The origin of the Canary Island Seamount Province New ages of old seamounts. Paul van den Bogaard. Supplementary information
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1 The origin of the Canary Island Seamount Province New ages of old seamounts. Paul van den Bogaard Supplementary information
2 Supplementary information S1: Major CISP seamount coordinates Longitude Latitude ºW ºN Essaouira Smt. ("Lars Smt." in Geldmacher et al., 05) unnamed Smt Rybin Smt. ("Anika Smt." in Geldmacher et al., 05) unnamed Smt Dacia Smt unnamed Smt unnamed Smt unnamed Smt unnamed Smt. ("Nico Smt." in Geldmacher et al., 01) Conception B unnamed Smt. ("Last Minute Smt." in Geldmacher et al., 01) Selvagen G Selvagen P Lanzarote Fuerteventura Amanay Smt Canary Ridge Smt Gran Canaria El Hijo Smt Tenerife La Gomera La Palma Palma Ridge Smt El Hierro Hierro Ridge Smt Henry Smt. ("Kiel Smt." in Schmincke & Graf, 00) Bisabuelas Smt. ("Las Hijas Smt." in Schmincke & Graf, 00) unnamed Smt. ("Hierro Smt." in Schmincke & Graf, 00) Echo Smt. ("Endeavour Smt." in Schmincke & Graf, 00) The Paps SE The Paps NW unnamed Smt Tropic Smt. Geldmacher, J., Hoernle, K. A., van den Bogaard, P., Zankl, G. & Garbe-Schönberg, D. Earlier history of the >70-Ma-old Canary hotspot based on the temporal and geochemical evolution of the Selvagen Archipelago and neighboring seamounts in the eastern North Atlantic. J. Volcanol. Geotherm. Res. 111, (01). Geldmacher, J., Hoernle, K. A., van den Bogaard, P., Duggen, S. & Werner, R. New 40Ar/39/Ar age and geochemical data from seamounts in the Canary and Madeira volcanic provinces: Support for mantle plume hypothesis. Earth Planet. Sci. Lett. 237, 85-1 (05). Schmincke, H. U. & Graf, G. DECOS/OMEX II, Cruise No. 43, 25 November January 1999 Meteor Reports, 00-1 (Univ. Hamburg), 1-99 (00).
3 Supplementary information S2: 40Ar/39Ar dating results table Unit Sample No Sample coordinates Rock type Phase Latitude Longitude Water depth (m.b.s.l.) Single-crystal weighted mean age Step-heating plateau age ± ± 2Sigma incl. J-error 2Sigma incl. J-error MSWD Probability MSWD Probability Number of singlecrystal analyses used Number of heating steps in plateau %39Ar in plateau Alteration indices and rejection criteria Canary Ridge Seamount tephrite hornblende 17.8 ± AI(36/37) = 2E-4 to 4E-3 matrix 17.7 ± to 76 Plateau steps AI(36/39) = 1E- 3 to 3E-3 El Hijo Seamount trachybasalt biotite 0.24 ± of 11 2 analyses with AI(36/39) > 2E-3 rejected Palma Ridge Seamount phonolite biotite 2.11 ± AI(36/39) = 1E-4 to 1E-3 Hierro Ridge Seamount trachyte K-feldspar ± AI(36/39) = 4E-5 to 1E-3 hornblende ± AI(36/37) = 1E-4 to 3E-3 Bisabuelas Seamount plagioclase ± of trachyte plagioclase ± of 13 Ca/K = 6 to 41; 3 analyses with AI(36/37) >1E-4 rejected Ca/K = 4 to 5; 4 analyses with AI(36/37) >3E-4 rejected The Paps Seamount trachyte K-feldspar 91.1 ± to 52.4 Plateau steps AI(36(39) = 3E- 4 to 1E-3 Tropic Seamount trachyte K-feldspar ± AI(36/39) = 6E-6 to 2E basalt matrix ± to trachyte Plateau steps AI(36/37) = 7E- 4 to 2E-3 K-feldspar ± AI(36/39) = 2E-4 to 4E-3 hornblende ± AI(36/37) = 2E-4 to 1E trachyte plagioclase ± AI(36/37) = 1E-4 to 4E-3 hornblende ± AI(36/37) = 5E-5 to 8E-4
4 Supplementary information S3: 40Ar/39Ar analysis data hornblende single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00 2.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00 4.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 Mean age = 17.8±0.3 Ma (2s, including J-error of.123%) MSWD = 1.6, probability = matrix step-heating analysis Heating step Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E-16 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E+01 7.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 Plateau age = 17.7±0.2 Ma (2s, including J-error of.123%) MSWD = 1.3, probability = % of the 39Ar, steps 8 through and biotite single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E+01 rej. 5.27E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E+01 rej. 3.25E E E E E-01 2.E E E E E E E E E E-03 0.
5 E E E E E E E E E E E Mean age = 0.24±0.02 Ma (2s, including J-error of.23%) MSWD = 0.37, probability = biotite single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E Mean age = 2.11±0.03 Ma (2s, including J-error of.128%) MSWD = 0.80, probability = K-feldspar single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E-02 8.E E E E E E E E E E E E E E E E-01 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-14 2.E E E E E E E E E E E E E E E E E E E E-01 Mean age = 133.3±0.2 (2s, including J-error of.119%) MSWD = 1.4, probability = hornblende single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00 6.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E+02 2.E E E E E E E E E E E E+02 2.E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01
6 E E E E E E E E E E E E E E E E E E E E E E E E-01 Mean age = 133.8±0.6 Ma (2s, including J-error of.128%) MSWD = 0.89, probability = plagioclase single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E-16 4.E E E E E E E E E E E E E E-00 rej. 1.33E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-16 4.E E E E E E E E E E E E E E+01 rej. 1.30E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E+01 rej. 1.36E E E E E E E E E E E E E+02 2.E E E E E E E E-16 4.E E E E E E E E-01 Mean age = 140.5±0.7 Ma (2s, including J-error of.17%) MSWD = 1.19, probability = plagioclase single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E-00 rej. 1.41E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00 rej. 1.41E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00 rej. 1.38E E E E E E E E E E E-00 rej. 1.42E E E E E E E E E E E E E E E E E E E E E E E-02 9.E E E E E E E E E E E E E E E E E E-01 Mean age = 141.7±0.4 Ma (2s, including J-error of.23%) MSWD = 1.7, probability = K-feldspar step-heating analysis Heating step Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 9.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E
7 Plateau age = 91.1±0.2 Ma (2s, including J-error of.135%) MSWD = 1.3, probability = % of the 39Ar, steps 7 through K-feldspar single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 2.E E E E E E E E E E E E-01 1.E E E E E E E E E E E-01 1.E E E E E E E E E E E E E E E E E E E E E E-01 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 1.E E E E E E E E E E E-01 1.E E E E E E E E E E E-01 1.E E E E E E E E E E E-00 1.E E E E E-01 Mean age = 119.3±0.3 Ma (2s, including J-error of.23%) MSWD = 1.01, probability = matrix step-heating analysis Heating step Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 3.E E E E E E E E E E E+01.00E E E E E E E E E E E E E E E E E+01 5.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-15 1.E E E-01 1.E E E E E E E E E E E E E E E E E E+01 6.E E E-15 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00.00E E E E E E-01 Plateau age = 113.9±0.2 Ma (2s, including J-error of.17%)
8 MSWD = 1.06, probability = % of the 39Ar, steps 23 through hornblende single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI(36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-15 8.E E E E E E E E E E E E E E-00 5.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 Mean age = 116.8±0.5 Ma (2s, including J-error of.135%) MSWD = 1.3, probability = K-feldspar single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/39) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-04 1.E E E E E+02 4.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 1.E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 Mean age = 116.3±0.2 Ma (2s, including J-error of.135%) MSWD = 0.71, probability = plagioclase single-crystal analyses Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-01 Mean age = 115.6±0.5 Ma (2s, including J-error of.230%) MSWD = 0.77, probability = hornblende single-crystal analyses
9 Analysis Laser power (W) 40Ar/39Ar 37Ar/39Ar 36Ar/39Ar Mol 39ArK Ca/K % 40ArA Cum 39ArK Age 2 Sigma AI (36/37) J 2 Sigma E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E-00.00E E E E E E-01 Mean age = 117.0±0.5 Ma (2s, including J-error of.135%) MSWD = 0.78, probability = 0.64 Single-crystal and heating-step isotope ratios, ages and J-values are calculated with a TCR monitor age of Ma. Mean and plateau ages are recalculated to TCR-2 monitor age of Ma (Lanphere & Dalrymple, 00) and include J-error. Accepted single-crystal analyses and plateau steps boldface. MSWD = SumS/(n-1). Probability from Chi Square tables. Alteration indices (Baksi, 07) for K-feldspar, biotite, K-rich matrix (Ca/K<1) are here calculated as AI(36/39) = [(36Ar/39Ar) (36Ar/37Ar)Ca x (37Ar/39Ar)] x (J/0.01). Alteration indices for plagioclase, hornblende, Ca-rich matrix (Ca/K>1) are calculated as AI(36/37) = [(36Ar/39Ar) (36Ar/37Ar)Ca x (37Ar/39Ar)] x (J/0.01)/ (37Ar/39Ar). (36Ar/37Ar)Ca = 4.
10 Supplementary information S4: Age spectra, Ca/K-ratios, % 40 Ar atm, and isotope correlation diagrams (inverse isochrons; x-values scaled to J = 1E-3).
11 794-1 hornblende single-crystal analyses matrix step-heating analysis % 40 Aratm Ca/K Age 15 Weighted mean age = 17.7 ± 0.2 Ma Age 15 Plateau age = 17.7 ± 0.2 Ma Isochron age = 18.0 ± 0.6 Ma Initial 40Ar/36Ar = 298 ± MSWD = 1.7 Isochron age = 18.4 ± 0.7 Ma at initial 40Ar/36Ar = 281 ± 15 MSWD =
12 biotite single-crystal analyses biotite single-crystal analyses Weighted mean age = 0.24 ± 0.02 Ma 3.0 Age 0.4 Age Weighted mean age = 2.11 ± 0.03 Ma Isochron age = 0.23 ± 0.04 Ma Initial 40Ar/36Ar = 298 ± 6 MSWD = 0.36 Isochron age = 2. ± 0.05 Ma Initial 40Ar/36Ar = 298 ± 7 MSWD =
13 K-feldspar step-heating analysis K-feldspar single-crystal analyses Age Plateau age = 91.3 ± 0.2 Ma Age 115 Weighted mean age = ± 0.3 Ma 70 1 Isochron age = 91.2 ± 0.4 Ma Initial 40Ar/36Ar = 303 ± 33 MSWD = 2.1 Isochron age = ± 0.3 Ma Initial 40Ar/36Ar = 160 ± 82 MSWD =
14 plagioclase single-crystal analyses hornblende single-crystal analyses Age 1 Weighted mean age = ± 0.5 Ma Age 1 Weighted mean age = ± 0.5 Ma 5 5 Isochron age = ± 0.3 Ma Initial 40Ar/36Ar = 273 ± 8 MSWD = 1.5 Isochron age = ± 0.9 Ma Initial 40Ar/36Ar = 321 ± 43 MSWD =
15 692-3 K-feldspar single-crystal analyses hornblende single-crystal analyses Age 1 Weighted mean age = ± 0.2 Ma Age 5 1 Weighted mean age = ± 0.5 Ma Isochron age = ± 0.2 Ma Initial 40Ar/36Ar = 291 ± 7 MSWD = 0.73 Isochron age = ± 1.0 Ma Initial 40Ar/36Ar = 304 ± 24 MSWD =
16 692-1 matrix step-heating analysis Age Plateau age = ± 0.3 Ma Isochron age = ± 0.6 Ma Initial 40Ar/36Ar = 308 ± 9 MSWD =
17 689-2 plagioclase single-crystal analyses plagioclase single-crystal analyses Age 130 Weighted mean age = ± 0.7 Ma Age 130 Weighted mean age = ± 0.4 Ma 1 1 Isochron age = ± 1.0 Ma Initial 40Ar/36Ar = 148 ± 77 MSWD = 0.5 Isochron age = ± 1.2 Ma Initial 40Ar/36Ar = 279 ± 2 MSWD =
18 K-feldspar single-crystal analyses hornblende single-crystal analyses Age 130 Weighted mean age = ± 0.2 Ma Age Weighted mean age = ± 0.6 Ma Isochron age = ± 0.3 Ma Initial 40Ar/36Ar = 279 ± 67 MSWD = 1.6 Isochron age = ± 0.7 Ma Initial 40Ar/36Ar = 294 ± 8 MSWD =
MSWD = 1.06, probability = 0.39
MSWD Institute of Geophysics and Planetary Physics Incremental Heating 36Ar(a) 37Ar(ca) 38Ar(cl) 39Ar(k) 40Ar(r) Age (Ma) 40Ar(r) (%) 1B15835D 670 C 4 0.000001 0.078288 0.000010 0.001470 0.010633 9.19
S
MSWD Institute of Geophysics and Planetary Physics Incremental Heating 36Ar(a) 37Ar(ca) 38Ar(cl) 39Ar(k) 40Ar(r) Age (Ma) 40Ar(r) (%) 1B16079D 600 C 4 0.000034 0.033821 0.000003 0.001780 0.001016 0.72
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