Supplementary Materials: Risk Assessment for Children Exposed to Beach Sands Impacted by Oil Spill Chemicals

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1 S1 of S5 Supplementary Materials: Risk Assessment for Children Exposed to Beach Sands Impacted by Oil Spill Chemicals Jennifer C. Black, Jennifer N. Welday, Brian Buckley, Alesia Ferguson, Patrick L. Gurian, Kristina D. Mena, Ill Yang, Elizabeth McCandlish and Helena M. Solo-Gabriele Table S1. Non-target tentatively identified compounds in beach sands and tar collected from Grand Isle beaches. Order of chemicals in terms of highest levels to lowest Toluene Oxime-, methoxy-phenyl Benzene, 2,4-diisocyanato-1-methyl Methyl-1-(o-methylphenyl)-1-silacyclobutane Pentadecane Hepten-3-one, 5-methyl Indane H-Benzimidazol-2-one, 1,3-dihydro-5-methyl Oxirane, [[(2-ethylhexyl)oxy]methyl] b,8-Dimethyl-2-isopropylphenanthrene, 4b,5,6,7,8,8a,9,10-octahydro n-hexane Decane, 2,3,5,8-tetramethyl Hexadecane p-xylene ,5-Cyclohexadiene-1,4-dione, 2,6-bis(1,1-dimethylethyl) ,4-Dihydroxy-5-methoxybenzaldehyde Ethylbenzene Benzene, 1,2,3,4-tetramethyl Hexanal, 3,3-dimethyl Ethanol, 2-[2-(2-ethoxyethoxy)ethoxy] Pentanol, 3-ethyl Heptanone, 3-methyl Phenol, 2,4-bis(1,1-dimethylethyl) Mesitylene ,6-Difluoro-3-methylbenzamide, N-(1-naphthyl)

2 S2 of S5 CAS Number Propan-2-ol, 1-(2-isopropyl-5-methylcyclohexyloxy)-3-(4-morpholyl) Benzene, 1,3-dimethyl m-xylene Octane, 2,2-dimethyl ,4,6-Cycloheptatrien-1-one, 2-hydroxy-5-(3-methyl-2-butenyl)-4-(1-methylethenyl) Methyl-2-(2-methyl-2-tetrahydrofuryl)tetrahydrofuran alfa.,21.beta.-28,30-Bisnorhopane Phosphonous dichloride, (1,7,7-trimethylbicyclo[2.2.1]hept-2-yl) Indole-2-one, 2,3-dihydro-6-amino Methylpyrazolo[bis(9-borabicyclo[3.3.1]nona-9-yl)thio]oxide Benzene, 1,4-dihexadecyl Hexadecane, 1,1-bis(dodecyloxy) ,3-Heptadien-5-yne, 2,4-dimethyl Undecane Octanol, 2,6-dimethyl Octadecanoic acid, tert-butyldimethylsilyl ester Benzene, 1-(1,1-dimethylethyl)-3-ethyl Hexane, 2,2,3-trimethyl Eicosene, (E) Benzoyl chloride Butanone, 2-chloro-3-methyl-1-phenyl Benzene, 1,2,3,5-tetramethyl Benzamide, N-(3-methylthio-1,2,4-thiadiazol-5-yl) p-cymene ,2 -Isopropylidenebis(5-methylfuran) Biphenyl Ethanone, 1-(3-methylphenyl) Decanone Octatetracontane, 1-iodo Heptane, 4-(1-methylethyl) Decanol Hexadecanoic acid, methyl ester

3 S3 of S5 1-Adamantanecarboxylic acid, 2-tetrahydrofurylmethyl ester Naphthalene tert-butyl isopropyl carbonate o-fluoroacetophenone S-2,3,8,8-Tetramethyltricyclo[ (1,6)]undec-2-ene Borinic acid, diethyl Decanone, 5,9-dimethyl H-Pyrazolo[3,4-b]pyridin-3(2H)-one, 6-hydroxy-4-methyl-2-phenyl Bicyclo[3.1.1]hept-2-ene, 2, 6-dimethyl-6-(4-methyl-3- pentenyl) Verapamil ,2,6,7-Tetramethyl-10-oxatricyclo[ (1,7)]decan-one ,6-Dimethyl-4-octanone Octanone Benzene, 1-ethyl-3-methyl H-Pyrano[2,3-e]benzothiophen-8-one, 4-formamido-6-methyl Pyrimidin-5-amine, 2-(4-butoxyphenyl) H-Indene, 2,3-dihydro-1,1,3-trimethyl-3-phenyl Methylisoborneol Isopropylbenzene Chloro-N,N-dimethyl-6-phenyl-11H-indolo[3,2-c] quinoline-11-ethanamine, 5-oxide Phenanthrene Benzaldehyde, 4-(1-methylethyl) Cyclopropanedodecanoic acid, 2-octyl-, methyl ester Benzene, pentamethyl Hepten-3-yn-2-ol, 6-methyl-5-(1-methylethyl) /7/3983 Cyclohexene,1-(2-methylpropyl) H-Indene, 1-ethylidene Sulfurous acid, octyl 2-pentyl ester Hydroxylamine, O-decyl Heptadecanol Benzo[b][1,8]-naphthyridin-5(10H)-one, 2,4,7-trimethyl tert-Butyl-2-pyrazolin-5-one

4 S4 of S Methylnaphthalene Naphthalenol,6,7-epoxy-5,6,7,8-tetrahydro-5-isopropyl- 3-methyl-8-methylene Furan, 2-pentyl Cyclohexane, (ethoxymethoxy) Phorone Ethanol, 2-(1,1-dimethylethoxy) Tetrahydroionone o-xylene Isopropylbenzene Propanone, 2-chloro-1-(2,4-dimethylphenyl)-2-methyl (1-Cyclopentenyl)furan Cyclohexanone, 2,2,6-trimethyl Naphthalene, 1,2,3,4-tetrahydro-1,1,6-trimethyl (3H)-Furanone, 5-(acetyloxy)dihydro-5-methyl Heptanone, 6-methyl α-l-fucopyranose 1,2:3,4-bis(benzeneboronate) Ethyl-2-pentadecanone [(Z)-1-Butenyl]-1,4-cycloheptadiene Ethanone, 1-(2,4-dimethylphenyl) Dodecanol (3H)-Furanone, dihydro-4,4,5,5-tetramethyl Tridecanoic acid, 12-methyl-, methyl ester Methyldodecanol Phthalic acid, bis(7-methyloctyl) ester Anthracene ,3-Dichlorobenzene Benzene, 1-[2-(2-chloroethoxy)ethoxy]-4-(1,1,3,3-tetramethylbutyl) Butanedioic acid, ethyl methyl ester (1,2,3-Trimethyl-cyclopent-2-enyl)-ethanone Naphthalene, 2,3,6-trimethyl Hepten-2-one Butyric acid, 6-(4-cyano-phenyl)-naphthalen-2-yl ester

5 S5 of S Benzaldehyde, 4-(1-methylethyl) Benzoic acid, 4-(1-methylethyl)-, methyl ester Benzocyclododecene, 2,3-diethyl-4a,5,6,7,8,9,10,11,12,13-decahydro ,2-Dimethyl-1-(2,4,6-trimethylphenyl)propan-1-one Cannabidiol Hexacosene Hydroxy-7-oxodehydroabietic acid, methyl ester Penten-3-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl) Benzene, 1,4-dichloro Naphthalene, 2,3,6-trimethyl m-cymene, 5-tert-butyl Caranol, trans,trans-(+) Androst-5-en-3-ol-17-one, 16,16-trimethylenedithio Benzenesulfonohydrazide, N -tricyclo[ (1,5)dec-8-ylidene] Nonanone Tricyclo[ (3,8)]undecane, 1-methoxy Hydroxylamine, O-decyl Hexadecane Methylene-1-phenyl-3,6-diazahomoadaman Sum (ng/g) by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (