SPEKTRUM HASIL ANALISA GC-MS METIL ESTER

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Spectrum pada RT = 18.685menit 1 74 53 59 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 Hit 1. (replib) Hexadecanoic acid, methyl ester Hexadecanoic acid, methyl ester Lib : A MAMER, MCGILL UNIVERSITY, MNTREAL, CANADA 1 Hexadecanoic acid, methyl ester Lib : Chuck Anderson, Aldrich Chemical Co. Hexadecanoic acid, methyl ester Mass Spectrometry Data Center Hexadecanoic acid, methyl ester 59 74 Pentadecanoic acid, 14-methyl-, methyl ester 87 87 93 11 17 115 121 125 129 135 139 143 153 1 1 171 185 191 199 213 227 239 27 93 11 17 115 121 125 129 135 139 143 145 149 153 1 163 1 171 185 194 199 213 227 239 27 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 Hit 2. (replib) Hexadecanoic acid, methyl ester 1 51 59 74 87 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 Hit 3. (mainlib) Hexadecanoic acid, methyl ester 1 51 59 74 87 93 11 15 115 121 125 129 143 135 139 145 149 153 1 163 1 171 177 1 185 191 1 199 29 213 219 223 227 239 27 243 93 11 17 115 121 125 129 143 135 139 149 153 1 163 171 185 194 199 213 219 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 Hit 4. (replib) Hexadecanoic acid, methyl ester 1 59 62 74 87 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 Hit 5. (mainlib) Pentadecanoic acid, 14-methyl-, methyl ester 92 11 15 19 113 117 129 143 147 1 171 185 199 213 227 239 27 227 239 27 47

Spectrum pada RT = 19.3menit 1 124 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 1. (mainlib) Cholest-4-en-3-one Cholestenone Mass Spectrometry Data Center 1 Cholesterone Cholestenone Linolenin, 1-mono- 17 121 71 17 121 124 135 147 135 147 159 1 187 193 21 211 217 229 159 1 187 21 215 Cholestenone Lib : Div. of Experiment Therapeutics WRAIR, WRAMC, Washington DC 237 229 245 252 2 271 2 288 299 313 327 342 351 3 3 384 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 2. (replib) Cholest-5-en-3-one 1 245 2 271 278 29 299 36 313 32 327 333 342 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 3. (replib) Cholest-4-en-3-one 1 53 63 17 121 124 135 147 159 166 175 187 193 21 211 217 224 229 245 2 271 2 288 299 311 327 352 359 3 376 342 349 3 3 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 4. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- 1 53 71 19 17 121 135 1 1 1 191 23 21 217 224 231 237 245 2 277 291 39 321 335 352 121 124 135 147 159 166 1 187 193 2 27 214 22 229 245 253 2 271 2 299 314 327 342 351 3 384 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 5. (replib) Cholest-4-en-3-one 384 384 C27H44 H H 48

Spectrum pada RT = 2.331menit SPEKTRUM HASIL ANALISA GC-MS METIL ESTER 1 65 74 87 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 Hit 1. (replib) 9-ctadecenoic acid (Z)-, methyl ester leic acid, methyl ester Lib : RADIAN CRP 1 65 74 87 Elaidic acid, methyl ester Mass Spectrometry Data Center trans-13-ctadecenoic acid, methyl ester Mass Spectrometry Data Center 11-ctadecenoic acid, methyl ester Mass Spectrometry Data Center cis-13-ctadecenoic acid, methyl ester Mass Spectrometry Data Center 93 96 11 11 11 115 123 128 137 151 1 166 175 18 193 199 27 213 222 235 296 11 115 123 128 137 152 1 166 18 185 19 1 2 25 21 215 222 227 233 239 245 2 2 278 296 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 Hit 2. (replib) 9-ctadecenoic acid, methyl ester, (E)- 1 74 87 11 123 128 137 152 1 166 171 18 185 19 1 2 25 21 215 222 227 235 241 246 253 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 Hit 3. (mainlib) trans-13-ctadecenoic acid, methyl ester 1 278 296 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 Hit 4. (replib) 11-ctadecenoic acid, methyl ester 1 59 63 74 87 93 74 87 11 11 11 115 123 128 137 152 1 166 171 18 185 19 1 2 25 21 215 222 227 235 241 246 253 123 128 137 152 1 166 171 18 185 19 1 2 25 21 215 222 227 233 239 245 2 2 278 296 278 296 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 Hit 5. (mainlib) cis-13-ctadecenoic acid, methyl ester C19H362 49

Spectrum pada RT = 21.626menit 1 53 6 74 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 Hit 1. (mainlib) Hexadecanoic acid, 2-hydroxy-1-(hydroxymethyl)ethyl ester Palmitin, 2-mono- 1 6 Palmitin, 1-mono- 84 2,3-Dihydroxypropyl palmitate Lib : Japan AIST/NIMC Database- Spectrum MS-NW-5623 Palmitoyl chloride Mass Spectrometry Data Center 87 74 84 87 Dipalmitin Lib : R.T.HLMAN,UNIVERSITY F MINNESTA 11 112 112 123 134 134 143 154 168 176 182 194 29 221 227 143 154 171 185 194 213 22 227 239 2 27 299 311 33 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 Hit 2. (mainlib) Hexadecanoic acid, 2,3-dihydroxypropyl ester 1 74 84 239 256 27 299 312 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 Hit 3. (mainlib) Hexadecanoic acid, 2,3-dihydroxypropyl ester, (±)- 1 112 134 14 147 154 163 1 175 182 189 1 21 29 218 225 239 256 27 2 299 311 329 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 Hit 4. (mainlib) Palmitoyl chloride 1 6 84 87 91 112 116 125 125 129 139 154 168 182 1 29 22 135 141 149 1 163 171 177 185 194 2 26 213 219 227 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 Hit 5. (mainlib) Hexadecanoic acid, 1-(hydroxymethyl)-1,2-ethanediyl ester 239 239 248 H H Cl H H H H 256 262 268 274 28 286 292 299 35 313 325 331 34 354 3 3 38 41 49 H

Spectrum pada RT = 23.32 menit 1 71 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 1. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- Linolenin, 1-mono- 1 Linoleoyl chloride Lib : RADIAN CRP E,E,Z-1,3,12-Nonadecatriene-5,14-diol Lib : J. Klune, Insect Chem. Ecol. Lab., USDA, Beltsville, MD 275 Linolein, 1-mono- 19 121 135 1 1 1 191 23 21 217 224 231 237 245 2 277 291 39 321 335 352 Cl 59 74 19 121 135 141 151 159 166 1 18 187 193 25 214 22 235 262 294 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 2. (replib) 9,12-ctadecadienoyl chloride, (Z,Z)- 1 85 91 19 121 135 149 163 177 1 191 1 25 219 225 237 244 251 262 277 294 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 3. (mainlib) E,E,Z-1,3,12-Nonadecatriene-5,14-diol 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 4. (mainlib) 9,12-ctadecadienoic acid (Z,Z)-, 2,3-dihydroxypropyl ester 1 59 71 19 19 121 121 135 149 156 164 177 1 191 199 25 213 22 227 234 241 247 2 Cyclopropaneoctanoic acid, 2-[[2-[(2-ethylcyclopropyl)methyl]cyclopropyl]methyl]-, methyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA 262 28 H 2 35 321 336 354 135 143 149 1 163 177 185 192 25 224 235 249 263 277 289 33 334 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 5. (mainlib) Cyclopropaneoctanoic acid, 2-[[2-[(2-ethylcyclopropyl)methyl]cyclopropyl]methyl]-, methyl ester H H H H H 51

Spectrum pada RT = 23.77 menit 1 6 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 1. (replib) 9-ctadecenoic acid (Z)-, 2,3-dihydroxypropyl ester lein, 1-mono- 1 59 leic acid, 3-hydroxypropyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA lein, 2-mono- 93 93 2,3-Dihydroxypropyl elaidate Lib : Japan AIST/NIMC Database- Spectrum MS-IW-486 leic anhydride Lib : Japan AIST/NIMC Database- Spectrum MS-IW-4184 123 129 137 151 165 176 1 191 199 27 221 235 246 253 19 123 137 151 165 18 193 27 221 235 246 282 325 338 356 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 2. (mainlib) leic acid, 3-hydroxypropyl ester 1 93 19 123 129 137 151 165 171 1 185 193 27 221 227 235 245 253 H 282 39 322 34 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 3. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester 1 2 2 37 325 338 354 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 4. (mainlib) 2,3-Dihydroxypropyl elaidate 1 6 6 93 123 129 137 151 166 18 193 2 27 214 221 227 235 246 252 259 123 137 151 158 165 171 18 187 193 2 27 214 221 227 235 247 254 274 282 2 37 325 337 354 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 Hit 5. (mainlib) leic anhydride C21H44 C21H44 H H 282 291 36 319 333 347 39 43 416 429 52

Spectrum pada RT = 23.22 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- Linolenin, 1-mono- 1 lein, 2-mono- Nonanoic acid, 9-(3-hexenylidenecyclopropylidene)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester, (Z,Z,Z)- cis-8,11,14-eicosatrienoic Acid Lib : R.T.HLMAN,UNIVERSITY F MINNESTA Linoleic acid Lib : SHRADER 19 19 123 121 135 1 163 1 191 23 211 219 227 235 243 2 277 291 39 321 335 352 137 151 165 1 193 27 221 235 245 253 2 2 37 325 338 354 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (mainlib) Nonanoic acid, 9-(3-hexenylidenecyclopropylidene)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester, (Z,Z,Z)- 1 18 121 135 149 163 1 191 24 213 222 232 241 249 2 278 296 37 321 334 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (replib) 8,11,14-Eicosatrienoic acid, (Z,Z,Z)- 1 6 6 93 17 121 135 1 19 163 177 185 193 28 217 231 249 288 36 H 123 137 149 1 165 1 1 191 199 27 22 235 251 262 28 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (replib) 9,12-ctadecadienoic acid (Z,Z)- 352 H H C18H322 C21H44 H H 53

Spectrum pada RT = 23.2 menit 1 6 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 1. (replib) leic Acid leic Acid Lib : Japan AIST/NIMC Database- Spectrum MS-NW-37 1 Z-(13,14-Epoxy)tetradec-11-en-1-ol acetate Lib : J. Klune, Insect Chem. Ecol. Lab., USDA, Beltsville, MD 275 leic Acid lein, 2-mono- 82 cis-13-eicosenoic acid Mass Spectrometry Data Center 123 137 151 165 18 196 24 212 22 228 236 245 253 276 284 19 121 135 149 1 165 18 189 1 25 213 221 229 237 245 253 262 27 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 2. (mainlib) Z-(13,14-Epoxy)tetradec-11-en-1-ol acetate 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 3. (replib) leic Acid 1 6 129 137 147 1 163 171 185 193 27 22 228 236 246 256 282 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 4. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester 1 6 19 123 137 151 165 1 193 27 221 235 245 253 125 137 151 165 1 1 189 1 25 213 221 229 237 245 253 263 2 282 292 32 31 2 2 37 325 338 354 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 5. (mainlib) cis-13-eicosenoic acid H H C21H44 H 54

Spectrum pada RT = 23.492 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 1. (mainlib) Cholestan-3-ol, 2-methylene-, (3β,5α)- 5α-Cholestan-3β-ol, 2-methylene- Lib : CARL DJERASSI DEPT F CHEM STANFRD UNIV STANFRD CALIF 9435 1 7-Methyl-Z-tetradecen-1-ol acetate Lib : J. Klune, Insect Chem. Ecol. Lab., USDA, Beltsville, MD 275 Estradiol, 3-deoxy- Lib : LAC, NIDDK, NIH, Bethesda, MD 2892 15 xiraneoctanoic acid, 3-octyl-, cis- Lib : R.T.HLMAN,UNIVERSITY F MINNESTA leic acid, 3-(octadecyloxy)propyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA 121 133 149 1 175 185 193 23 213 227 245 26 315 329 4 99 6 129 141 149 1 1 175 1 191 199 27 215 223 231 239 251 266 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 2. (mainlib) 7-Methyl-Z-tetradecen-1-ol acetate 1 6 85 17 122 137 151 171 185 199 213 227 238 256 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 3. (mainlib) Estra-1,3,5(1)-trien-17β-ol 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 4. (mainlib) xiraneoctanoic acid, 3-octyl-, cis- 1 6 8 87 19 127 141 1 168 185 199 213 221 229 237 245 253 2 2 28 125 137 149 165 1 193 27 221 229 237 2 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 5. (mainlib) leic acid, 3-(octadecyloxy)propyl ester 296 2 291 31 31 322 H C28H48 341 3 365 4 412 43 44 4 516 H

Spectrum pada RT = 23.587 menit 1 15 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (replib) β-tosterol β-tosterol Lib : Humboldt-Universitatzu Berlin, Department of Chemistry, Analytical Group 1 85 17 γ-tosterol 119 133 119 133 145 145 159 1 1 185 199 1 185 199 213 213 231 239 247 2 2 2 289 33 314 329 339 351 3 3 396 231 241 2 263 2 2 289 414 H 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (mainlib) γ-tosterol 33 313 329 339 354 364 372 3 396 414 H 1 93 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (mainlib) Pseduosarsasapogenin-5,2-dien Pseduosarsasapogenin-5,2-dien Lib : LAC, NIDDK, NIH, Bethesda, MD 2892 1 15 121 133 145 153 1 1 185 1 25 215 223 232 241 2 275 285 2 35 317 325 343 3 3 384 396 414 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (mainlib) 9,1-Secocholesta-5,7,1(19)-triene-1,3-diol, 25-[(trimethylsilyl)oxy]-, (3β,5Z,7E)- 9,1-Secocholesta-5,7,1(19)-triene-1,3-diol, 25-[(trimethylsilyl)oxy]-, (3β,5Z,7E)- 1 6 6 63 71 91 15 15 115 9,12,15-ctadecatrienoic acid, 2-phenyl-1,3-dioxan-5-yl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA 131 152 159 1 187 1 211 H H 227 241 251 259 2 34 365 38 3 412 121 129 149 165 1 185 21 29 219 227 239 247 265 278 286 294 32 31 318 326 H H 452 488 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (mainlib) 9,12,15-ctadecatrienoic acid, 2-phenyl-1,3-dioxan-5-yl ester 334 346 354 363 371 3 392 439 56

Spectrum pada RT = 23.682 menit 1 15 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (replib) β-tosterol β-tosterol Lib : Humboldt-Universitatzu Berlin, Department of Chemistry, Analytical Group 1 85 17 γ-tosterol 119 133 119 133 145 145 Ethyl iso-allocholate Lib : R RYHAGE MS-LAB KARLINSKA INSTITUTET STCKHLM SWEDEN 159 1 1 185 199 1 185 199 213 213 231 239 247 2 2 2 289 33 314 329 339 351 3 3 396 231 241 2 263 2 2 289 414 H 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (mainlib) γ-tosterol 1 6 11 17 33 313 329 339 354 364 372 3 396 121 129 145 1 171 185 1 211 219 227 235 243 253 2 272 2 289 2 35 313 321 329 339 3 3 382 4 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (mainlib) Ethyl iso-allocholate 414 418 H H H H 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (mainlib) Pseduosarsasapogenin-5,2-dien Pseduosarsasapogenin-5,2-dien Lib : LAC, NIDDK, NIH, Bethesda, MD 2892 1 Linolenin, 1-mono- 93 15 19 121 133 145 153 1 1 185 1 25 215 223 232 241 2 275 285 2 35 317 325 343 3 3 384 396 414 121 135 1 163 1 191 23 211 219 227 235 243 2 277 291 39 321 335 352 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- H H H H

Spectrum pada RT = 24.377 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 1. (replib) leic Acid leic Acid Lib : Japan AIST/NIMC Database- Spectrum MS-NW-37 1 6 6 cis-13-eicosenoic acid Mass Spectrometry Data Center leic Acid trans-13-ctadecenoic acid Mass Spectrometry Data Center 123 137 151 165 18 196 24 212 22 228 236 245 253 276 284 125 137 151 165 1 1 189 1 25 213 221 229 237 245 253 263 2 282 292 32 31 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 2. (mainlib) cis-13-eicosenoic acid 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 3. (replib) leic Acid 1 6 129 137 147 1 163 171 185 193 27 22 228 236 246 256 282 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 4. (mainlib) trans-13-ctadecenoic acid 1 6 19 123 137 151 159 1 175 1 191 199 27 217 225 235 246 278 123 135 149 165 1 1 193 211 22 231 239 248 262 2 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 5. (mainlib) 12-Methyl-E,E-2,13-octadecadien-1-ol 12-Methyl-E,E-2,13-octadecadien-1-ol Lib : J. Klune, Insect Chem. Ecol. Lab., USDA, Beltsville, MD 275 H H H H H 58

Spectrum pada RT = 24.7 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester β-monoolein 1 6 leic Acid Lib : Japan AIST/NIMC Database- Spectrum MS-NW-37 cis-vaccenic acid Mass Spectrometry Data Center leic Acid 19 123 trans-13-ctadecenoic acid Mass Spectrometry Data Center 137 151 165 1 193 27 221 235 245 253 123 137 151 165 18 196 24 212 22 228 236 245 253 276 284 2 2 37 325 338 354 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (replib) leic Acid 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (mainlib) cis-vaccenic acid 1 6 123 137 151 165 18 189 1 25 213 222 231 239 247 278 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (replib) leic Acid 1 6 6 129 137 147 1 163 171 185 193 27 22 228 236 246 256 282 123 137 151 159 1 175 1 191 199 27 217 225 235 246 278 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (mainlib) trans-13-ctadecenoic acid H H H C21H44 H 59

Spectrum pada RT = 24.947 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 1. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester β-monoolein 1 6 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- Lib : Japan AIST/NIMC Database- Spectrum MS-IW- Linolenin, 1-mono- leic Acid Lib : Japan AIST/NIMC Database- Spectrum MS-NW-37 leic Acid 19 123 137 151 165 1 193 27 221 235 245 253 123 137 151 165 1 1 27 22 228 236 246 254 2 2 37 325 338 354 274 282 291 37 319 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 2. (mainlib) 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- 1 19 121 135 1 163 1 191 23 211 219 227 235 243 2 277 291 39 321 335 352 339 351 365 3 393 C21H44 CH146 47 419 433 449 4 475 489 3 517 529 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 3. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 4. (replib) leic Acid 1 6 6 123 137 151 165 18 196 24 212 22 228 236 245 253 276 284 129 137 147 1 163 171 185 193 27 22 228 236 246 256 282 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 Hit 5. (replib) leic Acid H H H H 6

Spectrum pada RT = 25.593 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 1. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1-Monolinoleoylglycerol trimethylsilyl ether 1 75 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- leic Acid Linoleoyl chloride Lib : RADIAN CRP 13 117 129 12-Methyl-E,E-2,13-octadecadien-1-ol Lib : J. Klune, Insect Chem. Ecol. Lab., USDA, Beltsville, MD 275 147 19 117 131 149 163 175 191 163 171 191 23 27 221 27 223 233 249 262 243 251 26 2 2 2 35 325 341 3 3 3 3 48 429 4 482 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 2. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 3. (replib) leic Acid 1 6 129 137 147 1 163 171 185 193 27 22 228 236 246 256 282 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 4. (replib) 9,12-ctadecadienoyl chloride, (Z,Z)- 1 19 19 121 135 151 159 1 175 187 1 25 214 222 235 262 294 123 135 149 165 1 1 193 211 22 231 239 248 262 2 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 5. (mainlib) 12-Methyl-E,E-2,13-octadecadien-1-ol Cl H H

Spectrum pada RT = 26.323 menit 1 19 121 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (mainlib) Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- 1 13 117 129 135 1-Monolinoleoylglycerol trimethylsilyl ether 149 1 175 189 23 211 219 227 235 243 251 259 271 285 299 313 327 341 3 3 3 3 48 416 426 444 147 163 175 191 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1 75 19 117 131 149 163 171 191 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 23 27 221 27 223 233 249 262 243 251 26 2 2 2 35 325 341 3 3 3 3 48 429 4 482 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 91 15 119 135 149 159 1 187 21 213 227 239 247 2 263 271 2 287 2 39 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (mainlib) 2-[4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)hexa-1,3,5-trienyl]cyclohex-1-en-1-carboxaldehyde 2-[4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)hexa-1,3,5-trienyl]cyclohex-1-en-1-carboxaldehyde Lib :A.S.Moskovkin,I.M.Karnaukh, Russian Center on Disaster Medicine 1 6 63 71 91 15 115 131 152 159 1 187 1 211 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (mainlib) 9,1-Secocholesta-5,7,1(19)-triene-1,3-diol, 25-[(trimethylsilyl)oxy]-, (3β,5Z,7E)- 9,1-Secocholesta-5,7,1(19)-triene-1,3-diol, 25-[(trimethylsilyl)oxy]-, (3β,5Z,7E)- H H 227 241 251 259 2 34 365 38 3 412 324 H 452 488 62

Spectrum pada RT = 26.3 menit 1 6 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 1. (mainlib) Ethyl iso-allocholate Ethyl iso-allocholate Lib : R RYHAGE MS-LAB KARLINSKA INSTITUTET STCKHLM SWEDEN 1 leic acid, 3-(octadecyloxy)propyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA β-monoolein 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- Lib : Japan AIST/NIMC Database- Spectrum MS-IW- cis-13-eicosenoic acid NIST Mass Spectrometry Data Center 11 17 121 129 145 1 171 185 1 211 219 227 235 243 253 2 272 2 289 2 35 313 321 329 339 3 3 382 4 125 137 149 165 1 193 27 221 229 237 2 2 291 31 31 322 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 2. (mainlib) leic acid, 3-(octadecyloxy)propyl ester 1 19 123 137 151 165 1 193 27 221 235 245 253 2 2 37 325 338 354 418 H H 341 3 365 4 412 43 44 4 516 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 3. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 4. (mainlib) 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- 1 6 6 123 137 151 165 1 1 27 22 228 236 246 254 274 282 291 37 319 125 137 151 165 1 1 189 1 25 213 221 229 237 245 253 263 2 282 292 32 31 339 351 365 3 393 C21H44 47 419 433 449 4 475 489 3 517 529 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 Hit 5. (mainlib) cis-13-eicosenoic acid H H CH146 63

Spectrum pada RT = 26.863 menit 1 6 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 1. (mainlib) Ethyl iso-allocholate Ethyl iso-allocholate Lib : R RYHAGE MS-LAB KARLINSKA INSTITUTET STCKHLM SWEDEN 1 Linolenin, 1-mono- 11 1-Heptatriacotanol Lib : LAC, NIDDK, NIH, Bethesda, MD 2892 17 Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- 121 129 145 1 171 185 1 211 219 227 235 243 253 2 272 2 289 2 35 313 321 329 339 3 3 382 4 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 2. (mainlib) 9,12,15-ctadecatrienoic acid, 2,3-dihydroxypropyl ester, (Z,Z,Z)- 1 19 121 135 1 163 1 191 23 211 219 227 235 243 2 277 291 39 321 335 352 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 3. (mainlib) 1-Heptatriacotanol 1 17 121 133 147 1 175 19 21 215 229 237 245 2 272 2 536 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 4. (mainlib) Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- 1 19 121 135 149 1 175 189 23 211 219 227 235 243 251 259 271 285 299 313 327 341 3 3 3 3 48 416 426 444 418 H H H H H H 91 15 119 135 149 159 1 187 21 213 227 239 247 2 263 271 2 287 2 39 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 5. (mainlib) 2-[4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)hexa-1,3,5-trienyl]cyclohex-1-en-1-carboxaldehyde 2-[4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)hexa-1,3,5-trienyl]cyclohex-1-en-1-carboxaldehyde Lib ;A.S.Moskovkin,I.M.Karnaukh, Russian Center on Disaster Medicine 324 H 64

Spectrum pada RT = 27.63 menit 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 1. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1-Monolinoleoylglycerol trimethylsilyl ether 1 6 Dasycarpidan-1-methanol, acetate (ester) Lib : CARL DJERASSI DEPT F CHEM STANFRD UNIV STANFRD CALIF 9435 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- Lib : Japan AIST/NIMC Database- Spectrum MS-IW- β-monoolein 13 117 124 129 147 137 149 1 163 175 191 18 23 27 221 194 28 222 233 249 262 2 237 256 2 275 284 294 33 311 326 2 35 325 341 3 3 3 3 48 429 4 482 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 2. (mainlib) Dasycarpidan-1-methanol, acetate (ester) 1 75 19 117 131 149 163 171 191 27 223 243 251 26 2 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 3. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 HN 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 4. (mainlib) 9-ctadecenoic acid, 1,2,3-propanetriyl ester, (E,E,E)- 1 6 19 123 123 137 151 165 1 1 27 22 228 236 246 254 274 282 291 37 319 137 151 165 1 193 27 221 235 245 253 339 2 2 37 325 338 354 351 365 3 393 N CH146 47 419 433 449 4 475 489 3 517 529 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 5. (mainlib) 9-ctadecenoic acid (Z)-, 2-hydroxy-1-(hydroxymethyl)ethyl ester C21H44 65

Spectrum pada RT = 27.629 menit 1 13 117 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 1. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1-Monolinoleoylglycerol trimethylsilyl ether 1 13 115 9,12,15-ctadecatrienoic acid, 2-[(trimethylsilyl)oxy]-1-[[(trimethylsilyl)oxy]methyl]ethyl ester, (Z,Z,Z)- leic acid, 3-(octadecyloxy)propyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA 129 129 133 147 149 163 175 191 1 1 177 191 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- Spirost-8-en-11-one, 3-hydroxy-, (3β,5α,14β,2β,22β,25R)- Lib : CARL DJERASSI DEPT F CHEM STANFRD UNIV STANFRD CALIF 9435 23 27 221 27 221 233 249 262 2 249 262 2 2 2 35 325 341 3 3 3 3 48 429 4 482 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 2. (mainlib) 9,12,15-ctadecatrienoic acid, 2-[(trimethylsilyl)oxy]-1-[[(trimethylsilyl)oxy]methyl]ethyl ester, (Z,Z,Z)- 1 125 137 149 165 1 193 27 221 229 237 2 2 291 31 31 322 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 3. (mainlib) leic acid, 3-(octadecyloxy)propyl ester 1 75 19 117 131 149 163 171 191 27 223 243 251 26 2 341 3 365 4 412 43 44 4 516 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 4. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 6 77 19 121 135 147 159 1 187 1 27 211 219 229 239 253 2 2 286 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 5. (mainlib) Spirost-8-en-11-one, 3-hydroxy-, (3β,5α,14β,2β,22β,25R)- 299 314 327 34 356 3 3 45 428 H 66

Spectrum pada RT = 27.949menit 1 13 117 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 1. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1-Monolinoleoylglycerol trimethylsilyl ether 1 75 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- leic acid, 3-(octadecyloxy)propyl ester Lib : R.T.HLMAN,UNIVERSITY F MINNESTA Spirost-8-en-11-one, 3-hydroxy-, (3β,5α,14β,2β,22β,25R)- Lib : CARL DJERASSI DEPT F CHEM STANFRD UNIV STANFRD CALIF 9435 Dodecyl cis-9,1-epoxyoctadecanoate Lib : Japan AIST/NIMC Database- Spectrum MS-IW-4723 129 147 19 117 131 149 163 175 191 163 171 191 23 27 221 27 223 233 249 262 243 251 26 2 2 2 35 325 341 3 3 3 3 48 429 4 482 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 2. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 3. (mainlib) leic acid, 3-(octadecyloxy)propyl ester 1 125 137 149 165 1 193 27 221 229 237 2 2 291 31 31 322 341 3 365 4 412 43 44 4 516 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 4. (mainlib) Spirost-8-en-11-one, 3-hydroxy-, (3β,5α,14β,2β,22β,25R)- 1 6 77 19 121 135 125 139 147 159 1 168 1 187 1 27 211 219 229 239 253 2 185 1 25 213 221 229 241 249 2 2 2 286 299 314 327 34 356 2 311 325 341 353 3 3 45 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 Hit 5. (mainlib) Dodecyl cis-9,1-epoxyoctadecanoate 428 368 377 391 45 419 437 446 464 H C3H5

Spectrum pada RT = 28.284 menit 1 13 117 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 56 Hit 1. (mainlib) 1-Monolinoleoylglycerol trimethylsilyl ether 1-Monolinoleoylglycerol trimethylsilyl ether 1 75 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- Dasycarpidan-1-methanol, acetate (ester) Lib : CARL DJERASSI DEPT F CHEM STANFRD UNIV STANFRD CALIF 9435 Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- 129 147 19 117 131 149 163 175 191 163 171 191 5H-Cyclopropa[3,4]benz[1,2-e]azulen-5-one, 3,9,9a-tris(acetyloxy)-3-[(acetyloxy)methyl]-2-chloro-1,1a,1b,2 Lib : DKFZ HD SCHMIDT, HEIDELBERG, GERMANY, F.R.G. 23 27 221 27 223 234 249 262 243 251 26 2 2 2 35 325 341 3 3 3 3 48 429 4 482 2 33 341 3 3 377 48 429 443 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 56 Hit 2. (replib) 9,12,15-ctadecatrienoic acid, 2,3-bis[(trimethylsilyl)oxy]propyl ester, (Z,Z,Z)- 1 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 56 Hit 3. (mainlib) Dasycarpidan-1-methanol, acetate (ester) 1 6 124 137 149 1 18 194 28 222 237 256 2 275 284 294 33 311 326 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 56 Hit 4. (mainlib) Tricyclo[2.8..(7,16)]triacontane, 1(22),7(16)-diepoxy- 1 53 91 19 121 19 135 149 1 175 189 23 211 219 227 235 244 2 265 2 285 299 313 327 341 3 3 3 3 48 416 426 444 114 125 133 149 1 175 1 1 213 223 239 251 2 28 291 38 325 333 351 359 3 377 386 394 411 422 43 438 447 464 472 489 5 524 548 6 7 8 9 1 11 12 13 14 1 16 17 18 19 2 21 22 23 24 2 26 27 28 29 3 31 32 33 34 3 36 37 38 39 4 41 42 43 44 4 46 47 48 49 51 52 53 54 5 56 Hit 5. (mainlib) 5H-Cyclopropa[3,4]benz[1,2-e]azulen-5-one, 3,9,9a-tris(acetyloxy)-3-[(acetyloxy)methyl]-2-chloro-1,1a,1b,2,3,4,4a,7a,7b,8,9,9a-dodecahydro-4a,7b-dihydroxy-1,1,6,8-tetramethyl-, [1aR-(1aα,1bβ,2α,3β,4aβ,7aα,7bα,8α,9β,9aα)]- HN N 68