2008 3 Mar. 2008 CHEMICAL INDUSTRY AND ENGINEERING 25 2 Vol. 25 No. 2 :1004-9533 (2008) 02-0177 - 06,,, (,, 163318) :,, :;; ;; : TQ3141248 :A Development and Application of the Flame Retardants for Plastic J I Wei, WANGJian, DONG Qun, ZHANG Xue2jia (Chemistry and Chemical Engineering College, Daqing Petroleum Institute, Daqing 163318, Heilongjiang Province, China) Abstract : The mechanism and process of plastic burning were introduced and the basic theory and the category of flame retardants were summarized, especially the application in plastic was discussed. At last, the developing tendency of the flame retardants were prospected. Key words :plastic ; burning ; flame retardant ; application ; developing tendency,,,, [1 ], 1 111,2, 2, HO O,,, HO O [2 ] :1), HO O 2), (LOI, ) LOI, LOI 22 25, ;LOI 26 ; LOI 30 112 [3 ] ; :2007-06 - 21 : (1983 - ),,, :,: (0459) 6503379,E2mail :mrwj163 @163. com
178 2008 3 31 %( ) 22 %( 2 ) Π [4 ] 4 [5 ] 1) :,,,,, Π ;2) :,, ;3) : O OH,,, ;4) :,,,,,,, 2,65 % 70 %, 20 %,5 %,3 %,2 % [6 ] ABS 211 ( PVC) PVC 5618 % ( ), PVC (DOP) PVC,,,, [4 ] PVC, PVC, 212, (PP) ( PE) ( PS) (PMMA) [3 ],,,, PE PE PP,200,, 200, ;, ;, PP PE,, 1,22 ( ) ( ETPB) PP PE [4 ],, (1),,,,, [3 ] Lancaster Ebdon [7 ], (St) (MMA),,LOI,,,LOI, Gentilhomme [8 ] CH 2 C(CH 3 ) C(O) OCH(R) P(O) (OC 2 H 5 ) 2 MMA,R H C 6 H 4 Br C 10 H 7,,,PMMA,, Banks [9 ] CH 2 CHP(O) (OC 2 H 5 ) 2, St MMA (AN) (AM), TGA LOI, LOI, TGA, AM AN,
25 2 : 179 2 [10 ] PP, NH 2 P2N,, PP,PP LOI, 213 ( PS) ABS PS, PS,, (2,32 ) ( ) ; A, ;,, PS,,,,PS, PS [4 ] ABS 3 ABS ABS LOI 1818 2012,,,, 1 ABS, ABS [11 ] ABS [12 ] :1),, ;2), PVC,CPE ;3), ABS Suzuki [13 ],, Wang Zhitao [14,15 ] Friedel2Crafts 42 22 (DPP),, 214,,,,,,,,, Asrar Mo [16 ] TPA EG 22 (CEPP)
180 2008 3 PET2co2CEPP Zhao [17 ] TPA EG DDP PET2co2DDP,, E a : PET2co2 DDP < PET < PET2co2CEPP,, 3 311 4 000, 52 % 58 %,,,,, (ATH) ATH ATH,,,,, ATH, ATH [18 ],, ATH Soler Hyfex311 11 m ATH ; Eerozcn Halofree ATH Mg (OH) 2 ; ; Sb 2 O 5,0101 0102 m,; NI Oncar23A Sb 2 O 3 SbO 2 ; Anzcn American FFR22, PVC 50 % [4 ] 312, :,, Ferro PB268,, 15 000, 68 % (, ) ; Ameribron FR21025, 30 000 80 000, 68 % [19 ] ; BC252 BC258 A, 3 000,,,,,, CR2720, 10 %( ), [4 ] 313, [20 ],LOI 34 36,,,, 10 % ( ) 20 % AKIO Fyrolflex RDP, (300 ), PVC ABS ; Albright2Wilson ; Amgard NL ph, [4 ] 314, Borox,Firebrake
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