Research and Applications of Functional Materials of Titanate

Transcript

1 PROGRESS IN CHEMISTRY Vol. 17 No. 6 Nov ( ; ) : O ; TB34 : A : X(2005) Research and Applications of Functional Materials of Titanate Feng Xiuli 1 2 Wang Gongying 1 3 Qiu Fali 1 (11Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu China ; 21Graduate School of the Chinese Academy of Sciences Beijing China) Abstract The properties synthesis technologies and applications of titanates are reviewed. It is pointed out that the preparation of novel structured titanates the discovery of novel properties and new application fields are worth studying deeply. Key words titanates ; electroproperties ; photoproperties ; synthesis [1 2 ] [ ] ] [10 11 ] (2) 11 (1) : : e2mail com [7 1880

2 BaTiO 3 ; (120 ) (0 ) [12 ] 1 BaTiO 3 Fig. 1 The structure of cubic BaTiO 3 [13 15 ] [27 (5) 34 ] ( PTC) ; [16 18 ] [19 24 ] BaTiO 3 (675 ) [25 ] (3) 21 (1) TiO 2 TiO [35 36 ] [37 41 ] A 2 O[ TiO 2 ] n (A = H [26 ] (4) Li Na K Cs ; n = 2 3 4) TiO 6 10 (ATiO 3 ) T c ( ) [38 ] A ( 1) 014nm ; A ;

3 ATiO 3 A [45 ] [46 ] (4) (2) ; ; ; [42 ] [47 ] [48 ] [43 ] Fe 3 + V 5 + Sb 5 + ( ) ( = 55) ( = 100) SrTiO 3 Sr 2 + O 2 - Ti Ti 4 + Fe 3 + (1) Ti 4 + (ABO 3 ) Fe 3 + :A Fe 3 + : Ti O Fe O 2 - ; Fe 3 + Ti 5 O 2 - Fe 3 + Ti 4 + Ti 3 + Fe O Fe SrTiO 3 Fe O Ti 4 + [47 ] ; Fe 3 + Ti 4 + d Fe 3 + SrTiO 3 [49 ] Fe O Fe 3 + BaTiO 3 Fe 4 + Fe 4 + [50 ] [44 ] BaTiO 3 (3) BaTiO 3 BaTiO 3 ; ( ) ( )

4 (2) 3h BaTiO [58 ] K 2 Ti 6 O 13 TiO 6 K + BaO TiO nm [51 ] ; (A 12 TiO 5 ) BaTiO 3 6 TiO 6 AlO 8 : [52 ] [53 54 ] [55 56 ] (1) Narita [57 ] Ba (OH) 2 8H 2 O TiO 2 (1) 2 11 [59 62 ] TiO % 014 % MnO 1 2 MTiO(C 2 O 4 ) 2 2H 2 O 215h MTiO 3 5 Πmin 1 000nm MTiO 3 M Ti : ; MTiO 3 ; MTiO 3 [63 65 ] (2) ph (NH 4 ) 2 CO 3 TiOCl 2 Ti (OH) 4 MCO 3 Abe (1 100 ) ph

5 M Ti ; 2 BaTiO 3 (3) ml M(OH) 2 30min (NH 4 ) 2 TiO 3 M MTiO 3 MTiO 3 M ph M/ Ti MTiO 3 [66 67 ] BaTiO 3 [74 78] : [78] BaTiO 3 ; [68 ] ph ph BaTiO 3 (2) [79 2 BaTiO ] 3 2 [69 ] BaTiO 3 ; ; 24h ; BaTiO 3 [70 ] [81 ; ] [82 ; ] [80 ] 95 2 [83 ] ; 120 BaTiO 3 11 [71 73 BaTiO 3 ] 2 ph 1947

6 PTC 60 PTC 1980 PTC 21 X 3mm 5mm 1kg kj ; 1111 % ; ; [26 ] 8g 1Π3 1Π10 CO ( E) E E SO 2 90 %

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