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1 6 37 1,2 1,, , (11, ; 21, ) : : ;; ; % [1 ] 80 % 1986, [2, Dioxin ], [3 ], [4,, ] 85 %,15 1 [5 ] : : : ; : ( ),, 3

2 , 2. 1,,, [6 ] [7,8 ] Leoutid [9 ] PET Wang [10 ] [11 ] Peters HDPE 8 % [12 HDPE UL94 V20 ],LDPE 70 %ATH( ) 24, 8 % 27 ATH [13,14 30 ] (UHMWPE), (LOI) 10 %LOI,UL94 V Narihiro [15 ],EVOH 5 % (APP), APP,APP 15 %,UL294 V - 0 Hymont SPINFLAM MF82 Clariant EXPLOITAP [16 ] Riva [17 ] EVA, min APP 5min, Bourbigot [18 ] PPΠAPPΠ ( EPR) 015 %1 %, LOI 5 7 Bourbigot [19 ] APPΠEVA, - 6Π EVA Zilbermanl [20 ] :EVA,APP Al (OH) 3, Hooker 3. 1 ( EP),

3 6 39,,, [21 ] A LOI 1915, [22,23 ] ( 1), DGEBAΠDDS [22,LOI 32 ] Toldy [23 ] LOI 1ΠFigure 1 2 Liu [24 ] 2, BGPPO,BGPPO 4,42 (DDM) 4,42 (DDS) DICY DDM > DICY > DDS,LOI BGPPO 2ΠFigune 2 Liu [25 ] Epon828 Eponex, Epon828 Eponex 18 %35 % DGEBA DDM, DICY DDS, P = O, BGPPO 10 %, 45 %,LOI 51, DOPO,

4 DOPO, 3, [26 ] DOPO Wang [27 ] DOPO DDS DICY, :DICY> DDS > TGA 2A,, 1103 %,UL - 94 V20 Lin [28 ] DOPO DOPOMA ( 3 ) DOPOITA ( 3 ), DGEBA DGEBA2DOPOMA DGEBA2DOPOITA :DOPOBQ (3 ) > DOPOITA > DOPOMA 018 %,UL294 V21 ; 111 %,UL294 V20 3ΠFigune 3 Liu [29 ] DOPO 4 - DOPO2PN, DSC TGA, DOPO2PN DOPO2PNΠCNE200 (O2cresol Novolac epoxy) LOI LOI 2 %,DOPO2PN LOI 26, UL94 V20 312,PP PE PS PMMA ( 4) Lancaster Ebdon [30 ] (St) (MMA), LOI, :,LOI Gentilhomme [31 ] CH 2 = C ( CH 3 ) C (O) OCH ( R) P (O) (OC 2 H 5 ) 2 MMA, R = H C 6 H 4 B r C 10 H 7

5 6 41 4ΠFigune 4, PMMA Banks [32 ] CH 2 = CH P(O) (OC 2 H 5 ) 2 St MMA (AN) (AM) TGA LOI, LOI, TGA, AM AN, 2 Abdel2Mohdy [33] CH 2 = C(CH 3 ) C(O) OCH 2 CH 2 O P(O) [ (NC 2 H 5 ) 2 ] 2, 40 % [34 ] PP, NH 2 P N,, PP LOI 3. 3 Matsunage [35 ] TPA EG PPA PET2co2PPA Asrar Mo [36 ] TPA EG22 CEPP PET2co2CEPP Zhao [37 ] TPA EG DDP PET2co2DDP, Ea :PET2co2DDP < PET < PET2co2CEPP Chen2Yang [38 ] N 3 P 3 [OC 6 H 4 OP (O) (OC 2 H 5 ) 2 ] 3 [OC 6 H 4 OH] 3 ( EPPI),, EPPI LOI EPPI Funda [39 ] 2 (NH 2 C 6 H 4 O) 2 P(O) C 6 H 5 ) (BAPPO) BAPPO,LOI 27 4, [40 ] : (1) ; (2) ; (3) ;

6 : [ 1 ] Irvine D J,Mccluskey J A,Robinson I M. Polym Degrad and Stab, 2000, 61 : [ 2 ] Hietaniemi J,Kallonen R,Mikkola E. Fire Mater,1999,23 (4) : [ 3 ] Poortere M De,Schonbach C,Simonson M. Fire Mater,2000,24(1) :5360. [ 4 ] Hsiue G H,Shiao S J,Wei H F,et al. J Appl Polym Sci, 2001,79 : [ 5 ] Wilki C V. J Vinyl Additive Tech, 1999, 5 (4) : [ 6 ]., 1991,5 (2) :1215. [ 7 ],.,1994,3 :410. [ 8 ].,1997,3 :13. [ 9 ] Laoutid F, Ferry L, LopezCuesta J M,et al. Polym Degrad and Stab, 2003,82 : [10 ] Wang Z Z,Wu G S,Hu Y,et al. Polym Degrad and Stab,2002, 77 : [11 ] Peters E N. J Appl Polym Sci,1979,24 : [12 ],.,1992,5 : [13 ],., 2001,29(4) :4-6. [14 ],., 1995,1 :29. [15 ] Narihiro M,Hiroaki S,Keisuke T,et al. Polym Degrad and Stab, 2003, 79 :1320. [16 ] Edward W D., 2000,1 :1319. [17 ] Riva A,Camino G,Fomperie L,et al. Polym Degrad and Stab, 2003, 82 : [18 ] Bourbigot S,Bras M L,Delobel R. J Chem Soc Trans, 1996,92 (8) : [19 ] Bourbigot S,Bras M L,Dabrowski F,et al. Fire Mater, 2000, 24 : [20 ] Zibermanl J,Hull T R,Pricel D,et al. Fire Mater, 2000, 24 : [21 ] Hamerton I. Recent developments in epoxy resins. Rapara review report 91,Shrewbury :Rapra Technology Ltd ;1996. [22 ] Derouet D,Morvan F,Brosse J C. J Appl Polym Sci,1996,62 (11) : [23 ] Toldy A,Anna P,Marosi Gy,et al. Polym Degrad and Stab, 2003,82 : [24 ] Liu YL,Hsiue G H,Chiu YS,et al. J Appl Polym Sci,1996,61 (4) : [25 ] Liu YL,Hsiue G H,Lee R H,et al J Appl Polym Sci,1996,61 (4) : [26 ],., 2002,17(1) : [27 ] Wang C S,Shieh J Y. J Appl Polym Sci,1999,73(3) : [28 ] Lin C H,Wu C Y,Wang C S. J Appl Polym Sci,2000,78 (1) : [29 ] Liu YL. Polymer, 2001,42 : [30 ] Ebdon J R,Price D,Hunt B J,et al. Polym Degrad and Stab,2000, 69 : [31 ] Gentilhomme A,Cochez M,Ferriol M,et al. Polym Degrad and Stab, 2003, 82 : [32 ] Banks M,Ebdon J R,Jhonson M. Polymer, 1994,35 (16) : [33 ] AbdelMohdy F A. J Appl Polym Sci,2003,89 : [34 ],,,., 2001,29(5) :3640. [35 ] Matsunaga S. JP ,1984. [36 ] Asrar J,Mo C. USP 5,399,428,1995. [37 ] Zhao H,Wang Y Z,Wang D Y,et al. Polym Degrad and Stab, 2003, 80 : [38 ] Chen2Yang Y W,Yuan C Y,Li C H,et al. J Appl Polym Sci,2003,90 : [39 ] Funda C,Osman P,Leyla A,et al. J Appl Polym Sci,2004,91 : [40 ],,.,1998,5 :2428. ( 83 )

7 6 83 [13 ] Karas M, Bahr U, Giessmann U. Mass Spectrom Rev, 1992, 10, 335. [14 ] Chan K P, Wang Y F, Hay A S. Macromolecules, 1995, 28, 653. [15 ] Hillenkamp F, Karas M, Beavis R C, et al. Anal Chem, 1991, 63, [16 ],,,., 1999, 27 (7), 749. [17 ] Qi Y H, Chen T L, Jiang H Y, et al. Macromol Chem Phys, 1999, 20, [18 ] Nordgiff E, Kirpekar F, Roepstorff P. Mass Spectrom Rev, 1996, 15, 67. [19 ] Little D P, Aaserud D J, Valaskovic G A, et al. J Am Chem Soc, 1996, 118, [20 ] Dole M, Mach L L, Hines F L, et al. J Chem Phys, 1968, 49, [21 ] Teer D, Dole M. J Polym Sci, 1975, 13, 985. [22 ] Hodge P, Colquhoun H M, Williams D J. Chem Indus,1998, 2, 162. [23 ] Wang H H, Ding J Y, Chen T L. Chin Chem Lett, 2004,15 (11),1377. [24 ],,,., 2004, 62 (14),1344. [25 ],.,,2001,92. Structure Characterization of Aromatic Cyclic Oligomers WANG Hong2hua, CHEN Tian2lu 3 (1 State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun , China ; 2 Graduate School of the Chinese Academy of Sciences, Beijing , China) Abstract: Structure characterization of aromatic cyclic oligomers including its developing process and latest progress is reviewed in this article. HPLC, FAB2MS ( FIB2MS), MALDI2TOF2MS, ESI2MS combined with other assistant methods are introduced respectively. Characteristics and application range of each kind of characterization method are compared. Key words :Aromatic cyclic oligomers ; Characterization ; HPLC ; FAB2MS ( FIB2MS) ; MALDI2TOF2MS ; ESI2 MS ( 42 ) Some Aspects of Preparation and Application of Halogen2Free Flame Retardant Polymers Containing Phosphorus WU Yu2liang 1,2,WANG Chang2an 1,2,XU Kai 1,CHEN Ming2cai 1 (11 Guangzhou Institute of Chemistry, The Chinese Academy of Science, Guangzhou , China ; 21 Graduate School of the Chinese Academy of Sciences, Beijing , China) Abstract :An overview of recent developments of halogen2free flame retardant polymers containing phosphorus is presented in this paper. Two approaches to the achievement of flame retardancy in polymers were generally known as the additive2 type and the reactive2type. Some aspects of these polymer systems such as synthesis, structure, property and applications are discussed here in. Key words : Phosphorus ; Halogen2free ; Flame retardant ; Polymer