#%" )*& ##+," $ -,!./" %#/%0! %,!

-!"#$% -&!'"$ & #("$$, #%" )*& ##+," $ -,!./" %#/%0! %,! %!$"#" %!#0&!/" /+#0& 0.00.04. - 3 3,43 5 -, 4 $ $.. 04

... 3. 6... 6.. #3 7 8... 6.. %9: 3 3 7....3. % 44 8... 6.4. 37; 3,, 443 8... 8.5. $; 3 7 8....6. #3 3 He-N H O... 8.7. %9: 3 7 3 7... 3.! 8; 3... 35.. $ 8;... 35.. 37 8 3... 38.3. 84 8 8... 39.4. ;... 4.5. 8 6; N (X Σ + g )... 48 3.! 3... 5 3.. # 4 3 8 83... 5 3.. # 3 6; 3... 56 3.3. # ;... 69 4. #; 67... 84 4.. 3 3... 84 4... 3... 88 4.3. $ 3 3... 9 4.4. ' 3 Ar... 04 4.5. ' 3 N... 7 ;... 5 /... 7

3. 6 3 4, 4 9: 3 8 3 ; 6. 3 7 3 33. " 3 33 < 3 (,, ), 4 3 7 8. 3 7 3 8,,, 37,, 3 7 4 3 8 83, 44 8, 8 6; 67 3, 6 3 3;3 3 6 3 4, 9: 3, 6 6 3 3, 9: 3 4 4 7 ;- ; 4.. 4 6; ; 43, 93 69, 7 49, 4 3. < - :,, ;9 ; 9: 4, 493 3 ; 7 8. #6 - ; 6 &%, 7 7 # -0-3074 _ ( «- 4 #» 009 03 = 4.B37..0763.

4. 3-4, 9: 4 4 3 3 7 3 7,,. #6 ; 9: 3: ).; ( 4, 84 8 8,, 37; 8 3, 69 3 ). ) (6 4, ), 6 9: 4 6 3 6 4. 3)!, 99: 4 3 8 83 (#..), ; 8, 84 4 8, 44 4 ;, 9:9.. 44 4 6 3-6 ; 4 7 3 7. 3-4, 9: 6; 8 33 N, O, NO, 4. : 8 9: 3 7 3,, ; 3 7 3 8 3 8 ;

5 3 ; - 4, 9: 9: 3, 7 -, 93 6;9. 73 ; ; 3 8; 69 3 3 3 3 ; < 8; (, 69: ). &< 8; ; < 6 3 69: ; 4 ;.. 6 ; 6; ; 6 4, 4 3 8, 43, 4.. #6 «%3 6 8» (%!.%) «-». ; 6> 8; ;. 7 6 3 3 4 6 %!.% 3 3-7 3.. #; 6 6 67 VI!7 (, 0.), XXXVIII - XL!7 ( ) 4 %$ (, 0-03..), VII 4, 7 «! -03» ($- 6, 03.),!7 4 «; - 4» (, 00-0..).

6 ; 6 6 5 6, 7 0. 5. ; 3 3, 6 8 39 6 8 9 []. 8 6 6 4 ; (, O, H O ), 8 ; 3, 7 []. ; 8 ; 8 63 6. ;3 673 3 3 6; 6 6. $ 3 33 3 <3 4 3 : 3, 3 8-; 3 ; 4, [3] 7 6 [4]. 9 9: 3 7 7 8, 3 4, 6 ; 7 8, 3. 3-7; 9 8 3 6 7 3 3. $: 9: 3< ; 3 4, 9: 3 3, 9 9 ; 6 7. 7 3 3 43 6 8 3 8 6 3. < 3, 6; 3 3 9 4, 9: 3 7.

7.. #3, 8 ( 6) ;3 3:3 7; (, 8, 3 3 ) 9 6;<.. 6>333,,, :;9 8 3 7 ; 9 44 3. %3 73. $, 8 4 8 3 3 ; 3 8 7, 3-4. 3 3 7 8 (#-.) 3 ; 37. 44 8 6 7; 3 7 3 <.,;; 3 3, 3 ; 8 6 3 8, 3 #-.. #-. < ;3 3 66, 3 3.. [5]. < #-., 7 3, 3 3 ; 8, 7 8 [6], 9 7 3 6. 7 3 3 7 8 8 4 4 ; ; 4, 7 7 6 3. ; 8, 9 4 9: 3,,, 3 7<..3 8 9 3 33 ; 4, 39: 7; 3 3, 6

8 3 8 3 4. 9 ; 4 8-89669:, 4, 4 66.. 3 7 3 4 3.. 4, 3 73 3, 93 7 3 3 4 7 -. 3 7 6; ; : 9:3 6.. ; 6 7.. 9: 7;9 3 7 7 8. 3. $4 4 3, ; 6 8 3 8., 63 66 7, 43 4 8, 3 3, 3 ; 3., 43 6 6 3, 4 9 4 49 :3. ;, 6, 3 8, : 3 4-7;. 8 7 ;3 69:, 7: 3 6, 9: 7. 7 4, 9:3 ;9 8 8,...

9 7 3 8 9 4-4, < 9 373. $ 8 3 33 4 ; 37 4 (83 37 4 )., 3 8 73 44 3. & 3 69:3 4 9 4. 7 3 7 8 8 3 8 8 3, 373 4., 3, 6 ; 6 3:, 9 ; 3.. 3 ;9 78 3 3 63, 4 3. 37 63 7 8 : 7, 7 3 8 (..). 3 3 4 9: 3 8 9 3 00-400 6;< 700-800.. < 6 3 ; 3 4 9: 3 7 3. 3 ; 3 33, ; 9: 3 8.! 8 8 8, 3 ; 6; γ - 8 9: 3, 9 ; 3 66. 3 7 ; 00, ; 6;< 9: 3 9: 3 8. 37; 3 7; 6 9: 3 7 8 8

0 3 000 500 /. 4 37 3 9, ; pd ( 3 ) 3 9: 3 9: 3 8. #.. $6 4 ( - 9: 3, 6-3, - 3, - 3 7 3 7 8): -, -, 3,4-8, 5 -, 6 -. 4-4 4 ; 3 3 8, 7. 8 4 < 6 8 9 ; 4. # 8 3, 67..6, 9 6 8 6. 37

3 7 8. 6 ;9: 3. 3 ;. &3 43 8 9: 3 6 7...! 8 3, 67 : 3 7 7 8 6 $.. 3 : 3 9: 3,. 3 9: 3 3 7 6 6; 8, 7 8 3, 3 7 3 8. 9 3 8 3: ; 6 (.,, 6 [7, 8, 9, 0], 7 6 [,, 3, 4, 5]). 7 3, 6 [7, 8],, 3 3 8,, 9: 3 7 8. 6 : 7 9: 3 3 8 8. 9: 3 8 3 γ-83 7; -3, 3 3 3 83, 3 7 6;<3 ; 8 8. 7< 8 3 33 ; 3 4, ; 9: 3 3 ;, 4 ;. - 3 7

.. 67 ; 3 7; 4; 3 7 8 3 9: 3, N He U air? U(N )> U He. 37 ;, 3 9: 3. 4; 7 69; N, 3 3 He ; 3 ( 7 Ar). voltage (kv),6,4,,0 air, water cathode air, water anode N, water cathode N, water anode He, water cathode He, water anode 0,8 0,6 5 0 5 0 5 30 current (ma) #... ;-, N He 3 7; 4; 3 7 8.. 69; 6 [6]. %3 3 He 9 N 7 6; 3 8 3 ( 7; 6). 373 8 3 6;<, ;, 373 7 3 3 (..) 6: 373 3 33 3 He, 3 ; ( 80%) 6: 373 He. 373 ;< ; N 7 6; 6>3 8 3 8, 3 373, 7 7; 6, <9 [7].

3 ;3 He 3 33 3. & N 3 3.. 3 %64.. 3 ", / U c, U c (Cu), T (OH), K T rot (N ), K 0.95 79 370 350 ± 50 [6] 350 ± 50 [6] N.036 703 08 34 ± 00 900 ±00 He 0.36 68 77 8 ± 00 00 ± 00 Ar 0.4 46 30 008 ± 00 400 ± 00 N O 0.78 703-755 ± 00 000 ± 00 CO.4 69 460 93 ± 00 00 ± 00 3 ", / U a, U a (Fe), T (OH), K T rot (N ), K 0.90 63 69 350 ± 50 [6] 350 ± 50 [6] N 0.97 68 5 - - He 0.5 9 50 5 ± 00 00 ± 00 E 37; 7; 6, 4 7 8 5 (U c U a ), 4 Cu Fe 8 [8], :;3 () T J<3, :;3 % rot (N ) 7; 6. % 3 5., 6 [6] 37 N ; 7, 373, 3 ; 373 N 8; <.. 7 6>3; N,, 6, 9. 37; 8 3 7; 6, 7 3 4 6 7 8 5 64. 3 9: 3, N,,, N O CO. 4 3; :9:3 8, ;< 834 9 33 7 8. <; 8 8 3, 3 4 3 3 / 5,. 64., 37; 8 3 7; 6 ; 7, 3..

4 7; 6 3 93, 8; <, 3 3., He : 3 4 3 93-8 7; 6 <. 7 3 33, ;< [9]. 64. 7, 4 9 69 ; 6, 9 3 373 Ar. 373 He CO, 8; <, 3 3 8 6 (6 [8]) 3 6.., 9: 3 8 H O + ( 3 + ), 84 8 8 8, : 693,.! 8 8 8 3: 3 3, 3 ( 3 4, 37; 3.) 3 8 7 9: 3 [7, 9, 0] ; ; 9: 3 [0]. 8 7 43 3, 9:3 6 : 3 3, 69; 3.,, < 6 [0, ]. 6 [] 84 γ-8 8 4 ; 6 ; 8 7. $ 4, 84 γ ~ 0-3 - 7 ~3, ;< ;<. %3 γ-8 7 8 6,.. 6..". $ [3]. 6 8

5 9 ; 4 : ( - ) 3 7;, : 9: + + ; - +, 8 9.. 7 6; 6 8, 6 ;3 7 4. % 4 9 8 3 9 4 8, 69: ; 8, 63 cond I aq. 6 6 8. 8 7 6 ; 8 34 3 ( =.58 8) 4 χ = 0.3 8. $3 83 ϕ = I cond e aq + B + χ 6 6 3 33 6 8 4 9.,3 ϕ = 0.06 8, 3 ;< (8.77 8 3 Cl - 8.65 8 3 ;- ). ; [3] 84 γ-8 8 8 669: 4 8. 8 9: 400 8 84 8, 3 4, γ=0..,3 ; ; 3 6 ; 8 669:. 7 3 3 γ, 9: 3 6 4, 393 <., ;, : 9:, 33 3 : 84 8 8 84 4. ' 6;< 8 84, ;< 3, 6 3 : 3 4 3. 9, 4 8

6 <, ; 9: 3. 7 3 84 γ-8 3 3 3 0-0 - [4]. $ ;, 3 8 7 7; ;< 3 84 γ. 3 6 [5, 5] 3 84 γ-8 8 6 8; ; <3 3 3 4 ; 9: 3: B U c = (.78 )ln +, (.) A γ 84 8 7 3 84 4 α B p = Aexp. (.) p E ; ;9, 3 33 84 4 3 7 (α). $43 :3, ;, 4 3 393,., ;, (.) < 84 B/A 73 (.), (B/A =.3) (B/A =4.3), 3 3.3 [6].. 3 4; 84 8 3 4. #; 4 3 8 3 γ 0-4 0-3..3. "# $$ $: 9 4 8 9: 3 3 3 8. 6 [7] 3 3, 7 3 ( 3

7..)., 3 7 3 4 0, 3-0 - 300. ; 3, 3. 3 3 n e ~ ( - ) 0-3, ; 6.5 7, 6 6. 66 ; $' 3 7,, 33 443 8 (4 7) 0-3.. 9, 3 7 9 n e < 9 ; $'. Lu Laroussi [8] 4 449 8 3 0-0 3 c -3. 3 8 [8] 8 6 []. 3 ; 8-78 3 3 7. # n e 6 9 3 4. [9] 9 3 6;, 7-0 9-3. %7 Mezei Cserfalvi [30] 3 8, 3. 3 0 9-3 ( ;<). 44 8, 4 3, 3 3 He 3, 64. [], 7 3 3 3 0 9-3., -, ; 7; 8, ;. %, ; 4 0 9-3 3 33. 4 3 8 7 6;,, 8 7 6; 4 7; 6 [8, 3]: 0-4 N n e exp(-e i / kt e ) = n e n + k d (.3) 8 3, 4 3 643 3 33 6 8 T e, 3 83 ;<, 83 4 E i. $; ;,,

8 3 ;<, 4 64. n e? n +? 0 9-3 7; 6, ; ; N 3 (-7) 0 4-3 ; 4 64 k d ~ 0-4 3 / [3, 33, 34]. E i / % 7.-3.5. % 3, 6 ; 3 8 4,6 8, 8 6 3 8. He 8 3 83 4 7 6; ; < (E i = 4,6 8), 443 <, 83 8 7 6; < ;3 ; 7 8. 8, 6.4. "% " ", "#, $$ 6 [35] 7; N ; 3 3 :; ( rot ) 6; ( vib ) 33 3 Πu. 3, 6 rot = 500 ± 00 vib = 3800 ± 00, 3 6 3 < 39 rot = 00 ± 00, vib = 400 ± 00. 6 [36] ; 8; 3 3 3 (i=5 50 ), 67 ( 3 7 7 ), 7 4 4. :;3 800 000. 7 6; ; ;4 8 6; T vib ~ 4000 K. $3, 3 67 33 6 67 4. % :;3 43 6, :;3 () N (C) ;3 3 4 [37]. ;< ;9 :;9 N (C) 7 4 3, [38, 39, 40]. %,

9 (), < 3 7 3; :; 3 N (C). #4 8 :; 3 N ;<, 3 ( :; 3 3 N ($),8 -, 3 () - 7,4 - ), 7 6 ; 6 6 4 :; 3 N ($) 9 (). 6 [] 6 67, () :; 3 7 ; 3. 3 T 3 3 :; j<3. ln(iλ/(g+)a jj (a.u. )) 0 8 6 4 0 - -4 900 000 00 400 00 J = 3 J = T = 4000-6000 K J = 30 He Ar N N O CO 30000 35000 40000 45000 50000 E j, cm - #..3 # :; () 7; 6 3 He, Ar, N, N O CO. 3 7, 64 3. $ 3 :; N ($),% 3 () J = 4-5. # :; ().3. $ 3, ;4 6 7 He Ar, 3 3.,3 3

0 :; N (C) He, Ar CO 6 N. 6 0,% N, 6 ; ; 3 N (C-B) He Ar.. 3 ;, 3, 63 9 H O., CO 6; 6 N 4%, 6 ; N (C-B). :;3 N (C) 3 < T N He, 3 N O, CO Ar 693 (. 64 ).,3 3 Ar <, 8 3 6; 3 Ar * N N (C) :; 3 [4].. 7 6>3;, :; N (C) Ar 6;<, T. [] 3, 3 6 :; () (J = 4-5), -, ; (..3). 3 :; 7 :3 J = 3 ( He) J = ( N ) (..3). % 443 3, 7 4; ; <3 ; 3 :;. %, 6; 9: 3 He, He H O 8 <9 (). 84 <3 ; 6;<, He [], 3, ; <3 () 6 3;3, 7 3 44 3., ; 3 :; :; 7 7; 6 3 8 :; 3, 8 3 7 :; 3 ;<,. 00 ± 00K He, 6;< 3 7 3, :; 3 7 ; 9: : BJ (J (J + ) (J )J) > kt [ ], (.4)

B J - :;3 33 7,4 - k 33 ;4, J> 8. %, ; :; 3 7 3 J = 3. (4),, 7; N 6; 7, 6;<.. 7 6; 3 3 6;- :;. :; ;, 83 :3 8 9: 6; 3,.. BJ J(J + ) = @ = 380.5, (.5) J = 3.. 7 ;, 3 :; 7 6; 6 6; :;- 6;3 83 :;. J=3 7 7 3 ; [4]. (-X) 7 6; 7 ; ;, 9: 3 3. $ ;, -;4 :; () 7 ;3 ; 3 8-4 67 H O [43], 7 63 4 8 64 H O + ( 3 + ) [44]..5. " % # $; ; 8 8 7. ; ;9 9,. 8 3 ; 69: 8, 3 4 3 3, 44 4, 3., 6 3 33 9 3, 6;, 6993, N, NO, 7 NH. ; 3 393 (:,

), 9. 8 693 ( 3 33 ; 6) 4, 9 <. % 6, 3 9: 3 : 9 ; 4 8. 43 ; 3 3 7 8 64 =.. (;9 3 6 6 ;, 3 8, 679 ;. 7 3 3 8 8 3 39 6, 3 8 9: 4.., 3 3 3 3, :, 44,.. 6 3 0-850 7; 6 He, Ar, N, N O CO, 6 [],.4. 44 (, (-X)) 69: 3 69 8. [] 9, () 6; ; 4 8 64 + ( 3 + ), 4 8 673 H O, 3 6; Ar 4 64 (X) 9: 67 8 (). 3 6;< 8 6; He (9,8 8 <), 6 : ;, ; () [45].

3 %64.. ; 3 3 8 ( 69: )!,.. - 3 4 I = 5 45, $ = 0. ; / NaCl 0. 35 I = 5 45, $ = 0. ; / KCl 0.0.6 I = 5 45, $ = 0. ; / RbCl 0..4 3 3 3 33 84;. I =5 45, $ = 0. ; / CsCl 0.045.3 Ca I 43, ph =.5, I = 00, = 03 0 94. 3., ; Cu I 34.7, ph =.5.65, I = 00, = 03 0 50 Na I 589, ph =.5.4, I = 00, = 03 0 97 Ca I 43, U =650 50 0 5 Cu I 34.7, U =650 540 B 0 50 Na I 589, U =650 50 B 0 00 6 9 ph.5, 7 3 3 ;< ph. H 486, = 6.5 0.8, I = 30 7 ; 3 H 486, = 6.5 0.8, I = 50 48 ;< ph. [47] H 486, = 6.5 0.8, I = 80 5 87 Cd I 8.8, $ = 0.0 0.5 (L - ) NO 3 5 77 Cd I 8.8 $ = 0.0 0. (L - ) K SO 4 5 75 Cd I 8.8, $ = 0.0 0. (L - ) H SO 4 0 45 Cd I 8.8, $ = 0.0 0.5 (L - ) KCl 5 7 Cd I 8.8,$ = 0.0 0.5 (L - ) HNO 3 7 90 Cd I 8.8, $ = 0.0 0. (L - ) HCl 35 330 $ 44 $d I 8.8. Zn I 3.8, $ = 0.0 0.06 (M) HCl 50-00,3 Cu I 34.7 Pb I 405.8 Cd I 8.8, $ = 0.0 0.06 (M) HCl 00 50 693.,3 ; 7 Ni I 34.5, $ = 0.0 0.06 (M) HCl 00 400 ; 6 $ = 0.0 0.06 (M) HCl 00 400 44. $ = 0.0 0.06 (M) HCl 000 4000 [] [46] [46] [48] [48]

4 3 4 Na I 589, I = 50 0 0 00 $ 3 ; I 766.5, I = 50 0 5 0 3. Zn I 3.8, =.5 00 0 Ni I 34.5, =.5 030 50 Pb I 405.8, =.5 470 60 Cu I 34.7, =.5 3650 80 Zn I 3.8, P = 75 50 0 30 Na I 589, P = 750 60 0 70 Ca I 43, P = 700 40 00 Cd I 8.8, P = 660 40 5 65 $ = 0.0 ;/ NaCl, I = 5 45 0. 60 $ = 0.0 ;/ RbCl, I = 5 45 0. 4 $ = 0.0 ;/ KCl, I = 5 45 0.0 5 $ ; 3 3 33 9: 4. ; 3 3. ; 3 Na I 3, ; 33. $ = 0.0 ;/ CsCl, I = 5 45 0.05 0.3 $ = 0.005 0. ;/ NaCl, I = 35 0.4 30 ; 3 $ = 0.005 0. ;/ KCl, I = 35 0.06 3 $ = 0.005 0. ;/ RbCl, I = 35 0.04 ; 44 NaCl, 44 ; 3 33. $ = 0.005 0. ;/ CsCl, I = 35 0.05 0. 3 3 3 = 0-350, $ = 0. ;/ CsCl, I = 35 0.055 0.8 ; 3 3 3 3 = 0 350, $ = 0. ;/ KCl, I = 35 0.7 3 3 3 3. [49] [49]

5 #..4 3 7; 6 He, Ar, N, N O CO 5. #4 8 9, ;, 4 63 6 6 9 (), Ar 3 43 8, 6 < 44. He, 9 8 4 6 49 4 9: 4 64 8 6 () [45]. (), (X), H(n = 3), O(3p 5 P) 7: e + H O A H(n = 3) + OH(X) + e k~ 0 4 ( ev) 0 0 ( ev)m 3 s [5], (a) e + H O A O(3p 5 P) + H (X) + e

6 k 0 6 ( ev) 0 ( ev)m 3 s [5], (b) e + H O A OH(A) + H + e k~0 9 ( ev) 0 7 ( ev)m 3 s [5], (c) e + H O+(H 3 O + ) A OH(A) + k~0 5 m 3 s [4], (d) e + H O+(H 3 O + ) A OH(X) + k~0 4 m 3 s [], (e) He + + H O A HeH + + OH(A) + He k~.3 0 6 m 3 s Ar m + H O A OH(A) + H + Ar k~0 6 m 3 s [6], (g) N (A) + H O A OH(X) + H + N (X) k~0 0 m 3 s [7], (h) O( D) + H O A OH(X) k~. 0 6 m 3 s [8], (i) e + OH(X) A OH(A) + e k~0 4 ( ev) 0 3 ( ev)m 3 s [9]. (j), 83 ; 8 7; 6 0 9-3 8,. 3, H O + / H 3 O + 3 393 69:, 4 3 643 (43 (e)), 7 6, 3 8 4 67 (43 (c)), 443 7; 6 <, 0%. 7;, 443 7; 6 ;<, 8 6.. 4 6 6 3 3 5%.,4 3 643 7 7 6 9 (X), 6;3 () 8 (43 (j)).

7 $; 4 (X) N (A) <, 6 ; ; 3, 3 44 O( D) 7 ;, ; 44. He Ar, (A) 7 7 6; 6; He (9,8 8) Ar (,6 8). 3, ; He m 8, 6 (n = 3) O ( 3 P), Ar 7 693 H B O (777 ).. 7 ;, 6; 33, H(n = 3) O( 5 ) 7; 6.. 73, ; 6 6 3 6;< 3 44 8, ; 64,, ; 6 (. 49 (e) (g)) [50]. % 4 8 64 H O + 3 + 8 3 H (n = 3) O ( 5 P), 8 7 6; 643 7; 4;. % 7 6 6 N N O, NO (A-X).,3 N O CO 6993 44 (CO, NO, N ), ; 6 3,. $ 693 3 Na (589 ) 7 8. N (C-B) 7 6; ; 3 673, 43 7 63. ; 3 Ar 3, 3, ;<3 83 673 9: 3 Ar 3 3, 8. <, Ar (4p-4s) 7 ;3, 9: 3 3 3 ; 7. 63 4 64 Ar + [5]. ; 3 3 9 3 3 3 Ar 6993,, ; Ar(4p-4s) [5]. % 6, Ar (.4), 7 7 ; 7 64 4. $; 3 9 7,. 6 [6] 693 3 9: 3

8 8, 7: :, 6 ;. ;9 33 73 (, ). 6;< 3 33 : (7 6) 6 3,. 8 ;< 9 : 9, 7; 6. 6 < ; 3, 69: 4;..6. & He-N "# H O,3 6 ; 6 6 8 (.3) 3, 6 -N ; 44 []. He, N 3 393 8 <3 8-67 3 (). 9, 3 44 N <3, :, 9: 43, 33 3. - 3, 3 ; 7 3 44, 49 7...5 373 3 N He. $ 44 N He 693 ; 373, 673 379 3 N. 6 693 8 [6, 53]. 9: 3 7.6 3 (-X), N (C-B) H B N He. 3 N (C-B) ( 337 ) 5%- 44 N He. $ 44 N 3 N ($-) ;<93. ; 3 (A-X) H B ;<3.., 44 N 7 8 7: 5% N.. 7 7 6; 3 ; 7 6; N (C) 5%- 73 (..7).

9,4 discharge voltage (kv),3,,,0 0,9 0 0 40 60 80 00 % N (in He) #..5 ; 373 3 44 N He 3. 3 3 37 3 N. normalized intensity 0, 0,0 OH(A-X) N (C-B) H α 0 00 % N (in He) #..6. 3 OH (A-X) (309 ), N (C-B) (337 ) H B (656 ) 44 N He 3., 8 7 6; 6>3; - (, 3, ) 44 3.

30 6; N (C) 443 N <, 5% [] 3 9 9: ;< N, ; 3 ; 8, 8 (E/N). 5000 4500 4000 T rot (N (C)) T vib (N (C)) T (OH(A)) T (K) 3500 3000 500 000 500 000 0, 0 00 % N (in He) #..7. :;3 (), T, 3 J<3, :;3 6;3 N (C) 44 N He. ;< (A-X) 7 6; 3 < (..6.7), 6 9: ;<, 7;, 3 449 3 <. ; 7 8 7 ; ; 7 3 (-X), 9: ; 4 8 673 8 3-8, ; 693. % 7 H B 7 6; 3 67 8 7; 6. 6:9 []: 6 3 H(n = 3) 6 4 64. % 33 83 H(n=3) <, 6 ;3 4 64 H O + 3 +, 3 H B 5 6;<, (A-X), 6 (n=3) 7o 64 7; 4;.

3 0 He + 0. % N ln(iλ/(g+)a jj (a.u. )) 8 6 4 0 J = He + 5 % N He + 40 % N N J = 30 - J = 3 T = 4000-6000 K 30000 35000 40000 45000 50000 E j, cm - #..8 # :; () 7; 6 N He 3. :; N (C), :;3 T () 33 3 J = 4-5..8 :; (A) 43 44 N He. /<3 4 N,, 3...3,, 9: 6;< :; (). < 6;< 4 8 8..7. ".;, 9:3 3 3 7 7, 7 3 3. ; ;<, & /, 63, 9: ; 3 ( 9: 3 7 j const = p ), 33-66 6 [37]. < 3 8 ; 33. 7, & [38] < <, 3 9: 9 ; 3 < 3: j =.56 0 p,

3 ; /, 6. 7, 63 3 : 4 [39, 40, 4, 54]. < 4, 79: 8, 3 6.! [55] 3 3. #3 73 7 7 8. 3 ;.9. 6 8 6 (..0,.). 3, 69; 6 : [55] <, 63 4 33 ;9 4 64 7;. 43 ; 3 3 7 8 7 64 =.3.!7 ;, ; 3 3. 43 3 3, 4, 37; 3, 84 8.., 3,. 0,50 0,45 0,40 J, / 0,35 0,30 0,5 0,0 00 400 600 800 000 P, #..9. ; 3 78 3 4, 3 80.,

33 #..0. 3, 3 3 7 8 4. 3 3 66 ~#, 3 B-66 # 0.5. #... 3, 3 3 7 8 4. 3 3 66 ~#, 3 B-66 # 0.5. % 6, 8; 3 7 3 7, - 4, 9: 4 4 3 7 3 7,, 3 33 ; 6.. 3 4; 4 6.

34 ; 3 3 8 ( 69: )!,.. I = 5 45, # = 7 0 6 ; OH 3 I = 30 45, # = 93 0 3. 8 I = 30 45, # = 798 0 6 ; ;<3 3 I = 0-30. H 486, # = 480 980, I = 90, =.5 90 40 ; H C 486 O II 44.5 306, # = 500-90, I = 90, =.5 8 60 44.7 ;<3 3 < II 44.5 44.7, # = 580 960, I = 90, =, 3 ; 306 60 48.5 3. $d I 8.8, /p = 0.85 0-3.58 0-3 ( / mbar), I = 90, =.5 300 3 3 /p 3 33 9: 4. Zn I 3.8 /p = 0.85 0-3.54 0-3 ( / mbar), I = 90, =.5 50 3 Ca II 393.4, /p = 0.9 0-3.3 0-3 ( / mbar), I = 90, =.5 00 6 Na I 589, /p = 0.85 0-3.8 0-3 ( / mbar), I = 90, =.5 70 8 Zn I 3.8, # = 60 40, I = 90, =.5 0 5 Cd I 8.8, # = 60 00, I = 90, =.5 0 50 Ca II 393.4, # = 700 0, I = 90, =.5 0 90 Na I 589, # =70 40, I = 90, =.5 0 60 Zn I 3.8 # = 680 00, ph =.7,I = 85 00 Zn I 3.8 # = 680 00, ph =, I = 85 0 50 Zn I 3.8, # = 800 0, ph =.6, I = 85 0 75 Pb I 405.8, # = 680 00, ph =.7, I = 85 0 65 Pb I 405.8, # = 680 00, ph =, I = 85 0 3 Pb I 405.8, # = 680 00, ph =.6,I = 85 0 Zn I 3.8, / p=0.88 0-3.5 0-3 ( / ), ph =.7, I = 85 00 5 Zn I 3.8, / p =0.88 0-3.5 0-3 ( / ) ph =, I = 85 50 ; ; ;<3 ;<9:3 673 9. ; ; Zn I 3.8 Pb I 405.8 ;<3 ph. Zn I 3.8, / p=0.86 0-3. 0-3 ( / ), ph =.6, I = 85 80-3 Pb I 405.8, / p=0.86 0-3.7 0-3 ( / ), ph =.7, I = 85 70 9 /p 3 33 9: 4. Pb I 405.8, / p=0.86 0-3.7 0-3 ( / ), ph =, I = 85 3 3.5 Pb I 405.8, / p=0.86 0-3.7 0-3 ( / mbar), ph =.6, I = 85 5 $d I 8.8, # =00 900, =.5, I = 80 300 0 3 Zn I 3.8, # =00 000, ph =.5, I = 80 00-40 Pb I 405.8, # = 00 50, ph =.5, I = 80 80 0 3 3 33 : 4 9: :. %64.3. - [56] [56] [56]

.! ".. & "% # #3 3 67 7 < ;9, 3 7.,33 < 4 7 8 (,5 $% 665-85)., ;, 6, 6, ;, 7 9: 4 3. -6 3 3 8 8 67. 8 3 33 63 (..). 3 6 ; 3 39:.,; 6 4. 3.. #... #63 : d 78.

36,3 6> 6 3 -. $ :;9 3. 4 3 ; 6 ; 6 3.,36 6 5. #6 6. #... 3 -; - ; 3-6 6>; 4-3; 5-6 ; 6-.,3 3 3 ; 3 ; 6 9: 3 0D I D00; UD (..3). 33 93 ; 6. 4; 9 33 5. ; 3 9; 6 7, 9: 4. 7 3 3 6 3 7. ; 8 ; 373 0 R =5,4!. ( 3,

37 3; 373, 3 R =40,4, ; ;< 3 ; ; ;!) 93 4 ; 8 (Fluke 89 ), 9 7 3 373. % 4 33 9.. ; 3 i=40 6 p=0,-. 7 ; 9. 6> H O 3 50-00. #3 7 8 ;9 ;3-0. #..3..3 - ; -/%#; 3- <9: 00/0 ; 4- ; 5-; 6 ; 7-6; 8- ;; 9-; 0- ; 373; -6 6>; -79: 0/00.

38.. " " " 3 373 :9:3.!78 3 3-0. #3 7, :;9 <: 6 373 3 7. 6 3 3 40. 3 373 6, 3 6 8 7 4. #4 8 373 3 7. #..4. 37 8 3 3 4 3 3 373 3 7 78 33 U=f(d) ; 84 34 7 0,99 (..4.). 84 37; 8 3 6 3..343 7; U = U c + d 9 d=0 3 4., 3; 3 8 3 7 6 3.

39.3. "!!$ 8; ; <3 3 3 4 ; 9: 3: U B = (.78 )ln + c A γ, (.) 84 8 7 3 84 4 [8]: α B p = Aexp p E. 6 4 84 8 E 3 4..4. " & " " $ :;9 4 6 3: 3. ; Screen Calipers 4.0 3 6 3 3 6 3 3. 3; ;, ; 4 <4, 43: Y D Z D3 = =, X D X D D, D D3-3 8 3, X, Y Z- 3 8, ; 3 (..5). 3 :; 3. : 3 ; ; 3 :; 3 7 3.. 3 33 7 :;9. ; 3; <9 3 : 3. 3 3 :; 3 ;9.

40 D(X) D3(Z) D(X) D(Y) D4 D5 #..5. 8 : 3 (i=40, 78 3 d=0 ).5. ' " %& & $ 3 3 50 950 :;9 «AvaSpec-048FT-» 4

4 < 600 < /, < :- 50. #3 3 : 65. 3 3. #;3 <9:3 6; 6 3 0,36. $ 3 ; 3, 8..6. 6 3 ; 3 3 ; 4, 69 (; : 3 4 : : 3 /( ), ;3 9 6. 6 73 4 ;9, 6 6> 3. : #..6 $ 69 $, F = I πr, (.) 4 I 3 ;, - -, R (4 ),. ' df, 8 6> 3 dv 4 : J df = ( r, z, ϕ) dv 4π Ω, (.3) Ω(r,z,ϕ),, J 693 ; ;, -3 - : J = A N, (.4) λ

4 A 3; ;, -, N 443 9: 4 7, 6 67 3., L,R>>R L>>h (. ) 7 7;: πr Ω ( r, z, ϕ ) Ω =, (.5) L R 3, R. % (.3) (.5) 3 F 7 ;: π H R Aλ N R Aλ N R F = rdrdϕdz = πr p H. (.6) 4 L 4 L 0 0 0 $ (.) (.6) 7 ; 7, 3 9: 449 67 9: 4 3 : 4L = I (.7) A R H N λ p 3 3 5 0 3 3 4 ;. # < ; 3;9 0,9..4. " "# % " " ;3 ; 3 33 7. 3 ; 4, 4, 4. 3 ;3, ; 7 6; ; 6 ; 6 3. %, 3 <9 - ;,, 3 8. 7 693 ; <. ; 6 ; 3 ;,, 6 64 ( ) 4 67 4, 4

43 7.. $ 3 3 ; [57]. 6 3 3 ;, :; 8-6; 3 [58]. c N ; ; 3 8-6; N (C 3 Π u, V =0 B 3 Π g, V =). 3 3 9 6 (<%). 7 :; ; 7, :; 3 67 8 33 33 9 ;4 <; :;-;3 43. 6, 6 3; F rot << F r, F rot F r 3 :; 4 3 7 9: 67 33,. F rot 7 4; 9: 6: Vσ N 8kT σ p τ = = rot Z, (.8) π m Z kt V ; ; 73-9, σ 3 9:3, N 443 4, Z, 6 3 :; 4, m 3,, T, k ;4., ;4 :; 3 3 N (C 3 Π u,v=0) 3 3 [58].%, N Ar, N CO He 67 3 : "", 9: ;4,, "3" 6 :;. 8 44 6 6 3 :; J > 5 R-, 6 39., 6

44 "3" 3 67 33 N (E 3 Σ + g ) 3 N ( ). #; < 3 ;4 3 :; 5<J<9 (..4). -, 7 3 : 6 8 <3 33 N (E 3 Σ + g ), 3, 6 3,. % 3, 3 8; C 3 Π u V=0 B 3 Π g, V'= < :;,, :;. 69 ;,, 6 [59, 60, 6] 4 ; 3 7: 3. 3 3 3 7 :; ; 3 6. <3 8-6; 3 ; 73 ; :;, ; 33 4. C 3 G u AB 3 G g, 0-9:9 [58]. 3 C 3 G 0, C 3 G C 3 G ( 9: F, F F 3. $ 7 33 6 B 3 G 0, B 3 G B 3 G ( f, f, f 3 ). 6 (HJ=0, ± (93 J=0IJ =0); HJ=0, ±; J=J =0 HJ = ±), F Af 69 R - P -, F Af 9 R -, Q - P -, F 3 Af 3 R 3, Q 3 P 3 : P ( J ) = F ( J ) f ( J + ) i =,, 3 i i i, R ( J ) = F ( J ) f ( J ) i =,, 3 i i i, Q ( J ) = F ( J ) f ( J ) i =, 3 F F F i i i, 4 ( J ), f( J ) = BV [ J ( J + ) z + z ] DV ( J 0.5), 4 ( J ), f ( J ) = BV [ J ( J + ) + 4z ] DV ( J + 0.5), 4 3 ( J ), f3( J ) = BV [ J ( J + ) + z z ] DV ( J +.5),

4 4 z = = Y ( Y 4) + + 4J ( J + ), z = [ Y ( Y ) J ( J + )], Y. 3 3z 9 B V!3 3, 6 3, 6... %64..!3 3 3 3 C 3 G u B 3 G g N [58] 45 V B V, - D V 0 6, - Y A, - HG(V), - C 3 G u (T e =88977.8 - ) 0.849 6.7.5 39 994.34 B 3 G g (T e =59306.8 - ).598 6.7 6.4 4.3 647.36 3 43 6 3 3 3 Ne (λ=394,4 ) ; 3. # ;, 8;. ;3 3 :;, 3 ; 8; ; ;<. 66..7.,3 3 3 7: 3 ; 3, 6 A [6] 6 3.,3 4 3 : T T ( rλ( T ) ) + λ( T ) r r r z + jeδ = 0, (.9) λ ( T ), T, j, E, δ - 84,, ;, 37; 8 3 3 8, 3:3.,

46 #..7..; (3 3) (3 ) 7; 3 ( C 3 G u AB 3 G g, 0A, A3, A4, 3A5). #3 3 8, 3 40, 3 7 ;9 0, :;3 N (C 3 G u ) 400, 8 3 6;3 N (C 3 G u ) 500. ' < 3 (.9) 3 ; ; 3, 3 3 i, 37 8 3 E 9 8, 3:. 6 ; 3 ( ), (4) 3, T z=0 T z=0,0. T(r, z) 7 ; 99 9 3, 7: T = πr R π 0 Trdrdϕ = R R 0 0 Trdr. (.0) 84 3 6 [63]. 37; 8 3, ; 3 3 3; 8;. 3 ; 363 ( 67, 7 6; < 3 ), 00 (3; 8;

47 9 ). % 4 3 3; 3 ;-. % ; ; ; 3 ; 3 6.!; 3 4 3, : : 3, 3 3. 8 3; 834 33 4 3.,38 ; 0,95. 3 : 3..8. 0,00 z, T, K 0,00 z, T, K 0,008 0,008 3 0,006 0,006 0,004 0,004 0,00 0,00 0,000 0,00 0, 00 r, 0,000 0,00 0, 00 r, ) 6) ) #..8. 3 (), ; 3 3 8 4 (6, % =750 ) 3 (, % =660 ). z - ; 3, 3, r- ;3. % 3 40.

48.5. "!! (% "# N (X Σ + g ),3 73 7 6; 8 33 N (X Σ + g ) ;, 3 6 [64].! 66 8; 6 3 8-6; N (C 3 Π u B 3 Π g )." 3 C 3 Π u 338 6; 8 33 N (X Σ + g ), '' 3, 3 I ( V ) 3 ' V 3 [ N ( X, ) ] 6 n ' '' [ N ( X, V )] I( V ), (.) ' '' e kv V = ' V n e - 443 8, k ' ' - 673 V ' V 8 33 3 Π u, V N (, V ). #< (.) 3 n e k ' ' 3 V ' 3 6; N (X Σ g +, V) 7 < 3 4 8-6;. 9: C 3 Π u B 3 Π g : 0, 3, 3, 3 3, 4 4; 0 3, 4, 5, 3 6, 4 7; 0 4, 5, 6, 3 7, 4 8; ( 6; 3 33 C 3 Π u (V''), B 3 Π g (V')).,3 ; 3, 6 6 3 3 7 3 3 ( 673) 6; 3 I v'', 9 ( A A ) I V = IV V V '' / V V ', (.) V - 33 ; V» V', AV '' - 3 3; I V V 8 3 C 3 Π u,v''; A V V - 3; 9:.

49 < (.) [64] ;, 84 8 673 C 3 Π u,v'' 6; N (X, V') 93 ; - 3-9:. 6 4; 673 6 3 9: #...,3 673 ; ; 6 [0], 8;, 4; 3 (Q v'v» ) 7 ; ( ) = q f ( ε ε ) M Q V V V V / V V e ε, (.3) q V V - - ; M e 8 (38 0-8 3 C 3 Π u B 3 Π g ); f(ε/ ε v'v» ) ;3 43 <3 : 8 8 8 4 ( 8 4 [0]). [65] 3 93 6 3 33. 9: 3 6 3 8 R-4 [0], ; 6 [0, 66]. ; 3 3 [67]. # 3 3 ; ; 4 8;, [65]. #.. 3 8 N, O, NO, H O, 8-8 (e-e) 3 3 6; 67. ; 49 4. 4 e-e 3 3 -, 3 73 673 3 6;. 449 8 (n e ) 3 3 I E/N, 3, ; n e 4 3.

50 7 N (, V>4) ; 3 (834 6; ;4), 7 6; - 673.. 6 4; (6 ;< - 9: ) 6;.,; 4 N (C 3 Π u, V) 7 6; < 3 69: 8 3. $ 44 8 <3 49 7 ;3.!7 4; ;9 <3, 3 < 8 9 3 40.,3 3 C 3 Π u, V=0 <3 N, O, H O 0 - [5, 68], 3 0-0 [68] ~ 0 - [83]. $ ; N, O, H O 44 4 N = 4 0 8-3 <3 3 4,0 0 8 -.' 4 4 3 C 3 Π u, V=0,74 0 7 - [66]. $ ; 4 <3 3, 4 33 C 3 G u 3 3 33 ; <. % 3-7; (.) 6 ; υ υ '' n kυυ Nυ = Zυ ' I, (.4) ' e ' υ ' υ '' υ A A υkυkk 3; 4 4 6; 3 N (C 3 G u, υk), n e 443 8, k υυk 673 3 υk 33 C 3 G u 3 υ 33 X Σ + g, N υ 443 X Σ + g 6; υ, Z υk <3, I υkυkk 9: - 7; N. $ 3 6; 3 33. #< 8 8; 3 I υkυkk 3 ; 6; 8 33.

5 84 3 (.4) 67 7 <, 6. 8 3 <3 ; 34 % [69]. 34 6 6, 6 3 ; < δ=5%. 8; ; 7 6; N (X Σ + g ) ; 3;9 0.95 93 ;4 ( ;..9). Ln((A 0, / A v'v" )(I v'v" / I 0, )) -9.0-9. -9.4-9.6-9.8-0.0-0. -0.4-0.6 0 000 4000 6000 8000 0000 E, - #..9. 66 6; 33 N (C 3 Π u ) 3 7 3 7 ( 3 ). % 8, ;< 3.

5 3. # " 3..!# $ " " ",3 3 4 3 8 83 (#.., f(l)) ; 3 4 #.., 67 73 3 : d df β = J + J + dε dε J ee, (3.) E β = ε k Y k Q tr, 3 N k E/N 3 37; 8 3, ε :3 83 8, Y k ;3 3 k-, k Q tr 3 8 k-, J, J, J ee, 8-8 (e-e). J d kt df = γ + γ f dε e dε, kt, e k YkQtr γ = m + k M ε 6ε k m 8, M k,, B k, :;3 33, k B k Y k Q k r k Q r 673 :; k-., 67 :; 3 9 6: 3, ; 6 3 3 8 8 6; 67.

J 3 ( 9: 3 - -, : J J = 53 k k Yk [ ε Q ( ε ) f ( ε ) ( ε + ε jk ) Q ( ε + ε jk ) f ( ε + ε jk )] j j j k k k [ ε Q ( ε ) f ( ε ) ( ε ε ) Q ( ε ε ) f ( ε ε )] = Yk j jk j j k (3.) (3.3) ε jk 3 83 j- 4; k Q j 4 3 - ; k Q j. $ 3 j- 43 3 k-. $3 k Q j jk jk J, (3.). (3.3) J ), k Q j 3 7 6 4 ; 3 Q ε ε ( ε + ε ) k jk k j = Q j jk. ε 8-8 33 J ee ε ε 3/ d df = ν ee ε f dε 3 dε 0 o ε / 3/ 3/ ( ε ) ε f ( ε ) dε + ε f ( ε ) dε + ε f ( ε ) dε, 4 4π e ln λ ν ee = Y, e - -, 3 m υ lnλ - : / K ε T ln λ = ln. e 3 / n e 73 Y e, n e, υ, e, ε ;3 3, 443, ;, 3 33 83 8,. 0 / #.. ;: ε ( ε ) dε = f. <3 3 ;4 6.. #6 [70]. ; -3 3 3. 6 8,,... m, m+,...n (3.) ( ε m ε m+ )

54 3; 4 3 (3.) m m m m m m m d f c f b f a = + +. (3.4) 84 m m m c b a,, m d 3 393 9: <3: ( ) + + + = m N m d f d f Y m e e kt a e m m ε ε ε ε ε ε ε ε ε λ π γ β 3/ 3/ 4 3 ln 4, ( ) + + + + + = + m d f Y m e Q Y Q Y a a b e j k j k k m j k k m j k m m m m m ε ε ε ε ε λ π ε ε γ / 4,, ln 4, + + + + + = + + + + + + + / 3 3/ 4,, 3 ln 4 m N m d f d f Y m e Q Y Q Y a c m e j k j k k m j k k m j k m m m m ε ε ε ε ε ε ε ε ε λ π ε ε γ, + + + + = + + + + + + + + + + + + j k k n m j n m n m k n m j n m n m k j k k n m j n m n m k n m j n m n m k m j j j j j j j j j j j j Q f Q f Y Q f Q f Y d,,,, ε ε ε ε ε. m, m +, m + ± n j, m ± n j 9, 33 9:3, ( ) /, + = = + ε ε ε ε ε ε jk j m m n. $ (3.4) 3 3 3, 9: 8 8 ε=ε ε=ε N : ( ) 0 = + f a f a γ, (3.5) ( ) 0 = + N N N N n f a f a γ. (3.6) #3 (3.4)-(3.6) 3 33, ; 3 9 3 8 8, 7;, 3 k j k j Q Q, 9 3 ε>ε N.

55,3 <3 ; ; 67, 93 9:. 49 673 3! 8 8 3 84 a, b, c d. %3 4 4 ;, 6 <;, ; 3 #.. 9: 673. 43 4 3;, ; 3 ;3 <; δ = 0,000. ;, ; ; 673, 3 6 4. ;; 9 6 8 8 : ; 63 8 8 8 3 7 3;3 ; 8 4 8. 6 N 3 ε N, 3 7 3;3 6. ', 3 8 3 (-60) 0-6. N=5000 6 6 8 ;9 7 0,5%. 8 4 3 8, 33 83 ε, 84 DN, ; V D, 4, 9: ; 8 k kj : ε = 0 ε 3 / ( ε ) f dε, (3.7) DN e = 3 m / 0 k ( ε ) ε f dε, (3.8) k Y k Q tr V D e = 3 m / E N 0 k ε Y k Q k tr df dε, (3.9) dε

56 k kj / e k = ε Q0 ( ε ) f ( ε ) dε. (3.0) m ε jk 3 43 $.. $ Delphi 7... #6,.. 6 3.. " # " (% # # 4 3 6; 3 8 33 6 <3, 9 3 4 3 8, V T- 3, 4 V V-6, 4, 4, 4 8-67.. 7 4 3 4 6; 8 3 N, O, NO H O 7: 3, 3,, O, N, Ar 64 3..! (X) 3; 43 (00), (00) (00), 8 ; <3, [7]. 6 3., 9: 4 6; N ( X + Σ g ). 93 3 6; 7:3 ; 69:3 ; 4.

[ V ] d dt VTN KV = + KV + W = 0,V 57 VTO 3 VTN 4 V,V V,V V,V [ ] + KV,V [ O( P) ] + KV,V [ N( S )] 3 W,W + W,W + W,W + ( KV,V W + ) + ( KV,V [ W + ] ) + ( KV,V [ W + ] ) + VTO VTNO VTH O [ N ( 0) ] + K [ O ( 0) ] + K [ NO( 0) ] + K H O( 0) VTAr,V [ Ar] + [ ] W = 0 45 35 W,W + W,W + ( KV,V [ W + ] ) + KV,V [ W + ] W = 0 W = 0 39 W,W + ( ) + ( KV,V [ W + ] ) W = 0 VTN VTN VTO VTO VTNO VTNO VTH O VTH O ( KV,V + KV,V + ) [ N( 0) ] + ( KV,V + KV,V + ) [ O ( 0) ] + ( KV,V + KV,V + ) [ NO( 0) ] + ( KV,V + KV,V + )[ H O( 0) ] 46 45 VTO VTO 3 VTN VTN 4 VTAr VTAr W,W W,W + + ( KV,V + KV,V + ) [ O( P) ] + ( KV,V + KV,V + ) [ N( S )] + ( KV,V + KV,V + )[ Ar] + ( KV,V + [ W ]) + ( KV,V [ W ]) 4 3 W,W W,W + + ( KV,V + [ W ]) + KV,V [ W ] W = W = 0 W = + W = W 0 W VTN VTO VTNO KV +,V [ N( 0) ] + KV +,V [ O ( 0) ] + KV +,V NO( 0) + K VTO 3 VTN 4 VTAr + KV +,V [ O( P) ] + KV +,V [ N( S )] + KV +,V [ Ar] + 46 36 + W,W W,W + ( KV +,V [ W ] ) + KV +,V [ W ] + Kh + W = W = W 4 3 3 W,W W,W W + ( [ ]) + [ ] + KV +,V W KV +,V W KV + W = W = W = W = 0 3 3 W,W W,W + W,W W,W + ( ) + ( KV,V + [ W ]) + ( KV,V [ W ]) + ( KV,V + [ W ]) + ( KV,V [ W ]) W = 0 36 35 40 39 W,W W,W + W,W ( KV,V + [ W ]) + ( KV,V [ W ]) + KV,V + [ W ] + W,W + ( ) ( K [ W ]) = = W = 0 V,V VTH O [ ] [ H O( 0) ] V +,V 40 W,W ( ) ( KV +,V [ W ] ) =,W ( ) ( [ W ] ),V + W = + K W = h + + n K e V0 W = 0 W = 0 + [ V + ] + n K [ N ( 0) ] + Q = 0 e 0V V [ V ] + + [ V ] + (3.) (3.) ; 9: 63: [V] ; 6; 3 V 3 N ( X + 6; W 3 N ( X ), O ( X + Σ g ); [W] Σ g 3 Σ g ), NO(X ); VTO VTN VTAr VTO H O(X); VTH O VTNO K, K, K, K K, K, K VTN V V,V V,V V,V V,V, V,V T-4 3 O( 3 P), N( 4 S), Ar O, H O, NO, N 6; N V, V,V V,V ; V ; W,W + V,V K 4 V V-6 3 W V 33 W+ V,. 7 9 6; 3 N, 6; 3 9; K 0V K V0 673 673 3 V N 8, ; K h 8 3 4; Q V 3 3 9: 33 4. $ 3 6; 3 44: V = 4 3 H O(00), V = 3 3 H O(00), V = 3 3 H O(00), V = 40 3 NO(X ), V = 36 3 + 3 O ( X ) V = 46 3 N ( X ). Σ g Σ g

58 %64 3.. 7 4, 9: 4 3 + 3 6; 3 3 N ( X ), O ( X ), NO(X ), H O(X) Σ g Σ g = 4 V N (V=0) + e N (V= 8) + e V O (V=0) + e O (V= 4) + e V3 NO(V=0) + e NO(V= 5) + e V4 H O(000) + e H O(00) + e V5 H O(000) + e H O(00) + e V6 H O(000) + e H O(00) + e V7 N (V) + N (W) N (V ) + N (W+) V8 O (V) + N (W) O (V ) + N (W+) V9 NO(V) + N (W) NO(V ) + N (W+) V0 H O(00) + N (V) H O(000) + N (V+) V H O(00) + N (V) H O(000) + N (V+) V H O(00) + N (V) H O(000) + N (V+) V3 O (V) + O (W) O (V ) + O (W+) V4 NO(V) + O (W) NO(V ) + O (W+) V5 H O(00) + O (V) H O(000) + O (V+) V6 H O(00) + O (V) H O(000) + O (V+) V7 H O(00) + O (V) H O(000) + O (V+) V8 NO(V) + NO(W) NO(V ) + NO(W+) V9 H O 00 (V) +H O 00 (W) H O 00 (V ) +H O 00 (W+) V0 H O 00 (V) +H O 00 (W) H O 00 (V ) +H O 00 (W+) V H O 00 (V) +H O 00 (W) H O 00 (V ) +H O 00 (W+) V N (V) + N (W=0) N (V ) + N (W=0) V3 N (V) + (W=0) N (V ) + (W=0) V4 N (V) + N(W=0) N (V ) + N(W=0) V5 O (V) + O (W=0) O (V ) + O (W=0) V6 O (V) + N (W=0) O (V ) + N (W=0) V7 O (V) + N(W=0) O (V ) + N(W=0) V8 O (V) +H (W=0) O (V ) +H (W=0) V9 N (V) +H (W=0) N (V ) +H (W=0) V30 NO(V)+NO(W=0) NO(V )+ NO(W=0) V3 NO(V) + N (W=0) NO(V ) + N (W=0) V3 NO(V) + O (W=0) NO(V ) + O (W=0) V33 NO(V) +H (W=0) NO(V )+H (W=0) V34 H (00)+H (V=0) H (000)+H (V=0)

= 4 V35 H (00)+N (V=0) H (000)+N (V=0) V36 H (00)+O (V=0) H (000)+O (V=0) 59 V37 H (00)+H (V=0) H (000)+H (V=0) V38 H (00)+N (V=0) H (000)+N (V=0) V39 H (00)+O (V=0) H (000)+O (V=0) V40 H (00)+H (V=0) H (000)+H (V=0) V4 H (00)+N (V=0) H (000)+N (V=0) V4 H (00)+O (V=0) H (000)+O (V=0) V43 N (V) + Ar N (V ) + Ar V44 O (V) + Ar O (V ) + Ar V45 N (V) + N( 4 S) N (V ) + N( 4 S) V46 O (V) + N( 4 S) O (V ) + N( 4 S) V47 O (V) + O( 3 P) O (VK<V) + O( 3 P) V48 N (V) + O( 3 P) N (V ) + O( 3 P) V49 NO(V) + N( 4 S) NO(V ) + N( 4 S) V50 NO(V) + O( 3 P) NO(V ) + O( 3 P) V5 N (V) + O( 3 P) NO(&) + N( 4 S) V5 O (V) + N( 4 S) NO(&) + O( 3 P) V53 NO(V) + N( 4 S) N (V = ) + O( 3 P) V54 O (a) + O (V = 5,6) O (V = 5,6) V55 N (V) V56 O (V) V57 NO(V) V58 H O(00) V59 H O(00) V60 H O(00) W W W W W W N (V-) O (V-) NO(V-) H O(000) H O(000) H O(000) : 4 V55 V60 9 9 49. 3 6 V T- V V-4, ; 9 6;<9 3; [7]. 9 3 4 V T-4 (X, V) ( 3 ), (V47). 8 7 ; 6 [73], 6,,, 3 V=4-9 3; 77: V=m 3 m, 93 < K vm =K 0 [+0.04(V-)],

60 8343 K vm 6; 3 V V= 3 K 0, 6 [74]. 3 4 (V V6) 3 <3 3 ;4 3 <, 7: N, O, H O, NO Ar, ( 3 #). V V- V T-4 ; <, M 4 $ 4; (SSH) 33 6 84; 73.,3 V T-4 3 V V [75] K V + ( ) ( V + ) ( x ) e hxeωev T exp ( ) δvtv x V + kt,v = K0, (3.) 8 π ω e x e µ δ VT =, V 0 3 α kt γ V [ ( V + ) ] e γ ; VT 3 ( x ) ( x ) µ 3 4 x e π ω e e δ =, e α kt γ V > 0 ; π ω e x e µ =. (3.3) α kt,3 V V-6: K W,W V + V, + 0 ( V + )( W + )( x )( x ) = h K0 ( T ) F ( Y ) exp [ x ( V + ) ][( x ( W + ) ] ( ω x W ω x V ) kt. (3.4) F(Y) 3 33 ( δ W δ V + δ p ) ( p) F ( Y ) = exp exp δ, (3.5) 8 π ωx µ 8 π ω x µ δ =, δ =, 3 α kt 3 α kt p ω ω + ( ω x ω x ) =. xω 3 F(Y) 33 9: 73: [.5 0.5exp( V W )] exp( V ) F ( Y ) = δ δ W, Y < 0, (3.6) VV 8 π ω e x e µ δ VV =, 3 α kt VV

7 3 3 F ( Y ) 8 π = Y exp( 3Y 3 ( V W ) 4π ωe x e µ Y =. α kt 6 ), Y > 0, (3.7) V T- V V-6 3 6 4 3 ; 4 ; 3: K K K V, V + = V +, V W +,W V, V + = K W,W + V + V, [ X e ( V ) ] hω e + exp T, (3.4) [ ω ( x ( W + ) ) ω ( x ( V ) )] h + exp kt. (3.5) MM (3.3) µ = 3 9; M + M, 9:.;, ; ω, ω, ω 6; ;,, 33 3 6; ;, 6; 6 V, W; h 33 ; k 33 ;4; α 4 3. +,3 N ( X ) ; 3 ω = 359, = 6.06N0-3, Σ g 3 3 O ( X ) ω = 580, = 7.59 0 3, 3 NO(X ) ω = 904, = 7.39N0 3 Σ g [67], 7 9: 3 4 3 B, [76]: α(n N ) = 3.6, α(o O ) = 8.5, α(no NO) = 3.6, α(n O ) = 30., α(n NO) = 36.4, α(o NO) = 37.8, α(n N) = 33., α(o N) = 4.3, α(no N) = 4., α(n O) = 5., α(o O) = 48.5, α(no O) = 39.5. 3 ; 63 - (00) - 4, (00) - (00)

6..3 6; E(v,v,v 3,), 3,.. E(0,0,0,) 3 9: 7: E( v v v ) = ω v 3 + ω v + x + x 3 [( v [( v + ω v 3 3 + x + 0.5)( v + 0.5)( v 3 v ( v + 0.5) + x + 0.5) 0.5] + x + 0.5) 0.5] v ( v 3 [( v + 0.5) + x + 0.5)( v 3 33 v ( v 3 3 + 0.5) + + 0.5) 0.5] +,3 H O ; 3 ω = 3656.65, = -45.8, = -5.4, ω = 594.78, = -7.04, 3 = -9.99, ω 3 = 3755.79, 33 = - 44.6, 3 = -65.48 [77]. 4 3 67, 8 7 6; 4 <9 α = IP 3.74 ( IP AB M / ), IP AB IP M 4 4 9: 9: α(n H O) = 4.6 Å -, α(o H O) = 3.66 Å -, α( H O) = 3.74 Å -, α(h O O ) = 3.8 Å -, α(h O N ) = 3.37 Å -. (R 0 ) 3 /-,7 (σ). # R 0 ;<3 67 R = σ T, * - 6 * 0.085 0.05 ( T / ) 4; 3 4 3. σ =.5( σ + ), 0 σ T * * * T T =.,3 N : σ=3.789 0-8, *=7.4 K, 3 O : σ=3.467 0-8, *=06.7 K, 3 H O: σ=.64 0-8, *=809. K [78]. 3 N -H O: R 0 =5.3 0-8 T -0.085, *=40.35 K, O -H O: R 0 =5.88 0-8 T -0.085, *=93.8 K, H O-H O: R 0 =4.666 0-8 T -0.085, *=809. K.,3 3 4 8; 3 V T-4 3 V= V=0, 7 9: 6 (; 3 ): NO NO: K 0 = 3.5 0 4 exp(5/t) +.39 0 exp( 58/T) [79], K 0 = 35. 0 T/ 000 exp( 80/T) exp 379. (T/ 000 ) [80], 9 O O : 3 ( )[ ] N N : K 0 = 4.5 0 9 exp(.303t 0.357 ) [7],

NO O: K 0 = 3 0 [76], 63 O O: = 4 K 3 0 5. 7 0 T exp 30 T [74], N : K V, V =.40 0 3 exp( 95/T) [7], 6. N H O: K0 =.5 0 T exp( ) [8], / 3 T 6 / 3 O H O: K =. 0 exp( 57 / ) [8], 0 T 3 / 3 H O(00) H O: K ( T ) = 0.4 T exp( 5.59 8.65 / T / + 930.55/ ) [8], 0 T / 3 / 3 H O(00) N : K = 0.4 T exp( 33.79 8.574 / T + 47.35 / ) [83], 0 T / 3 / 3 H O(00) O : K = 0.4 T exp( 40.06 99. / T + 68.334 / ) [83]. 0 T,3 V T 4 N N <; 33 4, : N N: K 0 D 3.0 0 5 [84]. V T-4 8, 6 [80]. = K 0 3. 6 0 exp 8. 58 T/ 000 3, 6 N O : ( ) O N : = 6. 0 exp. 508( T/ ) 3 K 0 000, O N : = 7 4. 66 0 exp 8. 903( T/ ) 3 K 0 000.,3 6;. 8, ;3 SSH 3 9:9,, (00)- O (00)- O.. 8 67, : 5 / 3 /3 (00)- N : K = 9 0 T exp( 4.35 04.848 / T + 30.607 / ), 0 T 7 / 3 / 3 (00)- : K = 7.85 0 T exp( 6.0 84.099 / T + 60.94/ ), 0 T 3 3 (00)- : K = 4.6 0 T exp( 0.363 396.58 / T / + 5.00 / / ), 0 T 4 / 3 / 3 (00)- N : K = 7 0 T exp( 4.408 0.3 / T + 5.37 / ), 0 T 7 / 3 / 3 (00)- O : K = 9.0 0 T exp( 6.04 98.059 / T + 67.744 / ), 0 T / 3 / 3 (00)- : K =.954 0 T exp( 0.5 439.9 / T + 499.5/ ), 0 T / 3 / 3 (00)- N : K = 0.4 T exp( 33.79 8.574 / T + 47.35 / ), 0 T

/ 3 / 3 (00)- O : K = 0.4 T exp( 40.06 99. / T + 68.334 / ). 64 0 T 4 V V-6 3 7 6; 3 3 <3: 3 0 7 O O : K = 5. 54 T [74], 0 0 0 8 0 0 3 N O : K = 5. 37 T [85], 0 0 0. 4 N N : K 4. 54 0 exp( 3. T ) = [76]. 0 99 0 K 0 V V-6 7 NO 6 8; ; 95 3.4 0-4 3 / [86].,3 6 ; ; 3 84 V V-6 7 N 95. ; 9: 7: 3 0 0 NO O : K =. 4 T. 0 0 6;3 43 NO 6; (NO(V = ) A NO(V = ) + NO(V = 0)), 6 [86] 77 468. 3 8 6 ;3 9 < 3 3 43, 9: V V-6: NO NO: 7 3 0 = 3 + T K 0 7. 0 3. 0 exp. 35 V T-4 V V-6 NO, 3 8;, 7. V T- 4 8 K 0 = S st F at Z V Z tr Z, (3.0) S st = /3 73. 33 4 3, F at = 84./ 373

65 6; 3 6 ; 7 Z V Z : Z V = 4π α ( xe ) M ωe h, (3.) Z 8kT =.998 0 π R0. (3.) πµ %34, 39: 9 ; 3 6; Z tr, 7 9: 6: Z tr Θ Θ Θ Θ = 8 LT LT 6 LT V + exp 3 3. (3.3) π 3 Θ T T T V &3 / % O LT 3 6;3 O V, 9:3 V()AV(0), : 4 ωe xeωe µ Θ LT = π, (3.4) α k ( ω x ω ) h e e e Θ V =. (3.5) k V V-6 3; 9: 6 [75]: 0 K0 = Sst Fat ZV ZV ZtrZ. (3.6) $ S st 8 7 /9. 6; 3 6 ; 7 Z V 7 < Z V Z V ( ω xω ) ( ω xω ) 4MM = α α h 4 8π ω. (3.7) ; 7 393 7, V T- 4. O LT O V ; 9: <3: ( ω x ω x ) 4 ω ω + µ Θ LT = π, (3.8) α k ( ω ω + ( ω x x )) h ω Θ V =. (3.9) k

66 #43 V5 6 6. 6, [86], : 855. V 3094. K T ( V ) = 5. 0 exp.,3 6 4 [87] 6 9: 73: K K 39958-396 V ( V ) K ( V ) + exp exp[. 65. 03 V + 0. 075 V ] = T 0DV<, 485. -93. 4 V ( V ) K ( V ) + exp exp[. 65. 03 V + 0. 075 V ] = DVD0. T,3 4 V-V- 6 N (V=) + (000) I N (V=0) + (00) H O(00)+ (V=0)I O (V=)+ (000) 6 [83] ; 3 ; : K 0 0 / 3 / 3 = exp( 7.658 49.03 T + 37.4 T 88.093 T 0 / K 0 =.39 0 T. K 4 SSH ( T ) = ( πr0 ) ZV VT Ztr ( θv, θlt, ). 9 0 0 T N (V=)+ (000)A N (V=0)+ (00): 0 5 / 3 K0 = 0 T exp( 8.856 98.438 / T 67.456 / T H O(00)+ (V=0) A O (V=)+ (000): 0 8 /3 K0 = 3.3 0 T exp(.75 78.3/ T 77.64 / T 0 8.33 (00)+ (000)A (000)+ (00): K = 5.5 0 T exp(809./ ), (00)+ (000)A (000)+ (00): 0 4 / 3 K 0 =. 0 T exp(.3 87.35 / T + 366.07/ T N (V=)+ (000)I N (V=0)+ (00): 0 4 / 3 K0 =.3 0 T exp(.447 98.48 / T 3.76 / T H O(00)+ (V=0)I O (V=)+ (000): 0 9 / 3 K0 = 8.788 0 T exp(.54 6.538 / T 467.85/ T / 3 ), /3 ), ), 0 T 0 8.33 (00)+ (000)A (000)+ (00): K = 5. 0 T exp(809./ ), (00)+ (000)A (000)+ (00): / 3 ), / 3 ), / 3 ), 0 T

67 0 5 / 3 K 0 =.0 0 T exp(.64 44. / T + 30.93 / T (00)+ (000)A (000)+ (00): 0 5 / 3 K 0 = 5.0 0 T exp( 0.785 84.058 / T + 36.34 / T 0 7.33 (00)+ (000)A (000)+ (00): K =.83 0 T exp(809./ ). / 3 / 3 ), ), 0 T 3 : (00)AhP+ (000) =73.7 c - ; (00)AhP+ (000) =5.6 c -. [88]. 3 3 6; 6; 9 A 3 n +, n = n + ) [ ( e xe ) n / E] [ ( ωe xe ) n / E] ( ω A, ω x e e - 33 ; E = ω ( ω x ) - 83 6; 3 n=, 3 e e e ;,0 3; 3. 4 V5, V53, V54 <3:,0 3 [ 7. 60 ( V )] + ( ) = 7389. 545. 6 V K V 5 V 5. 53 0 exp exp, [89] T T 666 K V 54. [90]. 3 K V 53 =. 05 0 T, = 9 47 0 exp T 4 (V55 V60) K D = R /(5.87D) 3, K h = K D + K γ, D 84 N, O, NO, H O ( 33 ), K γ =V % γ(r), V % 33 3 ;, γ 3; 4, R. 3 γ ; 3;3, 93 3, 7 [9]. 67 ; γ= 0-3., 3 43 : 33 ; 6; ( ) NO( ). 8 8 ; γ ; 3 6;- 67 N 6, 6 6;3 3 8

68 6; 3 7, 8. $4 3 6 (3.) 33 6, 9: 4 6; : m [ V ] + bm [ V ] + Cm[ V + ] d m a =. (3.30) (3.30) ;< 6;. #; <3 3 33 4, 9: 9: 3: 39 36 45 [ NO ( V )] = const, [ O ( V )] = const, [ ( V )] V = 0 V = 0 V = 0 N = const, 3 4 00 00 00 [ H O ( V )] = const, [ H O ( V )] = const, O ( V ) V = 0 V = 0 [ ] V = 0 H = const, [NO(V = 40)] = 0, [O (V = 37)] = 0, [N (V = 46)] = 0, [H O 00 (V = 4)] = 0, [H O 00 (V = 3)] = 0, [H O 00 (V = 3)] = 0.. 3 9, 3 3 6; 3 7 6;, 6 6; 9 9 449 O, N, H O NO., ; 4 3 V = 36 ; V = 37 3 O, V = 39 ; V = 40 3 NO, V = 3 ; V = 4 3 H O(00), V = ; V = 3 3 H O(00), V = ; V = 3 3 H O(00) V = 45 V = 46 3 N 44 6; 8 33.,3 <3 (3.30) ; 49 4 3 7 4. 67 ;4 8 6; 5000, 000, 000 3000 K 3 N, O, NO, H O. 4 : 7 ; < δ=0,00 3 7 6;. ;, 4 ; 673, ;.

69 3.3. %& " " (; 3 6 3 4, 6 9 4 3 3 < ;. # 3 < 6 3 4 67. ; 3 4 3, 8 3 43 4 673 4, 9 49 9:, 7 4 7 3 673. ; #.. 4 8 3 6;, 6;- 67 9 :3, 3 < 3 6; ;4 3 8. ; 49 4. ; < ;4 8 <; 8-6; 33. 67 8 4 3 4 8.. ; < 6;. $ ; < ;4, 3 4 3;, ; 7 ; ; 44 3 δ=0,00 3. 6 3 E/N 6, 449 8. 3 3 4 (, 64 4 6;- 67 ) 6 4 6, 6 ; 9:3 8;. $ ; ; 3 9 6 7 8 9 8;

70 44 ;, 6; 3 3.,3 7 4 6 3 6, 9 ;, 3, 6 4,,, 3 ;<, 4. 8, ; 4, ; 39 6, ; 79 ; 6 3 6. #4, 3 a priori, ; 3 ;, 8 4 ; 79 ;, 4 9. < 3 ;4 3 8 N ( ), O ( ), H O( ), NO( ), (a g ), Ar, ( 3 ) 8-8 3.,3 ( ) 67 X 3 - Σ g V=-4, a, b Σ, A 3 Σ, 449 67 3, 3:3 -, - 3-44, 4, 49 (3 6 [9]); 3 N ( ) 9: 4: 67 3 X Σ + g V=- 8, A 3 Σ + u, B 3 Π g, W 3 u, B 3 Σ - u, a Σ - u, a Π g, w u, C 3 Π u, E 3 Σ + g, b Π u, a Σ + g, b Σ + u, c Σ + u, c Π u, 49 (3 6 [93]); 3 H O(X): 67 ( 6 [94]); 3 NO(X): 67 X Π V=-5, A Σ +, B Π r, b 4 Σ -, B, E Σ +, F, H Σ +, O Σ +, N, O Π, 449 67 8 3,, 49 (3 6 [95]).,3 ( 3 ): 67 3 p 4 D, p 4 S, 3s 5 S 0, 3s 3 S 0, 3p 5 P, 3p 3 P, 3d 5 D 0, 3d 3 D 0, 4s 5 S 0, 4s 3 S 0, 4p 5 P, 4p 3 P, 4d 5 D 0, 4d 3 D 0, 5s 5 S 0, 5s 3 S 0, 43 (3 6 [96]); 3 (a g ): 67 b Σ + g < 7 3 [97, 98], 4 43 [99]; 3 Ar: 3 S, 3 D, 3 D, 3 D 3, D, 3 P 0, P, 3 P, 3 P, S 0, 4 (3 6 [00]). $3 6;- 67 (!) N (X), (X), H (X) NO(X) 7. #.. 9:3 4;3 ;. - ; 8 6; 3 N (X, V) (T V 4000-6000 ),, 6; N (X) 6 ; ;

7. %7 7 ; 7 6; H O(00) (T V 3000-5000 )..; 3 8 8. ; 7 ; <; 3 8 673, ;3;, 6,, 6 [0]. 8 3 693 6 8, 7 ;4 ( - ),,, 6 8 6;- 67,, ; 673 8 3 4; 44 N, H O, 67 6; N (X, V), H O(00) 3, ; < 6;. 8 7 4 44 ; 9 449. 9 3 4 6 3 NO 6; 67 33 N ( ), 4 673 8 N ( 3 Π u, V 4) 3 B 3 Π g (V 3), a Π g (V 5), C 3 Π u (V 5), b Π u (V=0, -4, V 7), 443 N. $; 44 3 3 4; 6; 3 N (, V). $3 673 8 <3.3, 6 3 6 [0, 0]. # 6; O ( ), H O(00), H O(00) NO( ), 3 8 3 6;3 (T V 500 K), 39:3 ; 6;, 8 6. 6 ;, 6 7 6; N (X, V) 7 6 3 ;3, 6 [93], 7 6 N O. 8 4, 3. ", 3 [93], ;4 3 ; N (X, V=0), ; - 8 3 9 3 8 ; 8 8.

7 %64 3.. 4, 39: 4 = 4 /- -, 3 -, 6 - R O (X)+ e O (a ) + e ƒ(e/n) R O (a ) + e O (X) + e ƒ(e/n) R3 O (X)+ e O (b Σ) + e ƒ(e/n) R4 O (X)+ e O (A 3 Σ) + e ƒ(e/n) R5 O (b Σ) + e O (a ) + e ƒ(e/n) R6 O (b Σ) + e O (X) + e ƒ(e/n) R7 O (X) + O (X) + e O + O (X) 0 30 [03] R8 O (a ) + e O + O( 3 P) ƒ(e/n) R9 O (a ) + e O (b Σ) + e ƒ(e/n) R0 O( D) + e O( 3 P) + e ƒ(e/n) R O( S) + e O( 3 P) + e ƒ(e/n) R O (X)+ e O( 3 P) + O( 3 P) + e ƒ(e/n) R3 O (X)+ e O( 3 P) + O( D) + e ƒ(e/n) R4 O( 3 P) + e O( D) + e ƒ(e/n) R5 O( 3 P) + e O( S) + e ƒ(e/n) R6 O 3 + e O( 3 P) + O (X) + e 0(K R +K R3 ) [04] R7 O (X) + e O + O( 3 P) ƒ(e/n) R8 O( D) + O( 3 P) O( 3 P)+ O( 3 P).5 0 [04] R9 O 3 + e O( 3 P) + O 0 9 [04] R0 O + O (a ) O (X)+ e 0 0 [05] R O + O (b Σ) O (X)+ e 3.6 0 0 [06] R O (A 3 Σ) + O( 3 P) O (X)+ O( S).4 0 [07] R3 O + O (a ) O 3 + e 3 0 0 [05] R4 O + O (b Σ) O( 3 P) + O (X)+ e 6.9 0 0 [04] R5 O( 3 P) + O 3 O (a ) + O (X) 0 exp(-80/t) [04] R6 O + O( 3 P) O 3 + e.5 0 0 [05] R7 O (b Σ) + wall O (X) ƒ(γ) R8 O + O( 3 P) O (X)+ e 5 0 0 [08] R9 O (b Σ) + O 3 O( 3 P) + O (X).8 0 [09] R30 O (b Σ) + O (X) O (a ) + O (X) 4.3 0 T.4 exp( 4/T) [0] R3 O (b Σ) + O( 3 P) O (a ) + O( 3 P) 8 0 4 [09]

73 = 4 /- -, 3 -, 6 - R3 O (b Σ) + O( 3 P) O (X)+ O( D) 3.39 0 (300/T) 0. exp( 40/T) [] R33 O (A 3 Σ) + O (X) O (b Σ).93 0 3 [07] R34 O (A 3 Σ) + O( 3 P) O (b Σ) + O( D) 9 0 [07] R35 O( D) + O (X) O( 3 P) + O (b Σ).56 0 exp(67/t) [] R36 O( D) + O (X) O( 3 P) + O (X) 6.4 0 exp(67/t) [] R37 O( S)+ O 3 O( D) + O( 3 P) + O (X).9 0 0 [3] R38 O( S) + O 3 O (X)+ O (X).9 0 0 [3] R39 O( S) + O (a ) O( 3 P) + O (A 3 Σ).3 0 0 [4] R40 O( S) + O( 3 P) O( D) + O( 3 P) 5 0 exp(-30/t) [5] R4 O( 3 P) + wall 0.5O (X) ƒ(γ) R4 O (a ) + O (X) O (X). 0 8 (T/300) 0.8 [0] R43 O( D) + wall 0.5O (X) ƒ(γ) R44 O( S) + O (X) O( 3 P) + O (A 3 Σ) 3.7 0 exp(-850/t) [6] R45 O( S) + O (X) O( D) + O (X).43 0 exp(-850/t) [6] R46 N (X) + e N (A) + e ƒ(e/n) R47 N (X) + e N (B) + e ƒ(e/n) R48 N (X) + e N (a) + e ƒ(e/n) R49 N (&, V) + e N (C) + e ƒ(e/n) R50 N (&, V) + e N( 4 S) + e ƒ(e/n) R5 N( 4 S) + e N( D) + e ƒ(e/n) R5 N( 4 S) + e N( P) + e ƒ(e/n) R53 O( 3 P) + N( P) NO + + e 0 [7] R54 O + N (A) O (X)+ N (X) + e. 0 9 [8] R55 O + N (A) O( 3 P) + N (X) + e. 0 9 [8] R56 O + N( 4 S) NO + e 5 0 0 [9] R57 O + N( 4 S) NO + e.6 0 0 [0] R58 O + NO NO + e.6 0 0 [0] R59 N( 4 S)+ NO N (X,V=) + O( 3 P).05 0 T []

74 = 4 /- -, 3 -, 6 - R60 NO + O 3 O (X)+ NO 4.3 0 - exp(-560/t) [] R6 N (A) + O (X) N (X) + O( 3 P).54 0 [] R6 N (A) + O( 3 P) NO + N( D) 0 [3] R63 N (A) + N (A) N (C) + N (X) 0 [4] R64 N (A) + O (X) N (X) + O (a) 6 0 [] R65 N (A) + N( 4 S) N (X) + N( P) 5 0 [5] R66 N (A) + O( 3 P) N (X) + O( S). 0 [6] R67 N (A) + NO N (X) + NO. 0 0 [7] R68 N (B) + N (X) N (A) + N 5 0 [5] R69 N (B) N (A) + hν.5 0 5 [8] R70 N (B) + NO N (A) + NO.4 0 0 [7] R7 N (B) + O (X) N + O( 3 P) 3 0 0 [5] R7 N (a) + N (X) N (B) + N (X) 0 3 [9] R73 N (a)+o (X) N (X)+O( 3 P)+ O( 3 P).8 0 [9] R74 N (a)+no N (X)+ N( 4 S) + O( 3 P) 3.6 0 0 [9] R75 N (C) N (B) + hν 3 0 7 [8] R76 N (C)+O (X) N (X)+O( 3 P)+O( S) 3 0 0 [5] R77 O (a) + NO O (X)+ NO.5 0 [30] R78 O (b) + N (X) O (a) + N (X) 4.9 0 5 exp(-53/t) [3] R79 O (b) + NO O (a) + NO 4 0 4 [3] R80 O (A) + N (X) O (b) + N (X) 3 0 3 [33] R8 N( D) + O (X) NO + O( 3 P).5 0 T / 300 [7] R8 N( D) + O (X) NO + O( D) 6.0 0 T / 300 [7] R83 N( D) + NO N (X) + O( 3 P) 6 0 [3] R84 N( P) + O (X) NO + O( 3 P).6 0 [34]

75 = 4 /- -, 3 -, 6 - R85 N( P) + NO N (A) + O( 3 P) 3.4 0 [35] R86 O( D) + N (X) O( 3 P) + N (X).8 0 exp(07/t) [36] R87 O( D) + NO N( 4 S) + O (X).7 0 0 [3] R88 O( S) + NO O( 3 P) + NO.8 0 0 [3] R89 O( S) + NO O( D) + NO 3. 0 0 [3] R90 N( 4 S) +wall 0.5N (X) ƒ(γ) R9 NO + e N( 4 S) + O( 3 P) + e ƒ(e/n) R9 O( 3 P)+NO+N (X) NO + N (X) 9.37 0 33 [7] R93 O( 3 P)+N( 4 S)+N (X) NO + N (X).36 0 3 T -0.5 [7] R94 O( 3 P)+NO + O (X) NO + O (X) 9.4 0 33 [7] R95 O( 3 P) + N (X,V) NO + N( 4 S) 9.6 0 [37, 38] R96 N (A) +wall N (X) ƒ(γ) R97 O (b Σ) O (X) + hν 0.085 [8] R98 N (C) + N (X) N (X) + N (X) 5 0 - [5] R99 Ar( 3 D 3 )+ Ar Ar + Ar. 0-0 (T/300) 0.5 [39] R00 Ar( 3 D 3 )+ O (X) Ar + O (X). 0-0 (T/300) 0.5 [39] R0 Ar + e Ar( 3 P M ) + e ƒ(e/n) R0 Ar( 3 P ) hν+ Ar( 3 P M ) 7. 0 6 [8] R03 Ar( 3 P ) hν+ Ar( 3 P M ) 4.4 0 6 [8] R04 Ar( P ) hν+ Ar( 3 P M ) 0.7 0 6 [8] R05 Ar( D ) hν+ Ar( 3 P M ) 7.4 0 6 [8] R06 Ar( 3 D ) hν+ Ar( 3 P M ) 5.4 0 6 [8] R07 Ar( 3 D ) hν+ Ar( 3 P M ) 9.5 0 6 [8] R08 Ar( 3 D 3 ) hν+ Ar( 3 P M ) 35 0 6 [8] R09 Ar( 3 S ) hν+ Ar( 3 P M ) 8 0 6 [8] R0 Ar( P R )+e Ar( 3 P M )+e 3. 0-7 [40]

76 = 4 /- -, 3 -, 6 - R Ar( 3 P M 0 )+e Ar( 3 P M )+e 3. 0-7 [40] R Ar( 3 P R )+e Ar( 3 P M )+e 3. 0-7 [40] R3 Ar( 3 P M )+ Ar( 3 P )+ R4 Ar( 3 P M )+e Ar( 3 P )+ e R5 Ar( 3 P M )+e Ar( P )+ e R6 Ar( 3 P M )+e Ar( D )+ e R7 Ar( 3 P M )+e Ar( 3 D )+e R8 Ar( 3 P M )+e Ar( 3 D )+e R9 Ar( 3 P M )+e Ar( 3 D 3 )+ e R0 Ar( 3 P M )+e Ar( 3 S )+e ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) R Ar( 3 P M )+e Ar( P R )+e.35 0-7 [40] R Ar( 3 P M )+e Ar( 3 P 0 M )+e.35 0-7 [40] R3 Ar( 3 P M )+e Ar( 3 P R ) +e.35 0-7 [40] R4 Ar( 3 P M )+e Ar + +e ƒ(e/n) R5 Ar( 3 P M )+Ar( 3 P M ) Ar + +e. 0-9 [40] R6 Ar( 3 P M )+Ar( 3 P M 0 ) Ar + +e. 0-9 [40] R7 Ar( 3 P M )+Ar( 3 P R ) Ar + +e. 0-9 [40] R8 Ar( 3 P M )+Ar( P R ) Ar + +e. 0-9 [40] R9 Ar( 3 P M )+Ar Ar +Ar 0-3 [40] R30 Ar( 3 P M )+Ar Ar +Ar. 0-5 [4] R3 Ar( 3 P M )+wall Ar ƒ(γ) [4] R3 Ar( 3 P M )+O( 3 P) O(3p 3 P)+Ar.38 0 T [4] R33 Ar( 3 P M )+ AAr( S)+O( D)+O( S).7 0-0 [4] R34 Ar + e Ar( 3 P R ) + e ƒ(e/n) R35 Ar( S 0 ) hν+ Ar( 3 P R ) 0.4 0 6 [8] R36 Ar( 3 P ) hν+ Ar( 3 P R ).9 0 6 [8] R37 Ar( 3 P ) hν+ Ar( 3 P R ) 8.9 0 6 [8] R38 Ar( P ) hν+ Ar( 3 P R ) 0.0 0 6 [8]

77 = 4 /- -, 3 -, 6 - R39 Ar( 3 P 0 ) hν+ Ar( 3 P R ) 44 0 6 [8] R40 Ar( D ) hν+ Ar( 3 P R ) 4.6 0 6 [8] R4 Ar( 3 D ) hν+ Ar( 3 P R ) 6 0 6 [8] R4 Ar( 3 D ) hν+ Ar( 3 P R ) 0 6 [8] R43 Ar( 3 S ) hν+ Ar( 3 P R ) 5.3 0 6 [8] R44 Ar( P R )+e Ar( 3 P R )+e 3. 0-7 [40] R45 Ar( 3 P M 0 )+e Ar( 3 P R )+e 3. 0-7 [40] R46 Ar( 3 P R )+ Ar( S 0 )+ R47 Ar( 3 P R )+e Ar( 3 P )+ e R48 Ar( 3 P R )+e Ar( 3 P )+ e R49 Ar( 3 P R )+e Ar( P )+ e R50 Ar( 3 P R )+e Ar( 3 P 0 )+e R5 Ar( 3 P R )+e Ar( D )+e R5 Ar( 3 P R )+e Ar( 3 D )+ e R53 Ar( 3 P R )+e Ar( 3 D )+e R54 Ar( 3 P R )+e Ar( 3 S )+e ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) R55 Ar( 3 P R )+e Ar( P R )+e.35 0-7 [40] R56 Ar( 3 P R )+e Ar( 3 P 0 M )+e.35 0-7 [40] R57 Ar( 3 P R )+e Ar + +e ƒ(e/n) R58 Ar( 3 P R )+Ar( 3 P M 0 ) Ar + +e. 0-9 [40] R59 Ar( 3 P R )+Ar Ar +Ar. 0-3 [40] R60 Ar( 3 P R ) hν+ Ar 0 8 [8] R6 Ar( 3 P R )+O( 3 P) O(3p 3 P)+Ar.38 0 T [4] R6 Ar( 3 P R )+ AAr( S)+O( D)+O( S).5 0-0 [4] R63 Ar( 3 P R )+ (a )AAr( + S)+.9 0-4 [43] R64 Ar + e Ar( 3 P 0 M ) + e ƒ(e/n) R65 Ar( 3 P ) hν+ Ar( 3 P 0 M ).5 0 6 [8] R66 Ar( P ) hν+ Ar( 3 P 0 M ) 9 0 6 [8]

78 = 4 /- -, 3 -, 6 - R67 Ar( 3 D ) hν+ Ar( 3 P M 0 ).6 0 6 [8] R68 Ar( 3 S ) hν+ Ar( 3 P M 0 ) 0.9 0 6 [8] R69 Ar( P R )+e Ar( 3 P M 0 )+e 3. 0-7 [40] R70 Ar( 3 P M 0 )+ Ar( 3 P )+ R7 Ar( 3 P M 0 )+e Ar( P )+ e R7 Ar( 3 P M 0 )+e Ar( 3 D )+ e R73 Ar( 3 P M 0 )+e Ar( 3 S )+ e ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) R74 Ar( 3 P 0 M )+e Ar( P R )+e.35 0-7 [40] R75 Ar( 3 P 0 M )+e Ar + +e ƒ(e/n) R76 Ar( 3 P M 0 )+Ar( 3 P M 0 ) Ar + +e. 0-9 [40] R77 Ar( 3 P M 0 )+Ar( P R ) Ar + +e. 0-9 [40] R78 Ar( 3 P M 0 )+Ar Ar +Ar 0-3 [40] R79 Ar( 3 P M 0 )+wall Ar ƒ(γ) [4] R80 Ar( 3 P M 0 )+O( 3 P) O(3p 3 P)+Ar.38 0 T [4] R8 Ar( 3 P M 0 )+ AAr( S)+O( D)+O( S).4 0-0 [4] R8 Ar( 3 P M 0 )+ArAAr+Ar 5.7 0-5 [4] R83 Ar + e Ar( P R ) + e ƒ(e/n) R84 Ar( S 0 ) hν+ Ar( P R ) 45 0 6 [8] R85 Ar( 3 P ) hν+ Ar( P R ) 7 0 6 [8] R86 Ar( 3 P ) hν+ Ar( P R ) 3 0 6 [8] R87 Ar( P ) hν+ Ar( P R ) 3 0 6 [8] R88 Ar( D ) hν+ Ar( P R ) 5.3 0 6 [8] R89 Ar( 3 D ) hν+ Ar( P R ) 0 6 [8] R90 Ar( 3 D ) hν+ Ar( P R ).4 0 6 [8] R9 Ar( 3 S ) hν+ Ar( P R ) 0.9 0 6 [8] R9 Ar( P R ) + Ar( S 0 )+ R93 Ar( P R ) + e Ar( 3 P )+ e R94 Ar( P R ) + e Ar( 3 P )+ e ƒ(e/n) ƒ(e/n) ƒ(e/n)

79 = 4 R95 Ar( P R ) + e Ar( P )+ e R96 Ar( P R ) + e Ar( D )+e R97 Ar( P R ) + e Ar( 3 D )+e R98 Ar( P R ) + e Ar( 3 D )+ e R99 Ar( P R ) + e Ar( 3 S )+e R00 Ar( P R ) + e Ar + +e -, 3 -, 6 - ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) /- R0 Ar( P R ) + Ar Ar +Ar. 0-3 [40] R0 Ar( P R ) hν+ Ar 5 0 8 [8] R03 Ar( P R ) + O( 3 P) O(3p 3 P) +Ar.38 0 T [4] R04 Ar( P R )+ AAr( S)+O( D)+O( S) 3. 0-0 [4] R05 Ar( P R ) + (a ) A Ar( + S) +.9 0-4 [44] R06 Ar +e Ar( 3 S ) + e R07 Ar +e Ar( 3 D 3 ) + e R08 Ar +e Ar( 3 D ) + e R09 Ar +e Ar( 3 D ) + e R0 Ar +e Ar( D ) + e R Ar +e Ar( 3 S ) + e R Ar +e Ar( P ) + e R3 Ar +e Ar( 3 P ) + e R4 Ar +e Ar( 3 P ) + e R5 Ar +e Ar( S 0 ) + e R6 O( 3 P) + e O(3s 3 S) + e R7 O(3p 3 P) + O (X) O( S) + O( 3 P) R8 O(3s 3 S) + O (X) O( S) + O( 3 P) R9 O(3s 3 S) + e O(3p 3 P) + e ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) ƒ(e/n) 4.6 0 T [39] 9.8 0 T [39] ƒ(e/n) R0 O(3p 3 P) O(3s 3 S) + hν.8 0 7 [45] R O(3s 3 S) O( 3 P) + hν 6.0 0 8 [45] R O( 3 P) + e O(3p 3 P) + e ƒ(e/n)

80 = 4 R3 O (X)+ e O(3p 3 P) + O( 3 P) + e -, 3 -, 6 - ƒ(e/n) /- R4 O (b) + Ar O (X)+ Ar.5 0-5 [] R5 O (X)+ e O(3s 3 S) + O( 3 P) + e R6 N O + e N (X) + O - ƒ(e/n) ƒ(e/n) R7 O - + N (X) O (X) + N (X)+e.9 0 - (T/300) 0.5 exp(-4990/t) [7] R8 NO + e NO + O - ƒ(e/n) R9 O( 3 P)+O (X) + e O - + O (X) 0-3 [46, 47] R30 O( 3 P)+O (X) + e O( 3 - P) + O 0-3 [7] R3 N( 4 S) + NO N (X) + O (X) 7 0-3 [] R3 N( 4 S)+NO N (X) + O( 3 P) + O( 3 P) 9. 0-3 [] R33 N( 4 S) + NO N O + O( 3 P) 3 0 - [] R34 N( 4 S) + NO NO + NO.3 0 - [] R35 O( 3 P) + NO NO + O (X).3 0 - (T/000) 0.8 [] R36 O( 3 P) + NO 3 O (X)+ NO 0 - [] R37 O (X)+N (X)+e O - + N (X).07 0-3 (300/T e )exp(-70/t) [48, 49] R38 NO + NO 3 NO + NO.79 0 - exp(0/t) [] R39 NO + O 3 O (X)+ NO 3. 0-3 exp(-450/t) [] R40 NO 3 + NO 3 O + NO +NO 5 0 - exp(-3000/t) [] R4 NO + NO 3 NO+NO +O (X).3 0-3 exp(-600/t) [] R4 O - + O (X) O (X) + O (X) + e.7 0-0 (T/300) 0.5 exp(-5590/t) [7] R43 O( 3 P) + NO +M NO 3 + M 8.08 0-33 (000/T) [] R44 N (A) + O (X) N O + O( 3 P) 7.8 0-4 [] R45 O( D) + N O NO + NO 7. 0 - [36] R46 O( D) + N O N (X) + O (X) 4.4 0 - [36] R47 O 3 + e O - + O 0 - [50] R48 O - + O (X) O 3 + e 5 0-5 [46,

8 = 4 47] /- -, 3 -, 6 - R49 N(4S) + O (X) NO(X)+O (X). 0-4 Texp(-350/T) [] R50 H O + e H + OH + e ƒ(e/n) R5 OH + OH H O.5 0 - T -0.4 [5] R5 OH + OH + O (X) H O + O (X) 6.5 0-3 (300/T) -0.7 [5] R53 OH + OH + H O H O + H O.5 0-3 (/T) exp(/t) [53] R54 OH + OH H O + O( 3 P).9 0-0 T.6 exp(945/t) [54] R55 OH + O 3 HO + O (X).9 0 - exp(-000/t) [5] R56 OH + H + O (X) H O + O (X) 6.9 0-3 T - [53] R57 OH + H + H O H O + H O 4.4 0-3 T - [53] R58 OH + H H O.7 0-4 [55] R59 OH + H H + O( 3 P).38 0-4 Texp(-3500/T) [54] R60 OH + O( 3 P) O (X)+ H.0 0 - exp(/t) [54] R6 OH + H H O + H 7.69 0 - exp(-000/t) [54] R6 OH + HO H O + O (X) 4.8 0 - exp(50/t) [54] R63 OH + H O H O + HO.9 0 - exp(-60/t) [54] R64 H + H + M H + M.7 0-3 T -0.6 [54] R65 H + H O OH + H 7.6 0-6 T.6 exp(-98/t) [54] R66 H + HO H + O (X) 7. 0 - exp(-70/t) [54] R67 H + HO OH + OH.8 0-0 exp(-440./t) [54] R68 H + HO H O + O( 3 P) 5 0 - exp(-866/t) [54] R69 H + H O H O + OH.69 0 - exp(-780/t) [54] R70 H + H O HO + H.8 0 - exp(-890/t) [54] R7 H + O 3 OH + O (X). 0-0 exp(-480/t) [5] R7 H + O 3 HO + O( 3 P) 0-0 exp(-480/t) [5] R73 H + O (X) O + OH 3.7 0 - exp(-8450/t) [5] R74 H + O (X)+ O (X) HO + O (X) 5.9 0-3 (300/T) [5] R75 O( 3 P)+O( 3 P)+O (X) O (X)+ O (X).3 0-3 (300/T)exp(-70/T) [56]

8 = 4 /- -, 3 -, 6 - R76 O( 3 P) + O (X)+ H O O 3 + H O 9.9 0-34 exp(50/t) [5] R77 O( 3 P) + O (X)+ O (X) O 3 + O (X) 6.4 0-35 exp(663/t) [56] R78 O( 3 P) + O 3 O (X)+ O (X).8 0 - exp(-300/t) [56] R79 O( 3 P) + H OH + H 3.44 0-3 (T/98).67 exp(-36/t) [54] R80 O( 3 P) + H O OH + OH 0 - exp(-550/t) [5] R8 O( 3 P) + HO OH + O (X).9 0 - exp(00/t) [54] R8 O( 3 P) + H O OH + HO.4 0 - exp(-000/t) [54] R83 O 3 + O (X) O( 3 P)+ O (X)+ O (X) 7.6 0-0 exp(-400/t) [56] R84 HO + O 3 OH + O (X)+ O (X).4 0-4 exp(-600/t) [5] R85 HO + H O H O + OH 4.7 0 - exp(-6500/t) [5] R86 HO + HO H O + O (X). 0-3 exp(600/t) [54] R87 HO +HO +O (X) H O + O (X).9 0-33 exp(-8/t) [53] R88 H O +N (X) N (X)+OH +OH R89 H O OH + OH R90 H O +O (X) HO + HO R9 O 3 + N (X) N (X)+O (X)+O( 3 P) R9 O 3 O (X) + O( 3 P) R93 H( S) + wall 0.5H (X).55 0-8 exp(-80/t) 3.0 0-4 exp(-4430/t) 9.0 0-8 exp(-9976/t) 9.6 0-8 exp(-60/t) 7.6 0-8 exp(-70/t) ƒ(γ) R94 O (a) + H O O (X)+ H O 3 0-8 [0] R95 O (b) + H O O (X)+ H O 6.7 0 - [0] R96 O( D) + H O OH + OH.8 0-0 [36] R97 O( D) + H O H O + O( 3 P).8 0-0 [36] R98 O( D) + H O H + O (X).3 0 - [36] R99 NO+OH +O (X) HNO +O (X) 7 0-3 (T/98) -.6 [57] R300 NO+OH +N (X) HNO +O (X) 7 0-3 (T/98) -.6 [57] R30 HNO + OH NO + H O 6.4 0 - (T/98)exp(-68.5/T) [58] R30 NO + O NO + O 3.4 0 - exp(70/t) [33] R303 NO + OH + N (X) HNO 3 + N.6 0-30 (T/98) -.9 [59]

83 = 4 /- -, 3 -, 6 - R304 NO +O +N (X) HNO 3 +N +O( 3 P).8 0-3 (T/98) -3. [33] R305 NO + OH NO + O 3.0 0 - exp(-336/t) [58] R306 O( D) + NO O (X) + NO 3 0-0 [60] R307 NO + H( S) NO + O 4 0-0 exp(-34/t) [6] R308 NO + H( S) HNO.44 0-0 (T/98) -0.4 [58] R309 NO+H( S)+N (X) HNO+N (X).34 0-3 (T/98) -.3 exp(-37/t) [58] R30 NO+H( S)+O (X) HNO+O (X).34 0-3 (T/98) -.3 exp(-37/t) [58] R3 NO + H( S) +H O HNO+H O.34 0-3 (T/98) -.3 exp(-37/t) [58] R3 HNO + O( 3 P) O + NO 5.99 0 - [58] R33 HNO + O( 3 P) ( S) + NO 4.63 0-8 [58] R34 N( 4 S) + O 3 NO +O (X) 0-6 [] R35 N( 4 S)+N( 4 S)+M N (A)+M 8.7 0-34 exp(500/t) [] R36 O( 3 P)+O( 3 P)+N (X) O (X)+N (X).76 0-34 exp(70/t) [] R37 O( 3 P)+O (X)+N (X) O 3 +N (X) 6. 0-34 (300/T) [] R38 N (A)+N O N (X)+N( 4 S)+NO 0 - [6, 63] R39 N (A)+N (X) N (X)+N (X) 3 0-8 [64] R30 O (a)+o 3 O (X)+O (X)+O( 3 P) 9.7 0-3 exp(-564/t) [65] R3 O( D) + O 3 O (X) + O( 3 P)+O( 3 P). 0-0 [65] R3 O 3 + e O - + O (X) 0 - [48] R33 O + HNO 3 O + NO 3 8.3 0-5 exp(85/t) [66]

84 4.! $ 4.. ) 6; 3 3 6 6 3:3 6. 3 (O, N, Ar, Ar+% N, ) 6993 3 9: 3 6:, 7; 6,, (. 4.). $ ;, 3 6 3 69 3, 6; 3 33 3.,3 78 3 3, 3: ; (6-3) 7 3, 9: 6 9 3. 43 3 ; 7 4 3, 69 3. $ 7 3 ; 3 ;<3. 7 p ~ 500 ; 67 93. O 98%Ar+%N N Ar #. 4.. 6 3, 3: 69:. -, 7; 6; 3 3.!78 3 0, 3 40., 760.

#. 4.. 3 7 3 760 76. #. 4.3. 3 7 3 760 76.

86 #. 4.4. 3 98%Ar+%N 7 3 760 76. #. 4.5. 3 7 3 76 760.