Applications and Index

Transcript

1 and Index HPLC...0 Pharmaceutical... Food / Environmental...4 Life Science...49 Others...50 GC...5 Environmental...54 Petrochemicals...68 Chemicals...8 Solvents...92 Food Pharmaceutical SPE...2 Food...24 Environmental Pharmaceutical...2 Others...22 Compound Index...2 Product Index...240

2 HPLC Index Industry Index Pharmaceutical... Food / Environmental...4 Life Science...49 Others...50 Product Index Bio-Bond Proteins...49 Endeavorsil Acidic Compounds...4 Antialcers... Antibacterials...2 Antifungals...4 Anti-inflammatories... β-blockers at Low ph...4 β-blockers at Neutral ph...4 Catecholamine...5 Parabens...45 Polar Acids...47 Steroids...50 TCAs at Low ph...40 Leapsil Antibacterials...2 Antifungals...4 Anti-inflammatories... β-blockers at Low ph...4 β-blockers at Neutral ph...4 Parabens...46 Polar Acids...47 Polar Bases...9 Water-Soluble Vitamins...40 Spursil Acidic Compounds... Benzoic Acid and Sorbic Acid in Milk...42 Benzoyl Peroxide in Wheat Flour...42 Catecholamine...5 Catechols and Resorcinols...4 Cephalosporin Antibiotics...6, 7 Flavonoids...8 Herbicides...44 Organic Acids...45 Phenols...46, 50 Sweeteners...47, 48 TCAs and Benzos...9 Inspire Alkaloids... Antialcers...2 Antibacterials...2 Antifungals...4 Antihistamines... Anti-inflammatories... Antioxidants...49 Benzoylurea and Bishydrazide Mixture...42 Caffeine Metabolites...42 Catecholamine...5 Cephalosporin Antibiotics...5, 6 Colorants...4 Derivatized Carbonyl Compounds...4 Flavonoids...8 Herbicides...4 Melamine...44 Organic Acids...44 Parabens...45 Penicillins...8 Polar Acids...46 Quinolones...9 Steroids...50 Sweeteners...47 TCAs and Benzos...9 TCAs at Low ph...40 Unsaturated Fatty Acids

3 Pharmaceutical Acidic Compounds Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. L-Ascorbic acid 2. Acetaminophen. p-aminobenzoic acid 4. Homovanillic acid 5. Acetylsalicylic acid 6. Sorbic acid 7. Benzoic acid 2 4 Acidic Compounds Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. L-Ascorbic acid 2. Acetaminophen. p-aminobenzoic acid 4. Homovanillic acid 5. Acetylsalicylic acid 6. Sorbic acid 7. Benzoic acid Min Min AN: S67 AN: S68 Alkaloids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:20 mm KH 2 PO 4 (ph 2.) = 42:58 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Theobromine 2. Quinine. Hydrastine 4. Berberine Antialcers Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeOH:0 mm CH COONH 4 (ph 7) = 5:65 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 220 nm Sample:. Famotidine 2. Ranitidine. Cimetidine 4. Nizatidine Min. AN: I Min. AN: E0

4 Pharmaceutical Antialcers Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:0 mm CH COONH 4 (ph 7) = 5:65 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 220 nm Sample:. Famotidine 2. Ranitidine. Cimetidine 4. Nizatidine Antibacterials Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Sulfanilamide 6. Sulfamethoxypyridazine 2. Carbadox 7. Furazolidone. Sulfapyridine 8. Sulfamethoxazole 4. Sulfamerazine 9. Sulfisoxazole 5. Thiamphenicol 0. Oxolinic acid Min Min. AN: I02 AN: I0 Antibacterials Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate: 0. ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Sulfanilamide 2. Carbadox. Sulfamerazine 4. Sulfamethazine 5. Sulfamethoxypyridazine 6. Furazolidone 7. Sulfamethoxazole 8. Sulfisoxazole 9. Oxolinic acid 0. Sulfadimethoxine Antibacterials Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate: 0.5 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Sulfanilamide 2. Carbadox. Sulfamerazine 4. Sulfamethoxypyridazine 5. Furazolidone 6. Sulfamethoxazole 7. Sulfisoxazole 8. Oxolinic acid 9. Sulfadimethoxine 0. Sulfaquinoxaline Min Min. AN: I0 AN: E02 2

5 Pharmaceutical Antihistamines Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:5 mm NH 4 HCO (ph 0) = 75:25 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Maleic acid 2. Pheniramine. Doxylamine 4. Chlorpheniramine 5. Brompheniramine 6. Diphenhydramine Anti-inflammatories Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 55:45 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Phenacetin 2. Tolmetin. Ketoprofen 4. Fenoprofen 5. Flurbiprofen 6. Diclofenac 7. Ibuprofen Min Min. AN: I04 AN: I05 Anti-inflammatories Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 50:50 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. Phenacetin 2. Tolmetin. Ketoprofen 4. Fenoprofen 5. Flurbiprofen 6. Ibuprofen Anti-inflammatories Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 50:50 Flow Rate: 0. ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Phenacetin 2. Tolmetin. Ketoprofen 4. Fenoprofen 5. Flurbiprofen 6. Ibuprofen Min Min. AN: E0 AN: L02

6 Pharmaceutical β-blockers at Low ph Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 25:75 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 220 nm Sample:. Nadolol 2. Pindolol. Acebutolol 4. Metoprolol 5. Labetolol 6. Propranolol 7. Alprenolol β-blockers at Low ph Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 25:75 Flow Rate: 0. ml/min Temperature: 0 ºC Detection: UV 220 nm Sample:. Nadolol 2. Pindolol. Acebutolol 4. Metoprolol 5. Labetolol 6. Propranolol Min Min. AN: E04 AN: L0 β-blockers at Neutral ph Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeCN:20 mm phosphate buffer (ph 7) = 0:70 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 220 nm Sample:. Nadolol 2. Pindolol. Metoprolol 4. Labetolol 5. Propranolol β-blockers at Neutral ph Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeCN:20 mm phosphate buffer (ph 7) = 25:75 Flow Rate: 0. ml/min Temperature: Ambient Detection: UV 220 nm Sample:. Nadolol 2. Pindolol. Metoprolol 4. Labetolol 5. Propranolol Min. 0 2 Min. AN: E05 AN: L04 4

7 Pharmaceutical Catecholamine Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 20 mm KH 2 PO 4, ph 7 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 270 nm Sample:. Norepinephrine 2. Epinephrine. Dopamine Catecholamine Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% TFA in H 2 O Flow Rate: 0.5 ml/min Temperature: Ambient Detection: UV 270 nm Sample:. Norepinephrine 2. Epinephrine. Dopamine Min. 0 2 Min. AN: I06 AN: E06 Catecholamine Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: 20 mm KH 2 PO 4, ph 7 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 270 nm Sample:. Norepinephrine 2. Epinephrine. Dopamine Cephalosporin Antibiotics Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:0.% TFA in H 2 O = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Ceftazidime 2. Cefadroxil. Cefazoline 4. Cefaclor 5. Cephalexin 6. Cefoxitin 7. Cefradine Min. AN: S Min. AN: I2 5

8 2 4 5 Pharmaceutical Cephalosporin Antibiotics Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:00 mm acetate buffer = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Cefadroxil 2. Cefuroxime. Cefaclor 4. Cefoxitin 5. Cefradine Cephalosporin Antibiotics Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:25 mm phosphate buffer (ph ) = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Cefadroxil 2. Ceftazidime. Cefaclor 4. Cephalexin 5. Cefazoline 6. Cefoxitin 7. Cefradine Min. AN: I Min. AN: I08 Cephalosporin Antibiotics Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeOH:0.% TFA in H 2 O = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Ceftazidime 2. Cefadroxil. Cefuroxime 4. Cefazoline 5. Cefaclor 6. Cephalexin 7. Cefradine Cephalosporin Antibiotics Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeOH:00 mm acetate buffer = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Ceftazidime 2. Cefadroxil. Cefuroxime 4. Cefoxitin 5. Cefaclor 6. Cefradine Min. AN: I Min. AN: E02 6

9 Pharmaceutical Cephalosporin Antibiotics Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeOH:25 mm phosphate buffer (ph ) = 25:75 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Cefadroxil 2. Ceftazidime. Cefaclor 4. Cephalexin 5. Cefazoline 6. Cefradine Cephalosporin Antibiotics Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeOH:0.% TFA in H 2 O = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Ceftazidime 2. Cefadroxil. Cephalexin 4. Cefradine 5. Cefazoline 6. Cefoxitin Min. AN: D Min. AN: D5 Cephalosporin Antibiotics Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeOH:00 mm acetate buffer = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Ceftazidime 2. Cephalexin. Cefaclor 4. Cefradine 5. Cefoxitin Cephalosporin Antibiotics Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeOH:25 mm phosphate buffer (ph ) = 25:75 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Cefadroxil 2. Ceftazidime. Cefaclor 4. Cephalexin 5. Cefradine 6. Cefazoline Min. AN: I Min. AN: E0 7

10 Pharmaceutical Flavonoids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeCN:0.085% H PO 4 = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 280 nm Sample:. Gallic acid 2. Catechin. Caffeic acid 4. Vanillic acid 5. p-coumaric acid 6. Quercitrin 7. Myricetin 2 Flavonoids Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeCN:0.085% H PO 4 = 20:80 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 280 nm Sample:. Gallic acid 2. Catechin. Caffeic acid 4. Vanillic acid 5. p-coumaric acid 6. Quercitrin 7. Myricetin Min. AN: I Min. AN: S54 Flavonoids Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeCN:0.085% H PO 4 = 25:75 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 280 nm Sample:. Gallic acid 2. Catechin. Vanillic acid 4. Caffeic acid 5. p-coumaric acid 2 Penicillins Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:25 mm KH 2 PO 4 = 55:45 Flow Rate: 0.5 ml/min Temperature: Ambient Detection: UV 220 nm Sample:. Amoxicillin 2. Ampicillin. Piperacilin 4. Penicillin G 5. Oxacillin 6. Cloxacillin 7. Dicloxacillin Min. AN: S Min. AN: I25 8

11 Pharmaceutical Polar Bases Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 40:60 Flow Rate: 0. ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Doxepin 2. Protriptyline. Nortriptyline 4. Amitriptyline 5. Trimipramine 6. Clomipramine Quinolones Column: Inspire 5 µm C8, 250 x 4.6 mm Cat. No.: 8006 Mobile Phase A: MeOH t / min Mobile Phase B: 0.2% H PO 4 in H 2 O A / % Flow Rate:.0 ml/min B / % Temperature: 5 ºC Detection: UV 254 nm Sample:. Marbofloxacin 8. Sarafloxacin 2. Ofloxacin 9. Gatifloxacin. Norfloxacin 0. Sparfloxacin 4. Enrofloxacin. Oxolinic acid 5. Ciprofloxacin 2. Nalidixic acid 6. Pazufloxacin. Flumequine 7. Difloxacin Min Min. AN: L05 AN: I24 TCAs and Benzos Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 40:60 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Nitrozepam 2. Nordoxepin. Alprazolam 4. Diazepam 5. Oxazepam 6. Triazolam 7. Nortriptyline 8. Clonazepam 9. Trimipramine TCAs and Benzos Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 40:60 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Nitrozepam 2. Estazolam. Alprazolam 4. Diazepam 5. Triazolam 6. Clonazepam 7. Nortriptyline 8. Amitriptyline 9. Trimipramine Min. AN: I Min. AN: S55 9

12 Pharmaceutical TCAs at Low ph Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 5:65 Flow Rate: 0.5 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Doxepin 2. Desipramine. Nortriptyline 4. Amitriptyline 5. Trimipramine 6. Clomipramine TCAs at Low ph Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 40:60 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Nordoxepin 2. Doxepin. Desipramine 4. Nortriptyline 5. Amitriptyline 6. Trimipramine 7. Clomipramine Min. AN: E Min. AN: I26 Water-Soluble Vitamins Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0 mm HCOONH 4, ph Flow Rate: 0. ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Pyridoxamine 2. L-Ascorbic acid. Pyridoxal 4. Nicotinamide 5. Pyridoxol Min. AN: L

13 Food / Environmental Acidic Compounds Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 25:75 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. L-Ascorbic acid 2. p-aminobenzoic acid. Homovanillic acid 4. Acetylsalicylic acid 5. Sorbic acid 6. Salicylic acid Antifungals Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Acetylsalicylic acid. Benzoic acid 4. Salicylic acid Min Min. AN: E08 AN: I4 Antifungals Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 0:70 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Acetylsalicylic acid. Benzoic acid 4. Salicylic acid Antifungals Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 0:70 Flow Rate: 0. ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Acetylsalicylic acid. Benzoic acid 4. Salicylic acid Min. 0 2 Min. AN: E09 AN: L0 4

14 Food / Environmental Benzoic Acid and Sorbic Acid in milk Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: Mobile Phase: MeOH:phosphate buffer = 0:90 Flow Rate:.2 ml/min Injection Volume: 0 µl Temperature: 40 ºC Detection: UV 227 nm Sample:. Benzoic acid 2. Sorbic acid Benzoyl Peroxide in Wheat Flour Column: Spursil 5 µm C8, 250 x 4.6 mm Cat. No.: Mobile Phase: MeOH:20 mm acetate buffer = 0:90 Flow Rate:.0 ml/min Injection Volume: 0 µl Temperature: 0 ºC Detection: UV 20 nm Sample:. Benzoyl peroxide Min Min AN: S56 AN: S57 Benzoylurea and Bishydrazide Mixture Column: Inspire 5 µm C8, 250 x 4.6 mm Cat. No.: 8006 Mobile Phase A: MeOH t / min Mobile Phase B: H 2 O A / % Flow Rate:.0 ml/min B / % Temperature: 0 ºC Detection: UV 248 nm Sample:. Methoxyfenozide 2. Tebufenozide. Diflubenzuron 4. Chlorbenzuron 5. Triflumuron 6. Hexaflumuron 7. Teflubenzuron 8. Flufenoxuron 9. Chlorfluazuron Caffeine Metabolites Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:% CH COOH in H 2 O = 0:90 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Uric acid 2. Xanthine. 7-Methylxanthine 4. -Methyluric acid 5. -Methylxanthine 6.,-Dimethyluric acid 7. Theobromine 8.,7-Dimethylxanthine 9. Theophylline Min. AN: I Min. AN: I2 42

15 Food / Environmental Catechols and Resorcinols Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeCN:0.% HCOOH in H 2 O = 25:75 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 270 nm Sample:. Resorcinol 2. Catechol. 2-Methylresorcinol 4. 4-Methylcatechol 5. 2,5-Dimethylresorcinol 6. -Methylcatechol 7. 4-Nitrocatechol Colorants Column: Inspire 5 µm C8, 250 x 4.6 mm Cat. No.: 8006 t / min Mobile Phase A: MeCN A / % Mobile Phase B: 0.05 M CH COONH 4 B / % Flow Rate:.0 ml/min Temperature: 5 ºC Detection: UV 254 nm Sample:. Tartrazine 0. Lissamine green B 2. Amaranth. Brilliant blue. Indigotin 2. Acid orange I 4. Carmine. Erythrosine 5. Brilliant black 4. Acid orange II 6. Sunset yellow 5. Patent blue V 7. Fancy red 6. Auramine 8. Acid red 2G 7. Acid yellow 6 9. Azorubine 8. Basic orange Min. AN: S Min. AN: I7 Derivatized Carbonyl Compounds Column: Inspire 5 µm C8, 250 x 4.6 mm Cat. No.: 8006 Mobile Phase A: MeOH t / min Mobile Phase B: H 2 O A / % Flow Rate:.0 ml/min B / % Temperature: 5 ºC Detection: UV 60 nm Injection Volume: 20 µl Sample:. Formaldehyde-DNPH 9. Isovaleraldehyde-DNPH 2. Acetaldehyde-DNPH 0. Valeraldehyde-DNPH. Acrolein-DNPH. o-tolualdehyde-dnph 4. Acetone-DNPH 2. m-tolualdehyde-dnph 5. Propionaldehyde-DNPH. p-tolualdehyde-dnph 6. Crotonaldehyde-DNPH 4. 2,5-Dimethylbenzaldehyde-DNPH 7. Butyraldehyde-DNPH 5. Hexaldehyde-DNPH 8. Benzaldehyde-DNPH Herbicides Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 40:60 Flow Rate: 2.0 ml/min Temperature: Ambient Detection: UV 24 nm Sample:. Dalapon 2. 2,4-D. 2,4,5-T Min. AN: I Min. AN: I9 4

16 Food / Environmental Herbicides Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeCN:H 2 O = 60:40 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 24 nm Sample:. Fenuron 2. Monuron. Diuron 4. Linuron Herbicides Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeCN:H 2 O = 60:40 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 24 nm Sample:. Fenuron 2. Monuron. Diuron 4. Linuron Min Min. AN: S59 AN: S60 Melamine Column: Inspire 5 µm C8, 250 x 4.6 mm Cat. No.: 8006 Mobile Phase: MeCN:Buffer = 8:92 Flow Rate:.0 ml/min Temperature: 0 ºC Detection: UV 24 nm Sample:. Melamine Organic Acids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 25 mm KH 2 PO 4, ph 2.5 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Oxalic acid 2. Tartaric acid. Malic acid 4. Lactic acid 5. Acetic acid 6. Citric acid 7. Fumaric acid 8. Succinic acid Min. AN: I Min. AN: I2 44

17 Food / Environmental Organic Acids Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: 25 mm KH 2 PO 4, ph 2.5 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Oxalic acid 2. Tartaric acid. Malic acid 4. Lactic acid 5. Acetic acid 6. Citric acid 7. Fumaric acid 8. Succinic acid Organic Acids Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: 25 mm KH 2 PO 4, ph 2.5 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Oxalic acid 2. Tartaric acid. Malic acid 4. Lactic acid 5. Acetic acid 6. Citric acid 7. Succinic acid 8. Fumaric acid Min. AN: S Min. AN: S62 Parabens Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeCN:20 mm K 2 HPO 4 (ph 7) = 50:50 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Methyl paraben 2. Ethyl paraben. Propyl paraben 4. Butyl paraben Parabens Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeCN:20 mm K 2 HPO 4 (ph 7) = 50:50 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. Methyl paraben 2. Ethyl paraben. Propyl paraben 4. Butyl paraben Min Min. AN: I AN: E0 45

18 Food / Environmental Parabens Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeCN:20 mm K 2 HPO 4 (ph 7) = 55:45 Flow Rate: 0. ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. Methyl paraben 2. Ethyl paraben. Propyl paraben 4. Butyl paraben 2 4 Phenols Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 55:45 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 280 nm Sample:. Phenol 2. 2-Nitrophenol. 4-Nitrophenol 4. 2-Chlorophenol 5. 4-Chlorophenol 6. 4-Chloro--methylphenol 7. 2,4-Dichlorophenol 8. 2,4,6-Trichlorophenol Min Min. AN: L08 AN: S6 Phenols Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 55:45 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 280 nm Sample:. Phenol 2. 4-Nitrophenol. 2-Chlorophenol 4. 4-Chlorophenol 5. 2-Nitrophenol 6. 4-Chloro--methylphenol 7. 2,4-Dichlorophenol 8. 2,4,6-Trichlorophenol Polar Acids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 0:70 Flow Rate: 0. ml/min Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Homovanillic acid. Sorbic acid 4. p-nitrobenzoic acid 5. p-toluic acid Min. AN: I Min. AN: I

19 Food / Environmental Polar Acids Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 20:80 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Homovanillic acid. Sorbic acid 4. Salicylic acid 5. p-chlorobenzoic acid 6. p-nitrobenzoic acid Polar Acids Column: Leapsil 2.7 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: 0.% HCOOH in MeCN:0.% HCOOH in H 2 O = 25:75 Flow Rate: 0. ml/min Detection: UV 254 nm Sample:. p-aminobenzoic acid 2. Homovanillic acid. Sorbic acid 4. Salicylic acid 5. p-nitrobenzoic acid 6. p-toluic acid Min. AN: E Min. AN: L09 Sweeteners Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:20 mm CH COONH 4 (ph 5) = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Acesulfame K 2. Sodium saccharin. Aspartame Sweeteners Column: Spursil 5 µm C8, 50 x 4.6 mm Cat. No.: 8200 Mobile Phase: MeOH:20 mm CH COONH 4 (ph 5) = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Acesulfame K 2. Sodium saccharin. Aspartame Min. AN: I Min. AN: S

20 Food / Environmental Sweeteners Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeOH:20 mm CH COONH 4 (ph 5) = 0:70 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 20 nm Sample:. Acesulfame K 2. Sodium saccharin. Aspartame Unsaturated Fatty Acids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: 0.% TFA in MeCN:0.% TFA in H 2 O = 95:5 Flow Rate:.5 ml/min Temperature: Ambient Detection: UV 24 nm Sample:. Linolenic acid 2. Linoleic acid. Oleic acid Min. AN: S Min. AN: I2 48

21 Life Science Antioxidants Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase A: 5% CH COOH in H 2 O Mobile Phase B: MeCN:MeOH = 50:50 t / min. A / % Flow Rate:.0 ml/min B / % Temperature: Ambient Detection: UV 280 nm Sample:. Propyl gallate 6. Ionox TBHQ 7. Octyl gallate. THBP 8. BHT 4. NDGA 9. Lauryl gallate 5. BHA Proteins Column: Bio-Bond 5 µm C8, 50 x 4.6 mm Cat. No.: 8400 Mobile Phase A: 0.% TFA in H 2 O Mobile Phase B: 0.% TFA in MeCN t / min. A / % Flow Rate:.0 ml/min B / % 0 50 Detection: UV 280 nm Sample:. Cytochrome C 2. Insulin. Lysozymes Min Min. AN: I22 AN: B0 Proteins Column: Bio-Bond 5 µm C8-EP, 50 x 4.6 mm Mobile Phase A: 0.% TFA in H 2 O t / min. 0 5 Mobile Phase B: 0.% TFA in MeCN A / % Flow Rate:.0 ml/min B / % 0 50 Detection: UV 280 nm Sample:. Cytochrome C 2. Insulin. Lysozymes Min. AN: B

22 Others Phenols Column: Spursil 5 µm C8-EP, 50 x 4.6 mm Cat. No.: 820 Mobile Phase: MeCN:0.% HCOOH in H 2 O = 25:75 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 270 nm Sample:. Phenol 6. 2,4-Dimethylphenol 2. 4-Nitrophenol 7. 4-Chloro--methylphenol. 2-Chlorophenol 8. 2,4-Dichlorophenol 4. 2,4-Dinitrophenol 9. 2,4,6-Trichlorophenol 5. 2-Nitrophenol 0. Pentachlorophenol Steroids Column: Endeavorsil.8 µm C8, 50 x 2. mm Cat. No.: Mobile Phase: MeOH:H 2 O = 50:50 Flow Rate: 0.5 ml/min Temperature: 0 ºC Detection: UV 254 nm Sample:. Prednisone 2. Prednisolone. Dexamethasone 4. Hydrocortisone 2-acetate 5. -α-hydroprogesterone Min. 0 2 Min. AN: S66 AN: E2 Steroids Column: Inspire 5 µm C8, 50 x 4.6 mm Cat. No.: 800 Mobile Phase: MeOH:H 2 O = 55:45 Flow Rate:.0 ml/min Temperature: Ambient Detection: UV 254 nm Sample:. Prednisone 4. Dexamethasone 2. Cortisone 5. Hydrocortisone 2-acetate. Prednisolone 6. -α-hydroxyprogesterone Min. AN: I2 50

23 GC Index Industry Index Environmental Petrochemicals Chemicals... 8 Solvents Food Pharmaceutical Product Index DM- / DM-MS Air Sample: TO Citronella Java Oil Fatty Acids (Free) Flavor Volatiles Fragrance Gasoline Aromatics Hydrocarbons, C7 - C Oxygenates MTBE Petroleum Oxygenates Solvents Mixture #... 9 Solvents Mixture # Solvents Mixture # Sulfide Sulfur in Gasoline Sulfur in Naphtha USP Solvents DM-5 / DM-5MS Alcohols Basic Drugs Benzidines / Phenols (EPA 604 / 605)... 6 Butyl Tins Chlorinated Hydrocarbons (EPA 62) Food Packaging Volatiles Glycols / Alcohols Nitrogen-Containing Herbicides... 6 Organochlorine Pesticides Organochlorine Pesticides (EPA 808) PAHs (EPA 60) PAEs Solvents Steroids, Anabolic DM-5 Amine Amines / Phenols Antihistamines Ethylenediamines Sympathomimetic Amines Drugs DM-5MS / LB PAHs (EPA 60) Phenols (EPA 528) Semi-volatile Organic Compounds Volatile Organic Compounds (EPA 526) DM-7 BHA / BHT Chlorophenoxyacid Herbicides (EPA 55.) Organochlorine Pesticides (EPA 808) PAEs (EPA 8060) Phenols (EPA 604)... 6 Triazine Herbicides (EPA 69) DM-70 Acrylic Esters... 9 Formaldehyde

24 GC Index Fragrance Organochlorine Pesticides (EPA 808) Styrene Impurities... 9 DM-5 Acidic / Neutral Drugs Basic Drugs Chlorinated Hydrocarbons (EPA 62) Chlorophenoxyacid Herbicides (EPA 65) Endocrine Disruptors Butyl Tins (Hexyl Derivatives) Nitrogen-Containing Herbicides... 6 Organochlorine Pesticides (EPA 808) Organophosphorus Pesticides (EPA 840 / 84 / 84A) DM-5 Amine Cold Medicine Ethanolamines Primary Amines... 8 Sympathomimetic Amines Drugs DM-200 Aromatics (Benzene / Toluene / Xylene)... 8 Basic Drugs Chlorinated Hydrocarbons (EPA 62) Explosives Glycols Nitroamines... 6 PAHs (EPA 60) Silanes... 9 Solvents Mixture # Solvents Mixture # Solvents Mixture # USP Solvents Volatile Organic Compounds in Water (EPA 55.) DM-225 Neutral Sterols Sugars (Alditol Acetates) DM-624 / DM-624MS EP Class and Class 2 Solvents... 2 Organic Volatile Impurities... 2 Organic Volatile Impurities (USP 467)... 2 Primary, Second and Tertiary Amines Residual Solvents Volatile Organic Compounds (EPA 524.2) DM-20 Dioxins PUFA (Animal Source) Sugars (Alditol Acetates) DM-2887 Simulated Distillation DM-2560 FAMEs (cis / trans Isomers) DM-Wax Alcohols Alcohols / Aldehydes Aldehydes Amines / Alcohols / Chlorides Aromatics... 8, 82 Concentrated Liquors Esters Flavor Volatiles Glycols Ketones Peppermint Oil Petroleum Oxygenates PUFA (Animal Source)

25 GC Index Solvents Mixture # Solvents Mixture # Solvents Mixture # Styrene Impurities... 9 DM-Wax Amine Amines (Low MW)... 8 Hexamethylenediamine Nitrosamines Primary Amines (Low MW)... 8 DM-InertWax Aldehydes FAMEs DM-HT SimDist Metal Bleed Profile Hydrocarbons, C0 - C Hydrocarbons, C0 - C Hydrocarbons, C44 - C DM-FFAP Alcoholic Standard: Acids and Esters Fatty Acids (Free) DM-FAMEWAX FAMEs (Black Currant Seed Oil) FAMEs (Flax Seed Oil) FAMEs (Marine Oil Standard) DM-PLOT Alumina,-Butadiene Purity Hydrocarbons... 7 Propylene Purity... 7 Refinery Gas DM-PLOT Alumina / Na 2 SO 4 Refinery Gas DM-PLOT Alumina / KCl Butane Lighter Fluid DM-PLOT CFC Impurity Analysis of,,,2-tetrafluoroethane DM-PLOT MS 5A Permanent Gases... 68, 69 DM-PLOT Q Alcohols Hydrocarbon Gases... 7, 72, 7 Permanent Gases... 68, 69 Polar Solvents DM-PLOT QS Natural Gas # DM-PLOT S / DM-PLOT U Hydrocarbon Gases Permanent Gases Polar Solvents DM-PONA Detailed Hydrocarbons Analysis DM-TCEP Aromatics... 8 Petroleum Oxygenates DM-Volatile Amine Short Chain Amaines in Water... 8 DM-PAH PAHs DM-AQUA Volatile Organic Compounds in Water DM-BDTG Metal Glycerin in Biodiesel (ASTM D6584) DM-TVOC TVOCs

26 Volatiles TVOCs Column: DM-TVOC, 50 m x 0.2 mm x.00 µm Cat. No.: 78 Index: CEO0000 Carrier Gas: N 2 Oven Temp.: 50 ºC (hold 0 min) to 250 ºC at 5 ºC/min Injection: Split, 0:, 250 ºC µl Detector: FID, 250 ºC. Methanol 2. Benzene. Toluene 4. Butyl acetate 5. Ethylbenzene 6. p-xylene 7. m-xylene 8. Vinyl benzene 9. o-xylene 0. Undecane. Impurity 2. Impurity Air Sample: TO-4 Column: DM-, 60 m x 0.2 mm x.00 µm Cat. No.: 742 Index: CER0008 Oven Temp.: 0 ºC (hold 4 min) to 250 ºC (hold 5 min) at 7 ºC/min Carrier Gas: He, 2 cm/sec, 0 ºC Detector: MS, 250 ºC Ionization: EI Scan Range: AMU Cryotrap Temp.: -60 ºC Cryotrap Desorb Temp.: 50 ºC. Dichlorodifluoromethane 2. Chloromethane.,2- Dichlorotetrafluoroethane 4. Vinyl chloride 5. Bromomethane 6. Chloroethane 7. Trichlorofluoromethane 8.,-Dichloroethene 9. Methylene chloride 0. -Chloropropene.,,2-Trichloro-,2,2- trifluoroethane 2.,-Dichloroethane. cis-,2-dichloroethene 4. Chloroform 5.,2-Dichloroethane 6.,,-Trichloroethane 7. Benzene 8. Carbon tetrachloride 9.,2-Dichloropropane 20. Trichloroethylene 2. cis-,-dichloropropene 22. trans-,-dichloropropene 2.,,2-Trichloroethane 24. Toluene 25.,2-Dibromoethane 26. Tetrachloroethene 27. Chlorobenzene 28. Ethylbenzene 29. m-xylene 0. p-xylene. Styrene 2. o-xylene.,,2,2-tetrachloroethane 4. 4-Methyltoluene 5.,,5-Trimethylbenzene 6.,2,4-Trimethylbenzene 7.,-Dichlorobenzene 8.,4-Dichlorobenzene 9.,2-Dichlorobenzene 40.,2,4-Trichlorobenzene 4. Hexachlorobutadiene 54

27 Volatiles Volatile Organic Compounds (EPA 524.2) Column: DM-624, 75 m x 0.5 mm x.00 µm Cat. No.: 7752 Index: CER000 Oven Temp.: 5 ºC (hold 8 min) to 220 ºC (hold min) at 0 ºC/min Detector: MS, 250 ºC Scan Range: AMU Purging Time: min Sorbent Tube: Tenax / Silica gel / Active carbon Desorb Temp.: 220 ºC (hold 2 min), at 225 ºC Desorb Speed.: 0 ml/min. Dichlorodifluoromethane 2. Chloromethane. Vinyl chloride 4. Bromomethane 5. Chloroethane 6. Trichlorofluoromethane 7.,-Dichloroethene 8. Methylene chloride 9. trans-,2-dichloroethylene 0.,-Dichloropropane. cis-,2-dichloroethylene 2. 2,2-Dichloropropane. Chlorobromomethane 4. Chloroform 5.,,-Trichloroethane 6. Tetrachloromethane 7.,-Dichloropropene 8. Benzene 9.,2-Dichloroethane 20. Trichloroethylene 2.,2-Dichloropropane 22. Dibromomethane 2. Bromodichloromethane 24. cis-,-dichloropropene 25. Toluene 26. trans-,-dichloropropene 27.,,2-Trichloroethane 28. Tetrachloroethylene 29.,-Dichloropropane 0. Dibromochloromethane.,2-Dibromoethane 2. Chlorobenzene.,,,2-Tetrachloroethane 4. Ethylbenzene 5. m-xylene 6. p-xylene 7. o-xylene 8. Styrol 9. Bromoform 40. Anisoxide 4. Bromobenzene 42.,,2,2-Tetrachloroethane 4.,2,-Trichloropropane 44. Propylbenzene Chlorotoluene 46.,,5-Trimethylbenzene Chlorotoluene 48. tert-butylbenzene 49.,2,4-Trimethylbenzene 50. sec-butylbenzene 5.,-Dichlorobenzene 52. p-isoproplyl toluene 5.,4-Dichlorobenzene 54. n-butylbenzene 55.,2-Dichlorobenzene 56.,2-Dibromo--chloropropane 57.,2,4-Trichlorobenzene 58. Hexachlorobutadiene 59. Naphthalene 60.,2,-Trichlorobenzene Dioxins Column: DM-20, 60 m x 0.25 mm x µm Cat. No.: 8624 Index: CER0008 Oven Temp.: 200 ºC (hold min) to 250 ºC (hold 5 min) at 8 ºC/min, to 275 ºC (hold 5 min) at 5 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Splitless, 275 ºC Sample: TCDD isomers, 2.0 µl Detector: ECD, 2 khz full scale, 275 ºC Dioxins Column: DM-20, 60 m x 0.2 mm x µm Cat. No.: 864 Index: CER0009 Oven Temp.: 200 ºC (hold min) to 240 ºC (hold 6 min) at ºC/min, to 275 ºC (hold 0 min) at 5 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Cold on-column, 275 ºC Sample: TCDD isomers,.5 µl Detector: ECD, 5 khz full scale, 275 ºC.,4,7,8-TCDD 2. 2,,7,8-TCDD.,2,,4-TCDD 4.,2,,7 +,2,,8-TCDD 5.,2,7,8-TCDD 6.,2,6,7-TCDD.,4,7,8-TCDD 2. 2,,7,8-TCDD.,2,,4-TCDD 4.,2,,7 +,2,,8-TCDD 5.,,7,8-TCDD 6.,2,6,7-TCDD 55

28 Semi-volatiles PAHs Column: DM-PAH, 0 m x 0.25 mm x 0.25 µm Cat. No.: 8862 Index: CER60 Sample: EPA 80 PAHs in dichloromethane solution, 0 ppm Oven Temp.: 65 ºC (hold 0.5 min) to 220 ºC at 5 ºC/min, to 0 ºC (hold 5 min) at 4 ºC/min Carrier Gas: He, 2.0 ml/min Injection: Splitless (hold.75 min), 0.5 µl, 20 ºC Makeup Gas: 75 ml/min Detector: FID, 20 ºC. Naphthalene 2. 2-Methylnaphthalene. -Methylnaphthalene 4. Acenaphthylene 5. Acenaphthene 6. Fluorene 7. Phenanthrene 8. Anthracene 9. Fluoranthene Pyrene. Benzo[a]anthracene 2. Chrysene. Triphenylene 4. Benzo[b]fluoranthene 5. Benzo[k]fluoranthene 6. Benzo[j]fluoranthene 7. Benzo[a]pyrene 8. -Methylcholanthrene 9. Dibenzo[a,h]acridine 20. Dibenzo[a,j]acridine 2. Indeno[,2,-cd]pyrene 22. Dibenzo[a,h]anthracene 2. Benzo[ghi]perylene 24. 7H-Dibenzo[c,g]carbazole 25. Dibenzo[a,e]pyrene 26. Dibenzo[a,i]pyrene 27. Dibenzo[a,h]pyrene / / min. PAHs (EPA 60) Column: Cat. No.: 872 Index: DM-5 MS / LB, 0 m x 0.25 mm x 0.25um CER00595 Oven Temp.: 40 ºC (hold 2 min) to 250 ºC at 25 ºC/min to 265 ºC at 5 ºC/min, to 00 ºC (hold 4 min) at 25 ºC/min Carrier Gas: H 2, 4 ml/min constant flow Injection: Splitless hold 2 min, 0 ºC Sample: Detector: FID, 50 ºC 2 mm splitless inlet liner w / wool PAHs standard,.0 µl, 50 μg/ml V.S.. Naphthalene 2. Acenaphthylene. Acenaphthene 4. Fluorene 5. Phenanthrene 6. Anthracene 7. Fluoranthene 8. Pyrene 9. Benzo[a]anthracene 0.,2-Benzphenanthrene. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene. Benzo[a]pyrene 4. Indeno[,2,-cd]pyrene 5. Dibenzo[a,h]anthracene 6. Benzo[ghi]perylene PAHs (EPA 60) Column: DM-5 MS / LB, 0 m x 0.25 mm x 0.50 µm Cat. No.: 872 Index: CER00549 Oven Temp.: 40 ºC (hold min) to 200 ºC at 20 ºC/min to 0 ºC (hold 5 min) at 4 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Splitless hold min, 00 ºC Sample: PAHs standard,.0 µl, 20 ng/µl Detector: FID, 0 ºC 56

29 Semi-volatiles PAHs (EPA 60) Column: DM-5, 0 m x 0.5 mm x.50 µm Cat. No.: 725 Index: CER0004 Oven Temp.: 4 ºC (hold 6 min) to 00 ºC (hold 5 min) at 0 ºC/min Carrier Gas: H 2, 80 cm/sec Injection: Direct, 00 ºC Sample: PAHs standard, 2.5 µl Detector: FID, 8 x 0 - AFS, 00 ºC. Naphthalene 2. Acenaphthylene. Acenaphthene 4. Fluorene 5. Phenanthrene 6. Anthracene 7. Fluoranthene 8. Pyrene 9. Benzo[a]anthracene 0.,2-Benzphenanthrene. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene. Benzo[a]pyrene 4. Indeno[,2,-cd]pyrene 5. Dibenzo[a,h]anthracene 6. Benzo[ghi]perylene PAHs (EPA 60) Column: DM-5, 0 m x 0.2 mm x 0.25 µm Cat. No.: 72 Index: CER0076 Oven Temp.: 5 ºC (hold 4 min) to 25 ºC at 0 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Direct, cold on-column Sample: PAHs standard, 0.5 µl Detector: FID, 8 x 0 - AFS, 25 ºC. Naphthalene 2. Acenaphthylene. Acenaphthene 4. Fluorene 5. Phenanthrene 6. Anthracene 7. Fluoranthene 8. Pyrene 9. Benzo[a]anthracene 0.,2-Benzphenanthrene. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene. Benzo[a]pyrene 4. Indeno[,2,-cd]pyrene 5. Dibenzo[a,h]anthracene 6. Benzo[ghi]perylene PAHs (EPA 60) Column: DM-200, 0 m x 0.25 mm x 0.25 µm Cat. No.: 82 Index: CER00044 Oven Temp.: 40 ºC (hold 4 min) to 40 ºC at 0 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 40:, 40 ºC Sample: PAHs standard,.2 µl Detector: FID, 6 x 0 - AFS, 40 ºC. Naphthalene 2. Acenaphthylene. Acenaphthene 4. Fluorene 5. Phenanthrene 6. Anthracene 7. Fluoranthene 8. Pyrene 9. Benzo[a]anthracene 0.,2-Benzphenanthrene. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene. Benzo[a]pyrene 4. Indeno[,2,-cd]pyrene 5. Dibenzo[a,h]anthracene 6. Benzo[ghi]perylene 57

30 Semi-volatiles Volatile Organic Compounds (EPA 526) Column: DM-5 MS / LB, 0 m x 0.25 mm x 0.25 µm Cat. No.: 872 Index: CER00656 Oven Temp.: 50 ºC (hold min) to 200 ºC (hold 5 min) at 20 ºC/min, to 0 ºC (hold min) at 0 ºC/min Carrier Gas: He, 0.8 ml/min Injection: Splitless hold 0. min, 00 ºC Sample: EPA 526 mix, µl, 0 ppm Transfer line Temp.: 280 ºC Tune: DFTPP Solvent Delay: 5.5 min Ionization: EI Scan Range: AMU Detector: MS. Nitrobenzene 2. 2,4-Dichlorophenol.,-Dimethyl-2-nitrobenzene 4. 2,4,6-Trichlorophenol 5. Acenaphthene-d0 6. Azobenzene 7. Prometon 8. Terbufos 9. Diazinon 0. Fonofos. Phenanthrene-d0 2. Disulfoton. Acetochlor 4. Cyanazine 5. Triphenyl phosphate 6. Chrysene Phenols (EPA 528) Column: DM-5 MS / LB, 0 m x 0.25 mm x 0.25 µm Cat. No.: 872 Index: CER00664 Oven Temp.: 40 ºC (hold min) to 220 ºC at 2 ºC/min, to 00 ºC (hold min) at 0 ºC/min Carrier Gas: He,. ml/min, constant flow Injection: Splitless, 220 ºC Sample: EPA 528 mix, µl, 5 ppm Transfer line Temp.: 280 ºC Tune: DFTPP Solvent Delay: 5.5 min Ionization: EI Scan Range: AMU Detector: MS. Phenol 2. 2-Chlorophenol-,4,5,6-d4. 2-Chlorophenol 4. 2-Methylphenol 5. 2-Nitrophenol 6. 2,4-Dimethylphenol-,5,6-d 7. 2,4-Dimethylphenol 8. 2,4-Dichlorophenol 9. 4-Chloro--methylphenol 0.,2-Dimethyl--nitrobenzene. 2,4,6-Trichlorophenol 2. 2,4-Dinitrophenol. 4-Nitrophenol 4. 2,,4,5-Tetrachlorophenol 5. 2-Methyl-4,6-dinitrophenol 6. 2,4,6-Tribromophenol 7. Pentachlorophenol 58

31 Semi-volatiles Semi-volatile Organic Compounds Column: DM-5MS / LB, 0 m x 0.25 mm x 0.50 µm Cat. No.: 872 Index: CER0052 Oven Temp.: 40 ºC (hold 2 min) to 290 ºC at 20 ºC/min, to 0 ºC at 2 ºC/min, to 0 ºC (hold min) at 6 ºC/min Carrier Gas: He,.0 ml/min, constant flow Injection: Splitless, 00 ºC Sample: EPA 8270 standard, 80 ng Scan Range: AMU Detector: MS, 280 ºC. N-nitrosodimethylamine 2. Pyridine. Methyl methanesulfonate 4. 2-Fluorophenol 5. Ethyl methanesulfonate 6. Phenol-d6 7. Phenol 8. Aniline 9. bis(2-chloroethyl)ether 0. 2-Chlorophenol-d4. 2-Chlorophenol 2.,-Dichlorobenzene.,4-Dichlorobenzene-d4 4.,4-Dichlorobenzene 5. Benzyl alcohol 6.,2-Dichlorobenzene-d4 7.,2-Dichlorobenzene 8. 2-Methylphenol 9. bis(2-chloroisopropyl)ether Methylphenol / -Methylphenol 2. N-Nitroso-di-n-propylamine 22. Acetophenone 2. Hexachloroethane 24. Nitrobenzene-d5 25. Nitrobenzene 26. Isophorone 27. 2,4-Dimethylphenol Nitrophenol 29. Benzoic acid 0. bis(2-chloroethoxy)methane. 2,4-Dichlorophenol 2.,2,4-Trichlorobenzene. Naphthalene-d8 4. Naphthalene 5. 2,6-Dichlorophenol 6. 4-Chloroaniline 7. Hexachloropropene 8. Hexachlorobutadiene 9. 4-Chloro--methylphenol 40. Isosafrole 4. 2-Methylnaphthalene 42. -Methylnaphthalene 4. Hexachlorocyclopentadiene 44.,2,4,5-Tetrachlorobenzene 45. 2,4,6-Trichlorophenol 46. 2,4,5-Trichlorophenol Fluorobiphenyl 48. Safrole Excellent benzo[b] and benzo[k] fluoranthene separation! 80 ng splitless 0.50 µm film thickness Silarylene phase Chloronaphthalene Nitroaniline 5.,4-Naphthoquinone 52. Dimethylphthalate 5.,-Dinitrobenzene 54. 2,6-Dinitrotoluene 55. Acenaphthylene 56. -Nitroaniline 57. Acenaphthene-d0 58. Acenaphthene 59. 2,4-Dinitrophenol Nitrophenol 6. Pentachlorobenzene 62. 2,4-Dinitrotoluene 6. Dibenzofuran 64. 2,,4,6-Tetrachlorophenol 65. Diethyl phthalate Chlorophenyl phenyl ether 67. Fluorene Nitroaniline 69. 4,6-Dinitro-2-methylphenol 70. Diphenylamine 7. Azobenzene 72. 2,4,6-Tribromophenol 7. Phenacetin Bromophenyl phenyl ether 75. Hexachlorobenzene 76. Pentachlorophenol 77. Pentachloronitrobenzene 78. Dinoseb 79. Phenanthrene-d0 80. Phenanthrene 8. Anthracene 82. di-n-butylphthalate 8. 4-Nitroquinoline--oxide 84. Isodrin 85. Fluoranthene 86. Benzidine 87. Pyrene 88. Aramite 89. p-terphenyl-d4 90. Chlorbenzilate 9. Benzyl butyl phthalate 92. Kepone 9. bis(2-ethylhexyl)phthalate 94., -Dichlorobenzidine 95. Benzo[a]anthracene 96. Chrysene-d2 97. Chrysene 98. di-n-octyl phthalate 99. Benzo[b]fluoranthene 00. Benzo[k]fluoranthene 0. Benzo[a]pyrene 02. Perylene-d2 0. -Methylcholanthrene 04. Indeno[,2,-cd]pyrene 05. Dibenzo[a,h]anthracene 06. Benzo[ghi]perylene 59

32 Pesticides Chlorinated Hydrocarbons (EPA 62) Column: DM-200, 0 m x 0.5 mm x 0.50 µm Cat. No.: 847 Index: CER0005 Oven Temp.: 40 ºC to 280 ºC (hold 5 min) at 8 ºC/min Carrier Gas: He, 40 cm/sec, 40 ºC Injection: Direct, 275 ºC Sample: Chlorinated hydrocarbons mix, 0.5 µl Detector: 220 ºC.,-Dichlorobenzene 2.,4-Dichlorobenzene..2-Dichlorobenzene 4. Hexachloroethane 5.,2,4-Trichlorobenzene 6. Hexachlorobutadiene 7. Hexachlorocyclopentadiene 8. 2-Chloronaphthalene 9. Hexachlorobenzene PAEs (EPA 8060) Column: DM-7, 0 m x 0.2 mm x.00 µm Cat. No.: 745 Index: CER0007 Oven Temp.: 00 ºC to 275 ºC (hold 0 min) at 5 ºC/min Carrier Gas: He, 20 cm/sec Injection: Direct, 275 ºC Sample: PAEs,.5 µl, 60 µg/ml Detector: FID, 64 x 0 - AFS, 275 ºC. DMP 2. DEP. DIBP 4. DBP 5. DMEP 6. BMPP 7. BEEP 8. DPP 9. DOP 0. DNHP. BBP 2. DBEP. DCHP 4. DEHP 5. DNOP 6. DNNP Chlorinated Hydrocarbons (EPA 62) Column: DM-5, 0 m x 0.5 mm x.00 µm Cat. No.: 795 Index: CER00052 Oven Temp.: 40 ºC to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: He, 5 cm/sec, 40 ºC Injection: Direct, 250 ºC Sample: Chlorinated hydrocarbons, 0. µl Detector: 00 ºC V.S. Column: DM-5, 0 m x 0.5 mm x 0.50 µm Cat. No.: 7247 Index: CER0005 Oven Temp.: 40 ºC to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: He, 5 cm/sec, 40 ºC Injection: Direct, 250 ºC Sample: Chlorinated hydrocarbons, 0. µl Detector: 00 ºC.,-Dichlorobenzene 2.,4-Dichlorobenzene.,2-Dichlorobenzene 4. Hexachloroethane 5.,2,4-Trichlorobenzene 6. Hexachlorobutadiene 7. Hexachlorocyclopentadiene 8. 2-Chloronaphthalene 9. Hexachlorobenzene 60

33 Pesticides Phenols (EPA 604) Column: DM-7, 0 m x 0.25 mm x 0.25 µm Cat. No.: 742 Index: CER00029 Oven Temp.: 50 ºC (hold 0 min) to 250 ºC (hold 5 min) at 5 ºC/min Carrier Gas: He, 20 cm/sec Injection: Split, 40 cc/min, 280 ºC Sample: Phenols mix,.0 µl, - 5 ng/µl Detector: FID, 2 x 0 - AFS, 280 ºC. Phenol 2. 2-Chlorophenol. 2,4-Dimethylphenol 4. 2-Nitrophenol 5. 2,4-Dichlorophenol 6. 4-Chloro--methylphenol 7. 2,4,6-Trichlorophenol 8. 2,4-Dinitrophenol 9. 4-Nitrophenol 0. 2-Methyl-4,6-dinitrophenol. Pentachlorophenol Nitrosamines Column: DM-200, 0 m x 0.5 mm x 0.50 µm Cat. No.: 847 Index: CER00040 Oven Temp.: 00 ºC (hold min) to 200 ºC at 5 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 40 cc/min, 250 ºC Sample: Nitrosamines mix,.0 µl, 0 µg/ml Detector: FID, 6 x 0-2 AFS, 250 ºC. N-Nitrosodimethylamine 2. N-Nitrosomethylethylamine. N-Nitrosodiethylamine 4. N-Nitrosoazetidine 5. N-Nitrosopiperidine 6. N-Nitrosomorpholine 7. N-Nitrosopyrrolidine 8. N-Nitrosohexamethyleneimine Benzidines / Phenols (EPA 604 / 605) Column: DM-5, 0 m x 0.2 mm x.00 µm Cat. No.: 725 Index: CER0002 Oven Temp.: 0 ºC to 290 ºC at 8 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 00:, 0 ºC Sample: Phenols / Benzidines mix,.5 µl Detector: FID, 2 x 0 - AFS, 0 ºC V.S. Column: DM-5, 0 m x 0.5 mm x.50 µm Cat. No.: 725 Index: CER000 Oven Temp.: 40 ºC (hold 6 min) to 00 ºC (hold 5 min) at 0 ºC/min Carrier Gas: H 2, 80 cm/sec Injection: Direct, 00 ºC Sample: Phenols / Benzidines mix, 2.5 µl Detector: FID, 8 x 0 - AFS, 00 ºC. Phenol 2. 2-Chlorophenol. 2-Nitrophenol 4. 2,4-Dimethylphenol 5. 2,4-Dichlorophenol 6. 4-Chloro--methylphenol 7. 2,4,6-Trichlorophenol 8. 2,4-Dinitrophenol 9. 4-Nitrophenol 0. 2-Methyl-4,6-dinitrophenol. Pentachlorophenol 2. Benzidine., -Dichlorobenzidine 6

34 Pesticides Organophosphorus Pesticides (EPA 840 / 84 / 84A ) Column: DM-5, 0 m x 0.2 mm x 0.25 µm Cat. No.: 79 Index: CER00696 Oven Temp.: 00 ºC to 80 ºC (hold 2 min) at 0 ºC/min to 00 ºC at 8 ºC/min Carrier Gas: He, 42 cm/sec constant flow, 60 ºC Injection: 0.5 µl, splitless (hold 5 min), 220 ºC Detector: FPD, 280 ºC. Dichlorvos 2. Hexamethylphosphoramide. Mevinphos 4. Trichlorfon 5. Tributyl phosphate 6. Demeton-O 7. TEPP 8. Thionazin 9. Ethoprop 0. Sulfotepp. Naled 2. Phorate. Dicrotophos 4. Demeton-S 5. Terbufos 6. Monocrotophos 7. Diazinon 8. Fonophos 9. Disulfoton 20. Dioxathion 2. Dimethoate 22. Phosphamidon isomer 2. Dichlorofenthion 24. Chlorpyrifos methyl 25. Phosphamidon 26. Ronnel 27. Parathion-methyl 28. Aspon 29. Trichloronate 0. Chlorpyrifos. Fenitrothion 2. Merphos. Malathion 4. Parathion-ethyl 5. Fenthion 6. Chlorfenvinphos 7. Crotoxyphos 8. Merphos oxone 9. Tokuthion 40. Stirofos 4. Ethion 42. Bolstar 4. Fensulfothion 44. Carbofenothion 45. Famphur 46. Triphenyl phosphate 47. EPN 48. Phosmet 49. Leptophos 50. tri-o-cresyl phosphate 5. Azinphos-methyl 52. Azinphos-ethyl 5. Coumaphos Organochlorine Pesticides Column: DM-5, 0 m x 0.25 mm x 0.25 µm Cat. No.: 722 Index: CER0008 Oven Temp.: 60 ºC to 00 ºC (hold 0 min) at 4 ºC/min Carrier Gas: He, 0 cm/sec Injection: Splitless, 250 ºC Sample: Pesticides mix, 2.0 µl Detector: 20 ºC. Etridiazole 50 pg/µl 2. Chlorneb 000 pg/µl. Propachlor 000 pg/µl 4. Trifluralin 50 pg/µl 5. α-bhc 20 pg/µl 6. Hexachlorobenzene 0 pg/µl 7. γ-bhc 0 pg/µl 8. β-bhc 20 pg/µl 9. PCNB 00 pg/µl 0. PCNB (IS) 00 pg/µl. δ-bhc 20 pg/µl 2. Chlorothalonil 50 pg/µl. Heptachlor 20 pg/µl 4. Aldrin 0 pg/µl 5. DCPA 50 pg/µl 6. DCB 5000 pg/µl 7. Heptachlor epoxide 0 pg/µl 8. γ-chlordane 0 pg/µl 9. Endosulfan I 0 pg/µl 20. α-chlordane 0 pg/µl 2. Dieldrin 40 pg/µl 22. Endrin 0 pg/µl 2. Endosulfan II 0 pg/µl 24. Chlorobenzilate 000 pg/µl 25. 4,4 -DDD 50 pg/µl 26. Endrin aldehyde 50 pg/µl 27. Endosulfan sulfate 0 pg/µl 28. 4,4 -DDT 20 pg/µl 29. Methoxychlor 00 pg/µl 0. cis-permethrin 000 pg/µl. trans-permethrin 000 pg/µl 62

35 Pesticides Nitrogen-Containing Herbicides Column: DM-5, 0 m x 0.5 mm x.00 µm Cat. No.: 795 Index: CER00088 Oven Temp.: 60 ºC (hold min) to 290 ºC (hold 5 min) at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Direct, 290 ºC Sample: Nitrogen-containing herbicides, 0.2 µl Detector: FID, 6 x 0 - AFS, 290 ºC. Eptam 2. Sutan. Vernam 4. Tillam 5. Ordram 6. Treflan 7. Balan 8. Ro-Neet 9. Propachlor 0. Tolban. Propazine 2. Atrazine. Simazine 4. Terbacil 5. Sencor 6. Dual 7. Paarlan 8. Prowl 9. Bromacil 20. Oxadiazon 2. GOAL 22. Hexazinone Nitrogen-Containing Herbicides Column: DM-5, 0 m x 0.5 mm x 0.50 µm Cat. No.: 7247 Index: CER00087 Oven Temp.: 60 ºC (hold min) to 290 ºC (hold 5 min) at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Direct, 290 ºC Sample: Nitrogen-containing herbicides, 0.2 µl Detector: FID, 6 x 0 - AFS, 290 ºC. Eptam 2. Sutan. Vernam 4. Tillam 5. Ordram 6. Propachlor 7. Ro-Neet 8. Treflan 9. Balan 0. Simazine. Atrazine 2. Propazine. Tolban 4. Terbacil 5. Sencor 6. Bromacil 7. Dual 8. Paarlan 9. Prowl 20. Oxadiazon 2. GOAL 22. Hexazinone 6

36 Pesticides Organochlorine Pesticides (EPA 808) Column: DM-5, 0 m x 0.5 mm x 0.50 µm Cat. No.: 7247 Index: CER00408 Oven Temp.: 50 ºC (hold 5 min) to 275 ºC (hold 5 min) at 4 ºC/min Carrier Gas: He, 40 cm/sec Injection: Direct, 200 ºC Sample: Pesticides mix,.0 µl, ng/ml Detector: ECD, 5.2 x 0 - AFS, 275 ºC Organochlorine Pesticides (EPA 808) Column: DM-70, 0 m x 0.5 mm x 0.50 µm Cat. No.: 747 Index: CER00409 Oven Temp.: 50 ºC (hold 5 min) to 275 ºC (hold 5 min) at 4 ºC/min Carrier Gas: He, 40 cm/sec, 50 ºC Injection: Direct, 200 ºC Sample: Organochlorine pesticides,.0 µl, ng/ml Detector: ECD, 5.2 x 0-0 AFS, 275 ºC. 2,4,5,6-Tetrachloro-m-xylene 2. α-bhc. γ-bhc 4. Heptachlor 5. Aldrin 6. β-bhc 7. δ-bhc 8. Heptachlor epoxide 9. Endosulfan I 0. γ-chlordane. α-chlordane 2. 4,4 -DDE. Dieldrin 4. Endrin 5. 4,4 -DDD 6. Endosulfan II 7. 4,4 -DDT 8. Endrin aldehyde 9. Endosulfan sulfate 20. Methoxychlor 2. Endrin ketone 22. Decachlorobiphenyl Organochlorine Pesticides (EPA 808) Column: DM-7, 0 m x 0.5 mm x.00 µm Cat. No.: 745 Index: CER0040 Oven Temp.: 50 ºC (hold 5 min) to 275 ºC (hold 5 min) at 8 ºC/min Carrier Gas: He, 40 cm/sec, 50 ºC Injection: Direct, 200 ºC Sample: Pesticides,.0 µl Detector: ECD, 5.2 X 0-0 AFS, 275 ºC. 2,4,5,6-Tetrachloro-m-xylene 2. α-bhc. γ-bhc 4. β-bhc 5. Heptachlor 6. δ-bhc 7. Aldrin 8. Heptachlor epoxide 9. γ-chlordane 0. α-chlordane. Endosulfan I 2. 4,4 -DDE. Dieldrin 4. Endrin 5. 4,4 -DDD 6. Endosulfan II 7. 4,4 -DDT 8. Endrin aldehyde 9. Endosulfan sulfate 20. Methoxychlor 2. Endrin ketone 22. Decachlorobiphenyl Organochlorine Pesticides (EPA 808) Column: DM-5, 0 m x 0.2 mm x 0.50 µm Cat. No.: 79 Index: CER00079 Oven Temp.: 20 ºC (hold min) to 285 ºC (hold 6 min) at 8.5 ºC/min Carrier Gas: He, 2. ml/min, 20 ºC Injection: Direct, 200 ºC Detector: ECD 00 ºC with anode purge. 2,4,5,6-Tetrachloro-m-xylene 2. α-bhc. γ-bhc 4. β-bhc 5. δ-bhc 6. Heptachlor 7. Aldrin 8. Heptachlor epoxide 9. γ-chlordane 0. α-chlordane. 4,4 -DDE 2. Endosulfan I. Dieldrin 4. Endrin 5. 4,4 -DDD 6. Endosulfan II 7. 4,4 -DDT 8. Endrin aldehyde 9. Methoxychlor 20. Endosulfan sulfate 2. Endrin ketone 22. Decachlorobiphenyl 64

37 Pesticides Triazine Herbicides (EPA 69) Column: DM-7, 0 m x 0.5 mm x 0.50 µm Cat. No.: 745 Index: CER00058 Oven Temp.: 50 ºC to 250 ºC (hold 5 min) at 4 ºC/min Carrier Gas: He, 40 cm/sec, 50 ºC Injection: Direct, 250 ºC Sample: EPA Method 69 triazine herbicides, 0.5 µl Detector: TSD, 275 ºC Butyl Tins Column: DM-5, 0 m x 0.2 mm x 0.50 µm Cat. No.: 72 Index: CER00047 Oven Temp.: 00 ºC (hold min) to 285 ºC at 0 ºC/min Carrier Gas: He, 45 cm/sec Injection: 500 pg on-clumn direct, 250 ºC Detector: FPD with 60 nm filter, 250 ºC. Tetrapropyltin 2. Tetrabutyltin. Tributyltin 4. Dibutyltin 5. Tripentyltin 6. Monobutyltin. Atraton 2. Prometon. Terbutylazine 4. Atrazine 5. Simazine 6. Propazine 7. Secbumeton 8. Terbutryne 9. Ametryne 0. Simetryne. Prometryne Chlorophenoxyacid Herbicides (EPA 55.) Column: DM-7, 0 m x 0.25 mm x 0.50 µm Cat. No.: 742 Index: CER0009 Oven Temp.: 50 ºC (hold 0.75 min) to 84 ºC at 4 ºC/min, to 65 ºC at 0 ºC/min to 270 ºC at 4 ºC/min, to 00 ºC (hold 6 min) at 20 ºC/min Carrier Gas: He, 0 cm/sec constant flow, 50 ºC Injection: Splitless, 0.75 min, 220 ºC Sample: Chlorophenoxyacid herbicides, 2.0 µl Detector: ECD, 20 ºC. Dalapon methyl ester 2. 2,4-Dichlorophenylacetic acid methyl ester. Dicamba methyl ester 4. Dibromooctafluorobiphenyl methyl ester 5. 2,4-D methyl ester 6. Pentachlorophenol 7. 2,4,5-TP (silvex) methyl ester 8. 2,4,5-T methyl ester 9. Dinoseb methyl ester 0. 2,4-DB methyl ester. Picloram methyl ester Chlorophenoxyacid Herbicides (EPA 65) Column: DM-5, 0 m x 0.5 mm x.00 µm Cat. No.: 795 Index: CER00094 Oven Temp.: 60 ºC to 50 ºC (hold 5 min) at 8 ºC/min, to 20 ºC at 4 ºC/min Carrier Gas: He, 5 cm/sec, 60 ºC Injection: Direct, 250 ºC Sample: Chlorophenoxyacid herbicides, 0.5 µl Detector: ECD w / anode purge, 275 ºC. Dalapon 2. DCAA (SS). Dicamba 4. MCPP 5. MCPA 6. DBOB (IS) 7. Dichlorprop 8. 2,4-D 9. 2,4,5-TP 0. 2,4,5-T. Dinoseb 2. 2,4-DB 65

38 Drinking Water Volatile Organic Compounds in Water (EPA 55.) Column: DM-200, 0 m x 0.25 mm x.00 µm Cat. No.: 825 Index: CER00024 Oven Temp.: 5 ºC (hold 22 min) to 200 ºC at 0 ºC/min, Carrier Gas: He, 0 cm/sec, 50 ºC Injection: ng on-column, 200 ºC Split Ratio: 0: Detector: ECD, 20 khz full scale, 290 ºC. Chloroform 2.,,-Trichloroethane. Carbon tetrachloride 4. Trichloroacetonitrile 5. Trichloroethylene 6. Bromodichloromethane 7. Chloral hydrate 8. Dichloroacetonitrile 9.,-Dichloro-2-propanone 0.,,2-Trichloroethane. Chloropicrin 2. Dibromochloromethane.,2-Dibromoethane 4. Tetrachloroethylene 5. Bromochloroacetonitrile 6.,,-Trichloro-2-propanone 7. Bromoform 8. Dibromoacetonitrile 9.,2,-Trichloropropane Bromofluorobenzene 2.,2-Dibromo--chloropropane Volatile Organic Compounds in Water Column: DM-AQUA, 60 m x 0.25 mm x.00 µm Cat.No.: 780. Bromomethane 2. Chloroethane Index: CEO0428. Trichlorofluoromethane Carrier Gas: He, 25 cm/sec, 50 ºC 4., Dichloroethylene Oven Temp.: 40 ºC to 200 ºC at 4 ºC/min 5. Dichloromethane Injection: Split, :00, 0.5 µl 6. trans-,2-dichloroethylene Detector: FID 7.,-Dichloroethane 8. 2,2 Dichloropropane 9. cis-,2-dichloroethylene 0. Chloroform. Bromochloromethane 2.,,-Trichloroethane.,-Dichloropropene 4 Tetrachloromethane 5.,2 Dichloroethane 6. Benzene 7. Benzotrifluoride 8. Trichloroethylene 9.,2-Dichloropropane 20. Bromodichloromethane 2. Dibromomethane 22. cis-,-dichloropropylene 2. Toluene 24. trans-,-dichloropropylene 25.,,2-Trichloroethane 26.,-Dichloropropane 27. Tetrachloroethylene 28. Dibromochloromethane 29. -Chlorohexane 4. m-chlorotoluene 0.,2-Dibromoethane 44. p-chlorotoluene. Chlorobenzene 2.,,,2-Tetrachloroethane. Ethylbenzene 4. m-xylene 5. p-xylene 6. o-xylene 7. Bromoform 8.,,2,2-Tetrachloroethane 9. 4-Bromofluorobenzene 40.,2,-Trichloropropane 4. Bromobenzene 42. o-chlorotoluene 45.,-Dichlorobenzene 46.,4-Dichlorobenzene 47.,2-Dichlorobenzene 48.,2-Dibromo--chloropropane 49.,2,4-Trichlorobenzene 50.,,2,,4,4-Hexachloro-,2-butadiene 5.,2,-Trichlorobenzene 66

39 PAEs / Explosives PAEs Column: DM-5MS, 0 m x 0.25 mm x 0.50 µm Cat. No.: 822 Index: CER00049 Oven Temp.: 5 ºC (hold min) to 285 ºC at 0 ºC/min Pressure: 7.5 psi Injection: 00 pg on-column Detector: MS-SIM. Dimethyl phthalate 2. Diethyl phthalate. Isobutyl phthalate 4. Dibutyl phthalate 5. Dipentyl phthalate 6. Dihexyl phthalate 7. Benzyl ethyl phthalate 8. Diheptyl phthalate 9. 2-Ethylhexyl phthalate 0. Cyclohexyl phthalate. Dioctyl phthalate Endocrine Disruptors Butyl Tins (Hexyl Derivatives) Column: DM-5, 0 m x 0.2 mm x 0.50 µm Cat. No.: 79 Index: CER00048 Oven Temp.: 00 ºC (hold min) to 285 ºC at 0 ºC/min Carrier Gas: He, 45 cm/sec Injection: 500 pg on-column, 250 ºC Detector: FPD with 60 nm filter, 250 ºC. Tetrapropyltin 2. Tetrabutyltin. Tributyltin 4. Dibutyltin 5. Tripentyltin 6. Monobutyltin Explosives Column: DM-200, 0 m x 0.25 mm x 0.25 µm Cat. No.: 82 Index: CER00060 Oven Temp.: 80 ºC (hold 2 min) to 260 ºC (hold 2 min) at ºC/min Carrier Gas: He, 20 cm/sec, 80 ºC Injection: Splitless, hold 0.6 min, 280 ºC Sample: Explosives,.0 µl Detector: MS, 00 ºC. 2-Nitrotoluene 2. -Nitrotoluene. 4-Nitrotoluene 4. 2,-Diaminotoluene 5. 2,6-Diaminotoluene 6. 2,4-Diaminotoluene 7.,4-Dinitrobenzene 8. 2,6-Dinitrotoluene 9. 2-Amino-6-nitrotoluene 0.,-Dinitrobenzene. 2,4-Dinitrotoluene 2. 2-Amino-4-nitrotoluene. 2,-Dinitrotoluene 4.,4-Dinitrotoluene 5. -Nitrobiphenyl 6. 2,4,6-Trinitrotoluene 7. 2,4,5-Trinitrotoluene 8. 4-Amino-2,6-dinitrotoluene 9. 2,,4-Trinitrotoluene 20.,-Dinitronaphthalene 2. 2,6-Diamino-4-nitrotoluene Amino-4,6-dinitrotoluene 2. 2,2 -Dinitrobiphenyl 67

40 Petrochemicals Permanent Gases Column: DM-PLOT Q + DM-PLOT MS 5A, A: 0 m x 0.5 mm x µm B: 0 m x 0.2 mm x 0.00 µm Cat. No.: = A + B Index: CSR007 Carrier Gas: H 2, 8 psi Injection: Split, 0:, 20 µl Detector: TCD, 200 ºC Injector Universal Y Connector Cat. No.: 2502 DM-PLOT Q 0 m x 0.5 mm Cat. No.: 886 Universal Y Connector Cat.No.: 2502 Detector. Helium 2. Argon. Oxygen 4. Nitrogen 5. Methane 6. Carbon dioxide 7. Carbon monoxide 0.5 m DM-PLOT Q DM-PLOT MS 5A 0 m x 0.5 mm Cat. No.: m DM-PLOT Q DM-PLOT Q DM-PLOT MS 5A Permanent Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0069 Oven Temp.: 0 ºC Carrier Gas: H 2, 8 cm/sec Injection: Split, 40:, 0 ºC Sample Concentration: 2-5 mol %, 0 µl Detector: TCD, 200 ºC Permanent Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0074L Carrier Gas: H 2, 4 cm/sec Injection Temp.: 5 ºC Split Ratio: 40: Sample Concentration: 2-5 mol % Detector: TCD, 5 ºC Permanent Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0074R Carrier Gas: H 2, 20 cm/sec Injection Temp.: -40 ºC Split Ratio: 40: Sample Concentration: 2-5 mol % Detector: TCD, -40 ºC. Helium 2. Air. Carbon monoxide 4. Methane 5. Carbon dioxide. Air 2. Carbon monoxide. Methane 4. Carbon dioxide. Nitrogen 2. Oxygen. Argon 5 ºC -40 ºC 68

41 Petrochemicals Permanent Gases Column: DM-PLOT MS 5A, 0 m x 0.2 mm x 0.00 µm Cat. No.: 8822 Index: CSR0065 Oven Temp.: 70 ºC Carrier Gas: H 2, 64 cm/sec Injection Temp.: Split, 70 ºC Sample Concentration: 2-5 mol%, 20 µl Detector: TCD, high senstivity, 200 ºC Permanent Gases Column: DM-PLOT Q / DM-PLOT S / DM-PLOT U, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 / 880 / 8824 Index: CSR0080 Oven Temp.: 50 ºC Carrier Gas: H 2 Injection: Split, 20:, 200 ºC Sample: 000 ppm (v / v) in He, 00 µl Detector: FID, 200 ºC. Methane 2. Ethylene. Ethane 4. Acetylene 5. Propylene 6. Propane. Helium 2. Argon. Oxygen 4. Nitrogen 5. Methane 6. Carbon monoxide DM-PLOT Q has least selective for functional groups Permanent Gases Column: DM-PLOT MS 5A, 0 m x 0.5 mm x µm Cat. No.: 882 Index: CSR0070 Oven Temp.: 27 ºC Carrier Gas: He, 4 cm/sec Injection: Sample loop, 0.5 ml Detector: Valco HID DM-PLOT S has selective for polar, unsaturated compounds. Hydrogen 2. Argon. Oxygen DM-PLOT U has most selective for unsaturated compounds 69

42 Petrochemicals Refinery Gas Column: DM-PLOT Alumina / Na 2 SO 4, 0 m 0.5 mm 0.00 µm Sample: Refinery gas Cat. No.: 8806 Index: CSR09 Injection: Split, 0 µl, 200 ºC Split Vent Flow Rate: 40 ml/min Oven Temp.: 60 ºC (hold 2 min) to 200 ºC (hold min) at 0 ºC/min Carrier Gas: He, constant pressure (5.0 psi, 4.5 kpa), 7. cm/sec, 60 ºC Detector: FID, 200 ºC Make up gas: N 2. Methane 2. Ethane. Ethylene 4. Propane 5. Propylene 6. Isobutane 7. n-butane 8. Propadiene 9. Acetylene 0. trans-2-butene. -Butene 2. Isobutylene. cis-2-butene 4. Isopentane 5. n-pentane 6.,-Butadiene 7. trans-2-pentene 8. 2-Methyl-2-butene 9. -Pentene 20. cis-2-pentene 2. Hexanes Impurity Analysis of,,,2-tetrafluoroethane Column: DM-PLOT CFC, 0 m x 0.5 mm x 0.00 µm Cat. No.: 8859 Index: Sample: CGR55 Injection: Split, 500 µl Oven Temp.: Carrier Gas: Detector:,,,2-Tetrafluoroethane 80 ºC (hold 6 min) to 40 ºC (hold 2 min) at 0 ºC/min He FID. Chloropentafluoroethane (CFC-5) 2. Dichlorodifluoromethane (CFC-2). Chlorodifluoromethane (CFC-22) 4.,,,2-Tetrafluoroethane (CFC-4a) Natural Gas #2 Column: DM-PLOT QS, 0 m x 0.5 mm x µm Cat. No.: 880 Index: CSR00 Oven Temp.: 40 ºC (hold 2 min) to 225 ºC (hold 5 min) at 20 ºC/min Carrier Gas: He, 5.7 ml/min Injection: 20 µl split (split ratio 0:), 240 ºC Sample: Natural gas mix (mol%) Detector: FID, 240 ºC Butane Lighter Fluid Column: DM-PLOT Alumina / KCl, 50 m 0.5 mm 0.00 µm Cat. No.: 88 Index: CSR0086 Sample: Butane lighter fluid Injection: Valve, 00 µl, 200 ºC Oven Temp.: 45 ºC (hold min) to 200 ºC (hold.5 min) at 0 ºC/min Carrier Gas: H 2, constant pressure (8.0 psi, 55.2 kpa) 74 cm/sec 45 ºC Detector: FID, 200 ºC. Methane 2. Ethane. Propane 4. Isobutane 5. n-butane 6. Isopentane 7. n-pentane 8. Hexanes / Hexenes. Methane 2. Ethane. Propane 4. Isobutane 5. n-butane 6. trans-2-butene 7. -Butene 8. Isobutylene 70

43 Petrochemicals Propylene Purity Column: DM-PLOT Alumina, 50 m x 0.5 mm x 6.00 µm Cat. No.: 880 Index: CSR0085 Oven Temp.: 40 ºC (hold min) to 20 ºC (hold 5 min) at 0 ºC/min Carrier Gas: He, 7.5 cm/sec, 80 ºC Injection: Gas-tight syringe, 60 ml/min, 200 ºC Sample: Hydrocarbons mix, 00 µl Detector: FID,.28 x 0-0 AFS, 200 ºC. Methane 2. Ethane. Ethylene 4. Propane 5. Cyclopropane 6. Propylene 7. Isobutane 8. n-butane 9. Propadiene 0. Acetylene. trans-2-butene 2. -Butene. cis-2-butene 4. Isopentane 5. n-pentane 6.,-Butadiene 7. Propyne Hydrocarbon Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0052 Oven Temp.: 40 ºC to 240 ºC (hold 0 min) at 8 ºC/min Carrier Gas: He, 5 cm/sec, 40 ºC Injection: Split, 20:, 250 ºC Head Pressure: 8.0 psi Column flow rate:.5 ml/min, 40 ºC Sample: Hydrocarbon gases mix, 0 µl Detector: FID, 240 ºC. Methane 2. Ethene. Ethane 4. Propene 5. Propane 6. Propadiene 7. Isobutane 8.,-Butadiene 9. -butene 0. Isobutene. n-butane 2. cis-2-butene. trans-2-butene 4. Isopentane 5. n-pentane 6. n-hexane 7

44 Petrochemicals Hydrocarbon Gases Hydrocarbon Gases Column: DM-PLOT U, 0 m x 0.2 mm x 0.00 µm Cat. No.: 8824 Index: CSR0077 Oven Temp.: 50 ºC to 90 ºC at 0 ºC/min Carrier Gas: He, 42 cm/sec, 80 ºC Injection: Split, 00 µl, 40 ml/min, 40:, 250 ºC Detector: FID,.28 x 0-0 AFS, 250 ºC. Methane 2. Ethylene. Ethane 4. Acetylene 5. Propane 6. Propylene 7. Cyclopropane 8. Propadiene 9. Propyne 0. Isobutane. n-butane 2. -Butene. cis-2-butene 4. trans-2-butene 5.,-Butadiene 6. Isopentane 7. n-pentane Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0076 Oven Temp.: 50 ºC (hold 2 min) to 220 ºC at 5 ºC/min Carrier Gas: He, 42 cm/sec, 80 ºC Injection: Split, 00 µl, 40 ml/min, 40:, 250 ºC Detector: FID,.28 x 0-0 AFS, 250 ºC. Methane 2. Ethylene. Acetylene 4. Ethane 5. Propylene 6. Propane 7. Cyclopropane 8. Propadiene 9. Propyne 0. Isobutane.,-Butadiene 2. -Butene. n-butane 4. cis-2-butene 5. trans-2-butene 6. Isopentane 7. n-pentane Refinery Gas Column: DM-PLOT Alumina, 50 m x 0.5 mm x 6.00 µm Cat. No.: 880 Index: CSR008 Oven Temp.: 40 ºC to 20 ºC (hold 5 min) at 5 ºC/min Carrier Gas: He, 7.5 cm/sec, 80 ºC Injection: Split (gastight syringe) 60 ml/min, 200 ºC Sample: Hydrocarbons mix, 00 µl,,000 ppm Detector: FID,.28 x 0-0 AFS, 200 ºC. Methane 2. Ethane. Ethylene 4. Propane 5. Cyclopropane 6. Propylene 7. Isobutane 8. n-butane 9. Propadiene 0. Acetylene. trans-2-butene 2. -Butene. cis-2-butene 4. Isopentane 5. n-pentane 6.,-Butadiene 7. Propyne,-Butadiene Purity Column: DM-PLOT Alumina, 50 m x 0.5 mm x 6.00 µm Cat. No.: 880 Index: CSR0086 Oven Temp.: 80 ºC Carrier Gas: He, 42 cm/sec, 80 ºC Injection: Gastight syringe, 40 ml/min, 200 ºC Sample: 99+%,-Butadiene, 500 µl Detector: FID,.28 x 0-0 AFS, 200 ºC. Methane 2. Ethane. Propane 4. Isobutane 5. n-butane 6. trans-2-butene 7. -Butene 8. Isobutylene 9. cis-2-butene 0. Isopentane.,-Butadiene 72

45 Petrochemicals Hydrocarbons Column: DM-PLOT Alumina, 50 m x 0.5 mm x 6.00 µm Cat. No.: 880 Index: CSR0055 Oven Temp.: 80 ºC Carrier Gas: He, 42 cm/sec, 80 ºC Injection: Gastight syringe, 40 ml/min, 200 ºC Sample: 200 µl,,000 ppm Detector: FID,.28 x 0-0 AFS, 200 ºC Hydrocarbon Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR0052 Oven Temp.: 40 ºC to 240 ºC (hold 0 min) at 0 ºC/min Carrier Gas: He, 5 cm/sec, 40 ºC Head Pressure: 8.0 psi Column flow rate:.5 ml/min, 40 ºC Injection: Split, 20:, 250 ºC Sample: Hydrocarbon gases mix, 0 µl Detector: FID, 240 ºC. Methane 2. Ethane. Ethylene 4. Propane 5. Cyclopropane 6. Propylene 7. Isobutane 8. n-butane 9. Propadiene 0. Acetylene. trans-2-butene 2. -Butene. cis-2-butene 4. Isopentane 5. n-pentane 6.,-Butadiene 7. Propyne. Methane 2. Ethane. Propane 4. Isobutane 5. n-butane 6. Isopentane 7. n-pentane 8. Hexane Hydrocarbon Gases Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR00522 Oven Temp.: 5 ºC to 240 ºC (hold 0 min) at 0 ºC/min Carrier Gas: He, 5 cm/sec, 40 ºC Head Pressure: 8.0 psi Column flow rate:.5 cc/min, 40 ºC Injection: Split, 20:, 250 ºC Sample: Hydrocarbon gases mix, 0 µl Detector: FID, 240 ºC. Methane 2. Ethylene. Ethane 4. Propylene 5. Propane 6. Isobutane 7.,-Butadiene 8. -Butene 9. Isobutene 0. n-butane. cis-2-butene 2. trans-2-butene 7

46 Petrochemicals Petroleum Oxygenates Column: DM-Wax, 0 m x 0.5 mm x.00 µm Cat. No.: 755 Index: CSR0096 Oven Temp.: 45 ºC (hold 4 min) to 220 ºC at 6 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Direct, 220 ºC Sample: Synthetic blend, 0.2 µl, 5-0 ng/µl Detector: FID, 6 x 0 - AFS, 220 ºC. Heptane 2. C oxide. Benzene 4. Toluene 5. Ethylbenzene 6. p-xylene 7. m-xylene 8. Cumene 9. o-xylene 0. Styrene. 2-Methylpentanol 2. p-diethylbenzene. m-diethylbenzene 4. α-methylstyrene 5. o-diethylbenzene 6. Phenylacetylene 7. Benzaldehyde 8. Monopropylene glycol 9. Acetophenone Phenyl-2-propanol 2. α-methylbenzyl alcohol 22. Benzyl alcohol 2. Phenylethyl alcohol 24. Phenol Petroleum Oxygenates Column: DM-TCEP, 60 m x 0.25 mm x 0.40 µm Cat. No.: 7809 Index: CSR0095 Oven Temp.: 60 ºC (hold 5 min) to 00 ºC (hold 0 min) at 5 ºC/min Carrier Gas: He, 0 cm/sec, 80 ºC Injection: Split, 46 ml/min, 200 ºC Sample:.0 µl, 500 ppm Detector: FID, 6.4 x 0 - AFS, 200 ºC. Methyl tert-butyl ether 2. n-undecane. tert-butanol 4. Methanol 5. Isopropyl alcohol 6. Ethanol 7. n-dodecane 8. n-tridecane 9. n-butanol 74

47 Petrochemicals Petroleum Oxygenates Column: DM-, 0 m x 0.5 mm x.00 µm Cat. No.: 755 Index: CSR0094 Oven Temp.: 60 ºC Carrier Gas: He, 5 ml/min, 60 ºC Injection: Split, 5:, 200 ºC Sample: Oxygenates blend - 0 % wt in surrogate gasoline, 0.5 µl Detector: FID, 250 ºC. Methanol 2. Ethanol. Isopropanol 4. tert-butanol 5. n-propanol 6. Methyl tert-butyl ether 7. sec-butanol 8. DIPE 9. Isobutanol 0. Ethyl tert-butyl ether. tert-amyl ether 2. Dimethoxyethane. n-butanol 4. Benzene 5. TAME 6. Total heavy hydrocarbons Oxygenates MTBE Column: DM-, 0 m x 0.5 mm x 5.00 µm Cat. No.: 757 Index: CSR0097 Oven Temp.: 40 ºC (hold 8 min) to 200 ºC at 5 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Direct, 200 ºC Sample: Methyl tert-butyl ether, 0. µl Detector: FID, 8 x 0 - AFS, 200 ºC. Dimethylether 2. Methanol. C4s 4. tert-butyl alcohol 5. Methyl tert-butyl ether 6. sec-butyl methyl ether 7. Diisobutylene 8. 4-Vinyl cyclohexene- 9. Triisobutylene 75

48 Petrochemicals Sulfur in Gasoline Column: DM-, 0 m x 0.2 mm x 4.00 µm Cat. No.: 74 Index: CSR0098 Oven Temp.: 40 ºC (hold min) to 275 ºC (hold 5 min) at 0 ºC/min Carrier Gas: He, 70 cm/sec Injection: Split, 0:, 275 ºC Sample: Sulfur in gasoline,.0 µl, 00 ppm Detector: SCD, 275 ºC Sulfur in Naphtha Column: DM-, 0 m x 0.2 mm x 4.00 µm Cat. No.: 74 Index: CSR0099 Oven Temp.: 5 ºC to 275 ºC (hold 5 min) at 0 ºC/min Carrier Gas: He, 24 cm/sec Injection: Split, 0:, 275 ºC Sample: Sulfur in naphtha,.0 µl, 500 ppm Detector: AED, 8 nm, 275 ºC. Thiophene 2. 2-Methylthiophene. -Methylthiophene 4. 2-Ethylthiophene 5. Alkylthiophenes 6. Benzothiophene 7. Methylbenzothiophenes 8. Dimethylbenzothiophenes. Hydrogen sulfide 2. Thiophene. 2-Methylthiophene 4. -Methylthiophene 5. 2-Ethylthiophene Sulfide Column: DM-, 60 m x 0.5 mm x 5.00 µm Cat. No.: 758 Index: CSR00200 Oven Temp.: 50 ºC to 200 ºC at 5 ºC/ min Carrier Gas: He, 0 cm/sec, 50 ºC Injection: Direct, 50 ºC Sample: Sulfide mix, 00 µl Detector: FPD, 20 ºC. Hydrogen sulfide 2. Sulfur dioxide + Carbonyl sulfide. Methanthiol 4. Ethanethiol 5. Carbon disulfide 6. Methyl sulfide 7. 2-Propylmercapatan 8. Allylmercaptan 9. -Propylmercapatan 0. Ethyl thioether. Butanethiol 2. Methyl disulfide. Diallylsulfide 4. Dipropyl sulfide 5. Butyl sulfide + Diallyl disulfide 76

49 Petrochemicals Bleed Profile Column: DM-HT SimDist Metal, 5 m x 0.5 mm x 0.0 µm Cat.No.: 7806 Index: CSR00527 Oven Temp.: 40 ºC to 40 ºC (hold 0 min) at 0 ºC/min Carrier Gas: He, 60 cm/sec Injection: On-column Flow Rate: 7.8 ml/min Head Pressure:.0 psi Detector: FID, 40 ºC Glycerin in Biodiesel (ASTM D6584) Column: DM-BDTG Metal, 4 m x 0.5 mm x 0.6 µm (with 2 m Integra-Gap,total length 6 m) Cat. No.: 8864 Index: Sample: Injection: CSR00969 Biodiesel (B00) in n-hexane µl cold on-column 50 ºC (hold min) to 80 ºC at 5 ºC/min Oven Temp.: to 20 ºC at 7 ºC/min, to 80 ºC (hold 5 min) at 0 ºC/min Carrier Gas: H 2, 4 ml/min Detector: FID, 80 ºC Diglyceride Triglyceride Monoglyceride Monoglyceride Tricaprin Low Bleed! Glycerol Butanetrid Hydrocarbons, C44 - C00 Column: DM-HT SimDist Metal, 5 m x 0.5 mm x 0.0 µm Cat. No.: 7806 Index: CSR0054 Solvent: Carbon disulfide Injection: On-column Oven Temp.: 40 ºC to 40 ºC (hold 0 min) at 60 ºC/ min Carrier Gas: H 2,.0 psi Sample: Polywax 000, 0.2 µl Detector: FID, 40 ºC Hydrocarbons, C44 - C00 Column: DM-HT SimDist Metal, 5 m x 0.5 mm x 0.0 µm Cat. No.: 7806 Index: CSR005 Injection: On-column, 0.2 µl Oven Temp.: 40 ºC to 40 ºC (hold 25 min) at 60 ºC/min Carrier Gas: He, 60 cm/sec,.0 psi Sample: Polywax 000, 0.2 µl Flow Rate: 7.8 ml/min Detector: FID, 40 ºC 77

50 Petrochemicals Simulated Distillation Column: DM-2887, 0 m x 0.5 mm x 2.65 µm Cat. No.: 7808 Index: CSR00227 Oven Temp.: 5 ºC to 60 ºC (hold 5 min) at 5 ºC/min Carrier Gas: N 2, 2 cm/sec Injection: Direct, 60 ºC Sample: wt% Hydrocarbon in CS 2 solvent,.0 µl Simulated Distillation Column: DM-2887, 0 m x 0.5 mm x 2.65 µm Cat. No.: 7808 Index: CSR00226 Oven Temp.: 5 ºC to 60 ºC (hold 5 min) at 5 ºC/min Carrier Gas: N 2, 2 cm/sec Injection: Direct, 60 ºC Sample: wt% Hydrocarbon in CS 2 solvent,.0 µl. C5 2. C6. C7 4. C8 5. C9 6. C0 7. C 8. C2 9. C4 0. C6. C8 2. C20. C24 4. C28 5. C2 6. C6 7. C40 8. C44 Hydrocarbons, C0 - C0 Column: DM-HT SimDist Metal, 5 m x 0.5 mm x 0.0 µm Cat. No.: 7806 Index: CSR0050 Oven Temp.: 40 ºC to 40 ºC (hold 0 min) at 0 ºC/min Carrier Gas: He, 60 cm/sec Injection: On-column Flow Rate: 7.8 ml/min Head Pressure:.0 psi Hydrocarbons, C0 - C44 Column: DM-HT SimDist Metal, 5 m x 0.5 mm x 0.0 µm Cat. No.: 7806 Index: CSR00529 Oven Temp.: 40º C to 40 ºC (hold 0 min) at 0 ºC/min Carrier Gas: He, 60 cm/sec Injection: On-column Flow Rate: 7.8 ml/min Head Pressure:.0 psi Solvent: CS 2 Sample: Polywax 000, 0.2 µl Detector: FID, 40 ºC Solvent: CS 2 Sample: Hydrocarbons, 0.2 µl Detector: FID, 40 ºC 78

51 Petrochemicals Detailed Hydrocarbons Analysis Column: DM-PONA, 00 m x 0.25 mm x 0.50 µm Cat. No.: 7805 Index: CSR00209 Oven Temp.: 5 ºC (hold min) to 45 ºC (hold 5 min) at 0 ºC/min to 60 ºC (hold 5 min) at ºC/min to 200 ºC (hold 5 min) at.9 ºC/min Carrier Gas: He, 24 cm/sec, 5 ºC Injection: Split, 00:, 250 ºC Sample: Reformulated gasoline, 0.5 µl Detector: FID, 4 x 0-2 AFS, 250 ºC. Propane 2. iso-butane / Methanol. n-butane 4. iso-pentane 5. n-pentane 6. -Methylpentane 7. n-hexane 8. Benzene 9. 2-Methylhexane 0. n-heptane. Toluene 2. 2,-Dimethylhexane. n-octane 4. Ethylbenzene 5. m-xylene 6. p-xylene 7. 2,-Dimethylheptane 8. o-xylene 9. n-nonane 20.,,5-Trimethylbenzene 2.,2,4-Trimethylbenzene 22. n-decane 2. n-undecane 24. Naphthalene 25. n-dodecane Methylnaphthalene 27. n-tridecane Hydrocarbons, C7 - C42 Column: DM-, 0 m x 0.25 mm x 0.0 µm Cat. No.: 79 Index: CSR0026 Oven Temp.: 40 ºC to 40 ºC at 5 ºC/min Carrier Gas: H 2, 40 cm/sec, 40 ºC Injection: Direct, 40 ºC Sample: 0.2 µl Injection of a synthetic hydrocarbons mix, 0. mg/ml per component. C7 2. C8. C9 4. C0 5. C 6. C2 7. C 8. C4 9. C5 0. C6. C7 2. C8. C9 4. C20 5. C22 6. C2 7. C24 8. C25 9. C C28 2. C0 22. C2 2. C4 24. C6 25. C8 26. C C42 Detector: FID, 64 x 0 - AFS, 40 ºC 79

52 Petrochemicals Gasoline Aromatics Column: DM-, 60 m x 0.25 mm x.00 µm Cat. No.: 726 Index: CSR0025 Oven Temp.: 50 ºC (hold min) to 90 ºC at 2 ºC/min Injection: Split, 200:, 250 ºC Sample: Neat gasoline,.0 µl Detector: MS, m/e, scan/sec, 280 ºC TIC. Benzene 2. Toluene. Ethylbenzene 4. m-xylene 5. p-xylene 6. o-xylene 7. Isopropyl benzene 8. n-propylbenzene 9. -Methyl--ethylbenzene 0. -Methyl-4-ethylbenzene.,,5-Trimethylbenzene 2. -Methyl-2-ethylbenzene.,2,4-Trimethylbenzene 4.,2,-Trimethylbenzene 5. Indane 6.,4-Diethylbenzene 7. Butylbenzene 8.,2-Diethylbenzene 9.,2,4,5-Tetramethylbenzene 20.,2,,5-Tetramethylbenzene 2. Pentamethylbenzene 22. Naphthalene 2. 2-Methylnaphthalene 24. -Methylnaphthalene RIC 80

53 Petrochemicals Aromatics (Benzene / Toluene / Xylene) Column: DM-Wax, 0 m x 0.5 mm x.00 µm Cat. No.: 755 Index: CSR009 Oven Temp.: 50 ºC Carrier Gas: H 2, 40 cm/sec Injection: Direct, 250 ºC Sample: Benzene, toluene, xylene, 0. µl Detector: FID, 6 x 0 - AFS, 250 ºC Aromatics (Benzene / Toluene / Xylene) Column: DM-200, 0 m x 0.5 mm x 0.50 µm Cat. No.: 847 Index: CSR0089 Oven Temp.: 60 ºC Carrier Gas: He, 40 cm/sec Injection: Direct, 250 ºC Sample: Benzene, toluene, xylene standard, 0. µl Detector: FID, 4 X 0 - AFS, 250 ºC. Benzene 2. Toluene. Ethylbenzene 4. p-xylene 5. m-xylene 6. o-xylene. Benzene 2. Toluene. Ethylbenzene 4. m-xylene 5. p-xylene 6. o-xylene Aromatics Column: DM-TCEP, 60 m x 0.25 mm x 0.40 µm Cat. No.: 7809 Index: CSR002 Oven Temp.: 60 ºC (hold 5 min) to 00 ºC (hold 0 min) at 5 ºC/min Carrier Gas: He, 0 cm/sec, 80 ºC Injection: Split, 46 ml/min, 200 ºC Sample: 500 ppm (Ethylbenzene,000 ppm),.0 µl Detector: FID, 6.4 x 0 - AFS, 200 ºC. n-undecane 2. Benzene. n-dodecane 4. Toluene 5. Ethylbenzene 6. p-xylene 7. m-xylene 8. Cumene 9. n-propylbenzene 0. o-xylene. Mesitylene 2. -Ethyl-2-methylbenzene. m-diethylbenzene 4. p-diethylbenzene 5. o-diethylbenzene 8

54 Petrochemicals Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR0009 Oven Temp.: 40 ºC (hold 0 min) to 245 ºC (hold 20 min) at 4 ºC/min Carrier Gas: He, 50 cm/sec, 50 ºC Injection: Split, 7:, 250 ºC Sample: Aromatics mixture,.0 µl Detector: MS, 280 ºC Ionization: EI. trans-decahydronaphthalene 2. o-xylene. cis-decahydronaphthalene 4.,,5-Trimethylbenzene 5. p-cymene 6.,2,4-Trimethylbenzene 7. α-methylbenzene 8.,2,-Trimethylbenzene 9. Diisopropylbenzene 0. Triethylbenzene. Pentadecane 2. Nitrobenzene. Nonadecane 4. o-cresol 5. Bibenzyl Aromatics Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR00 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 50 cm/sec, 50 ºC Injection: Split, 7:, 250 ºC Sample: Aromatics mixture,.0 µl Detector: FID, 285 ºC Ionization: EI, scan 0, range 00. Toluene 2. Ethylbenzene. p-xylene 4. Isopropyl benzene 5. Propylbenzene 6. tert-butylbenzene 7. Styrene 8. Butylbenzene 9. Pentadecane 0. Naphthalene. Nonadecane 2. p-cresol 82

55 Amines Primary Amines (Low MW) Column: DM-Wax Amine, 0 m x 0.5 mm x.00 µm Cat. No.: 78 Index: CCR0004 Oven Temp.: 45 ºC Carrier Gas: H 2, 40 cm/sec Injection: Direct,.0 µl, 250 ºC Sample: Amines in water,.0 µl Detector: FID, x 0 - AFS, 250 ºC Amines (Low MW) Column: DM-Wax Amine, 0 m x 0.5 mm x.00 µm Cat. No.: 78 Index: CCR0005 Oven Temp.: 50 ºC Carrier Gas: H 2, 47 cm/sec Injection: Split, 40:, 200 ºC Sample: Methanol in water, 0.6 µl, 500 ng/µl Detector: FID, 4 x 0 - AFS, 200 ºC. Trimethylamine 2. Dimethylamine. Ethylamine 4. Methylamine 5. Isopropylamine 6. n-propylamine 7. tert-butylamine 8. Diethylamine 9. sec-butylamine. Trimethylamine 2. Diethylamine. Methanol Primary Amines Column: DM-5 Amine, 0 m x 0.5 mm x.00 µm Cat. No.: 7825 Index: CCR00578 Oven Temp.: 5 ºC (hold 5 min) Carrier Gas: He, 5.7 cm/sec constant pressure Injection: Split, 0: Sample: Primary amines in water, 50 ppm,.0 µl Detector: FID, 00 ºC Short Chain Amaines in Water Column: DM-Volatile Amine, 60 m x 0.2 mm Cat. No.: 8857 Index: CGN54 Sample: 200 -,000 ppm Short chain amines in water Injection: Split, 5:,.0 µl, 220 ºC Oven Temp.: 40 ºC (hold 0 min) to 250 ºC (hold 0 min) at 20 ºC/min Carrier Gas: H 2, 2.0 ml/min, 5 cm/sec, 40 ºC Detector: FID, 250 ºC pa. Methylamine 2. Dimethylamine. Trimethylamine 4. Ethylamine 5. Isopropylamine 6. tert-butylamine 7. n-propylamine 8. Diethylamine 9. sec-butylamine IS 5. Methanol 2. Dimethylamine. Trimethylamine 4. Isopropylamine 5. Dimethylethylamine 6. Diethylamine 7. Diethylmethylamine 8. Triethylamine min. 8

56 Amines Ethylenediamines Column: DM-5 Amine, 0 m x 0.25 mm x 0.50 µm Cat. No.: 785 Index: CCR00298 Oven Temp.: 40 ºC (hold 4 min) to 5 ºC (hold 5 min) at 0 ºC/min Carrier Gas: H 2, 4 cm/sec, 40 ºC Injection: Split, 20:, 5 ºC Sample: Ethylenediamines,.0 µl, 5-80 ng Detector: FID, 6.4 x 0 - AFS, 5 ºC. Isopropanol 2. Monoethanolamine. Ethylenediamine 4. Piperazine 5. Diethylenetriamine 6. Aminoethylethanolamine 7. Aminoethylpiperazine Ethanolamines Column: DM-5 Amine, 0 m x 0.2 mm x.00 µm Cat. No.: 782 Index: CCR00585 Oven Temp.: 50 ºC (hold 0.5 min) to 280 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec constant pressure, 50 ºC Injection: Split, 0:, 00 ºC Sample: 500 µg/ml Ethanolamines standard in water,.0 µl Detector: FID, 00 ºC. Monoethanolamine 2. Diethanolamine. Triethylene glycol monomethylether 4. Triethanolamine Hexamethylenediamine Column: DM-Wax Amine, 0 m x 0.2 mm x 0.25 µm Cat. No.: 7829 Index: CCR0002 Oven Temp.: 95 ºC (hold 6 min) to 25 ºC (hold 4 min) at 7 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Direct, 250 ºC Sample: Hexamethylenediamine, 0.4 µl, 0-00 ng Detector: FID, 2 x 0 - AFS, 250 ºC V.S. Column: DM-Wax Amine, 0 m x 0.5 mm x 0.50 µm Cat. No.: 787 Index: CCR000 Oven Temp.: 95 ºC (hold 6 min) to 25 ºC (hold 2 min) at 7 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Direct, 255 ºC Sample: Hexamethylenediamine, 0.2 µl Detector: FID, 64 x 0 -, 255 ºC. Cyclohexane 2. Hexamethyleneimine.,4-Diaminobutane 4. Pentamethylenediamine 5.,2-Diaminocyclohexane 6.,5-Diamino-2-Methylpentane 7. Aminomethylcyclopentylamine 8. Hexamethylenediamine 9. 6-Aminocapronitrile 0. n-valeramide. Adiponitrile 2. bis-hexamethylenetriamine 84

57 Nitrosamines Column: DM-Wax Amine, 60 m x 0.5 mm x.00 µm Cat. No.: 786 Index: CCR0006 Oven Temp.: 00 ºC (hold min) to 70 ºC at 5 ºC/min Carrier Gas: He, 00 cm/sec Injection: Direct, 200 ºC Sample: Nitrosamines,.0 µg/ml Detector: TSD, 200 ºC Amines / Alcohols / Chlorides Column: DM-Wax, 0 m x 0.5 mm x 0.50 µm Cat. No.: 7547 Index: CCR0007 Oven Temp.: 00 ºC to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 40:, 250 ºC Sample: Mix, 0.5 µl Detector: FID, 28 x 0 - AFS, 250 ºC. Solvent 2. N-Nitrosodimethylamine. N-Nitrosodiethylamine 4. N-Nitrosodiisopropylamine 5. N-Nitrosodipropylamine 6. N-Nitrosodibutylamine 7. N-Nitrosopiperidine 8. N-Nitrosopyrrolidine 9. N-Nitrosomorpholine. n-octyl-n,n-dimethylamine 2. n-octyl chloride. n-decyl-n,n-dimethylamine 4. n-decyl chloride 5. n-octyl alcohol 6. n-dodecyl-n,n-dimethylamine 7. n-dodecyl chloride 8. n-decyl alcohol 9. n-tetradecyl-n,n-dimethylamine 0. n-tetradecyl chloride. n-dodecyl alcohol 2. n-hexadecyl-n,n-dimethylamine. n-hexadecyl chloride 4. n-tetradecyl alcohol 5. n-octadecyl-n,n-dimethylamine 6. n-hexadecyl alcohol 7. n-octadecyl alcohol Amines / Phenols Column: DM-5 Amine, 0 m x 0.2 mm x.00 µm Cat. No.: 787 Index: CCR000 Oven Temp.: 20 ºC to 220 ºC at 0 ºC/min Carrier Gas: H 2, 8 cm/sec, 20 ºC Injection: Split, 25:, 05 ºC Sample: Miscellaneous amines and phenols in water,.0 µl, 22 ng Detector: FID, 6.4 x 0 - AFS, 05 ºC. Diethylamine 2. Pyridine. Morpholine 4. Phenol 5. Aniline 6. 2-Chlorophenol 7. Diethylenetriamine 8. Octylamine 9. -Methyl-2-pyrrolidinone 0. 2-Nitrophenol. 2,6-Dimethylaniline 2. Nicotine. 2-Nitroaniline 85

58 Alcohols. Pentane 2. Hexane. Heptane 4. Ethanol 5. Decane 6. -Propanol 7. -Butanol 8. Dodecane 9. -Pentanol 0. -Hexanol. Tetradecane 2. -Heptanol. -Octanol 4. Hexadecane 5. -Nonanol 6. -Decanol 7. -Undecanol 8. -Dodecanol Alcohols Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR00288 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 5 cm/sec, 50 ºC Injection: Split, 8:, 250 ºC Sample: Alcohols,.0 µl Detector: MS, 250 ºC Ionization EI. Pentane 2. Methanol. 2-Methyl-2-propanol (tert-butylalcohol) 4. 2-Methyl--buten-2-ol 5. -Buten-2-ol 6. Undecane 7. 2,2-Dimethyl--propanol (Neopentanol) 8. -Penten--ol 9. 2-Methoxyethanol 0. 2,2,2-Trifluoroethanol. 2-Ethoxyethanol 2. -Pentanol. 2-Methyl--pentanol 4. 2,2-Dimethyl--pentanol 5 Tetradecane 6. trans-2-hexen--ol 7. -Octanol 8. Ethylene glycol 9. -Undecanol 20.,4-Butanediol Alcohols Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: Index: CCR00495 Oven Temp.: 00 ºC to 240 ºC (hold 0 min) at 5 ºC/min Carrier Gas: He, cm/sec, 00 ºC Head Pressure: 8.0 psi Column Flow Rate:. cc/min, 00 ºC Injection: Split, 70:, 250 ºC Sample: Alcohols,.0 µl Detector: FID, 270 ºC. Methanol 2. Ethanol. 2-Propanol 4. -Propanol 5. tert-butanol 6. 2-Butanol 7. Isobutyl alcohol 8. -Butanol 9. 2-Methyl-2-butanol 0. -Methyl--butanol. 4-Methyl-2-pentanol 86

59 Glycols Column: DM-Wax, 0 m x 0.5 mm x.00 µm Cat. No.: 755 Index: CER00476 Oven Temp.: 80 ºC to 200 ºC (hold 0 min) at 8 ºC/min Solvent: H 2 O:MeOH = 50:50 septa purge 5.0 cc/min Carrier Gas: He, 50 cm/sec Injection: Direct Flow Rate: 6.9 ml/min Sample: Glycol mix,.0 µl, 50 ppm Detector: FID, 270 ºC.,2-Propylene glycol 2. Ethylene glycol.,-butylene glycol 4.,-Propylene glycol 5.,4-Butylene glycol 6. Diethylene glycol 7. Glycerol Alcohols Column: DM-5, 60 m x 0.2 mm x.00 µm Cat. No.: 726 Index: CCR00292 Oven Temp.: 25 ºC (hold 4 min) to 80 ºC (hold 5 min) at 8 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 40:, 200 ºC Sample: Alcohol mix, 0.0 µl Detector: FID, 28 x 0 - AFS, 200 ºC. Methanol 7. 2-Methyl--propanol 2. Ethanol 8. -Butanol. Acetone 9. -Pentanol 4. Isopropanol 0. -Methyl--butanol 5. -Propanol. 2-Methyl--butanol 6. Ethyl acetate Glycols Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CCR0026 Oven Temp.: 40 ºC to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 9:, 200 ºC Sample: Glycols,.0 µl, 50 ng on-column Detector: FID, 6.4 x 0 - AFS, 250 ºC Glycols / Alcohols Column: DM-5, 0 m x 0.5 mm x.00 µm Cat. No.: 7249 Index: CCR0027 Oven Temp.: 40 ºC to 85 ºC (hold 5 min) at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Direct, 50 ºC Sample: Glycols and alcohols,.0 µl, 00 ppm Detector: FID, 8 x 0 - AFS, 200 ºC. Ethylene glycol 2. Propylene glycol. Diethylene glycol 4. Tetraethylene glycol. n-butyl alcohol 2. Ethylene glycol. Propylene glycol 4. Butyl cellosolve 5. Butyl carbitol 87

60 Aldehydes / Ketones Alcohols / Aldehydes Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR00295 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 50 cm/sec, 50 ºC Injection: Split, 7:, 250 ºC Sample: Alcohols and aldehydes,.0 µl Detector: FID, 285 ºC Ionization: EI, scan 0, range 00. Pentane 2. Heptane. Acetaldehyde 4. Dimethoxymethane 5. Butyraldehyde 6. -Pentanol 7. -Penten--ol 8. -Octanol 9. Cyclohexanol 0. Furfural. Pentadecane 2. Benzaldehyde. Ethylene glycol + 2-Methyl-2,4-pentanediol 4. Furfuryl alcohol 5. Nonadecane 6.,4-Butanediol 7. Diethylene glycol Aldehydes Column: DM-InertWax, 0 m x 0.25 mm x 0.50 µm Cat. No.: 852 Index: CCR0000 Oven Temp.: 40 ºC (hold 5 min) to 200 ºC at 0 ºC/min Carrier Gas: H 2, 5 cm/sec, 40 ºC Injection: Split, 00:, 200 ºC Sample: C2-C Aldehydes mix, 250 ng on-column Detector: FID, 82 x 0 - AFS, 200 ºC. Ethanal 2. Propanal. Butenal 4. Pentanal 5. Hexanal 6. Heptanal 7. Octanal 8. Nonanal 9. Decanal 0. Undecanal 88

61 Aldehydes / Ketones Formaldehyde Column: DM-70, 60 m x 0.25 mm x. µm Cat. No.: 724 Index: CCR00 Oven Temp.: 40 ºC constant Carrier Gas: He, 20 cm/sec Injection: Split, 0 ml/min, 50 ºC Sample: Formaldehyde, 0.5 µl Detector: TCD, 8 mv, 75 ºC Ketones Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR006 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 5 cm/sec, 50 ºC Injection: Split, 8:, 250 ºC Sample: Ketones,.0 µl Detector: MSD, 250 ºC Ionization: EI. Air 2. Water. Formaldehyde 4. Acetaldehyde 5. Methanol. 2,4-Dimethyl--pentanone 2. 4-Methyl-2-pentanone. 4-Heptanone 4. 4-Methyl--penten-2-one 5. 5-Methyl-2-hexanone 6. 5-Methyl--heptanone 7. 4-Hexen--one 8. -Pentanol 9. 4-Hydroxy-4-methyl-2-pentanone 0. Butyrolactone. Nonadecane Aldehydes Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR005 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 5 cm/sec, 50 ºC Injection: Split, 8:, 250 ºC Sample: Aldehydes,.0 µl Detector: MSD, 250 ºC Ionization: EI. Pentane 2. Acetaldehyde. Dimethoxymethane 4. Propanal 5. 2-Methyl propanal 6. Methanol 7. Pentanal 8. 2-Butenal 9. Hexanal 0. Undecane. Heptanal 2. -Pentanol. Octanal 4. Tetradecane 5. Nonanal 6. 2-Furancarboxaldehyde 7. Decanal 8. Benzaldehyde 9. -Octanol 89

62 Esters Esters Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR004 Oven Temp.: 45 ºC (hold 0 min) to 250 ºC (hold 20 min) at 2 ºC/min Carrier Gas: He, 50 cm/sec, 50 ºC Injection: Split, 7:, 250 ºC Sample: Esters,.0 µl Detector: MS, 285 ºC. Pentane 2. Heptane. Methyl formate 4. Methyl acetate 5. Methyl propionate 6. Methyl butyrate 7. Methyl valerate 8. Methyl hexanoate 9. Methyl octanoate 0. Pentadecane. Methyl decanoate 2. Methyl benzoate. Nonadecane Esters Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR008 Oven Temp.: 40 ºC (hold 0 min) to 245 ºC (hold 20 min) at 4 ºC/min Carrier Gas: He, 50 cm/sec, 50 ºC Injection: Split, 7:, 250 ºC Sample: Esters,.0 µl Detector: MS, 280 ºC. Tetrahydro-2-methyl furan 2. Butyraldehyde. Butyl ether 4.,-Dioxolane 5. Ethyl acrylate 6.,4-Dioxane 7. 2-Methoxy ethyl ether 8. 2-Ethoxy ethyl ether 9. Pentadecane 0.,2-bis(2-Methoxyethoxy)ethane. Nonadecane 2. bis(2-(2-methoxyethoxy)ethyl)ether. Benzyl ether 90

63 Cinnamene / Silylating Agent Acrylic Esters Column: DM-70, 0 m x 0.2 mm x.00 µm Cat. No.: 7 Index: CCR002 Oven Temp.: 70 ºC (hold 0 min) to 20 ºC at 5 ºC/min to 250 ºC at 5 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 56:, 250 ºC Sample: Acrylic esters, 0.5 µl Detector: FID, 4 x 0 - AFS, 250 ºC Silanes Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CCR0062 Oven Temp.: 40 ºC to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 40 ml/min, 200 ºC Sample: Silanes, 0.5 µl Detector: FID,.02 x 0-9 AFS, 270 ºC. Butyl alcohol 2. Methacrylate. Butyl acetate 4. Isopropyl methacrylate 5. n-butyl ether 6. Isobutyl isobutyrate 7. Isobutyl methacrylate 8. Methacrylic acid n-butyl ester 9. n-butyl methacrylate 0. Butylbutyrate. Hydroxybutanoic acid n-butyl ester. Dimethylchlorosilane 2. Methyldichlorosilane. Trimethylchlorosilane 4. Methyltrichlorosilane 5. Dimethyldichlorosilane Styrene Impurities Column: DM-Wax, 0 m x 0.5 mm x 0.50 µm Cat. No.: 7547 Index: CCR0056 Oven Temp.: 40 ºC (hold 0 min) to 50 ºC (hold 5 min) at 0 ºC/min Carrier Gas: He, 20 cm/sec, 40 ºC Injection: Split, 40 cc/min, 50 ºC Sample: 95% Styrene, 0.5 ml Detector: FID, 6 x 0 - AFS, 50 ºC Styrene Impurities Column: DM-70, 0 m x 0.5 mm x.00 µm Cat. No.: 755 Index: CCR0057 Oven Temp.: 40 ºC (hold 0 min) to 50 ºC (hold 5 min) at 2 ºC/min Carrier Gas: He, 20 cm/sec, 40 ºC Injection: Split, 40 cc/min, 50 ºC Sample: 95% Styrene, 0.5 ml Detector: FID, 6 x 0 - AFS, 50 ºC. Butene 2.,-Butadiene. Diethylhydroxylamine 4. Acrylonitrile 5. Vinylcyclohexene 6. Toluene 7. Ethylbenzene 8. m-xylene 9. Cumene 0. o-xylene. Styrene.,-Butadiene 2. Butene. Acrylonitrile 4. Diethylhydroxylamine 5. Toluene 6. Vinylcyclohexene 7. Ethylbenzene 8. m-xylene 9. o-xylene 0. Styrene. Cumene 9

64 Solvents USP Solvents Column: DM-, 60 m x 0.5 mm x.00 µm Cat. No.: 756 Index: CER0046 Oven Temp.: 5 ºC (hold 4min) to 250 ºC at 4 ºC/min septa purge 5 ml/min Carrier Gas: He, 45.6 cm/sec, 5 ºC Head Pressure:.0 psi constant pressune Injection: Split, 00 ml/min, ~:, 250 ºC Sample: Solvents, ~.% each Detector: MS Scan Range: 0 AMU AMU. Formaldehyde 2. Water. Chloromethane 4. Methanol 5. Acetaldehyde 6. Ethylene oxide 7. Chloroethane 8. Ethanol 9. Acetonitrile 0. Acetone. 2-Propanol 2. 2-Chloropropane. Diethyl ether 4. Pentane 5. Ethyl formate 6. Formic acid 7. Methylal 8.,-Dichloroethene 9. Methyl acetate 20. Methylene chloride 2. Nitromethane 22. -Propanol 2. trans-,2-dichloroethene 24. Methyl tert-butyl ether Methylpentane (spiked at 9%) Butanone Butanol 28. cis-,2-dichloroethene 29. Acetic acid 0. Isopropyl ether. Ethyl acetate 2. Hexane. Chloroform 4. Tetrahydrofuran 5. 2-Methoxyethanol 6.,2-Dichloroethane 7. Methyl cyclopentane 8.,,-Trichloroethane 9.,2-Dimethoxyethane 40. Methyl isopropyl ketone 4. 2,2-Dimethoxypropane 42. Isopropyl acetate 4. -Butanol 44. Benzene 45. Carbon tetrachloride 46. Ethylene glycol 47. Formamide 48.,4-Dioxane 49. Trichloroethylene 50. Isooctane 5. 2-Ethoxyethanol 52. n-heptane 5. Isoamyl alcohol 54. Hexanone 55. Pyridine 56. Methyl cyclohexane 57. Dimethyl formamide 58.,,2-Trichloroethane 59. -Pentanol 60. Isobutyl acetate 6. Toluene Hexanone 6. Dimethyl sulfoxide 64. Butyl acetate 65.,-Diethoxypropane 66. N,N-Dimethylacetamide 67. Chlorobenzene 68. Ethylbenzene 69. Isoamyl acetate 70. p-xylene 7. m-xylene 72. o-xylene 7. Anisole 74. Isopropyl benzene (Cumene) 75. -Methyl-2-pyrrolidinone 76. Sulfolane 77.,2,,4-Tetrahydronaphthalene USP Solvents Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CER00464 Oven Temp.: 5 ºC (hold 4 min) to 250 ºC at 4 ºC/min Head Pressure:.0 psi constant pressure Carrier Gas: He, 45.6 cm/sec, 5 ºC Injection: Split, 00 ml/min, :, 250 ºC Sample: Solvents, ~.% each Detector: MS Scan Range: 0 AMU AMU 92

65 Solvents Solvents Mixture # Column: DM-, 60 m x 0.5 mm x.00 µm Cat. No.: 756 Index: CCR005 Oven Temp.: 40 ºC (hold 5 min) to 285 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS full scan, 285 ºC. Pentane 2. Methylene chloride. Ethylene glycol 4. Heptane 5. Cyclopentanol 6. -Hexanol 7. Acetamide 8. 2-Methyl--pentanol 9. Furfuryl alcohol 0. Butyl ether. Nonane 2. Cume ne. Ethyl amyl ketone 4. Heptanol 5. Butyl butanoate Benzyl alcohol 8. Dipropylene glycol 9. Diethylbenzene Hexachloroethane 2. Undecane 24. -Nonanol 25. p-methoxyphenol 26. Triethylene glycol 27. Dodecane 28. Undecanal 29. Tridecane Dodecanal 2. Dicyclohexylamine. bis(2,2-methoxy)ethyl ether 4. Pentadecane 5. Heptadecane 6. Octadecane 7. Nonadecane 8. Eicosane 9. Acetyl tributyl citrate Buten--ol 4. Formamide 42. -Pentanol 4. -Nitropropane 44. Dimethyl formamide Methyl--pentanol 46. Toluene 47. Ethyl chloroacetate 48. Dimethylacetamide 49. p-xylene 50. sec-tetrachloroethane 5. Benzaldehyde 52. o-chlorotoluene 5. 2,6-Dimethyl-4-heptanone Octanone 55. o-cresol 56. α-methylbenzyl alcohol Nonanone 58. Nonanal 59. Decanal Decanol 62. -Undecanol 6. 2-Dodecanone 64. -Dodecanol 65. Tetraethylene glycol 66. Dibenzyl 67. Diethyl phthalate 68. Tributyl phosphate 69. Diphenyl sulfone 70. Allyl alcohol Isopropyl acetate 7. Benzene Nitropropane 75. Nitroethane 76. Pentanal Bromobutane 78. -Chloropentane 79. Cyclopentanone Hexanol 8. Butyl acetate Ethyl--butanol 8. -Ethyl--pentanol 84.,4-Dichlorobutane Methyl-2,4-pentanediol 86. Butoxyethanol 87.,2,-Trichloropropane 88.,4-Butanediol 89. Methyl hexanoate 90.,2,4-Trimethylbenzene 9. 2-Ethyl--hexanol 92. Dipentene 9. Tetrahydrofurfuryl acetate Decahydronaphthalene Decanol 99.,2-bis(2-Methoxyethoxy)ethane Phenoxyethanol Benzyl ether 9

66 Solvents Solvents Mixture # Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CCR006 Oven Temp.: 40 ºC (hold 5 min) to 285 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS, TIC mode, 285 ºC See the Previous Page Solvents Mixture # Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR007 Oven Temp.: 40 ºC (hold 5 min) to 250 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS full scan, 285 ºC See the Previous Page 94

67 Solvents Solvents Mixture #2 Column: DM-, 60 m x 0.5 mm x.00 µm Cat. No.: 756 Index: CCR008 Oven Temp.: 40 ºC (hold 5 min) to 250 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #2,.0 µl Detector: MS full scan, 285 ºC. Pentane 2. Methylene chloride. Ethylene glycol 4. Heptane 5. Cyclopentanol 6. -Hexanol 7. Acetamide 8. 2-Methyl--pentanol 9. Furfuryl alcohol 0. Butyl ether. Nonane 2. Cume ne. Ethyl amyl ketone 4. Heptanol 5. Butyl butanoate Benzyl alcohol 8. Dipropylene glycol 9. Diethylbenzene Hexachloroethane 2. Undecane 24. -Nonanol 25. p-methoxyphenol 26. Triethylene glycol 27. Dodecane 28. Undecanal 29. Tridecane Dodecanal 2. Dicyclohexylamine. bis(2,2-methoxy)ethyl ether 4. Pentadecane 5. Heptadecane 6. Octadecane 7. Nonadecane 8. Eicosane 9. Acetyl tributyl citrate Buten--ol 4. Formamide 42. -Pentanol 4. -Nitropropane 44. Dimethyl formamide Methyl--pentanol 46. Toluene 47. Ethyl chloroacetate 48. Dimethylacetamide 49. p-xylene 50. sec-tetrachloroethane 5. Benzaldehyde 52. o-chlorotoluene 5. 2,6-Dimethyl-4-heptanone Octanone 55. o-cresol 56. α-methylbenzyl alcohol Nonanone 58. Nonanal 59. Decanal Decanol 62. -Undecanol 6. 2-Dodecanone 64. -Dodecanol 65. Tetraethylene glycol 66. Dibenzyl 67. Diethyl phthalate 68. Tributyl phosphate 69. Diphenyl sulfone 70. Allyl alcohol Isopropyl acetate 7. Benzene Nitropropane 75. Nitroethane 76. Pentanal Bromobutane 78. -Chloropentane 79. Cyclopentanone Hexanol 8. Butyl acetate Ethyl--butanol 8. -Ethyl--pentanol 84.,4-Dichlorobutane Methyl-2,4-pentanediol 86. Butoxyethanol 87.,2,-Trichloropropane 88.,4-Butanediol 89. Methyl hexanoate 90.,2,4-Trimethylbenzene 9. 2-Ethyl--hexanol 92. Dipentene 9. Tetrahydrofurfuryl acetate Decahydronaphthalene Decanol 99.,2-bis(2-Methoxyethoxy)ethane Phenoxyethanol Benzyl ether 95

68 Solvents Solvents Mixture #2 Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CCR009 Oven Temp.: 40 ºC (hold 5 min) to 285 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #2,.0 µl Detector: MS full scan, 285 ºC See the previous page Solvents Mixture #2 Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR0040 Oven Temp.: 40 ºC (hold 5 min) to 250 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #2,.0 µl Detector: MS full scan, 285 ºC See the previous page 96

69 Solvents Solvents Mixture # Column: DM-, 60 m x 0.5 mm x.00 µm Cat. No.: 756 Index: CCR004 Oven Temp.: 40 ºC (hold 5 min) to 285 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS full scan, 285 ºC. Pentane 2. Methylene chloride. Ethylene glycol 4. Heptane 5. Cyclopentanol 6. -Hexanol 7. Acetamide 8. 2-Methyl--pentanol 9. Furfuryl alcohol 0. Butyl ether. Nonane 2. Cume ne. Ethyl amyl ketone 4. Heptanol 5. Butyl butanoate Benzyl alcohol 8. Dipropylene glycol 9. Diethylbenzene Hexachloroethane 2. Undecane 24. -Nonanol 25. p-methoxyphenol 26. Triethylene glycol 27. Dodecane 28. Undecanal 29. Tridecane Dodecanal 2. Dicyclohexylamine. bis(2,2-methoxy)ethyl ether 4. Pentadecane 5. Heptadecane 6. Octadecane 7. Nonadecane 8. Eicosane 9. Acetyl tributyl citrate Buten--ol 4. Formamide 42. -Pentanol 4. -Nitropropane 44. Dimethyl formamide Methyl--pentanol 46. Toluene 47. Ethyl chloroacetate 48. Dimethylacetamide 49. p-xylene 50. sec-tetrachloroethane 5. Benzaldehyde 52. o-chlorotoluene 5. 2,6-Dimethyl-4-heptanone Octanone 55. o-cresol 56. α-methylbenzyl alcohol Nonanone 58. Nonanal 59. Decanal Decanol 62. -Undecanol 6. 2-Dodecanone 64. -Dodecanol 65. Tetraethylene glycol 66. Dibenzyl 67. Diethyl phthalate 68. Tributyl phosphate 69. Diphenyl sulfone 70. Allyl alcohol Isopropyl acetate 7. Benzene Nitropropane 75. Nitroethane 76. Pentanal Bromobutane 78. -Chloropentane 79. Cyclopentanone Hexanol 8. Butyl acetate Ethyl--butanol 8. -Ethyl--pentanol 84.,4-Dichlorobutane Methyl-2,4-pentanediol 86. Butoxyethanol 87.,2,-Trichloropropane 88.,4-Butanediol 89. Methyl hexanoate 90.,2,4-Trimethylbenzene 9. 2-Ethyl--hexanol 92. Dipentene 9. Tetrahydrofurfuryl acetate Decahydronaphthalene Decanol 99.,2-bis(2-Methoxyethoxy)ethane Phenoxyethanol Benzyl ether 97

70 Solvents Solvents Mixture # Column: DM-200, 60 m x 0.5 mm x.00 µm Cat. No.: 856 Index: CCR0042 Oven Temp.: 40 ºC (hold 5 min) to 285 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS full scan, 285 ºC See the previous page Solvents Mixture # Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CCR004 Oven Temp.: 40 ºC (hold 5 min) to 250 ºC at 5 ºC/min Carrier Gas: He, 40 cm/sec Injection: Split, 50 ml/min, 275 ºC Sample: Solvents mixture #,.0 µl Detector: MS full scan, 285 ºC See the previous page 98

71 Solvents Polar Solvents Column: DM-PLOT U, 0 m x 0.2 mm x 0.00 µm Cat. No.: 8824 Index: CSR0082 Oven Temp.: 50 ºC constant Carrier Gas: H 2 Injection: Split, 20:, 200 ºC Sample: 50 ppm (w / v) each in He, 20 µl Detector: FID, 200 ºC Polar Solvents Column: DM-PLOT Q, 0 m x 0.2 mm x 0.00 µm Cat. No.: 888 Index: CSR008 Oven Temp.: 50 ºC constant Carrier Gas: H 2 Injection: Split, 20:, 200 ºC Sample: 50 ppm (w / v) each in He, 20 µl Detector: FID, 200 ºC. Methane 2. Methanol. Ethanol 4. n-pentane 5. Acetone 6. n-hexane 7. Ethyl acetate. Methane 2. Methanol. Ethanol 4. Acetone 5. n-pentane 6. Ethyl acetate 7. n-hexane Solvents Column: DM-5, 60 m x 0.2 mm x.00 µm Cat. No.: 7242 Index: CCR0046 Oven Temp.: 50 ºC (hold 4 min) to 20 ºC (hold 20 min) at 5 ºC/min Carrier Gas: H 2, 40 cm/sec, 50 ºC Injection: Split, 00 ºC Sample: in CS2 solvent,.0 µl Detector: FID, 28 x 0-2 AFS, 00 ºC. Acetone 2. Acrylonitrile. Carbon disulfide impurity 4. Hexane 5. Methyl ethyl ketone 6. Ethyl acetate 7. Methyl cellosolve 8. Tetrahydrofuran 9. n-butyl alcohol 0. Isopropyl acetate. Heptane 2. n-propyl acetate. Amyl alcohol 4. Toluene 5. n-butyl acetate 6. n-butyl acrylate 7. Cellosolve acetate 8. Cyclohexanone 99

72 Food Fatty Acids (Free) Column: DM-, 0 m x 0.5 mm x 5.00 µm Cat. No.: 757 Index: CCR0028 Oven Temp.: 60 ºC to 80 ºC at 5 ºC/min Carrier Gas: H 2, 50 cm/sec Injection: Direct, 250 ºC Sample: Fatty acids (free), 0.2 µl, 0-20 ng/µl Detector: FID, 4 x 0 - AFS, 250 ºC Fatty Acids (Free) Column: DM-FFAP, 0 m x 0.25 mm x 0.25 µm Cat. No.: 762 Index: CCR00280 Oven Temp.: 45 ºC, constant Carrier Gas: H 2, 40 cm/sec Injection: Split, 50:, 250 ºC Sample: Fatty acids (free),.0 µl, 0-20 ng/µl Detector: FID, 2 x 0 - AFS, 250 ºC. Acetic acid 2. Propionic acid. Isobutyric acid 4. n-butyric acid 5. Isovaleric acid 6. n-valeric acid 7. Isocaproic acid 8. Caproic acid 9. Heptanoic acid. Acetic acid 2. Propionic acid. Isobutyric acid 4. n-butyric acid 5. Isovaleric acid 6. n-valeric acid 7. Isocaproic acid 8. Caproic acid 9. Heptanoic acid Fatty Acids (Free) Column: DM-FFAP, 0 m x 0.2 mm x 0.25 µm Cat. No.: 76 Index: Oven Temp.: Carrier Gas: H 2 CFR ºC to 250ºC (hold 5 min) at 0ºC/min Injection: Splitless, 0.25 min, 250 ºC Sample: Free fatty acid mix,.0 µl Flow Rate: Make up gas: Solvent: 6.0 ml/min 75 ml/min H 2 O Concentration: 5 mg/ml in MeOH Detector: FID, 250 ºC. C4:0 (butyric acid) 2. C6:0 (caproic acid). C8:0 (caprylic acid) 4. C0:0 (capric acid) 5. C2:0 (lauric acid) 6. C4:0 (myristic acid) 7. C6:0 (palmitic acid) 8. C8:0 (stearic acid) 9. C8: (oleic acid) 0. C8:2 (linoleic acid). C8: (linolenic acid) 2. C20:0 (arachidic acid). C22:0 (behenic acid) FAMEs (cis / trans Isomers) Column: DM-2560, 00 m x 0.25 mm x µm Cat. No.: 8858 Index: Sample: CFR mg/ml cis / trans FAMEs mix in methylene chloride Injection: Split, 20:, µl, 225 ºC Oven Temp.: 00 ºC (hold 4 min) to 240 ºC (hold 0 min) at ºC/min Carrier Gas: H 2,.2 ml/min Detector: FID, 250 ºC. C8:0 (methyl stearate) 2. C8: (methyl petroselaidate (trans-6)). C8: (methyl elaidate (trans-9)) 4. C8: (methyl transvaccenate (trans-)) 5. C8: (methyl petroselinate (cis-6)) 6. C8: (methyl oleate (cis-9)) 7. C8: (methyl vaccenate (cis-)) 8. C8:2 (methyl linoleate (cis-9,2)) 200

73 Food PUFA (Animal Source) Column: DM-20, 0 m x 0.2 mm x µm Cat. No.: 86 Index: CFR009 Oven Temp.: 60 ºC to 250 ºC (hold 0 min) at 2 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 260 ºC Sample: PUFA (animal source) mix, 0. µl Detector: FID, 8 x 0 - AFS, 260 ºC FAMEs Column: DM-InertWax, 0 m x 0.25 mm x 0.25 µm Cat. No.: 852 Index: CFR0058 Oven Temp.: 20 ºC (hold min) to 220 ºC (hold 2 min) at 20 ºC/min Carrier Gas: He, 4 cm/sec, ml/min Injection: Split, 00:, 250 ºC Sample: Saw palmetto,.0 µl Detector: FID, 00 ºC. C4:0 2. C6:0. C6:n7 4. C8:0 5. C8:n9 6. C8:n7 7. C8:2n6 8. C8:n6 9. C8:n 0. C20:n6. C20:4n6 2. C20:5n. C22:4n6 4. C22:5n 5. C22:6n. C6:0 (methyl caproate) 2. C8:0 (methyl caprylate). C9:0 (methyl nonanoate) 4. C0:0 (methyl caprate) 5. C2:0 (methyl laurate) 6. C4:0 (methyl myristate) 7. C6:0 (methyl palmitate) 8. C6: (methyl palmitoleate) 9. C8:0 (methyl stearate) 0. C8: (methyl oleate). C8:2 (methyl linoleate) 2. C8: (methyl linolenate) PUFA (Animal Source) Column: DM-Wax, 0 m x 0.25 mm x 0.25 µm Cat. No.: 752 Index: CFR007 Oven Temp.: 60 ºC to 250 ºC (hold 0 min) at 2 ºC/min Carrier Gas: H 2, 40 cm/sec Injection: Split, 20:, 260 ºC Sample: PUFA mix, 0. µl Detector: FID, 8 x 0 - AFS, 260 ºC. C4:0 2. C6:0. C6:n7 4. C8:0 5. C8:n9 6. C8:n7 7. C8:2n6 8. C8:n 9. C8:4n 0. C20:n9. C20:2n6 2. C20:n6. C20:4n6 4. C20:5n 5. C22:4n6 6. C22:5n 7. C22:6n 8. C24:n9 20

74 Food FAMEs (Flax Seed Oil) Column: DM-FAMEWAX, 0 m x 0.25 mm x 0.25 µm Cat. No.: 78 Index: CFR0064 Oven Temp.: 65 ºC (hold 0 min) to 220 ºC (hold 5 min) at.5 ºC/min Carrier Gas: He, 40 cm/sec Injection Temp.: 225 ºC Detector: FID, 20 ºC FAMEs (Black Currant Seed Oil) Column: DM-FAMEWAX, 0 m x 0.25 mm x 0.25 µm Cat. No.: 78 Index: CFR0065 Oven Temp.: 65 ºC (hold 0 min) to 220 ºC (hold 5 min) at.5 ºC/min Carrier Gas: He, 40 cm/sec Injection Temp.: 225 ºC Detector: FID, 20 ºC. C6:0 2. C8:0. C8:n9 4. C8:2n6 5. C8:n6 6. C8:n. C6:0 2. C8:0. C8:n9 4. C8:2n6 5. C8:n6 6. C8:n FAMEs (Marine Oil Standard) Column: DM-FAMEWAX, 0 m x 0.2 mm x 0.25 µm Cat. No.: 78 Index: CFR00568 Oven Temp.: 95 ºC to 240 ºC (hold min) at 5 ºC/min Carrier Gas: H 2, 62 cm/sec Injection: Split, 50:, mm ID split liner, 250 ºC Sample: 2 mg/ml total FAMEs, 0.5 µl Detector: FID, 250 ºC. C4:0 2. C5:0. C6:0 4. C6: 5. C6:2 6. C7:0 7. C7: 8. C6:4 9. C8:0 0. C8: (oleate). C8: (vaccenate) 2. C8:2n6cis. C8:n 4. C8:4n6 5. C8:4n 6. C20:0 7. C20:n7 8. C20:n9 9. C20:4n6 20. C20:4n 2. C20:5n 22. C22:n7 2. C2:5n 24. C2:0 (IS) 25. C22:5n6 26. C22:5n 27. C22:6n 28. C24: 202

75 Food Flavor Volatiles Column: DM-, 60 m x 0.2 mm x 0.50 µm Cat. No.: 748 Index: CFR Acetone Oven Temp.: 70 ºC (hold 5 min) to 90 ºC (hold 5 min) at 2 ºC/min Carrier Gas: He, 20 cm/sec, 70 ºC Injection: Split, 20:, 220 ºC Sample: Flavor volatiles mix, 0.8 µl Detector: FID, 64 x 0 - AFS, 260 ºC. Methanol 2. Acetaldehyde. Ethanol 5. Isopropyl alcohol 6. Methylene chloride 7. Hexane 8. Ethyl acetate 9. Ethyl propionate 0. n-hexanal. Ethyl butyrate 2. Furfural. trans-2-hexenal 4. α-thujene 5. α-pinene 6. Camphene 7. Sabinene 8. b-pinene 9. Octanal 20. Myrcene 2. α-phellandrene 22. α-terpinene 2. p-cymene 24. d-limonene 25. g-terpinene 26. Octanol 27. Terpinolene 28. Nonanal 29. Linalool 0. cis-limonene monoxide. trans-limonene monoxide 2. Citronellal. Terpinene-4-ol 4. α-terpineol 5. Decanal 6. d / l Carveol 7. Neral 8. Carvone 9. Geranial 40. Neryl acetate 4. Geranyl acetate 42. α-ionone 4. b-caryophyllene 44. trans-α-bergamotene 45. BHA 46. b-ionone 47. Valencene 48. g-elemene 49. b-bisabolene 50. Nootketone Flavor Volatiles Column: DM-Wax, 60 m x 0.5 mm x.00 µm Cat. No.: 7552 Index: CFR0057 Oven Temp.: 70 ºC (hold 5 min) to 90 ºC (hold 5 min) at 2 ºC/min Carrier Gas: He, 20 cm/sec, 70 ºC Injection: Split, 20:, 220 ºC Sample: Flavor volatiles mix, 0.8 µl Detector: FID, 64 X 0 - AFS, 260 ºC. Hexane 2. Acetaldehyde. Acetone 4. Methanol 5. Ethyl acetate 6. Isopropyl alcohol 7. Ethanol 8. Methylene chloride 9. Ethyl propionate 0. α-pinene. Ethyl butyrate 2. n-hexanal. b-pinene 4. Sabinene 5. Myrcene 6. d-limonene 7.,8-Cineole 8. trans-2-hexenal 9. g-terpinene 20. p-cymene 2. Terpinolene 22. Octanal 2. Nonanal 24. cis-limonene monoxide 25. trans-limonene 26. Furfural 27. Citronellal 28. Decanal 29. Linalool 0. Octanol. trans-α-bergamotene 2. b-caryophyllene. Terpinene-4-ol 4. Neral 5. α-terpineol 6. Neryl acetate 7. Valencene 8. Geranial 9. Carvone 40. Geranyl acetate 4. d / l Carveol 42. α-ionone 4. d / l Carveol 44. b-ionone 20

76 Food Concentrated Liquors Column: DM-Wax, 0 m 0.25 mm 0.25 µm Cat. No.: 752 Index: CFO000 Oven Temp.: 7 ºC (hold 2 min) to 70 ºC at ºC/min Carrier Gas: 70 ºC (hold min) to 0 ºC at 6 ºC/min 0 ºC to 220 ºC at 0 ºC/min to 220 ºC (hold 0 min) High purity nitrogen, ml/min Injection: 260 ºC, Split ratio 0: Detector: FID, 260 ºC. Acetaldehyde 2. Propanal. Isobutanal 4. Acetone 5. Ethyl formate Ethyl acetate + Acetal 0. Methanol. 2-Butanone 2. 2-Methyl butyraldehyde. -Methyl butyraldehyde 4. Ethanol 5. Ethyl propionate 6. Ethyl isobutyrate 7. 2-Ethoxy butane 8. 2-Pentanone 9. sec-butyl alcohol 20. Ethyl butyrate 2. n-propanol Ethyl isovalerate 26. Diethoxy isopentane 27. Diethoxy--methylbutane Isobutyl alcohol 0. Isoamyl acetate. sec-pentanol 2. Ethyl valerate. n-butanol Isoamyl alcohol Ethyl caproate n-pentanol 4. Acetoin Propyl hexanoate Heptanol 45. Ethyl heptanoate 46. Ethyl lactate 47. n-hexanol 48. Butyl hexanoate 49. Ethyl octanoate Acetic acid 52. Furfural Benzaldehyde 56. Ethyl nonanoate 57. Propionic acid 58. L-2,-Butanediol 59. Capryl alcohol 60. Isobutyric acid 6. meso-2,-butanediol 62. Hexyl hexanoate 6. Ethyl caprate 64. n-butanoic acid 65. Isovaleric acid 66. Valeric acid n-hexanoic acid 69. Benzenepropanoic acid ethyl ester 70. b-phenethyl alcohol 7. Heptanoic acid Ethyl myristate Octylic acid Ethyl palmitate Ethyl oleate 86. Ethyl linoleate Alcoholic Standard: Acids and Esters Column: DM-FFAP, 50 m x 0.25 mm x 0.25 µm Cat. No.: 7672 Index: CFR00500 Oven Temp.: 70 ºC to 240 ºC (hold min) at 2 ºC/min Carrier Gas: H 2, 28 psi, 240 ºC Injection: Splitless,.0 µl, constant 0.5 min, 240 ºC Detector: FID. Ethyl octanoate 2. Acetic acid. Propionic acid 4. Isobutyric acid 5. -Decanol 6. Ethyl decanoate 7. Ethyl laurate 8. cis-lactone 9. 2-Phenylethanol 0. trans-lactone. Methyl myristate 2. Ethyl myristate. Octanoic acid 4. Ethyl palmitate 5. Decanoic acid 6. Dodecanoic acid 7. Vanillin 204

77 Food Peppermint Oil Column: DM-Wax, 0 m x 0.25 mm x 0.50 µm Cat. No.: 752 Index: CFR004 Oven Temp.: 75 ºC (hold 4 min) to 240 ºC at 4 ºC/min Carrier Gas: H 2, 40 cm/sec, 75 ºC Injection: Split,.0 µl, 50:, 250 ºC Sample: Peppermint oil,.0 µl Detector: FID, 6 x 0 - AFS, 250 ºC. α-pinene 2. β-pinene. Sabinene 4. Myrcene 5. α-terpinene 6. l-limonene 7.,8-Cineole 8. cis-ocimene 9. γ-terpinene 0. p-cymene. Terpinolene 2. -Octanol. -Octen--ol 4. l-menthone 5. trans-sabinenehydrate 6. Menthofuran 7. d-isomenthone 8. β-bourbonene 9. Linalool 20. Menthyl acetate 2. neo-menthol 22. β-caryophyllene 2. Terpinene-4-ol 24. l-menthol 25. Pulegone 26. α-terpineol 27. Germacrene-Δ 28. Piperitone 29. Viridiflorol Citronella Java Oil Column: DM-, 60 m x 0.25 mm x 0.25 µm Cat. No.: 722 Index: CFR0044 Oven Temp.: 00 ºC to 260 ºC (hold min) at 4 ºC/min Carrier Gas: He, 0 cm/sec, 50 ºC Injection: Split, 00 cc/min, 250 ºC Sample: Citronella java oil,.0 µl Detector: MS, 280 ºC. Limonene 2. Citronellal. Linalool 4. Borneol 5. g-elemene 6. b-caryophyllene 7. Neryl acetate 8. α-terpineol 9. Germacrene-Δ 0. b-citronellol. Geranyl acetate 2. d-cadenene. Nerol 4. Geraniol 5. Eugenol 6. α-bergamotene 205

78 Food Fragrance Column: DM-, 60 m x 0.25 mm x 0.25 µm Cat. No.: 722 Index: CFR00657 Oven Temp.: 50 ºC to 270 ºC at ºC/min Carrier Gas: He Injection: Split, 40:, 285 ºC Flow rate: 0.6 ml/min Sample: 5% FMA mix in acetone,.0 µl Detector: FID, 00 ºC. Ethyl butyrate 2. Limonene. Eucalyptol 4. Benzoic acid 5. Cinnamic aldehyde 6. Geraniol 7. Hydroxycitronellal 8. Thymol 9. Cinnamyl alcohol 0. Vanillin. Cinnamyl acetate 2. Benzyl salicylate Fragrance Column: DM-70, 60 m x 0.25 mm x 0.25 µm Cat. No.: 722 Index: CFR00658 Oven Temp.: 50 ºC to 270 ºC at ºC/min Carrier Gas: He Injection: Split, 40:, 285 ºC Sample: 5% FMA mix in acetone,.0 µl Detector: FID, 00 ºC. Ethyl butyrate 2. Limonene. Eucalyptol 4. Geraniol 5. Benzoic acid 6. Cinnamic aldehyde 7. Hydroxycitronellal 8. Thymol 9. Cinnamyl alcohol 0. Cinnamyl acetate. Vanillin 2. Benzyl salicylate BHA / BHT Food Packaging Volatiles Column: DM-7, 0 m x 0.5 mm x.00 µm Cat. No.: 745 Index: CFR0060 Oven Temp.: 50 ºC to 240 ºC (hold min) at 5 ºC/min Carrier Gas: He, 60 cm/sec, 50 ºC Injection: Direct, 280 ºC Sample: 50 ppm BHA / BHT each in MeOH,.0 µl Detector: FID, 280 ºC Column: DM-5MS, 0 m x 0.25 mm x 0.50 µm Cat. No.: 822 Index: CFR00459 Oven Temp.: 50 ºC to 92 ºC at ºC/min to 220 ºC (hold min) at 20 ºC/min Carrier Gas: He, 6 cm/sec Injection: Purge and trap Desorb Temp.: 220 ºC Detector: MSD, 280 ºC Ionization: EI, 70 ev Scan Range: AMU. Tetrahydrofuran 2. -Butanol. Toluene 4. Hexanal 5. Ethylbenzene 6. 4-Heptanone 7. Butyl ether 8. Styrene 9. -Methylethylbenzene 0. Propylbenzene. Benzaldehyde 2. Benzeneacetaldehyde. Acetophenone 4. Methyl benzoate 5. Decanal. BHA 2. BHT 206

79 Food Neutral Sterols Column: DM-225, 0 m x 0.25 mm x 0.25 µm Cat. No.: 842 Index: CFR004 Oven Temp.: 260 ºC constant Carrier Gas: He, 45 cm/sec, 240 ºC Injection: Split, 0:, 260 ºC Sample: Neutral sterols and phytosterols,.5 µl, 200 ng on-column Detector: FID, 8 x 0 - AFS, 260 ºC Sugars (Alditol Acetates) Column: DM-225, 0 m x 0.25 mm x 0.25 µm Cat. No.: 842 Index: CFR0028 Oven Temp.: 90 ºC (hold 5 min) to 250 ºC (hold 5 min) at 8 ºC/min Carrier Gas: H 2, 42 cm/sec, 40 ºC Injection: Split, 50:, 260 ºC Sample: Alditol acetates derivative, 0.5 µl Detector: FID, 6 x 0 - AFS, 260 ºC. 5-α-Cholestane 2. Coprosterol. Cholesterol 4. Brassicasterol 5. Coprostanone 6. Campesterol 7. Stigmasterol 8. β-sitosterol. Rhamnitol 2. Fucitol. Ribitol 4. Arabinitol 5. Mannitol 6. Galactitol 7. Glucitol 8. Inositol Sugars (Alditol Acetates) Column: DM-20, 0 m x 0.2 mm x µm Cat. No.: 86 Index: CFR0027 Oven Temp.: 75 ºC (hold 2 min) to 240 ºC (hold min) at 8 ºC/min to 265 (hold 2 min) at 8 ºC/min Carrier Gas: He, 80 cm/sec Injection: Split, 20:, 275 ºC Sample: Sugars, 0.6 µl Detector: FID, 2 x 0 - AFS, 275 ºC. Glyceraldehyde 2. Deoxyribitol. Rhamnitol 4. Fucitol 5. Ribitol 6. Arabinitol 7. Xylitol 8. Deoxyglucitol 9. Mannitol 0. Galactitol. Glucitol 2. Inositol. Glucoheptitol 4. n-acetyl galactose amine 5. n-acetyl glucose amine 6. 2-Keto--deoxyoctanate 207

80 Pharmaceutical Basic Drugs (Underivatized) Column: 0 m x 0.25 mm x 0.25 µm Cat. No.: DM-5, #792 DM-5, #722 DM-200, #82 Oven Temp.: 00 ºC to 25 ºC (hold 0 min) at 4 ºC/min Carrier Gas: He, 0 cm/sec, 00 ºC Injection: Split, 50:, 250 ºC Sample: Basic drugs,.0 µl, 000 ng/µl Detector: FID,.28 x 0-0 AFS, 20 ºC DM-5 Index: CPR0026. Nicotine 2. Benzocaine. Cotinine 4. Meperidine 5. Caffeine 6. Benzphetamine 7. Ketamine 8. Diphenhydramine 9. Lidocaine 0. Phenyltoloxamine. Tripelennamine 2. Phenothiazine. Dextromethorphan 4. Methadone 5. Amitriptyline 6. Trimipramine 7. Tetracaine 8. Pyrilamine 9. Medazepam 20. Bupivacaine 2. Scopolamine 22. Codeine 2. Morphine 24. Diazepam 25. Chlorpromazine 26. Temazepam 27. Flunitrazepam 28. Bromazepam 29. Prazepam 0. Acetopromazine. Flurazepam 2. Papaverine. Clonazepam 4. Haloperidol 5. Alprazolam 6. Triazolam 7. Thioridazine 8. Trazodone DM-5 Index: CPR0025 DM-200 Index: CPR

81 Pharmaceutical Acidic / Neutral Drugs (Underivatized) Column: DM-5, 0 m x 0.5 mm x.00 µm Cat. No.: 795 Index: CPR00262 Oven Temp.: 00 ºC to 280 ºC (hold 5 min) at 0 ºC/min Carrier Gas: He, 40 cm/sec, 00 ºC Injection: Splitless, 0.5 min, 250 ºC Sample: Acidic / Neutral drugs,.0 µl, 50 µg/ml Detector: FID, 5.2 x 0-0 AFS, 250 ºC. Ethosuximide 2. Barbital. Methyprylon 4. Aprobarbital 5. Butalbital 6. Amobarbital 7. Pentobarbital 8. Secobarbital 9. Meprobamate 0. Carisoprodal. Glutethimide 2. Phenobarbital. Methaqualone 4. Primidone 5. Carbamazepine 6. Diphenylhydantoin Sympathomimetic Amines Drugs Column: DM-5 Amine, 0 m x 0.25 mm x 0.50 µm Cat. No.: 782 Index: CPR00574 Oven Temp.: 50 ºC to 240 ºC at 7 ºC/min Carrier Gas: He, 0 cm/sec Injection: Split, 250 ºC Sample: Sympathomimetic amines drugs,.0 µl,,000 ng/µl Detector: MS Scan Range: AMU Ionization: EI, scan. Amphetamine 2. Methamphetamine. N-Ethylamphetamine 4. PMA 5. PMMA 6. MDA 7. MDMA 8. MDEA 9. HMMA 0. MBDB Sympathomimetic Amines Drugs Column: DM-5 Amine, 0 m x 0.25 mm x 0.50 µm Cat. No.: 785 Index: CPR0048 Oven Temp.: 00 ºC to 0 ºC at 0 ºC/min Injection: Split, 45 ml/min Detector: MS. Phenylethylamine 2. Amphetamine. Phentermine 4. Methamphetamine 5. Fenfluramine 6. Mephentermine 7. Cathinone 8. Phenylpropanolamine 9. Methcathinone 0. Nicotine. Ephedrine 2. Pseudoephedrine. Phenmetrazine 4. Phendimetrazine 5. Methylenedioxyamphetamine 6. Diethylpropion 7. Methylenedioxymethamphetamine 8. Methylenedioxyethylamphetamine 9. 4-Methyl-2,5-dimethoxyamphetamine 20. Phenylephrine 2. Caffeine 22. Benzphetamine 209

82 Pharmaceutical Steroids, Anabolic Column: DM-5, 0 m x 0.25 mm x 0.0 µm Cat. No.: 729 Index: CPR00255 Oven Temp.: 80 ºC to 40 ºC (hold min) at 0 ºC/min Carrier Gas: He, 5 cm/sec, 80 ºC Injection: Split, 50:, 280 ºC Sample: Anabolic steroids, 0.5 µl,,000 ng/µl Detector: FID,.28 x 0-0 AFS, 40 ºC. 5-Androstene-b,7b-diol 2. 7a-Methyl-5-androstene-b,7b-diol. 5a-Androstan-7b-ol--one 4. 9-Nortestosterone 5. 7α-Methylandrostan-7b-ol--one 6. Mesterolone 7. Testosterone 8. 7a-Methyltestosterone 9. -Dehydrotestosterone 0. -Dehydro-7a-methyltestosterone. Bolasterone 2. Oxymethalone. 9-Nortestosterone-7-propionate 4. Testosterone propionate 5. Fluoxymesterone 6. 4-Chlorotestosterone-7-acetate 7. Testosterone-7b-cypionate 8. -Dehydrotestosterone benzoate 9. -Dehydrotestosterone undecylenate Cold Medicine Column: DM-5 Amine, 0 m x 0.25 mm x 0.50 µm Cat. No.: 782 Index: CPR00575 Oven Temp.: 250 ºC to 00 ºC (hold 7 min) at 7 ºC/min Carrier Gas: He, 0 cm/sec Injection: Split, 250 ºC Sample: Underivatized cold medicine,.0 µl,,000 ng/µl Detector: MS Scan Range AMU Ionization EI, scan. Guaifenesin 2. Pheniramine. Phenyltoloxamine 4. Chlorpheniramine 5. Brompheniramine 6. Dextromethorphan 7. Pyrilamine 8. Triprolidine 9. Codeine 0. Hydrocodone Antihistamines Column: DM-5 Amine, 0 m x 0.2 mm x.00 µm Cat. No.: 787 Index: CPR00247 Oven Temp.: 0 ºC (hold 5 min) to 05 ºC (hold 5 min) at 0 ºC/min Carrier Gas: H 2, 4 cm/sec, 0 ºC Injection: Split, 50:, 05 ºC Sample: Antihistamines,.0 µl,,000 ng/µl Detector: FID, 6.4 x 0 - AFS, 05 ºC. Phenylpropanolamine 2. Ephedrine. Pseudoephedrine 4. Pheniramine 5. Diphenhydramine 6. Doxylamine 7. Phenyltoloxamine 8. Methapyrilene 9. Chlorpheniramine 0. Brompheniramine. Triprolidine 20

83 Pharmaceutical Organic Volatile Impurities (USP 467) Column: DM-624, 0 m x 0.5 mm x.00 µm + 5 m Guard column Cat. No.: 775 Index: CPR00259 Oven Temp.: 40 ºC (hold 20 min) to 240 ºC (hold 0 min) at 5 ºC/min Carrier Gas: He, 5 cm/sec, 5 ºC Injection: Split, 2:, 80 ºC Detector: FID,.25 x 0-0 AFS, 260 ºC Organic Volatile Impurities Column: DM-624, 0 m x 0.5 mm x.00 µm Cat. No.: 775 Index: CPR0026 Oven Temp.: 5 ºC (hold 0 min) to 00 ºC at 5 ºC/min to 240 ºC (hold 5 min) at 25 ºC/min Carrier Gas: He, 5 cm/sec, 5 ºC Injection: Split, 2:, 220 ºC Detector: FID,.05 x 0 - AFS, 240 ºC. Methylene chloride 2. Chloroform. Benzene 4. Trichloroethylene 5.,4-Dioxane. Ethylene oxide 2. Methanol. Ethanol 4. Diethyl ether 5.,-Dichloroethene 6. Acetone 7. Isopropanol 8. Acetonitrile 9. Methylene chloride 0. -Hexane. n-propanol 2. Methyl ethyl ketone. Ethyl acetate 4. Tetrahydrofuran 5. Chloroform 6.,,-Trichloroethane 7. Carbon tetrachloride 8. Benzene 9.,2-Dichloroethane 20. Heptane 2. Trichloroethylene 22. n-butanol 2.,4-Dioxane 24. Pyridine 25. Toluene EP Class and Class 2 Solvents Column: DM-624, 0 m x 0.5 mm x.00 µm Cat. No.: 775 Index: CPR0055 Oven Temp.: 40 ºC (hold 20 min) to 240 ºC (hold 20 min) at 0 ºC/min Carrier Gas: H 2, 5 cm/sec Injection: ml Headspace injection, using samples shaken and heated at 80 ºC for 5 min, 200 ºC Split Ratio: 2: Detector: FID,. x 0 - AFS, 250 ºC. Methanol 2.,-Dichloroethene. Acetonitrile 4. Dichloromethane 5. Hexane 6. cis-,2-dichloroethene 7. Nitromethane 8. Chloroform 9. Cyclohexane 0.,,-Trichloroethane. Carbon tetrachloride 2. Benzene.,2-Dimethoxyethane 4.,2-Dichloroethane 5.,,2-Trichlorethene 6. Methyl cyclohexane 7.,4-Dioxane 8. Pyridine 9. Toluene Hexanone 2. Chlorobenzene 22. DMF 2. Ethylbenzene 24. m-xylene 25. p-xylene 26. o-xylene 27. N,N-Dimethylacetamide 28.,2,,4-Tetrahydronaphthalene 2

84 Pharmaceutical Residual Solvents Column: DM-624, 0 m x 0.5 mm x.00 µm Cat. No.: 775 Index: CPR00257 Oven Temp.: 5 ºC (hold 8 min) to 240 ºC at 20 ºC/min Carrier Gas: He, 25 cm/sec, 5 ºC Injection: Split, 0:, 80 ºC Sample: Residual solvents, 0.5 µl Detector: FID,.28 x 0-0 AFS, 260 ºC. Methanol 2. Ethanol. Ether 4. Acetone 5. Isopropanol 6. Acetonitrile 7. Methylene chloride 8. tert-butanol 9. Hexane 0. n-propanol. Methyl ethyl ketone 2. Ethyl acetate. Tetrahydrofuran 4. sec-butanol 5. Chloroform 6. Cyclohexane 7. Benzene 8. Heptane 9. Trichloroethylene 20.,4-Dioxane 2. Pyridine 22. Toluene 2. Dimethyl formamide Primary, Second and Tertiary Amines Column: DM-624MS, 0 m x 0.2 mm x.80 µm Cat. No.: 888 Index: CPR62 Oven Temp.: 50 ºC (hold min) to 200 ºC (hold 5 min) at 20 ºC/min Carrier Gas: He, 7 cm/sec Injection: Split, 20:,.0 µl, 250 ºC Sample: Primary, second and tertiary amines in DMSO, 00 µg/ml Detector: FID, 250 ºC Secondary amine Tertiary amine. Isopropylamine 00 µg/ml 2. Diethylamine 00 µg/ml. Triethylamine 00 µg/ml Primary amine High activity, low inertness 22