) ( )

Σχετικά έγγραφα
任秉雄 王崇臣 ENVIRONMENTAL CHEMISTRY. 744 t 50% 10% 20% 1 mg L t S. SHZ-82 Spectrum-100 C 16 H 18 N 3 SCl 3H 2 O

,, *,, (, ) ,, [1 3]. B,. ,,, [4].,

Fenton. COD ρ NH N TP ENVIRONMENTAL PROTECTION OF CHEMICAL INDUSTRY

Removal of Dissolved Cadmium by Adsorption onto Walnut and Almond Shell Charcoal: Comparison with Granular Activated Carbon (GAC)

Removal of Organic Dyes from Industrial Wastewaters Using UV/H2O2, UV/H2O2/Fe (II), UV/H2O2/Fe (III) Processes

Supporting Information. Enhanced energy storage density and high efficiency of lead-free

Supplementary Table 1: Adsorption characteristics of different adsorbents for water treatment 22

SnO 2. Research Progress in the Preparation Modification and Aplication of Ti-based SnO 2. Electrode. LI Xiaoliang XU Hao YAN Wei SHAO Dan

ΠΡΟΣΟΜΟΙΩΣΕΙΣ ΧΗΜΙΚΩΝ ΔΙΕΡΓΑΣΙΩΝ ΜΕ ΧΡΗΣΗ ΤΟΥ ASPEN HYSYS: ΕΦΑΡΜΟΓΗ ΣΤΗΝ ΕΛΛΗΝΙΚΗ ΑΕΡΟΠΟΡΙΚΗ ΒΙΟΜΗΧΑΝΙΑ

Supporting information. An unusual bifunctional Tb-MOF for highly sensing of Ba 2+ ions and remarkable selectivities of CO 2 /N 2 and CO 2 /CH 4

Gro wth Properties of Typical Water Bloom Algae in Reclaimed Water

C 14 /Fe 3 O 2 :

Synthesis Characterization and Application of Phosphorus-Containing Derivatives of Chitosan

Vol.37 No Journal of South-Central University for Nationalities Nat.Sci.Edition Mar.2018

Δρ. Γεώργιος Ζ. Κύζας

Preparation of polystyrene magnetic microspheres for liquid chips by dispersion polymerization

Β Ι Ο Γ Ρ Α Φ Ι Κ Ο Σ Η Μ Ε Ι Ω Μ Α

Polymer-Based Composites with High Dielectric Constant and Low Dielectric Loss

Industrial Water Treatment. Study status and development trends in the wastewater treatment by electro-fenton method

( Fe 3 O 4 ) The Preparation Methods of Magnetite Nanoparticles and Their Morphology. Vol. 19 No. 6 June, 2007 PROGRESS IN CHEMISTRY )

Journal of Central South University (Science and Technology) Aug. 2010

ΒΙΟΓΡΑΦΙΚΟ ΣΗΜΕΙΩΜΑ ΔΗΜΗΤΡΙΟΣ Γ. ΚΑΛΔΕΡΗΣ

Air Drying Process of Granules and Characteristics of Their Structure

Synthesis of Micro/Mesopore Composite Molecular Sieves

The Exploitation and Utilization of Magnesium Resources in Salt Lakes

( ) ( ) ZnO/TiO 2 : COD. TiO 2. TiO 2

ΕΚΤΙΜΗΣΗ ΠΑΡΑΜΕΤΡΩΝ ΥΠΟΔΕΙΓΜΑΤΩΝ ΠΡΟΣΡΟΦΗΣΗΣ ΠΟΥ ΧΡΗΣΙΜΟΠΟΙΟΥΝΤΑΙ ΣΤΗΝ ΑΠΟΜΑΚΡΥΝΣΗ ΡΥΠΩΝ ΑΠΟ ΥΓΡΑ ΒΙΟΜΗΧΑΝΙΚΑ ΑΠΟΒΛΗΤΑ

( ) ( )

Study on Synthesis of Dibutyl Succinate Catalyzed by Phosphtungstic Acid and its Reaction Kinetics

Journal of Fuzhou University Natural Science Edition. The preparation and visible - light photocatalysis of Ag 3 PO 4 /TiO x N y

Progress in Biomimicing of Super2Hydrophobic Surface

Supporting Information

. (SERS),,. ( 1.2~ 0.9 V),

Supplementary Information

ΚΙΝΗΤΙΚΗ ΠΡΟΣΕΓΓΙΣΗ ΣΤΗ ΔΕΣΜΕΥΣΗ ΤΟΥ ΟΥΡΑΝΙΟΥ ΑΠΟ ΕΝΑΝ ΠΡΟΒΙΟΤΙΚΟ ΜΙΚΡΟΟΡΓΑΝΙΣΜΟ

Βιογραφικό Σημείωμα Dr. Απόστολος Γιαννής

Preparation of superfine aluminum hydroxide by ion-exchange membrane electrolysis

Supporting Information

Επιστημονική Επετηρίδα, Τμήμα Γεωλογίας, Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης Τιμητική έκδοση στη μνήμη του ομότιμου καθηγητή Κ.

LUO, Hong2Qun LIU, Shao2Pu Ξ LI, Nian2Bing

Β Ι Ο Γ Ρ Α Φ Ι Κ Ο Σ Η Μ Ε Ι Ω Μ Α

ΔΙΔΑΚΤΟΡΙΚΗ ΔΙΑΤΡΙΒΗ ΒΙΟΛΟΓΙΚΗ ΑΝΑΓΩΓΗ ΕΞΑΣΘΕΝΟΥΣ ΧΡΩΜΙΟΥ ΜΙΧΑΗΛ Κ. ΜΙΧΑΗΛΙΔΗ

Acta Phys. Sin. Vol. 61, No. 9 (2012) ) 1) 1) 2) 1) 1) (,, ) 2) (, ) ( ; )

ΕΦΑΡΜΟΓΗ ΕΥΤΕΡΟΒΑΘΜΙΑ ΕΠΕΞΕΡΓΑΣΜΕΝΩΝ ΥΓΡΩΝ ΑΠΟΒΛΗΤΩΝ ΣΕ ΦΥΣΙΚΑ ΣΥΣΤΗΜΑΤΑ ΚΛΙΝΗΣ ΚΑΛΑΜΙΩΝ

Studies on the Binding Mechanism of Several Antibiotics and Human Serum Albumin

Removal of Congo Red Dye from Textile Wastewater

Recent advances in coal to chemicals technology developed by SINOPEC

JOURNAL OF THE CHINESE CERAMIC SOCIETY. TiO 2 X

CYPRUS UNIVERSITY OF TECHNOLOGY Faculty of Geotechnical Sciences and Environmental Management Department of Environmental Science and Technology

The Radiation2Induced Synthesis of Hydrogels and Their Application for Removal of Heavy Metal Ions from Aqueous Solution

Carbon and Conducting Polymer Composites for Supercapacitors

Vol. 5 No. 1 Feb EL ECTROCHEMISTR Y ( ) ( ) ( EHD), ( FDN) ( TEA- PTS), Tri2 tonx-100 ,FDN. EHD. EHD. RH. RH 2. Guidelli, 1.

Adsorption separation performance of different absorbents for biogas decarbonization upgrading

STUDY ON SCREENING AND OPTIMIZATION OF MUNICIPAL SLUDGE DEEP DEWATERING CONDITIONERS

Δρ. Γεώργιος Ζ. Κύζας

Heterobimetallic Pd-Sn Catalysis: Michael Addition. Reaction with C-, N-, O-, S- Nucleophiles and In-situ. Diagnostics

[ΥΡΖΖ ΦΤΗΚΑ ΚΑΗ ΥΖΜΗΚΑ

16 1 Vol. 16 No ELECTROCHEMISTRY Feb MnO 6 Bir-Co5% Bir-Co10% Bir-Co15% Bir-Co20%. 3 3 Li mol L - 1 MgCl 2.

ΣΥΝΘΕΣΗ Υ ΡΟΞΥ-ΟΞΕΙ ΙΩΝ ΣΙ ΗΡΟΥ ΓΙΑ ΑΠΟΜΑΚΡΥΝΣΗ ΑΡΣΕΝΙΚΟΥ ΑΠΟ ΤΟ ΠΟΣΙΜΟ ΝΕΡΟ

PNS mg kg - 1. Rb 1

ΠΤΥΧΙΑΚΗ ΕΡΓΑΣΙΑ. ΘΕΜΑ: Αποσκλήρυνση Υπόγειων Νερών Με Χρήση Προσροφητικών Υλικών

Iodine-catalyzed synthesis of sulfur-bridged enaminones and chromones via double C(sp 2 )-H thiolation

Supplementary Material

Research on the Effect and Technique of Remediation for Multi-Metal Contaminated Tailing Soils

AΠΟΜΑΚΡΥΝΣΗ ΧΡΩΣΤΙΚΩΝ ΑΠΟ Υ ΑΤΙΚΑ ΣΥΣΤΗΜΑΤΑ ΜΕ ΧΡΗΣΗ ΤΕΧΝΙΚΩΝ ΕΠΙΠΛΕΥΣΗΣ ΚΑΙ ΡΟΦΗΣΗΣ

Electronic Supplementary Information

Electrolyzed-Reduced Water as Artificial Hot Spring Water

Œ.. ² μ,.. Œ ²μ, ƒ.. μ ±μ,. Ô Ô ², Œ.. ƒê Éμ, Œ.. Œ ² μ *

Rapid Raman spectra identification and determination of levofloxacin hydrochloride injection *

metriva 1. DietQuest, CE 3410 ( ) CE 7210 ( ), CECIL INSTRUMENTS,, 232, 266, 270 & 274nm. Cecil Instruments,., metriva. Cecil,,,,.

Επεξεργασία πειραματικών αποτελεσμάτων

Effects of lime sulphur synthetic solution on leaching characteristic of gold concentrates

. K HPLC. 2 ~ 50 μg / ml r ~ mg / kg 15

Study on the Strengthen Method of Masonry Structure by Steel Truss for Collapse Prevention

PROGRESS IN CHEMISTRY. ,ZnO. Yang Sen Ni Yonghong 3 3. (No )

Survey Efficiency of Ultraviolet and Zinc Oxide Process (UV/ZnO) for Removal of Diazinon Pesticide from Aqueous Solution

Study on surface acid2base properties of Chinese loess

(organic light emitting

Environmental applications of Graphene-based materials

ΠΟΛΥΤΕΧΝΕΙΟ ΚΡΗΤΗΣ ΤΜΗΜΑ ΜΗΧΑΝΙΚΩΝ ΠΕΡΙΒΑΛΛΟΝΤΟΣ

Η ΔΙΔΑΣΚΑΛΙΑ ΤΩΝ ΜΟΡΦΟΛΟΓΙΚΩΝ ΔΙΑΔΙΚΑΣΙΩΝ ΤΗΣ ΠΑΡΑΓΩΓΗΣ ΚΑΙ ΤΗΣ ΣΥΝΘΕΣΗΣ ΥΠΟ ΤΟ ΠΡΙΣΜΑ ΤΩΝ ΑΠΣ: ΜΙΑ ΚΡΙΤΙΚΗ ΘΕΩΡΗΣΗ

ADSORPTION OF DYE POLLUTANTS BY GREEK LIGNITE: A PRELIMINARY EXPERIMENTAL STUDY 1

1 Vol. 16 No ELECTROCHEMISTRY Feb mmol /L dimethylamino propyl -3-eth- 5 ylcarbo-diimide hydrochloride 99% EDC 6-7

The pathway of the ozonation of 2,4,62trichlorophenol in aqueous solution

- A. A Biphenol A BPA BPA BPA LLE 5 SPE Electrospinning Kang. Packed-fiber solid-phase extraction PFSPE 1 ml

SUPPORTING INFORMATION

ph Maillard MRPs maillard reaction products Maillard ph kDa Maillard Maillard DOI /j. issn

D-Glucosamine-derived copper catalyst for Ullmann-type C- N coupling reaction: theoretical and experimental study

Supporting Information

MSc Χατζηχρήστου Δ. Χρηστίνα

Evolution of Novel Studies on Thermofluid Dynamics with Combustion

Highly enantioselective cascade synthesis of spiropyrazolones. Supporting Information. NMR spectra and HPLC traces

Engineering Tunable Single and Dual Optical. Emission from Ru(II)-Polypyridyl Complexes. Through Excited State Design

2 1, 2 A 2F 10 : : 00 1A01 C 4F B 5F 10 : : 40 1B01 1C01 1A02 1C02 BC2N 1B02 1B04. 1A03 C/N Fe 1C03. 1C04 DNA Somlak Ittisanronnnachai

J. of Math. (PRC) 6 n (nt ) + n V = 0, (1.1) n t + div. div(n T ) = n τ (T L(x) T ), (1.2) n)xx (nt ) x + nv x = J 0, (1.4) n. 6 n

8Q5SAC) 8Q5SAC UV2Vis 8500 ( ) ; PHS23C ) ;721 ( ) :1 4. ;8Q5SAC : molπl ;Britton2Robinson Q5SAC BSA Britton2Robinson,

SMD Wire Wound Ferrite Chip Inductors - LS Series. LS Series. Product Identification. Shape and Dimensions / Recommended Pattern LS0402/0603/0805/1008

April 2013 Chinese Journal of Chromatography 380 ~ A

JOURNAL OF THE CH INESE RARE EARTH SOC IETY. Langmuir : H = kj mol - 1, S = 130 J (mol K) - 1, G 298 K = kj mol

Supplementary material

Transcript:

- - mbehzad@semnan.ac.ir() ( ) - (// // ). ph. ph...... :.[-]...[ ]...[-] 1 Activated Carbon (AC) -..[ ].. COD BOD.[]..[ ]. 84

/... (λ max ) --. UV-Vis. -- ( ). ( ppm) / / / / ph. AC/PVA AC /. UV-Vis. - ph... - ph --. ph. ppm ph. / () = 2 Beer -Lambert law Ci C C i f * 100 (AC/PVA).[].[].[].[]. AC AC/PVA. - --..... -- 85

-- ppm. ph / /) AC/PVA AC ( / / /.( ) /... 100 80 60 40 20 0 رنگ قرمز ۱۹۸ رنگ ابي ۱۹ 0 0.1 0.2 0.3 AC/PVA (گرم ( () C f C i.. / AC/PVA ph ph. ph.( ). ph ph. ph... () AC - AC/PVA - - -- ph ppm /. ph - AC - AC/PVA - 86

/ e.( ) AC/PVA ( ) e (Ci Ce)V = M.... -- ---. t = 0. = 0 t = t = e d K(e ) dt = k1t log( e ) = log e ( ) 2.303 e. K 1 t log( e -). ---.... 100 80 60 40 20 0 90 80 70 60 50 40 30 20 10 0 رنگ ابي ۱۹ رنگ قرمز ۱۹۸ 0 15 30 45 60 75 90 105 120 135 زمان (دقیقه) () ابي ۱۹ رنگ قرمز ۱۹۸ رنگ 0 30 60 90 120 150 زمان (دقیقه) - AC - AC/PVA - -- ---. ph 87

= e =0 t=t d dt 2 2 (e ) t=0 = k () t 1 t = + (k 2 2e) e K 2 (t/) k 2 e... () - AC - AC/PVA - - - - - - AC AC/PVA. AC/PVA AC.( ) 88

1/ n e = K F C e 1 log e = log KF + logce n e C e. K C m L e e = 1+ K LCe e C e m K L ( ). (K L ) ( m ) 1/C e 1/ e 1 e 1 t 1 = + () K C m L m e.( ) - AC/PVA - / / / / / - / / / e (mg g -1 ) / K 1 (min -1 ) / R 2 / max / e (mg g -1 ) - / K 2 (mg g -1 min -1 ) / R 2 AC - / / / / / - / / / e (mg g -1 ) / K 1 (min -1 ) / R 2 / max / e (mg g -1 ) - / K 2 (mg g -1 min -1 ) / R 2 --... 89

() AC - - AC/PVA - - -..[-]. - [] [] [] - [] [] [] AC/PVA - ( m ) / / (-) / / / 90

.. AC/PVA. - ph.. / ph. - 1. Gupta, V., and Suhas, K. (2009). Application of low-cost adsorbents for dye removal A review. J. of Environ. Manag., 90(8), 2313-2342. 2. Forgacs, E., Cserhati, T., and Oros, G. (2004). Removal of synthetic dyes from wastewaters: a review. J. of Environ. Int., 30(7), 953-971. 3. Robinson, T., McMullan, G., Marchant, R., and Nigam, P. (2001). Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. J. of Bioresource. Technol., 77(3), 247-255. 4. Kannan, C., Muthuraja, K.R., and Devi, M. (2013). Hazardous dyes removal from aueous solution over mesoporous aluminophosphate with textural porosity by adsorption. J. of Hazard. Mater., 244-245, 10-20. 5. Rajeshwari, S., Namasivayam, C., and Kadirvelu, K. (2001). Orange peel as an adsorbent in the removal of acid violet 17 (Acid Dye) from aueous solution. J. of Waste. Manage, 21(1), 105-110. 6. Rajkumar, D., and Kim, J.G. (2006). Oxidation of various reactive dyes with in situ electro-generated active chlorine for textile dyeing industry wastewater treatment. J. of Hazard. Mater., 136(2), 203-212. 7. Wan Ngah, W.S., Teong, L.C., and Mhanafiah, A.K.M. (2011). Adsorption of dyes and heavy metal ions by chitosan composites: A review. J. of Carbohyd. Polym., 83(4), 1446-1456. 8. Mohd Salleh, M.A., Khalid Mahmoud, D., Wan Abdul Karim, W.A., and Idris, A. (2011). Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. J. of Desalination. 280(1/3), 1-13. 9. Nguyen, T.A., and Juang, R.S. (2013). Treatment of waters and wastewaters containing sulfur dyes: A review. J. of Chem. Eng., 219, 109-117. 10. Zhang, S.J., Yu, H.Q., and Feng, H.M. (2006). PVA-based activated carbon fibers with lotus root-like axially porous structure. J. of Carbon, 44 (10), 2059-2068. 11. Malik, P.K. (2004). Dye removal from wastewater using activated carbon developed from sawdust: adsorption euilibrium and kinetics. J. of Hazard. Mater., 113 (1/3), 81-88. 12. Farahani, M., Sheikh Abdullah, S.R., Hosseini, S., Shojaeipour, S., and Kashisaz, M. (2011). Adsorptionbased cationic dyes using the carbon active sugarcane bagasse. J. of Procedia. Environ. Sci., 10, 203-208. 13. Li Wen, H., Yue, Q.Y., Gao, B.Y., Wang, X.J., Qi, Y.F., Zhao, Y.Q., and Li, Y.J. (2011). Preparation of sludge-based activated carbon made from paper mill sewage sludge by steam activation for dye wastewater treatment. J. of Desalination, 278(1/3), 179-185. 91

14. Mezohegyi, G.P., Van Der Zee, F., Font, J., Fortuny, A., and Fabregat, A. (2012). Towards advanced aueous dye removal processes: A short review on the versatile role of activated carbon. J. of Environ. Manage, 102, 148-164. 15. Mahmoodi, N.M., Salehi, R., and Arami, M. (2011). Binary system dye removal from colored textile wastewater using activated carbon: Kinetic and isotherm studies. J. of Desalination, 272(1/3), 187-195. 16. Kumar Gupta, V., Kumar, R., Nayak, A., Saleh, T.A., and Barakat, M.A. (2013). Adsorptive removal of dyes from aueous solution onto carbon nanotubes: A review. J. of Adv. Colloid. Interface, 193/194, 24-34. 17. Gehlot, P., Daga, K., and Mehta, R. (2011). Adsorption study of water using Poly Vinyl Alcohol coated carbon black as an effective and low cost adsorbent. Inter. J. Chem., 3(1916/9698), 1916-9701. 18. Feng, Y., Yang, F., Wang, Y., Ma, L., Wu, Y., Kerr, P.G., and Yang, L. (2011). Basic dye adsorption onto an agro-based waste material-sesame hull (Sesamum indicum L.). J. of Bioresour. Technol., 102, 10280-10285. 19. Sandeman, S.R., Gunko, V.M., Bakalinska, O.M., Howell, C.A., Zheng, Y., Kartel, M.T., Phillips, G.J., and Mikhalovsky, S.V. (2011). Adsorption of anionic and cationic dyes by activated carbons, PVA hydrogels, and PVA/AC composite. J. of Colloid Interface Sci., 358, 582-592. 20. Moussavi, Gh., and Mahmoudi, M. (2009). Removal of azo and anthrauinone reactive dyes from industrial wastewaters using MgO. J. of Hazard. Mater., 168, 806-812. 21. Guyen, K.N., Thi, T.H.P., Lam, T.D., and Tran, Q.H. (2013). A facile synthesis of nanostructured magnesium oxide particles for enhanced adsoption performance in reactive blue 19 removal. J. of Coloid. Interface. Sci., 398, 210-216. 22. Jiang, X., Yongmei, S, Liu, L., Wang, and Tian, X. (2013) Adsorption of C.I. reactive blue 19 from aueous solutions by porous particles of the grafted chitosan. J. of Chem. Eng., 235, 151-157. 23. Osman, G., Sahmurova, A., and Kama, S. (2011) Removal of Reactive Red 198 from aueous solution bypotamogeton crispus. J. of Chem. Eng., 174, 579-585. 24. Elkady, M.F., Lbrahim, A.M., and Abd El-latif, M.M. (2011) Assessment of the adsorption kinetics, euilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads. J. of Desalination, 278, 412-423. 92