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1.1. 1 1.1 4 3 1.1.1 Bi Bi 2 Te 3 Bi Bi 2 Te 3 Bi(111) Bi 2 Te 3 (111) Rashba π Bi(111) Bi 2 Te 3 (111) in-situ Bi(111) Rashba Bi 2 Te 3 (111) 3-6QL QL= FIB (FIB) 4 STM in situ in situ FIB Si(111) 8 QL Bi 2 Se 3 (111) FIB capped non-capped 1 2 - -1 2 2 4 capped non-capped 2 4 ( 1.1.1) FIB Ga Wire conductivity, σ wire (ms μm) 12 10 8 6 4 2 0 0 With Se capping(σ 4pp =1.32mS) Without Se capping(σ 4pp =1.20mS) σ wire =1.39(w-1.42) 2 4 6 8 Wire width, w (μm) σ wire =0.67(w-3.13) 1.1.1: ( ) ( ) Bi 2 Se 3 1 Bi 2 Se 3 FIB H Bi 2 Se 3 - Bi 2 Se 3 (111) 10 12

2 H ( 1.1.2 ) ( 1.1.2) H 1.1.2: H w L FIB-SIM( ) Si(110)2 5-Au Si(110)2 5-Au Au Si(110)2 5-Au 4 10μm 1.1.2 Ag Ag(111) Ag Ag(111) (ARPES) LEED RHEED Ag (QWS) / QWS Ag(111) RHEED ARPES Ag (QWS) Ag Ag / QWS Ag(111) RHEED Ag / RHEED LEED Ag(111) Ag(111) 3 3 Γ ( 1.1.3) CNR

1.1. 3 STM STM 1.1.3: - 200 Å - 1960 Bi(111) ( 100 Å) s 50 mev - 1.1.3 (10 11 Torr) ( 2.5 K) 8T Ag(111) (A) [1] 2012 7 [2] T. Hirahara, N. Fukui, T. Shirasawa, M. Yamada, M. Aitani, H. Miyazaki, M. Matsunami, S. Kimura, T. Takahashi, S. Hasegawa, and K. Kobayashi, Atomic and Electronic Structure of Ultrathin Bi(111) Films Grown on Bi 2Te 3(111) Substrates: Evidence for a Strain-Induced Topological Phase Transition, Phys. Rev. Lett. 109, 227401 (Nov, 2012). [3] T. Uetake, T. Hirahara, Y. Ueda, N. Nagamura, R. Hobara, and S. Hasegawa, Anisotropic conductivity of the Si(111)4 1-In surface: Transport mechanism determined by the temperature dependence, Phys. Rev. B 86, 035325 (Jul, 2012). [4] Y. Fukaya, K. Kubo, T. Hirahara, S. Yamazaki, W. H. Choi, H. W. Yeom, A. Kawasuso, S. Hasegawa, and I. Matsuda, Atomic and Electronic Structures of Si(111)- 21 21 Superstructure, e-journal of Surface Science and Nanotechnology 10, 310 (Jul, 2012). [5] M. Yamada, T. Hirahara, S. Hasegawa, H. Mizuno, Y. Miyatake, and T. Nagamura, Surface Electrical Conductivity Measurement System with Micro- Four-Point Probes at Sub-Kelvin Temperature under High Magnetic Field in Ultrahigh Vacuum, e- Journal of Surface Science and Nanotechnology 10, 400 (Jul, 2012).

4 [6] P. De Padova, P. Vogt, A. Resta, J. Avila, I. Razado-Colambo, C. Quaresima, C. Ottaviani, B. Olivieri, T. Bruhn, T. Hirahara, T. Shirai, S. Hasagawa, M. C. Asensio, and G. Le Lay, Evidence of Dirac Fermions in Multilayer Silicene, Appl. Phys. Lett, in press (2013). ( ) ( ) [7] S. Hasegawa, T. Hirahara, Y. Kitaoka, S. Yoshimoto, T. Tono, and T. Ohta, Nanometer-Scale Four-Point Probe Resistance Measurements of Individual Nanowires by Four-Tip STM, pp. 153-165, in Atomic Scale Interconnection Machines, ed. Christian Joachim (Springer 2012). [8] S. Hasegawa : Reflection High-Energy Electron Diffraction, pp. 1925-1938, in Characterization of Materials, ed. Elton N. Kaufmann (Wiley 2012). [9] in (, Oct 2012). [10] S. Hasegawa: The Image is My Life., in In Memory of Akira Tonomura: Physicist and Electron Microscopist (World Scientific, 2013), in press. ( ) [11], 2013 3. [12] 4. [13]. [14] S. Hasegawa:Topological and superconducting surface states, Workshop of DFG- and NOW- Research Units FOR 1700, FOR 1162 and FOM on Physics at the borderline between 1D and 2D, 2013 2 14 (Bad Honnef, Germany). [15] S. Hasegawa:Surface nanomaterials: Lowdimensional, spin-split, and superconducting, The 2nd International School on Surface Science: Technologies and Measurements on Atomic Scale, 2012 10 6 (Sochi, Russia). [16] T. Hirahara: Charge and Spin Transport at Nonmagnetic Surfaces, International Conference of Young Researchers on Advanced Materials (ICYRAM), 2012 7 3 (Singapore) [17] T. Hirahara: Comprehensive study of topological phase transitions using ultrathin films, Energy Materials Nanotechnology (EMN) West Meeting, 2013 1 7 (Houston, USA). [18] T. Hirahara, M. Aitani, and S. Hasegawsa: In situ Magnetotransport measurements of ultrathin Bi films on Si(111), Symposium on Surface and Nano Science 2013, 2013 1 17 ( ). [19] N. Fukui, T. Hirahara, and S. Hasegawa: In Situ Fabrication and Transport Measurements of Surface Nanostructures with a For-tip STM Combined with FIB, International Conference of Young Researchers on Advanced Materials 2012, 2012 7 3 (Singapore). [20] M. Aitani, T. Hirahara, and S. Hasegawa: In situ magnetotransport measurements of ultrathin Bi films, The Yonsei-Todai Joint Workshop 2013, 2013 2 19 ( ). [21] N. Fukui, T. Hirahara, and S. Hasegawa: Microfabrication of ultrathin films by focused ion beam and in situ electric conduction measurement by 4- tip STM, The Yonsei-Todai Joint Workshop 2013, 2013 2 19 ( ). The 10th Japan-Russia Seminar on Semiconductor Surfaces (JRSSS10), 2012 9 26-28 (, ) [22] T. Hirahara and S. Hasegawa: Ultrathin Bi films: Electronic structure and topological properties. [23] M. Yamada, T. Hirahara, R. Hobara, S. Hasegawa: Surface-state superconductivity measured by a UHV sub-kelvin micro-four-point-probe system under high magnetic field. [24] T. Tono, Y. Ueda, T. Hirahara, and S. Hasegawa: Measurements of non-integer dimensional transports in Si(110)-2 5 Au. [25] M. Aitani, T. Hirahara, and S. Hasegawa: Magnetotransport measurements of ultrathin Bi films on Si(111). [26] N. Fukui, T. Hirahara, and S. Hasegawa: The Surface-State Conduction of a Microstructure Fabricated by Focused Ion Beam. [27] T. Shirai, T. Hirahara, and S. Hasegawa: Study of the Quantum-Well States in Ultrathin Ag Films covered with Silicene. [28] :,, 2012 7 18 (NIMS, ).

1.1. 5 [29] :, 20, 2013 1 11 ( ). [30] :, 60, 2013 3 27 (, ). [31] :, 68, 2013 3 28 (, ). [32] :, UVSORIII, 2012 6 21 ( ). [33] :, A 1, 2012 7 25 ( ). [34] :, 2020 2013 1 23 ( ). [35] :, UVSOR, 2012 11 10 ( ). [36] Si(110)2 5- Au, 2012, 2012 9 18 ( ). [37] in situ, 2012, 2012 9 18 ( ). [38], 32, 2012 11 20. [39] Bi, 32, 2012 11 21. [40] Ag, 32, 2012 11 21. [41] :, 24, 2012 12 14 (,. [42],,, 68, 2013 3 26 (, ). [43] Ag, 68, 2013 3 27 (, ). [44] :,, 2012 4 27 ( ). [45] :, JEITA ( ), 2012 7 27 (JEITA, ). [46] :, ( ), 2012 8 22 (, ). [47] :, JST-ERATO, 2012 12 21 (, ). ( ) [48] :, ( ) 53, 2012 7 11 (, ). [49] :, II, 2012 7 17 (, ). [50] (TA) (TA) I 2012. [51] 2012. [52] :, IPhO2013, 2012 12 24 (, ). [53], :, 24 2012, 2012 8 10 (, ). [54] :, 2012 5 20 (, ); 2012 12 20 (, );2013 2 22 (, ); 2013 3 16 (, ). [55] : at, 2012 11 27 ( ); 2012 11 13 ( ); 2012 8 9 ( );2012 8 3 ( ).

6 1 Hasegawa Group Research Subject: Experimental Surface/Nano Physics Members: Shuji HASEGAWA and Toru HIRAHARA Surfaces of materials are platforms of our research where rich physics is expected due to the lowdimensionality and symmetry breakdown. (1) Electronic/spin/mass transports, (2) atomic/electronic structures, (3) phase transitions, (4) electronic excitations, (5) spin states and magnetism, and (6) epitaxial growths of coherent atomic/molecular layers/wires on semiconductor surfaces, topological surfaces, and nano-scale phases such as surface superstructures and ultra-thin films. We use various kinds of ultrahigh vacuum experimental techniques such as electron diffraction, scanning electron microscopy, scanning tunneling microscopy/spectroscopy (STM/S), photoemission spectroscopy, in-situ four-point-probe conductivity measurements with four-tip STM and monolithic micro-four-point probes, and surface mageto-optical Kerr effect measurements. Main results in this year are as follows. (1) Surface electronic transport: Control of surface electronic states and their conductivity of topological insulators by using FIB patterning techniques. Spin Hall effect, effects due to anti-weak localization and electron-electron interaction at strong spin-orbit coupling material surfaces. Anisotropic transport on a quasi-one-dimensional metallic surface. (2) Surface phases, ultra-thin films, and phase transitions: Silicene, semi-metal-to-semiconductor transition in Bi ultrathin films, 2D topological materials. Topological phase transition. Order-disorder phase transition, charge-density-wave transition, Mott transition on various metal-induced surface superstructures of Si. Quantum-well state in ultra-thin metal films. Rashba effect in surface state and hybridization with quantum-well states in thin films. (3) Surface magnetism: Monolayer ferromagnetic surfaces. Diluted magnetic surface states. Kondo effect and RKKY interaction in surface states. (4) Construction of new apparatuses: Low-temperature strong-magnetic-field scanning tunneling microscope and scanning tunneling potentiometery. Micro-four-point probes apparatus at mk under strong magnetic field. [1] T. Hirahara, N. Fukui, T. Shirasawa, M. Yamada, M. Aitani, H. Miyazaki, M. Matsunami, S. Kimura, T. Takahashi, S. Hasegawa, and K. Kobayashi, Atomic and Electronic Structure of Ultrathin Bi(111) Films Grown on Bi 2Te 3(111) Substrates: Evidence for a Strain-Induced Topological Phase Transition, Phys. Rev. Lett. 109, 227401 (Nov, 2012). [2] T. Uetake, T. Hirahara, Y. Ueda, N. Nagamura, R. Hobara, and S. Hasegawa, Anisotropic conductivity of the Si(111)4 1-In surface: Transport mechanism determined by the temperature dependence, Phys. Rev. B 86, 035325 (Jul, 2012). [3] Y. Fukaya, K. Kubo, T. Hirahara, S. Yamazaki, W. H. Choi, H. W. Yeom, A. Kawasuso, S. Hasegawa, and I. Matsuda, Atomic and Electronic Structures of Si(111)- 21 21 Superstructure, e-journal of Surface Science and Nanotechnology 10, 310 (Jul, 2012). [4] M. Yamada, T. Hirahara, S. Hasegawa, H. Mizuno, Y. Miyatake, and T. Nagamura, Surface Electrical Conductivity Measurement System with Micro-Four-Point Probes at Sub-Kelvin Temperature under High Magnetic Field in Ultrahigh Vacuum, e-journal of Surface Science and Nanotechnology 10, 400 (Jul, 2012). [5] P. De Padova, P. Vogt, A. Resta, J. Avila, I. Razado-Colambo, C. Quaresima, C. Ottaviani, B. Olivieri, T. Bruhn, T. Hirahara, T. Shirai, S. Hasagawa, M. C. Asensio, and G. Le Lay, Evidence of Dirac Fermions in Multilayer Silicene, Appl. Phys. Lett, in press (2013). [6] S. Hasegawa, T. Hirahara, Y. Kitaoka, S. Yoshimoto, T. Tono, and T. Ohta, Nanometer-Scale Four-Point Probe Resistance Measurements of Individual Nanowires by Four-Tip STM, pp. 153-165, in Atomic Scale Interconnection Machines, ed. Christian Joachim (Springer, 2012). [7] S. Hasegawa: Reflection High-Energy Electron Diffraction, pp. 1925-1938, in Characterization of Materials, ed. Elton N. Kaufmann (Wiley, 2012). [8] S. Hasegawa: The Image is My Life., inmemory of Akira Tonomura: Physicist and Electron Microscopist (World Scientific, 2013), in press.