Inclusion Complexation of Amylose

Transcript

1 PROGRESS IN CHEMISTRY Vol. 22 No. 6 Jun * O O A X Inclusion Complexation of Amylose Li Bengang 1 2 Zhang Liming 2 1. College of Science Nanjing Forestry University Nanjing China 2. School of Chemistry and Chemical Engineering Sun Yat-Sen University Guangzhou China Abstract Amylose can form single helix in solutions which may act as a host molecule to complex various hydrophobic guest molecules by hydrophobic interactions. In this article the research progress in the inclusion complexation of amylose is reviewed. The category and preparation of amylose inclusion complexes are introduced in detail. In addition the applications of the inclusion complexation of amylose in flour food as well as the preparation of new materials are summarized. Key words amylose inclusion complexes preparation application Contents 1 Introduction 2 Category and preparation of amylose inclusion complexes 2. 1 Inorganic materials as gust molecules 2. 2 Organic compounds as gust molecules 2. 3 Polymers as gust molecules 2. 4 SWNTs as gust molecules 2. 5 Soluble amylose inclusion complex 3 Applications of amylose inclusion complexation in flour food 4 Applications of amylose inclusion complexation in the preparation of new materials 4. 1 Biomaterials 4. 2 Optical materials 4. 3 Physically cross-linked gels 4. 4 Self-assembly films 5 Conclusion and outlook 1 D- α-1 4 D- α-1 4 α- β- γ * No Corresponding author Libengang_1980@ yahoo. com. cn ceszhlm@ mail. sysu. edu. cn

2 a C3 C X b 3 I - 3 I-I I - I ph a b 20 5 Fig. 1 Molecular structures of cyclodextrins a and single helix formed by amylose b Vamylose Vamylose Vamylose V h amylose V butanol V isopropanol V glycerol V 4 7 α-naphthol V h amylose V h amylose V h amylose 6

3 Kida 31 / ε- V butanol V isopropanol V glycerol ε Kadokawa 32 - α- vine-twining polymerization V α-naphthol V α-naphthol a - 2 b Kadokawa Vamylose - 21 Gunninga 22 Tween AFM / KOH / HCl KOH HCl ph / / a b Fig. 2 Mechanism of the preparation of amylose by enzymatic polymerization a and the vine-twining polymerization b 32

4 Kim 42-10% 20% / SWNTs 1nm Fig. 4 In situ synthesis of amylose-swnts inclusion 3 complex through vine-twining polymerization / DP = 47 3 Wullf 46 5 Fig. 3 Schematic illustration of the formation of amylose- SWNTs inclusion complex DP DP = 80 DP < 50 DP >

5 Gunninga 22 Polewski Karlberg PEG 25 PEG 56 Akiyoshi 45 / / / 4. 1 Lalush 24 PEG 3-70% DNA Fu 43

6 V V = min / Kim DASPC n V V = 2 1 ca Da / V V = min / V V = Kim Sanji Fig. 5 Schematic illustration for the construction of LbL assembly films between partially methylated amylose and a ph guest polymer onto substrate 70 ph LbL 69 LbL Kida /

7 Song L X Bai L Xu X M He J Pan S Z. Coordination Chemistry Reviews Guo M Y Jiang M. Progress in Chemistry Star A Steuerman D W Heath J R Stoddart J F. Angew. Chem. Int. Ed Tufvesson F Eliasson A C. Carbohydrate Polymers Nuessli J Putaux J L Bail P L Buléon A. International Journal of Biological Macromolecules Le Bail P Rondeau C Buléon A. International Journal of Biological Macromolecules Cardoso M B Putaux J L Nishiyama Y et al. Biomacromolecules Nimz O Geβler K Usón I et al Carbohydrate Research 9 Sarko A Biloski A. Carbohydrate Research Senti R F Witnauer L P. J. Polym. Sci Rundle R E. J. Am. Chem. Soc Yu X Houtman C Atalla R H. Carbohydrate Research Cui K Y Lv M Wang R Z. Science Information Winter W T Sarko A. Biopolymers Kim J Y Lim S T. 116 Carbohydrate Polymers Zabar S Lesmes U Katz I Shimoni E Bianco-Peled H. Food Hydrocolloids Biais B le Bail P Robert P Pontoire B Buléon A. Carbohydrate Polymers Lundqvist H Eliasson A C Olofsson G. Carbohydrate Polymers Kim O K Choi L S Zhang H Y He X H Shih Y H. J. Am. Chem. Soc Egermayer M Piculell L. J. Phys. Chem. B Karlberg M Piculell L Huang L. Carbohydrate Polymers Gunninga A P Giardinab T P Faulds C B et al. Carbohydrate Polymers Karkalas J Ma S Morrison W Pethrick R A. Carbohydr. Res Lalush I Bar H Zakaria I Eichler S Shimoni E. Biomacromolecules Lesmes U Cohen S H Shener Y Shimoni E. Food Hydrocolloids Choi L S Kim O K. Macromolecules Tufvesson F Wahlgren M Eliasson A C. Starch-St rke Tufvesson F Wahlgren M Eliasson A C. Starch-St rke Shogren R L Green R V Wu Y V. J. Appl. Polym. Sci Shogren R L. Carbohydr. Polym Kida T Minabe T Akashi M. Chem. Commun Kaneko Y Kadokawa J. The Chemical Record Ziegast G Pfannemüller B. Carbohydrate Research Kadokawa J Kaneko Y Tagaya H Chiba K. Chem. Commun Kadokawa J Kaneko Y Nagase S Takahashi T Tagaya H. Chem. Eur. J Kaneko Y Beppu K Kadokawa J Biomacromolecules Kadokawa J Kaneko Y Nakaya A Tagaya H. Macromolecules Kadokawa J Nakaya A Kaneko Y Tagaya H. Chem. Phys Macromol. 39 Kaneko Y Saito Y Nakaya A Kadokawa J Tagaya H. Macromolecules Kaneko Y Beppu K Kadokawa J. Macromol. Chem. Phys Lii C Stobinski L Tomasik P Liao C. Carbohydrate Polymers Kim O K Je J Baldwin J W Kooi S Pehrsson P E Buckley L J. J. Am. Chem. Soc Fu C Meng L Lu Q Zhang X Gao C. Macromol. Rapid Commun Yang L Q Zhang B Liang Y Yang B Kong T Zhang L M. Carbohydrate Research Akiyoshi K Maruichi N Kohara M Kitamura S. Biomacromolecules Wulff G Steinert A H ller O Carbohydrate Research Gidley M J Bulpin P V. Macromolecules Polewski K Napieral D Carbohydrate Research Li B G Zhang L M. CN Dong B Dou K N. Processing Grain 51 Nimz O Gessler K Usón I Sheldrickb G M Saengera W. Carbohydrate Research Gelders G G Goesaert H Delcour J A. J. Agric. Food Chem Arvisenet G Bail P L Voilley A Cayot N. J. Agric. Food Chem Jouquand C Ducrueta V le Bail P. Food Chemistry

8 Tapanapunnitikul O Chaiseri S Peterson D G Thompson D B. J. Agric. Food Chem Cohen R Orlova Y Kovalev M Ungar Y Shimoni E. J. Agric. Food Chem Meng L Fu C Lu Q. Progress in Natural Science Kim O K Choi L S Zhang H Y He X H Shih Y H. Solid Films / Thin 59 Clays K Olbrechts G Munters T Persoons A Kim O K Choi L S. Chemical Physics Letters Kim O K Je J Melinger J S. J. Am. Chem. Soc Pepitone M F Jernigan G G Melinger J S Kim O K. Lett Org. 62 Sanji T Kato N Tanaka M. Macromolecules Sanji T Kato N Tanaka M. Org. Lett Gruber J V Konish P N. Macromolecules Chronakis I S Egermayer M Piculell L. Macromolecules Egermayer M Norrman J Piculell L Egermayer M Karlberg M Piculell L Langmuir Langmuir Karlberg M Piculell L Ragout S. Langmuir Xuan L J Qian J W Chen Y F Zhang P Progress in Chemistry 70 Kida T Minabe T Nakano S Akashi M. Langmuir