22 6 2010 6 PROGRESS IN CHEMISTRY Vol. 22 No. 6 Jun. 2010 * 1 2 2 1. 210037 2. 510275 O636. 1 O641. 4 A 1005-281X 2010 06-1161-08 Inclusion Complexation of Amylose Li Bengang 1 2 Zhang Liming 2 1. College of Science Nanjing Forestry University Nanjing 210037 China 2. School of Chemistry and Chemical Engineering Sun Yat-Sen University Guangzhou 510275 China Abstract Amylose can form single helix in solutions which may act as a host molecule to complex various hydrophobic guest molecules by hydrophobic interactions. In this article the research progress in the inclusion complexation of amylose is reviewed. The category and preparation of amylose inclusion complexes are introduced in detail. In addition the applications of the inclusion complexation of amylose in flour food as well as the preparation of new materials are summarized. Key words amylose inclusion complexes preparation application Contents 1 Introduction 2 Category and preparation of amylose inclusion complexes 2. 1 Inorganic materials as gust molecules 2. 2 Organic compounds as gust molecules 2. 3 Polymers as gust molecules 2. 4 SWNTs as gust molecules 2. 5 Soluble amylose inclusion complex 3 Applications of amylose inclusion complexation in flour food 4 Applications of amylose inclusion complexation in the preparation of new materials 4. 1 Biomaterials 4. 2 Optical materials 4. 3 Physically cross-linked gels 4. 4 Self-assembly films 5 Conclusion and outlook 1 D- α-1 4 D- α-1 4 α- β- γ- 6 7 8 2009 8 2009 9 * No. 20676155 Corresponding author e-mail Libengang_1980@ yahoo. com. cn ceszhlm@ mail. sysu. edu. cn
1162 22 2 1 a 1 2. 1 C3 C5 8 9 10 X 11-12 - 6 1 2 5 8 1 b 3 I - 3 I-I 3. 1 30 40 I - I - 13 6 7 8 ph 4 7 1 1 3 a b 20 5 Fig. 1 Molecular structures of cyclodextrins a and single helix formed by amylose b 1 3 13 2. 2 14 15 16 17 18 19 20 21 Vamylose Vamylose Vamylose V h amylose V butanol V isopropanol V glycerol V 4 7 α-naphthol V h amylose V h amylose V h amylose 6
6 1163 Kida 31 / ε- V butanol V isopropanol V glycerol ε- 7 6 7 Kadokawa 32 - α- vine-twining polymerization V α-naphthol V α-naphthol -1-8 33 2 a - 2 b Kadokawa Vamylose - 21 Gunninga 22 Tween-20 34 36 37 39-38 AFM 40 32 - - 20 21 / 23 25 KOH / HCl 23 25 KOH HCl ph 4. 7 - / / 16 26 28 2. 3 2 a b 32 29 31 32 Fig. 2 Mechanism of the preparation of amylose by enzymatic polymerization a and the vine-twining polymerization b 32
1164 22 Kim 42-10% 20% 6-2. 4 / SWNTs 1nm 3 - - - - 4-3 3 4-44 - Fig. 4 In situ synthesis of amylose-swnts inclusion 3 complex through vine-twining polymerization 44 41 42 / 43 2. 5 45 46 3 - DP = 47 3 Wullf 46 5 Fig. 3 Schematic illustration of the formation of amylose- SWNTs inclusion complex 3 44 44 46 DP DP = 80 DP < 50 DP > 2 000 47 44 2 3 -
6 1165 51-21 22 48 Gunninga 22 Polewski 48 52 Karlberg 21 53 55 PEG 25 PEG 56 Akiyoshi 45 / 25 56-4 49 / / 4. 1 Lalush 24 PEG 3-70% DNA 57 3 41 44 50 - Fu 43
1166 22 4. 2 V V = 2 1 15min / Kim 19 58 59 DASPC n V V = 2 1 ca. 4 500 Da / V V = 1 9 15min 19 58 / V V = 1 9 59 5 Kim 60 61 Sanji 62 63 4. 3 5 70 Fig. 5 Schematic illustration for the construction of LbL 64 68 assembly films between partially methylated amylose and a ph guest polymer onto substrate 70 ph 5 64 65-67 - - - 66 68 4. 4 LbL 69 LbL Kida 70 - - /
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