N 2 O + , Fermi, . N 2 O + . Larzilliere (FIBLAS), O + ( 4 S) + N 2 ( X 1 + ) NO + ( X 1 +, v) ], N 2 O + ( A 2 + )

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1 Π2004Π53 (04) Π ACTA PHYSICA SINICA Vol 53,No 4,April,2004 ν 2004 Chin Phys Soc A g (,, ) (, ) ( ; ) nm N 2 O (3 + 1) X 2 3Π2,1Π2 (000) A 2 + NO nm (PHOFEX) A 2 + X 2 PHOFEX A 2 + : A 2 +,, Fermi, PACC: 3320L, 3310G, 3520P 11 (020) (100) [1,2 ] O + ( 4 S) + N 2 ( X 1 + ) NO + ( X 1 +, v) + N( 4 S) ev (1) [1 ] [2 ], ( A 2 + ) [16, ] 2 ( TEFP) [17 ] ( A 2 + ) A 2 + [3 17, ] A 2 + A Callomon Creutzberg [3 ] A 2 + X 2 A 2 +, A 2 + (300) A 2 + [3 10 ] A 2 +,, X 2 N 2 O (3 + 1) 2 Renner2Teller Fermi, Larzilliere (FIBLAS) NO + A 2 + (010), [11 15 ] X 2 (REMPI) nm A 2 +,A 2 + NO + (PHOFEX) A ( : G ) ( : ) g Tel : , E2mail edu cn Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

2 ( TOF), [18,19 ] 200 Pa,N 2 O 20 % N 2 OΠHe [3,4,11,12,16 ] Penning 9 ] 015 mm [10 ] [17 ] 200 s 2 5 cm LΠs (2X2 70 2X215, ) 1500 LΠs ( F2400, REMPI ) ( ) 1 (a) ( nm) Pa TOF 1 (a) ( ), ( 3 mj) Pa ( f = 30 cm), Nd : YAG( PRO2190,Spectra Physics NO + [20 22 ] ) (532 nm 1 % 470 mj),n 2 O (3 + 1) REMPI (PRSC2LG218,Sirah ) 3 P 1 (000) KD 3 P 30 cm, 2, X 2 3Π2 (000) X 2 1Π2 (000) nm PHOFEX 3 mj ( PRSC2LG224,Sirah nm (3 + 1) REMPI, ) KD 3 P,, 60 cm, X 2 3Π2,1Π2 (000) nm 1 2 mj AΠD ( SR245, Stanford Research System ), Ne 32 cm TOF, (MCP) MCP Boxcar (SR250,Stanford Research System ) 30 Boxcar Ne TOF, (TDS380,Teltronix ), [5 1 ( nm) (a) ( nm) (b) (c) TOF Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

3 4 : A , NO + 10 ns,, X 2 3Π2,1Π2 (000), A 2 +,NO + NO + 1 (b) ( nm) 1 (c) TOF 1 (c) A (a), (b) NO + NO + ( PHOFEX ), 1 (c) NO + A NO + PHOFEX Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

4 PHOFEX, A 2 + N2O ( 1 ) ( 2 ) N2N ( 3 ), = cm - 1, 2 = cm - 1, 3 = cm - 1 [3] ( v 1, v 2, v 3 ) ( v 1-1, v 2 + 2, v 3 ), ( v 1, v 2, v 3 ) ( v 1 + 2, v 2, v 3-1) Fermi Fermi :2 v 1 + v v 3 = P ( ) P (vibrational cluster) Fermi Dunham , [23 ], P P Fermi v 1, v 2, v 3 ^H eff v 1, v 2, v 3 = gg( v) = i v i + d i i 2 + ij v i + d i ij 2 v j + d j 2, ^H eff i ij, d i Fermi v 1, v 2, v 3 ^H eff v 1 + 1, v 2-2, v 3 = K 122 v 2 2 ( v 1 + 1), v 1, v 2, v 3 ^H eff v 1 + 2, v 2, v 3-1 = K 113 v 3 ( v 1 + 1) ( v 1 + 2), K 122 K 113 1, Fermi ( v 1, v 2, v 3 ) ( v 1-2, v 2 + 4, v 3 ), ( v 1, v 2, v 3 ) ( v 1, v 2 + 4, v 3-1) 3 v 3 = 3 3, 1 3, K 113 = nm ( PHOFEX cm - 1 ) NO + PHOFEX 2 A 2 + ( P[ i ]) X 2 (000) 1 NO + PHOFEX Πcm Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved [16 ] ) 4[1] (000) F 1 4[4] (000) F 2 4[4] (000) F 1 5[4] (000) F 2 5[4] (000) F 1 6[1] (000) F 2 6[1] (000) F 1 6[2] (000) F 2 6[2] (000) F 1 6[3] (000) F 2 6[3] (000) F 1 6[5] (000) F 2 6[5] (000) F 1 6[6] (000) F 2 6[6] (000) F 1 7[3] (000) F 2 7[3] (000) F 1 7[6] (000) F 2 7[6] (000) F 1 8[1,2 ] (000) F 2 8[1,2 ] (000) F 1 8[3] (000) F 2 8[3] (000) F 1 8[6] (000) F 2 8[6] (000) F 1 8[8] (000) F 2 8[8] (000) F 1 8[9] (000) F 2 8[9] (000) F 1 9[1] (000) F 2 9[1] (000) F 1 9[6] (000) F 2 9[6] (000) F 1 9[9] (000) F 2 9[9] (000) F 1 10[1 ] (000) F 2 10[1 ] (000) F 1 10[4 ] (000) F 2 10[4 ] (000) F 1 10[5 ] (000) F 2 10[5 ] (000) F 1 11[4 ] (000) F 2 11[4 ] (000) F 1 12[2 ] (000) F 2 12[2 ] (000) F 1 12[8 ] (000) F 2 12[8 ] (000) F 1 1) F 1 X 2 3Π2 ( 000), F 2 X 2 1Π2 (000)

5 4 : A P A 2 + i 2 A 2 + P[ i ] X 2 3Π2 (000) X 2 1Π2 (000), 2 A 2 + P[ i ], ( 3 + 1) REMPI 2 Fermi X 2 3Π2 (000) X 2 1Π2 (000) 2 Scheper [22 ] A 2 + Fermi X ,A cm - 1 [3,,22] 2 Fermi 1 K cm PHOFEX, F 1 X 2 3Π2 (000), F 2 A 2 + X 2 1Π2 (000) A 2 + P = 6 cm X 2 A 2 + X 2 (000) P A 2 +, P A 2 + [4 ] A 2 + X 2 2, 1 Fermi 2 A 2 + P[ i ] P[ i ] G( v) obs Πcm - 1 G( v) cal Πcm - 1 G( v) obs - G( v) cal Πcm - 1 Π% 4[1] 4[4] 5[4] 6[1] 6[2] 6[3] 6[5] 6[6] 7[3] 7[6] 8[1,2 ] 8[3] 8[6] 8[8] 8[9] 9[1] 9[6] 9[9] 10[1 ] 10[4 ] 10[5 ] 11[4 ] 12[2 ] 12[8 ] (8[1]) (8[2]) (100) 200(9711) 210(9218) 021(9816) 060(7712), 140 (2118) 140(6414), 060 (2210), 220 (1314) 220(8118), 140 (1317) 300(9612) 150(4710), 070 (3015), 230 (2117) 310 (9014), 230 (910) 080 (5612), 160 (3811), 240 (515) 041 (9216), 121 (714) 002 (100) 240 (4617), 160 (3115), 320 (1615), 080 (511) 320(7617), 240 (1712) 400(9515) 090(4511), 170 (4413), 250 (1010) 170(3812), 250 (2515), 330 (2511), 090 (1010) 410(8817), 330 (1014) 180 (4717), 0100 (3417), 260 (1610) 0100 (4619), 260 (3814), 340 (1115) 141(6810), 061 (1918), 221 (1211) 0110 (4516), 270 (3314), 350 (1911) 081(6010), 161 (3514) 122 (9111), 042 (616) Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

6 A 2 + [16 ] [3] [17 ] [15 ] K 122 T X 2 3Π2,1Π :1) cm - 1 2) [15 ] 41 A 2 + N 2 O (3 + 1) REMPI X 2 3Π2,1Π2 (000) A 2 +, nm NO + PHOFEX Fermi PHOFEX A 2 + [1] Burley J D, Evin K M, Armentrout P B 1987 J Chem Phys [2] Komiha N 1994 J Mol Struct [3] Callomon J H, Creutzberg F 1974 Philis Trans Roy Soc Lond Ser A [4] Aarts J F M, Callomon J H 1982 Chem Phys Lett [5] Fellows C E, Vervloet M 2001 Chem Phys [6] Tsuji M, Maier J 1988 Chem Phys [7] Imamura T, Imajo T, Koyano I 1995 J Phys Chem [8] Tokue I, Kudo T, Ito Y 1992 Chem Phys Lett [9] Ibuki T, Sugita N 1984 J Chem Phys [10] Tokue I, Kobayashi M, Ito Y 1992 J Chem Phys [11] Lerme J, Abed S, Larzilliere M et al 1986 J Chem Phys [12] Lerme J, Abed S, Holt R A et al 1983 Chem Phys Lett [13] Larzilliere M, Gragued K, Lerme J et al 1987 Chem Phys Lett [14] Abed S, Broyer M, Carre M et al 1983 Chem Phys [15] Larzillere M, Jungen C H 1989 Mol Phys [16] Frey R, Kakoschke R, Schlag E W 1982 Chem Phys Lett [17] Frey R, Gotchev B, Poatman W B et al 1978 Chem Phys Lett [18] Zhang L M, Chen J, Xu H F et al 2001 J Chem Phys [19] Zhang L M et al 1999 Acta Phys Sin (in Chinese) [ ] [20] Michael G, Wallace S C 1991 J Chem Phys [21] Patsilinakou E, Wiedmann R T, Fotakis C et al 1989 J Chem Phys [22] Scheper C R, Kuijt J, Buma WJ et al 1998 J Chem Phys [23] Bernath P F, Dulick M, Field R W 1981 J Mol Spectrosc Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

7 4 : A The spectral a ssignment for the A 2 + transition of ions 3 X 2 Xu Hai2Feng Guo Ying Li Qi2Feng Dai Jing2Hua Liu Shi2Lin g Ma Xing2Xiao ( Open Laboratory of Bond Selective Chemistry, Department of Chemical Physics, University of Science and Technology of China, Hefei , China) Liang Jun Li Hai2Yang ( Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei , China) (Received 10 June 2003 ; revised manuscript received 9 July 2003) Abstract The spectra of ions in A 2 + state have been investigated Pure parent ions, in the X 2 3Π2,1Π2 (000) state, were prepared by (3 + 1) multiphoton ionization of jet2cooled N 2 O molecules using a laser beam at nm By introducing another laser, the parent ions were excited to the predissociative A 2 + state, and the fragment NO + was detected by a time2of2 flight mass spectrometer The NO + photofragment excitation (PHOFEX) spectra were recorded by scanning the dissociation laser in the wavelength range of nm The PHOFEX spectra could be attributed completely to the A 2 + X 2 transition of, in which most vibronic bands were observed for the first time By considering the Fermi resonance between the 1 and 2 modes, the spectra were assigned, and the spectral constants, such as vibrational frequencies, anharmonic constants, and Fermi interaction constant, were obtained with relatively high reliability and precision Keywords : ions A 2 + PACC: 3320L, 3310G, 3520P state, PHOFEX, Fermi resonance, spectral constants 3 Project supported by the State Key Development Program for Basic Research of China ( Grant No G ) and the National Natural Science Foundation of China ( Grant No ) g Corresponding author Tel : , E2mail edu cn Tsinghua Tongfang Optical Disc Co, Ltd All rights reserved

ACTA PHYSICA SINICA nm NO + ( X 1 + ) + N ( 4 S) = 8, 9) + N( 4 S) NO + ( X 1 +, v = 0, 1) + N ( 2 D), [7,8 ]

ACTA PHYSICA SINICA nm NO + ( X 1 + ) + N ( 4 S) = 8, 9) + N( 4 S) NO + ( X 1 +, v = 0, 1) + N ( 2 D), [7,8 ] 53 6 2004 6 100023290Π2004Π53 (06) Π1759207 ACTA PHYSICA SINICA Vol 53 No 6 June 2004 ν 2004 Chin Phys Soc N 2 O + A 2 + 3 g ( 230026) (2003 7 24 ;2003 10 13 ) 360155nm N 2 O (3 + 1) (REMPI) X 2 (000)

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