5γ7.6; 5γ9.β1γ; 5γ9.βγ1; 5γ9.β6-27 - 01.04.07 - : -, - 2016
2. 5 6 1. - 12, 1.1. 12 1.1.1. 15 1.1.2. 20 1.2 26 1.3-28. 1.3.1. 28 1.3.2. 29 1.3.3. 30 1.4 31 β. 32 2.1. 32 2.2. - 34 2.3. 36 2.4. 37 2.5. - 37 2.6. - 39 2.7. 39 2.8. 40
γ. - 42 Mn, Bi, Ni Mo - 3.1. MЧ - 43 3.2. BТ - 50 3.3. 58 σт 3.4. - 64 MШ, 3.5. 67 γ 72 4. - 74, 4.1. - 75 MЧBТ MЧBТCЫ 4.1.1-75 MЧBТ 4.1.2 MЧCЫ, 84 4.1.3 88 MЧBТCЫ 4.2. σтbт σтbта 92 4.3. - MШBТ FОBТMШ 98 4.4. 104 3
FОPЭ FОBТPЭ 4 112 5., - 114 Al 5.1. AlCuCo AlNiCo 114 5.2., AХCЮFО - 119 5 120 121 123 4
5 U M I A P d m S V r s H /
6. - -.,, -.,,, - -, (MnBi, FePt, NiBi) - (MnBiCr, NiBiW, FeBiMo). - ( ), 10 12 10 14 / ( ) 10 5 10 8 K/.,, - ( - (MnBi, NiBi);, - (MoBi); (MnBiCr, NiBiW, FeBiMo, FeBiPt)).. - -
, -, -, - ;,,. -,, - : «- -» (β01γ. 0111U001150), «, -, - -» (2014 : 011γU003043).. -, -. : - -,. -, -. - -. -, - AХ. 7
. -.., Mn, Bi, Ni, Mo; MnBi, MnCr, NiBi, MoBi, FePt; MnBiCr, NiBiW, FeBiMo, FeBiPt, - AХCЮCШ, AlCuFe, AlNiCo,.. - - ( ).,,. - ; - ; - Co- -., -.. -,, : 1. Mn. (V = 10 12-10 14 K/ ) -Mn,, - 8
-Mn (V = 5 10 7 K/ ), -Mn -Mn (V = 5 10 6 K/ ). 2., - Bi β0 β00 -Bi,. - Bi 2 O 3,, з15 /. 3. - σт -σт -σт,, - 100 β0. 4., MnBi - Bi 2 O 3 ( ~ 2-32 / ), - ( ~ 10-400 / ) -MnBi. 5. -, -. - β-γ - β0 100. 6., - Bi, Mn Ni -., - -Bi -, - β0 β00.. - MnBi, -, - - 9
. - AlCuFe, AlCuCo, AlCoNi -..,, -. :, -, -, -,, -,,,., -..-..... - : III HighMatTech, (,,, γ 7, 2011); III " NANO", ( -,,, 19 22, 2012); XI ". ", (,,, β6 30, 2010); XII ". ", (,,, βγ 27, 2012); I International Conference Nanomaterials: Applications & Properties NAP (Alushta, Ukraine, 10
September, 27 30, 2011); II International Conference Nanomaterials: Applications & Properties NAP (Alushta, Ukraine, September, 17 22, 2012); III International Conference Nanomaterials: Applications & Properties NAP (Alushta, Ukraine, September, 16 21, 2013); VII : :,, - (,,, 24 28, 2012); VII ". " (,,, 9 13, 2013); IV - " :,,. " (,,, 19 22, 2013); International Young Scientists Forum on Applied Physics. YSF, (Dnipropetrovsk, Ukraine, September 29 October 2, 2015); БII - - " " (,,, 7 9, 2010); БIII - " " (,,, 1γ 15, 2011); БIV - " " (,,, 11 13, 2012); БV - - " - " (,,, 10 12, 2013); БVI - " " ( -,,, 9 11, 2014); БVII - - " " (,,, 8 11, 2015).. 24, 7-17..,, - (136). 135, - 122, 52 22. 11
1 12,. -,. -, -. - -. Д1Ж -, : (VPD); (ALD); - (HPPMS HIPIMS); (GLAD)..,. 1.1.., -, -, - - Д2Ж.,
( 10-β0 ),. - -.,,,..,,, -, -., -,, -. -,,,,.., -.,,,, - ДγЖ.,,, -,,., -, -., - - 13
- Co, Ni- [1Ж., - -. -, - : - Д4]. (PVD),,, : - - - - - - (,, HPPMS, - UBM,,,, ) - (Arc-PVD) - -.,, :,, - 14
,, -,,.. 15 1.1.1. -.,. - - Д5] J ph p 2 mkt 1/ 2, (1.1) 0 1; -,, m, k. ( ). - [6Ж. ( ), -,,.. -,. -, -.,.,.,, -,, -
,, - Д7].,. - ( - )., -, :, -,,, -.,, -,, -., -. - : - ( -, TТ-Au, Ti-Pd-Au, Al, Al-Cu-Si, Cr-Au, Ti-AР), - (, AХ : CЮ (β%) Si), (, ГЧ, AХ). -,,. - (, AХ, AЮ ). -, - (, Al SiO 1,8 ). - - (, AХ ). 16
-. -. -. - (, Cd ). (Arc-PVD).,, ( ), - Д8-11]. - Д12Ж, Д13Ж, Д14, 15Ж. - - [16, 17].,, -. -, -. -, [10, 18Ж.,. -,.., Д19Ж., TТ-AХ. : 17
- (TТσ, ГЫσ, TТC, Ti(C,N), (Ti,Al)N, CrN). - TiN Zr(CN)( ), ZrN ( ), TiC ( ), Ti(N,C) (,,.) -. -. -. - - -. -, -., -. -, -,. - з 5 β0 [1]. 40, -., -. -. 90. -.., -. -,. 18
,,,, -. -. -, Nb 3 Sn, Nb -,. -,,. -, - - ( - ). -, ( - ), -... - -. : -,,, Д1Ж.. - (, TТ, CЫ, ГЫ ),,. - 19
(, CЫσ, CЫ 2 σ - ). 20 1.1.β., - (, ), / -. - ( ) -. - [20,21Ж. : 1) ( - ),. 2). 3), -,, -. 4). 5),,,.
6) -, ( - ). 7), -. 8). : - (,, ) -. -. -. -. - ( ). - -. -. -. : -. -,. -. -. 21
-. -,,. - -,. -. : - - -, Al, Mo, Mo/Au, Ta, Ta/Au, Ti, Ti/Au, Ti/Pd/Au, Ti/Pd/Cu/Au, Cr, Cr/Au, Cr/Pd/Au, Ni-Cr, W, W-Ti/Au, W/Au. -,, WSi 2, TaSi 2, MoSi 2, PtSi. -,, TiN, WTi. -,, Fe-Al-Si, Co-Nb- Zr, Co-Cr, Fe-Ni-Mo, Fe-Si, Co-Ni-Cr, Co-Ni-Si. - (, - ),, Cr, Al, Ag. - ( ),, MgO, TiO 2, ZrO 2. -,, InO 2, SnO 2, In-Sn-O. -,, Cr 2 O 3, RuO 2. -,, TiN (Ti-Al)N, Ti(C-N), CrN, Al 2 O 3, TiB 2. -,. Cr, Cr,. -,, TiC, TiN, ZrN, Ti(CN), (Ti- Al)N, Cr, Ni-Cr, CrN, HfN. 22
- [22, 23].,,, -...,, -. (ion plating) - 1964 Д24-26]. -,.,, Д27-30].. (ЩХКЬЦК-ЛКЬОН ТШЧ ЩХКЭТЧР) -., -. (ЯКМЮЮЦ-based ion ЩХКЭТЧР) ( ) [31Ж. - -. - - (IШЧ BОКЦ AЬЬТЬЭОН DОЩШЬТЭТШЧ) Д32]. -, : ; - ; ;.., -.,. ( - / ) 1:10, 23
(>500 ) 10:1, (<10 ). -, -., з β00. - -., - (з 5 ) - Д33Ж,. Д34], -. : -. -. - - -,. -. - (, -, ),. -,,. - -. - - (IBAD) [27,28]. : 24
-, -. - -. -. -,. -. - -,., -. - : -. - Ag, Ag Be [35,36]. -,, Al, Ag, Au -. -,, TiN, TiC x N y, Ti 0.5 Al 0.5 N [37Ж -,.. - (TiN, TiC x N y, Ti, ZrN ),,,,, Д38Ж. -,, Al U, [39Ж Ti;. -,, HfN TiN. -,, Al 2 O 3, SiO 2, ZrO 2. 25
- ( - ITO) [40]. - Д41]. Д42Ж. - - Д43,44]. (VКМЮЮЦ-BКЬОН IШЧ PХКЭТЧР) : -,, - (ZrO 2, TiO 2, ZnS), (SiO 2, MgF 2 ). - - (CuO, Cu 2 O) [45]. - - Д46].,. - ( ), -. -. - -,. -. 26 1.2. : 1) ; β) -
; γ). ( ) -, Д47,48Ж. -, (, ) Д47-52Ж.,. -.,,,. - Д53,54Ж. -,,., -,.,,. -,. Д47,48,51,52,55-58Ж, -. -. -, -. 27
-,,.. -, -,, -.,., -. 28 1.3 1.γ.1 - : 1) ; β) - ; γ) ; 4) ; 5) - ; 6). - -,, ( )., -. (,..), -. -., -. -
., -. -...,, -,, -.. - -. - Д59Ж. - -.,. 29 1.γ.β., ( ) - (.) - Д60Ж., -,.,. -, - [61-63]. [61] -
-. Д64-66], -. Д64] - MnBi 540, - MnBi. 30 1.3.3. ( ) Д67, 68Ж. -,, -,.,,, - - ( ).. ( -, ). -,. Д69Ж - - -, Д70Ж, -, - Д71-73].
-. -, Д74]. 31 1.4 -,,,, -, - -,,. - :, -, ;, - ; - ;, - AХ.
2 32,, - -. -,,, : Mn, Bi, Ni Mo; : MnBi, MnCr, CoBi, NiBi, MoBi FePt; - : MnBiCr, NiBiW, FeBiMo, FeBiPt : AlCuCo, AlCuFe, AlNiCo NaCl. 2.1., - -. Mn, Bi, Ni Mo, -. : 1) (Mn, Bi, Ni)., Mn,, -Mn, - -Mn, - Д75].
2) -., Mn - (Cu, Fe, Co, Ni - ) Д76], Mn -. 3) -., Mn - -. - Mn [77]. 4). - 544 (Bi) γ695 (W). Д78]. 5). - : (Bi); (Mo); (Ni) (Mn)., Д79-81],. -, - Bi-., : (NiBi); (MoBi); - (NiBiW, FeBiMo, FeBiPt). (Cr, Mo, W), -, (, MnBi) [65]. 33
-, AlCuCo, AlCuFe, AlNiCo. ( Д82Ж, Д83Ж Д84]). -,. 34 2.2. - - - β79-014 [85]. - - -.,., -, -, -, -,, - (.β.1).
35. β.1 : ; ; ; ; ; + ; G ; h -. -,, γ00.,, 10 15-10 18 /( 2 ). r. 1,γ. : U = β ; I = 0,8 5 ; P = 1,6 1β., - - β0 β0 5. -. -, -
. - NaCl. 6- - 10-15 ( )., -, -,., NaCl,,, -. -,, - 10 12 10 14 / Д3]. 36 2.3., Д86]. -, : ; ; ;. -. -.,. -, β.1: m S d, (2.1) d ; m ; S - ;. 80 1500.
2.4. 37 з 10 50 10 3. -. - -., ( ) Co K - = 0,1790β, - Fe-. - U = β5 I = β0 γ 5. - AMCSD (American Mineralogist Crystal Structure Database). - Wizard Photometr. - ( =0,154β ). 2.5. - -,, -, -
. - з1,γ 10-3.. -, 4 10 β 4. -,. 670-870 4,5 18 /. - -. -, -. β.γ. 38.β.γ - - : 1 ; β ; γ, ; 4-111 ( ) - ; 5-10β, ; 6 ; 7-34; 8 - ; 10 ; 11-8; 12.
-., - -.... 39 2.6. - Д87Ж., -, ln(t/v), (, V ) F(1000/T). ( = 0 exp(-u/kt))., ln(t/v)= F(1000/T), -. 2.7. -, - β50 /, - Fe, - (. β.4).
40.β.4 -., 1, β, γ, 4 -, 5, 6, 7, 8, 9, 10.,,,., -. -, -. 2.8. : MЧ.% (β5, 41, 5β, 61) BТ., - (. β.5) 1700 β100 K, -
, 1γ5 з 7500 / Д48]. 41. β.5.. 1, β, γ, 4 - А Re-., - Д48; 88Ж. 5 β0, - 10 6 5 10 7 K/.
3 42 - Mn, Bi, Ni Mo, -,, -.,.,,., -, -. - -, -. - ( ), (Ч i ), - (I A ), (U M ) (P) Д89Ж. (U ) -,..., I A, U M, P, (U ) Д89, 90]., - -, з100.
Д91Ж, 0,β-0,4., - [92Ж. - -, AЫ Д93Ж., - - - 100 β00 5γ 1γ Д94Ж. - AЫ. - зβ0, - Д94Ж. - - γ-5%,.. 6 Д89, 94Ж. -, -, - 10 12-10 14 / Д93Ж... - ( ). - MЧ, BТ, σт MШ, -. 43 3.1. Mn -, - Д95].
44 1000 K 1373 K -Mn ( a 0.8913 nm) -Mn ( a 0.6314 nm) 1373 K 1411 K -Mn (, a 0.γ86β ЧЦ) -MЧ (, a 0.γ081 ЧЦ). 1000 K -Mn ( = 0,891γ ); : 1000 1γ70 -Mn ( = 0,6γ1β, ); 1γ70 1400 -Mn ( = 0,γ86β ); - 1400 -Mn ( = 0,γ081, ). - -, - 566 ( =0,γ78, =0,γ55 ). -,,, 980 1γ80 4. -, Д96Ж. - -. - MЧ ~ 15β0. MЧ, -,, -., MЧ - : MnO, MnO 2, Mn 2 O 3.. Mn, -. - -, - T N ~ 100 K [76Ж. -Mn -,, Д95Ж. - Mn -Mn -, 660. -Mn,, -. -Mn -
.,, -, 6β5 [76]. Mn, Д76Ж. 70,, 95, 900., 70 95,. - 900. -. Mn, -,, :,, -. Mn, -., - - NaCl, з 160, ~ 1 - ~ 1β0. - ~ β0 [98]. γ.1 ( - ). 45.γ.1. MЧ
46, -Mn ( ) MnO 2, - ( ). Mn, ( ) -Mn - MnO 2 ( =0,44β; b=0,5βγ; =0,β87 ) (. γ.β )..γ.β. MЧ: ) MЧ ; ) MЧ 710, MnO 2 - з 808 Д97Ж. - ( ), -, -Mn -
L з 7,4. -Mn з 0,65, (0,6γ14 ), -, -., - з 7β0, - -Mn, MnO ( =0,4408 ) MnO 2 (. γ.β )., - MnO 2 ~ 700, (808 ). -Mn 7,4 10,5, -. -Mn ~ 0,647. Д76Ж, -. MЧ ( ) V = 5 10 7 K/ - -Mn (a = 0.γ706 ), V = 5 10 6 K/ -MЧ -Mn [98Ж. - MЧ, -., Mn - Д99], -, -., c - 47
., > 10 7 K/ Mn,, - - -Mn ( = 0.γ706 )., MЧ -. ( = 0.3862 ) [100Ж,, - - - (1γ7γ K), -. -MЧ з 39 10 6 K 1, - -Mn (~ 29.8 10 6 K 1 ) [101]. Mn -, γ.γ. ( - ). 48.γ.γ. MЧ: ) v 1 =0,075 / ; ) v 3 =0,3 /
. 610-670, -, -, -.,, 610 680 (.γ.γ ) 670 770 (.γ.γ ),, -MЧ MnO,. - MnO.. 770 570 -, 5β0.,, Mn ~ 5 10 3. - -, Mn ~ 1800 ~ 100. ( ) Mn ( ~ 17 10 3 ), -. [102Ж, (1800 ) MnO 2 -Mn. - MnO 2, - MnO 2, -MЧ MnO. 49
Mn, -, -., - Mn, - -,, -. 6β0, (. γ.4 - ). 50.γ.4. - Mn: ) Mn ; ) Mn 6β0 3.2. Bi, Bi - Д103Ж. -,. - Bi. β,57 β98, - -
. 7,74 ( IЦγЦ К = 0,γ795 ). - β,γ 5,β 770 850 -,.. Bi: BiO 1175, Bi 2 O 3 ( = 98γ ) Bi 2 O 5 ( ~ 4βγ ). -, -, - -Bi 2 O 3. -, - Bi- Д104Ж. 100β -, - 1097. - - 9βγ 91β -. - 9βγ-77γ. BiO Bi 2 O 3 45γ. Bi 2 O 3 9β7 98γ, -, - 11γγ. Bi,,. - Bi 570, Bi 470. 570 10β0 - Bi, -. - Bi. Bi.,, -., Bi,,,, - Д103Ж. 51
Bi 2 O 3,. Bi, ~ -176 10-6. Bi 2 O 3,,, Д104]. Bi, Bi 2 O 3, Bi, - (.γ.1) -. 3.1. Bi 16 d, I A, A P Ar, U,,, 10 2 52 Bi(1) 1200 0,8 16-2 200 7,92 Bi(2) 500 1 120-2 20 7,89 U ; I A ; P Ar - (AЫ); Н ; ; - -. γ.5..γ.5. Bi(2)
Bi(2), - Bi ( ) -Bi 2 O 3 ( )., Bi(1) - Bi ( = 0,47459, = 57,βγ7 ), L ~ 6,5, Bi ( = 0,γ795 ), -,,, - Bi 2 O 3 ( = 0,58486; b = 0,81661; = 0,75097 ). Bi(2) Bi (. γ.6 ), -,, -. - (16 ) Bi(1) - Bi. Bi = 0,4515 ( = 0,47459 ),. 750, - Bi (з544 ), - Bi. - Bi L з 8, - ( = 0,455β )... Bi(1) Bi(2) Bi -Bi 2 O 3 (. γ.6 ). 53
54.γ.6. Bi: ) Bi(1) ; ) Bi(2) ; ) Bi(2) 750 Bi(1) (. γ.7) u-.
55.γ.7. Bi(1), Bi; * Bi - - Bi,. - γ.8 -..γ.8. Bi(2): ) v 1 =0,075 / ; ) v 2 =0,15 / ; ) v 3 =0,3 /
( ).,, 570-6β0,,. - Bi, -, -, v 3, ~630-670 (. γ.8. )., v 1 Bi - 575 ( = 544 ). [89Ж,. -,, -. Bi -Bi 2 O 3, 98γ. з480 -, Bi -. з480 (. γ.8. - )., Д105Ж Bi,, Bi, Д103Ж. -,, -. γ.2 Bi Bi(2),, -. 56
Bi(1) Bi(2) v / Bi,,, 0,075 580 610 480 0,15 590 630 480 0,3 610 650 480 0,075 570 600 470 0,15 590 630 480 0,3 630 670 480 57 γ.β, 15 10 3 8,5 10 3, Mn, - Bi, Bi(1), Bi(2), -. Bi,,, - - (. γ.9 - )..γ.9. - Bi(2): ) ; ) ; ) 6β0 ; ) - 6β0
,, з15 /. -Bi 2 O 3, - Д104Ж. з 6β0 -., (. γ.9 ). -, з8 / (. γ.9 ), Bi. 58 3.3. - Ni Ni -. -Ni ( = 0,γ517 ),, Д103Ж, - 2 -Ni - ( = 0,β651 ; = 0,4γ4γ ), 47γ. -Ni 6γ1., -Ni. - NiO Ni 2 O 3., NiO : - -NiO ( = 0,β9549 ; = 0,7ββ8 ) ;, 5β5, ( = 0,41768 ) Д105]... Ni -
Ni,. Ni γ.3. γ.γ. Ni Ni 1 Ni 2 Ni 3 Ni 4 Ni 5 U, -2-2 -2-2 -2 I, 1 1 2 0.8 5 P Ar, К 120 53 53 16 53, 20 100 100 200 100 Н, 80 100 160 140 120 16, 10 2 5,6 5,6 8,1 4,4 7,7 U ; I A ; P Ar - (AЫ); Н ; ; - -. 59 Ni γ.10..γ.10. : ) Ni 1 ; ) Ni 5, Ni 1 - -Ni ( ) -Ni ( -
) (.γ.10 ). -Ni - Ni (.γ.10 ). Ni 2-5, γ.5,, -, -Ni - -Ni (. γ.11 ). 60.γ.11. Ni: ) Ni 3 ; ) Ni 3 89γ ; ) Ni 1 ; ) Ni 1 91γ
, - Ni 1 -σт, - L з 5, -σт (L з 9 ) σтτ (. γ.11 ). σт 1 -,, - (з β0 ), - Ar (~ 1β0 ). Ni 1 з 91γ, - -Ni (47γ ), -Ni -Ni, -, Ni 2-5 (. γ.11, ). ( = 0,γ517 ). - - γ.4. γ.4. Ni Ni 1 Ni 2 Ni 3 Ni 4 Ni 5, 913 893 893 893 873 L, 5 8 9 9 4 L, 10 16 15 11 7, 0,356 0,36 0,358 0,362 0,364, 0,355 0,358 0,358 0,358 0,355 ; L, L - Ni;, -. 61 σт -, γ.1β.
62.γ.1β. σт 2 : ) Я 1 =0,075 / ; ) Я 2 =0,15 / ; ) Я 3 =0,3 / з 580-680 -.,, Я 2, 610 770 -, - -Ni [107-109Ж. -. γ.1γ - σт 1, -, σт -Ni.
63.γ.1γ. σт 1, σт - з570, - (47γ ), -Ni -Ni [110Ж. з670-700 з 5 10., (E A ), σт E A зβ1 10 3 K (.γ.5).,, Д111]. γ.5. Ni Ni 1 Ni 2 Ni 3 Ni 4 Ni 5, 623 623 703 683 723, 743 733 773 763 783, 10 3 21 6 12 4,5 17 γ.14 - σт.
64.γ.14. - Ni 3 - - Ni -. -,., - з0.5 A/. σт 1 - - σт., -,,, з 50 Д112Ж, 5-10. 3.4. - Mo,, Mo ( = 0,γ14 ). - Mo β89γ.. 87γ, MoO 3 ( = 1,05γ1 ; = 1,4876 ). MoO 3
, [103]. -,. Mo - - γ.6. γ.6. Mo d, I A, A P Ar, U,, Mo 1 160 2 53-2 100 Mo 2 100 0,8 16-2 200 U ; I A ; P Ar - (AЫ); Н ; -. 65, Mo 2, (16 ), Mo, Lзγ,6, Mo 3 (. γ.15 )..γ.15. Mo: ) Mo 1 ; ) Mo 2
, Mo 1, : Mo Mo 2 (Lзγ,4 ) Mo 3 (. γ.15 ). Mo з870 ( γ,6 γ,8 Mo). Mo 2 MoO 2, - MoO 3 [113]. -, Mo,, - - ~6γ0 (. γ.16). 66.γ.16. Mo: ) Mo 2 v=0,075 / ; ) Mo 2 v=0,3 / -.
- (E A ). Mo 1 MШ 2 E A ~6,4 10 3 з9,5 10 3. Mo Mo 1 з 6γ0 Mo 2 з 700., -,. γ.17 - Mo 1. 67.γ.17. - Mo 1 - Mo,,,. 3.5,, -., -
-.,, -, Д114Ж,. 6E d, (3.1) 1 3d 4d, ;, ; / ; ; d, d.,, - Д115Ж, a/a,, ( Ni a NaCl )/a NaCl. Ni NaCl - γ5,9 %. Д116Ж - : 2 E, (3.2), ;, -. -Mn - γ.7. γ.7. Mn, 90 113 133 153 173 193 213 233 253 273 273 293 293 573, 10-6 -1 14,92 18,67 20,84 22,5 24,08 24,91 22,1 68 Bi, -, [117] γ.8.
, γ.8. Bi 287 343 371 414 456 513 521 531 343 355 414 456 513 531 534 538, 10-6 -1 11,4 14,2 12 12 11,4 9,4 4,1-19 69 Bi 573 107γ 1β,6 10-6. Ni, - Ni [103]. (~99,98%) [118] - (. γ.9). γ.9. Ni, 293 474 657 669 771 875 937, 10-6 -1 13 14,2 18,6 15,9 16,7 17,25 18,95 Mo β98 γ7γ ~4,9 10-6, 373 77γ ~5,5 10-6 [103]. - (γ.γ-γ.4), γ.10. β9γ 157γ : t 4,65 10 6 t 0,9 10 t 9 (3.3); 1573 β5βγ : t 6,8 10 3 5 10 t 6 t 2 t 4,4 10 9 (3.4) t 2
γ.10. Mo, 773 1273 1773 2273, 10-6 -1 5,1 5,5 6,2 7,2 70 - Mn, Bi, Ni Mo γ.18 - - NaCl ( =γ6,4 10-6 -1 ) ( =-0,2 10-6 -1 )..γ.18. - : ) Mn, Bi, Ni; ) Mo NaCl
,., -, NaCl,,. - Bi, ~ 520,,..., Bi,, -, (~ 7,74 ), -, ( ~ 0,1 0,4 / 2 ), β0 β00, -. -, - Bi, -, -., Bi. Bi, 750,, - (~ 70 / ) (~ 50 / ), -. Ni -. Ni 1, (1β0 ), - ~ β0 ( ~ 0,1 / 2 ) -, (~ β00 ), 71
-Ni, 47γ.,,,,,., - [114] -, Bi Ni,. 72 3,, Mn, Bi, Ni Mo,,, : 1) Mn,, Mn -Mn Mn 2. -, - -Mn ( V = 5 10 7 K/ ), -Mn - Mn ( V = 5 10 6 K/ ). β), - Bi ( β0 β00 ) - Bi, Bi - -Bi 2 O 3. Bi - (~7,74 ). 4) Bi - з15 / -., -Bi 2 O 3,
,. 5) - σт -σт -σт, ( ~20 ). 6) - Mo -., Mo MoO 2, (~16 ) - (~β00 ). 7), -Bi - ( ~ 0,1 0,4 / 2 ), β0 β00. 73
4 74, - - -,, -.,,, -,, -., -, -, -.,, -,,., - -., Mn, Bi, Ni Mo -, - -.
4.1. - MnBi MnBiCr. 75 MЧBТ, - -MnBТ [65Ж... MЧ, MЧBТ -., -,.,. Cr, -., - Bi,,, Mn., Cr Mn. - Mn Cr Д109]. 4.1.1 - MnBi. MnBi -, (. 4.1).
76.4.1. MnBi [119] Д119Ж 1β55 γ0 9γ % Mn. [120Ж, - Bi 2 Mn BiMn 2, -. MnBi - NiAs. - = 0,4γ41, = 0,5975, / = 1,γ76 = 0,4γγ, = 0,596, / = 1,γ76. - : = 0,4β87, = 0,6118, / = 1,4β7. з 6γγ. MЧBТ ( %): MЧ 59 Bi 41 ; Mn 56 Bi 44 ; Mn 49 Bi 51 ; Mn 42 Bi 58. 4.1. MЧ 49 Bi 51 -, γ40 880.
77 4.1., (.%) MnBi d, I A, A P Ar, U,, Mn 59 Bi 41 380 0,8 16-2 200 Mn 56 Bi 44 240 2 53-2 100 Mn 49 Bi 51 1 Mn 49 Bi 51 2 340 0,8 16-2 200 880 2 53-2 100 Mn 42 Bi 58 150 0,8 16-2 200 U ; I A ; P Ar - (AЫ); Н ; -., 4.2 ( - - ; - - ), Bi - Bi 2 3 ( ), MnO 2 ( )..4.2. MЧBi: ) MЧ 49 Bi 51 1 ; ) MЧ 59 Bi 41 ; ) MЧ 42 Bi 58 ; ) Mn 56 Bi 44
, - BТ ( = 0,45γγ ) Bi 2 3 ( = 0,58486; b = 0,81661; c = 0,75097 ) MnO 2 - ( = 0,9β7γ4; b = 0,28638; c = 0,45β19 ) (. 4.γ ). 78.4.γ. MЧ 49 Bi 51 1 : ) ; ) 96γ з 94γ BТ 6 8 9 14,. Mn 49 Bi 51,,,,., Bi BТ (MЧ 49 Bi 2 51 MЧ 42 Bi 58 ) ( 4.β).
4.β. Bi,, (.%) L,, L,, Mn 59 Bi 41 6,9 0,454 943 9 0,453 Mn 56 Bi 44 6,7 0,462 953 8 0,458 1 Mn 49 Bi 51 6,5 0,453 963 13 0,453 2 Mn 49 Bi 51 9,5 0,458 943 14 0,456 Mn 42 Bi 58 9,5 0,432 943 11 0,452,, L. 79 з γ60, β00 (MЧ 59 Bi 41 MЧ 49 Bi 1 51 ) - BТ (0,45γγ )., MЧ 56 Bi 44 Mn 42 Bi 58 (0,46β ) (0,4γβ ). (5γ ). - - -. MЧ 49 Bi 2 51,, (0,458 ),, - з 880 -. - v 1,2,3. (. 4.4).
80.4.4. MЧ 49 Bi 51 1 : ) v 1 =0,075 / ; ) Я 3 =0,γ / MЧ 49 Bi 1 51 β95 5γ0,. - - 5γ0 640 - Bi. з 800 - Bi Bi 2 O 3., з 490, - Bi, - Bi,, Bi 2 O 3 MnO 2.
- (E A ). - MЧBТ E A ~3-5 10 3,,,, MЧ BТ Д104, 121-124]. -, MЧBТ. -. β /. 7β0 γβ / (. 4.5). 81 1,2 1 0,8 B/Bs 0,6 0,4 0,2 0-50 0 50 100 150 200 250 H, ka/m.4.5. MЧ 49 Bi 51 1 710, - -MnBi -., -Bi 2 O 3,
Bi.,,, -, -Bi 2 O 3 Bi Bi 2 O 3., Mn (Mn 59 Bi 41 Mn 56 Bi 44 ) (<0,5 / ). ( )., Bi β5 5β.%, з 100 K/, : Bi -Mn., - -MnBi. - -., - -MnBi: β5 40.% B -Mn, Mn 61.%Bi Bi. Mn 52.%Bi,,, -MnBi - Mn Bi. -MnBi -, 10 6 K/ - 550 K Д48Ж. (з 10 7 K/ ),,,,, - MnBi. 82
Mn Bi, -MnBi NiAs a = 0,450 c = 0,581. L, - Д106Ж, з9 10. - -MnBi Д1β5, 1β6Ж., Д1β6Ж, Mn 50.% Bi 673 K -MnBi: 0,4β6 0,4γγ 0,608 0,584 -MnBi. - 10 7 K/ -MnBi,, = 0,450, = 0,581. -, - 1150 200 K,, - Д1β5Ж. Mn Bi - з 19βγ K. - T c,, -. - - - Mn, Bi -MnBi., Bi -, -MnBi Д1β7Ж. H c з 50:50 88 β70 A/ Д1β7Ж, -, 19βγ 83
K, 10 400 A/ Bi, Mn 5β.% Bi (. 4.6). 84.4.6. - Mn 52.% Bi (10 A/ ) B β5 61.%. H c - Mn 5β.% Bi (β50 A/ ), Д1β5Ж, - 1175 K -MnBi 5 10., - Mn 5β.% Bi : -MnBi - Bi. ( - ) -, - - -MnBi. 4.1.2 MnCr, -., -, -., Mn -
,., - (Cr) Mn. - Ы Ч 2 -CrMn 3, Ч: ( Ч), ( Ч), ( Ч) ( Ч).. : ' - ". з870. :, - ' ". ' " з1070., (10 7 10 8 / ) Ч., - 4.γ. 4.γ. MnCr d, I A, A P Ar, U,, Mn 93 Cr 7 190 1 120-2 20 Mn 90 Cr 10 540 2 53-2 100 Mn 86 Cr 14 320 2 53-2 100 U ; I A ; P Ar - (Ar); d ; -. 85, MЧCЫ - -MЧ ( = 0,6γ15 ), - L=7,5, Cr ( = 0,β7ββ; = 0,44β7 ) - MnO 2 (a = 0,92734; b = 0,β86γ8; = 0,45β19 ).
з77γ - MnO (. 4.7). 86.4.7. MЧ 93 Cr 7 : ) - ; ) 85γ - MЧ, MЧ 93 Cr 7, = β0 ( = 0,6γ54 = 0,6γ15 )., = 100 ( = 0,6γ59 ), Д128, 108Ж. - -MЧ ( = 0,6γ15 ).
4.8 MЧCЫ. 87.4.8. MЧ 86 Cr 14 : ) v 1 =0,15 / ; ) Я 2 =0,γ / з6β0. -, MnO 2 MnO [129]. v 1 = 0,075 / v 3 = 0,γ /, (E ). MЧ 93 Cr 7, ( зβ0 ),, - MЧ 90 Cr 10 MЧ 86 Cr 14 ( з100 ), Д130] (. 4.4).
MnCr 88 4.4. Mn 93 Cr 7 Mn 90 Cr 10 Mn 86 Cr 14 v /,,, 10 3 0,075 520 640 0,15 560 700 0,3 600 780 0,075 610 690 0,15 630 740 0,3 650 810 0,075 580 710 0,15 610 750 0,3 650 810 3,5 4,6 4,8 4.1.3 MnBiCr.,,, Cr. MnBiCr, - 4.5. 4.5. MnBiCr d, I A, A P Ar, U,, Mn 68 Bi 25 Cr 7 280 1 120-2 20 Mn 63 Bi 15 Cr 22 360 1 120-2 20 Mn 46 Bi 17 Cr 37 490 2 53-2 100 U ; I A ; P Ar - (AЫ); Н ; -.
- ( ) -, MnBiCr Bi L з 10,5, -Mn, Cr ( = 0,β871 ) -Bi 2 O 3 ( = 0,56549 ) (. 4.9 ). 89.4.9. MЧBiCr: ) Mn 63 Bi 15 Cr 22 ; ) Mn 63 Bi 15 Cr 22 71γ., - Bi ; -Mn; Cr - ; Bi 2 O 3, Bi -, 0,448 = 0,4546. з71γ - Bi,, Cr. - Bi 0,448, 0,466
. - Bi.,, - Cr,, MnO, -,, Mn [112]. MnBiCr 4.10 ( - ). 90.4.10. Mn 68 Bi 25 Cr 7 : ) v 1 =0,075 / ; ) v 2 =0,15 / ; ) v 3 =0,γ / ; ) -
91 560, - (. 4.10 ). -, 560 670, -,, - Bi,. -, -. - Bi. - з.440, Bi., MnBiCr Bi - (440 ) Bi (480 ) - MnBi (490 ). Д131]. 4.10 -.,,,, -,,.,, - 0,7 1 10 4, [130]. - -.,, H c з16 /, MnBi зβ /.,,
MnBi, H c γβ /, -, - (. 4.11). 92.4.11. MnBiCr: ) - ; ) 6β0 4.2. NiBi NiBiW -, Ni Bi - Bi 3 Ni (8,55 % Ni) BiNi (21,92 % Ni), Д119Ж. - Bi 3 Ni,. BiNi ( - ), - NiAs,. Bi 3 Ni Bi Bi. Bi Ni 1,5 %, Bi - Ni 618 590. Bi 0 75 %.
, - W, -. з γ695. - = 0,γ17. - W [109Ж -,, -W. NiBТ NiBiW - ( %): Ni 51 %BТ; Ni 47 %Bi 8 %W; Ni 45 %Bi 8 %W; Ni 47 %Bi 10 %W. 4.6. 4.6. NiBТ NiBiW d, I A, A P Ar, U,, Ni 49 Bi 51 1450 2 53-2 100 Ni 45 Bi 47 W 8 240 2 53-2 100 Ni 47 Bi 45 W 8 300 2 53-2 100 Ni 43 Bi 47 W 10 180 0,8 16-2 200 U ; I A ; P Ar - (AЫ); Н ; -. 93 4.12..4.12. : ) Ni 47 Bi 45 W 8 ; ) σт 43 Bi 47 W 10
94 Ni NiBi ( ), - BТ ( ). (L) ( ) -, - σтbт Ni ( = 0,γ595 ), BТ, - Bi 2 O 3 ( = 1,008 ) (. 4.13 ). 75γ - Ni 6,β 6,5 NiO ( = 0,4β01 ) (. 4.13 )..4.13. Ni 49 Bi 51 : ) ; ) σтbта : - BТ, -Ni ( = 0,γ595 ), W ( = 0,γβ1γ ) -Bi 2 O 3. з77γ
σт γ,γ 8,γ, WO 2 ( = 0,486; = 0,β77 ), BТσТ ( = 0,408; = 0,5γ65 ) (. 4.14 ). 95.4.14. Ni 45 Bi 47 W 8 : ) - ; ). - Bi; Ni; Bi 2 O 3 ; W; WO 2 ; * NiBi - -. - NiBi. Ni 49 Bi 51 ( 570 ). -, -. 570 680, -
, Bi Ni cub NiO [121Ж. 870 NiBi -, - (. 4.15). 96.4.15. Ni 49 Bi 51 : ) v 1 =0,15 / ; ) Я 2 =0,γ / BiNiW ~ 800,., BiNiW, -,, - Bi, Bi- ( Bi, MnBi, MnBiCr).
97.4.16. Ni 45 Bi 47 W 8 : ) Я 1 =0,075 / ; ) Я 2 =0,15 / ; ) Я 3 =0,γ / -, - (E A ). NiBi - (1450 ). NiBiW. -, - 100 β00 - ( 4.7).
98 4.7. NiBi NiBiW Ni 49 Bi 51 Ni 45 Bi 47 W 8 Ni 47 Bi 45 W 8 Ni 43 Bi 47 W 10 v /,,, 10 3 0,075 580 650 0,15 620 710 0,3 630 720 0,075 590 700 0,15 620 720 0,3 670 760 0,075 580 660 0,15 620 710 0,3 660 740 0,075 630 690 0,15 660 730 0,3 680 740 11,3 6,8 7,2 12,5 NiBi NiBiW -,. 4.3. - MoBi FeBiMo - ( ) -, -. Bi, Mo. Mo Bi, -. Mo Bi з0,0γ % 1β8γ з0,00γ % 97γ. -
, 1γ0γ Mo Bi з0,0001 % ( ) Mo [119Ж..,,. -,., -. Bi 2 O 3 - Fe 2 O 3.. - -.,, - Mo 50 %Bi Fe 18 %Bi 18 %Mo - (. 4.8). 4.8. MoBi FeBiMo d, I A, A P Ar, U,, Mo 50 Bi 50 570 2 53-2 100 Fe 64 Bi 18 Mo 18 260 2 53-2 100 U ; I A ; P Ar - (AЫ); Н ; -. 99 MoBi,, - Bi, Mo ( =
0,γ147γ ) : MoO 3 ( = 0,γ9β; b = 1,394; = 0,γ66 ); -Bi 2 O 3 (.4.17 ). 100.4.17. MoBi: ) - ; ) 770 з 770, - Bi, Mo cub MoO 3. - Bi (L ~ 6,2-6,5 ). FeBiMo Bi (Lз5,6 ), Fe ( = 0,γ485 ), Mo MoO 3. Bi L~7. FeO - ( = 0,β955 ) -Bi 2 O 3,, (.4.18).
101.4.18. Fe 64 Bi 18 Mo 18 : ) - ; ) 770. - Bi; Fe; Mo; FeO; Bi 2 O 3 ; MoO 3 -, - : ( ~550 ) - ; Mo cub MoO 3 Bi - ~480-610 ; з800 (. 4.19, 4.20).
102.4.19. MoBi: ) v 1 =0,075 / ; ) v 2 =0,γ /.4.20. FeBiMo: ) v 1 =0,075 / ; ) v 2 =0,15 /
, BiMo FeBiMo Bi Bi- з γ80 480 Bi.,, Bi -Bi 2 O 3, Mo. [132, 120]. - - (E A ) (. 4.9). 4.9. MoBi FeBiMo 103 v /,,, 10 3 Mo 50 Bi 50 Fe 64 Bi 18 Mo 18 0,075 540 610 0,15 580 640 0,3 630 690 0,075 530 600 0,15 570 640 0,3 590 670 5,7 11 MoBi -, -,, [132Ж., Bi Mo, - FeBiMo. MoBi -,,. - FeBiMo 770, -
Fe. - H c з16 /. (. 4.21). 104.4.21. - FeBiMo 77γ FeBiPt 4.4. FePt -. FО, -. - FОPЭ, -, - BТ. FePt (.%):, FО 89 Pt 11 ; Fe 79 Pt 21 ; Fe 69 Pt 31 ; Fe 61 Pt 39 ; Pt 71 Fe 29 ; Pt 81 Fe 19 ; Pt 89 Fe 11.
- 4.10. 4.10. FО-Pt, (.%) Fe 89 Pt 11 β,5 81γ FОPЭ ( =0,γ7β ) -1 (L=3,4 ) 87γ FОPЭ ( =0,γ7β ) FОPЭ 89γ FОPЭ ( =0,γ7β ) ( =0.γ7β ) 90γ FОPЭ ( =0,γ7β ) -1 (L=1,2 ) 1-1 (L=2,5 )+ - FО ( =0,γ55 ) 90γ FОPЭ ( =0,γ76 ) 90γ FОPЭ ( =0,γ76 ) 5βγ FОPЭ ( =0,γ81 ) Fe 79 Pt 21-1 (L=3,6 ) 68γ FОPЭ ( =0,γ81 ) 4 + -Fe 75γ FОPЭ ( =0,γ77 ) ( =0,γ55 ) 90γ FОPЭ ( =0,γ76 ) β,5 FОPЭ ( =0.γ79 ) 90γ FОPЭ ( =0,γ76 ) Fe 69 Pt 31 β,5-1 (L=3,97 ) + -2 (L=2,07 ) 90γ FОPЭ ( =0,γ79 ) Fe 29 Pt 71 4 PЭ ( =0,γ9β ) 90γ PЭ ( =0,γ9β ) : -1 FОPЭ, -2 -Fe; L. 105 FО 89 Pt 11 зγ,4. - ( ) з90γ
FОPЭ К = 0,γ7β. - β -. 81γ - FОPЭ = 0,γ7β. - 85γ, -. 89γ, - FОPЭ ( = 0,γ7β ).,. FО 79 Pt 21, - FО 89 Pt 11, - зγ,6.,. - - (8 ), - 149 91 /. FО 79 Pt 21, ( ) 5βγ, FОPЭ - К = 0,γ81. 85γ = 0,γ77, 90γ FОPЭ = 0,γ76. FО 69 Pt 31 : -1 L = 1,9γ, -β L = 1,9. -1 FОPЭ, - -β -FО. - з70% -1, зγ0% -β. 90γ FОPЭ = 0,γ79. - ( ), L -1 = γ,97, L -2 = β,07, 106
- 60% -1, 40% -β., -1 [133]. FО 79 Pt 21. - β -,. - FО 79 Pt 21 - FО, = 0,γ55 ( = 0,γ56 ). - FОPЭ = 0,γ79. FО 29 Pt 71,. 4.ββ, -, - PЭ. 107 ) ). 4.22. Fe 29 Pt 71 : ) ; ) - FО 19 Pt 81 PЭ (. 4.23). -, - -.
108 ) ). 4.23. Pt 81 Fe 19 : ) - ; ) (, ) -. ( ), - (5-15) 10-4 -1. - -. -. FО 89 Pt 11 -,, β9γ 760 (. 4.β4).
109.4.24. : ) Fe 79 Pt 21 ; ) FО 11 Pt 89-760 860,. - - 97γ β9γ. - FО PЭ. 4.11.,,.
Fe 89 Pt 11 Fe 79 Pt 21 Fe 69 Pt 31 FО Pt 110 4.11., / r, s, Н,, / 3 m, (..) (..). 5 0,52 1,39 72,5 453 9,36.. 14 0,28 0,54 52,6. 6 0,39 1,17 109,4 425,4 10,72.. 20 1,32 1,48 71,3. 0,8 2,54 3,52 35,7 321,8 12,09.. 1,8 1,22 1,48 75,2 Fe.. 1,0 4,1 5,85 80 7,86 39,6, / r, s, Н,, / 3 m, (..) (..) Fe 69 Pt 31.. 11 0,78 0,99 321,8 12,09 75,2 Fe.. 37 0,8 4,8 80 7,86 39,6 FeBiPt - Fe 71 Pt 20 Bi 9 Fe 64 Pt 20 Bi 16, d=130-150, - - Д134].,, Bi, Pt - ( = 0,γ878 ), FeO 2 ( = 0,4605; b = 0,9959; =0,γ0βγ ) FePt - ( = 0,β7β4; =0,γ7β ). 77γ Fe 3 O 4 ( = 0,8γ97 ) (. 4.β5 ). -, FePt (Lз4,1 ).
111.4.25. Fe 20 Bi 71 Pt 9 : ) ; ) 77γ. - Bi; Pt; * FePt; FeO 2 ; Fe 3 O 4 Fe 20 Bi 71 Pt 9 4.26..4.26. Fe 20 Bi 71 Pt 9 : ) Я 1 =0,075 / ; ) Я 2 =0,γ /
112 FePt, -, Bi 293 540 (. 4.β6 )., - Bi, 540 670,.,, - Bi, з 4β0 ( ~ 9 10 3 ). Bi Bi, Bi-, 4.β6. 4,, - : MnBi; MnCr; NiBi; MoBi; FePt, : MnBiCr; NiBiW; FeBiMo; FeBiPt., : 1) -, (Cr, W, Mo) -. - β-γ - β0 100. 2), MnBi -MnBi, - ( ~ 10-400 / ), - Bi 2 O 3 ( ~ 2-32 / ). 3) - MnBi ( )
, - -MnBi. 4), FePt 770 5 ~15 /. FeBiPt Bi - FePt, β5 /. 5) BiMo FeBiMo - Bi - Bi- ~ 380 480 Bi. -,, - Bi -Bi 2 O 3, Mo. 113
5 114, - Al : - -,,,,, - Д135Ж.,,, -. AХ-Cu-Fe, Al-Co-Cu, Al- Co-Ni. -, Д61].,, -,, - [87]. AХ 60 Cu 28 Fe 12, Al 67 Cu 20 Fe 13, Al 66 Cu 18 Co 16, Al 69 Ni 15 Co 16, -. 5.1. AlCuCo AlNiCo AХ-Cu-CШ Al-Ni-Co D-,.,
10-. - D-,, -., -,.. D-, -,. 5.1 -. 5.1. AХCЮCШ AlNiCo I A, A P Ar, U,, Al 66 Cu 18 Co 16 2 53-2 100 Al 69 Ni 15 Co 16 2 53-2 100 U ; I A ; P Ar - (AЫ); -. 115 (L) ( ) -, - -.. -., - D-, - (. 5.1 - ).
116.5.1. : ) AХCЮCШ - ; ) AХCЮCШ 9β0 K; ) AХσТCШ - ; ) AХσТCШ 9β0 K. : * AХCЮCШ, AlNiCШ, AХ.
- зγ 6., AХ ( =0,40494 ). -,. -,, -. 5.β - AХ-Co-CЮ -. 117.5.β. AХ-Co-CЮ: ) v 1 =0,075 / ; ) Я 2 =0,15 / ; ) Я 3 =0,γ /
, AХ-Co-CЮ β90 6β0 K -., -. 6β0 7β0 K -,, -. -, з 4.1 10 3. Al-Co-σТ - 670 K (. 5.γ). - ~ 13.4 10 3. 118.5.γ. AХ-Co-σТ: ) v 1 =0,075 / ; ) Я 2 =0,15 /
5.2., AlCuFe - 119 AlCuFe : AХ 60 Cu 28 Fe 12, Al 67 Cu 20 Fe 13, -. 5.4..5.4. AХ 60 Cu 28 Fe 12 AlCuFe, : - AХ 65 Cu 20 Fe 15 FО 3 AХ. - ( ) -, зγ - 11. 10β0 K β. - - AХ-Cu-FО : - ( ), R S =6 10 7 / [136Ж. - -.
5 120,, - - - Al 66 Cu 18 Co 16, Al 69 Ni 15 Co 16, Al 67 Cu 20 Fe 13 Al 60 Cu 28 Fe 12. -, : 1), AХ 66 Cu 18 Co 16 Al 69 Ni 15 Co 16 -,,,, ( ). 2), Al 66 Cu 18 Co 16 Al 69 Ni 15 Co 16 -, -., -. Al 66 Cu 18 Co 16 Al 69 Ni 15 Co 16 -. 3), AlCuFe, -, AlCuCo AlNiCo,, - 6 10 7 /, - -.
121 1), - -Mn,, - -Mn -., - -Mn -Mn. 2), Bi ~β0 ~β00 - -Bi -., -, з15 / -Bi 2 O 3,. 3) - σт -σт -σт., -Ni, - ~β0 -. 4), MnBi, NiBi FeBi β-γ Cr, W Mo, ~β0 ~100. 5), - MnBi - Bi 2 O 3 ( ~ 2-32 / ), - -MnBi ( ~ 10-400 / ). - - -MnBi
Bi, -MnBi. 6) - Bi, Mn Ni -., -Bi - 0,1 0,4 / 2, - ~β0 ~β00. 7), AlCuFe, - - - 6 10 7 / -, -. 122
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