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1 Technical Information T-23 ENG ddupont Fluorochemicals Thermodynamic Properties of HFC-23 (trifluoromethane) DuPont Product Names: Freon 23

2 Thermodynamic Properties of HFC-23 Refrigerant (trifluoromethane) Engineering (I/P) Units New tables of the thermodynamic properties of HFC-23 have been developed and are presented here. These tables are based on experimental data developed by Y. C. Hou and J. J. Martin, and presented in their paper, Physical and Thermodynamic Properties of Trifluoroemethane (A. I. Ch. E. Journal 5:125 29). Equations have been developed, based on the Martin-Hou equation of state, which represent the data with accuracy and consistency throughout the entire range of temperature, pressure, and density. Physical Properties Chemical Formula CHF 3 Molecular Weight Boiling Point at One Atmosphere F ( C) Critical Temperature, T c F (25.92 C) R ( K) Critical Pressure, P c psia ( kpa [abs]) Critical Density, D c lb/ft 3 ( kg/m 3 ) Critical Volume, V c ft 3 /lb ( m 3 /kg) Units and Factors t = temperature in F T = temperature in R = F P = pressure in lb/in 2 absolute (psia) v f = volume of saturated liquid in ft 3 /lb v g = volume of saturated vapor in ft 3 /lb V = volume of superheated vapor in ft 3 /lb d f = 1/v f = density of saturated liquid in lb/ft 3 d g = 1/v g = density of saturated vapor in lb/ft 3 h f = enthalpy of saturated liquid in Btu/lb h fg = enthalpy of vaporization in Btu/lb h g = enthalpy of saturated vapor in Btu/lb H = enthalpy of superheated vapor in Btu/lb s f = entropy of saturated liquid in Btu/(lb) ( R) s g = entropy of saturated vapor in Btu/(lb) ( R) S = entropy of superheated vapor in Btu/(lb) ( R) C p = heat capacity at constant pressure in Btu/(lb) ( F) C v = heat capacity at constant volume in Btu/(lb) ( F) v s = velocity of sound in ft/sec The gas constant, R = (psia) (ft 3 )/( R) (lb-mole) for HFC-23, R = (psia) (ft 3 )/lb R One atmosphere = psia Conversion factor from Work Units to Heat Units: J = Btu/lb = (psia ft 3 )/lb J Reference point for enthalpy and entropy: h f = 0.0 Btu/lb at 40 F s f = 0.0 Btu/lb R at 40 F Equations 1. Conversion Factors I/P Units to SI Units Properties listed in the following thermodynamic tables in I/P units can be converted to SI units using the conversion factors shown below. Please note that in converting enthalpy and entropy from I/P to SI units, a change in reference states must be included (from H = 0 and S = 0 at 40 F for I/P units to H = 200 and S = 1 at 0 C for SI units). In the conversion equation below, H (ref) and S (ref) are the saturated liquid enthalpy and entropy at 40 C. For HFC-23, H (ref) = kj/kg and S (ref) = kj/kg K. P (kpa) T ( C) D (kg/m 3 ) V (m 3 /kg) H (kj/kg) S (kj/kg) C p (kj/kg K) C v (kj/kg K) v s (m/sec) = P (psia) = (T[ F] 32) 1.8 = D (lb/ft 3 ) = V (ft 3 /lb) = [H (Btu/lb) ] + H (ref) = [S (Btu/lb R) ] + S (ref) = C p (Btu/lb F) = C v (Btu/lb F) = v s (ft/sec)/ Martin-Hou Equation of State Coefficients for the Martin-Hou equation of state are presented below: 6 P = RT/(V b) + Σ (A i + B i T + C i exp [ kt/t c ])/(V b) i i=2 1

3 For SI units T and T c are in K = C , V is in m 3 /kg, and P is in kpa. R = kj/kg K for HFC-23 b, A i, B i, C i, and k are constants: A 2 = E 01 A 4 = E 07 B 2 = E 04 B 4 = E 10 C 2 = E+00 C 4 = E+00 A 3 = E 05 A 5 = E 10 B 3 = E 07 B 5 = E 13 C 3 = E 03 C 5 = E 09 A 6 = E+00 B 6 = E+00 C 6 = E+00 b = E 05 k = E+00 X and Y are constants used in the enthalpy and entropy equations for the Martin-Hou equation of state: X = E+02 Y = E 01 For I/P units T and T c are in R = F , V is in ft 3 /lb, and P is in psia. R = (psia) (ft 3 )/lb R for HFC-23 b, A i, B i, C i, and k are constants: A 2 = E+00 A 4 = E 03 B 2 = E 03 B 4 = E 06 C 2 = E+02 C 4 = E+00 A 3 = E 02 A 5 = E 05 B 3 = E 05 B 5 = E 08 C 3 = E+00 C 5 = E 04 A 6 = E+07 B 6 = E+05 C 6 = E+00 b = E 03 k = E+00 X and Y are constants used in the enthalpy and entropy equations for the Martin-Hou equation of state: Ideal Gas Heat Capacity (at constant volume): C o v = a + bt + ct 2 + dt 3 + f/t 2 For SI units C o v = kj/kg K T is in K = C a, b, c, d, f are constants: a = E 01 d = E 09 b = E 05 f = E+00 c = E 06 For I/P units C o v = Btu/lb R T is in R = F a, b, c, d, f are constants: a = E 02 d = E 10 b = E 06 f = E+00 c = E Vapor Pressure log 10 P sat = A + B/T + C log 10 T + D T + E (T) 2 + F(T) 3 For SI units T is in K = C and P is in kpa A, B, C, D, E, F are constants: A = E+02 D = E 01 B = E+03 E = E 04 C = E+02 F = E 07 For I/P units T is in R = F and P is in psia A, B, C, D, E, F are constants: A = E+02 D = E 01 B = E+03 E = E 04 C = E+02 F = E 08 X = E+01 Y = E 01 2

4 4. Density of the Saturated Liquid d f = A f + B f (1 T r ) (1/3) + C f (1 T r ) (2/3) + D f (1 T r ) + E f (1 T r ) (4/3) For SI units T r = T/T c, both in K = C and d f is in kg/m 3 A f, B f, C f, D f, E f are constants: A f = E+02 D f = E+03 B f = E+03 E f = E+03 C f = E+02 For I/P units T r = T/T c, both in R = F and d f is in lb/ft 3 A f, B f, C f, D f, E f are constants: A f = E+01 D f = E+02 B f = E+01 E f = E+02 C f = E+01 3

5 TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table TEMP. F PRESSURE psia LIQUID v f VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F

6 TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table TEMP. F PRESSURE psia LIQUID v f VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F

7 TEMP. F PRESSURE psia LIQUID v f TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F 6

8 TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table TEMP. F PRESSURE psia LIQUID v f VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F

9 TEMP. F PRESSURE psia LIQUID v f TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F 8

10 TABLE 1 (continued) HFC 23 Saturation Properties Temperature Table TEMP. F PRESSURE psia LIQUID v f VOLUME ft 3 /lb v g DENSITY lb/ft 3 LIQUID LIQUID 1/v f 1/v g h f ENTHALPY Btu/lb LATENT h fg h g LIQUID s f ENTROPY Btu/(lb)( R) s g TEMP. F

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34 For General Information: DuPont Fluorochemicals Wilmington, DE (302) SUVA For Technical Information: Fluorochemicals Laboratory Wilmington, DE (302) Europe DuPont de Nemours International S.A. 2 Chemin du Pavillon P.O. Box 50 CH-1218 Le Grand-Saconnex Geneva, Switzerland Canada DuPont Canada, Inc. P.O. Box 2200, Streetsville Mississauga, Ontario Canada L5M 2H3 (905) Mexico DuPont, S.A. de C.V. Homero 206 Col. Chapultepec Morales C.P Mexico, D.F South America DuPont do Brasil S.A. Alameda Itapecuru, 506 Alphaville Barueri São Paulo, Brazil DuPont Argentina S.A. Casilla Correo 1888 Correo Central 1000 Buenos Aires, Argentina Pacific DuPont Australia P.O. Box 930 North Sydney, NSW 2060 Australia Japan Mitsui DuPont Fluorochemicals Co., Ltd. Mitsui Seimei Bldg. 2-3, 1-Chome Ohtemachi Chiyoda-Ku, Tokyo 100 Japan Asia DuPont Taiwan P.O. Box Taipei, Taiwan Du Pont Asia Pacific Limited P.O. Box TST Tsim Sha Tsui Kowloon, Hong Kong DuPont Thailand P.O. Box 2398 Bangkok 10501, Thailand Du Pont China Ltd. Rm. 1704, Union Bldg. 100 Yenan Rd. East Shanghai, PR China Phone: Telex: DCLSH CN Fax: DuPont Far East Inc. P.O. Box Kuala Lumpur, Malaysia Phone: Telex: (784) DUFE M Fax: DuPont Korea Ltd. C.P.O. Box 5972 Seoul, Korea DuPont Singapore Pte. Ltd. 1 Maritime Square #07 01 World Trade Centre Singapore DuPont Far East, Philippines 5th Floor, Solid Bank Bldg. 777 Paseo de Roxas Makati, Metro Manila Philippines DuPont Far East Inc. 7A Murray s Gate Road Alwarpet Madras, , India DuPont Far East Inc. Pakistan 9 Khayaban-E-Shaheen Defence Phase 5 Karachi, Pakistan DuPont Far East Inc. P.O. Box 2553/Jkt Jakarta 10001, Indonesia The information contained herein is based on technical data and tests which we believe to be reliable and is intended for use by persons having technical skill, at their own discretion and risk. Because conditions of use are outside of DuPont control, we can assume no liability for results obtained or damages incurred through the application of the data presented. Reorder No.: H (10/94) A Printed in U.S.A. ddupont Fluorochemicals

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