Progress in Biomimicing of Super2Hydrophobic Surface

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1 PROGRESS IN CHEMISTRY Vol. 18 No. 6 June, , ( ; ), : O647 : A : X(2006) Progress in Biomimicing of Super2Hydrophobic Surface Guo Zhiguang 1,2 Liu Weimin (1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou , China ; 2. Graduate School, Chinese Academy of Sciences, Beijing , China) Abstract Biomimic super2hydrophobic surface has been considered as a new research field in mimicing biological systems with chemistry. The super2hydrophobic phenomena of lotus etc. give such model of preparations of biomimic super2hydrophobic surfaces on many substrates. The studies on super2hydrophobic properties and micro2structures of lotus and the research progress in biomimicing of super2hydrophobic surface are reviewed. The author s opinions with respect to the future development of this research field are proposed. Key words lotus effect ; super2hydrophobic ; contact angle ; binary structure ; nano2materials 1 (lotus effect), 90 ;,, [1 4 ] (, A ) ( R ), (hysteresis) [5 ] [6 ] [7 ] [8 ], [9 ] [6,10 ] (contact angle) [11 14 ] : , : (No , ) 3 3 e2mail ac. cn

2 [1 (binary structure) (surface energy) 14 ], [15,16 ] [17 2 ( sol2gel) 19 ] [20,21 ] [7 ] [11 ] [22 ] [5 ] 2 SEM ( Fig. 2 The SEM images of taro in various magnifications FAS) [10 12 ], 8 10 m, 2, 20 50nm Barholtt Neinhuis [23 ] SEM, 5 8 m 20 50nm [24 Holloway 26 ] ( ), SEM 1a 3 SEM 1 SEM :a ; Fig. 3 The SEM images of haulm in various magnifications b Fig. 1 The SEM images of lotus in various magnifications 4 3 XPS 4,3 C O, 5 9 m, 1a 1b, 50 70nm [27 2 5, ] XPS Fig. 4 The XPS spectrums of lotus, taro and haulm SEM 2

3 SEM XPS Shang [17 ] 2, (sol2gel) TiO 2 3 Wang [4 ] 311 (ACNTs) TiO 2 TiO 2 773K (ACNTs) ACNTs (CVD) 72 1 ;,, 0 1,, 60nm, ( ) ACNTs , 160 Nakajima [12 ] ArΠH 2 ( FePC) (AACA) ( TACA) 900 ACNTs [8 ], ACNTs 1 500rmp , s, [9 ] [13 TiO 2 ] ACNTs CVD, 193 ACNTs :, 150 ;, 30, ,, 33nm [28,29 ], Lau [10 ] ( PECVD) Hsieh [30 ] 2 (VACNTs) 3 :, ( 20nm),650 Ni ; DC Ni, VACNTs, VACNTs , VACNTs ;, Macak [31 ] (HFCVD), VACNTs PTFE 100nm, 150nm ,,,,,ACNTs Yuce [32 ] 312 TiO 2 ZnO Wu [33 ] ACNTs,

4 ,, 150 Jisr [39 ] (layer2by2layer), 16, 168,, (Wenzel ) (Cassie2Baxter ), Yan [40 ], [41 ] ( PMMA) 313 McCarthy [14,34 ] (SA) [42 ] (RFAP) ( PTFE), 2 ( PP2PMMA) Yabu [43 ], SA ;,RFAP PTFE Erbil [7 ], 172 Ma [16 ] 160 2,, nm, : ;, 163, 15 [35,36 ] (PAN) 314 Shirtcliffe [44 ] 10416nm 51318nm PAN ( ),, ph (ph = ) 165 [37 ] [45 ] ( l2b2l assembly technique) [46, ] ph, ph, Chen [47 ] (FPU), ;, 3D Han [38 ] 2,

5 6 725, Nakajima [11 ], TiO 2,,,, Dupuis [54 ] - 4 Gu [48 ], 155 Whitesides [2 ] Roig [49 ] (MSA) 011 1mm 4 SMA, HS(CH 2 ) 15 COOH MSA [ CH 3 (CH 2 ) 11 S] 2 McCarthy [50 ], Onda [5 ], X2Y 32 m 5 Bikerman [51 ] 90, Johnson [52 ],, ;, Nakajima, [11 13 ],, [55 59 ],, (, ),, Cassie [53 ], :

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