gal/yr lb/gal lb/day lb/yr HAP lb/day lb/yr conc. % to air % lb/day lb/yr lb/day lb/yr Fail free formaldehyde, max. 000050-00-0 VOC, HAP 0.000066 0.0165 100 100 0.00 0.02 0.01 3.8 pass ethanol 000064-17-5 VOC 31.86 7,961.30 100 100 31.86 7,961.30 74 27,147 pass methanol 000067-56-1 VOC, HAP 0.24 62.19 100 100 0.24 62.19 10 3,783 pass isopropanol 000067-63-0 VOC 33.03 8,258.07 100 100 33.03 8,258.07 14 5,044 fail acetone 000067-64-1 VOC 115.50 28,875.00 100 100 115.50 28,875.00 33 12,180 fail n-propanol 000071-23-8 VOC 2.07 517.09 100 100 2.07 517.09 27 9,946 pass butanol 000071-36-3 VOC 2.70 671.93 100 100 2.70 671.93 6.7 2,458 pass isobutanol 000078-83-1 VOC 0.06 11.98 100 100 0.06 11.98 6.0 2,195 pass methyl ethyl ketone 000078-93-3 VOC, HAP 0.42 105.73 100 100 0.42 105.73 7.9 2,871 pass dibutyl phthalate 000084-74-2 VOC 0.03 8.13 100 100 0.03 8.13 0.2 72 pass butyl benzyl phthalate 000085-68-7 VOC 0.03 5.59 100 100 0.03 5.59 napthalene 000091-20-3 VOC, HAP 9.03 2,260.90 100 100 9.03 2,260.90 1.5 49 fail 1,2,4-trimethylbenzene 000095-63-6 VOC 1.74 432.83 100 100 1.74 432.83 4.9 1,776 pass methyl ethyl ketoxime 000096-39-7 VOC 0.12 28.18 100 100 0.12 28.18 butryolactone 000096-48-0 VOC 0.03 9.95 100 100 0.03 9.95 tetramethylthiuram monosulfide 000097-74-5 VOC 0.00 3.66 100 100 0.00 3.66 isobutyl isobutyrate 000097-85-8 VOC 0.24 58.21 100 100 0.24 58.21 cumene 000098-82-8 VOC, HAP 0.00 2.00 100 100 0.00 2.00 ethyl benzene 000100-41-4 VOC, HAP 0.57 140.76 100 100 0.57 140.76 7.9 2,871 pass methoxypropanol 000107-98-2 VOC 2.82 706.13 100 100 2.82 706.13 16 5,741 pass methyl isobutyl ketone 000108-10-1 VOC, HAP 0.06 15.30 100 100 0.06 15.30 24 8,612 pass isopropylacetate 000108-21-4 VOC 0.36 90.68 100 100 0.36 90.68 68 24,998 pass 1-methoxy-2-acetozypropane 000108-65-6 VOC 0.00 0.08 100 100 0.00 0.08 toluene 000108-88-3 VOC, HAP 13.53 3,383.29 100 100 13.53 3,383.29 5.3 1,927 fail cyclohexane 000108-94-1 VOC 0.36 91.82 100 100 0.36 91.82 3.2 1,159 pass propyl acetate 000109-60-4 VOC 0.42 101.85 100 100 0.42 101.85 1.37 49,937 pass isobutyl acetate 000110-19-0 VOC 8.01 2,005.89 100 100 8.01 2,005.89 117 42,641 pass n,n'-ethylenebisstearameide 000110-30-5 VOC 0 1.02 100 100 0.00 1.02 2-heptanone 000110-43-0 VOC 6.93 1,728.77 100 100 6.93 1,728.77 38 13,934 pass hexane 000110-54-3 VOC 0.00 2.77 100 100 0.00 2.77 7 2,541 pass 2-butoxyethanol 000111-76-2 VOC, HAP 0.63 155.30 100 100 0.63 155.30 102 37,318 pass diethylene glycol methyl ether 000111-77-3 VOC 0.00 0.00 100 100 0.00 0.00 ethoxyethoxyethanol 000111-90-0 VOC 0.90 225.80 100 100 0.90 225.80 butoxyethoxyethanol 000112-34-5 VOC 100 100 0.00 0.00 benzophenone 000119-61-9 VOC 6.96 1736.46 100 100 6.96 1,736.46 n-buty acetate 000123-86-4 VOC 26.31 6,574.14 100 100 26.31 6,574.14 28 10,926 pass calcium 2-ethylhaxandoate 000136-51-6 VOC 0.00 0.05 100 100 0.00 0.05 ethyl acetate 000141-78-6 VOC 0.78 195.62 100 100 0.78 195.62 80 29,111 pass 2-ethylhazanoic acid 000149-57-5 VOC 0.00 0.00 100 100 0.00 0.00 0.14 51 pass subsituted silohexane 000556-67-2 VOC 0.00 0.25 100 100 0.00 0.25
gal/yr lb/gal lb/day lb/yr HAP lb/day lb/yr conc. % to air % lb/day lb/yr lb/day lb/yr Fail 2-hydroxyethyl methacrylate 000868-77-9 VOC 3.69 922.91 100 100 3.69 922.91 xylene, mixed isomers 001330-20-7 VOC 2.43 603.97 100 100 2.43 603.97 12 1,641 pass 1-ethoxy-2-propanol 001569-02-4 VOC 0.12 29.82 100 100 0.12 29.82 2-propoxyethanol 002807-30-9 VOC 0.00 0.99 100 100 0.00 0.99 butyl glycolate 007397-62-8 VOC 0.00 0.78 100 100 0.00 0.78 hydroxymethylphenylpropanone 007473-98-5 VOC 4.14 1,031.55 100 100 4.14 1,031.55 alkali refineed linseed oil 008001-26-1 VOC 0.12 27.67 100 100 0.12 27.67 paraffinic hydrocarbon 008002-74-2 VOC 0.00 0.02 100 100 0.00 0.02 0.66 239 pass VM&P naptha, ligroine 008032-32-4 VOC 0.03 8.22 100 100 0.03 8.22 54 19,664 pass VM&P naptha, ligroine 008032-32-4 VOC 1.20 308.29 100 100 1.20 308.29 stoddard solvent 008052-41-3 VOC 45.06 11,268.08 100 100 45.06 11,268.08 21 7,581 fail stoddard solvent 008052-41-3 VOC 0.03 6.78 100 100 0.03 6.78 stoddard solvent 008052-41-3 VOC 1.35 336.98 100 100 1.35 336.98 polyethylene 009002-88-4 VOC 0.63 158.96 100 100 0.63 158.96 polypropylene 009003-07-0 VOC 1.59 396.71 100 100 1.59 396.71 1,6-hexanediol diacrylate 013048-33-4 VOC 30.90 7,722.94 100 100 30.90 7,722.94 trimethylolpropane triacrylate 015625-89-5 VOC 1.50 372.87 100 100 1.50 372.87 polyethylene glycol 025322-68-3 VOC 0.00 0.71 100 100 0.00 0.71 1.6 597 pass trimethylbenzenes 025551-13-7 VOC 0.00 0.46 100 100 0.00 0.46 4.9 1,777 pass allyl alcohol ethoxylated 027274-31-3 VOC 0.00 1.44 100 100 0.00 1.44 aliphatic triacrylate 028961-43-5 VOC 0.03 7.51 100 100 0.03 7.51 tripropylene glycol diacrylate 042978-66-5 VOC 36.21 9,051.06 100 100 36.21 9,051.06 dipropylene glycol diacrylate 057472-68-1 VOC 0.90 226.12 100 100 0.90 226.12 mod bisphenol a diacrylate 064401-02-1 VOC 3.03 759.35 100 100 3.03 759.35 petroleum naptha 064741-65-7 VOC 0.06 16.01 100 100 0.06 16.01 mineral spirits, jet fuel 064742-47-8 VOC 10.23 2,555.03 100 100 10.23 2,555.03 7.9 2,888 fail mineral spirits, jet fuel 064742-47-8 VOC 0.09 20.79 100 100 0.09 20.79 aliphatic hydrocarbon 064742-88-7 VOC 5.97 1,495.30 100 100 5.97 1,495.30 naptha 064742-89-8 VOC 0.06 11.78 100 100 0.06 11.78 aliphatic hydrocarbon 064742-89-8 VOC 59.40 14,846.70 100 100 59.40 14,846.70 aromatic solvent 064742-94-5 VOC 81.18 20,295.00 100 100 81.18 20,295.00 diisononyl phthlate 068501-48-0 VOC 3.63 903.82 100 100 3.63 903.82 mixed cyclosiloxanes 069430-24-6 VOC 0.00 0.02 100 100 0.00 0.02 2-methoxy-1-propanol acetate 070657-70-4 VOC 0.00 0.00 100 100 0.00 0.00 modified alcohol VOC 0.03 4.85 100 100 0.03 4.85 ethoxylated pe tetraacrylate VOC 6.90 1,725.55 100 100 6.90 1,725.55
gal/yr lb/gal lb/day lb/yr HAP lb/day lb/yr conc. % to air % lb/day lb/yr lb/day lb/yr acrylated amine VOC 8.10 2,021.42 100 100 8.10 2,021.42 acrylated oil VOC 20.10 5,023.79 100 100 20.10 5,023.79 modified polyester acrylate VOC 5.13 1,286.13 100 100 5.13 1,286.13 polyester acrylate VOC 7.71 1,929.18 100 100 7.71 1,929.18 linseed alkyd VOC 0.03 5.10 100 100 0.03 5.10 aliphatic solvent VOC 0.30 78.51 100 100 0.30 78.51 total VOC lb 151,892 acetone 28,875 net VOC lb 123,017 Fail anthraquinone based pigment 000072-48-0 0.45 115.70 100 10 0.045 11.57 zinc stearate 000557-05-1 0.48 119.76 100 10 0.048 11.98 1.2 427 pass acid azo calcium salt 001103-39-5 0.12 31.52 100 10 0.012 3.15 iron oxide 001309-31-1 6.54 1,634.14 100 10 0.654 163.41 iron oxide 001332-37-2 1.92 482.28 100 10 0.192 48.23 carbon black 001333-86-4 0.18 42.69 100 10 0.018 4.27 0.41 150 pass aluminum oxide 001344-28-1 0.18 46.81 100 10 0.018 4.68 1.2 428 pass manganese salt of perm. Red 2B 005280-66-0 HAP 0.33 81.66 100 10 0.033 8.17 diarylide pigment 006358-85-6 2.04 509.39 100 10 0.204 50.94 manganese 007439-96-5 HAP 0.57 140.63 100 10 0.057 14.06 0.0079 0.82 fail barium 007440-39-3 0.00 0.69 100 10 0.000 0.07 0.020 7.3 pass carbon 007440-44-0 0.51 125.45 100 10 0.051 12.55 cobalt 007440-48-4 HAP 0.00 0.00 100 10 0.000 0.00 0.00056 0.21 pass synthetic amorphous silica 007631-86-9 0.03 9.21 100 10 0.003 0.92 0.079 29 pass phosphoric acid 007664-35-2 0.00 0.41 100 10 0.000 0.04 0.12 43 pass barium sulfate 007727-43-7 0.09 20.11 100 10 0.009 2.01 3.3 1,197 pass calcium phosphate (3:2) 007758-87-4 3.69 919.86 100 10 0.369 91.99 nitrocellulose 009004-70-0 9.12 2,278.47 100 10 0.912 227.85 mica 012001-26-2 0.18 48.20 100 10 0.018 4.82 0.12 43 pass gilsonite 012002-43-6 0.03 6.47 100 10 0.003 0.65 manganese complex 012238-31-2 HAP 0.09 23.36 100 10 0.009 2.34 titanium dioxide 013463-67-7 0.51 129.08 100 10 0.051 12.91 0.4 144 pass talc 014807-96-6 6.27 1,569.86 100 10 0.627 156.99 0.079 29 fail quartz 014808-60-7 1.08 271.59 100 10 0.108 27.16 0.0028 1 fail diazo pigment 015110-84-6 0.03 3.88 100 10 0.003 0.39
gal/yr lb/gal lb/day lb/yr HAP lb/day lb/yr conc. % to air % lb/day lb/yr lb/day lb/yr aluminum trihydroxide 021645-51-2 0.00 0.36 100 10 0.000 0.04 iron oxide 051274-00-1 0.06 16.04 100 10 0.006 1.60 oxide yellow 051274-00-1 0.03 4.75 100 10 0.003 0.48 epoxy acrylate resin 055818-57-0 4.56 1,140.32 100 10 0.456 114.03 poly(dimethylsiloxane) 063148-62-9 0.00 0.02 100 10 0.000 0.00 silica gel 063231-67-4 11.61 2,898.93 100 10 1.161 289.89 sodium soap 067701-10-4 0.00 0.00 100 10 0.000 0.00 butylated u/f resin 068002-19-7 0.00 3.68 100 10 0.000 0.37 polysiloxane copolymer 068937-54-2 0.03 8.04 100 10 0.003 0.80 organophilic clay 068953-58-2 0.93 229.91 100 10 0.093 22.99 chromium II compound 085828-90-6 HAP 0.03 3.83 100 10 0.003 0.38 amorphous silica 112926-00-8 9.57 2,394.91 100 10 0.957 239.49 0.40 144 fail chromium (III) HAP 0.00 2.74 100 10 0.000 0.27 0.014 5.1 pass chromium (III) compound HAP 0.00 100 10 0.000 0.00 chromium (III) complex dye HAP 0.00 100 10 0.000 0.00 amine alkyl acid phosphate 0.00 100 10 0.000 0.00 phosphated polyester 0.00 0.17 100 10 0.000 0.02 acrylated epoxy resin 51.06 12,766.92 100 10 5.106 1,276.69 modified polymide resin 0.00 100 10 0.000 0.00 deodorizer 0.00 100 10 0.000 0.00 aliphatic ester sodium salt 0.00 100 10 0.000 0.00 Fail
Bradford Veneer and Panel Co., Inc. RTAP - STEP 2 - In-Stack Evaluation if fails AAL, next step modeling Chemical Emitted Stack air flow In-Stack conc μg/m 3 CAS No. lb/day g/sec μg/sec m 3 /sec = acfm/2119 Calculated Adjusted AAL μg/m 3 ID =lb/day/190.56 =g/sec*1000000 acfm m 3 /sec =(μg/sec)/(m 3 /sec) =calc/400 24-hr Annual Fail isopropanol 000067-63-0 33.03 0.173331234 173331.2343 25,380 11.98 14471.59 36.18 1,757 1,171 pass acetone 000067-64-1 115.50 0.606108312 606108.3123 25,380 11.98 50604.55 126.51 4,243 2,829 pass napthalene 000091-20-3 2.70 0.014168766 14168.76574 25,380 11.98 1182.96 2.96 186 3.0 pass toluene 000108-88-3 13.53 0.071001259 71001.25945 25,380 11.98 5927.96 14.82 671 400 pass stodddard solvent 008052-41-3 46.44 0.243702771 243702.7708 25,380 11.98 20346.97 50.87 2,641 1,761 pass mineral spirits, jet fuel 064742-47-8 10.32 0.054156171 54156.17128 25,380 11.98 4521.55 11.30 1,006 671 pass quartz 014808-60-7 0.108 0.000566751 566.7506297 25,380 11.98 47.32 0.12 0.36 0.24 pass amorphous silica 112926-00-8 0.957 0.00502204 5022.040302 25,380 11.98 419.29 1.05 50 34 pass manganese 007439-96-5 0.05 0.000262385 262.3845508 25,380 11.98 21.91 0.05 1.0 0.05 pass talc 014807-96-6 0.627 0.003290302 3290.302267 25,380 11.98 274.71 0.69 10 6.7 pass lb/day taken from last column of Green Mountain Custom Finishing, Inc. Summary of Hazardous Materials and multiplied by 3 except for the following adjustments to achieve in-stack compliance napthalene lowered from 9.03 lb/day to 2.70 lb/day manganese lowered from.057 lb/day to 0.05 lb/day HAP Review Hazardous Air Pollutant CAS No. lb/yr ton/yr methanol 000067-56-1 62 0.03 methyl ethyl ketone 000078-93-3 106 0.05 napthalene 000091-20-3 2,261 1.13 cumene 000098-82-8 2 0.00 ethyl benzene 000100-41-4 141 0.07 methyl isobutyl ketone 000108-10-1 15 0.01 toluene 000108-88-3 3,383 1.69 20butoxyethanol 000111-77-3 155 0.08 chromium (III) 3 0.00 chromium (III) compound 0 0.00 chromium (III) compound dye 0.00 formaldehyde 000050-00-0 0.0165 0.00 manganese 007439-96-5 141 0.07 cobalt 007440-48-4 0.00 manganese complex 012238-31-2 23 0.01 chromium II compound 085828-90-6 4 0.00 total tpy 3.15