0 5958 (9) (Achillea millefolium L.) * * souri97@gmail.com : : 90 : 9 : 9 Achillea millefolium L. (Asteraceae). 0 9 7. 90. (GC) (GC/MS). % % % % % %5 %. 5 8 8 5 7 (%/7/) 8 (%7/78/5) D (%/7) (%8) (%/6/) (%/69/). 8 8. : (Achillea millefolium L.).D 8.... 8.(Yavari et al., 00) DOI: http://dx.doi.org/0.09/ijmapr.0.98
... 50 Talwar & ) (Trumbeckaite et al., 0 (Bozin et al., 008 Srivastava, 006 Talwar & ).(Srivastava, 006 090.. //5...(Rehus & Neugebauerova, 0) (Tricolporate).. (Colpus) Azani et ).(al., 009 0 8....(Bimbiraitė et al., 008)..(Bimbiraitė et al., 008) (00) Azizi (00) Azizi. 8. %6 8 750. 60. (Achillea) (Azizi et al., 00) 00 Kiumarsi et ).(al., 009. 9..(Azani et al., 009).(Calmasur et al., 006) Kiumarsi et ) (Ethnopharmacology) (al., 009 Rehus & ).(Neugebauerova, 0 Rehus & ).(Neugebauerova, 0 (Karaalp et al., 009).. Trumbeckaite et al., ).(0. Bozin et al., 008)
0 5. (Cissabinene hydrate).. 8.(Azizi et al., 00) 9 5 %5 (v/w) %0/069 (v/w). 8..(Gudaityte & Venskutonis, 007) %9 (v/w) 0 ) Gudaityte &.(Venskutonis, 007 D.(Rohloff, 00) % (v/w).(zheljazkov & Astatkie, 0). D (Guaiazulene).(Suleimenov et al., 00) Suleimenov (00) %9/) (. 8. Jaimand (999). SPMEGC/MS 8 D. Paduch (008). 8.... Achillea millefolium L. 90 ) ( ) ( ) ( ) ( ) (
5... ).(. (m) ( C) (mm) 8 09 E 5 / 6/ 5 5 E 5 7/6 75 5 50 E 5 7/6 8 57 N 7 E 5 /7 9/ 6 E 5 /6 6/8 06 5 E 5 5/9 8/6 557 0 8 E 5 /6 6/8.. ) Sefidkon &.(RahimiBidgoly, 00. 0 ) British pharmacopoeia,.(988.. (GC) Varian CP800 0 5 5 VF5. 60 50. 50 0. 50 80. FID ) (. (GC/MS) CP800GC 000. /5 70 5 00. (C6C)
0 5...(Shibamoto, 987) A. millefolium L. (%) (%). 8 7 5 5 8 ).( %9/8 %9/ %97/ %9/ %96/ %9/5 %9/6. A. millefolium L. : 8 (%6/) (%9/) (%7/09) D (%6/6) (%/) (%/) (%8/0) 8 (%7/7) (%/) 8 (%5/) (%6/5) (%6/) (%5/8) 8 (%5/) (%6/) D (%5/) (%/6) (%9/) (%8/5) 8 (%7/7) 8 (%8/5) D (%) (%0/0) (%6/) (%) 8 (%/6) (%6/9) (%5/9) ).( %/7 %. 7 (CisCadinen7ol) (%/8) (Zvalerenyl acetate) (%) (%/). (Transcarvyl acetate) (%8) (Methylchavicol) (%). (Cischrysanthenol) (%).
5... RI αthujene 96 0/07 αpinene 96 9/ /8 6/ 9/ /6 6/9 camphene 95,(0)thujadien 956 5 sabinene 975 /8 / / 6 βpinene 98 6/ /9 / /7 / 7 dehydro,8cineole 99 8 αterpinene 00 9 ortho, cymene 08 0/7 / 0,8Cineole 08 6/ 7/7 5/ 5/ 7/7 8/5 /6 artemisia ketone 059 /7 gammaterpinene 06 cissabinene hydrate 07 artemisia alcohol 08 / 5 linalool 0 6 transsabinene hydrate 06 7 cispmenthenol /0 0/7 8 αcampholene aldehyde 9 cissabinole 7 / / 0 transverbenol 5 / / 8/5 camphor 5 0/7 / cischrysanthenol 59 Pinocarvone 70 6/ 5/ / /8 / borneol 80 6/5 /6 /6 / 5 terpineneol 87 / / 6 αterpineol 0 / / /5 / / / 7 myrtenol 0 / 8 methyl chavicol 0 9 verbenol 7 0 isogeraniol cischrysanthenyl acetate 58 / / / /7 neryl formate 8 /7 /8 / 5/9 /6 bornyl acetate 8 0/7 thymol 9 0/09 5 transcarvyl acetate 6 eugenol 55 0/7 7 αcopaene 78 0/07
0 55 RI 8 transcaryophyllene 5 /7 /8 /8 /8 6/ / 9 allo aromadendrene 6 /5 / / /5 /8 0 βchamigrene 77 / αamorphene 80 0/08 0/06 Germacrene D 87 6/6 5/ /8 5/ 7/ /7 bicyclogermacrene 500 cisalphabisabolene 5 5 γcadinene 58 6 δcadinene 5 7 Zvalerenyl acetate 56 8 βvetivenene 55 9 elemol 559 50 transnerolidol 57 / / 6/ / /9 /9 /6 5 spathulenol 59 / /5 /6 / 5 caryophyllene oxide 599 / /7 /5 /5 0 /9 5 guaiol 6 / 5 hinesol 67 55 ciscadinen7ol 67 /8 56 δcadinol 69 7 / / 5/8 /6 /7 57 βeudesmol 65 / / 58 αeudesmol 668 /8 8 6/ 5/5 /0 / 5/9 59 Khusinol 689 /0 /6 / / /9 60 β sinensa 69 /5 5/6 /8 /0 6 (Z,E)farnesol 70 6 (E,E)farnesol 75 6 chamazulen 70 /7 (%) 8/8 8/ 7/97 /6 7/ / (%) 9/ / /5 5/6 6/5 / /9 (%) /7 8 7/6 8 5/ / 7/8 (%) / 58/ 6/8 / / 8/9 (%) 96/ 97/ 9/6 9/8 9/ 9/5 9 SAS () () () () ().
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Iranian Journal of Medicinal and Aromatic Plants, Vol. 0, No., 0 58 Chemical composition of Achillea millefolium L. essential oil from different regions of Eest Azerbaijan province M. Ghanbari and M.K. Souri * MSc. Student, Department of Horticultural Sciences, Faculty of Agriculture, Tarbiat Modares University, Tehran, Iran * Corresponding author, Department of Horticultural Sciences, Faculty of Agriculture, Tarbiat Modares University, Tehran, Iran, Email: Souri97@gmail.com Received: January 0 Revised: January 0 Accepted: February 0 Abstract Genus Achillea millefolium L. (Asteraceae) consists of about 00 species. Nineteen species grow naturally in Iran of which seven are endemic. In this study, chemical composition of the essential oils of seven Achillea populations growing wild in northwest Iran, during the flowering period were investigated. The aerial parts were collected from Zonoz, Basmenj, Pirbala, Bonab, Shabestar, Kondlaj and Jolfa regions from Eest Azerbaijan province in May and June 0. The essential oils were obtained by hydrodistillation method and analyzed by combination of GCFID and GCMS. Mean essential oil yield was calculate to be 0.%, 0.%, 0.%,0.%, 0.%, 0.5% and 0.% (w/w) for Zonoz, Basmenj, Pirbala, Bonab, Shabestar, Kondlaj and Jolfa, respectively. Overall, 5, 8, 8,, 5, 7 and compounds were identified from Zonoz, Basmenj, Pirbala, Bonab, Shabestar, Kondlaj and Jolfa, respectively. The main constituents of the oils were δcadinol (..7%),,8cineole (8.57.7%), transnerolidole (.6.%), germacrene D (.70.9%), alphapinene (.069.%), borneole (0.0 6.5%) and pinocarvone (.86.%). According to the obtained results, Basmenj and Zonoz are recommended as two suitable regions for the extraction of,8cineol and δcadinol. Key words: Achillea millefolium L., essential oil, δcadinol,,8cineole, germacrene D.