Synthesis and Crystal Structure of Supramolecular Complex of Zn( ) Bridged by Phthalate

Σχετικά έγγραφα
4, Cu( II), Zn( II)

College of Life Science, Dalian Nationalities University, Dalian , PR China.

LUO, Hong2Qun LIU, Shao2Pu Ξ LI, Nian2Bing

Studies on the Binding Mechanism of Several Antibiotics and Human Serum Albumin

8Q5SAC) 8Q5SAC UV2Vis 8500 ( ) ; PHS23C ) ;721 ( ) :1 4. ;8Q5SAC : molπl ;Britton2Robinson Q5SAC BSA Britton2Robinson,

H 3 {[ Cu( en) 2 ] 5 [ ( VO) 12 O 6 B 18 O 42 ] }[ B( OH) 3 ] 2 16 H 2 O

Electronic Supplementary Information

[ Co( aipamp apamp) ( amp) Cl] [ ZnCl 4 ]

Studies on Synthesis and Biological Activities of 2( 1 H21,2,42 Triazol212yl)2 2Arylthioethyl Substituted Phenyl Ketones

Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4

Multifunctinality and Crystal Dynamics of Highly Stable Porous Metal-Organic Framework [Zn 4 O(NTB) 2 ]

Table S1. Summary of data collections and structure refinements for crystals 1Rb-1h, 1Rb-2h, and 1Rb-4h.

NMR Studies on Interactions between Diperoxovanadate Complexes and 1-Methylimidazole

C H Activation of Cp* Ligand Coordinated to Ruthenium. Center: Synthesis and Reactivity of a Thiolate-Bridged

Studies on the Interaction between Copper( ) Complex with Phenanthroline and L2Methionine Ligands and D NA

ACTA CHIMICA SINICA . :AAO. H 3 PO 4 AAO AAO. Unstable Growth of Anodic Aluminum Oxide Investigated by AFM

Study of Ne w Chemiluminescence Technique Recognition of Sodium Azide by External Reference Method

N 2. Temperature Programmed Surface Reaction of N 2Nitrosonornicotine on Zeolites and Molecular Sieves

Supporting Information. Enhanced energy storage density and high efficiency of lead-free

Syntheses of a Series of Lactato Cobalt Complexes and Their Interaction with Bovine Serum Albumin

Table of Contents 1 Supplementary Data MCD

Supporting Information. Generation Response. Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi , China. China , USA

Supporting Information. Research Center for Marine Drugs, Department of Pharmacy, State Key Laboratory

Supporting Information

Copper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones

Study on the Strengthen Method of Masonry Structure by Steel Truss for Collapse Prevention

Supporting Information

FENXI HUAXUE Chinese Journal of Analytical Chemistry. Savitzky-Golay. n = SG SG. Savitzky-Golay mmol /L 5700.

Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Chiral Carbonyl Iron Systems

Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships. or W, and D = P or V)

Supplementary Information. Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C 6 F 5 ) 3

Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides

Rapid determination of soluble reactive silicate in seawater by flow injection analysis with spectrophotometric detection and its application

Zebra reaction or the recipe for heterodimeric zinc complexes synthesis

Protease-catalysed Direct Asymmetric Mannich Reaction in Organic Solvent

Supporting Information. Asymmetric Binary-acid Catalysis with Chiral. Phosphoric Acid and MgF 2 : Catalytic

Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A. new Entry to N-Carbamate Protected Arylamines

Supporting Information

Resurvey of Possible Seismic Fissures in the Old-Edo River in Tokyo

Experimental. Crystal data

Supporting Information

Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation

D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical and experimental study

Supporting Information

Free Radical Initiated Coupling Reaction of Alcohols and. Alkynes: not C-O but C-C Bond Formation. Context. General information 2. Typical procedure 2

Supporting Information

Supporting Information

Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.

metal-organic compounds

Fused Bis-Benzothiadiazoles as Electron Acceptors

Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information

Quantum dot sensitized solar cells with efficiency over 12% based on tetraethyl orthosilicate additive in polysulfide electrolyte

Electronic Supplementary Information (ESI)

Engineering Tunable Single and Dual Optical. Emission from Ru(II)-Polypyridyl Complexes. Through Excited State Design

Supporting Information. Pd(0)-Catalyzed Decarboxylative Coupling and Tandem C H Arylation/Decarboxylation for the. Synthesis of Heteroaromatic Biaryls

Uncovering the impact of capsule shaped amine-type ligands on. Am(III)/Eu(III) separation

Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes

Antibacterial property of fabric treated with a fiber-reactive chitosan derivative

ACTA POL YMERICA SINICA

Supporting Information

and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol

Table S1 Selected bond lengths [Å] and angles [ ] for complexes 1 8. Complex 1. Complex 2. Complex 3. Complex 4. Complex 5.

DFT Kinetic Study of the Pyrolysis Mechanism of Toluene Used for Carbon Matrix

Zn 2 +, Studies on the Structures and Antihyperglycemic Effects of Zn 2 +, Cu 2 +, Ni 2 + 2Metformin Complexes. ZHU, Miao2Li LU, Li2Ping YANG, Pin Ξ

Room Temperature Highly Diastereoselective Zn-Mediated. Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled

Investigation on Fast Determination of Trace N2Nitrosamines Assisted by Microwave Radiation

Rapid Raman spectra identification and determination of levofloxacin hydrochloride injection *

J. of Math. (PRC) Banach, , X = N(T ) R(T + ), Y = R(T ) N(T + ). Vol. 37 ( 2017 ) No. 5

Separation and Determination of Ephedrine Pseudoephedrine and Methylephedrine by Capillary Electrophoresis with Electrochemiluminescence Detection

Patrycja Miszczyk, Dorota Wieczorek, Joanna Gałęzowska, Błażej Dziuk, Joanna Wietrzyk and Ewa Chmielewska. 1. Spectroscopic Data.

Electronic Supplementary Information (ESI)

Stereochemistry and mechanistic insight in the [2 k +2 i +2 i ] annulations of ketenes and imines

Studies on Diazetetraene Cobalt( ) Metallic Complex as Neutral Carriers for the Preparation of Salicylate2Selective Ion Electrodes

Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings

Electronic Supplementary Information (ESI)

Computational study of the structure, UV-vis absorption spectra and conductivity of biphenylene-based polymers and their boron nitride analogues

Antimicrobial Ability of Limonene, a Natural and Active Monoterpene

Discovery of multi-target receptor tyrosine kinase inhibitors as novel anti-angiogenesis agents

2 PbO 2. Pb 3 O 4 Sn. Ti/SnO 2 -Sb 2 O 4 -CF/PbO x SnO 2 -Sb PbO 2. Sn-Sb 1:1. 1 h. Sn:Sb=10:1. PbO 2 - CeO 2 PbO 2. [8] SnO 2 +Sb 2 O 4 _

16 1 Vol. 16 No ELECTROCHEMISTRY Feb MnO 6 Bir-Co5% Bir-Co10% Bir-Co15% Bir-Co20%. 3 3 Li mol L - 1 MgCl 2.

SUPPLEMENTARY MATERIAL

Enantioselective Synthesis of the Anti-inflammatory Agent ( )-Acanthoic Acid

IV. ANHANG 179. Anhang 178

Optimizing Microwave-assisted Extraction Process for Paprika Red Pigments Using Response Surface Methodology

Supporting Information. Three new high-nuclear transition-metal-substituted

Quick algorithm f or computing core attribute

17 min R A (2009) To probe into the thermal property the mechanism of the thermal decomposition and the prospective

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide

Preparation of Hydroxyapatite Coatings on Enamel by Electrochemical Technique

) ; GSP ) ;PXD g, 100 ml

Supplementary Materials: Exploration of vanadate selenites Solid Phase Space, crystal structures and polymorphism

Electronic supplementary information for

N 2 O + , Fermi, . N 2 O + . Larzilliere (FIBLAS), O + ( 4 S) + N 2 ( X 1 + ) NO + ( X 1 +, v) ], N 2 O + ( A 2 + )

Supporting Information

Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran

The toxicity of three chitin synthesis inhibitors to Calliptamus italicus Othoptera Acridoidea

Nitric oxide (NO) reactivity studies on mononuclear Iron(II) complexes supported by a tetradentate Schiff base Ligand

Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3- Oxyfluorination and 1,3-Difluorination

,,, (, ) , ;,,, ; -

Transcript:

2004 62 14, 1362 1366 ACTA CHIMICA SINICA Vol 62, 2004 No 14, 1362 1366 Zn( ) a, b a Ξ, b c Ξ ( a 110004) ( b 110142) ( c 110036) Zn (NO 3 ) 2, phen ( ) phth ( ) {[ Zn 2 (phen) 2 (phth) 2 ( H 2 O) 2 ] 2H 2 O} n X, P2 (1) / n a = 019643 (3) nm, b = 018976 (3) nm, c = 211410 (7) nm, = 901776 (5), Z = 4, V = 118531 (10) nm 3, D c = 11598 g/ cm 3, = 11367 mm - 1, F(000) = 912, R 1 = 010409, wr 2 = 010818,,, 2,,, Synthesis and Crystal Structure of Supramolecular Complex of Zn( ) Bridged by Phthalate SUN, Ya2Guang a, b WEI, De2Zhou a GAO, En2Jun Ξ, b DING, Fu c ( a School of Resource & Civil Engineering, Northeastern University, Shenyang 110004) ( b Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142) ( c Institute of Chemical Science and Engineering, Liaoning University, Shenyang 110036) Abstract Novel supramolecular complex {[ Zn 2 (phen) 2 (phth) 2 ( H 2 O) 2 ] 2H 2 O} n (phen = phenanthroline ; phth = phthalate) has been synthesized by the reaction of phen and phth with zinc( ) salt Elemental analysis, IR spectra and X2ray crystal structure analysis were carried out to determine the composition and crystal structure of title complex The title complex belongs to monoclinic system with space group P2 (1) / n, a = 019643 (3) nm, b = 018976 (3) nm, c = 211410 (7) nm, = 901776 (5), Z = 4, V = 118531 (10) nm 3, D c = 11598 g/ cm 3, = 11367 mm - 1, F (000) = 912, R 1 = 010409, wr 2 = 010818, and the zinc atom rendered five2coordinate in a distorted trigonal bipyramidal configuration The complex formed 12D helix chain bridged by phth and 22D network structure by 2 action of neighbouring helix chain Keywords zinc complex, supramolecular, phthalate, crystal structure, [6,7], [1 4],,, {[ Zn 2 ( phen) 2 ( phth) 2 ( H 2 O) 2 ], 2H 2 O} n X [5] :, Ξ E2mail : ejgao @yahoo com cn Received November 5, 2003 ; revised February 2, 2004 ; accepted March 22, 2004 (No 20022018) (No 200301)

No 14 : Zn( ) 1363 2, :, P2 (1) / n 1 1 1 Finnigan EA 1112 C, H, a = 019643 (3) nm, b = 018976 (3) nm, c = 211410 (7) nm, = 901776 (5), V = 118531 (10) nm 3, Z = 4, D c = 11598 Mg/ m 3, = 11367 mm - 1, F(000) = 912, R 1 = 010409, wr 2 = 010818, 851-320 e/ nm 3 2 N ; Nicolet470 ( KBr ) 2 1 ; Bruker Smart CCD X, 1 2 011 mmol 20 ml 012 mmol phen N C 1503 cm - 1 1422 cm - 1, Zn 2 + COO, 20 ml, 011 mmol as (COO - ) 1595 cm - 1 s (COO - ) 1383 cm - 1 as s 20 ml,, ph 012 mol/ L KOH ph 7126, 5 h ph 7108, 200 cm - 1,, 25 ml, 200 cm - 1, 212 cm - 1, ( ),,30 d X IR : 3404 (s), 1612 (s), 1595 (s), 1518 (s), 1493 (m), 1449 (s), 1383 (s), 1224 (m), 1147 (m), 1086 (m), 2 2 851 ( s), 759 ( s) cm - 1 Anal calcd for C 20 H 16 N 2 O 6 Zn : C 1, 53189, N 6128, H 3162 ; found C 53180, N 6119, H 3154 1 3 0120 mm 0116 mm 0114 mm, Bruker 2 1,, Smart CCD X, Mo K,Zn(1A) N(1A) Zn (1A) N (2A) : ( = 01071073 nm), 2130 26138, 012143 012166 nm, Zn (1A) O (1A), Zn (1A) O (5A) / 2, (293 K) 10385 Zn(1A) O (4B) : 012124, 012110 011997, 3786, nm, Zn O Zn N,N(2A),O(4B) O (5A) 1 Figure 1 Molecular structure of complex

1364 Vol 62, 2004 1 ( 10 4 ) ( 10 5 nm) Table 1 Nonhydrogen fractional atomic coordinates ( 10 4 ) and equivalent isotropic temperature factors ( 10 5 nm) of complex Atom x y z U eq Atom x y z U eq Zn(1) 8059(1) 3913(1) 6617(1) 29 (1) C(13) 4542 (3) 4107 (3) 7658(1) 27 (1) N(1) 8654(3) 5501(3) 5923(3) 29 (1) C(14) 4403 (3) 5113 (3) 8149(1) 26 (1) N(2) 6796(3) 3278(3) 5816(1) 33 (1) C(15) 3171 (3) 5128 (4) 8483(2) 35 (1) C(1) 9589(4) 6574(4) 5978(2) 38 (1) C(16) 2102 (3) 4164 (4) 8328(2) 41 (1) C(2) 9992(4) 7459(4) 5478(2) 46 (1) C(17) 2248 (4) 3164 (4) 7840(2) 46 (1) C(3) 9415(4) 7217(4) 4903(2) 46 (1) C(18) 3467 (4) 3138 (4) 7508(2) 39 (1) C(4) 8400(4) 6112(4) 4825(1) 38 (1) C(19) 5812 (3) 4147 (4) 7261(1) 30 (1) C(5) 7729(4) 5775(4) 4236(2) 48 (1) C(20) 5613 (3) 6086 (4) 8335(1) 28 (1) C(6) 6733(4) 4724(4) 4194(2) 48 (1) O(1) 6582 (2) 2995 (2) 7235(1) 37 (1) C(7) 6357(4) 3857(4) 4724(2) 40 (1) O(2) 6084 (2) 5295 (3) 6961(1) 41 (1) C(8) 5327(4) 2735(4) 4713(2) 50 (1) O(3) 6749 (2) 5493 (3) 8431(1) 48 (1) C(9) 5071(4) 1939(4) 5241(2) 51 (1) O(4) 5360 (2) 7475 (2) 8385(1) 35 (1) C(10) 5839(4) 2219(4) 5786(2) 44 (1) O(5) 9123 (2) 5144 (2) 7313(1) 37 (1) C(11) 7036(3) 4107(4) 5298(1) 32 (1) O(6) 6227 (2) 8348 (3) 6614(1) 45 (1) C(12) 8056(3) 5268(4) 5351(1) 30 (1) 2 (nm) ( ) Table 2 Selected bond distances (nm) and angles ( ) of complex Zn(1) O(4) 0 1997(2) O(4) # 1 Zn(1) O(5) 88 65 (9) Zn(1) O(5) 0 2110(2) O(4) # 1 Zn(1) O(1) 105 61 (9) Zn(1) O(1) 0 2124(2) O(5) Zn(1) O(1) 95 02 (9) Zn(1) N(1) 0 2143(3) O(4) # 1 Zn(1) N(1) 102 51 (9) Zn(1) N(2) 0 2166(3) O(1) Zn(1) N(1) 151 43 (9) C(19) O(1) 0 1275(3) O(4) # 1 Zn(1) N(2) 104 42 (10) C(19) O(2) 0 1244(3) O(5) Zn(1) N(2) 163 66 (9) O(1) Zn(1) N(2) 90 91 (10) N(1) Zn(1) N(2) 77 24 (10) O(2) C(19) C(13) 119 0 (3) C(19) O(1) Zn(1) 96 19 (19) O(2) C(19) O(1) 121 5 (3) Symmetry code : # 1 - x + 3/ 2, y - 1/ 2, - z + 3/ 2,N(1A) O (1A),,N(1A) Zn (1A) O (1A) 151143 (9), 180, N (2A), O (4B) O(5A) [ N ( 2A) Zn ( 1A) O ( 5A) 163166 (9), O(4B) Zn(1A) O(5A) 88165 (9), N(2A) Zn (1A) O(4B) 104142 (10) ] 356173, 360 3127, N(2A), O(4B) O (5A),,, [9 14] [9] [10] [11],, [ Co (phth) 2 (bipy) ] [11],, 2 Zn, [ 100 ] Figure 2 12D chain structure of complex ( 2)

No 14 : Zn( ) 1365, 0 44 nm 0 61 nm,,,x ac 3 : Zn 2 +, ( 4) phen, phth 5, 013355 nm, [15], 2 3 {[Zn 2 (phen) 2 (phth) 2 (H 2 O) 2 ] 2H 2 O} n 3 ac Figure 3 Projection of tubular channel formed by helical chain in ac plane 4 Figure 4 22D network of complex References 1 Zaworotko, M J Angew Chem, Int Ed 2000, 39, 3052 2 Hagrman, P J ; Hagrman, D ; Zubieta, J Angew Chem, Int Ed 1999, 38, 2639 3 Batten, S R ; Robson, R Angew Chem, Int Ed 1998, 37, 1461 4 Evans, O R ; Lin, W Acc Chem Res 2002, 35, 511 5 Wang, K Bioinorganic Chemistry, Tsinghua University Press, Beijing, 1988, pp 144 146 (in Chinese)

1366 Vol 62, 2004 (,,,, 1998, pp 144 146 ) 6 Blondin, G ; Girerd, J J Chem Rev 1990, 90, 1359 7 Tahir, M M ; Karlim, K D J Am Chem Soc 1992, 114, 7659 8 Deacon, G B ; Phillips, R J Coord Chem Rev 1980, 33, 227 9 Baca, S G ; Simonov, Y A ; Gdaniec, M ; Gerbeleu, N ; Filippova, I G ; Timco, G A Inorg Chem Commun 2003, 6, 685 10 Brechin, E K ; Graham, A ; Parkin, A ; Parson, S ; Seddon, A M ; Winpenny, R E P J Chem Soc, Dalton Trans 2000, 3242 11 Lightfoot, P ; Snedden, A J Chem Soc, Dalton Trans 1999, 3549 12 Yao, J C ; Huang, W ; Li, B ; Gou, S ; Xu, Y Inorg Chem Commun 2002, 5, 711 13 Ma, C ; Wang, W ; Zhu, H ; Chen, C ; Liu, Q Inorg Chem Commun 2001, 4, 730 14 Chen, C ; Zhu, H ; Huang, D ; Wen, T ; Liu, Q ; Liao, D ; Cui, J Inorg Chim Acta 2001, 320, 159 15 Janiak, C J Chem Soc, Dalton Trans 2000, 3885 (A0311052 SONG, J P ; LING, J )

Graphical Abstract Vol 62, 2004 Synthesis of Hydrothermally Stable Mesoporous Aluminosilicates with Tubular Morphology from MFI Zeolitic Precursors and Sodium Silicates ZHENG, Jun2Lin ; ZHANG, Ye ; WU, Dong ; SUN, Yu2Han Acta Chimica Sinica 2004, 62 (14), 1357 Hydrothermally stable mesoporous aluminosilicates with hollow tubular morphology and hexagonal nanochannels were prepared through co2assembly of sodium silicates, sodium aluminates and MFI aluminosilicate precursors Coassembling with soluble silica species, protozeolitic nanoclusters serving as one part of precursors enhanced the hydrothermal stability Synthesis and Crystal Structure of Supra2 molecular Complex of Phthalate Zn( ) Bridged by SUN, Ya2Guang ; WEI, De2Zhou ; GAO, En2 Jun ; DING, Fu Acta Chimica Sinica 2004, 62 (14), 1362 Novel supramolecular complex {[Zn 2 (phen) 2 (phth) 2 (H 2 O) 2 ] 2H 2 O} n (phen = phenanthroline ; phth = phthalate) has been synthesized by the reaction of phen and phth with zinc( ) salt The zinc atom rendered five2coordinate in a distorted trigonal bipyramidal configuration The complex formed 12D helix chain bridged by phth and 22D network structure by 2 action of neighbouring helix chain Chemical Modification of Carbon Nanotubes and Tribological Properties as Lubricant Additive CHEN, Chuan2Sheng ; CHEN, Xiao2Hua ; LIU, Tian2Gui ; YANG, Dong ; ZHANG, Gang ; YI, Guo2Jun Acta Chimica Sinica 2004, 62 (14), 1367 After CNTs were modified with stearic acid, the peaks at about 3752, 1723 and 1543 cm - 1 (Fig a) corresponding to carbonyl groups, oxygen2hydrogen bonds and C C bonds, respectively, disappeared, and two new peaks at about 2924 and 2866 cm - 1 were observed, attributed to cymene group ( Fig b) The results showed that the CNTs were coated with stearic acid by chemical reaction Executive editor PAN, Bing2Feng ; computer typesetter DONG, Hua2Zhen

2025 © DocPlayer.gr Πολιτική Απορρήτου | Όροι Χρήσης | Σχόλια