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Δάμαρις Κουταλιανός
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1 (8-) * (,, ) ( ; ).., (8- ) (Alq 3) -,, Alq 3, Alq 3., (1 nm) Alq 3 (100 nm), Alq 3. Alq 3, Li +1 Alq 1,,. :,,, (8-) PACS: Fi 1,,., (organic light emitting device, OLED),, [1,2] ;,,, ; (organic thin-film transistor, OTFT),,, [3]. (organic photovoltage, OPV),, [4].., (time of flight, TOF) [5].,.,,.,,,,., TOF 2 8 µm, OLED (100 nm). TOF. (space charge limited currents, * ( : 2011AA03A110) ( : 2010CB327701) ( : , , , , ) ( : ) ( : ). duanyu@jlu.edu.cn c 2012 Chinese Physical Society

2 SCLC) [6,7], (),.,, 100 nm,,., SCLC,.,,,, SCLC [8 10]. SCLC (8-) (tris (8-hydroxyquinolinato) aluminum, Alq 3 ) (100 nm). J/V, SCLC, Alq 3, Alq 3, Alq 3 LiF/Al , 3, 4 1, ( ) LiF. : 1,, 10 3 Pa 50 nm Al. Alq 3 LiF Pa, 10 3 Pa 50 nm Al. IL-400 ; Keithley-2400 ;. 3 SCLC I-V., [11],,,,., (1) (2), J V (3). ε 0 ε r e de(x) d(x) = ρ(x), (1) J = ρ(x)eµe(x), (2) J = 9 8 ε 0ε r µ V 2 L 3, (3) ρ(x), E(x), x ; µ, V, L ; e, ε 0 ε r, ε r 3. Mott Gurney, (3) Mott-Gurney [12]., Poole-Frenke (4) [13] : µ(e) = µ 0 exp(γ E), (4) µ 0, γ,. (3) (4) (5) : J = 9 8 ε 0ε r µ 0 : ln = ln ( 9 8 L exp(γ E). (5) ) ε r ε 0 µ 0 + γ E, (6) L

3 Acta Phys. Sin. Vol. 61, No. 14 (2012) ln E. ln E, µ 0. (4). 4 2 J-V, 2, 4 J 1, 3., ln E, 3.,., (6), 1. 2 J-V 3 ln E 1 µ 0 γ µ 0 /cm 2 V 1 s 1 γ/(cm/v) 1/ ,, 2 4 Alq 3 [14], ,., 2 4 SCLC,

4 Acta Phys. Sin. Vol. 61, No. 14 (2012) , Alq 3 /LiF/Al Alq 3 Al, Al/LiF/Alq 3 Al Alq 3., [15]. Alq 3 Al LiF, : 3LiF + Al + 3Alq 3 AlF 3 + 3Li + Alq 3. (7) Alq 3 Alq 3 Al,, [16,17]., Alq 3 LiF Al,. LiF Al Alq 3, LiF Al Alq 3, Alq 3 LiF, Al,. Alq 3 LiF/Al, Alq 3 LiF Al,. (7), Al 2300 C, Al LiF/Alq 3,,,. Alq C, Alq 3 LiF/Al,,., Alq 3 /LiF/Al Alq 3 Al, SCLC Alq 3. 2, 4 (4), ( 4),, Alq 3. [18] , 4 SCLC Alq 3, Alq 3 /LiF/Al Alq 3 Al,,, ;,. Alq (cm 2 V 1 s 1 ), 10 3 (cm/v) 1/2, Alq 3 ( (V cm 1 )) 10 6 (cm 2 V 1 s 1 ). [1] Di C A, Yu G, Liu Y Q, Xu X J, Song Y B, Zhu D B 2007 Appl. Phys. Lett [2] Chen Z J, Yu J S, Sakuratani Y, Li M R, Sone M, Miyata S, Watanabe T, Wang X Q, Sato H 2001 J. Appl. Phys [3] Sun Q J, Xu Z, Zhao S L, Zhang F J, Gao L Y, Tian X Y, Wang Y S 2009 Acta Phys. Sin (in Chinese) [,,,,,, ] [4] Ong K H, Lim S L, Tan H S, Wong H K, Li J, Ma Z, Moh L C H, Lim S H, Mello J C D, Chen Z K 2011 Adv. Mater [5] Xu M, Peng J B 2009 Acta Phys. Sin (in Chinese) [, ] [6] Blom P W M, De Jong M J M, Vleggaar J J M 1996 Appl. Phys. Lett [7] Bozano L, Carter S A, Scott J C, Malliaras G G, Brock P J 1999 Appl. Phys. Lett [8] Yasuda T, Yamaguchi Y, Zou D C, Tsutsui T 2002 Jpn. J. Appl. Phys. Part [9] Kim S H, Jang J, Lee J Y 2000 Appl. Phys. Lett [10] Chu T Y, Song O K 2007 Appl. Phys. Lett [11] Carbone A, Pennetta C, Reggiani L 2009 Appl. Phys. Lett [12] Mott N P, Gurney R W 1948 Electronic Processes in Ionic Crystals (London: Oxford University Press) [13] Pal A J, Osterbacka R, Kallman K M, Stubb H 1997 Appl. Phys

5 Lett [14] Fong H H, So S K 2005 J. Appl. Phys [15] Le Q T, Yan L, Gao Y 2000 Appl. Phys. Lett [16] Hung L S, Zhang R Q, He P, Mason G 2002 J. Phys. D [17] Mason M G, Tand C W, Hung L S, Raychaudhuri P, Madathil J, Giesen D J, Yan L, Le Q T, Gao Y, Lee S T, Liao L S, Cheng L F, Salanech W R, Don S D A, Bredas J L 2001 J. Appl. Phys [18] Liu X D, Xu Z, Zhang F J, Zhao S L, Zhang T H, Gong W, Song J L, Kong C, Yan G, Xu X R 2010 Chin. Phys. B Preliminary investigation on the method of determining electron mobility of tris (8-hydroxyquinolinato) aluminum by space charge limited current Luo Yang Duan Yu Chen Ping Zang Chun-Liang Xie Yue Zhao Yi Liu Shi-Yong ( State Key Laboratory on Integrated Optoelectronics, College of Electronics Science and Engineering, Jilin University, Changchun , China ) ( Received 19 November 2011; revised manuscript received 19 December 2011 ) Abstract The charge-carrier mobility of an organic semiconducting material determines the material potential applications in devices. The investigation on mobility of organic material plays a significant role in improving the performance of organic device, such as organic light emitting diode, organic solar cell and organic thin film transistor. In this paper, we employ the space charge limited current (SCLC) method to evaluate the electron mobility of the controlled device based on tris (8-hydroxyquinolinato) aluminum (Alq 3). The zero-field mobilities and field-dependent factors of the four devices are fitted respectively. The results show that depositing Al as top-electrode onto buffer layer LiF (1 nm) and Alq 3 (100 nm) can significantly improve the the zero-field mobility and field-dependent factor of Alq 3. The reason for that is that LiF could strengthen the complex reaction between Al and Alq 3 to form Li +1 Alq 1 particles, which leads to the enhanced ohmic injection and electron injection. Keywords: SCLC, buffer layer, carrier mobility, Alq 3 PACS: Fi * Project supported by the National High Technology Research and Development Program of China (Grant No. 2011AA03A110), the National Basic Research Program of China (Grant No. 2010CB327701), the National Natural Science Foundation of China (Grant Nos , , , , ), the Research Fund for the Doctoral Program of Higher Education, China (Grant No ), and Scientific and Technological Developing Scheme of Jilin Province, China (Grant No ). duanyu@jlu.edu.cn

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