Supporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process
|
|
|
- θάνα Δράκος
- 5 χρόνια πριν
- Προβολές:
Transcript
1 Supporting Information for Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinylic carboxylic acids via a radical process Jincan Zhao 1, Hong Fang 1, Jianlin Han* 1,2 and Yi Pan* 1 Address: 1 School of Chemistry and Chemical Engineering, State of Key Laboratory of Coordination, Nanjing University, Nanjing, , China and 2 Institute for Chemistry & BioMedical Sciences, Nanjing University, Nanjing, , China Jianlin Han* - hanjl@nju.edu.cn; Yi Pan* - yipan@nju.edu.cn *Corresponding author Experimental details and spectral data Index 1. Experimental Section...S2 General Information...S2 General Procedure...S2 2. Characterization data for compounds 3a p and 4a f...s H and 13 C NMR spectra 3a p and 4a f...s9 4. References...S31 S1
2 1. Experimental Section General Information: All reactions were carried out under a nitrogen atmosphere. Column chromatography was carried out on silica gel ( mesh). Analytical thin layer chromatography (TLC) was performed on glass plates of Silica Gel GF-254 with detection by UV light. Standard techniques for synthesis under inert gas atmosphere by using gasbag and Schlenk glassware equipped with an 8 mm PTFE vacuum stop-cock (Synthware) were employed. All starting materials and reagents were commercially available. 1 H and 13 C NMR spectra were recorded on a Bruker AVANCE400M spectrometer. The chemical shift references were as follows: ( 1 H) CDCl 3, 7.26 ppm (CHCl 3 ); ( 13 C) CDCl 3, ppm (CDCl 3 ). HRMS spectra were carried out at Micromass GCT (TOF MS EI + ). Melting points were determined on a Melt-Temp apparatus (X-4) from Beijing Fukai Electro-optic Instrument Plant and are uncorrected. General Procedure: To a Schlenk tube equipped with a magnetic stir bar were added Fe(acac) 3 (21.2 mg, 0.06 mmol) and cinnamic acid (0.3 mmol) under a nitrogen atmosphere. Cycloalkane (2.0 ml, mmol) and DTBP (di-tert-butyl peroxide, 0.6 mmol, 113 μl) were added under nitrogen and the resulting reaction mixture was kept stirring at 120 C for 24 h. After cooling to room temperature and removal of volatiles the products were isolated by flash column chromatography (PE). Products 3a, 3e, 3h, 3j, 3k, 3p, 4a, 4c, 4e, 4f, 3b, 3l, 3d, 3n and 4b, are known compounds. 1 H and 13 C NMR spectra of these compounds have been confirmed to be identical to those of known samples (3a, 3e, 3h, 3j, 3k, 3p, 4a, 4c, 4e and 4f) [1], (3b and 3l) [2], 3d [3], 3n [4], 4b [5]). S2
3 2. Characterization data for 3a p and 4a f. (E)-(2-Cyclohexylvinyl)benzene(3a, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 4H), (m, 1H), 6.32 (d, J = 16.1 Hz, 1H), 6.15 (dd, J = 16.0, 6.9 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.12, 32.93, 26.16, (E)-1-(2-Cyclohexylvinyl)-4-methylbenzene(3b, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.22 (d, J = 8.1 Hz, 2H), 7.06 (d, J = 8.0 Hz, 2H), 6.29 (d, J = 16.0 Hz, 1H), 6.10 (dd, J = 16.0, 6.9 Hz, 1H), 2.29 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.11, 33.01, 26.19, 26.06, (E)-1-(2-Cyclohexylvinyl)-3-methylbenzene(3c): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 3H), (m, 1H), 6.29 (d, J = 16.0 Hz, 1H), 6.13 (dd, J = 16.0, 6.9 Hz, 1H), 2.29 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , 41.14, 32.97, 26.17, 26.04, HRMS (TOF MS EI + ) m/z calcd for [C 15 H 20 ] , found (E)-1-(2-Cyclohexylvinyl)-2-methylbenzene(3d, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.63 (d, J = 7.0 Hz, 1H), (m, 3H), 6.77 (d, J = 15.8 Hz, 1H), 6.26 (dd, J = 15.8, 7.0 Hz, 1H), 2.54 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , S3
4 41.43, 33.08, 26.18, 26.05, (E)-1-(2-Cyclohexylvinyl)-4-methoxybenzene(3e, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.17 (d, J = 8.7 Hz, 1H), 6.72 (d, J = 8.7 Hz, 1H), 6.19 (d, J = 16.0 Hz, 1H), 5.94 (dd, J = 16.0, 6.9 Hz, 1H), 3.67 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 55.15, 41.07, 33.06, 26.17, (E)-1-(2-Cyclohexylvinyl)-3-methoxybenzene(3f): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.18 (t, J = 7.9 Hz, 1H), (m, 2H), 6.72 (dd, J = 8.1, 2.1 Hz, 1H), 6.30 (d, J = 16.0 Hz, 1H), 6.16 (dd, J = 16.0, 6.8 Hz, 1H), 3.78 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , 55.07, 41.08, 32.89, 26.14, HRMS (TOF MS EI + ) m/z calcd for [C 15 H 20 O] , found (E)-1-(2-Cyclohexylvinyl)-2-methoxybenzene(3g): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.41 (dd, J = 7.6, 1.1 Hz, 1H), 7.14 (ddd, J = 8.8, 7.7, 1.1 Hz, 1H), 6.87 (t, J = 7.4 Hz, 1H), 6.80 (d, J = 8.2 Hz, 1H), 6.69 (d, J = 16.1 Hz, 1H), 6.14 (dd, J = 16.1, 7.0 Hz, 1H), 3.78 (s, 3H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , 55.31, 41.53, 33.04, 26.17, HRMS (TOF MS EI + ) m/z calcd for [C 15 H 20 O] , found (E)-1-(2-Cyclohexylvinyl)-4-fluorobenzene(3h, known compound): White solid, mp C, 1 H NMR (400 MHz, CDCl 3 ) δ 7.50 (d, J = 8.2 Hz, 2H), 7.38 (d, J = 8.2 Hz, 2H), 6.34 (d, J = 16.1 Hz, 1H), 6.25 (dd, J = 16.0, 6.6 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ (d, J = 1.2 Hz), , (d, J = 32.3 Hz), , , (q, J = 3.9 Hz), 41.23, 32.76, 26.12, S4
5 (E)-1-(2-Cyclohexylvinyl)-3-fluorobenzene(3i): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.20 (td, J = 7.9, 6.1 Hz, 1H), 7.04 (ddd, J = 10.4, 8.1, 4.8 Hz, 2H), (m, 1H), 6.29 (d, J = 16.0 Hz, 1H), 6.16 (dd, J = 15.9, 6.8 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ (d, J = Hz), (d, J = 7.7 Hz), , (d, J = 8.5 Hz), (d, J = 2.5 Hz), (d, J = 2.6 Hz), (d, J = 21.4 Hz), (d, J = 21.7 Hz), 41.08, 32.81, 26.12, HRMS (TOF MS EI + ) m/z calcd for [C 14 H 17 F] , found (E)-1-(2-Cyclohexylvinyl)-2-fluorobenzene(3j, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 1H), (m, 3H), 6.50 (d, J = 16.2 Hz, 1H), 6.22 (dd, J = 16.1, 7.0 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ (d, J = Hz), (d, J = 4.1 Hz), (d, J = 8.3 Hz), (d, J = 4.0 Hz), (d, J = 12.3 Hz), (d, J = 3.5 Hz), (d, J = 3.9 Hz), (d, J = 22.3 Hz), 41.52, 32.84, 26.14, (E)-1-Chloro-4-(2-cyclohexylvinyl)benzene(3k, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 4H), 6.27 (d, J = 16.0, 1H), 6.13 (dd, J = 16.0, 6.8 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.10, 32.84, 26.12, (E)-1-Chloro-2-(2-cyclohexylvinyl)benzene(3l, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.47 (dd, J = 7.7, 1.4 Hz, 1H), 7.29 (dd, J = 7.9, 1.1 Hz, 1H), (m, 2H), 6.72 (d, J = 15.9 Hz, 1H), 6.13 (dd, J = 15.9, 7.0 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , 41.31, 32.83, 26.13, S5
6 (E)-1,3-Dichloro-2-(2-cyclohexylvinyl)benzene(3m): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.25 (d, J = 8.0 Hz, 2H), 7.00 (t, J = 8.0 Hz, 1H), 6.28 (d, J = 16.4 Hz, 1H), 6.14 (dd, J = 16.3, 6.7 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.52, 32.51, 26.17, HRMS (TOF MS EI + ) m/z calcd for [C 14 H 16 Cl 2 ] , found Br (E)-1-Bromo-4-(2-cyclohexylvinyl)benzene (3n, known compound): White solid, mp C, 1 H NMR (400 MHz, CDCl 3 ) δ 7.36 (d, J = 8.5 Hz, 2H), 7.16 (d, J = 8.4 Hz, 2H), 6.25 (d, J = 16.1 Hz, 1H), 6.13 (dd, J = 16.0, 6.7 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.08, 32.79, 26.11, (E)-1-(2-Cyclohexylvinyl)-3-(trifluoromethyl)benzene(3o): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.57 (s, 1H), (m, 3H), 6.34 (d, J = 16.1 Hz, 1H), 6.22 (dd, J = 16.0, 6.7 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ (d, J = 13.6 Hz), (q, J = 32.0 Hz), (d, J = 1.1 Hz), , , , (q, J = 3.8 Hz), , (q, J = 3.8 Hz), 41.19, 32.81, 26.13, HRMS (TOF MS EI + ) m/z calcd for [C 15 H 17 F 3 ] , found (E)-2-(2-Cyclohexylvinyl)thiophene(3p, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.04 (d, J = 5.1 Hz, 1H), 6.90 (dd, J = 5.1, 3.5 Hz, 1H), 6.84 (d, J = 3.6 Hz, 1H), 6.45 (d, J = 15.8 Hz, 1H), 6.01 (dd, J = 15.8, 6.9 Hz, 1H), (m, 1H), (m, 5H), (m, 5H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 40.89, 32.77, 26.11, S6
7 (E)-(2-Cyclopentylvinyl)benzene(4a, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), 7.25 (dd, J = 10.4, 4.9 Hz, 2H), 7.14 (ddd, J = 8.5, 2.5, 1.2 Hz, 1H), 6.35 (d, J = 15.9 Hz, 1H), 6.18 (dd, J = 15.8, 7.7 Hz, 1H), (m, 1H), (m, 2H), (m, 4H), (m, 2H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 43.78, 33.18, (E)-1-(2-Cyclopentylvinyl)-4-methylbenzene(4b, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.48 (d, J = 6.5 Hz, 2H), 7.32 (d, J = 7.5 Hz, 2H), 6.59 (d, J = 15.8 Hz, 1H), 6.39 (ddd, J = 15.8, 7.7, 1.7 Hz, 1H), (m, 1H), 2.55 (s, 3H), (m, 8H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 43.78, 33.20, 25.19, (E)-1-(2-Cyclopentylvinyl)-4-fluorobenzene(4c): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), (m, 2H), 6.31 (d, J = 15.8 Hz, 1H), 6.09 (dd, J = 15.8, 7.8 Hz, 1H), (m, 1H), (m, 48H). 13 C NMR (100 MHz, CDCl 3 ) δ (d, J = Hz), (d, J = 2.2 Hz), (d, J = 3.2 Hz), (d, J = 7.8 Hz), , (d, J = 21.4 Hz), 43.75, 33.19, HRMS (TOF MS EI + ) m/z calcd for [C 13 H 15 F] , found (E)-1-Chloro-2-(2-cyclopentylvinyl)benzene(4d): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.31 (s, 1H), (m, 3H), 6.27 (d, J = 15.8 Hz, 1H), 6.18 (dd, J = 15.8, 7.4 Hz, 1H), (m, 1H), (m, 8H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , , , 43.71, 33.09, HRMS (TOF MS EI + ) m/z calcd for [C 13 H 15 Cl] , found S7
8 (E)-Styrylcycloheptane(4e, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ 7.31 (dd, J = 8.3, 1.1 Hz, 2H), 7.25 (dd, J = 10.4, 4.9 Hz, 2H), (m, 1H), 6.30 (d, J = 16.0 Hz, 1H), 6.19 (dd, J = 15.9, 7.4 Hz, 1H), (m, 1H), (m, 2H), (m, 10H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 43.20, 34.71, 28.38, (E)-Styrylcyclooctane(4f, known compound): Colorless oil, 1 H NMR (400 MHz, CDCl 3 ) δ (m, 2H), 7.24 (dd, J = 10.4, 4.9 Hz, 2H), 7.13 (dd, J = 10.2, 4.3 Hz, 1H), 6.30 (d, J = 16.0 Hz, 1H), 6.18 (dd, J = 15.9, 7.4 Hz, 1H), (m, 1H), (m, 14H). 13 C NMR (100 MHz, CDCl 3 ) δ , , , , , , 41.29, 31.83, 27.43, 25.98, S8
9 3. 1 H and 13 C NMR spectra 1 H- and 13 C NMR of 3a S9
10 1 H- and 13 C NMR of 3b S10
11 1 H- and 13 C NMR of 3c S11
12 1 H- and 13 C NMR of 3d S12
13 1 H- and 13 C NMR of 3e S13
14 1 H- and 13 C NMR of 3f S14
15 1 H- and 13 C NMR of 3g S15
16 1 H- and 13 C NMR of 3h S16
17 1 H- and 13 C NMR of 3i S17
18 1 H- and 13 C NMR of 3j S18
19 1 H- and 13 C NMR of 3k S19
20 1 H- and 13 C NMR of 3l S20
21 1 H- and 13 C NMR of 3m S21
22 1 H- and 13 C NMR of 3n S22
23 1 H- and 13 C NMR of 3o S23
24 1 H- and 13 C NMR of 3p S24
25 1 H- and 13 C NMR of 4a S25
26 1 H- and 13 C NMR of 4b S26
27 1 H- and 13 C NMR of 4c S27
28 1 H- and 13 C NMR of 4d S28
29 1 H- and 13 C NMR of 4e S29
30 1 H- and 13 C NMR of 4f S30
31 4. References 1. Jang, Y.-J.; Shih, Y.-K.; Liu, J.-Y.; Kuo, W.-Y.; Yao, C.-F. Chem. Eur. J. 2003, 9, Ikeda, Y.; Nakamura, T.; Yorimitsu, H.; Oshima, K., J. Am. Chem. Soc. 2002, 124, Yao, Q.; Kinney, E. P.; Yang, Z., J. Org. Chem. 2003, 68, Loeffler, L. J. and Delorefice, S. B., J. Pharm. Sci. 1975, 64, Ishikawa, T.; Nonaka, S.; Hirao, T., Chem. Commun. 1998, S31
A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes
Supporting Information
Supporting Information for Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Chun-Huan Jiang, Xiantao Lei,
Supporting Information
Supporting Information for AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds Qiuping Ding 1, Dan Wang 1, Puying Luo* 2, Meiling Liu 1, Shouzhi Pu* 3 and
Supporting Information
Supporting Information Lewis acid catalyzed ring-opening reactions of methylenecyclopropanes with diphenylphosphine oxide in the presence of sulfur or selenium Min Shi,* Min Jiang and Le-Ping Liu State
Copper-Catalyzed Oxidative Dehydrogenative N-N Bond. Formation for the Synthesis of N,N -Diarylindazol-3-ones
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2016 Supporting information Copper-Catalyzed Oxidative Dehydrogenative - Bond Formation
Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3
Supporting Information Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I 2 -aq NH 3 Shohei Shimokawa, Yuhsuke Kawagoe, Katsuhiko Moriyama, Hideo Togo* Graduate
Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic acids with the assistance of isocyanide
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Copper-catalyzed formal O-H insertion reaction of α-diazo-1,3-dicarb- onyl compounds to carboxylic
Electronic Supplementary Information
Electronic Supplementary Information Unprecedented Carbon-Carbon Bond Cleavage in Nucleophilic Aziridine Ring Opening Reaction, Efficient Ring Transformation of Aziridines to Imidazolidin-4-ones Jin-Yuan
Supporting Information
Supporting Information Montmorillonite KSF-Catalyzed One-pot, Three-component, Aza-Diels- Alder Reactions of Methylenecyclopropanes With Arylaldehydes and Aromatic Amines Li-Xiong Shao and Min Shi* General
Supporting Information. Asymmetric Binary-acid Catalysis with Chiral. Phosphoric Acid and MgF 2 : Catalytic
Supporting Information Asymmetric Binary-acid Catalysis with Chiral Phosphoric Acid and MgF 2 : Catalytic Enantioselective Friedel-Crafts Reactions of β,γ- Unsaturated-α-Ketoesters Jian Lv, Xin Li, Long
Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information
![Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information](/thumbs/64/50937700.jpg "Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans. Supporting Information")
Novel and Selective Palladium-Catalyzed Annulation of 2-Alkynylphenols to Form 2-Substituted 3-Halobenzo[b]furans Liang Yun, Shi Tang, Xu-Dong Zhang, Li-Qiu Mao, Ye-Xiang Xie and Jin-Heng Li* Key Laboratory
Free Radical Initiated Coupling Reaction of Alcohols and. Alkynes: not C-O but C-C Bond Formation. Context. General information 2. Typical procedure 2
Free Radical Initiated Coupling Reaction of Alcohols and Alkynes: not C-O but C-C Bond Formation Zhongquan Liu,* Liang Sun, Jianguo Wang, Jie Han, Yankai Zhao, Bo Zhou Institute of Organic Chemistry, Gannan
Supporting Information
Supporting Information Copper/Silver Cocatalyzed Oxidative Coupling of Vinylarenes with ICH 2 CF 3 or ICH 2 CHF 2 Leading to β-cf 3 /CHF 2 -Substituted Ketones Niannian Yi, Hao Zhang, Chonghui Xu, Wei
Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes
Supporting Information for Lewis Acid Catalyzed Propargylation of Arenes with O-Propargyl Trichloroacetimidate: Synthesis of 1,3-Diarylpropynes Changkun Li and Jianbo Wang* Beijing National Laboratory
Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2006
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2006 1 A Facile Way to Synthesize 2H-Chromenes: Reconsideration of the Reaction Mechanism between Salicylic Aldehyde and
Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate
upporting Information Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate Jing-Yu Wu, Zhi-Bin Luo, Li-Xin Dai and Xue-Long Hou* a tate Key Laboratory of Organometallic
Metal-free Oxidative Coupling of Amines with Sodium Sulfinates: A Mild Access to Sulfonamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting information for Metal-free Oxidative Coupling of Amines with Sodium Sulfinates:
Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces
Highly enantioselective cascade synthesis of spiropyrazolones Alex Zea a, Andrea-Nekane R. Alba a, Andrea Mazzanti b, Albert Moyano a and Ramon Rios a,c * Supporting Information NMR spectra and HPLC traces
Supporting information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting information Copper-catalysed intramolecular O-arylation: a simple
Supporting Information
Supporting Information Ceric Ammonium Nitrate (CAN) catalyzed efficient one-pot three component aza-diels-alder reactions for a facile synthesis of tetrahydropyranoquinoline derivatives Ravinder Goud Puligoundla
Supporting Information for
Supporting Information for Palladium-Catalyzed C-H Bond Functionalization of C6-Arylpurines Hai-Ming Guo,* Wei-Hao Rao, Hong-Ying iu, Li-Li Jiang, Ge ng, Jia-Jia Jin, Xi-ing Yang, and Gui-Rong Qu* College
Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran
1 Site-Selective Suzuki-Miyaura Cross-Coupling Reactions of 2,3,4,5-Tetrabromofuran Munawar Hussain, a Rasheed Ahmad Khera, a Nguyen Thai Hung, a Peter Langer* a,b a Institut für Chemie, Universität Rostock,
SUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 SUPPORTIG IFORMATIO Visible light-mediated decarboxylative amination of indoline-2- carboxylic
Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes
![Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes](/thumbs/61/45469742.jpg "Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes")
Supporting Information for Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: from alkynes to benzo[b]furans and benzo[b]thiophenes Yibiao Li* 1, Liang Cheng 1, Xiaohang Liu
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Silver or Cerium-Promoted Free Radical Cascade Difunctionalization
and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol
FeCl 3 6H 2 O-Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol Jialiang Wang, Wen Huang, Zhengxing Zhang, Xu
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A. new Entry to N-Carbamate Protected Arylamines
Rh(III)-Catalyzed C-H Amidation with N-hydroxycarbamates: A new Entry to N-Carbamate Protected Arylamines Bing Zhou,* Juanjuan Du, Yaxi Yang,* Huijin Feng, Yuanchao Li Shanghai Institute of Materia Medica,
Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine Reagents. An Efficient Method for 1,3- Oxyfluorination and 1,3-Difluorination
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supporting Information Fluorinative Ring-opening of Cyclopropanes by Hypervalent Iodine
Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via
Supporting Information
Electronic upplementary Material (EI) for Green Chemistry. This journal is The Royal ociety of Chemistry 204 upporting Information ynthesis of sulfonamides via I 2 -mediated reaction of sodium sulfinates
Eco-friendly synthesis of diverse and valuable 2-pyridones by catalyst- and solvent-free thermal multicomponent domino reaction
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 SUPPRTIG IFRMATI Eco-friendly synthesis of diverse and valuable 2-pyridones by catalyst-
The N,S-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H. Carbonylation using Langlois Reagent as CO Source. Supporting Information.
Electronic upplementary Material (EI) for rganic & Biomolecular Chemistry. This journal is The Royal ociety of Chemistry 2018 The,-Bidentate Ligand Assisted Pd-Catalyzed C(sp 2 )-H Carbonylation using
Supporting Information. Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles
Supporting Information for Consecutive hydrazino-ugi-azide reactions: synthesis of acylhydrazines bearing 1,5- disubstituted tetrazoles Angélica de Fátima S. Barreto*, Veronica Alves dos Santos, and Carlos
The Free Internet Journal for Organic Chemistry
The Free Internet Journal for Organic Chemistry Paper Archive for Organic Chemistry Arkivoc 2018, part iii, S1-S6 Synthesis of dihydropyranones and dihydropyrano[2,3- d][1,3]dioxine-diones by cyclization
Copper-Catalyzed Oxidative Coupling of Acids with Alkanes Involving Dehydrogenation: Facile Access to Allylic Esters and Alkylalkenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary information Copper-Catalyzed xidative Coupling of Acids with Alkanes Involving Dehydrogenation:
Hiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl
Hiyama Cross-Coupling of Chloro-, Fluoroand Methoxy- pyridyl trimethylsilanes : Room-temperature Novel Access to Functional Bi(het)aryl Philippe Pierrat, Philippe Gros* and Yves Fort Synthèse Organométallique
Supporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Proton nuclear magnetic resonance ( 1
Supporting Information One-Pot Approach to Chiral Chromenes via Enantioselective Organocatalytic Domino Oxa-Michael-Aldol Reaction
Supporting Information ne-pot Approach to Chiral Chromenes via Enantioselective rganocatalytic Domino xa-michael-aldol Reaction Hao Li, Jian Wang, Timiyin E-Nunu, Liansuo Zu, Wei Jiang, Shaohua Wei, *
Electronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Electronic Supplementary Information (ESI) For Iron-Catalysed xidative Amidation of Alcohols with Amines Silvia Gaspa, a Andrea
ESI for. A simple and efficient protocol for the palladium-catalyzed. ligand-free Suzuki reaction at room temperature in aqueous DMF.
ESI for A simple and efficient protocol for the palladium-catalyzed ligand-free Suzuki reaction at room temperature in aqueous DMF Chun Liu,* Qijian i, Fanying Bao and Jieshan Qiu State Key Laboratory
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols. Support Information
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with phenols or thiophenols Dr. Xiao un Tang and Prof. Qing un Chen* Key Laboratory of Organofluorine Chemistry,
Facile construction of the functionalized 4H-chromene via tandem. benzylation and cyclization. Jinmin Fan and Zhiyong Wang*
Facile construction of the functionalized 4H-chromene via tandem benzylation and cyclization Jinmin Fan and Zhiyong Wang* Hefei National Laboratory for Physical Science at Microscale, Joint- Lab of Green
Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines
![Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines](/thumbs/87/95187440.jpg "Direct Palladium-Catalyzed Arylations of Aryl Bromides. with 2/9-Substituted Pyrimido[5,4-b]indolizines")
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines Min Jiang, Ting Li, Linghua Meng, Chunhao Yang,* Yuyuan Xie*, and Jian Ding State Key Laboratory of
Supporting Information for Fe-Catalyzed Reductive Coupling of Unactivated Alkenes with. β-nitroalkenes. Contents. 1. General Information S2
Supporting Information for Fe-Catalyzed Reductive Coupling of Unactivated Alkenes with β-nitroalkenes Jing Zheng, Dahai Wang, and Sunliang Cui* College of Pharmaceutical Sciences, Zhejiang University,
Supporting Information
Electronic Supplementary Material (ESI) for rganic Chemistry Frontiers. This journal is the Partner rganisations 2018 Palladium-catalyzed direct approach to α-cf 3 aryl ketones from arylboronic acids Bo
First DMAP-mediated direct conversion of Morita Baylis. Hillman alcohols into γ-ketoallylphosphonates: Synthesis of
Supporting Information File 1 for First DMAP-mediated direct conversion of Morita Baylis Hillman alcohols into γ-ketoallylphosphonates: Synthesis of γ-aminoallylphosphonates Marwa Ayadi 1,2, Haitham Elleuch
Supporting Information. for. Highly Selective Hydroiodation of Alkynes Using. Iodine-Hydrophosphine Binary System
Supporting Information for Highly Selective Hydroiodation of Alkynes Using Iodine-Hydrophosphine Binary System Shin-ichi Kawaguchi and Akiya Ogawa * Department of Applied Chemistry, Graduate School of
Vilsmeier Haack reagent-promoted formyloxylation of α-chloro-narylacetamides
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Vilsmeier aack reagent-promoted formyloxylation of α-chloro-arylacetamides by formamide Jiann-Jyh
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone.
Regioselectivity in the Stille coupling reactions of 3,5- dibromo-2-pyrone. Won-Suk Kim, Hyung-Jin Kim and Cheon-Gyu Cho Department of Chemistry, Hanyang University, Seoul 133-791, Korea Experimental Section
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information 1. General experimental methods (S2). 2. Table 1: Initial studies (S2-S4).
Divergent synthesis of various iminocyclitols from D-ribose
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 205 Divergent synthesis of various iminocyclitols from D-ribose Ramu Petakamsetty,
Electronic Supplementary Information
Electronic Supplementary Information NbCl 3 -catalyzed [2+2+2] intermolecular cycloaddition of alkynes and alkenes to 1,3-cyclohexadiene derivatives Yasushi Obora,* Keisuke Takeshita and Yasutaka Ishii*
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Synthesis of 3-omosubstituted Pyrroles via Palladium- Catalyzed Intermolecular Oxidative Cyclization
Room Temperature Highly Diastereoselective Zn-Mediated. Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled
Supporting Information for: Room Temperature Highly Diastereoselective Zn-Mediated Allylation of Chiral N-tert-Butanesulfinyl Imines: Remarkable Reaction Condition Controlled Stereoselectivity Reversal
Rhodium-Catalyzed Oxidative Decarbonylative Heck-type Coupling of Aromatic Aldehydes with Terminal Alkenes
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Rhodium-Catalyzed Oxidative Decarbonylative Heck-type
Supporting information
Electronic upplementary Material (EI) for New Journal of Chemistry. This journal is The Royal ociety of Chemistry and the Centre National de la Recherche cientifique 7 upporting information Lipase catalyzed,-addition
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%.
Supplementary Figure S1. Single X-ray structure 3a at probability ellipsoids of 20%. S1 Supplementary Figure S2. Single X-ray structure 5a at probability ellipsoids of 20%. S2 H 15 Ph Ac Ac I AcH Ph Ac
Supporting Information. Experimental section
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Experimental section General. Anhydrous solvents were transferred by
Supplementary Material
Supplementary Material Control experiments S2 Characterization data for the products S2-S7 References S8 MR spectra for the products S9-S28 S1 Control experiments 2a (99.5 mg, 0.5 mmol), I 2 (50.8 mg,
Zuxiao Zhang, Xiaojun Tang and William R. Dolbier, Jr.* Department of Chemistry, University of Florida, Gainesville, FL
Photoredox-Catalyzed Intramolecular Difluoromethylation of -Benzylacrylamides Coupled with a Dearomatizing Spirocyclization: Access to CF2H Containing 2- Azaspiro[4.5]deca-6,9-diene-3,8-diones. Zuxiao
Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes
1 Mandelamide-Zinc Catalyzed Alkyne Addition to Heteroaromatic Aldehydes Gonzalo Blay, Isabel Fernández, Alícia Marco-Aleixandre, and José R. Pedro Departament de Química Orgànica, Facultat de Química,
D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical and experimental study
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical
Supporting Information
Supporting Information Rhodium-catalyzed Intramolecular Dehydrogenative Aryl Aryl Coupling Using Air as Terminal Oxidant Hannah Baars, 1,2 Yuto Unoh, 1 Takeshi Okada, 1 Koji Hirano, 1 Tetsuya Satoh,* 1,3
Supporting Information for Synthesis of Fused N-Heterocycles via Tandem C-H Activation
This journal is The Royal Society of Chemistry 212 Supporting Information for Synthesis of Fused -Heterocycles via Tandem C-H Activation Ge Meng, Hong-Ying iu, Gui-Rong Qu, John S. Fossey, Jian-Ping Li,*
Phosphorus Oxychloride as an Efficient Coupling Reagent for the Synthesis of Ester, Amide and Peptide under Mild Conditions
Supplementary Information for Phosphorus xychloride as an Efficient Coupling Reagent for the Synthesis of Ester, Amide and Peptide under Mild Conditions u Chen,* a,b Xunfu Xu, a Liu Liu, a Guo Tang,* a
Ferric(III) Chloride Catalyzed Halogenation Reaction of Alcohols and Carboxylic Acids using - Dichlorodiphenylmethane
Supporting Information Ferric(III) Chloride Catalyzed Halogenation Reaction of Alcohols and Carboxylic Acids using - Dichlorodiphenylmethane Chang-Hee Lee,, Soo-Min Lee,, Byul-Hana Min, Dong-Su Kim, Chul-Ho
Supporting Information for
Supporting Information for An atom-economic route to densely functionalized thiophenes via base-catalyzed rearrangement of 5-propargyl-2H-thiopyran-4(3H)-ones Chunlin Tang a, Jian Qin b, Xingqi Li *a a
Kishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng Wu*
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 204 Kishore Natte, Jianbin Chen, Helfried Neumann, Matthias Beller, and Xiao-Feng
Supporting Information for
Supporting Information for A ovel Synthesis of luorinated Pyrazoles via Gold(I)-Catalyzed Tandem Aminofluorination of Alkynes in the Presence of Selectfluor Jianqiang Qian, Yunkui Liu,* Jie Zhu, Bo Jiang,
Supporting Information
Supporting Information Metal-catalyzed Stereoselective and Protecting-group-free Synthesis of 1,2-cis-Glycosides Using 4,6-Dimethoxy-1,3,5-triazin-2-yl Glycosides as Glycosyl Donors Tomonari Tanaka,* 1
Supporting Information
Supporting Information Wiley-VC 007 9 Weinheim, Germany ew ear Infrared Dyes and Fluorophores Based on Diketopyrrolopyrroles Dipl.-Chem. Georg M. Fischer, Dipl.-Chem. Andreas P. Ehlers, Prof. Dr. Andreas
Supplementary information
Electronic Supplementary Material (ESI) for MedChemComm. This journal is The Royal Society of Chemistry 2015 Supplementary information Synthesis of carboxyimidamide-substituted benzo[c][1,2,5]oxadiazoles
Oxyhalogenation of thiols and disulfides into sulfonyl chlorides/ bromides in water using oxone-kx(x= Cl or Br)
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Oxyhalogenation of thiols and disulfides into sulfonyl chlorides/ bromides in water using
Supporting Information
Supporting Information Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao
Selective mono reduction of bisphosphine
Griffith Research Online https://research-repository.griffith.edu.au Selective mono reduction of bisphosphine oxides under mild conditions Author etersson, Maria, Loughlin, Wendy, Jenkins, Ian ublished
Jing-Yu Guo, Rui-Han Dai, Wen-Cong Xu, Ruo-Xin Wu and Shi-Kai Tian*
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 TfNHNHBoc as a SCF 3 source in the sulfenylation of indoles Jing-Yu Guo, Rui-Han Dai, Wen-Cong
Supporting Information
Supporting Information An Approach to 3,6-Disubstituted 2,5-Dioxybenzoquinones via Two Sequential Suzuki Couplings. Three-step Synthesis of Leucomelone Xianwen Gan, Wei Jiang, Wei Wang,,,* Lihong Hu,,*
Copper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds. in Aromatic Amides
Supporting Information for Copper-Catalyzed Direct Acyloxylation of C(sp 2 ) H Bonds in Aromatic Amides Feifan Wang, Qiyan Hu, Chao Shu, Zhiyang Lin, Dewen Min, Tianchao Shi and Wu Zhang* Key Laboratory
Supporting Information
Supporting Information 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions
Supplementary Data. Engineering, Nanjing University, Nanjing , P. R. China;
Supplementary Data Synthesis, Chemo-selective Properties of Substituted 9-Aryl-9H-fluorenes from Triarylcarbinols and Enantiomerical Kinetics of Chiral 9-Methoxy-11-(naphthalen-1-yl)-11H-benzo[a]fluorene
multicomponent synthesis of 5-amino-4-
Supporting Informartion for Molecular iodine-catalyzed one-pot multicomponent synthesis of 5-amino-4- (arylselanyl)-1h-pyrazoles Camila S. Pires 1, Daniela H. de Oliveira 1, Maria R. B. Pontel 1, Jean
Synthesis of novel 1,2,3-triazolyl derivatives of pregnane, androstane and D-homoandrostane. Tandem Click reaction/cu-catalyzed D-homo rearrangement
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of novel 1,2,3-triazolyl derivatives of
Efficient and Simple Zinc mediated Synthesis of 3 Amidoindoles
Electronic Supplementary Material (ESI) for rganic and Biomolecular Chemistry SUPPRTIG IFRMATI Efficient and Simple Zinc mediated Synthesis of 3 Amidoindoles Anahit Pews-Davtyan and Matthias Beller* Leibniz-Institut
Supplementary!Information!
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015! Synthesis)and)characterisation)of)an)open1cage) fullerene)encapsulating)hydrogen)fluoride! Supplementary!Information!
Supporting Information. A catalyst-free multicomponent domino sequence for the. diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3-
Supporting Information for A catalyst-free multicomponent domino sequence for the diastereoselective synthesis of (E)-3-[2-arylcarbonyl-3- (arylamino)allyl]chromen-4-ones Pitchaimani Prasanna 1, Pethaiah
Chiral Brønsted Acid Catalyzed Enantioselective Intermolecular Allylic Aminations. Minyang Zhuang and Haifeng Du*
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Chiral Brønsted Acid Catalyzed Enantioselective Intermolecular Allylic
SUPPORTING INFORMATION. Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts
S1 SUPPORTING INFORMATION Transition Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts Hao Yu, Zhen Li, and Carsten Bolm* Institute of Organic Chemistry, RWTH Aachen University
Sotto, 8; Perugia, Italia. Fax: ; Tel: ;
ELECTRONIC SUPPORTING INFORMATION Ermal Ismalaj a, Giacomo Strappaveccia a, Eleonora Ballerini a, Fausto Elisei a, Oriana Piermatti a, Dmitri Gelman b, Luigi Vaccaro a a CEMIN - Dipartimento di Chi mica,
Supporting Information. Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors
Supporting Information Synthesis and biological evaluation of 2,3-Bis(het)aryl-4-azaindoles Derivatives as protein kinases inhibitors Frédéric Pin, a Frédéric Buron, a Fabienne Saab, a Lionel Colliandre,
gem-dichloroalkenes for the Construction of 3-Arylchromones
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Pd(OAc)2/S=PPh3 Accelerated Activation of gem-dichloroalkenes for the Construction of 3-Arylchromones
Catalyst-free transformation of levulinic acid into pyrrolidinones with formic acid
Catalyst-free transformation of levulinic acid into pyrrolidinones with formic acid Yawen Wei, a Chao Wang,* a Xue Jiang, a Dong Xue, a Zhao-Tie Liu, a and Jianliang Xiao* a,b a Key Laboratory of Applied
Ligand-free Cu(II)-mediated aerobic oxidations of aldehyde. hydrazones leading to N,N -diacylhydrazines and 1,3,4-oxadiazoles
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Ligand-free Cu(II)-mediated aerobic oxidations of aldehyde hydrazones leading
Supporting Information For: Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes
Supporting Information For: Rhodium-Catalyzed Hydrofunctionalization: Enantioselective Coupling of Indolines and 1,3-Dienes Xiao-Hui Yang and Vy M. Dong* dongv@uci.edu Department of Chemistry, University
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information Facile diverted synthesis of pyrrolidinyl triazoles
Supporting Information
S1 Supporting Information Synthesis of 2-Arylated Hydroxytyrosol Derivatives via Suzuki-Myaura Cross-Coupling Roberta Bernini, a Sandro Cacchi, b* Giancarlo Fabrizi, b* Eleonora Filisti b a Dipartimento
Supporting Information. Direct Heptafluoroisopropylation of Arylboronic Acids via. Hexafluoropropene (HFP)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Direct Heptafluoroisopropylation of Arylboronic Acids via Hexafluoropropene
Sequential catalysis for the production of sterically hindered amines: Ruthenium(II)-catalyzed C-H bond activation and hydrosilylation of imines
Electronic Supporting Information Sequential catalysis for the production of sterically hindered amines: Ruthenium(II)-catalyzed C- bond activation and hydrosilylation of imines Bin Li, Charles B. Bheeter,
A New Type of Bis(sulfonamide)-Diamine Ligand for a Cu(OTf) 2 -Catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles with Nitroalkenes
A ew Type of Bis(sulfonamide)-Diamine Ligand for a Cu(OTf) 2 -Catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles with itroalkenes Jing Wu, Xincheng Li, Fan Wu, and Boshun Wan* Dalian Institute
Experimental procedure
Supporting Information for Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide Sébastien Alazet 1,2, Kevin Ollivier 1 and Thierry Billard* 1,2 Address: 1 Institute
Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates
Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates Yoshihiko Yamamoto,* Naohiro Kirai and Yu arada Department of Applied Chemistry, Graduate School of Science and Engineering,