361004 Phthalic Acid Easters PAEs PAEs TS207 TS761. 7 A DOI 10. 11980 /j. issn. 0254-508X. 2017. 05. 010 Current Situation of Research on Phthalic Acid Esters Plasticizers in Food Contact Plant Fiber Materials ZHANG Qian Xiamen Products Quality Supervision & Inspection Institute Xiamen Fujian Province 361004 E-mail zhangqian@ xmzjy. org Abstract The literatures in recent years about phthalic acid easters PAEs plasticizers in food contact paper materials were introduced from two aspects migration test condition and detection methods. Proper migration testing condition and detection methods with high sensitivity have been the focused points of domestic and overseas scholars but still need to be further studied. Meanwhile the published research works proved the existence of PAEs plasticizers in paper materials harm to consumers it was an early warning signal for paper material manufacturers it also proved a reference for drafting the regulation and standards about specific migration limit and detection method of PAEs plasticizers of food contact paper materials including paper packaging materials paper container and paper towel in China. Key words paper packaging materials plasticizers phthalic acid esters migration test detection methods PAEs 5 2008 GB 9685 2008 7 1 PAEs 6 PAEs 2-3 Phthalic PAEs Acid Easters PAEs 80% 4 DMP DBP 2-DEHP 2017-01-10 FJQI2016045 2017 36 5 53
PAEs 15 PAEs 16 5 PAEs Tenax PAEs 17 PAEs Tenax 1 18 PAEs Tenax 25 EN14338 50 75 100 Tenax MPPO 7 DIBP 75 100 40% ~ 80% 10 /2011 4 PAEs 8 9 65% 4% 4 PVC PAEs 19 10 3% 10% 20 21 95% PAEs PAEs 10 PAEs Park 11 7 PAEs 4% 20% 50% PAEs 2- DEHP 12 2 Tenax PAEs PAEs 13-14 Porapak 22-26 3 PAEs 27 100 11 20 3 PAEs - GC-MS 54 China Pulp & Paper Vol. 36 No. 5 2017
0. 1 ~ 40 mg /kg 0. 1 mg /kg 34 GC-MS J 26 7 0. 90 ~ 3. 5 μg /kg 3. 1 ~ 12 μg /kg1 6. 10 J. DMP GC-MS 2011 42 4 61. PAEs 28 PAEs GC-MS PAEs 35-36 Makkliang 29 PAEs - - PAEs 3 PAEs PAEs 2012 10 / 10 PAEs PAEs 0. 1 mg /kg 30 5 PAEs PAEs 0. 05 ~ 1. 50 mg /kg GB /T 21928 2008 16 PAEs GC-MS 31 PAEs 0. 05 mg /kg GC-MS PAEs Bononi 32 - DIBP 0. 2 ~ 20 μg /L 2013 33 GC-MS PAEs 0. 05 ~ 0. 2 mg /kg 2014 27 GC-MS 3 PAEs 1 Xu Jieling Wang Bo Xu Sizhao et al. Analysis of the harmful substances in paper-made food packaging materials J. Modern Food Science and Technology 2009 25 9 1083... 2009 25 9 1083. 2 Yu Li Kuang Hua Xu Liguang et al. Residual contaminant analysis in paper packaging of food J. Packaging Engineering 2015 36. 2015 36 1 6. 3 Yue Qingqing. Harmful substance in paper packaging material and its status of migration study J. East China Pulp & Paper Industry. 2017 36 5 55
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