574657 241 6 0-7.881018-6.217734-4.945242 242 6 0-7.638527-7.738701-4.892397 243 6 0-5.178631-7.358248-5.421608 244 6 0-9.100828 7.273670-3.687615 245 6 0-9.909023 5.932702-3.707360 246 6 0-11.295028 8.584956-3.596188 247 6 0-9.928853 8.429595-4.289893 248 6 0-10.953244-7.428774-0.837466 249 6 0-10.023736-8.259668-1.785083 250 6 0-10.713041-9.561321-2.239688 251 6 0-12.994955-8.481282-1.957225 252 6 0-12.320395-7.171113-1.506985 253 6 0-8.103300 1.835302 8.819051 254 6 0-6.768759 1.989623 9.610776 255 6 0-7.054002 2.357551 11.089549 256 6 0-9.304905 1.188592 10.972428 257 6 0-9.019471 0.804014 9.507903 258 6 0 12.957602-6.401207 6.882238 259 6 0 5.511389-13.049363 2.893593 260 6 0-3.421552-1.995277 11.000623 261 6 0-7.994299 1.342294 11.767605 S39

262 6 0 8.971288 9.829784 0.558333 263 6 0 10.288711 10.467266 1.038205 264 6 0 6.571097 9.884132 4.363693 265 6 0-11.289223 6.108802-3.033189 266 6 0-12.094731 7.269697-3.645742 267 6 0-6.629770 10.981217-3.455489 268 6 0-6.453390-8.140729-5.791070 269 6 0-12.077139-9.284228-2.899462 270 6 0 4.461711 0.543443-11.644766 271 6 0 8.743518-1.388042-11.211428 272 6 0-4.705530-1.951560 10.150403 273 1 0 6.248562-4.329071-8.163991 274 1 0 8.858540-0.254740-7.271739 275 1 0 10.445397 5.573870 1.490262 276 1 0 7.567716 8.416572-1.280073 277 1 0 3.547127 3.179244-8.581938 278 1 0 0.253277-0.339534-9.207329 279 1 0-2.486474 9.304542-1.132684 280 1 0-4.603088 8.340719-0.267526 281 1 0 4.613516-5.906383-4.328611 282 1 0 6.069488-4.782833-5.962376 283 1 0 3.086186-1.754158-6.553129 284 1 0 1.669204-2.807015-4.839794 285 1 0 11.961918-1.983135-2.716912 286 1 0 11.343378-2.881669-4.934772 287 1 0 8.011275-0.180364-5.111090 288 1 0 8.647277 0.749132-2.904452 289 1 0 12.882488 0.295048 0.172320 290 1 0 13.593257-1.199648 2.009630 291 1 0 10.135651-3.662925 1.345552 292 1 0 9.460736-2.205288-0.538595 293 1 0 11.815887 1.917175-2.918625 294 1 0 11.686547 4.360962-2.543192 295 1 0 9.282992 3.702683 0.953967 296 1 0 9.458625 1.250398 0.610724 297 1 0 2.334861 6.354841-0.380142 298 1 0 4.238504 7.144223 0.965545 299 1 0 6.907800 6.283172-2.285415 300 1 0 4.997326 5.562105-3.668366 301 1 0 3.870982 3.196973-2.850504 302 1 0 4.196557 1.605734-4.708269 303 1 0 1.592806 3.947026-7.188776 304 1 0 1.310613 5.582498-5.352100 305 1 0 0.060677 4.235556-2.646123 306 1 0-2.175080 5.295882-2.528374 307 1 0-0.360746 9.177751-2.737628 308 1 0 1.891560 8.117356-2.856684 309 1 0-4.981229 6.616791 3.880860 310 1 0-6.003493 7.768420 1.946729 311 1 0-3.094117 10.910612 2.278026 312 1 0-2.092452 9.788583 4.229891 313 1 0 4.902501-2.120005-8.241169 314 1 0 6.069105-1.642414-6.995017 315 1 0 10.209106-2.470947-7.059829 S40

316 1 0 8.656986-3.059937-6.442304 317 1 0 12.385118-2.868837 3.873953 318 1 0 13.462174-3.706590 2.768690 319 1 0 11.370613 6.158864-0.851590 320 1 0 9.651441 6.130167-1.278608 321 1 0 6.524890 7.926434 1.058645 322 1 0 7.351878 6.377011 0.814229 323 1 0 4.066936 1.141721-7.082685 324 1 0 2.311922 0.907414-7.186191 325 1 0-3.139506 8.034702-3.714224 326 1 0-3.520208 7.239703-2.194674 327 1 0-6.190325 10.476168 0.914259 328 1 0-4.552695 10.937467 0.455255 329 1 0 8.480459-3.617606-8.807857 330 1 0 7.236497-0.842770-8.959211 331 1 0 10.073980-1.836560-9.551424 332 1 0 9.540081-0.154911-9.602775 333 1 0 7.795209-2.918538-12.443408 334 1 0 9.014362-3.535112-11.329874 335 1 0 6.226187-2.495595-10.550111 336 1 0 6.761729-4.177046-10.518108 337 1 0 9.118463 7.536447 2.005883 338 1 0 9.909952 8.445505-0.791917 339 1 0 11.942604 10.011983 2.385956 340 1 0 10.353659 9.581826 3.015837 341 1 0 11.853457 8.128349 0.756897 342 1 0 11.576198 7.517220 2.389435 343 1 0 2.600369 2.238195-10.557926 344 1 0 2.645504-0.429583-9.089654 345 1 0 1.643059 0.352319-11.876258 346 1 0 1.504977-1.248572-11.143884 347 1 0 3.493789-1.107131-12.691706 348 1 0 3.967337-1.477359-11.034908 349 1 0 4.913818 0.524566-9.515095 350 1 0 5.068769 2.116060-10.264027 351 1 0-3.793449 11.069186-1.706301 352 1 0-5.576311 8.674891-2.389659 353 1 0-6.344773 11.449338-1.358527 354 1 0-7.440438 10.091261-1.630382 355 1 0-5.394515 11.841017-5.033770 356 1 0-5.093372 12.514659-3.432894 357 1 0-4.304438 9.713868-4.402811 358 1 0-3.185251 11.041766-4.090596 359 1 0 4.031313-10.373105-1.052705 360 1 0 2.236211-9.915817 2.441029 361 1 0-2.830126-3.590305 6.272877 362 1 0-0.589874-3.648231 7.771933 363 1 0 10.210547-3.339588 4.830956 364 1 0 11.444046-5.166942 2.275966 365 1 0 6.241551 5.577344 6.931654 366 1 0 3.617935 6.377122 4.678424 367 1 0 1.099375-7.403459-2.771168 368 1 0 1.997622-9.014613-1.128398 369 1 0 5.320264-6.402041-0.376996 S41

370 1 0 4.403685-4.765080-1.975977 371 1 0-3.211983-11.405300 2.866808 372 1 0-1.089350-12.588548 2.354673 373 1 0 0.692639-8.855528 1.170195 374 1 0-1.406420-7.674940 1.745828 375 1 0-6.116961-8.751688 3.792048 376 1 0-8.223398-9.066821 2.554542 377 1 0-6.019550-9.623606-1.089319 378 1 0-3.900016-9.281807 0.140334 379 1 0-2.093063-9.086244 4.915115 380 1 0-1.921506-7.579927 6.857255 381 1 0-4.809632-4.941647 5.094092 382 1 0-4.956735-6.423754 3.114257 383 1 0 2.665583 0.197428 4.594938 384 1 0 0.309447-0.299633 5.167561 385 1 0 1.592156-2.478906 8.632970 386 1 0 3.969267-1.990884 8.056735 387 1 0 4.649369-2.943262 4.860614 388 1 0 6.406517-4.686587 4.798692 389 1 0 9.032539-2.141346 7.039643 390 1 0 7.262339-0.397609 7.135833 391 1 0 6.785983 0.349967 4.348488 392 1 0 7.441169 2.690085 3.952341 393 1 0 4.329971 4.028561 6.586169 394 1 0 3.706806 1.677808 7.047759 395 1 0-0.941978 7.482822 3.341646 396 1 0 1.511197 7.638778 3.687035 397 1 0 0.932162 7.434486 7.928076 398 1 0-1.512614 7.351948 7.605261 399 1 0 5.399112-8.720331 0.387616 400 1 0 3.925778-8.673534 1.349743 401 1 0 1.196416-12.572211 1.719742 402 1 0 1.553646-11.411998 0.427122 403 1 0-9.414316-9.455538 0.604035 404 1 0-8.642366-10.531404-0.558851 405 1 0-4.133986-5.551303 8.041423 406 1 0-2.379718-5.533530 7.916697 407 1 0-1.010914-0.728771 7.896164 408 1 0-1.277518-1.633725 6.415565 409 1 0 8.982472-5.134255 6.812114 410 1 0 8.686393-5.330825 5.083206 411 1 0 7.410724 5.005770 4.739462 412 1 0 5.836235 5.302949 4.020027 413 1 0 3.095955 8.796960 6.262494 414 1 0 3.200146 7.175009 6.939820 415 1 0 3.768678-12.242044 0.249618 416 1 0 4.327684-10.571019 2.740490 417 1 0 3.438161-13.476228 2.402700 418 1 0 3.634201-12.617366 3.930516 419 1 0 7.165214-13.239342 1.483697 420 1 0 5.630268-13.869705 0.889836 421 1 0 6.335054-10.898939 1.249255 422 1 0 6.158973-11.748991-0.288104 423 1 0-3.482343-1.888022 7.655295 S42

424 1 0-2.055135-3.878421 9.488053 425 1 0-2.173239-0.827658 9.679007 426 1 0-1.251526-1.914025 10.716809 427 1 0-4.682277-4.012162 9.504605 428 1 0-5.565713-2.954597 8.403954 429 1 0 12.308138-4.006722 5.751447 430 1 0 10.964811-6.280206 4.222092 431 1 0 13.913085-5.447645 4.403909 432 1 0 13.275487-6.764736 3.417671 433 1 0 14.239059-7.608059 5.593205 434 1 0 12.520571-7.976154 5.457615 435 1 0 10.799931-6.458771 6.771548 436 1 0 11.411501-5.129263 7.760286 437 1 0 5.688499 7.784789 6.788422 438 1 0 5.420477 7.450457 3.765629 439 1 0 4.761202 9.852141 5.539141 440 1 0 4.462017 9.710169 3.807169 441 1 0 8.560535 9.701438 5.240690 442 1 0 7.256793 9.831540 6.419641 443 1 0 7.850357 7.391771 4.647875 444 1 0 8.127726 7.495536 6.387493 445 1 0-4.107568-4.186868-5.633668 446 1 0-6.081472-3.437136-4.230774 447 1 0-7.084319 6.716058-3.723631 448 1 0-8.565386 4.328538-3.800230 449 1 0-9.665193-6.318441 0.386740 450 1 0-8.200422-7.673378-0.974087 451 1 0-7.230542 2.210076 6.995868 452 1 0-4.888576 2.804512 9.232862 453 1 0 0.711773-5.634732-5.684369 454 1 0-1.783545-5.638896-5.829815 455 1 0-2.019788-4.304190-1.761885 456 1 0 0.456637-4.300623-1.609567 457 1 0-4.830117-0.388330-8.318090 458 1 0-5.835705-2.591386-7.869155 459 1 0-7.713636-1.020984-4.333874 460 1 0-6.673855 1.172535-4.752703 461 1 0-4.504593 2.890721-9.234836 462 1 0-2.329739 2.801454-10.424794 463 1 0-0.589542 0.703985-7.108433 464 1 0-2.779816 0.772071-5.920564 465 1 0-7.713969 2.351711-6.940859 466 1 0-8.786957 4.518821-6.486846 467 1 0-4.937343 6.272134-5.713918 468 1 0-3.861105 4.093030-6.129533 469 1 0-6.774160 1.948693 1.389615 470 1 0-6.846577 4.067475 0.121709 471 1 0-10.173851 2.614983-2.157752 472 1 0-10.129689 0.487101-0.871386 473 1 0-7.514511-1.126536-1.156170 474 1 0-8.139393-3.285667-2.199463 475 1 0-10.774861-4.114628 1.091119 476 1 0-10.151330-1.946764 2.138554 477 1 0-6.893091-1.703423 2.658942 S43

478 1 0-6.555111-1.546814 5.107856 479 1 0-9.218362 1.810158 5.275728 480 1 0-9.568120 1.657424 2.814882 481 1 0-2.712036 4.762046 5.668369 482 1 0-4.190287 3.421670 7.154261 483 1 0-6.209827 7.012669 8.371415 484 1 0-4.779417 8.337906 6.839047 485 1 0-3.867005-6.069361-3.374839 486 1 0-4.013025-4.334956-3.169269 487 1 0-8.540773-3.261753-5.685318 488 1 0-7.274347-3.972651-6.681755 489 1 0-0.185404 1.743157-10.677784 490 1 0 0.621109 2.571389-9.333566 491 1 0-6.979398 7.697692-6.203319 492 1 0-8.572212 6.957553-6.231469 493 1 0-9.312183 5.492001-1.192891 494 1 0-7.650379 5.349811-1.735991 495 1 0-10.783828-4.937767-1.969680 496 1 0-9.107230-5.460974-1.976379 497 1 0-8.462887-0.445961 7.339363 498 1 0-6.725797-0.228473 7.149407 499 1 0-6.254574 4.865091 9.780710 500 1 0-7.237885 4.388957 8.405169 501 1 0-5.657285-5.575071-6.514482 502 1 0-6.352772-5.677738-3.538011 503 1 0-8.203602-5.945337-5.960888 504 1 0-8.692935-5.926013-4.267947 505 1 0-8.547019-8.269063-5.207370 506 1 0-7.443819-8.049505-3.855491 507 1 0-4.865544-7.650555-4.408380 508 1 0-4.350213-7.611649-6.093219 509 1 0-8.916097 7.523514-2.632113 510 1 0-10.093403 5.675798-4.761352 511 1 0-11.864022 9.397866-4.065893 512 1 0-11.139722 8.875281-2.545949 513 1 0-10.096908 8.245119-5.361870 514 1 0-9.343561 9.353339-4.216467 515 1 0-11.139587-8.031968 0.063588 516 1 0-9.847286-7.650521-2.683713 517 1 0-10.869438-10.218456-1.371747 518 1 0-10.044958-10.095011-2.926987 519 1 0-13.949696-8.260233-2.451811 520 1 0-13.233099-9.093721-1.074165 521 1 0-12.184539-6.527032-2.387970 522 1 0-12.955833-6.618824-0.805060 523 1 0-8.626622 2.803141 8.883075 524 1 0-6.259953 1.014252 9.591406 525 1 0-7.516078 3.355165 11.130014 526 1 0-6.103720 2.427139 11.637229 527 1 0-9.947041 0.430597 11.438795 528 1 0-9.862883 2.136395 11.001810 529 1 0-8.544670-0.187424 9.494829 530 1 0-9.952895 0.721864 8.937794 531 1 0 13.748087-5.655417 7.054105 S44

532 1 0 12.991983-7.096430 7.730839 533 1 0 5.665051-14.029571 3.363437 534 1 0 6.064068-12.319087 3.504528 535 1 0-3.444038-1.211322 11.768668 536 1 0-3.373981-2.956661 11.534339 537 1 0-8.205451 1.652688 12.799086 538 1 0-7.492399 0.364498 11.829924 539 1 0 8.243212 9.813960 1.382407 540 1 0 8.528037 10.436488-0.243398 541 1 0 10.966455 10.584384 0.178809 542 1 0 10.103155 11.474875 1.431635 543 1 0 6.588634 10.980681 4.317676 544 1 0 6.915163 9.522809 3.382486 545 1 0-11.151091 6.301863-1.958934 546 1 0-11.835379 5.162081-3.114279 547 1 0-12.338768 7.033584-4.693117 548 1 0-13.051397 7.382681-3.119296 549 1 0-7.444178 11.708632-3.571711 550 1 0-6.896979 10.100138-4.056775 551 1 0-6.710438-7.939699-6.842760 552 1 0-6.266140-9.219557-5.714885 553 1 0-12.554981-10.230698-3.183677 554 1 0-11.925473-8.715695-3.829468 555 1 0 4.113929 1.274188-12.390714 556 1 0 5.484587 0.266409-11.932178 557 1 0 9.570532-1.187645-11.904570 558 1 0 7.955439-0.654696-11.442611 559 1 0-5.589733-2.098276 10.784499 560 1 0-4.805069-0.953303 9.696389 --------------------------------------------------------------------- S45