17 6 2005 11 PROGRESS IN CHEMISTRY Vol. 17 No. 6 Nov. 2005 1 2 1 3 1 (11 610041 ; 21 100049) : O614141 ; TB34 : A : 10052281X(2005) 0621019209 Research and Applications of Functional Materials of Titanate Feng Xiuli 1 2 Wang Gongying 1 3 Qiu Fali 1 (11Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu 610041 China ; 21Graduate School of the Chinese Academy of Sciences Beijing 100049 China) Abstract The properties synthesis technologies and applications of titanates are reviewed. It is pointed out that the preparation of novel structured titanates the discovery of novel properties and new application fields are worth studying deeply. Key words titanates ; electroproperties ; photoproperties ; synthesis [1 2 ] [3 1 400 6 ] 142 9 ] 6 000 10 000 [10 11 ] (2) 11 (1) 32 21 20 : 2004 10 : 2005 1 3 e2mail :ciocwgy @sina. com [7 1880
1020 17 1947 BaTiO 3 ; (120 ) (0 ) [12 ] 1 BaTiO 3 Fig. 1 The structure of cubic BaTiO 3 [13 15 ] [27 (5) 34 ] ( PTC) ; [16 18 ] 10 3 10 4 1950 [19 24 ] BaTiO 3 (675 ) [25 ] (3) 21 (1) TiO 2 TiO 2 20 10 [35 36 ] [37 41 ] A 2 O[ TiO 2 ] n (A = H [26 ] (4) Li Na K Cs ; n = 2 3 4) TiO 6 10 (ATiO 3 ) T c ( ) [38 ] A ( 1) 014nm ; A ;
6 1021 ATiO 3 A [45 ] [46 ] (4) (2) ; ; ; [42 ] [47 ] [48 ] [43 ] Fe 3 + V 5 + Sb 5 + ( ) ( = 55) ( = 100) SrTiO 3 Sr 2 + O 2 - Ti 4 + 31 Ti 4 + Fe 3 + (1) Ti 4 + (ABO 3 ) Fe 3 + :A Fe 3 + : Ti O Fe 3 + 6 O 2 - ; Fe 3 + Ti 5 O 2 - Fe 3 + Ti 4 + Ti 3 + Fe 3 + 2 O Fe SrTiO 3 Fe 3 + 2 O Ti 4 + [47 ] ; Fe 3 + Ti 4 + d Fe 3 + SrTiO 3 [49 ] Fe 3 + 2 O Fe 3 + BaTiO 3 Fe 4 + Fe 4 + [50 ] [44 ] BaTiO 3 (3) BaTiO 3 BaTiO 3 ; ( ) ( )
1022 17 (2) 3h BaTiO 3 700 [58 ] K 2 Ti 6 O 13 TiO 6 K + BaO TiO 2 10 30nm [51 ] ; (A 12 TiO 5 ) BaTiO 3 6 TiO 6 AlO 8 : 1 820 1 860 15 750 1 300 1 820 21 [52 ] [53 54 ] [55 56 ] (1) Narita [57 ] Ba (OH) 2 8H 2 O TiO 2 (1) 2 11 [59 62 ] TiO 2 70 100 011 % 014 % MnO 1 2 MTiO(C 2 O 4 ) 2 2H 2 O 215h 1 300 700 1 000 1 500 MTiO 3 5 Πmin 1 000nm MTiO 3 M Ti : ; MTiO 3 ; MTiO 3 [63 65 ] (2) ph (NH 4 ) 2 CO 3 TiOCl 2 Ti (OH) 4 MCO 3 Abe (1 100 ) ph
6 1023 M Ti ; 2 BaTiO 3 (3) 80 1 000ml M(OH) 2 30min (NH 4 ) 2 TiO 3 M MTiO 3 MTiO 3 M ph M/ Ti MTiO 3 [66 67 ] BaTiO 3 [74 78] : [78] BaTiO 3 ; [68 ] ph ph BaTiO 3 (2) [79 2 BaTiO ] 3 2 [69 ] BaTiO 3 ; ; 24h ; BaTiO 3 [70 ] [81 ; ] [82 ; ] [80 ] 95 2 [83 ] ; 120 BaTiO 3 11 [71 73 BaTiO 3 ] 2 ph 1947
1024 17 PTC 60 PTC 1980 PTC 21 X 3mm 5mm 1kg 1125 10 5 kj ; 1111 % ; ; [26 ] 8g 1Π3 1Π10 CO 1938 1960 31 ( E) E E SO 2 90 %
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