УДК 082 ББК 94.3 М34 М34 УДК 082 ББК 94.3

-, 15 15 2013. 2013

Материалы региональной научно-практической конференции студентов, аспирантов и молодых учёных Школы естественных наук ДВФУ, Владивосток, 15 апреля 15 мая 2013 г. УДК 082 ББК 94.3 М34 М34 Материалы региональной научно-практической конференции студентов, аспирантов и молодых учёных Школы естественных наук ДВФУ, Владивосток, 15 апреля 15 мая 2013 г. [Электронный ресурс]. Электрон. дан. Владивосток : Издательский дом Дальневосточного федерального университета, 2013. Режим доступа: https://www.dvfu.ru/schools/school_of_natural_sciences/documents/2013.pdf. Загл. с экрана. ISBN 978-5-7444-3121-1 В сборнике опубликованы научно-исследовательские работы студентов, аспирантов и молодых ученых, представленные в рамках региональной научно-практической конференции студентов, аспирантов и молодых учёных Школы естественных наук ДВФУ, проходившей в Дальневосточном федеральном университете с 15 по 30 апреля 2013 года. Работы молодых исследователей охватывают научные направления, развивающиеся в высших учебных заведениях Дальневосточного федерального округа России. УДК 082 ББК 94.3 Дальневосточный федеральный ISBN 978-5-7444-3121-1 университет, 2013

-,,, 15 15 β01γ. I.... 13..,..,..,... Globcover13..... 16.. -... 19.. -... 22... XX XXI.... 25..... 26..... 29.. (. )... 32.. - ( )... 34.. -... 37..... 39..,..,..... 43..... 45...... 48.. -... 51..... 54 II.... 57 3

-,,, 15 15 β01γ...,..... 57..,..,..... 60..... 62.. -... 63..... 66..... 67..... 69..,..... 71..... 74..,..... 76.. -... 79..... 81..... 84..... 85..... 87..,..... 89..... 92.. -... 93..... 95..... 97 4

-,,, 15 15 β01γ... ЭЫКЧЬТЦЬ... 100..... 103.. - 105.... 108..,..... 111..... 112..... 114..... 116.. -... 119..... 122..... 124..... 127..... 128..... 130.. USB... 132..... 134 III.... 137..... 137..... 140.. SCAP... 142 5

-,,, 15 15 β01γ. IV.... 144..... 144.. 145..... 145.. -.. 146.. (Щ,1)-... 146..... 148 V. -... 151.......... 151.. -... 152..... 154.. -... 156..,..,..... 159..,..,..... 160.. FЫООFОЦ... 162..,..,.. Nvidia Cuda... 164..... 168..... 170.. 171..,... 173.. 176 6

-,,, 15 15 β01γ...,..,..... 179..... 182..,..... 185..,.. -... 186.. 188..... 189..... 191..,..... 193.. -... 195.... 198..... 201 VI.... 204..... 204..,..... 206..... 208..... 211.. 212 VII.... 216..... 216.. Ln 2 O 3 (Ln = La, Lu)... 219 7

-,,, 15 15 β01γ...,..,.. (IV) CS(I)... 221..,..... 222.. Ni(II)... 223.. : -... 224..... 226..,... 228.. -... 229.. SrF 2, Zn 2+... 231.., 2,2--4-(9- )-6--1,3,2-... 232.. CR(III)... 235 VIII.... 236.. -... 236..,.., A.A.... 239..,..... 240..,.. CPU GPU... 242.. - ACII (small animal instruments INC)... 244 8

-,,, 15 15 β01γ........β46.. - 2D... 249..... 250..,..... 252..... 255..... 257..... 259..... 263..,..... 265.. Multisource HDR... 267..... 269..... 271..... 274.. Multisource HDR... 277..,..... 278 IX.... 282.. -... 282.. 284..,..,..,.. Ca2Si Ca3Si4 Si... 286 9

-,,, 15 15 β01γ...,.. - -... 287..,.. FО Fe 3 O 4 / SiO 2 /Si(001)... 290..,..... 291..,.. FО, Fe 3 O 4 / SiO 2 /Si(001)... 293..... 294..... 297..,.. Co Si(111)... 298..... 299.. Fe Co... 301..,.. Si(111)... 304.., -... 306..,..,..... 309..,..... 311..,..,.. Co... 315..,..,..,..,.. Tl Au/Si(111)... 316..,..,.. CoP... 318 X.... 320..,..... 320 10

-,,, 15 15 β01γ...... 322..,.. ( )... 325..... 329..... 333...... 334..... 337.. 2,4- -... 340..,..,,... 343..,... 346..,..,... 349.. -... 351..... 353 XI.... 356..,..,..,..,.. (VI)... 356.. 1,3-... 358.. 4--2--1,3,5- -1,5 4--2--1,3,5- -1,5... 359.., Rubia jesoensis... 361 11

-,,, 15 15 β01γ... 3, 5--4- -1-1Ph-... 362.. /... 364....... 367.. 369.. 1,5-... 372......373..... 374.. -, -... 376.. Fucus evanescens... 378.. 2( -)-1,3,2-... 379.. 2,7-Д(2-)-Ж... 381.. TiO 2,... 383..... 386.. 3--1--2--1-... 386.. 70... 388 12

-,,, 15 15 β01γ. I...,.. GLOBCOVER,,,.... -. (,,..). 60-70-. Д1Ж.. GХШЛCШЯОЫ, -,,,. GlobCover (Global Land Cover Product) ESA,, MERIS (Medium Resolution Imaging Spectrometer) EnviSat. γ00 /. : β005-β006, β009. ββ,,,,,,,.. (δccs Land Cover Classification System) [2]., 197β (, ),, -, -, -. 4β, γβ4 13

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-,,, 15 15 β01γ. 190 83 158 75 200 16 4-12 210 38 30-8 4770 4770, 4,,,.,,.,, QЮТМФ BТЫН, δкчнькэ εшнть,.. 1.. 1...,..,... СЭЭЩ://ааа.РТЬМЫКПt.ru/projects/project01.shtml 2. http://due.esrin.esa.int/globcover/ 3.,.. - ББ /... -, 2000. 75. 4.,.. /..,..,.. // :....-.. :, β008.. 77-81. 5... // -, β009.. 4. СЭЭЩ:// botsad.ru/journal/number 4/4-18.pdf 15

-,,, 15 15 β01γ. 6. :. :, β011. 1β8.,..,..,. : -,,, ; - (); -, (),, [1].. β01γ 4γ () 11. β010, ().... : - ; -,, (),. : - (). / () : 1) ; 16

-,,, 15 15 β01γ. 2). / : - ; - ; - ; - ; - ( ). 17

-,,, 15 15 β01γ.. 2. () : ), ), )... 0,β5 β,5 %......... 10.. 1. /..,....,.. ;..... :, β008. 31. 18

-,,, 15 15 β01γ. -...,....,,.,,. :., β-γ,,, 14-15.,. β-γ,..,,, [3].,, [1].,,,.,.. -. :, - 1998 β008. (.1). -1 γ 1998 β008. :,,.. 1. 19

-,,, 15 15 β01γ.,, [2]. :....... 11 β001 : 26,3,. 21,2 β5 β001..,. ;,., β γ.,.,.,.,,. β001, β007.,,.,.. 0.... γβ9;. 197 (. β1γ). (.. 44).. β000. β005., β001. β006.,. β001. β006. 0 (.1). β007 15β ( ), β001 (40 ). 1 ( 1998 2008.) 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 14 12 8 6 8 20 13 5 19 22 7 6 4 9 3 8 7 3 21 6 13 7 9 17 17 15 1 11 23 15 7 4 6 2 7 9 7 0 11 7 6 2 0 7 5 5 3 1 14 1 8 0 6 19 11 13 0 8 20 8 8 5 0 3 7 13 7 2 8 17 20

-,,, 15 15 β01γ. 3 3 0 8 2 2 7 0 17 2 10 4 7 18 18 12 1 7 19 3 :. 0,1 β4,3 (. 2). 8 8,4, 7,0 8,γ, 7 8,4. 1998 β008. β4,γ 8 β001., 19,3 1γ β00γ.; 1γ β00γ, 18,γ. 2 ( 1998 2008.), % 8,05 2,97 0,2 16,3 37 8,31 3,05 1,0 24,3 37 8,5 2,93 1,3 15,7 35 7,14 3,02 0,3 17,2 42 7,16 3,05 1,1 19,3 43 8,22 3,33 1,2 18,1 40 7,39 3,02 0,1 14,3 41 7,66 3,09 0,3 18,3 40 8,25 2,97 0,3 15,4 36 (,, ), (, ).. ( ) -. 1.,.. /..., 198γ. 288. 2. - γ. 1-6.. 26.,, 1988. 416. 3. http://big-archive.ru/geography/basis_of_common_geography/21.php /15.02.2013/ 21

-,,, 15 15 β01γ. -...,..,,.,,,..,,. 1970-, 1980-,,,.,,,...,,,., [4].,,.,,.,,,.. : -.. 1971-2009. - ( - 5γ 05, -158 γ5 ),. ( ) -124. (. 1) 0,39, 0,0β, 5%. ( ) 0,07. 0,1β-0,14, 0,18. ( ) (8%), 6-7%. γ9-22

-,,, 15 15 β01γ. - 0,548 β007. 1971 0,β6γ, 1-1971 2009. I II III IV V VI VII VIII IX X XI XII 0,446 0,463 0,465 0,445 0,410 0,376 0,347 0,323 0,322 0,342 0,375 0,417 0,394 0,446 0,465 0,465 0,442 0,406 0,376 0,345 0,321 0,322 0,339 0,375 0,417 0,396 0,446 0,472 0,480 0,445 0,381 0,372 0,356 0,315 0,329 0,355 0,374 0,417 0,383 0,026 0,028 0,032 0,031 0,028 0,023 0,027 0,027 0,019 0,020 0,021 0,030 0,018 - - 1,769 0,751-0,422 0,400 0,466 0,547-0,411 0,592 0,425 0,284 0,410 1,862 0,246 0,392 0,322 0,429 1,026 8,492 2,635 1,966 1,958 1,870 0,468-0,473 0,879 0,632 0,388 0,405 0,399 0,389 0,355 0,330 0,280 0,263 0,268 0,291 0,307 0,366 0,364 0,530 0,548 0,521 0,534 0,468 0,437 0,410 0,440 0,376 0,407 0,425 0,507 0,438, % 6 6 7 7 7 6 8 8 6 6 6 7 5, Д1, 2]. -.. 1,, -, -. - (0,45-0,47 ), - (0,γβ ).,. 1. - 1971-β009. ( ; ), (. β), γ9 0,009, β%., 23

-,,, 15 15 β01γ., 16%.,. ) ) R R R. β. () () - 1971-β009. ( ; ) : - -, - -. ; Дγ],,, (1985.), (1987.) 199γ. 1994.,,. 1..,. :... :, 1987. 41γ. 2.....:, 197γ, β9β. 3...,..,..,.. γ0- //. 8. β004.. β4 35. 4.... //,. 2007. 24

-,,, 15 15 β01γ. I....,.. Д1Ж,.,,..,.,., Д2Ж, 0,6 0,8.,,.,,. - 1950 β010.. (,,,,,,, ) 1950 β010. :,,,.,.,.. R 2. 60 R 2 > 0.04 [3].,..... (.1)., 0,04,. 25

-,,, 15 15 β01γ., 14.18.β1.06γ7. 1 0,09 0,07 0,02 0,25 0,10 0,03 0,04 0,18 0,12 0,11 0,10 0,16 0,30 0,18 0.07 0,18 0,19 0,17 0,.09 0,09 0,23 0,19 0,05 0,14 0,08 0,10 0,22 0,05 0,17 0,22 0,18 0,22 1. (. 17 β009. N 861-), β009. 19. 2. Parry, M.L. Climate change 2007 the scientific basis. Summary for policymakers, a report of Working Group /M.L. Parry, O.F. Canziani, J.P. Palutikof, P.J. van der Linden and C.E. Hanson (eds)./ Cambridge University Press, Cambridge, USA. 2007., 114 p. 3.,.../..,.. / -., : -, β009. 87....,..,,,.,,., Д1, 2Ж,, -., -,, 10 β000... () 958, - 26

-,,, 15 15 β01γ. β000,, 945. () βγ9., - β00β.,, β000., 199., β005. γγ., 60%,, 11γ,0,, 1ββ,β. 555,6, - 564,6,. 1. 1 IV V VI VII VIII IX X.. 47,3 54,7 52,7 96,9 113,0 100,5 99,8 564,9-58,9 56,0 61,8 78,3 113,2 87,6 99,8 555,6 49,4 62,7 62,2 93,5 122,2 86,3 86,0 562,3, 49,4 58,9., - β00β. β44,4,,, β000. β8β,8.,, β00γ. - 7, β007. 1γ.,,. 0,06 /. γ,β0 /, β004,. 2., / 2 V VI VII VIII IX X 0,β6, β004 0,γ9, β009. 0,6β, β005 0,84, β004 γ,β0, β004 0,58, 2006-0,β0, β005. 0,61, β000 1,48, β007 β,γγ, β005 0,64, β005 0,64, 2000 0,18, β00β 0,75, β001 0,6β, β005 β,70, β004 2,40, 2000 0,65, β001,, β,γγ γ,β0 /., 23-γβ. 27

-,,, 15 15 β01γ., ДγЖ,... γ 0,1 0,5 8 14. 3,.., 0,1 0,5 1,0 5,0 10,0 β0,0 γ0,0 10,4 9,9 8,0 2,8 1,0 0,5 0,1-10,1 9,1 6,0 3,7 2,1 0,5 0 10,7 9,4 8,0 3,3 1,5 0,2 0,2 12,5 9,0 7,9 4,0 2,9 1,2 0,6-12,2 8,9 6,7 4,0 2,7 1,5 0,7 12,7 8,6 7,5 4,3 2,7 1,3 0,5 14,2 12,0 10,5 5,3 2,6 0,7 0,3-14,0 11,0 9,1 4,9 2,9 0,9 0,4 13,2 10,6 9,2 4,7 2,6 0,9 0,2 5,0 6, β0 30 1,5 0,8,. 1. -.. 1 6. γ...:, 1988.. β5. 416..... //., 1970.. 5.. /.. //.. 28

-,,, 15 15 β01γ....,.... :,.,. ( 15 /) ( γ0 /),,.,. (СЭЭЩ://ЧШМ.ЩШТ.НЯШ.ЫЮ/аОКЭСОЫ/) β00β-β008... «Terra» «Modis»., γ0. 16 10 β0 (. 1).,,, β8. β00γ β007.. 1. 29

-,,, 15 15 β01γ.,. Д1Ж [3Ж,,.., (/100 ), Дβ].,, 15 γ0 /. γγ60 (β8 4 ) ( ), ( ). -. 406,.. 14 15 (, )., (. 2).,,... β.. (.γ) 8-10 13-15,.. 40 50.. 160.. 160..,,,. ( 70 90%),. 30

-,,, 15 15 β01γ.,.., β006-β007... γ.,... 975 98β, -,. β005. 944, β007. 1006 (. 4)..4.. Terra Modis. 31

-,,, 15 15 β01γ. 1... 1198-97 β9.01.97. 2..:, 198γ. 3. Monahan H.H., Armendariz M. Gust factor variations with height and atmospheric stability.-j. Geophys. Res., 1971, vol. 76, N 24, p. 3807-3818. (. )...,.. 17.,. 68%..,.,...... β01β. β 9-.....,, [4]. :, -95,,,,,.. K : K m B, (1) B, ; m=, (2) 32

-,,, 15 15 β01γ.,. m.. 1. Ln T,. 1. LЧ (, 1,, 13) β :.. 1...,., γ0, [7]. β. (. 1). 4 β6%,,. [3, 6].. 1 / % 316 305-4 221 203-9 269 254-5 33

-,,, 15 15 β01γ. / % 468 370-26 328 297-10 399 358-16.. (, ) [5].,... 1β 34 % Д1Ж.... : ; ;. 1... - //.,, 1984.. 104 118. β... -. :, β008. γγβ. γ...,... : -. -, β009. 216. 4..:, 197γ 176. 5...,.... :, 1977. 180. 6... -. //. β004.. 137.. 75 81. 7..... :, 1976. 352. - ( )...,..., 34

-,,, 15 15 β01γ.,. -.,,, [1].,,,.,,.,,,,. - - --.,,.,,..,,, [4]., -. ( ).,,,. [2].,.,,,,.,,,,.,.,,,. -.,,.,.,,,. -.,, [3]., -., (,, ). 35

-,,, 15 15 β01γ.,.,.,,.,. -. -.,. -. 19,,, [5]., - -. -. - -.,.. - ( -, ).., -,. -, -,,. 1... -. :, β010. γβ8. 2..... : -. -, β00γ. 176. 3.... ; :, 2006. γβ8. 4... //. : -. -. 2009.. XXXIX.. 196 201. 5... ( ) //. : -. -, β009. БББIБ.. 202 207. 36

-,,, 15 15 β01γ. -...,.. -,. β500,...., [3]. [1].,.., [2],.,,, - (. 1). γ0 50 [2].. 1. β1- (β041 β060) CMIPγ β (,, ) γ0 (,, ) [2] - 60. 37

-,,, 15 15 β01γ. 25-1950 β010., -,. (СЭЭЩ://ааа.ЦОЭОШ.ЫЮ/)..... [4]. :,,,. : -12-3,,. ( -46-21), ( -27-22), ( ), +γ +6, ( ), +1β +β0. 10 β0%, ( 100%). β5,,.. 0,5 γ,0. 5 (. β): 60 ( γ,0), ( β,5), 1,5, (1). 5, ( ;, -,, )., ( ),.., ;. 38

-,,, 15 15 β01γ. R R R R R,,,. β. 1950 β010. (, ) 1... /..,..,.. // 1998. 1.. 19 29. 2.. I...: - (),, 2008. β88. 3.,.γ4,.4.,.. :, 1968. 258. 4... :.-. /..,... : -. -, β009. 88....,..,,.. :,,., 39

-,,, 15 15 β01γ. γγ-101-β00γ, ().,,,. [1,2].,,....., : P k =, P k ; ; k 2, k 1 ; m i- ; p i i-,. P k Pl = -lg (P k ). 16. : P( k )., 100%..,.. 1 4... (. 1). (. β),,...,... (. 3). (. 4).. 40

-,,, 15 15 β01γ.. 1..., P,%. β.. 41

-,,, 15 15 β01γ.. γ...,,%. 4.. 1.... : -, β004. 104. 2... //. 2008. 6.. 109 114. 42

-,,, 15 15 β01γ.,,,...,...,,..,,.. 1. ( ) ( ). 1. Q /.,, -,,,. G, /,.,,,,..,,., -, ( ), -,, ( ). pãð ( H h)( ext int) g p âåòð ext 2 2 Ê äèí ( ñ í ñ ç ) 43

-,,, 15 15 β01γ., ext. int,.,. β.04.05-91* [1Ж int.., int,,. ДβЖ,,. ( )., h,,. p 0,5H ( ext int ) g 0,25 23-02-β00γ, -,,, ( ); -, K ( ) 1; -, ; -,, 2 ð 0,55Í ( int) 0, 03 ext ext, : 3463 273 t : ext = 1γ,91/ 3 ; int = 11,8β/ 3, ;. p (t ext =-β8ºc, =4,9 /) ( Д1γ0Ж) (t ext =-β4ºc, =9 /)., β00 ( ),,., β00,,,, ( ).,,.,,. 1. β.04.05-91.,..: 199β. 2......: -, β007, β65. ext 2 K äèí ( ñ í ñ ç ) 44

-,,, 15 15 β01γ....,..,,. Д5Ж,.,.,,. γ4 100,.. - - 60.. : 1951 2009. ( ) 1914 β010. (http://www.meteo.ru/).,.., [1]. (...) β-.... (,,,, 1-, 2- ) β. Дβ].,. Д4]. (. 1). ( ). (,,, ),,,,., ( ),,.. (1959, 1967, 1978 1979.) (β00γ.) ДγЖ. (. 1) 19β0-194γ., (19β5 19β7), (19γ1 1941). 45

-,,, 15 15 β01γ. 1944 1977., : ( 1967 1977.). 1978..,, [5]. 1 1. β. 4,55 5,12 3,81 4,80 5,80 6,58 6,10-4,50 6,65 5,80 4,48 5,07 5,23 4,85 4,40 4,74 3,89 4,96 4,70 4,70 3,98 4,46 5,11 3,65 4,84 5,43 5,37 4,08 4,32 4,86 4,56 3,85 4,61 4,61 4,73 3,96 5,05 4,29 5,77 4,78 6,07 4,74 4,87 4,90 4,38 4,87 4,83 4,97 4,01 4,17 4,80 4,15 4,39 4,13 6,03 4,31 4,49 4,53 4,02 4,66 4,40 5,63 4,62, 4,49 7,55 4,94 4,55 4,58 5,23 3,70.,. [6Ж,. (. β),. 60 0,β0 10, 1980-0,γ7 10, γ0-10 ( 1981 1990.) 0,6. 6 : 60 (1,5),. (1,4), (1,β), (0,6) (0,8)., 1971 1980.,. β-,, 1-.., β-,. β-,., β-, 1-. 46

-,,, 15 15 β01γ.. 1. (11- ). 1, β -, γ -. β.,, β- ; 1-,. 45 55.. [5]. 14 γ7%., 1-.. : 2 8-; 12 15- β9-.,.,, ;., 10.09.2012. «100». 1... /...-.:, 1974.- β04. 2...:, 197β.-γ65. 3... β1- β008. /..,..,..,...//.. 2008.-. 15γ.. β54 263. 4... :.-. /..,.. : -. -, β009.- 88. 5... : /...-: - «-», β008. γ0β. 551.58γ. 6...,..,.. /..,..,.. :.....,,, β 5. β01β., β01β.. βγγ. 47

-,,, 15 15 β01γ.....,..,.,..., [1, 2].., Дγ, 4Ж,,,,,,,. ДγЖ.,.,, (, ),. ( ) 19β4 β011...,... ДγЖ., ( ). (, )., 95% 5%,. (.1).,, 48

-,,, 15 15 β01γ. (Tmin) (Tmin -β1º), (Tmax β6 º). 95% 5% (TЦКб95) (TЦТЧ5), º 1 Tmin5-9 -18-21 -18-10 -1 Tmax95 8 0-3 -1 6 13 Tmin5 4 8 13 16 10 1 Tmax95 18 21 25 26 22 17 19β4 β011.. β ( 10).., ( 1970-.), I.. (, )..,,.,,,. (.β),,., 14.18.β1.06γ7. 2 ( 1924 2011.).* Tmin 1947, 1956, 1962, 1976, 1998 1935, 1944, 1947, 1952, 1956 1927, 1931, 1936, 1945, 1947, 1951, 1931, 1933, 1942, 1969 1924, 1925, 1933, 1937, 1945, 1946, 1947, 1957, 1970 1931 49

-,,, 15 15 β01γ. Tmax 2001, 2004 1948, 1951, 1955, 1958, 1968, 1979, 2008 1953, 1960, 1977 1932, 1979, 1989, 1992, 2007 1935, 1960, 1989, 1990, 1998, 2002, 2004, 2007 1938, 1989, 1990, 1998, 2002, 2003 1989 Tmin 1930, 1933, 1946, 1972, 1978, 1980, 1985, 1997, 2011 Tmax 1948, 1951, 1952, 1961, 1962, 1966, 1967, 1976, 1982, 1989, 1991, 1998, 2001, 2004, 2009 1931, 1940, 1941, 1945, 1953, 1960, 1969, 1971, 1977, 1983, 1997 1925, 1942, 1944, 1946, 1950, 1951, 1958, 1965, 1970, 1982, 1988, 1990, 1991, 1997, 1999, 2000, 2001, 2002, 2003, 2004, 2005, 2008, 1931, 1932, 1934, 1941, 1945, 1947, 1954, 1956, 1966, 1967, 1971, 1974, 1979, 1983, 2009 1924, 1939, 1955, 1961, 1977, 1978, 1981, 1992, 1994, 1995, 1997, 1940, 1941, 1956, 1957, 1962, 1966, 1968, 1969, 1971, 1975, 1980, 1987, 1993, 1996, 1998, 2002 1924, 1929, 1939, 1944, 1949, 1950, 1951, 1955, 1967, 1973, 1975, 1929, 1964, 1966, 1967, 1969, 1972, 1986, 1992, 1995, 1997 1924, 1926, 1928, 1937, 1943, 1946, 1948, 1950, 1958, 1965, 1975, 1977, 1985, 1999, 2001, 2005, 2007, 2008, 2010 1924, 1926, 1963, 1974, 1984, 1997, 2002 1930, 1943, 2003, 2006 50

-,,, 15 15 β01γ. 2010 2004, 2008 1984, 1989, 1990, 1994, 2004, 2006, 2010 *.. 1.,.. /.. //. 2004.. 4.. 30 37. 2. Parry, M.L. Climate change 2007 the scientific basis. Summary for policymakers, a report of Working Group /M.L. Parry, O.F. Canziani, J.P. Palutikof, P.J. van der Linden and C.E. Hanson (eds)./ Cambridge University Press, Cambridge, USA. 2007., 114 p. 3.,.. /..,..,.. / «-». 17γ,, β007.. 38-53. 4.,.../..,.. /. : -, β008, 86. -...,..,, -. 1991 β005. () 6,γ %., (,,, ), (γ7 %) [1].,,,.,,,.,, (,,, ) [1]. - 51

-,,, 15 15 β01γ..,,... -. ( 15 /) (-,,,,, ) 1977-β010. (. 1).. 1.,,. 100 500. - (.) http://www.meteo.ru/3/. (15 / ), (.1.β). (β4β ), - (,, ) ( ). 1 (15 / ) 1977-2010., ( 3- ) I II III IV V VI VII VIII IX X XI XII - 1-1 3 4 2 1 - - 8 1-21 10 13 36 136 230 26 11 16 32 33 18 6 567 34 16 33 104 88 9 9 8 12 34 31 5 383 15-1 26 63 22 16 8 15 23 12 3 204 10 8 54 147 197 55 36 21 40 97 24 6 695 8 18 75 242 207 44 22 16 50 109 65 8 864 52

-,,, 15 15 β01γ.. 2. 1977-β010. ( ),.,,..,. -.. - (1, ). ДβЖ,.. (1891-1960. 1977-β010.),, (15 / ). 1.,.. - :.... : β5.00.γ0 /...-, β011. β0. 2.,. β5,. :. 1967. 328. 3. http://www.meteo.ru 15.01.2013. 53

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-,,, 15 15 β01γ. 1. KКМгЦКЫг, S., AЧРОЧтСОЫЭО AЮПХöЬЮЧР ЯШЧ SвЬЭОЦОЧ ХТЧОКЫОЫ GХОТМСЮЧРОЧ. BЮХХОЭТЧ IЧЭОЫЧКЭТШЧКХ НО Х'AМКНцЦТО PШХШЧКТЬО НОЬ SМТОЧМОЬ ОЭ НОЬ δоээыоь. CХКЬЬО НОЬ SМТОЧМОЬ εкэсццкэтqюоь ОЭ NКЭЮЫОХХОЬ. SцЫТО A, SМТОЧМОЬ εкэсццкэтqюоь, ЯШХ. γ5 (19γ7), ЩЩ. γ55 γ57 2. J. ЯШЧ NОЮЦКЧЧ, τч ЫТЧРЬ ШП ШЩОЫКЭШЫЬ. RОНЮМЭТШЧ ЭСОШЫв // AЧЧ. ШП εкэс. 50 (1949) Щ. 401 485 3. T. S. εшэгфтч, I. J. SМСШОЧЛОЫР, TСО ЫОХКбКЭТШЧ ЦОЭСШН ПШЫ ХТЧОКЫ ТЧОqЮКХТЭТОЬ // CКЧКНТКЧ JШЮЫЧКХ ШП εкэсоцкэтмь, 6(1954), Щ.γ9γ-404 4. AРЦШЧ SСЦЮОХ, TСО ЫОХКбКЭТШЧ ЦОЭСШН ПШЫ ХТЧОКЫ ТЧОqЮКХТЭТОЬ // CКЧКНТКЧ JШЮЫЧКХ ШП εкэсоцкэтмь 6(1954), Щ.γ8β γ9β 5. H. H. BКЮЬМСФО, J. ε. BШЫаОТЧ, τч ЩЫШУОМЭТШЧ КХРШЫТЭСЦЬ ПШЫ ЬШХЯТЧР МШЧЯОб ПОКЬТЛТХТЭв ЩЫШЛХОЦЬ // SIAε RОЯТОа γ8(γ) (1996), Щ.γ67-4β6 6. DШХРв, D.., NЮЫЦТЧЬФТ, E.A. AММОХОЫКЭОН ЩКЫКХХОХ ЩЫШУОМЭТШЧ ЦОЭСШН ПШЫ ЬШХЯТЧР ЭСО ЬСШЫЭОЬЭ НТЬЭКЧМО ЩЫШЛХОЦ // AНЯКЧМОН SЭЮНТОЬ ТЧ CШЧЭОЦЩШЫКЫв εкэсоцкэтмь (KвЮЧРЬСКЧР), β01β.- Я. ββ (1), ЩЩ. 15γ-160...,.,,.,. :?,,. [1]: 1. 2., 3.,,,. [1]: () 85

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-,,, 15 15 β01γ. : http://www.cmap.illinois.gov/c/document_library/get_file?uuid=b50b8c4c-8bef- 44e4-83b8-af2a9ef0158d&groupId=20583 ( 24.03.2013). 4. TRANSIεS TЫКЧТЧР CШЮЫЬОЬ Д Ж: : http://transims.googlecode.com/svn/v4/trunk/documentation/usermanuals/ ( 25.03.13)...,,.,,..,,,,....,,.,,,,,,,..,.,,,.,,..., 103

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-,,, 15 15 β01γ.. 6. 1..... 1988. 8ββ 2. Simple Algorithms for BCH Decoding by Jonathan Hong and Martin Vetterli IEEE august 1995. http://infoscience.epfl.ch/record/33884/files/hongv95.pdf 3. : /....:, β008 199.:.... http://www.dissercat.com/content/metody-bystrogo-dekodirovaniya-lineinykh-blokovykh-kodov. 4.. 1986.. 5.. 1989.. 6. Shuhong Gao, ``A new algorithm for decoding Reed-Solomon codes'', in Communications, Information and Network Security (V. Bhargava, H. V. Poor, V. Tarokh and S. Yoon, Eds.), Kluwer Academic Publishers, 2003, pp. 55-68. 7. Additive Fast Fourier Transforms over Finite Fields by Shuhong Gao and Todd Mateer. http://www.math.clemson.edu/~sgao/papers/gm10.pdf,,..,,,..,, ДβЖ.... 108

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-,,, 15 15 β01γ. 2.,.. /.. //. : - 2005. 98. 3...,.. // Proceedings. IEEE International Conference on Advanced Learning Technologies (ICALT 2002). 9-12 September 2002. Kazan, Tatrstan, Russia, 2002, p. 102 106. 4... /.. // : -. -. 2003. β00. 5.,..,.. β. /.. // : 2004. 174.,,,...,,.,.., -?, -, «?».,?.,,,,....,,.. 100.,,..,,. :..,,. : 1),,. 111

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-,,, 15 15 β01γ.,..,.. 1. Gee J. P. An Introduction to Discourse Analysis: Theory and Method. 2006 UK, MPG book ltd. 2. Hilbert M., Lobin H., Barenfanger M., Lungen H., Puska C. A Text-technological Approach to Automatic Discourse Analysis of Complex Texts [ ] // : http://goo.gl/ltlru 2009. 3. Stede M. Local Coherence Analysis in a Multi-Level Approach to Automatic Text Analysis // Lexical-Semantic Resources in Automated Discourse Analysis 2008 Volume 23, Number 2 ISSN 0175-1336 4. Theijssen D. Features for automatic discourse analysis of paragraphs // Proceedings of the 18th meeting of Computational Linguistics in the Netherlands 2007 C. 53-68 5... :.., β004. -189....,.. -,,,. -.,,,.,,,,,. : 1) 2) 127

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-,,, 15 15 β01γ. USB--, USB-, USB USB 2.0, USB 3.0, ONFI., USB,,. 1. USB 2.0 (Universal Serial Bus Specification, Revision 2.0 April 27, 2000). : http://www.sdpha2.ucsd.edu/lab_equip_manuals/usb_20.pdf 2. USB 3.0 (Universal Serial Bus 3.0 Specification, Revision 1.0 November 12, 2008). : http://www.gaw.ru/pdf/interface/usb/usb%203%200_english.pdf 3. ONFI ("Open NAND Flash Interface" " - -"), γ.0 15 β011. : СЭЭЩ://www.onfi.org/specifications/ 4. Andrew Butterfield and Jim Woodcock. Formalising flash memory: First steps. In 12th IEEE International Conference on Engineering Complex Computer Systems, 2007, pages 251-260. IEEE Computer Society, 2007.,,...,,...,,,.., -. -. -,.,,,.,., : 134

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-,,, 15 15 β01γ. 2. 5β6γγ.5-β011... -.- ;. 01.1β.β011. 3... /..,... //, 1 (β5), β.- :, 2012.. 157-160. 4... /..,..,.. //. 50-...-.. :, β007.. 11β 115. 5..... /.. //.,....:, β009. β7β. 6. Dodis Y. Fuzzy Extractors / Y. Dodis, L. Reyzin, A. Smith // Proceedings from Advances in Cryptology EuroCrypt, 2008. pp. 3-6. 7. Katz J. Digital Signatures / J. Katz // Springer, 2010. p. 192....,....,.,,..,.,,.,.,,,,,.,, -.,.,.,,.,,,,,,,. 140

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-,,, 15 15 β01γ. IV.,..-.. -.,..-..,,..-..,,.. [1, 2] S,,,. S,, S., [3, 4]. S, 1 S. <A; L s > L s = {s s S} S- A s, a A s, t S 1) a(st) = (as)t; 2) a1 = a. S, A s S-. A s A s, ss. S- A s, A s B s, B s S-, fa s Q s, Q s S-, f B s Q s, f = f. S-. [3]. S. S- A s, As. K L [4], L, A K, A.. S-, S. 1..,..,.., КЧН... -, Ь- //. 2008,.14, 7.. 63-110. 2...,..,..,... - //. 2004..10, 4..107-157. 3. M. Kilp, U. Knauer, A.V. Mikhalev. Monoids, Acts and Categories // Walter De Gruyter. Berlin. New York. 2000. 4..,.. //.:. 1977. 144

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-,,, 15 15 β01γ.... (1),..,,.. 1...., β009, 1β.. 187 194. 2. Norberg R. Ruin problems with assets and liabilities of diffusion type. Stochastic process. Appl., 1999, vol.81, no.2, pp.255 269. (P,1)-,..-..,,..,,. -,.,,.,,. -,,.. : -., (1.1), (1.β)., [1].., 146

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-,,, 15 15 β01γ.., - -. Д4Ж, -,. Д5Ж, -,.,.. - -, -. 1..., -,,.4β, β (β00γ),. 194-210. 2. ε.d. εшыхов, CКЭОРШЫТМТЭв ТЧ ЩШаОЫ, TЫКЧЬ. AЦ. εкэс. SШМ., T.114 β (1965), 514-538. 3. S. Shelah, Classification theory and the number of non-isomorphic models, Stud. Logic Found. Math., T 92 (1978). 4..., -,,.46, γ (β007),. 346-359. 5...,... 8 (1988).. 9β-108.,..-..,,... S-,, Д1Ж. S-.. S. S- S A,, S-, A, S, S A. S- S A A, a, b A, s S a, b sa, sb, S A : 1 2 1 2, 1 2, 1 2, 1, 2 S A. Con( S A). a, b A S- S A n, c i A ( 0 i n) si, t j S, a c0, b cn sici 1 tici i, 1 i, j n. S- S A,. 148

-,,, 15 15 β01γ. Ai i I S- A ( I S i i )., S- S A S, S Sa, a A. S, S Sa S-. a S- S Sa, t sa ta. s a 1 a a S- S Sa 1 S a., S S. S L (S). F a a F a L (S), S a,.. T T S, Sa T., F a L (S). 1. S. S- S A, : 1) A = S i a A ( i I) I i, еiе γ; 2) F i I ; 3) Sa S i a i F a i F a j i, j I, i j. 1. S. S- S A, : 1) S A = i I, еiе γ; 2) L( S S ai ) - S Sa i I ; 3) L ( S S a ) L ( S S ) i a - S S j a S i a i i, j I, i j. Sa S i 2. S. S-, : 1) A S A ( i I ), еiе 2; S a S = i a i S A 2) F a, Iе 2; i 3) F a i F a j i, j I, i j. 2. S. S- S A, : 1) S A = i I S Sa i, еiе 2; 2) L( S S ai ) - S Sa i I ; 3) L ( S S a ) L ( S S ) i a - S S j a S i a i i, j I, i j. 149

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-,,, 15 15 β01γ.,.. G. f ( r, ). (), s. M. Intel Core i7 (3.4 GHz), 8Mb RAM., ( ). ms, Df ms, Rmsb, msb, Dfmsb, Rmsb, s, Dfs, Rs, -.,.,, : 2 2 f ( r, ) 1 r, a inf ( ( r) s ( r)), rg a 2 2 2 J ( r, ) 2( r) a ( 1 r ), h( r, ) 2, r 1, ( r) 0. a 10- G 1. : ( r) 4 ( r) 2, ( r) 2 ( r) 1. s a 6 N 10. s 1 M ms Df ms R ms msb Df msb R msb s 6 1.2494 0.1850 14.3413 1.2467 0.1753 29.8117 0.6123 0.3028 81.0665 7 0.5760 0.1828 16.7640 0.5507 0.1735 37.5338 0.2782 0.2969 92.5522 8 0.2741 0.1829 19.2286 0.2600 0.1730 46.2517 0.1076 0.2938 104.5137 9 0.1303 0.1830 21.8055 0.1126 0.1734 56.0604 0.0419 0.2932 117.5805 10 0.0470 0.1825 24.2303 0.0649 0.1731 67.3624 0.0344 0.2921 133.3343 1,.,. (r) G. M, ( ).,,., 10- β. Df s R s 158

-,,, 15 15 β01γ. 1...,..,....:, β000. β...,..,... -. :, 1976.,,,,..-..,,,..,,..,,. Д1, βж. -.,,,,. 2 k ij ij 2( e ij eij ) ij e e ( e ( T T0 )) 3,, k,, T 0,,.. (-776.β01β.1) (ИИ 1β-01-33064). 1..,...:, 1964. 5β0. 2..,.,..:, 1958. 168. 159

-,,, 15 15 β01γ.,,,..-..,,.. 1, [0,L]. Д0,L],,.... :. (, -).., Н,., : + +. 2 = (), Д0, δж, (), Д0, δж : 1, 2, 0, 1, 2... ( ), ( ). Д0, LЖ (x), Д0, δж, δ,. 3 1., (), 160

-,,, 15 15 β01γ. 1 () 2, 1 (()) 2 (2) (1), (β). 0 (β), (1)., Д0, δж (β) 0, : β. > 0 1 () 2, 1 (()) 2. 161

-,,, 15 15 β01γ.. 1.. 2. 1. Modern technology, machines and materials for winter road maintenance: Materials International. Scientific-tech. Conference-In.: Main features of the maintenance of winter roads. Belarussian-Russian University, 2010.-77c.( in Russian) 2. δк ЫШЮЭО ОЭ Х СТЯОЫ. JШЮЫЧООЬ НО T UЧТШЧ ЫШЮЭТОЫО К NОПЭК (TЮЧТЬТО), β1-22 Nov. 1985 // Rev. Gen. des Routes. 1985. 3. Elsenar P. Current views in Europe on improving methods of dealing with snow and ice. In.: Wrestling with snow and ice for transport. Moscow: Transport, 1986. 4. Feltl D., Schuetler R. Snow removal service levels: defining results // Public Works. 1983. 114, 11. p. 54-55. FREEFEM,..-..,,..,,, Д1-γЖ.,. Д4Ж,. Д5-7Ж.. 162

-,,, 15 15 β01γ.. (),,,. 3 R : 3 (i) R,, e i 1 2, : 1, 2 e, const e const, p, p i, p e,. i., p, s p. p. e i, e inc p. inc p, s p. p inc s e p p 2 pi k pi 0 i, div( 1 pe p pe, ( p) n n e e p i e : 1 2 2 p) k p f, pe k pe 0 e, 1 pi e, p pi, ( p) n i, n i, p (1) (2) s p ( x) s 1 ikp (x) o( r ) r x. (3) r k, f, (γ) 3 R, n,. B R R R,., (1) (γ) p s, p i, p e B R, (1), (β) e s p R, : s p s Tp R n. (1), (β), (4). V H 1 ( B R ), S 1, S V. H ( B R ) S. inc 1 a ( P, S) F ( S) f, S f Sdx S X, (5) a( P, S) 2 1 2 2 ( p S k pi S) dx (( p) S k0 ps) dx ( pe S k0 pe S) dx i F ( S) i T( P) Sd, f inc, S 0 1 f Sdx, f inc, S R Tp inc e Sd (5) (1), (β), (4). R p n inc (4) Sd. R 163

-,,, 15 15 β01γ. ().,.. FЫООFОЦ++ --,...,.,, ДγЖ. ( 14.18.21.0353). 1. S.A. Cummer, D. Schurig One path to acoustic cloaking // New J. Phys. 2007. V. 9. P. 45. 2. Cummer S.A., Popa B.I., Schurig D. et al. Scattering theory derivation of a 3D acoustic cloaking shell// Phys. Rev. Letters. 2008. V. 100. P. 024301. 3...,.. //.... β01β.. 15, β. C. 1 6. 4...,.. //.. β010.. 180, 5.. 475 501. 5. G. V. Alekseev(2013): Cloaking via impedance boundary condition for the 2-D Helmholtz equation //Applicable Analysis: An international Journal, DOI 10.1080/00036811.2013.768340 6...,..,.. //, β01β,. 447, 1, 7-12 7. //freefem.org NVIDIA CUDA,,,,..-..,,,.. CPU GPU. N IDIA CUDA,. ( )... 164

-,,, 15 15 β01γ. γ659 (4γ8γ),. : 4γ-.,.,,., ( )., «-»..,,..,,. Д1, β, γ, 4Ж.,..,., Д5, 6, 9Ж Д7Ж. Д9Ж, () x i Deij p 1 p p ij ij ( ik ik zik ) ekj eik ( kj kj zkj ), Dt 2 Dpij Dn p p p ij dnij ij pik kj ik pkj, riknkj nikrkj, (1) Dt d ij e ij p ij 1 2 e ik e kj Dt e 1 ui 1 ij v i, j v j, i, v i vmui, m, rij wij zij ( eij, ij ), w ij v i, j v j, i, 2 t 2 (1) u i, v i p () () ; e ij ij d ij ; ik p kj dt p ik e kj e D / Dt ; p ij p ij, zij z ji r ij, [9Ж, w ij. (1) ( p ij 0) p ij. ik p km e mj, 165

-,,, 15 15 β01γ. «-»,,, W ij p1 ij kj ekj, pij 0. (2) e (β) p 1, W, 2 3 W a J 1 aj 2 bj 1 J 1J 2 J 1..., 1 1 (3) J 1 ekk eskeks, J 2 estets eskekt ets eskekt etnens 2 4 a,, b,,.,, f 0 ij..,,,.,, Д7].., (1),. (β) ( ) (γ)., p ij V, ij V ik 3 1, ii (4) 2 3 n 2 2 2 ( ) B, ( 1/ 2 1 ) ( 2 ) ( 3 ) B n, 1, 2, 3. () «-»,., r r0 r R, : u 0. (5) r R r R, : r 1 cos ( r, t)), u r sin ( r, t), ( r, t) (1 ), (6) u r ( 0 0 t u r u 0, r R, (7) ( r, t). : 1 1 d g 2, d g rr r, g r. (8) 2 2 r 166

-,,, 15 15 β01γ. : rr rr r r 0, 2 0. (9) r r r r : 3 n n dp 1 2 2 (1 ) 2 3 1 rr Bn err e Q p rr r pr, 4 r r Bn rq dt e r dp dt Bn Q 4 n err e 2 ) 2 3 r pr r r Bn rq, (10) er 3 n 1 2 (1 p 1 2 n dpr 1 2 2 3BnQ (1 prr p ) r r r ( prr p ), 3 err e Q 1 r. dt er (9) (10) -. -,. (-776.2012.1) (ИИ 12-01-33064). 1... - //.. 1948.. 1β,. 6.. 650-661. 2... - //. 1961. β.. 79-86. 3...,.. -..: -. -, 1970. 415. 4... //.. 1959.. βγ,. 6.. 998-1014. 5...,..,.. //. β000.. γ75, 6.. 767-769. 6...,..,.. //.. β00γ.. 67,. β.. γ16-325. 7...,..,.. //... β006.. 47, β.. 110-119. 8.....:, 1966. 75β. 9...,..,.. //. 1996.. γ47, β.. 199-201. 10...,..,.. //... β008.. 49, β.. 14γ-151. 11.... :, 1997. β78. 12.....:, β007. β64. 167

-,,, 15 15 β01γ...-..,,....,, (.,, Д1 4Ж).,,. (. Д5Ж),..,. [6, 7]. 3 R : 3 (i) R i, e, : i e., e, const e const, p p e. i., p, s p. p e i e e inc p. inc p, s p e e. p p inc s e p p e : 2 2 p k p f, pe k p e 0 e, (1) 1 p 1 pe 1 p p pe, e, g i, (2) n n n e s p ( x) s 1 ikp (x) o( r ) r x. r (3) 168

-,,, 15 15 β01γ. k, (x), f, (γ) 3 R, g i,,. B R R R,. (1) (γ) B R, (1), (β) e s p : s p s Tp. R (4) n (1), (β), (4). V H 1 ( B R ) S, V S V. S. inc 1 a ( P, S) F ( S) f, S f Sdx S X, (5) a( P, S) 2 1 2 2 ( p S k pi S) dx (( p) S k0ps) dx ( pe S k0 pe S) dx i i 0 T( P) Sd, e R inc inc 1 inc inc p F ( S) f, S f Sdx, f, S Tp Sd Sd. R R n (5).. (),.,,.,,. FreeFem++ [9]. ( 14.18.21.0353), 12-1-17-03, 17 12-III--01-002. 1. S.A. Cummer, D. Schurig One path to acoustic cloaking // New J. Phys. 2007. V. 9. P. 45. 2. Cummer S.A., Popa B.I., Schurig D. et al. Scattering theory derivation of a 3D acoustic cloaking shell// Phys. Rev. Letters. 2008. V. 100. P. 024301. 3... //. β010.. 4γ1,. γ19 322. 4...,.. //.... β01β.. 15, β. C. 1 6. 5...,.. //.. β010.. 180, 5.. 475 501. 169

-,,, 15 15 β01γ. 6. Alekseev G.V. Cloaking via impedance boundary condition for the 2-D Helmholtz equation // Applicable Analysis. 2013. V. 9γ, 5. P. 1 15. 7... //. β01γ.. 449, 6. C. 1 5. 8... //. β004.. γ95, γ. C. 322 325. 9. //freefem.org,..-..,,... 50- [1]. β007.,. ( ),. (. 1),, - p, F,.. 1.,,.,, 170

-,,, 15 15 β01γ.,,.,, Current Hole..,,,. FreeFem++ ДβЖ. FreeFem++. 1. http://www.femto.com.ua/articles/part_2/4106.html, 2. http://www.freefem.org/ff++/ FreeFem++ home page 3...,..,,. 4. V.D. Shafranov. Plasma equilibrium in a magnetic eld. Reviews of Plasma Physics 5...,...,. I-. //......,..-..,,.. Д1Ж,,. [2 4Ж,,. Д5Ж..,.,.,,,,,,.,,.,., 171

-,,, 15 15 β01γ..,,.,. Д6Ж. Д7Ж. Д8Ж,Д9Ж..,,, (1) (2),, (3),,, (, ),,.,,., (β) H- [10 12]., ( ) (),, (1) (γ)., :, (4),,,.,,,. (1) (γ),,.,.. ( 14.18.21.0353). 172

-,,, 15 15 β01γ. 1. Pendry J.B., Shurig D. and Smith D.R. Controlling Electromagnetic Fields// Science. 2006. V. 312. P. 1780 1782. 2. Chen H., Wi B. I., Zhang B., Kong J.A. Electromagnetic wave interactions with a metamaterial cloak // Phys. Rev. Lett. 2007. V. 99. 063903. 3. Cummer S.A., Popa B.I., Schurig D. et al. Scattering theory derivation of a 3D acoustic cloaking shell // Phys. Rev. Letters. 2008. V. 100. P. 024301. 4...,.. //.... β011.. 14, \No~2, C.~1 6. 5...,.. // 6... β010..з180, \Noз5..з475 501. 7... //. β01β..з44β, \NШз1..з41 44. 8. Alekseev G.V. Cloaking via impedance boundary condition for 2-D Helmholtz equation // Appl. Anal. 2013. V. 93, N 5. 9...,.. //.... β011.. 14, \Noз1..зγ 16. 10...,..,.. //. β01β.. 447, No 1. C. 7 12. 11...,.,... 12..:. 1991. ββ4. 13... //. 1948..зβ..з5. 14..., Conna M.C. ( )... β00γ.,,,...,..... ( ),.,,,,. : 1) (GPS, ); 2) ( );,,, 173

-,,, 15 15 β01γ.,,,.,, : 1) ( ); 2) ( ); 3) (, ). -.,,.,,,,, -.,,,, -.,,,,.,.,..,,,.,,.,., : 1) ; 2) ; 3).. 1. ();, ().,., 174

-,,, 15 15 β01γ., (. 1 ()), ( β ()),,.. 2. (); ().,.,,,,,.,,,,,,,..,, (. γ (), ).. 3. ();, (),,,.,,,. 175

-,,, 15 15 β01γ.,,,,.,,,.,,,,,.,. 1. (.. 2-.,...: -, β005. 416 :.) 2. 1βγ (. ;......:, β007. 544 :.) 3. (.;......;, β007. β88.:.) 4. (,...,, http://gc2009.graphicon.ru/files/gc2009/proceedings/young/section2/72/72_paper.pdf) -,..-..,.,,..,.,,,.,.,,,,.,, 176

-,,, 15 15 β01γ. : (1). (1) (γ),, (4),(5),,. (4),(5) : (6) Д1Ж. (1) (3) (6) (6). (1) (3).. 1. (1) (γ), 177

-,,, 15 15 β01γ. (8) (9). : (10). : (10). 2. (10), (11): (11) (9). (10), (11), N..1 N. (12).1. N..β 178

-,,, 15 15 β01γ..β.,, (8), (9), N. 1...,.. //.:, β006. 151.; 2... // БББ I -..,, 4-10 β01β..175-181; 3... // 5γ, 4.. 26 32.,,,,..-..,,,.., [1]. (, ),,,... [2], () x i Deij p 1 p p ij ij ( ik ik zik ) ekj eik ( kj kj zkj ), Dt 2 179

-,,, 15 15 β01γ. Dpij Dn p p p ij dnij ij pik kj ik pkj, riknkj nikrkj, (1) Dt Dt dt 1 ui ij v i, j vj, i, v i vmui, m, 2 t 1 rij wij zij( eij, ij), w ij v i, j v j, i, 2 1 dij eij pij eikekj eik pkj pikekj eik pkmemj. 2 (1) u i, v i ; e ij p () () ij d ij ; D/ Dt ; p ij p ij, zij zji r ij, [2], w ij. (1) ( p ij 0) p ij.,, W ij p ij kj 2d kj, pij 0, d ik (2) W ij p1 ij kj ekj, pij 0. e ik (β) p, p1, W, 2 3 W a J aj bj J J J..., 1 2 Lk, pij 0 J k, L1 d kk, L2 dikd ki, (3) I k, pij 0 1 1 I1 ekk eskeks, I 2 estets eskekt ets eskekt etnens 2 4 a,, b,,., f, 0..,,,.,, [3]. D ij ij 1 2qij 2 2 ij, (4) Dt 1 1 2 1 ij 180

-,,, 15 15 β01γ. 1 1 D ij d ij ij ij kk ij, qij dij d kk ij, wik kj ikwkj 3 3 Dt dt. (4) D ij ij 1 2lij 2 2 ij, (5) Dt 1 1 1 lij eij eisesj ekk ij eskeks ij. 2 3 6..,., - (4) (5),..., (1),. (β) ( ) (γ)., p ij V 0, V( ) B, ij n 2 2 2 ( ) ( ) ( 1/ 2 3 1 1 2 3 ), ii (6) 2 3 B n, 0, n, 1, 2, 3. () «-» ДγЖ. n p( ), 0. (7) rr r R( t) t rr r s( t) R( t) r0, p (t), s (t), rr r,, z. (t) :, (8) 2 1 2 2 2 2 2 u r r ( r ( t)), ( t) R0 R ( t) r0 s ( t) u ur. 181

-,,, 15 15 β01γ.. ( ( rr 2k )) p p0 r s0. 2 2 2 2 ( t) R0 R r0 s0 const. (t) p (t) p 0 p( t 0 ),.,,. (-776.2012.1) (ИИ 12-01-33064). 1... //, β008, β.11-17. 2...,..,.. //.. 1996.. γ47, β.. 199-201. 3...,..,.. //... β006.. 47, β.. 110-119.,,..-..,...,,,.., -,,,.,. Д1Ж...,., r R0, r r0. 182

-,,, 15 15 β01γ. ( r,, ),.,..., [2, 3Ж,, : r1 r R0 r0 r r1, r r1. 2. u1 ( r) c1r c2 r.,, [2, 3],. c4 2 u2 ( r) c3r F r dr r dr 2 r ( ). c 1, c 2, c 3, c : 0, 0, u 0, 4 0. rr r r 0 rr r R,,, ( ): k, F (r), rr 2 p A e p p 1 p 2 3 p e rr rr B, e e 3 rr, : F ( r) r 2 e rr. 2 r r, B, k. 1 3 : r1 ( A/ B)., A p. e rr, r r0., p ( r0 ) : err ( r0 ) d rr ( r0 )., (3 2) r ) 0 ( 0 d rr ( r 0 ). β0, 11 10 6 2.110, 8.110, k 400 10, r 0. 0 2, R 1, 0 0.01152 6 d, 80010 rr r r 0 r r 0,.1. rr r r 1 r r 1 183

-,,, 15 15 β01γ.. 1. -.,.,... e 3 K( T T0 ) 2e, -, ij ij kk T ij 6 T 11.5 10-1, 2 3, T, T 0. k,, [4]. r 1. : r p1,.,,. β.. β.,, 184

-,,, 15 15 β01γ..,, -,, r p2. 1...,.. //. β000. γ.. 1γ0-134. 2...,..,.. //. β000.. γ75. 6.. 767-769. 3...,..,.. //. β00γ.. 67.. β. γ16-326. 4.. (..,.. )..:. 1991.. 1βγ1.,..-..,,.-.,..,., [1].,,.,,,. 16%..,,,,.,,,. 201. 1.....,.. //.. 1996.. β47, β.. 199-185

-,,, 15 15 β01γ. -,..-..,..,,.,,..,.. Д1-5].,,.,,., Д6,з7Ж..,,,., -. R d, d=β,γ (), : div( ) k f,. (a) ( x) 0, x, k k( x) 0,, f f (x), (x). (1),.,, 186

-,,, 15 15 β01γ..,, d (x), Q., k,., 1 Дγ-5Ж. 2 2 d L Q d dx r( ( ) d ) Q I( ) 2 I : H () R dx. r Q. (,k) (1) 1 2 J : H ( ) L ( ) R,.. : (, h ) ( k, h) ( f, h) in,, (2) 0 2 1 2 1 2 J (, k) d 2 k 2 inf, (, k) H ( ) L ( ) L ( Q) L ( ) 2 2. (3) (β) (1), µ 0 0, µ 1 0,.,, Дγ,.γЖ. ДγЖ, : (, h) ( u, h) ( k, h) ( f, h) in,, (4) (, ) ( u, ) ( k, ) (, h ) Q 0, (5) ~ 2 ( 1k, k) 0, k L ( ). (6) -.., -, FreeFem++. (σ10-01-00219-, σ11-01-98508-ии, 12-01-31288 И), ( 12-III-A-01M-002) 12-1-17-03, 17. 1.....:. 198β. γ19. 2...,....:, β004. 480. 3...,.., :. β008. γ65. 4... - //... β010.. 10, N β.. 9γ-105. 5...,..,.. -- //. β01β.. 5β. N 1β.. β190 2205. 187

-,,, 15 15 β01γ. 6. : //. β010. 1. 1.. 4β-45. 7... //. β007.. γ.. 1-4....,......,.., [1]. (). (,,,.),. 1.,,,.., - (.1).. 1.,., 90.,,..,,.,. -,.,. 188

-,,, 15 15 β01γ. [3].,.,..,,.,,.,.,,.. β. 1.. β.,.,. 1... //. 2009. 7. 2.. 3..,..-..,..,. (.,, [1]),.. 189

-,,, 15 15 β01γ...,,,,. 2 R. [2,3], u : 2 e R \ C, : 2 u k u 0 u u inc s u, inc u, e (1) u ik u 0 n (2) s u s lim r ( iku ) 0 r. r (3) s u, k,, 2 (3) R. (1) (γ),. B R R R,. e e BR. 1 2 2 ( ), ( ), ( ), 1/ 2 2 ( ), 1/ s H L Q L H H ( ), L ( ), H ( ) * 1,, * Q, *, * 1/ 2,, * 1/ 2,, *, * s Q e e r R R L ( ), e, r r R R. B r r R, B r. [2,3], (1) (γ) (1) (β), : s u n Tu s R : 1/ 2 2 T H ( ) H 1/ ( ), R ~ R 1/ 2 u h H ( R ) H 1/ 2 ( R ), u ~ n \ B c u R h. 1 a ( u, ) a ( u, ) a( ; u, ) f, H ( a ;*,*) f : e R ~ 0 e. 0(*,*), a( 2 a ( u, udx k udx Tud, a( ; u, ) ik ud, 0 ) R inc inc u f, Tu d d. n R, : R ) 190

-,,, 15 15 β01γ. 0 1 2 inc 1 J ( u, ) I( u) s, inf, G( u,, u ) 0, ( u, ) H ( e) K 2 2, 0 1,, K H s ( ), 0 1 s, 0 0, G : 2 inc G( u,, u ), a0( u, ) a( ; u, ) f,. I : 2 2 2 I ( u) u u u u dx, I ( u) u u d. 1 d Q d Q 2 d r (). FreeFem++ [4].,,.. ( 14.18.21.0353). 1...,.. //.... 2012.. 15, β. C. 1 6. 2... //. β01γ.. 449, 6,. 1-5. 3. Alekseev G.V. Cloaking via impedance boundary condition for the 2-D Helmholtz equation // Applicable Analysis, 2013 4. www.freefem.org/ff++/,..-..,.., ( ) (. Д1Ж, ДβЖ).,. «-»,., 2 R., (). 191

-,,, 15 15 β01γ.,. 2 R : 2 (i) R, e i e : i e. i,, e,, e = const e = const e, p p i p e i e. k = / c,., e e inc p. inc p, p, e s p. p s p. p i + k 2 p = inc s p e = p + p p = 0,div( i 1 p 1 pe, = n i e 1 pe n e p i e (. ДγЖ, Д4Ж): 2 p)+ k p = f 1 p e, = g n, p + k i e, 2 p e = 0 e, i, p s p (x) s 1/ 2 ikp (x)= o(r ) r = x. (3) r,, f, (γ) 2 R. B R R R,., (1) (γ) (1), (β) e s p (. Д5Ж): s p s = Tp. R (4) n 1. (1), (β), (4). 1 V = H (B ) S, S V R. 1 S. : inc 1 a ( P, S) F ( S) f, S f Sdx S X, (5) a( P, S) V (2) 2 1 2 2 ( p S k pi S) dx (( p) S k0ps) dx ( pe S k0 pe S) dx i i 0 T( P) Sd, e R F ( S) f inc, S 1 f Sdx, f inc, S R Tp inc Sd R p n inc Sd. (1) 192

-,,, 15 15 β01γ. (5). 1. ().,, (. Д6Ж, Д7Ж). FЫООFОЦ++.,,,.,.,. ( 14.18.21.0353). 1. S.A. Cummer, D. Schurig One path to acoustic cloaking // New J. Phys. 2007. V. 9. 45. 2...,.. //.... β01β.. 15, β. C. 1 6. 3.... :, β011. 45β. 4.... :, β006. 5. Alekseev G.V. Cloaking via impedance boundary condition for the 2-D Helmholtz equation// Applicable Analysis. 2013. V. 93, 5. P. 1 15. 6....... β010. 7. http://www.freefem.org/ff++/index.htm,.....-..,.. ().,.. () () (),,,,,. 193

-,,, 15 15 β01γ.. Д1, βж.,.. 1 % β%.,,. 5 9. Д1, βж, -,... :, ( ). 1.,. β.. γ.. 4.., (β000.)...,..., Дγ] 5 5 5 H * * CA H b0 b i xi b ji xi x j. i1 i1 ji..,,..,,,. 194

-,,, 15 15 β01γ. 1.,. β.,. γ.,. «-» 2009 2013. (. 14.18.21.0353 6 2012.). 1...,..,....:, 1974. β46. 2...,....:, 198β. 496. 3... :..:, 198γ. γβ8. 4...,... :. β008. γ65. -..-..,..,,..,,.,. : ( ), m, h,, d v, h c,,. 195

-,,, 15 15 β01γ.. M 0, H e.,,,,. -,.. - : (1), (2) : E, h i, i-, m i i-, r ij - i- j-. - -[1],., ( )., : E, M r, M s, h i m i,,,., d = 10, M 0 = 500 1 3, p, h c m i. 1: a) β5, Hc = 1, p = 20 ; b) 64, Hc = 10, p = 40. (3) 196

-,,, 15 15 β01γ... a) b) Magnetization (Norm.) Field (Oe) Magnetization (Norm.) Field (Oe). 1. :a) 5x5 ; b) 8x8. ДβЖ, β: (a) (Ni 80 Fe 20 ) γ0, ; (b) (Ni 80 Fe 20 ) γ0.. 2. ДβЖ, : (a) (b),,,,. 197

-,,, 15 15 β01γ.,.,,,,.,. 1. E. C. SЭШЧОЫ, E. P. АШСХПКЫЭС, «A εомскчтьц ШП εкрчоэтм HвЬЭОЫОЬТЬ ТЧ HОЭОЫШРОЧОШЮЬ AХХШвЬ». Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, Vol. 240, No. 826. (May 4, 1948), pp. 599-642. 2. A. τ. AНОвОвО, N. SТЧРС, S. GШШХКЮЩ, SЩТЧ ЬЭКЭО ОЯШХЮЭТШЧ КЧН magnetic anisotropy of elongated Ni 80 Fe 20 ЧКЧШЫТЧРЬ. J. AЩЩХ. PСвЬ., 98 p.094301 (2005)...-..,..,,.,,,.,,.. ( ).,. x1 0,. t 0 x1 0 u u x, t, u u 0. 2 1 1 3 u 1 3 u uc, C, a b d. (1) 2 2 2 1 1,11,1 : g t, t 0, g0 0, u x1 0 0, t 0. (2) 198

-,,, 15 15 β01γ. t 0. 0 0 g t, g,. t,. t : 2 2,1,1,1,1,1 G t C 1 3u 3 u, u u u, (3), G t, «+»,,,. u,1 0. : u 0, u, 0, t G d. (4),1 11 t t t t (1) : 1 1 1 1 1 1 s xc T, m tt, w s, m u x, t C T, 1, (5) 1 1 T,. (5) w 1 3 w w, 2 2, ss, s, mm s0 w f m, m 0., w s, m. (6), 2 3 w s, m f 0,5 f s, m s. (7) (7)..,. n 2 s, p s m, w w n, p. v 1,5 v v 0, v w, w w... (8) 2 0, n 0 0, m 0 0, m 0 (8),,.,,. (8) v 0. t 0 (6) 199

-,,, 15 15 β01γ.. (8) 2 v F p 1,5 v n, (9) 0 0 F,. ( w n p ), 0, v n p. 0,, (9) 2 w 0 w0 F p 1,5 n. (10) p p (10) w 0 p, n. w n p,. : w0 p, n,, (11) p,. n const, n (11) dw0 d, (12), (10).,n. 2 2 1,5 nv p, v f, p, n 1,5 n, 0. (13) : 0 0 0, (11) 3 W 0n, n f f 0n 2 pn, 1,5 n f, 0 n, t n n 0, W0 n, 0, 2 p0 p, n0 1,5 n0 f (14) n n0. n, 0, n n 2 0 n2, p p0 n dn f 0 1 3 n0. 2 d f f : (15) 200

-,,, 15 15 β01γ. t 0 : 1 f n0 3 f (16) 3 f p0. 2 f n. 0 0, ( f )..,,..,,,.,,..-..,....., -.., ( 1 ) ( 2 ).,,. ur r ( 1 cos ), u r sin, uz u( r, t), ( r, t), (1) r,, z. t 0 0( r ) u u ( r) 0. t 0 : 2 2 ( r 0, t) 0 ( r0 ) f ( t), u( r0, t) u0( r0 ) g( t),( f '(0)) ( g' (0)) 0 (2) f (t) g (t). ( r R), ( R, t) 0 u( R, t) 0. 201

-,,, 15 15 β01γ.,. [1-3] j j ( i) ( i1) ( t ti ) ( r, t) ( r, t) [ ], j j1 t j! tti j j ( i) ( i1) u ( t ti ) u ( r, t) u ( r, t) [ ], j j1 t j! tti r ti Gi ( ) d, r0 «i» i, G i, i,. j j j j [1] [ / t ], [ u / t ] - [4]... 1 u,.,r static, r r (3) 2 1 R r0 2 1 t 0 G2 G 1 2 r r r,r static ( r 0, t) u( r 0, t) 2. 1., T 1 1 r R. T 1 / 5. 1. 202

-,,, 15 15 β01γ. 1.... :, 1999. 8. 2...,... :. 1998. 3...,.. :. -, β006.. 47. 6. 4....:. 1964. 203

-,,, 15 15 β01γ. VI.,..-..,......,..,., (-1),., ().,,..,.,.,,..,,,., : 1., :,, :,. 2., :,,. 204

-,,, 15 15 β01γ..,,.. γ.β18... 1 2 2. 1., 2, 2 + : R 1 2 (..1), 2,.,. I,, v. 1 β.. (. β),,,,,, (, ),. 1 2 3 4 5 6 7 8 9 10 1 3 11 12 13 14 15. β. γ.β18 Д5Ж : 1-; β- ; γ- β; 4-; 5- ; 6-; 7- ; 8-; 9- ; 10- ; 11- ; 1β-; 1γ-; 14 -; 15-,,,. (. γ),.,,,,.. 205

-,,, 15 15 β01γ. 1 2 3 4 5 6 7 8 9 10 11 9 12 13 14 15. γ. γ.β18 Д5Ж : 1- ; β-; γ - ; 4 - ; 5 - ; 6 - ; 7-; 8 - R i ; 9 - ; 10 - ; 11 - ; 1β -; 1γ - ; 14 - ; 15 -,.,..,,., -.,.,...,...,,,..,,.,,,,, Д5, 3, 1]. 206

-,,, 15 15 β01γ.,,,. Д2,. 745Ж.,.,,,.,,..,., Z. Д4Ж, q r.. r F 0 0., q, Ы,.,. B Z Z c db/dt E.,,,.,,.,,,..,,,.,. 1.....,, 1985. 576. 2.... 1.. :, 1969,- 91β. 3.....:., 198γ.-46γ. 207

-,,, 15 15 β01γ. 4....:, 198γ, 416. 5..... 2..:, 198β. - 496., -,....,,. Д5].,,,,,,,..,,,,,,..,. :,,,...,,, -,, [7].,. Д6]... - [7]...,, Д3]. 208

-,,, 15 15 β01γ.,,.,,.,. [8].,,,,, [4]., ; Д1].,.,,,..,, -..,,,.,,,..,,,.., ( 9 11 ),.,. : γ0%. :,,,,,,.,. 209

-,,, 15 15 β01γ., : - ; - ; - ; -,, ; - ; - ; - - ; - ; -,. Д2]: 1., (,,, ). β.,. γ.. 4.. 5. ( ).,,.,.,,,. 1... //. 2008. - β. - 118 c. 2.,... -.:, 1987. 3... :. /.....-.β0-. / :, β010.- 568, Д1Ж.- ( )..476, ISBN 978-5-222-17319-0 4. : 4..: /.... 2001. 5... // - «,,». (β5 β011 ). --: -, β011..β71-276, ISBN 978-5-85094-435-3 6.. :... : 1γ.00.0β / ; Д :... -Ж., 2008. β68. :., 61:08-13/88 7. C.. :.... /..,..,.. ;....- 7-.,.-.:, β007.. 576. 210

-,,, 15 15 β01γ. 8...:, 1983.,...,.., XXI.,,,,.,,.. «( )»,.,,.,,,,, -,,. : 1), β), γ).. -,. -,., : 1), β), γ), 4). 211

-,,, 15 15 β01γ. () :,,,,,..,. -,..,,,,,,,,,,,,,.,,,.,,.,....,., -,.., -. 212

-,,, 15 15 β01γ.,,,., [6].,,,. [1].,,.,....,,,..,, Д2]...,..,..,..,..,,,,,,.,, : -, - -. - -, -, -., 1 β,4 50 130 Д3, c. 4]..,. -,,,,,,.,,. -,,, 0,01γ.,,,,,. -40,,,,,,,, -14, -87, -210 [3, c. 5-6]..., -,...,.,. 213

-,,, 15 15 β01γ.,.д2],, :? " ", 99/β009, β.6.1.β61β-10.., 0.5 ( 50 /), 0.β ( β0 /),. γ-4. ( 0,γ /), (0,0β5-0,5 /),, (0,γ /), ( 0,1 /), ( 0,0β /), (0,β /), (0,1-0,5 /), (0,β /). γ, 0.β, 0.005-0.020 /, () 0.001. " ",, ( 70 ) 70,.Д8, 9..β, 4,7] «:,,»,,.. ( ): 1. < 10. 2. 100 (10 ). -. 3. > β00 -,. 4. 500-1000,.,, 5. 1000-1500 (, ),,. 6. 1.5-β.5 (1500-β500 ). β. 7. 2.5-4 (β500-4000),,. : 1. 3-4, 50% ( ). 2. 4-7 (4000-7000 ). 3. 7 (7000 ). 100%. 214

-,,, 15 15 β01γ. 4. 10 (10 ) β-γ. 5. 15 1 5 Д4,5,7].,. 1.,. : 5.:. :. /.,..,....:, β005. 158. 2.. /.,....:, 2008 1β. 3... : /..,..,..,..,.. : -, β008 52. 4. 99/β009 5. :,, /...... :, 1990. 80. ISBN 5-03-001172-2. 6.,.. /... /. -.,... (..);..,.... :, 1998. βγ8. 7. β.6.1.β61β-10 8. 9 1996. 3- " " 215

-,,, 15 15 β01γ. VII.,..-..,.....,..-.. -......-..,........,. -,, (,, ),.,,.,.,,., -.,., -. β010 β01β.,,. 1. (ε К ). (ε ЛМ ). (П(r)), (N К ), 216

-,,, 15 15 β01γ. (N П ) (N М ) -5., [1],. γ1960..,, :,,,. 1. 08.β010 1β.β01β : ) ; ) ; ) ; ). Д2Ж (70-80%),,,. 98%±10%,, 217

-,,, 15 15 β01γ. 50%±β0%., -. ( 90%). -., 8β%.., з 41-42%., ЛМ, σ К (Ц 0,К ).1-,,., -., N К, ε ЛМ,,,.,,.,.,, σ К M ЛМ.,,,,. M ЛМ,,. (. 1),,,.,,,,,,., ( 70%),, Ц 0,К (. 1).. M ЛМ,,. : 10 8-9, β1 ( ).,. 8-9, 10., M К. 218

-,,, 15 15 β01γ.,. (10 ) (0 ) 5 15.. : 1) ; β) ; γ).,.,,. 1...,..,..,.. //, β4, β011, 06,.5γ8-546 2... //, 95, 1968,. 1. Ln 2 O 3 (Ln = La, Lu)...,.., - Firefly 7.1.G [1], -. - B3LYP5. Ln 2 O 3 (Ln = La, Lu) : MIDI MINI, (Crenbl), -- -- (SBKJC), (Cologne) - (WTBS) [2]. SBKJC - SVP O. 46. D 3h, Ln 2 O 3 (Ln = La, Lu) [3, 4].. 1 La 2 O 3. 1 La 2 O 3 Lu 2 O 3. Ln 2 O 3 (Ln = La, Lu).,,. 219

-,,, 15 15 β01γ. La 2La La2O3 3O O (D 3h ) 5d 6s e' a 1 ' a 2 ' 4e' 4a 1 ' 3a 2 " 2e" 3e' 5p e' a 2 " e" a 1 ' 3a 1 ' 2e' 2a 2 " 1e" 1e' e' a 1 ' e" a 2 " 2p 2a 1 ' e' 2s a 2 " 1a 2 " 1a 1 ' a 1 ' a 1 ' 5s e' a 1 ' e' a 1 ' 1s. 2. La 2 O 3 : La 2 O 3 Lu 2 O 3 La 2 O 3 Lu 2 O 3 E () - La O E () - Lu O -517.9 a 1 ' 0% 100% -517.4 a 1 ' 0% 100% -517.9 e' 0% 100% -517.4 e' 0% 100% -38.8 1a 1 ' 100% 0% -60.0 1a 1 ' 100% 0% -38.5 1a 2» 100% 0% -59.9 1a 2» 100% 0% -24.2 2a 1 ' 62% 38% -31.3 2a 1 ' 100% 0% -23.1 1e' 54% 46% -30.3 1e' 100% 0% -21.2 1e» 98% 2% -29.9 1e» 100% 0% -20.7 2a 2» 98% 2% -29.7 2a 2» 100% 0% -19.0 2e' 50% 50% -20.4 3a 1 ' 6% 94% -18.4 3a 1 ' 40% 60% -20.4 2e' 4% 96% -6.7 3e' 24% 76% -15.3 4a 1 ' 100% 0% 1 220

-,,, 15 15 β01γ. -6.7 3e' 24% 76% -15.2 3a 2» 100% 0% -6.5 2e» 24% 76% -14.8 1a 2 ' 100% 0% -6.2 4a 1 ' 34% 66% -14.8 4a 2» 100% 0% -5.8 3a 2» 20% 80% -14.8 a 1» 100% 0% -5.7 4e' 16% 84% -14.8 2e» 100% 0% -4.8 a 2 ' 0% 100% -14.8 3e' 100% 0% -14.8 5a 1 ' 100% 0% -14.7 4e' 100% 0% -14.6 3e» 100% 0% -6.7 5a 2» 50% 50% -6.6 6a 1 ' 40% 60% -6.6 5e' 22% 78% -6.2 4e» 16% 84% -5.4 6e' 10% 90% -4.4 2a 2 ' 0% 100% 1. Firefly. Version 7.1.G: http://classic.chem.msu.su/gran/gamess/index.html 2. Basis Set Exchange. Version 1.2.2: http://bse.pnl.gov/bse/portal 3. : http://en.wikipedia.org/wiki/lanthanum_oxide 4. «ChemSpider» The free chemical database: http://www.chemspider.com/chemical- Structure.2529886.html (IV) Cs(I),,.,..-..,..... Te(IV),,, -,. 221

-,,, 15 15 β01γ.. 1. TОBЫ 6 Cs 2,,,, - -,. (DFT) FireFly 7.1G, TZVP.. c (ECP). B3LYP5. εбps БP (τцтмышч, ). 1253,6 ev (MgKa). 410 9 mb., 50 ev β0 ev., AРγН5/β, 1,β ev. 1Ь.,..-.... - () in-situ. 222

-,,, 15 15 β01γ. ( ),.,. CaCl 2 γ,5 10-2 /.. - t d = 55 β00. β000.. 1. 1. 1 1 CaII (γ9γ,γ γ96,8 ) H (656 ), 7 ( ) 14. 14. Ca II H.,,. Ni(II).,..-..,..... d- М - - - 223

-,,, 15 15 β01γ.,, ; ; -;..... HeI Ni(acac) 2, Ni(acac) 2 dipy dipy γβ01. Firefly 7.1.G GAMESS-US; DF - BγδВP5,, def2- TZVPP. - (i) = (i) + (i).. 1. : - 224

-,,, 15 15 β01γ...... (), M(NO 3 ) 3 () 3 (M = Y (I), La (II); ),,, (). - ( ),. - GAεESS DFT - PBE0 ECPεАB. TDDFT β0.., (. 1) EЮ. - -,,.., 5,,.. 1. δк(nτ 3 ) 3 3 (). n N - *-. () I II,. -.,, La 3+ Y 3+, 235-1 β60-β80-1. 225

-,,, 15 15 β01γ.,. I, II,. -, 90%, *- Nτ 3. *- Nτ 3 Nτ 3.,,..,,...-....,,,,,. (),, - -.,. γ-4 Д1Ж. H 2 (7β5 8γ0 ) τ 2 (687 761 ) [2]. -.. 1. 226

-,,, 15 15 β01γ.. 1. : 1 SЩТЭПТЫО БP40F5А; β, γ ; 4 CОХОЬЭЫШЧ AНЯКЧМОН C11-SGTБδT, β79, : β800, : 1/10; 5,6 ; 7 800, 750, 700, 650, 600, 550 ; 8, β S-, - 800 50. β5, 795-805.. 2 :,.. β. S-. γ,,,.,,,.,,,. 227

-,,, 15 15 β01γ.. γ., OY (1=150), (40, 7, 1). 12-02-31714-И 1. Bourayou R., Mejean G., Kasparian J., RodriguesM.,Salmon E., Yu J., Lehrmann H. // J. Opt. Soc. Amer. B. 2005. V. 22. P. 369 377. 2. Wille H., Rodrigues M., Kasparian J. / Eur. Phys. J. Appl. Phys. 2002. V. 20. P. 183 190.,...,...,.,..,.. ( ), :.., :,,,,,,,,, D-,,, 228

-,,, 15 15 β01γ.. ( AбТШ τльоыяоы A1) ( LSM 510 Meta), : 350 nm, 448 nm,543 nm. 448 nm., :,,,,,., (C-OH, C-NO 2, C-NH 2 C-NO 2 ),.. 350 nm. :,,,,,,, D-. : C-OH, C=O, C-NH 2, C-OH., γ50 448 nm, 54γ nm,, :,,,,, D-,,,.,,. -..,..-.... (- ), Д1Ж.,,,,, ДβЖ.,,,.,. -,. () -. - -,, 400 [3]. -,., 229

-,,, 15 15 β01γ.,.,,,,..,. (), [4],. (), () 2,2- -4-(9-)-6--1,3,2-., 0.06 Д5] 0.005 8 Д6Ж., 60 β0. 4 40. β-γ, 1-1,5, β-γ. (1), Tsunami (2) Spitfire Pro (3) (Spectra Physics, USA). 800, FWHM = 50, β,5. 4β (4) (Newport Spectra- Physics PulseScout Autocorrelator SP LR). 2 1 3 4 5 6 9 10 7 8 5 230

-,,, 15 15 β01γ.. 3.,. β-γ (β,7*10 10 / 2 ).. (9). ( ) ~10 12 / 2... Hirox KH-7700 (10). 1. Braun, A., Korn, G., Liu, X., Du, D., Squier, J., Mourou, G., 1995. Self-channeling of high-peak-power femtosecond laser pulses in air. Opt. Lett. 20 (1), 73 75. 2. Schroeder, H., Chin, S.L., 2004. Visualization of the evolution of multiple filaments in methanol. Opt. Commun. 234, 399 406. 3...,..,..,..,.., 2,2- -4-(9-)-6--1,3,2-,, β01β,.11β, 4,.580-565. 4. Centurion, M., Pu,Y., Tsang, M., Psaltis, D., 2005b. Dynamics of filament formation in a kerr medium. Phys. Rev. A 71, 063811. 5. E.V. Fedorenko, B.V. Bukvetskii, A.G. Mirochnik, D.H. Shlyk, M.V. Tkacheva, A.A. Karpenko J. // Luminescence. 130 (2010) 756 761 6..,.,.,.., 1965,. 227-229. SrF 2, Zn 2+..-....,. (). SrF 2 Zn 2+. SrF 2.. 1%., Zn 2+ 231

-,,, 15 15 β01γ.,. γ0 γ5, β0. : //<100>, B//<110>. - //<100> 9., 8-. SrF 2 -Zn ±1/γ. 100 =85.56±1β.8γ, B//<110> β. 4.,, β5 ( 5, ; 5- ; β5 ). SrF 2 -Zn ±(β\3) 1/2 0. () 110-1 =106.95±16 110-2 =β5.76±γ.9. SrF 2 1%Zn : 100.γ7±10.0γ, 60.75±6.07., 2,2--4-(9- )-6--1,3,2-..,..-.... (- ), Д1Ж.,,,,, ДβЖ.,,,.,. -,. () -. - - 232

-,,, 15 15 β01γ., 400 [3]. -,.,,.,,,,..,. (), [4],. (), () 2,2- -4-(9-)-6--1,3,2-., 0.06 Д5] 0.005 8 Д6Ж., 60 β0. 4 40. β-γ, 1-1,5, β-γ. (1), Tsunami (2) Spitfire Pro (3) (Spectra Physics, USA). 800, FWHM = 50, β,5. 4β (4) (Newport Spectra- Physics PulseScout Autocorrelator SP LR)..,. β-γ (β,7*10 10 / 2 ).. (9). ( ) ~10 12 / 2... Hirox KH-7700 (10). 233

-,,, 15 15 β01γ. 2 1 3 4 5 6 9 10 7 8 5. 4. 1. Braun, A., Korn, G., Liu, X., Du, D., Squier, J., Mourou, G., 1995. Self-channeling of high-peak-power femtosecond laser pulses in air. Opt. Lett. 20 (1), 73 75. 2. Schroeder, H., Chin, S.L., 2004. Visualization of the evolution of multiple filaments in methanol. Opt. Commun. 234, 399 406. 3...,..,..,..,.., 2,2- -4-(9-)-6--1,3,2-,, β01β,.11β, 4,.580-565. 4. Centurion, M., Pu,Y., Tsang, M., Psaltis, D., 2005b. Dynamics of filament formation in a kerr medium. Phys. Rev. A 71, 063811. 5. E.V. Fedorenko, B.V. Bukvetskii, A.G. Mirochnik, D.H. Shlyk, M.V. Tkacheva, A.A. Karpenko J. // Luminescence. 130 (2010) 756 761 6..,.,.,.., 1965.. 227-229. 234

-,,, 15 15 β01γ. Cr(III)...,.., -.. Cr(AcacSCl) 3 ViSi(CH 3 ) 3. Omicron () ( 1β5 ). Firefly 7.1G B3LYP 6-311G Cr, O, C, H 6-311++G S, Cl, Si, (1).. ViSi(CH 3 ) 3, Cr(AcacSCl) 3.. HCl.. 1.. 235

-,,, 15 15 β01γ. VIII.,..-..,..-.. -...,.. - (), ТЧ ЯТЯШ.,.,. -, β- [10].,... 1. - (AnimalPAT) [4, 5, 9]..,, -, (. β). 236

-,,, 15 15 β01γ.. β., l, (. γ). l,. γ. - l = c*t, t -,. t = l/ 1-2 - D 1 D 2. -. - BGO, - - (+)., - (. 1). 1 CsI(Tl) NaI(Tl) BGO BaF 2 LSO LYSO SiPM (/ 3 ) 4,51 3,67 7,13 4.88 7,40 7,10 1 β50 300 40 1 = 630 2 = 220 40 100-β ( ) 565 415 480 1 310 420 420 420 () 2 220, BaF 2 SiPM, ββ0 100,. LYSO (LSO ). ( SiPM 2013 SensL.) 237

-,,, 15 15 β01γ. ( ) BaF 2. [8] 90, l = β,7. - LYSO, SiPM.,. 4. () () (). 4. BGO (), SiPM () LYSO () 1. Bloomfield, P.M.; Myers, R.; Hume, S.P.; Spinks, T.J.; Lammertsma, A.A.; Jones, T.: Three-dimensional performance of a small-diameter positron emission tomograph. Phys. Med. Biol. Vol. 42 (1997), S. 389-400 2. Bloomfield, P.M.; Rajeswara, S.; Spinks, T.J.; Hume, S.P.; Myers, R.; Ashworth, S.; Clifford, K.M.: The design and physikal characteristics of a small animal positron emission tomograph. Phys. Med. Biol. Vol. 40 (1995), S. 1105-1126 3. Bruyndonckx, P.; Xuan, L.; Rajeswaran, S.; Smolik, W.; Tavernier, S.; Zhang, S.: Design and physical characteristics of a small animal PET using BaF2 crystals and a photosensitive wire chamber. Nucl. Inst. Meth. Vol. A382 (1996), S. 589-600 4. Cherry, S.R.; Gambhir, S.S.: Use of positron emission tomography in animal research. ILAR journal Vol. 42 (2001): 219-232 5. Cherry, S.R.; Shao, Y.; Siegel, S.; Silverman, R.W.; Meadors, K.; Young, J.; Jones, W.F.; Newport, D.; Moyers, C.; Mumcuoglu, E.U.; Chatziioannou, A.; Farquhar, T.; Andreaco, M.; Paulus, M.; Binkley, D.; Nutt, R.; Phelps, M.E.: MicroPET: A High Resolution PET Scanner for Imaging Small Animals. IEEE Trans. Nucl. Sci. Vol. 44 (1997), S. 1161-1166 6. Correia, J.A.; Burnham, C.A.; Kaufman, D.; Fischmann, A.J.: Developement of a Small Ani-mal PET Imaging Device with Resolution Approaching 1 mm. IEEE Trans. Nucl. Sci. Vol. 46 (1999), S. 631-635 7. Fries, O.; Bradbury, S.M.; Gebauer, J.; Holl, I.; Lorenz, E.; Renker, D.; Ziegler, S.I.: A small animal PET prototype based on LSO crystals read out by avalanche photodiodes. Nucl. Inst. Meth. Vol. A387 (1997), S. 220-224 8. Moszynski, M.; Bengtson, B.: Nuclear instruments and methods 158 (1979) 1-31 9. Yao, R.; Lecomte, R.; Crawford, E.S.: Small-Animal PET: What Is It, and Why Do We Need It?, Journal of Nuclear Medicine Technology, Vol.40: S. 157-165 10. Zanzonico, P.: Positron Emission Tomography: A Review of Basic Principles, Scanner Design and Performance, and Current Systems. Seminars in Nuclear Medicine, Vol XXXIV, No 2 (April), 2004: pp 87-111. 238

-,,, 15 15 β01γ...,.., A.A. Д1, 2].,, Дβ-4Ж... / 100.Д5, 6].,,.,.,,. SpitfirePro, : =800, =4β, E max =7 =400, =80, E max =1. Ti:Sapphire TP-1A. (400, 1 ) (β66, 0.γ)... Maya 2000 Pro, β00-1100. 1. 1 = γ. : 1.. 5,5 0,54. β.. γ.,. 4. 674 =17,γ,,. 239

-,,, 15 15 β01γ. 1. Philipp Kukura, David W. McCamant, and Richard A. Mathies «Femtosecond SЭТЦЮХКЭОН RКЦКЧ SЩОМЭЫШЬМШЩв», DОЩКЫЭЦОЧЭ ШП CСОЦТЬЭЫв, 58, 461-488, 2007 2...,..,..,..,.. «ТЧ ЯТЭЫШ»,, 15, 107, β011 3..., γ1, 95-119, 2001 4. Miller K. δ., SОЫРООЯ I.., DЯШЫОЭЬФв D. P. «EППОМЭЬ ШП ХШа ТЧЭОЧЬТЭв ЫОН КЧН НТЬЭКЧЭ infra-ыон ХКЬОЫ ТЫЫКНТКЭТШЧ ШЧ ЭСО ЛХШШН» Regional Haemodynamics and Microcirculation, 10, 90-94, 2011 5. I. Stadler, R. Evans, B Kolb, JO Naim, V. Narayan, N. Buehner, R.J. LanzafКЦО, «IЧ vitro effects of low-хояох ХКЬОЫ ТЫЫКНТКЭТШЧ КЭ 660 ЧЦ ШЧ ЩОЫТЩСОЫКХ ЛХШШН ХвЦЩСШМвЭОЬ.» δкьоыь Surg. Med., 27, 255 261, 2011,..-..,..,...,... -,,,,.,,,.,,,,.,. TRIOL,, 12 4+ (γ,γ /) (),. 1 3,, (. 1). 68.,.. 240

-,,, 15 15 β01γ.. 1. 12 4+ (γ,γ /),.. [2].,,,,,.,,.. G(+)-C.,., G(+)-C (. β).. β 10-11.,.,,. [3] [4], 1.5 β.0.,, A2-T, G(+)-C, G4-C, C5-G, G6-C, A7-T, G8- C.,,, T1-A T9-A,,. 241

-,,, 15 15 β01γ.. β. T1A2G(+)G4C5G6A7G8T9,, :. 1. Plante, I. (2011) Radiat. Env. Biophys. 50, 389-403. 2. Belov O.V., Boyda D.L., Shirmovsky S. Eh. (2012) PoS(Baldin ISHEPP XXI)042 3. Peyrard M. (2004) Nonlinearity 17(2):R1 4. Kalosakas G., Ares S. (2009) arxiv:0906.4683v1 CPU GPU..,.., CUDA Nvidia, (CPU) (GPU). CPU 6-, 1β 242

-,,, 15 15 β01γ., 100 GFLOPs. 15γ6, 1 GHz γ.09 TFLOPs, γ0, CPU 60 FLOPs/. γ0, GPU... Z exp, ij i( j1) ij ( i1) j i, j ij Z ij,,. CPU GPU..,,.. GPU (МШКХОЬМТЧР).,..,, β1 512 * 512 1000. IЧЭОХ CШЫО Тγ-γββ5 γ.γghг ASUS GTX 650 Ti. ( x y* sizex ) CPU γ6.40. ββ.85. GPU 1.54. 1.08. GPU 14.84 β1.16 243

-,,, 15 15 β01γ. - ACII (SMALL ANIMAL INSTRUMENTS INC).....,........ -... "",.,.. -,., -,.,,, :,,..,,. : - SAII (Small Animal Instruments Inc),,. :,, 244

-,,, 15 15 β01γ.. 1.,, P-SAM. 2. () 245

-,,, 15 15 β01γ...,..-... Д1Ж..., (. 1).. 1.,,.. (MEPs), (NEB),.. Дβ-5Ж... (. β). : 1. ( (1)) ( (β)) (.. 1). 246

-,,, 15 15 β01γ. 2.,,. 3.. 4....,,.. β. F, H, : 1. E A. 2. E M. 3. E. 4. E ex. 5. E H. F= E A + E + E ex + E H + E M..,., «()-» Oz; «()-», m (1) Oz; «()-» Oz ; «()-», Oz. F Oz., (1) 247

-,,, 15 15 β01γ... (2),,,...,,... (3) : (4) (γ) (4).,,. 1. T. Shimatsu, H. Uwazumi, Y. Saki, A. Otsuki, I. Watanabe, H. Muraoka, Y. Nakamura, IEEE Trans. Mag. 37(2001) 1567 2. GrКОЦО HОЧФОХЦКЧ, GъЬХТ JяСКЧЧОЬЬШЧ КЧН HКЧЧОЬ JяЧЬЬШЧ DОЩКЫЭЦОЧЭ ШП CСОЦТЬЭЫв // Methods for finding saddle point and minimum energy paths, University of Washington, Seattle, WA 98195-1700 3. Daniel Sheppard, Rye Terrell, and Graeme Henkelman Department of Chemistry and Biochemistry// Optimization methods for finding minimum energy paths, The University of Texas at Austin, Austin, Texas 78712-0165, USA 4. R. Dittrich, T. Schrefl, D. Suess, W. Scholz, H. Forster, J. Fidler A path method for finding energy barriers and minimum energy paths in complex micromagnetic systems // Institute for Solid State Physics, Vienna University of Technology, Wiedner Hauptstr. 8-10, A-1040 Vienna, Austria 5. GЫКОЦО HОЧФОХЦКЧ, BХКЬ P. UЛОЫЮКРК КЧН HКЧЧОЬ JяЧЬЬШЧ DОЩКЫЭЦОЧЭ ШП CСОЦТЬЭЫв // A climbing image nudged elastic band method for finding saddle points and minimum energy paths Journal of Chemical Physics Vol 113, Number 22 248

-,,, 15 15 β01γ. - 2D..-..,,..,..-..,,..,, Д1Ж.,. -., 2D Z = 8 ZFC FC,. 1... 1. FC ГFC =0,4, =0,9 ГFC FC,, -. ГFC,. β., ГFC FC. 249

-,,, 15 15 β01γ.. β.,.. βd γd-. 1. K. Htoutou, A. Ainane, M. Saber and J. J. de Miguel, Physica A, 358, 184 (2005)....,....., (β0-β00 ).,.,,, [1]., -.,,,, 250

-,,, 15 15 β01γ.... -.. ( ),., :,,., Г ( Z 4 ), ( -3 )., () Г. ДβЖ (NPG). β0, IUPAC, () 100. (NPG) ()., 70-160,,,...,,,. [3] ; -60; : (NКCХ) ; : -300., NКCХ, NPG -γ00,... β0 β00, : 4 0,9% NКCХ 865β7,5±βγ56,9, 4 0,9% NКCХ+0,5 NPG 87511,4±β471,β, 4 0,9% NКCХ+0,5-300 86044,8±βγ98,9, 4 0,9% NКCХ+0,4 -γ00+0,5 90βγγ,1±β658,1.,,,.. 251

-,,, 15 15 β01γ. 1...,.., -..,... ; 2. ββ70045,., β0.0β.β006, 1; 3...,,..:, 2007.,..-..,..,,., [1]., [2]..,. m 1 m 2, ( 1, 1 ) ( 2, 2 ),,,, (3) (4),.. (5) 252

-,,, 15 15 β01γ. (ground state)...,.. (6) (7) (8) m 1 m 2 (), () ( ).,.. 1. 1010 0,010,01, d=1, C=0,5, N=63.,.. β. (9). 1.. β. N=10000. (x,y) [0;1].,,.. 0.1 0.5,.,. 253

-,,, 15 15 β01γ.,.,. 5. 1 ; β ; 3,, ; 4 5, 4 ; 5 4. 1 2 3 4 5. γ.,. 4., (β),,,,. й. 4. J~r -3,,. 254

-,,, 15 15 β01γ. 1. D.G. Rancourt. Magnetism of Earth, planetary, and environmental nanoparticles. Nanoparticles and the Environment, J.F. Banfield and A. Navrotsky (editors), Reviews in Mineralogy and Geochemistry 44 (2001) p. 217-292. 2. J. Norpoth, S. Dreyer, Ch. Jooss, and S. Sievers, J. Appl. Phys. 101, 09F518 (2007)...,....., :,,,,.,, [1].,,,, ДβЖ.....,.,.,, 4- ДγЖ. (,. ). (1,β5 /) (1/4) Д4Ж. (CCХ/4),,. Д5Ж. (57l/6)F 1 - «PСКЫЦКSМКЧ US 70/16» (BЫЮФОЫ, Germany) 7.0, γ00 εhг BGA 09P. ROI (Region of Tool Instrument) ParaVision 3.0.2.,. 255

-,,, 15 15 β01γ. : 1- β- RRИ8 EPI (FISP) Д6Ж.. t-.., -., - (. 1, 2).. 4. - ( ) 256

-,,, 15 15 β01γ.. 5. - ( )..-..,..,. ЬЩ 2 -, 0,142. [1],, [2].,, c.,,, -.. 257

-,,, 15 15 β01γ.,,.,, -. T. - staggered ( [3]). :. :. :,, ( ),,. :.. 1. T = 0,βγ. (γ) 258

-,,, 15 15 β01γ.. β. T = 0.β8. 1, [4]:,. (3) :,,, [4]. β,. 1. A.H. Castro Neto, F. Guinea, N.M.R. Peres, K.S. Novoselov and A.K. Geim, Rev. Mod. Phys. 81, 109 (2009). 2. A.K. Geim and K.S. Novoselov, Nature Materials 6, 183 (2007). 3. P.V. Buividovich, E.V. Luschevskaya, O.V. Pavlovsky, M.I. Polikarpov and M.V. Ulybyshev, Phys. Rev. B 86, 045107 (2012). 4. J. Gonzalez, F. Guinea and M.A.H. Vozmediano, Nucl. Phys. B 424, 595 (1994)...-..,.., 259

-,,, 15 15 β01γ. :, GMR-, Fert and Grunberg β007 Д1]. c.,, ДβЖ.. 1. (D- ). ДβЖ [1]. :,, - : =1/. [1] 1 1.5.., Д3] -.,, δ δ -., U L :., U L L,.,.,, Д3] (. ) :,,,,,. 260

-,,, 15 15 β01γ. Д4Ж. :, ; ( ). β. N (N- ), - (a) (b). [3],, β, γ. 261

-,,, 15 15 β01γ.. γ. (N- ) (, ). [4],,, -,,,,,. [2] -., 4,, : - SC 0,83 0,89 0,94 BCC 0,67 0,74 0,81 FCC 0,77 0,84 0,87,,,. 1. C A Faz, J A C Bland, G Lauhoff Magnetism in ultrathin structures. // Rep. Prog. Phys. (2008), pp. 2, 20-21 2. U. Gradmann. Monolayer films magnetism. // Encyclopedia of Materials: Science and Technology. ISBN: 0-08-0431526. pp. 5832-5837(2001) 3. Y. Laosiritaworn, J. Poulter, J. B. Staunton Magnetic properties of Ising thin-films with cubic lattices. // arxiv: cond-mat/0307291v1 [cond-mat/stat-mech](2003) 4...,...// Advanced Materials Research, Vols., 378 379, 2012, pp. 589 592 262

-,,, 15 15 β01γ....,.. PЬ Д1Ж,,. - PAL «ORTEC», 22 Na зγ00,, 22 Na ββ9,7±1,1. Taufit PALSfit vβ.βγ. - ДβЖ «TRAPPED». : ( ): C 21 H 20 BrN 3,, CCl 4, CHCl 3 (), AlF 3, C 8 H 12 N 4 O,., : H 2 O, AlCl 3, CH 2 Cl 2, C 2 H 6 OS.,. -. ДγЖ n i1 t1 1 N( t) R( t, t1 ) A exp dt, i i R(Э,Э 1 ) (); Ч ; i ; A i., 1. TКЮПТЭ PAδSПТЭ v2.23 [4Ж. : i I i,. «TRAPPED»,.,,.. 1. H 2 O 263

-,,, 15 15 β01γ. 1, I, % K, 1/ R, O 1-0,129 49,76 2-0,298 41,43 182,22 3-1,230 8,82 61,20 6,30 C 21 H 20 BrN 3 1-0,136 61,2 2-0,248 36,28 121,04 3-0,591 2,51 14,24 4,67 1-0,148 60,92 2-0,274 36,58 113,6 3-0,745 2,51 13,59 4,95 (CHCl 3 ) 1-0,149 57,67 2-0,316 38,35 135,66 3-0,814 3,98 21,82 5,11 CCl 4 1-0,160 60,35 2-0,325 36,53 116,04 3-0,909 3,12 16,06 5,19 CH 2 Cl 2 1-0,145 55,35 2-0,333 42,99 168,39 3-1,475 1,67 10,42 6,45 AlF 3 1-0,129 51,16 2-0,318 45,03 207,67 3-0,9900 3,82 25,76 5,82 AlCl 3 1-0,145 58,26 2-0,290 36,73 126,70 3-1,296 5,01 30,70 6,15 C 8 H 12 N 4 O 1-0,151 64,25 2-0,255 35,24 95,69 3-0,74 2,51 13,28 4,90 DiCl-Benzol 1-0,130 57,53 2-0,285 39,05 162,16 3-0,81 3,42 21,99 5,37 C 2 H 6 OS 1-0,157 59,69 2-0,301 35,48 107,72 3-1,115 4,83 26,38 5,65 264

-,,, 15 15 β01γ. ( 3 ),. 3 ( ), C 21 H 20 BrN 3, 3 = 0,59.,. CH 2 Cl 2, 3 = 1,475. (), C 2 H 6 OS (), c 3 = 1,115. 1. V.M.Byakov, at all. PAL spectroscopy and testing for potential carcinogens. Physics status solidi. 2.. // 46..,, -, 1996, γ77-378. 3. Nakanishi H., Jean Y.C., Positron and Positronium Chemistry. // Schrader D.M., Jean Y.C., Eds., Amsterdam: Elsevier, 1988. P. 159. 4. http://www.palsfit.dk 5. Y. Ito, Hamdy F. M. Mohamed, V. M. Byakov, and S.V.Stepanov, J. Radioanalyt. Nucl. Chem. 210, 607 (1996).,..-..,.. 265

-,,, 15 15 β01γ..,,..,, Д1Ж. Д2], [3],[4], [5].,,,,,,.,. : -,... - (, ).,,. -. 1, β. 1. G(+)TTGGGG t=15. 1,, 6 G(+)TTGGGG, G(+), G(+) GGG,. t=15. 266

-,,, 15 15 β01γ.. 2. G(+) t=15, t=20, t=40.β G(+)., 40 G(+),., :,. 1. Eley D.D., Spivey D.I. //Trans. Faraday Soc. 1962. Vol. 63. P.411-415. 2. Giese B., Wessely S., Spormann M., Lindemann U., Meggers E., Michel-Beyerle M. E.// Angew. Chem. Int. Ed. 1999. Vol. 38. P. 996-998. 3. Giese B., Meggers E., Wessely S., Spormann M., Biland A. // Chimia.- 2000. Vol. 54. P. 547-551. 4. Meggers E., Michel-Beyerle M.E., Giese B. // J. Am. Chem. Soc. 1998. Vol. 120. P. 12950-12955 5. Wessely S., Giese B.// J. of Biomol. Structure & Dynamics. 2000. Vol.2. P.293-295. MULTISOURCE HDR..,.. «HDR+» MultiSource HDR. «HDR+»,.,, - RОМШ-BШб.,, ( MultiSource HDR -60, γ,48, 267

-,,, 15 15 β01γ. 0,48 ) ( ) (.. 1). TG4γ 1995, β004. β-. r, (,.. 1). «HDR+», ( ).,.,,.,, ( ).,, 80%, ( ),. (,, ),.,., (,, )., -.,,.,,..,.. 268

-,,, 15 15 β01γ.. 1. 1...,..»., β006. 204. 2. MultiSource. Eckert&Ziegler, BEBIG, β009. β65. γ... (. β)..:, β008. γβ8...-..,.. (),...,..,. 1, 1. T =1,085±0,07. XY- 269

-,,, 15 15 β01γ.,,,,. GPU CUDA..,,. 1. Yamaguchi Y. Lecticans: organizers of the brain extracellular matrix. Cel. Mol. Lif 57, 276-289(2000). 2. Modeling Brain Extracellular Space from Diffusion Data. Journal of Theoretical Biology 234 (2005) 525-536. 3...,, β006..1. 1 γ00γ00 7 T 0.1 156 0.025-2000 270

-,,, 15 15 β01γ. - 30 80..-..,.. - (). - «Ortec», Tektronix DPO 7254. βt 0 = β47, = γ9,5 /. - 1..1 - n e, i R i Д1-3]., : β γ, (1) n e, i, u i, -. Д1,βЖ -., 271

-,,, 15 15 β01γ. - ( 3, I 3 ), ( 2, I 2 ),,. 1. 1 2, 3, I 2, % I 3, % Kβ, 1/ Kγ, 1/ «IЧЬЮХКЭ» 0,276 0,972 19,15 2,18 27,38 8,78 «CШЧНЮМЭ» 0,326 0,396 39,14 2,01 249,64 13,94 ( 3, I 3 ) (K2, K3) Kβ,.,,. β β, ( ). γ γ. 2, /, Condact1T 7,78E-05 1 Condact2T 1,02E-04 2 Conduct3T 2,17E-04 3 Conduct5T 7,71E-05 5 3 2, 3, I 2, % I 3, % Kβ, 1/ Kγ, 1/ Condact1T 0,339 0,719 21,00 1,65 57,41 7,07 Condact2T 0,292 0,849 14,07 2,72 26,31 11,20 Conduct3T 0,326 0,864 19,99 1,57 33,27 5,60 Conduct5T 0,285 0,970 23,67 1,48 21,83 5,02 272

-,,, 15 15 β01γ.. β.. γ. β (. γ),,,. β-γ (sigma) (β) (.γ), 1-2 β., ( ),,,. 1...,... //., 2002, 17β, 1 2. Goldanskii A.V., Onishchuk V. A., Shantarovich V. P. Some Principles of the Studies of Positronium Annihilation in Polymer Systems. // Phys. Stat. Sol.(a) 102, 559 (1987). 3. Brandt W., Berko S., Walker W. // Phys. Rev., 120, 1289 (1960) 4......:, 1968. 273

-,,, 15 15 β01γ...-..,,..., ( ).,.. : ( ), m, h,, d v, h c, m,.. H e.,,,,. -,.., : E, M r M s, h i m i,,,. - : (1), (2) 274

-,,, 15 15 β01γ. : E, h i, i-, m i i-, r ij - i- j-. - - [1],., d = 10, M 0 = 500 1 3, p, h c m i. 1: a) β5, Hc = 1, p = 20 ; b) 64, Hc = 10, p = 40... (3) a) b) Magnetization (Norm.) Field (Oe) Magnetization (Norm.) Field (Oe). 1. : a) 5x5 ; b) 8x8. ДβЖ, β: (a) NТ 80 Fe 20 γ0, ; (b) NТ 80 Fe 20 γ0. 275

-,,, 15 15 β01γ.. β. ДβЖ, : (a) (b),.,,,.,,,.,. 1. E. C. SЭШЧОЫ, E. P. АШСХПКЫЭС, «A εомскчтьц ШП εкрчоэтм HвЬЭОЫОЬТЬ ТЧ HОЭОЫШРОЧОШЮЬ AХХШвЬ». PСТХШЬШЩСТМКХ TЫКЧЬКМЭТШЧЬ ШП ЭСО RШвКХ SШМТОЭв ШП δшчншч. SОЫТОЬ A, εкэсоцкэтмal and Physical Sciences, Vol. 240, No. 826. (May 4, 1948), pp. 599-642. 2. A. τ. AНОвОвО, N. SТЧРС, S. GШШХКЮЩ, SЩТЧ ЬЭКЭО ОЯШХЮЭТШЧ КЧН ЦКРЧОЭТМ КЧТЬШЭЫШЩв ШП elongated Ni 80 Fe 20 ЧКЧШЫТЧРЬ. J. Appl. Phys., 98 p.094301 (2005). 276

-,,, 15 15 β01γ. MULTISOURCE HDR..,.. MultiSource HDR., 0,5 5. - ( MultiSource HDR - 60 -),,, β-γ., -...,,,., 0,5,,. εюхэтsшюымо, ( ) -..,..,.. εкщcсомф Dose-1 c.. 277

-,,, 15 15 β01γ....,, β0-. 1. MultiSource. EМФОЫЭ&ГТОРХОЫ, BEBIG, β009. 265. β... ( β)..:, β008. 328. γ.,.....:, β006.,..-..,...,.,...., 4γ β0-60.,,.,,. -.,. 4γ [1, 11, 12].,, 278

-,,, 15 15 β01γ.,.,, ( 4% ).,,,. 50.,,, 8,, Д.,, 2].,., (.,, Д3-10Ж),., Д1,12Ж, Д13,14Ж.,... β :, ;,, [15]. (MCA) (, ). MCA.. :,. :, 6. ( - i), (. 2)., 1 i 2 5 3 4 : - i, -, i 279. 1.

-,,, 15 15 β01γ., i -, i, j-, - j-, - i j, - i j. -, -, -. i j :. - i j,, (. );,. :,.. 1. Q A Pankhurst, J Connolly, S K Jones and J Dobson. Applications of magnetic nanoparticles in biomedicine. // J. Phys. D: Appl. Phys., 36, 2003, R167 R181 2. Christian Plank. Nanomagnetosols: magnetism opens up new perspectives for targeted aerosol delivery to the lung. //Trends in Biotechnology, Vol. 26, No.2 3...,..,..,..,..,..,..,..,..,.... //, β008 4...,..,... in vitro. // Nanosystems, Nanomaterials, Nanotechnologies, β008,. 6, 4,. 1β47 1259 5...,,. // -., β011 6...,... // http://tuarris.ucoz.ru/news/primenenie_ferromagnitny/2013-03-12-76 7...,..,..,..,..,.... //, β010 8. K. G. DШЛЫОЭЬШЯ,. ВЮ. AПШЧ ФТЧ, A. K. KТЫТМСОЧФШ,. P. δкнвртчк,s.. SЭШХвКЫ, τ. A. Bayukov, and A. V. Sipkin.A Method for Introduction of Magnetic Nanoparticles into Tissues by Means of Magnetic Field Gradient: An Experimental Study. // Bulletin of Experimental Biology and Medicine, Nanotechnology, 2009, Vol. 147, No. 6 280

-,,, 15 15 β01γ. 9. Murali M. Yallapu, Shadi F. Othman, Evan T. Curtis, Brij K. Gupta, Meena Jaggi, Subhash C. Chauhan.Multi-functional magnetic nanoparticles for magnetic resonance imaging and cancer therapy// Biomaterials, 32, 2011, 1890e1905 10. B. A. Larsen, M. A. Haag, N. J. Serkova, K. R. Shroyer and C.R. Stoldt. Controlled aggregation of superparamagnetic iron oxide nanoparticles for the development of molecular magnetic resonance imaging probes//nanotechnology, 19, 2008, 265102 (7pp) 11...,..,...,. 12...,..,..,.... 13...,... -. :, 198β. 184. :. 14...,... //, β01β, 8β,. 9. 15...,..,... //. 1998. 1.. 95-108. 281

-,,, 15 15 β01γ. IX.,..-..,..-.. -..-..,..,,. -.. - 1 Д1Ж.,,,,., ( ), ДβЖ.,.,,..,, ЬЩШЭ-, -.,.. 1,.,, -. : 1, 10, 150.. 282

-,,, 15 15 β01γ.. 2., : (Н ШЮЭОЫ ) ; (d inner ). β., (. β) γ0.,, y, Vmax,, x, n (. 3).. 3. 283

-,,, 15 15 β01γ.,,,. ±β. -.. -, -10.,. 1. McCord M.A., SPIE HКЧНЛШШФ ШП εтмышхтэсшрыкщсв, εтмышцкмстчтчр КЧН Microfabrication (2000). 2. Broers, A. N. et al., "Electron beam lithography Resolution limits". Microelectronic Engineering 32: 131 142 (1996)...-..,..;..-..,.., (), -.,,....., -. β0 100,,. -,,.,, TР. 284

-,,, 15 15 β01γ. : β-4.. : ; ;.,.., 1. 1,, 10 Fe 80 Ni 10 Si 4 B 6 30 6,5 γ0 Fe 60 Co 30 Si 3 B 7 27 1,9 I s I rs 900. 10 0 /. 650 0,,,.,. 1, : s II ( ) = 480, s I ( ) = 680. 0,17 0,γ 10 ( γ0 : II =0,1β5 I =0,β6 ).,.. 1. 10 γ0 285

-,,, 15 15 β01γ. ( з 0,8 ),,. β... 2. 10 γ0, 10 γ0, Fe 80 Ni 10 Si 4 B 6 з 4β0 0.,,.. 1...,..,. 2..,. -. 3...,... 4. http://do.nano.fcior.edu.ru/ Ca2Si Ca3Si4 Si,,,.-..,..,.. CК 1γ0 C 500 C Si Si, 286

-,,, 15 15 β01γ.., 1γ0 C Ca2SТ, 500 C Ca3Si4. In situ, Ca2Si, 1,0β. Ca2SТ ДβЖ. Ca3Si4 0,6γ ДγЖ., (CК2Si Ca3Si4) r..,, 500 C,,, Ca3Si4 0,89 0,91β. 1. D.B. Migas, L. Miglio, V.L. Shaposhnikov and V.E. Borisenko, Phys. Rev. B67, 205203 (2003). 2. S. Lebegue, B. Arnaud, and A. Alouani, Phys. Rev. B72, 085103 (2005). 3. S.A. Dotsenko, K.N. Galkin, D.A. Bezbabny, D.L. Goroshko, N.G. Galkin, Physics Procedia 23, 41 (2012). - -,..-..,..,, - Д1Ж. (10-8 ),,,,. -,,. - -,,.,.,,.. 1.. 287

-,,, 15 15 β01γ..,. (),.,.. 1. - -,.,,,.,, 1%. : 1) ; β).,, Д1Ж: I I 2 l 1 I 2 I1I 2 sin 0 I1, I2- ; ; ; l ; 0,,,,, 3 : 0., 2, ДβЖ, / L.,. N, / βn : 288

-,,, 15 15 β01γ. 2NL l 2N x 0 2 2 2 2 2 4 2 N ; ; x0 - ; -.,,,.,.,, 3, 0. 2,,. /. 6 /.... 2 -, β9 β01β 19:05,.. β., β9 β01β () 289

-,,, 15 15 β01γ. 1. - /.,.,.,.,.,. ;.. :..-.:.. -, 1990. β56. 2....;., 19γ5. 149. 3. -. /..... β008. 5β0. Fe Fe 3 O 4 / SiO 2 /Si(001),..-..,..;..-..,... -,.. - γd., (Fe 3 O 4 ) 100% -, 858 K,.,, SiO x /Si(001). O 2 10-6 Torr. FО γ00. -.. 0 4 koe. 4-., FО FО/SТτ 2 /Si. Д1Ж, FО γ00, FО τ 2. FО 3 O 4,., FО τ 2 γ00,. FО γ00,. FО γ00, FО, γ00. 290

-,,, 15 15 β01γ. Fe 3 O 4 65 nm (110), SiO 2 /Si(001), Fe 3 O 4 (γ11)... H c., Fe 3 O 4,, 1.07%, - 10.6%.. 1...,..,..,.. //, β009,. 51.. 565-571.,.-..,..,,,.,,,. CoP- CoNТP,. Carl Zeiss Libra 200 FE FEI TТЭКЧ 80-300.,,. CoP- CoNiP 512*512*512 й. AЦШЫЩСGОШ,. :,,,, :, :,,. TEεGPU GPGPU JEεS, -,. 291

-,,, 15 15 β01γ.. 1. FО. β. Fe. 51β*51β*512 й βγ 1-β., 16.552.11.7059,. 292

-,,, 15 15 β01γ. 1. Advanced computering in electron microscopy. E.J. Kirkland. Plenum, New York. 1998. Fe, Fe 3 O 4 / SiO 2 /Si(001),..-..,....,..-..,..... :.,. (Fe 3 O 4 ), (580 ),.,. Д1Ж, Fe 3 O 4, Fe 3 O 4, Fe γ nm,, Fe 3 O 4 Fe β60 C.,, SiO x /Si(001). O 2 10-6 Torr. FО γ00. -. nanomoke. 0 4 koe. 4- - Keithley-2400., FОτ Fe 3 O 4.,. FОτ,,.,., FО τ 2,. Fe 3 O 4 65 nm (γ11) (110), (з5%)., Fe 3 O 4,, 0.83% 1.05% τ 2, - 293

-,,, 15 15 β01γ. 9.β% 10.7%,... 1. T. Taniyama, T. Mori, K. Watanabe, E. Wada, M. Itoh, H. Yanagihara, J. Appl. Phys. 103 (2008) 07D705...-....,..-.... [1-3]. (50% ).,, (. 1)., [4]. (.1).,,,.. 1. () () (,, -) [5-7]., (; ).,. (β00, 30-50 ).,,., ( ):,. 294

-,,, 15 15 β01γ., β00 β, 500 4, 1000 5 (.β)..,.. (, ).,,,.. β. (β00, 500, 1000, β000).,.,,., (. 3),,,,.,,, (. 1).. γ. 295

-,,, 15 15 β01γ.,,... 4. (.4), /.,.,,,.., -. 1...,..,..,..,... IV «, DFMN-β011». β5-β8 β011,..585-586. 2. Zaichenko A.S., Tsarev S.A., Titov P.L., Kirillov A.V., Shegoleva S.A., Kuryaviy V.G., Kondrikov N.B. The investigation of impedance parameters, texture and self-organization of oxide formations on titanium and aluminum surfaces. 19ЭС IЧЭ. SвЦЩ. NКЧШЬЭЫЮМЭЮЫОЬ: PСвЬТМЬ КЧН TОМСЧШХШРв EФКЭОЫТЧЛЮЫР, RЮЬЬТК, JЮЧО β0 25, 2011. 3...,..,...,.,, β011. 4... -,.... -.. 01.04.07. β010,,. 190. 5...,....1..:, 1971. 664. 6...,....β..:, 197γ. 640. 7...,....γ..:, 1975. 496. 296

-,,, 15 15 β01γ...-..,.. (, 2 γ-, ),, "",,, ( ).,,,,. ( ).,,..,. -,. - (,..).,. (). : (, ) (, ). PЬ ()..,.,,,, [1].. 1 2, 3, 4, I 2, % I 3, % I 4, % K 2, K 3, K 4, H 2 O 0.29 0.72 1.91 41.43 8.63 4.01 182.22 57.56 30.21 80.1 CH 3 OH 0.296 1.20 2.41 35.634 4.84 5.11 115.94 28.70 32.45 33.1, 297

-,,, 15 15 β01γ. C 2 H 5 OH 0.29 1.77 2.68 36.31 7.04 1.66 116.31 41.64 10.15 25 C 3 H 7 OH 0.29 1.49 2.92 36.30 5.33 3.55 125.38 32.86 23.05 21.8 C 4 H 9 OH 0.292 1.39 3.20 34.015 5.45 3.78 103.23 35.81 26.36 17.1 C 6 H 6 0,32 1,87 38,64 13,61 178,48 98,44 CCl 4 0,32 0,74 40,41 3,45 145,33 18,52 CH 2 Cl 2 0,33 2,02 42,45 1,70 153,15 10,46 CHCl 3 0,32 1,12 39,53 2,53 126,80 13,80 C 6 H 5 Cl 0,32 1,79 39,09 4,23 131,04 24,94 C 6 H 4 Cl 2 0,29 1,28 40,09 2,10 131,42 12,42 (H 2 O, CH 3 OH, C 2 H 5 OH, C 3 H 7 OH, C 4 H 9 OH, C 6 H 6 ), (CCl 4, CH 2 Cl 2, CHCl 3, C 6 H 5 Cl, C 6 H 4 Cl 2 )., (I 3 ),.,.. 1. Vsevolod M. Byakov, Sergey V. Stepanov, and Olga P. Stepanova, PAL spectroscopy and testing for potential carcinogens//phys. Status Solidi C 6, No. 11, 2503 2506 (2009) / DOI 10.1002/pssc.200982080 2...,..,..,.... I.. β008. 6(44)..4-6. II. β009. 1(45)..10-12. 3. V. I. Grafutin, E. P. Prokop ev, S. P. Timoshenkov, S. S. Evstaf ev and Yu. V. Funtikov. Positronics and nanotechnologies: Possibilities of studying nanoobjects in critical engineering materials using positron annihilation spectrometry. Russian Microelectronics, 2009. Vol. γ8 6. P. 418-428. Co Si(111),.-..,.. Co,. Co Si(111), Д11-2] β 0. (P = 8 10-11 ) 1β00. Si(111), (step-up), 298

-,,, 15 15 β01γ., (step-down). Si(111) 5-7, 45-50.,,.. 50, - 1,5.,,.,...,,,., Si(111).,,.,,, ( 10)...-..,.., Д1Ж., (,,.),. (), (), ().,, 299

-,,, 15 15 β01γ.,,, [2].,, (GКN),,, (γ,4 ), ( 100 900 2 /*), /,. GКN: (GaN) 150. (GaN 750), 750, 150. (GaN/Al2O3) GКN 70. (GaN:Si) GКN,... 1. γ80 900.,, ANDτR SСКЦЫШМФ γ0γт,., 444, 5γβ, 560 659,.. 1. () GaN, T (). T(). β T() GaN:Si (444, 560 659 ).. β. GКN:SТ 300

-,,, 15 15 β01γ.. 2,., 444 1., GКN pump nm, ЧЦ 1/2 nm TЦКб% GaN 444 469,8 4 10,7 GaN 750 444 469,8 4 10,9 GaN/Al 2 O 3 GaN :Si 444 469,8 4 24 444 686 20 1,5 444 469,8 4 19 444 686 30 2 1 ( 4 ) ( γ0 ) 1,5 β4%. GaN ( GКN) - ( GКN 750), GКN: SТ GКN/AХβτγ,. GКN, GКN,., 12-HCC-008. 1. Stepanov S.I. Adaptive interferometry: a new area of applications of photorefractive crystals / International Trends in Optics, ed. J. W. Goodman. New York, London: Academic Press, Inc, 1991. Ch. 9. 2. Gunter P., Huignard J-P. Photorefractive Materials and Their Applications 2. Springer, 2007,Ch.11. Fe Co.-..,... (). :,,. 301

-,,, 15 15 β01γ.,.,, (). in-situ. - -.. 7,.., 1, - JXA- 8100. βγ 0 600 0 DSC-60. 10 /... 1, DCS- Fe 87 Ni 2 Si 5 B 4 () Fe 80 Ni 10 Si 5 B 5 (). DSC,. з (500 540),... ( ) () Fe80Ni10Si5B5. 1. DSC- Fe 87 Ni 2 Si 5 B 4 () Fe 80 Ni 10 Si 5 B 5 (), (Q b ). (Q c ), 1., Ni Fe, 1,. FО 80 Ni 10 Si 5 B 5 FО 87 Ni 2 Si 5 B 4 γ Q b..,, Q,.,. 302

-,,, 15 15 β01γ. FО 66 Co 24 Si 3 B 7, Fe 60 Co 31 Si 3 B 6, Co 87 Fe 6 Si 2 B 5 Q b,..,,, -,,. Q c. CШ 71 Ni 12 Fe 6 Si 6 B 4, Ni, Co Fe,,. CШ 82 Fe 4 Cr 3 Si 8 B 3,, 56γ 0. 1 Q before Q cryst (mw*s) 1 ( 0 ) 2 ( 0 ) (mw*s) Fe 87 Ni 2 Si 5 B 4 12860 351 546 558 Fe 80 Ni 10 Si 5 B 5 3961 435.6 527 543, 558, 583, 593 Fe 66 Co 24 Si 3 B 7 4382 852.5 488 549 Fe 60 Co 31 Si 3 B 6 12781 526 505 551 Co 87 Fe 6 Si 2 B 5 20861 252 510 552 Co 71 Ni 12 Fe 6 Si 6 B 4 29738 406 555 567 Co 82 Fe 4 Cr 3 Si 8 B 3 11609 420 563 -. : Ni Fe ; Co Fe. Ni Co(Fe), CШ 71 Ni 12 Fe 6 Si 6 B 4,,. 3% Cr Co,., FО 87 Ni 2 Si 5 B 4, Fe 66 Co 24 Si 3 B 7, Fe 60 Co 31 Si 3 B 6, Co 87 Fe 6 Si 2 B 5 Co 71 Ni 12 Fe 6 Si 6 B 4, (-), Fe 80 Ni 10 Si 5 B 5 CШ 82 Fe 4 Cr 3 Si 8 B 3... 303

-,,, 15 15 β01γ. Si(111),..-..,..., Д1, βж., SТ(111). -. - SТ(111), Cu Co ДγЖ. ТЧ ЬТЭЮ () 15 () ( ±β.0 B, 1 ). Об ЬТЭЮ () (). (MOK). - (). ()..., CЮ -., SТ(111)-5.55 5.55-CЮ Д4, 5Ж. 1β Cu (1 1 (111) Ю,.. β,09 ) SТ(111)-5.55x5.55-CЮ 550 0. Co 40 Cu γ0 A., Cu.. 1,,,. <110>SТ. Co з 1, з 8, 50., Si(111)-5.55 5.55- Cu,, Co,.1. Cu, CЮ (111),. 1. 304

-,,, 15 15 β01γ.,.. 1., <110>Si, Si(111)-5.55 5.55-CЮ, β70, Cu, 70. 4. Mr/Ms,,. β.. β. Mr/Ms, - Si(111)-5.55x5.55-CЮ/, - Si(111)-5.55x5.55-Cu/Cu/,, 4, <110>. 1......:,1981. 203.. 2..,.,...:,2002. 220. 3...,..,... Si(111) Co //. β010.5β, 1β,. βγ9β-2396 4. ε. εючньмскю, E. BКЮОЫ, А. TОХТОЩЬ, КЧН А. атмс. J. AЩЩХ. PСвЬ. 65(1989) 4747. 305

-,,, 15 15 β01γ. 5. T. Yasue, T. Koshikawa, M. Jalochowski, E. Bauer. Surface Science 493(2001)381. -..-..,..,...,, ( - ),.,..,,.,,.,......,., -..,,.,,,. -,,. - [1, 2]. 306

-,,, 15 15 β01γ.,.,,,,., -, [3]...,,.,..,,.. [4]..,.,.,,, - 2 2 2 2, (1) d S t x y t x y,, : v y d y x 2 y S, 2 y r xx y y v x x d y 2 x S, x xx y y : Lx 2 S Ly, (5) Ly 2 S Lx., 1 2, (5) x1 0, y 10 x2 0, y 20.., ( 1 2, -),.. 2, (2) 0 1 0 2 0 1 0 2 1 2 S 2 2 0 0 S0 0 2 0 S0 1 2 1 S S,, 1 0 2 r0. 307

-,,, 15 15 β01γ..,.,. 3. Lx, L y. a) 0.18, 1 0.1, 2 0; ) 0.04, 1 0.1, 2 0 ; ) -.....,,.,,,.,. 1. T. Simula. Collective dynamics of vortices in trapped Bose-Einstein condensates. Physical Review A. V. 87, 023630. 2013. 2. E. B. Sonin. Vortex oscillations and hydrodynamics of rotating superfluids. Reviews of Modern Physics. V. 59, pp. 87-155. 1987. 3...,...... β9,. 7γ7-740. 1979. 4...,...... 84,. β09β-2098. 1983. 308

-,,, 15 15 β01γ...,..,....-..,.. - (). - «Ortec», Tektronix DPO 7254. βt 0 = β47, = γ9,5 /. - 1..1. - n e, i R i Д1-3]., : β γ, (1) n e, i, u i, -. Д1,βЖ -. - ( 3, I 3 ), ( 2, I 2 ),,. 1. 1 309

-,,, 15 15 β01γ. 2, 3, I 2, % I 3, % Kβ, 1/ Kγ, 1/ «IЧЬЮХКЭ» 0,276 0,972 19,15 2,18 27,38 8,78 «CШЧНЮМЭ» 0,326 0,396 39,14 2,01 249,64 13,94 ( 3, I 3 ) (K2, K3) Kβ,.,.. β β, ( ). γ γ. 2, /, Condact1T 7,78E-05 1 Condact2T 1,02E-04 2 Conduct3T 2,17E-04 3 Conduct5T 7,71E-05 5 2, 3, I 2, % I 3, % Kβ, 1/ Kγ, 1/ Condact1T 0,339 0,719 21,00 1,65 57,41 7,07 Condact2T 0,292 0,849 14,07 2,72 26,31 11,20 Conduct3T 0,326 0,864 19,99 1,57 33,27 5,60 Conduct5T 0,285 0,970 23,67 1,48 21,83 5,02 3. β. 310

-,,, 15 15 β01γ.. γ. β (. γ),,,. β-γ (sigma) (β) (.γ), 1-β β., ( ),,,. 1...... //., 2002, 17β, 1 2. Goldanskii A.V., Onishchuk V. A., Shantarovich V. P. Some Principles of the Studies of Positronium Annihilation in Polymer Systems. // Phys. Stat. Sol.(a) 102, 559 (1987). 3. Brandt W., Berko S., Walker W. // Phys. Rev., 120, 1289 (1960) 4......:, 1968...,....-..,....,,, Fe 7 Co 71 Ni 12 [B,C,Si] 10.,,. 510.,. ( t 0 =20 0 800 0 ).. -... γ0.,. 311

-,,, 15 15 β01γ.,,.,,.. 4,γ*10-9 2.,,. 17,8 /. 150 (1500 ).. β0, 150.. 1.. β.. γ.. 4. - ( ).. 1., β50 0. 450 700.. -. = /,, ( ), = s / so, s, so ( ). = (/), (/).[1]. 71,5%,,, 1,715, so. so, s (T) ( ). ( ).β.,. 312

-,,, 15 15 β01γ. s, 2 t, 0 C.1.. 2. 400 600 0 s(t),, 650. (.γ)., β50..γ 650 15 (). 500., β50, (480 0 ) ( ).. 4 s(t) 800.,, 6β0. 313

-,,, 15 15 β01γ.. γ. s(t) 650., (. ) M. 4. s(t) 800,, β50 0, 800.. s(t), ( ),. 450 0,.., (11β1 0 ). 1.....:, 1968. 272. 314

-,,, 15 15 β01γ. Co,,..-..,... -. 5 10-10. Si(111). 150 0 8 SiO 2 Cu Co. 500 0 8, 1β00 0. Si(111) Cu Co. Cu Co 1 / 0,γ /. Cu β,4, 7. Ga +. 100, 10 10 10 17 / 2. ТЧ ЬТЭЮ () 15. Об ЬТЭЮ () (). (MOK).. Si(111)/SiO 2,, 1. Si(111), (111), <110>Co <112>Si, 1.. 1., K u,, 315

-,,, 15 15 β01γ. 4, β., SiO 2. Ku, 10 5 / 3 Hc,, / 2, / 2. β., -,, K u. 10 17 / 2 ( ),.,, 10 13 / 2, 10 17 / 2 ; 10 17 / 2. Tl Au/Si(111)..,..,..,..,..., -,.. - ( -) [1].. () (-) 316

-,,, 15 15 β01γ. Au/Si(111) Tl. γ γ-au γ γ, (. 1). (. 1) Au, Si [2]. γ γ-au - (. 1). ~0,15 Tl Si(111) γ γ-au,, (з500 ). Tl,. 1. () Si(111) γ γ-au () Tl. () - Si(111) γ γ-au () Tl, γ γ (. 1). 110 Tl.,,. Tl 0,05β -1 190 (. 1). AЮ/SТ,,,,,,. 317

-,,, 15 15 β01γ. 1. Yaji K., Ohtsubo Y., Hatta S., Okuyama H., Kimura K., Namatame H., Taniguchi M., Aruga T. Large Rashba spin splitting of a metallic surface-state band on a semiconductor surface // Nature Communications. 2010. Vol. 1. P.17. 2. Ding Y. G., Chan C. T., Ho K. M. Theoretical investigation of the structure of the ( γ γ)rγ0 -Au/Si(111) surface // Surf. Sci. 1992. Vol. 275. P.L691-L696. CШP,,..-..,.. CШP,. : 1, 100, 1000 10000. Д1Ж. 1 β0., (β0 ) (-19γ ),. CШP,, (. 1). 0,4 1,5, 50.. (. 2)..., 100. 0,7 1. γ,5 () 100 150. 1,5, (. γ). 100 (), 70 β00. 318

-,,, 15 15 β01γ.. 1. CШP,. β. CШP,. γ. CШP,. 4. CШP, 1000, 16.552.11.7059,. 1.....:., β006, 186. 319

-,,, 15 15 β01γ. X...,..,...,..,,.,,.,,..., [1].,., (), (), (),,. γγ, 4γ, γ5, γ1 31 %.,., 37%. - 400 4000-1., 1710 1718-1 ( ); 14β0 14β4-1 ( ). (1454 1464-1 ), -. 151β -1, ( ). 320

-,,, 15 15 β01γ. - 1100-1γ00-1 SТ-τ, [2].,. 0,015; 0,023; 0,030; 0,038; 0,045; 0,053; 0,060; 0,075 %-.. UNICτ 1β01 5 660. 1, β.. 1.,,.,,.. β. (,, ),,, (,, ). (,, ),.,,,.,. 321

-,,, 15 15 β01γ. 1. Hameed, B. H. Equilibrium and kinetic studies of methyl violet sorption by agricultural waste / B. H. Hameed // J. Hazard. Mater. 2008. N. 154. P. 204-212. 2. /..,..,..,..,.. //. 2005.. γ.. 1γ-15....,...,...,.,,..,,.,,,.,, Д2, 4]. (-) -709 -.,,,. 1 ( ) Д3] V, 3 / S r,, V 2 V V / - 0,62 0,60 0,02-0,80 745-709 0,60 0,08 0,45 0,07 10,00 261. ββ ± 1 1:100, 1:β00, 1:400-709 1:1000, 1:2000, 1:3000 -. 322

-,,, 15 15 β01γ.. 1. (1), (β) - (3): C (1) = 1 + C = C Ч P ХР = (3). β, [1]. Fu, Hansen, Bartell [5] (-G = RTlnK). 3., [3].,, -709 (. 1)... 1,.,, -,.,. 2 y ( ) R 2 ( ) -709-1:200 1:400 1:3000 y -11,815x + 7,4655 3,6296x + 0,2615 0,4391x + 0,0799 R 2 0,0598 0,3929 0,7788 y 0,4892x 1,97 0,8705x 1,5807 0,3422x + 1,1409 R 2 0,5932 0,7464 0,8113 y 0,0239x 2,0844 0,0557x 2,6681 0,0206x 0,7704 R 2 0,6434 0,7605 0,7788 3 (), (-G) -709-1:200 1:400 1:3000 1162,2 1444,7 1182,9 Fu, Hansen, Bartell -G, / 17311 17845 17354, 0,05 /.,. (. β). (2) 323

-,,, 15 15 β01γ. -709 1:100-1:1000 100 %. ( = 0 /) -709 (: = 1:β00) 1,4 /. : = 1:β000 = β /. -709, -. 1... β., -709 1:100-1:1000 100 %. γ... 1. -709 : 1:β00 (), 1:400 (); - -1:3000 (); -709 : 1:200 ( ) - 1:γ000 ( ) (). β. (S, %) (, /) : -709 : 1:100 (1), 1:β00 (β), 1:400 (γ); 324

-,,, 15 15 β01γ. - : 1:1000 (1), 1:β000 (β) 1:γ000 (3). 1.,...... 7-,.. :.., 1999. 479. β.,.. /..,..,.. //. 2005.. β.. 5β 54. 3.,.. /..,... : -, 2008. 160. 4. FКТЫцЧ-JТЦцЧОг, D. AНЬШЫЩЭТШЧ ШП BОЧгОЧО, TШХЮОЧО, КЧН БвХОЧОЬ ШЧ εшчшхтэстм CКЫЛШЧ AОЫШРОХЬ ПЫШЦ DЫв AТЫ FХШаЬ / D. FКТЫцЧ-JТЦцЧОг, F. CКЫЫКЬМШ-εКЫъЧ, C. εшыочш-castilla // Langmuir. 2007. Vol. 23. P. 10095 10101. 5. Fu, J. Thermodynamics of adsorption from solution. The coalition activity coefficient of adsorbed layer // J. Fu, R. S. Hunsen, F. E. Bartell // J. Phys. Coll. Chem. 1948. Vol. 52 P. 374 386. ( ),...,..,,. [1]. 1990-.,,. [2]..,, ДγЖ. :,,, Д4Ж.,. ( ) ( ). [1]. 325

-,,, 15 15 β01γ. 4 ( ) : 2-2012, ; 3-2012 ; 4-2012 ; 5 2012.. - β4 [1]. : 1-2012 ; 2-2012, (, ); 3-2012, -, 2-2012.,. 1.,, (2-2012),,.. () 6-7,.,,,, ()., (3-2012) (5-2012),, (4-2012). ( ), β 5,5.,..,.,.,,.,., (2-2012) (5-2012)..,.,.,., «,,,,,,.,,, (). (1-2012).. (2-2012).,.. 326

-,,, 15 15 β01γ., 4. 8. 327

-,,, 15 15 β01γ. 1 -,. 2.1.4.1074-01 /, β010. -, /, / -, /, / -, / -/ Ca 2+ +Mg 2+ Ca 2+ Mg 2+ Fe., / 6,0-9,0 20 1,5-1000 5-7,0-10,0 - - 0,3 350 500 6,5-8,5 35 - - - - - - 180 40 0,1 12 100 β 2012 6,48 52 3,7 940 850 27,3 10,07 10,4 74,54 81,33 0,08 9 62,2 γ 2012 7,71 131 12,05 1053 817 190,32 13,5 4,3 57,8 16,9 0,22 6,3 30,7 4 2012 7,05 77 9,5 777 548 201,3 6,1 9,6 76,43 70 0,34 9,45 60,5 5 2012 6,43 269 22,7 606 478 173,8 3,7 7,1 78,3 38,4 0,55 4,05 58,1 1 2012 6,91 3310 2,05 336,5 246,5 134,68 0,49 0 0 0 0,8 5,58 0 2 2012 6,89 65 3,85 178,5 160,5 145,6 0,48 2,09 28,56 8,08 0,06 6,97 0 3 2012 6,65 223 12,05 241,5 213 18,2 0,39 2,75 38,07 10,4 0,2 4,65 0 l -, / SO 4 2-, / 328

-,,, 15 15 β01γ. 1.,.... Д Ж. 2012. : http://www.fegi.ru/primorye/geology/coal/index.htm,... 2.,.. /.. // - (- ). 2004. 6.. 148-150. 3.,.. ( ) /.. //. 2010. γ.. 11γ-118. 4.,.. /..,..,..,..,..,.. //. 2004. 1.. 87-93. :...,.,,., : - (); - ; -.,,.,, 15 β0 %..,,,,,, Д1-γЖ. ДβЖ. ДγЖ.. 1. 1..,...,,. 329

-,,, 15 15 β01γ. : - 1 +1; - 0,γ15 +0,γ15-1; - 0,β +0,β -0,315;. - - «GC 6890 Plus» («AgilentTechnologies», USA) - 5973N («AgilentTechnologies», USA) HP5-MS (30 0,25 0,β5 ) 2. 1. 1 2 3 5 4. 1. : 1 ; β ; γ ; 4 ; 5 β. 2 330

-,,, 15 15 β01γ. 100 90 80 70 10^6 60 50 40 30 20 10 0 1 0.γ15 0.β. 2. β, 0.β,,. 0.315. 0.γ15. 0.γ15 NТ/CЫ Cr /Cr, 3 : : - - +0,γ15-1, Ni/Cr; - - +0,γ15-1, Cr /Cr. - - γ. 3..,,. 331

-,,, 15 15 β01γ.. 3. γ, Cr /Cr. Ni/Cr. : 1.. +0,β -0,315. 2. Ni/Cr. 1. Highly effective P-modified HZSM-5 catalyst for the cracking of C 4 alkanes to produce light olefins // Guiyuan Jiang, Li Zhang, Zhen Zhao, Xinyu Zhou // Applied Catalysis A: General. 2008. Vol. 340.. 176-182; 2. /..,..,..,.. //. 2006.. γ. 39-40; 3. Zeolite-based materials for novel catalytic applications: Opportunities,perspectives and open problems / Ji.ri.Cejkaa, Gabriele Centib, Joaquin Perez-Parientec, Wieslaw J. Rotha // Catalysis Today. 2012. Vol. 179.. 2-15. 332

-,,, 15 15 β01γ....,..,..., ( γ /) [1, 2]. (4/).,. ( )., - ().,. (< 0,1 / 3 ).,., -,.. (,,, ) [3].,. () γ00 90 (, γ60 ). β0 %. ( -).,. (-) 10, β0, γ0 ( γ00 )., -.,. 1. - 1 333

-,,, 15 15 β01γ. ph, / 3, /, /, % 7,0 0,265 2,64 5,80 1-5,5 0,214 2,96 4,92 1-6,0 0,244 3,83 3,00 93,00 70-86 %..,,,,.,.. 1.,.. // : /.. // 2008.. 1.. 19-25. 2.,.. /..,... :, β005. β68.,.. : /..,... :, β000.. 1β- 17.....,..,,,. Д1Ж...,,,.,,,.. 334

-,,, 15 15 β01γ.,. : (., 51); ( ); ( ); ( )...., :,,,,,,,,,. ДβЖ. Hach DR2700-01B1 (Hach Company (rhymes with "Bach"), ). ДγЖ.,,,, Д4Ж.,.,.,,... β011. «,, β01β..,...,. β01β.,.,,.,,,. ()..,,., β01β.,.. 335

-,,, 15 15 β01γ.,....,,,,,,.,.,,,.,,,.,,,.,,..,,,.,,,,,,,,,,.,,,.,,.,,. 1 /.,.,.,.,...,..//. β004. 1.. 87-93. 2,.. /.... : -, 1970 γ91. 3 DR β800:.., β005. 134. 4,... /..,.. // :,, 16-18 2011., β011.. γ-6. 336

-,,, 15 15 β01γ....,...,.,.,,. β,14 %.,.,.,,,., FОS ( )..,,,. ( ).ДγЖ,.,.,. :, ;, ; ; ;, ( ) ; -.. β01β 1,547.,.,, γ,1%. β,5%, β007. АШЫХН SЭООХ AЬЬШМТКЭТШЧ, β01β,,,,,,,. :,,,., ( 0,γ%), β,5 4,γ%,.Д5Ж 337

-,,, 15 15 β01γ., -.. 0,44, 0,4...1. ;. 1,64*10-3 /, 5,5 [1].... () ДβЖ..,. :,.,.,, Zn 2+.,.,,... () ()., ()., (). :,. (),, 338

-,,, 15 15 β01γ.,. (),,.,.,,,.,,,,,.,,,., [3]. β..,.. β. (Fe+C).,,..,,..,.,,,.Д4Ж,... 339

-,,, 15 15 β01γ. 1...,..:, 197γ.-γ9β. 2...,..:, 1976.-47β. 3...,..,..:, 1991.-168. 4...,..:, β00γ.-557. 5.. URL: http://www-theta.rbc.ru/rbcfreenews/20120723132222. shtml 2,4- -...,..;...,..,.,,,,. 2,4- (2,4-). β,4- (, -.),, β,4-. β,4-,,. - β,4-. β,4- -., 2,4-. β,4- : (),, ( ), ( ), SiO 2 nh 2 O ( 4214-78), (-709), ( ),, SiO 2 nh 2 O, SiO 2 nh 2 O (), nsio 2 msb 2 O 3 kh 2 O,, KAlSi x O y nh 2 O,. 2,4-4.1.11γβ-02 [1]. β,4- ( 0 ) [2] 5 [3], β,4-. 2,4-.., 340

-,,, 15 15 β01γ., β,4-. β,4- - 1. 1, β,4-. SТτ 2 ЧH 2 τ ЧSТτ 2 ЦSЛ 2 O 3 ФH 2 τ.,, SiO 2 ЧH 2 O (), SТτ 2 ЧH 2 τ KAlSi x O y ЧHβτ.,,,. 2,4- - 1 / - 2,4-, ppm 2,4-, % 1 0,0155 23 2 0,0150 25 3 0,0170 15 4 0,0175 13 5 SiO 2 ЧH 2 O () 0,0150 25 6 0,0 100 7 0,0170 15 8 0,0180 10 9 SiO 2 ЧH 2 τ 0,0140 30 10 SiO 2 ЧH 2 τ 0,0150 25 11 nsio 2 ЦSЛ 2 O 3 ФH 2 O 0,0135 32 12 0,0180 10 13 KAlSi x O y ЧHβτ 0,0150 25 β. 341

-,,, 15 15 β01γ. 2 / 0, / 5 1 1,2-2 β,4-0,1 / 3 β,4-4 β,4-819,0 787,5 23,2-49,5 33,3 [4], 80 % (,, ). β,4-,. β,, β,4-,. -,.,. 5 β,4-., β,4- (100 %). SТτ 2 ЧH 2 τ (γ0 %) nsio 2 ЦSЛ 2 O 3 ФH 2 O (32 %). β,4-,,. 1. 4.1.11γβ-0β... β,4-,,.. β00γ-01-01. 10. β. βγβ68.1β-78., -... 1980-01-01. 4. γ. 5β.β4.4β0-β005.... 01.01.β006 5γ 4., /..,..,..,. //. 2005.. 78,. β.. γβ4-328. 342

-,,, 15 15 β01γ.,,,...,.., γ0 %,. ( γβ ), Д1Ж. -..,. :,,,,. ()., / (10 6 10 7 /), /.,,. : 1., -, (). 2.. 3.., 1-0, β,56 2. (, 15 ),. ДγЖ. (Na 3 PO 4 12H 2 O, = 10-15 /). «..». (), 343

-,,, 15 15 β01γ. -4,, Д4Ж. 0,β 1,5, 1 β %.. 0,35.. -. ( ).,,,,,,, Дβ, 5Ж., ( U = 450 ), 660. (),, -,. 4-100,460-2-β4. ( ). - γ10 γ40 º,,., β,,,,., γ10,,,., γ40 º,. 344

-,,, 15 15 β01γ.. 1. 1-0: 1, γ10 º; β, γ40 º; γ 1. -.. 2.,, β-γ. 3.,. -,. 1... /..,.. //. 1998. 2.,.. /..,..,.. :, β008 14β. 3..., //..... 2000. 4γ1. 4. 1775419,.. 4β. /..,..... 199β. 5. Gnedenkov S.V., Sinebryukhov S.L., Mashtalyar D.V., Egorkin V.S., Tsvetnikov A.K., Minaev A.N. Charge at the Antiscale Composite Layer-Electrolyte Interface // Protection of Metals. 2007. ЯШХ.4γ, 7. p. 667-673. 345

-,,, 15 15 β01γ.,...,...,,,. 14. ( β009.) [1]., - (). () ( ), XX, ().,,,...,,. (, ), [2]. [4, 5]. - Дβ]., ( ),. β011. XX. (. ) (. ), (. ) (..,, ) [6]. - : Cu, Zn, Ni, Cd, Pb, As, Ag -. [3].,,,.,,, [4]. 346

-,,, 15 15 β01γ. ( ) (. 1). 1 (/. ) 2011. Zn Cu Cd Ni Pb As Ag ( )., 710 90 4.8 20.8 67.3 - - 5 142 63 6,1 8,3 1,2 - -., 153 23 0.8 13.3 17.6.. 2,8. 58-110 22,4-43,6 0,8-1,9 1,6-7,3 0,32-0,67.. 5,9-17,1 ( ). 7883 18 32 40.7 41.2 - - 514 95 14,4 5,3 0,88.... ().,. 126-385 22-23 1.5-2.6 14.9 30.3-40.2.. 3.7 89-114 16,8-19,3 0,3-0,5 0,7-1,9 0,6-1,1 0,10-0,19 1,3-1,5 ( ± ) 1γ6± βγ± 1.6± 1β± β1± 86 12 1.0 7.4 9.6 - - 95-228 12-36,8 0,25-1,1 0,16-1,40 0,38-0,96 0,06-0,1 0,9-1,8 ;...,,, Д6Ж.,, [2]..,, [4, 5].,,,, (. 1).. [7]., Pb, Cd, Zn, Cu Ni Ag,,, 347

-,,, 15 15 β01γ. As,. 1990.,, -, β-γ ( ). As,. As,. : 1),.,, Zn, Cu, Cd, Pb, As, Ag. Ni,,. β),,, : : > >. γ) As Ag., As, As. 1. Д Ж / :. : http://ru.wikipedia.org/wiki,..; 2.,.. /..,.... :, 1991. γ1β.; 3. Medvedeva L.A. Biodiversity of aquatic algal communities in the Sikhote-Alin biosphere reserve (Russia) // Cryptogamie, Algol., 2001, V. 22 (1). P. 65-100.; 4.,.. // -. :. 1990. P. 72-82. 5...,.. - //., βγ-β6 β006. /....,....:, 2007. γγ8. 6.,.. : /... :, β01β. 76 79. 7. Ramelow,G. J. Periphyton as monitors for heavy metal pollution in the Calcasieu River estuary / G. J. Ramelow, R. S. Maples, R. L. Thompson // Environmental Pollution, 1987, V. 43 (4). P. 247-261. 348

-,,, 15 15 β01γ.,,...,... (),,. [1,5].. -,.,,,. -,, [2,3,6]., -3. : 1. ; β. ; γ. -3; 4. ;, -γ. 1,5,, β0 γ0., GRIPO 1V,..,. 10 γ0. : (C 4 H 4 O 6 K 2 0,5 2 ), (NaF) (K 2 B 4 O 7 10 H 2 O)[2,4]. 25, ph 9,3. (,, ), (- 349

-,,, 15 15 β01γ. ). :, A B,. [1], -3. :, (, ) : U=450 480, t=30 40. β01,, β5 40. :, (, ) : U=350 400, t=60 70. β01, β5 40. :, (, ) : U=380 400, t=20 γ0. β01, β5 40.. (. 1).. 1. : 1 -γ+, (); β -γ+, (); 3 -γ+, (); 4 -γ+, ( ). 10-10 10-4.,.,,,., 350

-,,, 15 15 β01γ., -γ+, (),.... 1. -3. 2.. 3., -3. 1. /..,..,..,..,..,.. //.., β000,. 7γ,. 4.. 541-547. 2.,.., /..,.. // :,, β004, β,. β-8. 3. /..,..,..,..,..,.. // :,, β006, 8,. γ6-41. 4. Production of hard and heat-resistant coatings on aluminium using a plasma microdischarge / S. V. Gnedenkov, O. A. Khrisanfova, A. G. Zavidnaya, S. L. Sinebrukhov, A. N. Kovryanov, T. M. Skorobogatova, P. S. Gordienko // Surface and Coatings Technology. 2000. 123. P. 24-28. 5. /..,..,..,..,..,..,.. //. 1999,. γ5, 5,. 5β7-530. 6. /..,..,..,..,..,.. // :,. 2006. 8.. γ6 41. -...,..,, [1]. -,., -35 0 ( ), 351

-,,, 15 15 β01γ. 60 0 ( ).,,. [2],.,. - (). 90/130 [3] γ., 150 β5%..,. 180 0.,,... -0.15/22-150, ββ. -,, :,, β5 0 25, β5 0 β5 0 25., : β0, -β0, -10, -180. -180. β β00 /.., [4-7]. 1.. 1, 1. 1. 1 -, 352

-,,, 15 15 β01γ.,, -,.,, (, ) - (57 144 0 )., (- γ6-15 0 ), 36 0.,,,. 1...,..,,, 6, β008. 2..., -., γ(50), β01γ. 3. βββ45-90... 4. 11506-7γ... 5. 11507 78... 6. 11505-75*... 7. 11501-78..... (),,. (, ),, [1-3]..., β,5; 5; 10, ( ) 80, 100 1β0 353

-,,, 15 15 β01γ. XP-1500 Plus CEM Mars Xpress. 60 ( 6 ). Shimadzu UV-1800., β70. 1, 80, 100 1β0.. 80 100,, 120,. 1β0.,,,.,,.. 80, 6,, 10. 100,,, 80. 354

-,,, 15 15 β01γ. C, / 80 70 60 50 40 30 20 10 0 2,5 5 10 2,5 5 10 2,5 5 10 2,5 5 10 2,5 5 10 2,5 5 10 80 100 120 6 5 4 3 2 1. 1. 80, 100 1β0 (β,5, 5, 10 ) (1-6). 80 1β0 γ-4 β.. 1.,.. /..,..,.. //. 2007.. 80,. 6.. 10γβ-1036. 2. /..,..,..,..,.. //. 2006.. 79,. γ.. 1554-1557. 3., /..,..,..,.. // : II. : -. -, β005. I.. γ44-348. 355

-,,, 15 15 β01γ. XI..., (VI)..,..,..,..,..,...,,..,.. +6,,, [1, 2].,., +6.,.. +6, - (VI) - (MoO 2 Cl 2 β). [3] : 2[(PhSiO 1.5 )O 0.5 Na] n + nmoo 2 Cl 2 2 Д( PhSiO 1.5 ) 2 MoO 3 ] n +2NaCl + 2, MoO 2 Cl 2 β. (.1) (. β), (.γ). 1.,. (.β). 91,4 %,, β9,β %. 1, %. {(PhSiO 1,5 ) n MoO 3 } Si Mo Si Mo Si/Mo Si Mo 1 14,7 20,5 4,0 19,5 6,6 10,0 19,5 6,6 2 51,5 29,2 91,4 7,9 42,5 0,6 7,9 42,5 3 27,9 43,1 1,0 21,3 0,9 82,0 21,4 1,0 (.1).β, 11γ8-1, 356

-,,, 15 15 β01γ..,,, Si-O-Si 1000-1100 -1. () (.2),, (VI).,,, (.2),..1..2, 1, 3.,, -,,.,., (VI). 1.,.. /..,..,... :, 1984.. β0γ. 2. Catalytic Properties of the Dioxomolybdenum Siloxide MoO 2 (OSiPh 3 ) 2 and its 2,2'- Bipyridine Adduct MoO 2 (OSiPh 3 ) 2 (bpy) / Sofia M. Bruno, Bernardo Monteiro, Maria Salete BКХЮХК, CКЭКЫТЧК δшюыочхш, AЧКЛОХК A. КХОЧЭО, εкыэвч PТХХТЧРОЫ, PКЮХШ RТЛОТЫШ-Claro and Isabel S. GШЧхКХЯОЬ // Molecules. 2006. P. 298-308. 3.,.. /..,.,.. //. 2008.. 78. 4.. 600-603. 357

-,,, 15 15 β01γ. 1,3-...,... 1,γ-, Д1Ж., 1,γ-.,. [2],. 1,3-.,,,,. O O N H O + H 3 C NH COOH + Ph Ph N N 1 O O Ph Ph N N O N H 2a N CH 3 + Ph Ph N N O 2b N H N CH 3 358

-,,, 15 15 β01γ. O O N H O + H 3 C NH COOH + Ph Ph N N Ph 3 O O Ph Ph N N Ph O N H N CH 3 4a + Ph Ph N N Ph O N H N CH 3, :, 1:β (:). 1,5. (βa; 4a) (2b;4b), β, 4... 1.,.. - :..... /... :.. -..., β010.- ββ. 2. Facile three-component synthesis of spirooxindolepyrrololine ring systems via 1,3- dipolar cycloaddition with 1,4-naphthoquinone / Hua Chen, Shun-Yi Wang, Xiao-Ping Xu, Shun- Jun Ji // Synthetic Communications. 2011. T. 41. C. 3280-3288. 4b 4--2--1,3,5- -1,5 4--2--1,3,5- -1,5...,.. 4--2--1,3,5--1,5 ( I) 4- -2--1,3,5--1,5 ( II) ( )[1]. II 4--2--1,3,5--1,5 ( III). II. HCl II, - 359

-,,, 15 15 β01γ., -,. II. -. III. -, -. C 2 H 5 OH O O R X N N N O O X N N N O O N HO Cl N + O (I)R= (II)R= N N X N N N O (III)R= N O X=S; O; 1.,.. --'--1,5- : /..., β008.. 11-18. 360

-,,, 15 15 β01γ., RUBIA JESOENSIS...,..... Rubia () 60,.,, R. tinctorum R. iberica,,.,, R. cordifolia,,,,,.,,,,,, [2,3]. Rubia jesoensis (Miyabe et Miyake),,.,. R. jesoensis 11. (1), (2) (3), (4), (5) (6). 1 13 - COSY, HSQC HMBC. 7 8,,, - Shimadzu LCMS 2020. 9 10 - LH-20, - 1,4--3--2--9,10- (9) 4- -1,3--2--9,10- (10)., R. jesoensis (7) (8),., 11. O O R 1 R 2 R 4 R 3 R 1 R 2 R 3 R 4 1 OH O- ß-D-Glu-(1-6)- ß-D-Xyl H H 2 OH CH 3 O- ß-D-Glu-(1-6)- ß-D-Xyl H 3 OH CH 2 OH O- ß-D-Glu-(1-6)- ß-D-Xyl H 4 OH OH H H 5 OH OH H OH 6 OH CHO OH H 7 OH COOH OH OH 8 3 OH OH 9 OH COOCH 3 OCH 3 OH 10 OCH 3 COOCH 3 OCH 3 OH 11 OH COOC 2 H 5 OH H 361

-,,, 15 15 β01γ., Strongylocentrotus nudus. 1. Singh, Ram. 9,10-Antraquinones and Other Biologically Active Compounds from the Genus Rubia / Ram Singh, Geetanjali, S.M.S. Chauhan // Chemistry & Biodiversity. 2004. Vol. 1. P. 1241-1264. 2. Rubia cordifolia /..,..,..,..,..,..,..,.. // -. 2007.. 41, 11.. 38-41. 3. Liou, Meei-Jen. Constituents of the Roots of Rubia yunnanensis / Meei-Jen Liou, Pei-Lin Wu, Tian-ShungWu // Chem. Pharm. Bull. 2002. Vol. 50, No. 2. P. 276-279. 3, 5--4- -1-1Ph-,...,,..;...,.....,,,.,,,,,, (.,, Д1,βЖ). 4--3,5--1-1Ph- (HPz PhPz ):,, -. ДγЖ 4- -. 3--2,4-3,5--4--1-1PС- (. 1). N 2 H 4 *HCl + F F O B O S OEt P OEt O + N 2 H 3 Ph*HCl H N N S OEt P OEt O Ph N N S OEt P OEt O 362

-,,, 15 15 β01γ.. 1. -. 16- GAMESS, - B3LYP, TZV ( ) p- d-.. 2 3.,,..... β. HPz. γ. PhPz HPz PhPz,,., N1 PhPz.,, PhPz.., ( = 450-1 ) N-H HPz. N1-. «-» ( 14.18.21.0828). 6058. 1. Y.-S. Yang et al. / Bioorganic & Medicinal Chemistry. 2012. Vol. 20. P. 6048 363

-,,, 15 15 β01γ. 2. J.L. Wiley et al. / European Journal of Pharmacology. 2012. Vol. 695.. 62 70. 3. I.V. Svistunova et al. / Russian Journal of General Chemistry. 2011. ШХ. 81, 4.. 756 761. /...,..,.. ;...,,..... Д1, 2]. (),,, ДβЖ. (), ( 1), ( β).,,,,,., Дγ, 4Ж. (). (ZnCl 2 - ; (, N,N -)-ZnCl 2 -- H 2 PtCl 6 )., ZnCl 2 -,, Д5Ж. ( -- ZnCl 2 -),,. H 2 PtCl 6 6 2, H 2 PtCl 6 6 2, (. 1). 364

-,,, 15 15 β01γ.. β.. = -1,16. 1) 1, β) β, γ) 1 + Pt, 4) β + Pt = - 1,16 8000. (. γ) (. γ). () (). γ. () (). 1) 1, β) β, γ) 1 + Pt, 4) β + Pt,,, 50-100,. (. γ), -., (. γ γ, 4), H 2 PtCl 6 6 2,, Д5Ж. 365

-,,, 15 15 β01γ.,., H 2 PtCl 6 6 2,. H 2 PtCl 6 6 2 β, 4 8 /, β,74 18,58 β5,15. % (. 4). () () (). 4, β (/): β, 4, 8., Д4Ж., K 3 [Fe(CN) 6 ]/K 4 [Fe(CN) 6 Ж.,, β H 2 PtCl 6 6 2 0,β5 Д5Ж. : 1), ( 12-I-8-14); 2) ( 12-III--04-06) 3) ( 12-03-13003-13);. 1. Bouzek K., Mangold K.-M., Juttner J. K. // Journal of Applied Electrochemistry 2001. V. 31.. 501. 2... //....., 2009. 174. 3. Du Y., Luo X.L, Xu J, Chen Y.H // Bioelectrochem. 2007. V. 70. P. 342. 4. Sieben J.M., Duarte M.M.E., Mayer C.E. // J. Appl. Electrochem. 2008. V. 38. P. 483. 5...,..,..,.. //...,.,, β011.. 51. 366

-,,, 15 15 β01γ. -. -,,....., -,.,,, ;.. (. 1).. 1., - Д1-4Ж.,.,. :.. (). 367

-,,, 15 15 β01γ.,,,,.,, 99,99% 14. Naberthern L40/1β (). () (). : 1. 100 600, 1 ; 2. 1 6 100., () 2 3. ) ) ). 2.,, ) 100 ; ) γ00 ; ) 600 ) ) ). 3., ) 1 ; ) γ ; ) 6.. 368

-,,, 15 15 β01γ...., 600 6.. 1. CN1614102, C25D 11/04, 2005 2. JP 2002285382, C25D 11/04, 2002 3. Hideki Masuda, Kenji Kanezawa and Kazuyuki Nishio. Fabrication of IdeallyOrdered Nanohole Arrays in Anodic Porous Alumina Based on Nanoindentation Using Scanning Probe Microscope // Chem. Lett. 2002. P. 1218-1219. 4...,..,.. //. β01β. 6..11-14. -. -,,....,.,,,,..,.,,..,..,,,,.,, 99,99% 14. :, (1)..,. -,,. 369

-,,, 15 15 β01γ. = 0,4, = 0,5 0,6. 0,1 0,β 0,7 0,8 Д1,βЖ., 0,1 0,β. (1), 70 1γ0. Naberthern L40/1β (). () (). : 1) 100 600, 1 ; 2) 1 6 100. (. 1).. 1. Дγ,4Ж : ; (2) D, ; t, ; B,., (3), ; F J,. (β) (γ) 1. 1 (2) (3) A B F J A B F J -1-1 0,251 0,176 0,252 0,002 7,09 26,88 0,389 0,481 0,135 0,003 18,84 72,83 19,88 0,001 60,91 0,001 β γ.. 370

-,,, 15 15 β01γ., Д1, βж,.,.., 600 6... 2. : ) ; ). 3. : ) ; ),. 1. Callister, W. D. Materials Science and Engineering An Introduction, 7th edition / W. D. Callister John Wiley & Sons, 2007. 2...,....:, 1990. 5β8. 3...,.. :. :, β004. 1γ8. 371

-,,, 15 15 β01γ. 4......:, 1971. 19β. 1,5-...,,.., 1,5- -. 1,5- N-BOC- - I. 1,5- :,-. 1,5- III. N-BOC-- I II. N-BOC-- ( ). III IIIa ( 90%)., III : I, II KτH. γ0. III, IIIa,,, [1]. Ph Ph O Ph O N BOC I Ph (II) CH 2 O BOC BOC N O O III Ph N N BOC O O IV BOC BOC.1. N-BOC-- 1,5-. IV. - I γ6%- 60 C. IV IV 85%. I [2]. -. N N O O HO Ph OH N IIIa BOC IVa 372

-,,, 15 15 β01γ., (III) (IV) 1,5-. 1,5-. 1. S.Z. Vatsadze, M. L. Kostochka, V. P. Lezina, V. G. Vinokurov, N. V. Zyk, Russian Chemical Bulletin, International Edition; Vol. 53, No. 12, pp. 2805-2809, 2004. 2..... 5-. β011.. 1γ.,,,...... Si/Co β:1. 600 (10 ) : 1 ( 1 γ), γ ( β 4). 1.8 ( 1-β) 10:1 ( γ-4). : 2nPhSi(OH) 2 ONa + nl 2 6H 2 O Д(PhSiO 1, 5 ) 2 CoO] n + 2nNaCl + 8nH 2 O ( - ). - -. ( 60.9 % 61.β % 1-β; 55.1 % 55.6 % γ-4).., -, -,. -. 5000., -1, ( 1, : Si = 17.4, o = β.5, C = 57.4, Д(PСSТCХτ) 0.86 (PСSТτ 1.5 ) 1β.54 (PСSТττNК) 1.β CШτ)Ж Ч ; β, : Si = 19.β, o = β.1, C = 59.1, Д(PСSТCХτ) 0.6γ (PСSТτ 1.5 ) 17.γ7 (PСSТττNК) 1.β CШτ)Ж Ч ; γ, : Si = β0.γ, o = 0.7, C = 59.9, Д(PСSТCХτ) 1.6γ (PС β SТτ) 9.1 (PСSТτ 1.5 ) 47.97 (PСSТττNК) β.β CШτ)Ж Ч ; 4, : Si = β0.1, o = 0.5, C = 58.5, Д(PСSТCХτ)(PС β SТτ) 11.γ (PСSТτ 1.5 ) 70.β (PСSТττNК) β CШτ)Ж Ч ). 373

-,,, 15 15 β01γ.,., Co., m /m. = 1.8 Co β.1 β.5, m /m. = 10:1 0.5 0.7. -, Si Si 10β0 1100-1, Si 6 5 14γ0-1 11γβ -1. 3100-γ000-1. 1595-1 -. - Co-OSi- 950-1., - -,.. ( ) d = 11,0114 d = 1β,β064,. ( ) d = 4,547 d = 4,5ββ,., -,... (1) (. 1), Fascaplysinopsis sp. 1988,,,.,, CDK 4., - [1].,,., 6 7. R 2 R 1 374

-,,, 15 15 β01γ. N H O 2 O H N R 2. 1. (1) (2), 6 7, (2), [2, 3]. (3) 6-., 4 5 (. β). O R 1 9 10 8 11 7b 11a (1): R 1 =R 2 =H R1 7a N H 12 7 6 12a O 13 R 2 12b N + 5 O 13 4a 13a 4 1 3 2 O H N O 3 CH 3 8 7 9 6 4 5 3 N H 1 2 10 O 12 11 14 4 12,5% 15 16 19 18 17 N H 2 O NКH,, 1 O O. β. - 4 + m/z = β49. - NH- (γγβ0-1 ), (1707 1658-1 ), =, (1567-1 ). - 1 11. (-10) 6,94.. (1). - (-15-19) 8,05.. (2). -6-9 6,97 7,70.. -8 7,0β.., -17 7,59.. -7, -16-18 7,55 7,46.. (3). NH-, Z-, - -. - 13 4 95,0 111,9... 1β0 155... 188,γ 19β,5... 4. 5 -, m/z = β49,. (. γ), 6. N H 5 7% 375

-,,, 15 15 β01γ. O H N - H 2 C O Ph O O H N Ph NaH N H 2 O N H O N H O - OH - H N Ph O 6 4 O N H O + O N H -. γ.,,, Д1,β-a:3,4-b'Ж,., 2-(2--2- )-1,2--3H--3-. 1. Bharate, S. B. Chemistry and biology of fascaplysin, a potent marine-derived CDK 4 inhibitor / S. B. Bharate, S. Manda, N. Mupparapu, N. Battini, R. A. Vishwakarma // Mini Rev Med Chem.- 2012.- V. 12 (7).- P. 650-664. 2. Posner, T. Indigo group. II. A new vat dye from indigo and malonic ester // T. Posner, G. Pyl // Ber.- 1923.- B 56.- S. 31-44. 3. Posner, T. Indigo group. IV. A new vat dye formed from indigo and phenylacetic ester / T. Posner, W. Kemper // Ber.- 1924.- B 57.-S. 1311-1315. -, -...,...,. [1].,. - (). 376

-,,, 15 15 β01γ.,.,,, [2].,,,., 0,1 Na 2 SO 4 ( 3 ), Na 3 PO 4 ( 1 ), Na 2 SiO 3 ( 4 ) Na 2 B 4 O 7 ( 2 ),.. 1.,, (. 1)., - 100 /.,,, -. 1.,.. /.. :, 1996. β15. 2. /....- :, 1985. β78. 377

-,,, 15 15 β01γ. FUCUS EVANESCENS...,........, -, -1γ- 1γ;14- -L-. D-, D-, D-. β 4. [1], [2], [3]..,,,, [4]..,,., [5]. Fucus evanescens,,., Fucus evanescens,. ( ) β011.,. «Agilent»., F. evanescens, 80.. -. 1. SK-MEL-5 RPMI-7951. MTS., SK-MEL-5 RPMI-7951 400 /, 7β.. 378

-,,, 15 15 β01γ..,,.. 1. Chevolot L., Chaubet F. Sulphated heteropolysaccharides from Padina pavonia. Bioact. Carbohydr. Polymers. 2000. V. 16 P. 59-84. 2. Zvyagintseva T.N., Shevchenko N.M., Nazarenko E.L., Gorbach V.I., Urvantseva A.M., Kiseleva M.I., Isakov V.V. Water-soluble polysaccharides of some far-eastern brown seaweeds. Distribution, structure, and their dependence on the developmental conditions. J. Exp. Marine Biology and Ecology. 2003. V. 294 P. 1-13. 3...,..,...... β001.. β7. 444-448. 4. Cumashi A., Ushakova N.A., Preobrazhenskaya M.E., D'Incecco A., Piccoli A., Totani L., Tinari N., Morozevich G.E., Berman A.E., Bilan M.I. A comparative study of the antiinflammatory, anticoagulant, antiangiogenic, and antiadhesive activities of nine different fucoidans from brown seaweeds. Glycobiology. 2007. V. 17 P. 541-552. 5. A. SвЧвЭЬвК, А.J.KТЦ, S.ε. KТЦ, R.PШСХ, A.SвЧвЭЬвК, F.KЯКЬЧТМФК, J.CШЩШМШЯК, В.PКЫФ, SЭЫЮМЭЮЫО КЧН КЧЭТЭЮЦШЫ КМЭТЯТЭв ШП ПЮМШТНКЧ ТЬШХКЭОН ПЫШЦ ЬЩШЫШЩСвХХ ШП KШЫОКЧ ЛЫШаЧ ЬОКаООН UЧНКЫТК ЩТЧЧКЭТПТНК, CКЫЛШСвНЫКЭО PШХвЦОЫЬ. β010.. 81 P. 41-48 2(-)-1,3,2-,...,,..,. - - Д1Ж. Дβ,γЖ., Д4Ж. -,. β(-)-1,3,2- : 379

-,,, 15 15 β01γ. H 3 BO 3 BuOH OH OH Ph Ph O B O O O CH 3 1 O B O Ph O O O B OBu O 2 3 O B O O O 4 S CH 3 CH 3 O B O O O 2 CH 3 CH 3 : 1-, β-, γ-, 4- ()., -,., 1,,. 89%, 64%.,,..,, : CH CH 3 3 O O O O 2 S B SO 2 Cl Cl S B 2 O O O O 2 CH CH 3 3 1. - /..,..,..,.. //.... 2000. 6.. 10γ0-1033. 2.,.. β-2--4-(4, - )-6--1,3,2- /..,..,.. //. 2010.. 51, 4.. 795-798. 3.,.. 4(N-)-3-- /.. //, 380

-,,, 15 15 β01γ. - -β01β :... :, β01β.. 160. 4. Vovna, V. I. Photoelectron spectra and electron structure of boron difluoride ethyl acetonete, boron difluoride benzoyl acetonate, and its derivatives / V. I. Vovna, S. A. Tikhonov, I. B. δ ШЯ // RЮЬЬТКЧ JШЮЫЧКХ ШП PСвЬТМКХ CСОЦ. 2011.- Vol. 85 N 11. P. 1942-1948. 2,7-Д(2-)- Ж...,.. 1,5,9-,,.,, NaOH c 86% Д1Ж. I 2,7-Д(β-)Ж,,. I II., I, ( ) - III ( )., ДβЖ. I - III 1:β (T=110-150 C). 4- I ( 85% ) Ia t r 12,74 (t 11,2-113,0). 13 I, dept-, -, Ia., (RSRS RRSS) I. 381

-,,, 15 15 β01γ. + + N N T=110-150 0 C O O III O N + + N O III N N 1)T=110-120 0 C 2) H 2 O/H + O O O I O O IV IV. 1. I R S R S R R S S O O I' O O O I'' O. β. I, I ( 1) β. II t r 1β,0γ., Ia II ЭЫ 11,15., I II. 1,5,9-,. O OH NaOH/EtOH O O I O O II. γ. I I. - III 382

-,,, 15 15 β01γ. IV ( 1:β) 110-1β0. I. β II, (tr 11,157 11,477 ) 70%., II I.. II (50 ). t 184-185 (t r 11,157). 13 13 -dept II., I - III IV. I, 13 I., I. 1. N. S. Kravchenko, T. I. Akimova, V. A. Denisenko. An alicyclic 1,5,9-triketone of 2,6- bis(2-oxocyclohexylmethyl)cyclohexanone. Its cyclic form and interaction with mononucleophiles // Tetrahedron. 2008. Vol. 64, N.20. 9448 9454. 2.,.. - 1,5-1,5,9-:....: 0β.00.0γ /..., β001. 74-77. TiO 2,...,,..., -..,,.. Д1Ж. NH 4 F:HF ( L-1a) C 12 H 25 SO 4 Na ( L-0),. 1 2. 80. () S-5500. 1, L-1a,, 50 100. 383

-,,, 15 15 β01γ.,,.,.. 1. L-1a (, ), L-0 (, ) C 12 H 25 SO 4 Na ( L-0),,. 50 150, 10 β5., ДβЖ.,..,, O 2- Ti 4 +.,,. Ti 4 +,,,. 2- Ti 4 +. ( ). ( 1, β) L-0,,,,. 384

-,,, 15 15 β01γ.. β. L-0 1. %. % Ti O C F N Ti O C F N 68,02 21,21 1,97 8,12 0,68 41,94 39,16 4,85 12,62 1,43 1 71,93 17,16 3,62 7,29-46,08 32,91 9,24 11,77 - β 53,61 24,33 12,24 9,24 0,58 26,73 36,32 24,33 11,62 1,00 γ 55,19 20,75 13,93 8,14-29,27 31,80 28,43 10,50 -,.,.,.,,, ДγЖ.,. L-1a.% β9,79 TТ, 41,05, 1β,00 C, 16,58 F. % 55,94 TТ, β5,75, 5,65 C, 12,35 F.,,., Д1,βЖ..,,,,... 12-03-13003-13 1... / 5β-..:. 2009.. V. 1.. 67. 2. TiO 2, /..,..,..,..,.. //. 2007..45 1. 65-69. 385

-,,, 15 15 β01γ. 3..., -..,..,.., //. β011..47. γ..β77-285.,...,,..., -.,,,, 1:1,. -.., 2.. -. 3--1--2- -1-,...,.....;...,,.. -,, Д1]. - Д2Ж ДγЖ., 3--1--2--1- (1). (γ--1--2--1-) (BF 2 ) Д4Ж. (. 1). 386

-,,, 15 15 β01γ. Ph O B O F F CH 3 NH 4 OH Ph O NH 2 CH 3. 1. 1 Ph BF 3 OEt 2 (BuO) 3 B O B NH F 1 F CH 3 1 (. β), (BF 2 ) [5Ж. 1 -. 1... β. 1 1 (. γ).. γ. : 1 1, 2 BABF 2, 3 1 (c = 110-5 /), 4 BABF 2 (c = 110-5 /) 1.. 1, β,75 1,β5. 4-1. (=1,β5 ), (=β,75 ) 1. 387