Supporting Information
|
|
- Δάμαλις Χριστόπουλος
- 7 χρόνια πριν
- Προβολές:
Transcript
1 Electronic upplementary Material (EI) for Green Chemistry. This journal is The Royal ociety of Chemistry 204 upporting Information ynthesis of sulfonamides via I 2 -mediated reaction of sodium sulfinates with amines in aqueous medium at room temperature Xiaojun Pan, Jian Gao, Juan Liu, Junyi Lai, Huanfeng Jiang and Gaoqing Yuan* chool of Chemistry and Chemical Engineering, outh China University of Technology, Guangzhou 50640, China gqyuan@scut.edu.cn Table of Contents General Information...2 Typical procedure for the synthesis of sulfonamides...2 Analytical data of the prepared compounds...2 NMR spectra of the prepared compounds...9
2 General Information The H NMR and 3 C NMR spectra were recorded on a Bruker Advance 400 spectrometer in CDCl 3 at 400 MHz and 00 MHz, respectively. The chemical shifts were referenced to signals at 7.26 and 77.0 ppm, respectively. Proton coupling patterns were described as singlet (s), doublet (d), triplet (t), quartet (q) and multiplet (m). Mass spectra were recorded on a himadzu GCM- QP5050A spectrometer at an ionization voltage of 70 ev equipped with a DB-WAX capillary column (internal diameter: 0.25 mm, length: 30 m). GC-M was obtained using electron ionization. High resolution mass spectra (HRM) were recorded on a MAT95XP high resolution mass spectrometer. TLC was performed using commercially prepared mesh silica gel plates (GF254), and visualization was effected at 254 nm. All substrates were purchased commercially without further purification. Typical procedure for the synthesis of sulfonamides The mixture of iodine (0.25 mmol), sodium sulfinates (0.6 mmol), water (2 ml) and amines (0.5 mmol) were added to a 0 ml tube successively. Then, the reaction was performed at room temperature under magnetic stirring for 3 h. When it was finished, some ethyl acetate was added to the tube to extract the aqueous solution. After extracting, the obtained organic layer was dried with anhydrous Mg 4. The solvent was removed under vacuum, and the crude residue was purified by silica gel column chromatography to afford the desired pure product. Analytical Data of the prepared compounds N N-Benzyl-N,4-dimethylbenzenesulfonamide (3a) H NMR (400 MHz, CDCl 3 ): δ 7.73 (d, J =7.7Hz, 2H), (m, 7H), 4.2 (s, 2H), 2.58 (s, 3H), 2.45 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.4, 35.7, 34.3, 29.7, 28.6, 28.3, 27.8, 27.5, 54., 34.3, 2.5; M (EI) m/z: 275, 98, 84, 55, 20, 9. 2
3 NH 4-Methyl-N-(thiophen-2-ylmethyl)benzenesulfonamide (3b) 2 H NMR (400 MHz, CDCl 3 ): δ 7.77 (d, J =7.5 Hz, 2H), 7.32 (d, J =7.7 Hz, 2H), 7.20 (d, J =4.6 Hz, H), 6.88 (d, J =5.5 Hz, 2H), 5.8 (t, J =5.4 Hz, H), 4.34 (d, J =6.0 Hz, 2H), 2.45 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.5, 39.0, 36.7, 29.6, 27., 26.8, 26.4, 25.6, 4.9, 2.4; M (EI) m/z: 267, 207, 39, 2, 9. NH N-(Furan-2-ylmethyl)-4-methylbenzenesulfonamide (3c) 3 H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =7.6 Hz, 2H), 7.25 (d, J =7.8 Hz, 2H), 7.2 (s, H), 6.9 (s, H), 6.08 (s, H), 5.8 (br, H), 4.4 (d, J =5.8 Hz, 2H), 2.40 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 49.6, 43.3, 42.3, 36.8, 29.5, 27.0, 0.3, 08., 40.0, 2.4; M (EI) m/z: 25, 86, 55, 39, 96. H N 4-Methyl-N-phenylbenzenesulfonamide (3d) H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =8.2 Hz, 2H), 7.59 (br, H), (m, 7H), 2.32 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.8, 36.6, 35.9, 29.6, 29.2, 27.2, 25.0, 2.2, 2.4; M (EI) m/z: 247, 82, 68, 55, 9. NH N-Benzyl-4-methylbenzenesulfonamide (3e ) H NMR (400 MHz, CDCl 3 ): δ 7.75 (d, J =7.7 Hz, 2H), (m, 7H), 4.79 (br, H), 4. (d, J =5.9 Hz, 2H), 2.43 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.4, 36.8, 36.3, 29.6, 28.6, 27.8, 27.7, 27., 47., 2.4; M (EI) m/z: 26, 96, 55, 06, 9. 3
4 F NH N-(4-Fluorobenzyl)-4-methylbenzenesulfonamide (3e 2 ) 4 H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =7.6 Hz, 2H), 7.27 (d, J =7.6 Hz, 2H), (m, 2H), (m, 2H), 5.24 (t, J =5.6 Hz, H), 4.06 (d, J =6. Hz, 2H), 2.42 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 63.4, 6.0, 43.5, 36.8, 32.2, 29.7, 29.6, 29.5, 27.0, 5.5, 5.3, 46.4, 2.4; M (EI) m/z: 279, 24, 55, 24, 9. Cl NH N-(4-Chlorobenzyl)-4-methylbenzenesulfonamide (3e 3 ) 4 H NMR (400 MHz, CDCl 3 ): δ 7.69 (d, J =7.5 Hz, 2H), 7.25 (d, J =7.8 Hz, 2H), 7.8 (d, J =7.4 Hz, 2H), 7.0 (d, J =7.8 Hz, 2H), 5.42 (br, H), 4.04 (d, J =6.3 Hz, 2H), 2.4 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.5, 36.7, 34.9, 33.4, 29.6, 29.2, 28.6, 27.0, 46.4, 2.4; M (EI) m/z: 295, 230, 40, 25, 9. Br NH N-(4-Bromobenzyl)-4-methylbenzenesulfonamide (3e 4 ) 4 H NMR (400 MHz, CDCl 3 ): δ 7.69 (d, J =8.0 Hz, 2H), 7.33 (d, J =8. Hz, 2H), 7.25 (d, J = 7.7 Hz, 2H), 7.05 (d, J =8.0 Hz, 2H), 5.37 (br, H), 4.03 (d, J =4.2 Hz, 2H), 2.42 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.6, 36.7, 35.5, 3.6, 29.7, 29.5, 27.0, 2.6, 46.4, 2.4; M (EI) m/z: 339, 207, 84, 57, 9. NH 4-Methyl-N-(4-methylbenzyl)benzenesulfonamide (3e 5 ) 4 4
5 H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =7.7 Hz, 2H), 7.24 (d, J =7.7Hz, 2H), (m, 4H), 5.8 (br, H), 4.0 (d, J =6.0 Hz, 2H), 2.39 (s, 3H), 2.26 (s, 3H); 3 C NMR (00MHz, CDCl 3 ): δ 43.2, 37.3, 36.8, 33.2, 29.5, 29., 27.7, 27.0, 46.8, 2.3, 20.9; M (EI) m/z: 275, 20, 39, 20, 9. NH N-(4-Methoxybenzyl)-4-methylbenzenesulfonamide (3e 6 ) 5 H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =7.4 Hz, 2H), 7.25 (d, J =7.3 Hz, 2H), 7.08 (d, J =7.4 Hz, 2H), 6.75 (d, J =7.4 Hz, 2H), 5.22 (br, H), 4.00 (d, J =3.8 Hz, 2H), 3.73 (s, 3H), 2.40 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 59.0, 43.2, 36.8, 29.5, 29., 28.3, 27.0, 3.8, 55., 46.5, 2.3; M (EI) m/z: 29, 55, 35, 2, 9. N N,4-Dimethyl-N-phenylbenzenesulfonamide (3f ) H NMR (400 MHz, CDCl 3 ): δ 7.43 (d, J =7.8 Hz, 2H), (m, 5H), 7.0 (d, J =7.6 Hz, 2H), 3.6 (s, 3H), 2.4(s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.5, 4.6, 33.6, 29.3, 28.8, 27.9, 27.2, 26.6, 38., 2.5; M (EI) m/z: 26, 97, 55, 06, 9, 77. N Br N-(4-Bromophenyl)-N,4-dimethylbenzenesulfonamide (3f 2 ) H NMR (400 MHz, CDCl 3 ): δ 7.40 (d, J =8.5 Hz, 4H), 7.24 (d, J =7.7 Hz, 2H), 6.97 (d, J =7.3 Hz, 2H), 3.2 (s, 3H), 2.4 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.8, 40.6, 32.9, 3.8, 29.4, 28.0, 27.7, 20.8, 37.8, 2.4; M (EI) m/z: 340, 96, 55, 05, 9; HRM (EI) m/z: calcd for C 4 H 4 BrNNa 2 [M+Na]+, ; found NH N,4-Dimethylbenzenesulfonamide (3g ) 5
6 H NMR (400 MHz, CDCl 3 ): δ 7.77 (d, J =8.Hz, 2H), 7.33 (d, J =8.0 Hz, 2H), 4.65 (br, H), 2.65 (d, J =5.0 Hz, 3H), 2.45 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.5, 35.8, 29.7, 27.2, 29.3, 2.5; M (EI) m/z: 85, 55, 2, 9. NH 4-Methyl-N-propylbenzenesulfonamide (3g 2 ) H NMR (400 MHz, CDCl 3 ): δ 7.78 (d, J =7.7 Hz, 2H), 7.33(d, J =7.7 Hz, 2H), 4.76 (br, H), (m, 2H), 2.45 (s, 3H), (m, 2H), 0.88 (t, J =7.4 Hz, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.3, 37.0, 29.6, 27.0, 44.9, 22.9, 2.4,.0; M (EI) m/z: 23, 84, 55, 9. H N N-Tert-butyl-4-methylbenzenesulfonamide (3g 3 ) H NMR (400 MHz, CDCl 3 ): δ 7.77 (d, J =8.2 Hz, 2H), 7.27 (d, J =8.3 Hz, 2H), 4.63 (br, H), 2.42 (s, 3H),.22 (s, 9H); 3 C NMR (00 MHz, CDCl 3 ): δ 42.8, 40.5, 29.4, 27.0, 54.6, 30., 2.4; M (EI) m/z: 227, 22, 55, 9. NH N-Hexyl-4-methylbenzenesulfonamide (3g 4 ) H NMR (400 MHz, CDCl 3 ): δ 7.75 (d, J =8. Hz, 2H), 7.30 (d, J =8.0 Hz, 2H), 4.57 (br, H), (m, 2H), 2.43 (s, 3H), (m, 2H), (m, 6H), 0.84 (t, J =6.7 Hz, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.3, 37.0, 29.6, 27., 43.2, 3.2, 29.5, 26., 22.4, 2.5, 3.9; M (EI) m/z: 255, 84, 55, 00, 9. NH N N-(2-(Dimethylamino)ethyl)-4-methylbenzenesulfonamide (3h) H NMR (400 MHz, CDCl 3 ): δ 7.76 (d, J =7.7 Hz, 2H), 7.3 (d, J =7.6 Hz, 2H), (m, 2H), 2.43 (s, 3H), (m, 2H), 2.09 (s, 6H),.26 (br, H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.3, 36.7, 29.6, 27., 57.0, 44.7, 40.0, 2.5; M (EI) m/z: 242, 23, 55, 48, 9; HRM (EI) m/z: calcd for C H 8 N 2 Na 2 [M+Na]+, ; found
7 H N N-Allyl-4-methylbenzenesulfonamide (3i) H NMR (400 MHz, CDCl 3 ): δ 7.78 (d, J =8.3 Hz, 2H), 7.33 (d, J =8.0 Hz, 2H), (m, H), (m, 2H), 4.55 (br, H), 3.6 (t, J = 6.0 Hz, 2H), 2.45 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.5, 37.0, 33.0, 29.7, 27., 7.7, 45.8, 2.5; M (EI) m/z: 2, 84, 55, 9. N N,N-Diethyl-4-methylbenzenesulfonamide (3j) H NMR (400 MHz, CDCl 3 ): δ 7.7 (d, J =7.6 Hz, 2H), 7.30 (d, J =8.0 Hz, 2H), 3.24 (q, J =7. Hz, 4H), 2.43 (s, 3H),.4 (t, J =7. Hz, 6H); 3 C NMR (00 MHz, CDCl 3 ): δ 42.9, 37.4, 29.5, 27.0, 42.0, 2.4, 4.; M (EI) m/z: 227, 84, 55, 9. N N N-(2-cyanoethyl)-N,4-dimethylbenzenesulfonamide (3k) H NMR (400 MHz, CDCl 3 ): δ 7.69 (d, J =7.7 Hz, 2H), 7.35 (d, J =7.8 Hz, 2H), 3.33 (t, J =6.8 Hz, 2H), 2.86 (s, 3H), 2.67 (t, J =6.8 Hz, 2H), 2.45 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 44.0, 34.0, 29.9, 27.2, 7.4, 46.3, 36.0, 2.4, 8.; M (EI) m/z: 238, 98, 55, 9; HRM (EI) m/z: calcd for C H 4 N 2 Na 2 [M+Na]+, ; found N -Tosylpyrrolidine (3l) H NMR (400 MHz, CDCl 3 ): δ 7.72 (d, J =8.0 Hz, 2H), 7.32 (d, J =8.0 Hz, 2H), 3.23 (t, J =6.6 Hz, 4H), 2.43 (s, 3H), (m, 4H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.2, 33.9, 29.5, 27.5, 47.8, 25., 2.4; M (EI) m/z: 225, 55, 9. N 4-Tosylmorpholine (3m) 7
8 H NMR (400 MHz, CDCl 3 ): δ 7.64 (d, J =8. Hz, 2H), 7.35 (d, J =8.0 Hz, 2H), 3.74(t, J =4.8 Hz, 4H), 2.98 (t, J =4.8 Hz, 4H), 2.44 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.9, 32.0, 29.7, 27.8, 66.0, 45.9, 2.5; M (EI) m/z: 24, 98, 55, 06, 9, 86. N 4-Tosylthiomorpholine (3n) 6 H NMR (400 MHz, CDCl 3 ): δ 7.64 (d, J =7.7 Hz, 2H), 7.35 (d, J =7.8 Hz, 2H), 3.34 (s, 4H), 2.72 (s, 4H), 2.46 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 43.7, 33.7, 29.8, 27.4, 47.8, 27.3, 2.5; M (EI) m/z: 257, 242, 93, 55, 02, 9. N N-Benzyl-N-methylbenzenesulfonamide (3o ) 7 H NMR (400 MHz, CDCl 3 ): δ 7.85 (d, J =7.6 Hz, 2H), (m, 3H), (m, 5H), 4.5 (s, 2H), 2.6 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 37.4, 35.5, 32.6, 29., 28.6, 28.3, 27.9, 27.4, 54., 34.3; M (EI) m/z: 26, 84, 4, 8, 9. F N N-Benzyl-4-fluoro-N-methylbenzenesulfonamide (3o 2 ) 7 H NMR (400 MHz, CDCl 3 ): δ (m, 2H), (m, 7H), 4.5 (s, 2H), 2.6 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 66.3, 63.8, 35.3, 33.6, 30., 30.0, 28.6, 28.3, 27.9, 6.4, 6.2, 54.0, 34.2; M (EI) m/z: 279, 202, 20, 9. Cl N N-Benzyl-4-chloro-N-methylbenzenesulfonamide (3o 3 ) 7 8
9 H NMR (400 MHz, CDCl 3 ): δ 7.77 (d, J =7.9 Hz, 2H), 7.53 (d, J =8.0 Hz, 2H), (m, 5H), 4.5 (s, 2H), 2.6 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 39.2, 36.0, 35.2, 29.4, 28.8, 28.6, 28.3, 28.0, 54.0, 34.2; M (EI) m/z: 295, 28, 75, 20, 9. Br N N-Benzyl-4-bromo-N-methylbenzenesulfonamide (3o 4 ) 7 H NMR (400 MHz, CDCl 3 ): δ 7.70 (s, 4H), (m, 5H), 4.5 (s, 2H), 2.6 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 36.5, 35.2, 32.4, 28.9, 28.7, 28.3, 28.0, 27.6, 54.0, 34.3; M (EI) m/z: 339, 262, 55, 20, 9. 2-Tosylethene-,-diyldibenzene (4a) 8 H NMR (400 MHz, CDCl 3 ): δ 7.47 (d, J =8.2 Hz, 2H), (m, 2H), 7.29 (td, J =7.4,.6 Hz, 4H), (m, 2H), 7.4 (d, J =8. Hz, 2H), (m, 2H), 6.99 (s, H), 2.37 (s, 3H); 3 C NMR (00 MHz, CDCl 3 ): δ 54.6, 43.7, 39.2, 38.6, 35.5, 30.2, 29.7, 29.3, 28.9, 28.8, 28.5, 28., 27.7, 27.6, 2.5; M (EI) m/z: 334, 269, 78, 67, 39, 9. References. X. D. Tang, L. B. Huang, C. R. Qi, X. Wu, W. Q. Wu and H. F. Jiang, Chem. Commun. 203, 49, F. hi, M. K. Tse, X. J. Cui, D. Gördes, D. Michalik, K. Thurow, Y. Q. Deng and M. Beller, Angew. Chem., Int. Ed. 2009, 48, A. Kamal, J.. Reddy, E. V. Bharathi and D. Dastagiri, Tetrahedron Letters. 2008, 49, X. J. Cui, F. hi, Y. Zhang and Y. Q. Deng, Tetrahedron Letters. 200, 5, C. Z. Liu,. H. Liao, Q. Li,. L. Feng, Q. un, X. C. Yu and Q. Xu, J. rg. Chem. 20, 76, K. aruta, T. giku and K. Fukase, Tetrahedron Letters. 2009, 50, D. A. Powell and H. Fan, J. rg. Chem. 200, 75, D. C. Reeves,. Rodriguez, H. Lee, N. Haddad, D. Krishnamurthy and C. H. enanayake, Tetrahedron Letters. 2009, 50,
10 NMR spectra of the prepared compounds Fig. -. H-NMR spectrum of 3a. Fig C-NMR spectrum of 3a. 0
11 Fig. -3. H-NMR spectrum of 3b. Fig C-NMR spectrum of 3b.
12 Fig. -5. H-NMR spectrum of 3c. Fig C-NMR spectrum of 3c. 2
13 Fig. -7. H-NMR spectrum of 3d. Fig C-NMR spectrum of 3d. 3
14 Fig. -9. H-NMR spectrum of 3e. Fig C-NMR spectrum of 3e. 4
15 Fig. -. H-NMR spectrum of 3e 2. Fig C-NMR spectrum of 3e 2. 5
16 Fig. -3. H-NMR spectrum of 3e 3. Fig C-NMR spectrum of 3e 3. 6
17 Fig. -5. H-NMR spectrum of 3e 4. Fig C-NMR spectrum of 3e 4. 7
18 Fig. -7. H-NMR spectrum of 3e 5. Fig C-NMR spectrum of 3e 5. 8
19 Fig. -9. H-NMR spectrum of 3e 6. Fig C-NMR spectrum of 3e 6. 9
20 Fig. -2. H-NMR spectrum of 3f. Fig C-NMR spectrum of 3f. 20
21 Fig H-NMR spectrum of 3f 2. Fig C-NMR spectrum of 3f 2. 2
22 Fig H-NMR spectrum of 3g. Fig C-NMR spectrum of 3g. 22
23 Fig H-NMR spectrum of 3g 2. Fig C-NMR spectrum of 3g 2. 23
24 Fig H-NMR spectrum of 3g 3. Fig C-NMR spectrum of 3g 3. 24
25 Fig. -3. H-NMR spectrum of 3g 4. Fig C-NMR spectrum of 3g 4. 25
26 Fig H-NMR spectrum of 3h. Fig C-NMR spectrum of 3h. 26
27 Fig H-NMR spectrum of 3i. Fig C-NMR spectrum of 3i. 27
28 Fig H-NMR spectrum of 3j. Fig C-NMR spectrum of 3j. 28
29 Fig H-NMR spectrum of 3k. Fig C-NMR spectrum of 3k. 29
30 Fig. -4. H-NMR spectrum of 3l. Fig C-NMR spectrum of 3l. 30
31 Fig H-NMR spectrum of 3m. Fig C-NMR spectrum of 3m. 3
32 Fig H-NMR spectrum of 3n. Fig C-NMR spectrum of 3n. 32
33 Fig H-NMR spectrum of 3o. Fig C-NMR spectrum of 3o. 33
34 Fig H-NMR spectrum of 3o 2. Fig C-NMR spectrum of 3o 2. 34
35 Fig. -5. H-NMR spectrum of 3o 3. Fig C-NMR spectrum of 3o 3. 35
36 Fig H-NMR spectrum of 3o 4. Fig C-NMR spectrum of 3o 4. 36
37 Fig H-NMR spectrum of 4a. Fig C-NMR spectrum of 4a. 37
Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:
Διαβάστε περισσότεραCopper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2016 Supporting information Copper-Catalyzed Oxidative Dehydrogenative - Bond Formation
Διαβάστε περισσότεραCopper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic
Διαβάστε περισσότεραA facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Διαβάστε περισσότεραSupporting Information
Supporting Information for Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Chun-Huan Jiang, Xiantao Lei,
Διαβάστε περισσότεραCopper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes
Supporting Information for Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes Yibiao Li* 1, Liang Cheng 1, Xiaohang Liu
Διαβάστε περισσότεραSupporting information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting information Copper-catalysed intramolecular O-arylation: a simple
Διαβάστε περισσότεραDirect Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3
Supporting Information Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Shohei Shimokawa, Yuhsuke Kawagoe, Katsuhiko Moriyama, Hideo Togo* Graduate
Διαβάστε περισσότεραRh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A. new Entry to N-Carbamate Protected Arylamines
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A new Entry to N-Carbamate Protected Arylamines Bing Zhou,* Juanjuan Du, Yaxi Yang,* Huijin Feng, Yuanchao Li Shanghai Institute of Materia Medica,
Διαβάστε περισσότεραand Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol
FeCl 3 6H 2 O-Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol Jialiang Wang, Wen Huang, Zhengxing Zhang, Xu
Διαβάστε περισσότεραThe N,S-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H. Carbonylation using Langlois Reagent as CO Source. Supporting Information.
Electronic upplementary Material (EI) for rganic & Biomolecular Chemistry. This journal is The Royal ociety of Chemistry 2018 The,-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H Carbonylation using
Διαβάστε περισσότεραSupporting Information
Supporting Information Copper/Silver Cocatalyzed Oxidative Coupling of Vinylarenes with ICH 2 CF 3 or ICH 2 CHF 2 Leading to β-cf 3 /CHF 2 -Substituted Ketones Niannian Yi, Hao Zhang, Chonghui Xu, Wei
Διαβάστε περισσότεραDirect Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines Min Jiang, Ting Li, Linghua Meng, Chunhao Yang,* Yuyuan Xie*, and Jian Ding State Key Laboratory of
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization
Διαβάστε περισσότεραSupporting Information for
Supporting Information for An atom-economic route to densely functionalized thiophenes via base-catalyzed rearrangement of 5-propargyl-2H-thiopyran-4(3H)-ones Chunlin Tang a, Jian Qin b, Xingqi Li *a a
Διαβάστε περισσότεραTributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate
upporting Information Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate Jing-Yu Wu, Zhi-Bin Luo, Li-Xin Dai and Xue-Long Hou* a tate Key Laboratory of Organometallic
Διαβάστε περισσότεραVilsmeier Haack reagent-promoted formyloxylation of α-chloro-narylacetamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Vilsmeier aack reagent-promoted formyloxylation of α-chloro-arylacetamides by formamide Jiann-Jyh
Διαβάστε περισσότεραSupporting Information
Supporting Information for AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds Qiuping Ding 1, Dan Wang 1, Puying Luo* 2, Meiling Liu 1, Shouzhi Pu* 3 and
Διαβάστε περισσότεραSupporting information
Electronic upplementary Material (EI) for New Journal of Chemistry. This journal is The Royal ociety of Chemistry and the Centre National de la Recherche cientifique 7 upporting information Lipase catalyzed,-addition
Διαβάστε περισσότεραSupporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process
Supporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process Jincan Zhao 1, Hong Fang 1, Jianlin Han* 1,2 and Yi Pan* 1
Διαβάστε περισσότεραSupporting Information
Supporting Information Lewis acid catalyzed ring-opening reactions of methylenecyclopropanes with diphenylphosphine oxide in the presence of sulfur or selenium Min Shi,* Min Jiang and Le-Ping Liu State
Διαβάστε περισσότεραSupporting Information. Asymmetric Binary-acid Catalysis with Chiral. Phosphoric Acid and MgF 2 : Catalytic
Supporting Information Asymmetric Binary-acid Catalysis with Chiral Phosphoric Acid and MgF 2 : Catalytic Enantioselective Friedel-Crafts Reactions of β,γ- Unsaturated-α-Ketoesters Jian Lv, Xin Li, Long
Διαβάστε περισσότεραSupporting Information One-Pot Approach to Chiral Chromenes via Enantioselective Organocatalytic Domino Oxa-Michael-Aldol Reaction
Supporting Information ne-pot Approach to Chiral Chromenes via Enantioselective rganocatalytic Domino xa-michael-aldol Reaction Hao Li, Jian Wang, Timiyin E-Nunu, Liansuo Zu, Wei Jiang, Shaohua Wei, *
Διαβάστε περισσότεραDivergent synthesis of various iminocyclitols from D-ribose
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 205 Divergent synthesis of various iminocyclitols from D-ribose Ramu Petakamsetty,
Διαβάστε περισσότεραHiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl
Hiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl Philippe Pierrat, Philippe Gros* and Yves Fort Synthèse Organométallique
Διαβάστε περισσότεραFluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3- Oxyfluorination and 1,3-Difluorination
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supporting Information Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine
Διαβάστε περισσότεραRoom Temperature Highly Diastereoselective Zn-Mediated. Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled
Supporting Information for: Room Temperature Highly Diastereoselective Zn-Mediated Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled Stereoselectivity Reversal
Διαβάστε περισσότεραElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Electronic Supplementary Information (ESI) For Iron-Catalysed xidative Amidation of Alcohols with Amines Silvia Gaspa, a Andrea
Διαβάστε περισσότεραSupporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2006
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2006 1 A Facile Way to Synthesize 2H-Chromenes: Reconsideration of the Reaction Mechanism between Salicylic Aldehyde and
Διαβάστε περισσότεραCopper-Catalyzed Oxidative Coupling of Acids with Alkanes Involving Dehydrogenation: Facile Access to Allylic Esters and Alkylalkenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary information Copper-Catalyzed xidative Coupling of Acids with Alkanes Involving Dehydrogenation:
Διαβάστε περισσότεραFree Radical Initiated Coupling Reaction of Alcohols and. Alkynes: not C-O but C-C Bond Formation. Context. General information 2. Typical procedure 2
Free Radical Initiated Coupling Reaction of Alcohols and Alkynes: not C-O but C-C Bond Formation Zhongquan Liu,* Liang Sun, Jianguo Wang, Jie Han, Yankai Zhao, Bo Zhou Institute of Organic Chemistry, Gannan
Διαβάστε περισσότεραSupporting Information
Supporting Information Selective Synthesis of xygen-containing Heterocycles via Tandem Reactions of 1,2-Allenic Ketones with Ethyl 4-Chloroacetoacetate Qiang Wang, a, b Zhouqing Xu b and Xuesen Fan a *
Διαβάστε περισσότεραKishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng Wu*
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 204 Kishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng
Διαβάστε περισσότεραNovel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information
Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans Liang Yun, Shi Tang, Xu-Dong Zhang, Li-Qiu Mao, Ye-Xiang Xie and Jin-Heng Li* Key Laboratory
Διαβάστε περισσότεραSupporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Anhydrous solvents were transferred by
Διαβάστε περισσότεραPhosphorus Oxychloride as an Efficient Coupling Reagent for the Synthesis of Ester, Amide and Peptide under Mild Conditions
Supplementary Information for Phosphorus xychloride as an Efficient Coupling Reagent for the Synthesis of Ester, Amide and Peptide under Mild Conditions u Chen,* a,b Xunfu Xu, a Liu Liu, a Guo Tang,* a
Διαβάστε περισσότεραSupporting Information
Supporting Information Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao
Διαβάστε περισσότεραSupporting Information
Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General
Διαβάστε περισσότεραSupporting Information
Supporting Information Wiley-VCH 2014 69451 Weinheim, Germany Copper-Catalyzed Coupling of Oxime Acetates with Sodium Sulfinates: An Efficient Synthesis of Sulfone Derivatives** Xiaodong Tang, Liangbin
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Silver or Cerium-Promoted Free Radical Cascade Difunctionalization
Διαβάστε περισσότεραLigand-free Cu(II)-mediated aerobic oxidations of aldehyde. hydrazones leading to N,N -diacylhydrazines and 1,3,4-oxadiazoles
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Ligand-free Cu(II)-mediated aerobic oxidations of aldehyde hydrazones leading
Διαβάστε περισσότεραSupporting Information. Table of Contents. II. Experimental procedures. II. Copies of 1H and 13C NMR spectra for all compounds
Electronic upplementary Material (EI) for rganic & Biomolecular Chemistry. This journal is The Royal ociety of Chemistry 2017 Laboratoire de Méthodologie et ynthèse de Produit aturels. Université du Québec
Διαβάστε περισσότεραSupporting Information for
Supporting Information for Palladium-Catalyzed C-H Bond Functionalization of C6-Arylpurines Hai-Ming Guo,* Wei-Hao Rao, Hong-Ying iu, Li-Li Jiang, Ge ng, Jia-Jia Jin, Xi-ing Yang, and Gui-Rong Qu* College
Διαβάστε περισσότεραSupporting Information
Supporting Information Ceric Ammonium Nitrate (CAN) catalyzed efficient one-pot three component aza-diels-alder reactions for a facile synthesis of tetrahydropyranoquinoline derivatives Ravinder Goud Puligoundla
Διαβάστε περισσότεραFirst DMAP-mediated direct conversion of Morita Baylis. Hillman alcohols into γ-ketoallylphosphonates: Synthesis of
Supporting Information File 1 for First DMAP-mediated direct conversion of Morita Baylis Hillman alcohols into γ-ketoallylphosphonates: Synthesis of γ-aminoallylphosphonates Marwa Ayadi 1,2, Haitham Elleuch
Διαβάστε περισσότεραSupporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Proton nuclear magnetic resonance ( 1
Διαβάστε περισσότεραEco-friendly synthesis of diverse and valuable 2-pyridones by catalyst- and solvent-free thermal multicomponent domino reaction
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 SUPPRTIG IFRMATI Eco-friendly synthesis of diverse and valuable 2-pyridones by catalyst-
Διαβάστε περισσότεραZuxiao Zhang, Xiaojun Tang and William R. Dolbier, Jr.* Department of Chemistry, University of Florida, Gainesville, FL
Photoredox-Catalyzed Intramolecular Difluoromethylation of -Benzylacrylamides Coupled with a Dearomatizing Spirocyclization: Access to CF2H Containing 2- Azaspiro[4.5]deca-6,9-diene-3,8-diones. Zuxiao
Διαβάστε περισσότεραCopper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols. Support Information
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols Dr. Xiao un Tang and Prof. Qing un Chen* Key Laboratory of Organofluorine Chemistry,
Διαβάστε περισσότεραHighly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces
Highly enantioselective cascade synthesis of spiropyrazolones Alex Zea a, Andrea-Nekane R. Alba a, Andrea Mazzanti b, Albert Moyano a and Ramon Rios a,c * Supporting Information NMR spectra and HPLC traces
Διαβάστε περισσότεραSupporting Information for Fe-Catalyzed Reductive Coupling of Unactivated Alkenes with. β-nitroalkenes. Contents. 1. General Information S2
Supporting Information for Fe-Catalyzed Reductive Coupling of Unactivated Alkenes with β-nitroalkenes Jing Zheng, Dahai Wang, and Sunliang Cui* College of Pharmaceutical Sciences, Zhejiang University,
Διαβάστε περισσότεραEnantioselective Organocatalytic Michael Addition of Isorhodanines. to α, β-unsaturated Aldehydes
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Enantioselective Organocatalytic Michael Addition of Isorhodanines to α,
Διαβάστε περισσότεραFacile construction of the functionalized 4H-chromene via tandem. benzylation and cyclization. Jinmin Fan and Zhiyong Wang*
Facile construction of the functionalized 4H-chromene via tandem benzylation and cyclization Jinmin Fan and Zhiyong Wang* Hefei National Laboratory for Physical Science at Microscale, Joint- Lab of Green
Διαβάστε περισσότεραRhodium-Catalyzed Oxidative Decarbonylative Heck-type Coupling of Aromatic Aldehydes with Terminal Alkenes
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Rhodium-Catalyzed Oxidative Decarbonylative Heck-type
Διαβάστε περισσότεραSite-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran
1 Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran Munawar Hussain, a Rasheed Ahmad Khera, a Nguyen Thai Hung, a Peter Langer* a,b a Institut für Chemie, Universität Rostock,
Διαβάστε περισσότεραmulticomponent synthesis of 5-amino-4-
Supporting Informartion for Molecular iodine-catalyzed one-pot multicomponent synthesis of 5-amino-4- (arylselanyl)-1h-pyrazoles Camila S. Pires 1, Daniela H. de Oliveira 1, Maria R. B. Pontel 1, Jean
Διαβάστε περισσότεραIodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via
Διαβάστε περισσότεραSupporting Information
Supporting Information Wiley-VC 007 9 Weinheim, Germany ew ear Infrared Dyes and Fluorophores Based on Diketopyrrolopyrroles Dipl.-Chem. Georg M. Fischer, Dipl.-Chem. Andreas P. Ehlers, Prof. Dr. Andreas
Διαβάστε περισσότεραSUPPORTING INFORMATION. Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts
S1 SUPPORTING INFORMATION Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts Hao Yu, Zhen Li, and Carsten Bolm* Institute of Organic Chemistry, RWTH Aachen University
Διαβάστε περισσότεραSupporting Information
ynthesis of ubstituted Benzothiazoles via Copper-Catalyzed Condensation of 2-Aminobenzenethiols with itriles Yadong un,, Huanfeng Jiang,*, Wanqing Wu, Wei Zeng, Xia Wu chool of Chemistry and Chemical Engineering,
Διαβάστε περισσότεραAminofluorination of Fluorinated Alkenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Synthesis of ɑ CF 3 and ɑ CF 2 H Amines via Aminofluorination of Fluorinated Alkenes Ling Yang,
Διαβάστε περισσότεραSupporting Information
Supporting Information Copper-Catalyzed Sulfonamides Formation from Sodium Sulfinates and Amines Xiaodong Tang, Liangbin Huang, Chaorong Qi, Xia Wu, Wanqing Wu, and Huanfeng Jiang* School of Chemistry
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information 1. General experimental methods (S2). 2. Table 1: Initial studies (S2-S4).
Διαβάστε περισσότεραSupporting Information
Supporting Information An Approach to 3,6-Disubstituted 2,5-Dioxybenzoquinones via Two Sequential Suzuki Couplings. Three-step Synthesis of Leucomelone Xianwen Gan, Wei Jiang, Wei Wang,,,* Lihong Hu,,*
Διαβάστε περισσότεραEfficient and Simple Zinc mediated Synthesis of 3 Amidoindoles
Electronic Supplementary Material (ESI) for rganic and Biomolecular Chemistry SUPPRTIG IFRMATI Efficient and Simple Zinc mediated Synthesis of 3 Amidoindoles Anahit Pews-Davtyan and Matthias Beller* Leibniz-Institut
Διαβάστε περισσότεραgem-dichloroalkenes for the Construction of 3-Arylchromones
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Pd(OAc)2/S=PPh3 Accelerated Activation of gem-dichloroalkenes for the Construction of 3-Arylchromones
Διαβάστε περισσότεραJing-Yu Guo, Rui-Han Dai, Wen-Cong Xu, Ruo-Xin Wu and Shi-Kai Tian*
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 TfNHNHBoc as a SCF 3 source in the sulfenylation of indoles Jing-Yu Guo, Rui-Han Dai, Wen-Cong
Διαβάστε περισσότεραThe Free Internet Journal for Organic Chemistry
The Free Internet Journal for Organic Chemistry Paper Archive for Organic Chemistry Arkivoc 2018, part iii, S1-S6 Synthesis of dihydropyranones and dihydropyrano[2,3- d][1,3]dioxine-diones by cyclization
Διαβάστε περισσότεραCatalyst-free transformation of levulinic acid into pyrrolidinones with formic acid
Catalyst-free transformation of levulinic acid into pyrrolidinones with formic acid Yawen Wei, a Chao Wang,* a Xue Jiang, a Dong Xue, a Zhao-Tie Liu, a and Jianliang Xiao* a,b a Key Laboratory of Applied
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for rganic Chemistry Frontiers. This journal is the Partner rganisations 2018 Palladium-catalyzed direct approach to α-cf 3 aryl ketones from arylboronic acids Bo
Διαβάστε περισσότεραSupplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%. S1 Supplementary Figure S2. Single X-ray structure 5a at probability ellipsoids of 20%. S2 H 15 Ph Ac Ac I AcH Ph Ac
Διαβάστε περισσότεραLewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes
Supporting Information for Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes Changkun Li and Jianbo Wang* Beijing National Laboratory
Διαβάστε περισσότεραSupporting Information. Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles
Supporting Information for Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles Angélica de Fátima S. Barreto*, Veronica Alves dos Santos, and Carlos
Διαβάστε περισσότεραSupporting Information
Supporting Information 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
Διαβάστε περισσότεραSequential catalysis for the production of sterically hindered amines: Ruthenium(II)-catalyzed C-H bond activation and hydrosilylation of imines
Electronic Supporting Information Sequential catalysis for the production of sterically hindered amines: Ruthenium(II)-catalyzed C- bond activation and hydrosilylation of imines Bin Li, Charles B. Bheeter,
Διαβάστε περισσότεραSupplementary Material
Supplementary Material Control experiments S2 Characterization data for the products S2-S7 References S8 MR spectra for the products S9-S28 S1 Control experiments 2a (99.5 mg, 0.5 mmol), I 2 (50.8 mg,
Διαβάστε περισσότεραSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2017 Modular Synthesis of Propargylamine Modified Cyclodextrins by a Gold(III)-catalyzed Three Component
Διαβάστε περισσότεραSupporting Information for Synthesis of Fused N-Heterocycles via Tandem C-H Activation
This journal is The Royal Society of Chemistry 212 Supporting Information for Synthesis of Fused -Heterocycles via Tandem C-H Activation Ge Meng, Hong-Ying iu, Gui-Rong Qu, John S. Fossey, Jian-Ping Li,*
Διαβάστε περισσότεραESI for. A simple and efficient protocol for the palladium-catalyzed. ligand-free Suzuki reaction at room temperature in aqueous DMF.
ESI for A simple and efficient protocol for the palladium-catalyzed ligand-free Suzuki reaction at room temperature in aqueous DMF Chun Liu,* Qijian i, Fanying Bao and Jieshan Qiu State Key Laboratory
Διαβάστε περισσότεραSupporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2007
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 6945 Weinheim, 2007 A New Method for Constructing Quaternary Carbon Centres: Tandem Rhodium-Catalysed,4-Addition/Intramolecular Cyclization.
Διαβάστε περισσότεραSupplementary Data. Engineering, Nanjing University, Nanjing , P. R. China;
Supplementary Data Synthesis, Chemo-selective Properties of Substituted 9-Aryl-9H-fluorenes from Triarylcarbinols and Enantiomerical Kinetics of Chiral 9-Methoxy-11-(naphthalen-1-yl)-11H-benzo[a]fluorene
Διαβάστε περισσότεραSupporting Materials
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Carbonylative Coupling of Aryl Tosylates/triflates with Arylboronic Acids under CO Atmosphere
Διαβάστε περισσότεραNew excited state intramolecular proton transfer (ESIPT) dyes based on naphthalimide and observation of triplet excited states
Electronic upplementary Material (EI) for Chemical Communications This journal is The Royal ociety of Chemistry 2012 Electronic upplementary Information for: ew excited state intramolecular proton transfer
Διαβάστε περισσότεραSupporting Information for
Supporting Information for A ovel Synthesis of luorinated Pyrazoles via Gold(I)-Catalyzed Tandem Aminofluorination of Alkynes in the Presence of Selectfluor Jianqiang Qian, Yunkui Liu,* Jie Zhu, Bo Jiang,
Διαβάστε περισσότεραSupporting Information
S1 Supporting Information Synthesis of 2-Arylated Hydroxytyrosol Derivatives via Suzuki-Myaura Cross-Coupling Roberta Bernini, a Sandro Cacchi, b* Giancarlo Fabrizi, b* Eleonora Filisti b a Dipartimento
Διαβάστε περισσότεραSupporting Information
Supporting Information Rhodium-catalyzed Intramolecular Dehydrogenative Aryl Aryl Coupling Using Air as Terminal Oxidant Hannah Baars, 1,2 Yuto Unoh, 1 Takeshi Okada, 1 Koji Hirano, 1 Tetsuya Satoh,* 1,3
Διαβάστε περισσότεραSupporting Information
Supporting Information Metal-catalyzed Stereoselective and Protecting-group-free Synthesis of 1,2-cis-Glycosides Using 4,6-Dimethoxy-1,3,5-triazin-2-yl Glycosides as Glycosyl Donors Tomonari Tanaka,* 1
Διαβάστε περισσότεραSupporting Information. for. Highly Selective Hydroiodation of Alkynes Using. Iodine-Hydrophosphine Binary System
Supporting Information for Highly Selective Hydroiodation of Alkynes Using Iodine-Hydrophosphine Binary System Shin-ichi Kawaguchi and Akiya Ogawa * Department of Applied Chemistry, Graduate School of
Διαβάστε περισσότεραSynthesis and evaluation of novel aza-caged Garcinia xanthones
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Synthesis and evaluation of novel aza-caged Garcinia xanthones Xiaojin Zhang, a,1 Xiang Li, a,1 Haopeng Sun, * b Zhengyu Jiang,
Διαβάστε περισσότεραPd Catalyzed Carbonylation for the Construction of Tertiary and
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Pd Catalyzed Carbonylation for the Construction of Tertiary and Quaternary
Διαβάστε περισσότεραRegioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone.
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone. Won-Suk Kim, Hyung-Jin Kim and Cheon-Gyu Cho Department of Chemistry, Hanyang University, Seoul 133-791, Korea Experimental Section
Διαβάστε περισσότεραOne-pot β-substitution of enones with alkyl groups to β-alkyl enones
Electronic Supplementary Information ne-pot β-substitution of enones with alkyl groups to β-alkyl enones Jun-ichi Matsuo* and Yayoi Aizawa Center for Basic Research, The Kitasato Institute, 1-15-1-S105,
Διαβάστε περισσότεραSupporting Information. Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors
Supporting Information Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors Frédéric Pin, a Frédéric Buron, a Fabienne Saab, a Lionel Colliandre,
Διαβάστε περισσότεραSelective mono reduction of bisphosphine
Griffith Research Online https://research-repository.griffith.edu.au Selective mono reduction of bisphosphine oxides under mild conditions Author etersson, Maria, Loughlin, Wendy, Jenkins, Ian ublished
Διαβάστε περισσότεραSupporting Information for. Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds
Supporting Information for Catalytic C H α-trifluoromethylation of α,β-unsaturated Carbonyl Compounds Zhongxue Fang, a Yongquan Ning, a Pengbing Mi, a Peiqiu Liao, a Xihe Bi* a,b a Department of Chemistry,
Διαβάστε περισσότεραSupporting Information
1 upporting Information Rhodium(III)-Catalyzed rtho Halogenations of N-Acylsulfoximines and ynthetic Applications toward Functionalized ulfoximine Derivatives Ying Cheng, Wanrong Dong, Kanniyappan Parthasarathy,
Διαβάστε περισσότεραElectronic Supplementary Information
Electronic Supplementary Information NbCl 3 -catalyzed [2+2+2] intermolecular cycloaddition of alkynes and alkenes to 1,3-cyclohexadiene derivatives Yasushi Obora,* Keisuke Takeshita and Yasutaka Ishii*
Διαβάστε περισσότεραKOtBu-Mediated Stereoselective Addition of Quinazolines to. Alkynes under Mild Conditions
KOtBu-Mediated Stereoselective Addition of Quinazolines to Alkynes under Mild Conditions Dan Zhao, Qi Shen, Yu-Ren Zhou, and Jian-Xin Li* State Key lab of Analytical Chemistry for Life Science, School
Διαβάστε περισσότεραFerric(III) Chloride Catalyzed Halogenation Reaction of Alcohols and Carboxylic Acids using - Dichlorodiphenylmethane
Supporting Information Ferric(III) Chloride Catalyzed Halogenation Reaction of Alcohols and Carboxylic Acids using - Dichlorodiphenylmethane Chang-Hee Lee,, Soo-Min Lee,, Byul-Hana Min, Dong-Su Kim, Chul-Ho
Διαβάστε περισσότερα