938 Thermodynamics TABLE A 18. Ideal-gas properties of nitrogen, N 2 _ _ T
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1 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 18 Ideal-gas properties of nitrogen, N ,563 12, ,391 4, ,864 12, ,683 4, ,166 13, ,975 4, ,468 13, ,266 5, ,772 13, ,558 5, ,075 13, ,849 5, ,380 13, ,141 5, ,685 14, ,432 6, ,991 14, ,669 6, ,297 14, ,723 6, ,604 14, ,014 6, ,912 15, ,306 6, ,220 15, ,597 6, ,529 15, ,888 7, ,839 15, ,180 7, ,149 15, ,471 7, ,460 16, ,763 7, ,772 16, ,055 7, ,085 16, ,347 8, ,398 16, ,640 8, ,714 17, ,932 8, ,027 17, ,225 8, ,342 17, ,518 8, ,658 17, ,811 9, ,974 17, ,105 9, ,292 18, ,399 9, ,610 18, ,693 9, ,928 18, ,988 9, ,248 18, ,285 10, ,568 19, ,581 10, ,890 19, ,876 10, ,210 19, ,172 10, ,532 19, ,469 11, ,854 20, ,766 11, ,178 20, ,064 11, ,501 20, ,363 11, ,826 20, ,662 11, ,151 21, ,962 12, ,476 21, ,262 12, ,803 21,
2 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 939 ABLE A 18 Appendix Ideal-gas properties of nitrogen, N 2 (Conclded) ,129 21, ,227 41, ,784 22, ,938 42, ,442 22, ,651 42, ,101 23, ,363 43, ,762 23, ,075 43, ,426 24, ,790 44, ,092 24, ,504 44, ,760 25, ,220 45, ,430 25, ,936 45, ,104 26, ,654 46, ,777 26, ,381 47, ,452 27, ,090 47, ,129 27, ,810 48, ,807 28, ,612 49, ,488 28, ,417 50, ,170 29, ,226 52, ,853 29, ,040 53, ,539 30, ,856 55, ,227 30, ,676 56, ,915 31, ,496 57, ,605 31, ,320 59, ,295 32, ,149 60, ,988 33, ,981 62, ,682 33, ,814 63, ,377 34, ,650 65, ,073 34, ,488 66, ,771 35, ,328 67, ,470 35, ,171 69, ,168 36, ,014 70, ,869 36, ,859 72, ,571 37, ,705 73, ,275 37, ,556 75, ,980 38, ,407 76, ,686 38, ,260 77, ,393 39, ,115 79, ,099 39, ,972 80, ,807 40, ,830 82, ,516 41, ,690 83, Sorce: ables A 18 trog A 25 are adapted from Kennet Wark, ermodynamics, 4t ed. (New York: McGraw-Hill, 1983), pp Originally pblised in JANAF, ermocemical ables, NSRDS-NBS-37, 1971.
3 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 19 Ideal-gas properties of oxygen, O ,929 12, ,404 4, ,250 13, ,694 4, ,572 13, ,984 4, ,895 13, ,275 5, ,219 13, ,566 5, ,544 14, ,858 5, ,870 14, ,150 5, ,197 14, ,443 6, ,524 14, ,682 6, ,854 15, ,736 6, ,184 15, ,030 6, ,514 15, ,325 6, ,845 15, ,620 6, ,177 16, ,916 7, ,510 16, ,213 7, ,844 16, ,511 7, ,178 16, ,809 7, ,513 17, ,109 7, ,850 17, ,409 8, ,186 17, ,711 8, ,523 17, ,012 8, ,861 18, ,314 8, ,199 18, ,618 9, ,537 18, ,923 9, ,877 18, ,228 9, ,218 19, ,525 9, ,559 19, ,842 9, ,899 19, ,151 10, ,242 19, ,460 10, ,584 20, ,770 10, ,928 20, ,082 10, ,272 20, ,395 11, ,616 20, ,708 11, ,960 21, ,022 11, ,306 21, ,338 11, ,652 21, ,654 11, ,999 22, ,971 12, ,345 22, ,290 12, ,692 22, ,609 12, ,041 22,
4 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 941 ABLE A 19 Appendix Ideal-gas properties of oxygen, O 2 (Conclded ) ,389 23, ,880 44, ,088 23, ,624 44, ,789 24, ,371 45, ,490 24, ,118 45, ,194 25, ,866 46, ,899 25, ,616 47, ,606 26, ,365 47, ,314 26, ,116 48, ,023 27, ,868 48, ,734 27, ,620 49, ,447 28, ,374 50, ,162 29, ,127 50, ,877 29, ,881 51, ,594 30, ,772 52, ,312 30, ,668 54, ,033 31, ,573 55, ,753 31, ,484 57, ,475 32, ,397 58, ,198 32, ,316 60, ,923 33, ,243 61, ,648 34, ,174 63, ,374 34, ,112 64, ,102 35, ,057 66, ,831 35, ,004 67, ,561 36, ,956 69, ,292 36, ,916 70, ,024 37, ,881 72, ,756 37, ,852 73, ,490 38, ,826 75, ,224 39, ,808 77, ,961 39, ,793 78, ,696 40, ,785 80, ,434 40, ,780 81, ,172 41, ,778 83, ,912 41, ,784 85, ,652 42, ,795 86, ,394 43, ,809 88, ,136 43, ,827 89,
5 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 20 Ideal-gas properties of carbon dioxide, CO ,280 17, ,601 4, ,754 17, ,938 5, ,231 18, ,280 5, ,709 18, ,627 5, ,190 18, ,979 5, ,674 19, ,335 6, ,160 19, ,697 6, ,648 20, ,063 6, ,138 20, ,364 6, ,631 20, ,431 6, ,125 21, ,807 7, ,622 21, ,186 7, ,121 22, ,570 7, ,622 22, ,959 8, ,124 22, ,351 8, ,629 23, ,748 8, ,135 23, ,148 9, ,644 24, ,552 9, ,154 24, ,960 9, ,665 25, ,372 10, ,179 25, ,787 10, ,694 25, ,206 10, ,212 26, ,628 11, ,730 26, ,054 11, ,251 27, ,483 11, ,773 27, ,916 12, ,296 28, ,351 12, ,821 28, ,791 12, ,347 29, ,232 13, ,876 29, ,678 13, ,405 29, ,126 13, ,935 30, ,576 14, ,467 30, ,029 14, ,000 31, ,485 14, ,535 31, ,945 15, ,070 32, ,407 15, ,607 32, ,870 16, ,145 33, ,337 16, ,685 33, ,807 16, ,226 33,
6 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 943 ABLE A 20 Appendix Ideal-gas properties of carbon dioxide, CO 2 (Conclded) ,769 34, ,420 71, ,859 35, ,612 72, ,953 36, ,806 73, ,051 37, ,000 74, ,153 38, ,196 75, ,258 39, ,394 76, ,369 40, ,593 77, ,484 41, ,793 78, ,602 41, ,995 80, ,724 42, ,197 81, ,848 43, ,401 82, ,977 44, ,606 83, ,108 45, ,804 84, ,244 46, ,835 86, ,381 47, ,864 89, ,522 48, ,898 92, ,666 49, ,939 94, ,813 50, ,984 97, ,963 51, ,035 99, ,116 52, , , ,271 53, , , ,427 54, , , ,586 55, , , ,748 56, , , ,911 57, , , ,078 58, , , ,246 59, , , ,417 60, , , ,590 61, , , ,767 62, , , ,944 63, , , ,123 64, , , ,303 65, , , ,486 66, , , ,670 67, , , ,856 68, , , ,043 69, , , ,231 70, , ,
7 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 21 Ideal-gas properties of carbon monoxide, CO ,611 12, ,391 4, ,915 12, ,683 4, ,221 13, ,975 4, ,527 13, ,266 5, ,833 13, ,558 5, ,141 13, ,849 5, ,449 13, ,140 5, ,758 14, ,432 6, ,068 14, ,669 6, ,378 14, ,723 6, ,690 14, ,014 6, ,002 15, ,306 6, ,315 15, ,597 6, ,628 15, ,889 7, ,943 15, ,181 7, ,258 16, ,473 7, ,573 16, ,765 7, ,890 16, ,058 7, ,208 16, ,351 8, ,526 16, ,644 8, ,844 17, ,938 8, ,164 17, ,232 8, ,483 17, ,526 8, ,803 17, ,821 9, ,124 18, ,116 9, ,446 18, ,412 9, ,768 18, ,708 9, ,091 18, ,005 10, ,415 19, ,302 10, ,740 19, ,600 10, ,066 19, ,898 10, ,392 19, ,197 10, ,719 20, ,497 11, ,046 20, ,797 11, ,375 20, ,097 11, ,703 20, ,399 11, ,033 21, ,701 11, ,362 21, ,003 12, ,693 21, ,307 12, ,024 21,
8 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 945 ABLE A 21 Appendix Ideal-gas properties of carbon monoxide, CO (Conclded) ,355 22, ,756 42, ,020 22, ,473 42, ,688 23, ,191 43, ,357 23, ,910 43, ,029 24, ,629 44, ,702 24, ,351 44, ,377 25, ,072 45, ,054 25, ,794 45, ,733 26, ,516 46, ,406 26, ,238 47, ,095 27, ,961 47, ,780 27, ,684 48, ,466 28, ,408 48, ,154 28, ,224 50, ,844 29, ,044 51, ,534 29, ,864 52, ,226 30, ,688 54, ,919 30, ,516 55, ,613 31, ,345 57, ,309 31, ,178 58, ,007 32, ,015 60, ,707 32, ,852 61, ,408 33, ,692 62, ,110 33, ,537 64, ,813 34, ,383 65, ,517 35, ,230 67, ,222 35, ,077 68, ,928 36, ,930 70, ,635 36, ,784 71, ,344 37, ,639 72, ,053 37, ,495 74, ,763 38, ,352 75, ,472 38, ,210 77, ,184 39, ,073 78, ,895 39, ,939 80, ,609 40, ,802 81, ,323 41, ,667 83, ,039 41, ,534 84,
9 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 22 Ideal-gas properties of ydrogen, H ,808 30, ,370 5, ,091 31, ,657 5, ,384 32, ,945 5, ,683 33, ,233 5, ,990 34, ,468 5, ,303 35, ,522 6, ,622 36, ,100 6, ,947 37, ,680 6, ,279 38, ,262 7, ,618 39, ,843 7, ,962 40, ,426 8, ,311 41, ,010 8, ,668 42, ,594 8, ,031 43, ,179 9, ,400 44, ,764 9, ,119 46, ,350 10, ,847 47, ,935 10, ,584 48, ,107 11, ,328 50, ,280 12, ,080 51, ,453 13, ,839 52, ,630 13, ,608 54, ,807 14, ,383 55, ,988 15, ,168 56, ,171 16, ,960 58, ,359 17, ,755 59, ,551 18, ,558 60, ,747 19, ,368 62, ,948 19, ,186 63, ,154 20, ,008 65, ,364 21, ,838 66, ,580 22, ,671 67, ,802 23, ,512 69, ,028 24, ,358 70, ,262 25, ,211 72, ,502 26, ,065 73, ,749 27, ,926 75, ,002 28, ,793 76, ,263 28, ,667 78, ,530 29, ,545 79,
10 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 947 ABLE A 23 Appendix Ideal-gas properties of water vapor, H 2 O ,402 15, ,295 5, ,765 15, ,628 5, ,130 15, ,961 5, ,495 16, ,294 6, ,862 16, ,627 6, ,230 16, ,961 6, ,600 17, ,296 6, ,970 17, ,631 7, ,342 17, ,904 7, ,714 17, ,966 7, ,088 18, ,302 7, ,464 18, ,639 7, ,840 18, ,976 8, ,218 19, ,314 8, ,597 19, ,652 8, ,977 19, ,992 8, ,358 20, ,331 9, ,741 20, ,672 9, ,125 20, ,014 9, ,510 20, ,356 10, ,896 21, ,699 10, ,284 21, ,043 10, ,672 21, ,388 10, ,062 22, ,734 11, ,454 22, ,080 11, ,846 22, ,428 11, ,240 23, ,777 11, ,635 23, ,126 12, ,032 23, ,477 12, ,429 24, ,828 12, ,828 24, ,181 12, ,228 24, ,534 13, ,629 24, ,889 13, ,032 25, ,245 13, ,436 25, ,601 14, ,841 25, ,959 14, ,247 26, ,318 14, ,653 26, ,678 14, ,061 26, ,039 15, ,472 27,
11 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 23 Ideal-gas properties of water vapor, H 2 O (Conclded) ,882 27, ,535 55, ,709 28, ,523 56, ,542 28, ,513 57, ,380 29, ,507 58, ,223 30, ,506 59, ,071 30, ,506 60, ,923 31, ,511 60, ,780 32, ,517 61, ,642 32, ,527 62, ,509 33, ,540 63, ,380 34, ,555 64, ,256 35, ,573 65, ,137 35, ,593 65, ,022 36, ,156 68, ,912 37, ,735 70, ,807 38, ,330 72, ,707 38, ,940 74, ,612 39, ,562 76, ,521 40, ,199 79, ,434 40, ,846 81, ,351 41, ,508 83, ,273 42, ,183 85, ,198 43, ,868 88, ,128 43, ,565 90, ,062 44, ,273 92, ,999 45, ,991 94, ,942 46, ,717 97, ,888 47, ,453 99, ,838 47, , , ,792 48, , , ,748 49, , , ,709 50, , , ,675 51, , , ,643 51, , , ,614 52, , , ,589 53, , , ,567 54, , , ,550 55, , ,
12 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 949 ABLE A 24 Appendix Ideal-gas properties of monatomic oxygen, O ,894 30, ,852 4, ,936 31, ,892 4, ,979 32, ,197 7, ,021 32, ,713 13, ,064 33, ,150 19, ,108 34, ,234 20, ,152 34, ,317 22, ,196 35, ,400 23, ,241 35, ,482 24, ,286 36, ,564 25, ,332 37, ,605 26, ,378 37, ,646 27, ,425 38, ,687 27, ,520 39, ,728 28, ,619 41, ,769 29, ,720 42, ,811 29, ,824 43, ,852 30, ,932 44, ABLE A 25 Ideal-gas properties of ydroxyl, OH ,015 57, ,188 6, ,801 58, ,244 6, ,592 59, ,181 11, ,388 61, ,123 21, ,189 62, ,046 33, ,995 63, ,358 36, ,806 65, ,706 38, ,622 66, ,089 41, ,442 68, ,505 43, ,266 69, ,952 46, ,095 70, ,687 47, ,927 72, ,428 48, ,763 73, ,177 50, ,447 76, ,932 51, ,145 79, ,694 52, ,855 82, ,462 54, ,578 85, ,236 55, ,312 88,
13 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 26 Entalpy of formation, Gibbs fnction of formation, and absolte entropy at 25 C, 1 atm f g f Sbstance Formla kj/kmol kj/kmol kj/kmol K Carbon C(s) Hydrogen H 2 (g) Nitrogen N 2 (g) Oxygen O 2 (g) Carbon monoxide CO(g) 110, , Carbon dioxide CO 2 (g) 393, , Water vapor H 2 O(g) 241, , Water H 2 O( ) 285, , Hydrogen peroxide H 2 O 2 (g) 136, , Ammonia NH 3 (g) 46,190 16, Metane CH 4 (g) 74,850 50, Acetylene C 2 H 2 (g) +226, , Etylene C 2 H 4 (g) +52, , Etane C 2 H 6 (g) 84,680 32, Propylene C 3 H 6 (g) +20, , Propane C 3 H 8 (g) 103,850 23, n-btane C 4 H 10 (g) 126,150 15, n-octane C 8 H 18 (g) 208, , n-octane C 8 H 18 ( ) 249,950 +6, n-dodecane C 12 H 26 (g) 291, , Benzene C 6 H 6 (g) +82, , Metyl alcool CH 3 OH(g) 200, , Metyl alcool CH 3 OH( ) 238, , Etyl alcool C 2 H 5 OH(g) 235, , Etyl alcool C 2 H 5 OH( ) 277, , Oxygen O(g) +249, , Hydrogen H(g) +218, , Nitrogen N(g) +472, , Hydroxyl OH(g) +39, , Sorce: From JANAF, ermocemical ables (Midland, MI: Dow Cemical Co., 1971); Selected Vales of Cemical ermodynamic Properties, NBS ecnical Note 270-3, 1968; and API Researc Project 44 (Carnegie Press, 1953).
14 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page 951 ABLE A 27 Properties of some common fels and ydrocarbons Higer Lower Molar Entalpy of Specific eating eating mass, Density, 1 vaporization, 2 eat, 1 c p vale, 3 vale, 3 Fel (pase) Formla kg/kmol kg/l kj/kg kj/kg K kj/kg kj/kg Carbon (s) C ,800 32,800 Hydrogen (g) H , ,000 Carbon monoxide (g) CO ,100 10,100 Metane (g) CH ,530 50,050 Metanol ( ) CH 4 O ,660 19,920 Acetylene (g) C 2 H ,970 48,280 Etane (g) C 2 H ,900 47,520 Etanol ( ) C 2 H 6 O ,670 26,810 Propane ( ) C 3 H ,330 46,340 Btane ( ) C 4 H ,150 45,370 1-Pentene ( ) C 5 H ,760 44,630 Isopentane ( ) C 5 H ,570 44,910 Benzene ( ) C 6 H ,800 40,100 Hexene ( ) C 6 H ,500 44,400 Hexane ( ) C 6 H ,310 44,740 olene ( ) C 7 H ,400 40,500 Heptane ( ) C 7 H ,100 44,600 Octane ( ) C 8 H ,890 44,430 Decane ( ) C 10 H ,640 44,240 Gasoline ( ) C n H 1.87n ,300 44,000 Ligt diesel ( ) C n H 1.8n ,100 43,200 Heavy diesel ( ) C n H 1.7n ,500 42,800 Natral gas (g) C n H 3.8n N 0.1n ,000 45,000 1 At 1 atm and 20 C. 2 At 25 C for liqid fels, and 1 atm and normal boiling temperatre for gaseos fels. 3 At 25 C. Mltiply by molar mass to obtain eating vales in kj/kmol. Appendix 1 951
15 cen84959c18-ap01.qxd 8/11/06 1:21 PM Page ermodynamics ABLE A 28 Natral logaritms of te eqilibrim constant K p n P C n C P D D e eqilibrim constant K p for te reaction n A A + n B B Δ n C C + n D D is defined as K p n P A n A P B B emp., K H 2 Δ 2H O 2 Δ 2O N 2 Δ 2N H 2 O Δ H / 2 O 2 H 2 O Δ 1 / 2 H 2 + OH CO 2 Δ CO + 1 / 2 O 2 1 / 2 N / 2 O 2 Δ NO Sorce: Gordon J. Van Wylen and Ricard E. Sonntag, Fndamentals of Classical ermodynamics, Englis/SI Version, 3rd ed. (New York: Jon Wiley & Sons, 1986), p. 723, table A.14. Based on termodynamic data given in JANAF, ermocemical ables (Midland, MI: ermal Researc Laboratory, e Dow Cemical Company, 1971).
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