The Biomarker Catalogue. The collection of reference standards

Transcript

1 The Biomarker Catalogue The collection of reference standards

2

3 Professor Dr. Nils Andreas Sørensen ( ) I would like to dedicate this catalogue to a great and unique chemist, teacher and personality, the late Professor Nils Andreas Sørensen. General Professor Nils Andreas Sørensen was born in slo in 1909, moved to Trondheim and finished his master s degree at The Norwegian Institute of Technology (NT) in As a student of Professor C.N. Riiber he received his doctor degree in 1937, moved to eidelberg in 1938 where he studied with the Nobel laureate Richard Kuhn until he was appointed Professor in rganic Chemistry at NT in 1939, at just 30 years of age. Professor Sørensen contributed to several important areas of natural product chemistry. is scientific production covers the chemistry of mutarotation of sugars, and the chemistry of carotenoids. e was also the first to discover naturally occurring acetylenic compounds. Professor Sørensen was, in addition to being a unique chemist, an expert in botany which he combined with his chemistry background in a superb manner. e followed a tradition of natural product chemistry in Trondheim which has been manifested by later groups at NT. In addition to lecturing on specialized topics in traditional natural product chemistry, such as steroids and triterpenoids, he lectured on mycotoxins and chemotherapeutica. The results of the latter topics can be found in this catalogue. Professor Sørensen has given much inspiration to generations of organic chemists in Trondheim and elsewhere in Norway. Professor C.N. Riiber was a gentleman from the old school, elegant and witty in his form, with a tremendous precision characterizing his work. Professor Richard Kuhn s work revealed a stringent sense of formality and an exceptional ability to focus on essential problems. Influence and inspiration from these masters imprinted Professor Sørensen with a sparkling and elegant wit which distinguished him as a brilliant teacher and inspiring lecturer. Nonetheless are Professor Sørensen s immense knowledge and relentless curiosity probably the most distinguishing features of his personality. Professor Sørensen had, in addition, a relentless source of energy. e has, quite correctly, been described as a lighting bolt in a double breasted suit with an outdoor Alp hat and an indoor cigar. The picture of Professor Sørensen is not complete before mentioning that he was an enthusiastic moose hunter, mountain climber and farmer. Source: Sørenseniader Dr. Jon E. Johansen Chair, Chiron AS 1

4 Innovative and sophisticated standards - Creative solutions Chiron AS in fast development For more than 25 years Chiron has supplied oil and gas companies and analytical laboratories throughout the world with reference substances of high purity for geochemical and environmental analysis. Profile companies and institutions throughout the world have benefited from our supply of unique reference standards. igh focus on basic research applied to environmental and petroleum problems has brought Chiron to the forefront of analytical chemistry. This is a result of many years of investments, the enthusiasm and frontier spirit of our team, and a close cooperation with academic institutions and customers worldwide. In this catalogue you will find, in addition to a number of new products related to petroleum and environmental applications, two new sections: Food safety and Pharmaceutical and forensic. Several patented products and applications are included in our catalogue, and new inventions are continually under development. Updates on new products are included in our Biomarker Focus mailings and new products catalogues (see pdf versions under the Newsletters section on ). Chiron offers a varied, flexible and innovative range of biomarkers to suit the needs of the individual customer. The cover illustrated the strength of our team. If you look for an unique quality and unique compounds, please contact us: We welcome you to the Chiron biomarker era of Chiron Chiron was an immortal god, he was the eldest and wisest of the centaurs, a tribe of half horse-men. As opposed to his brethren Chiron was intelligent, civilized and kind. e was revered as an astrologer, healer and a great teacher to the likes of Ajax, eracles and Achilles. In the end Chiron sacrificed his immortality for allowing humanity to obtain the use of fire. Chiron:- ur symbol of strength. 2

5 The Biomarker catalogue 2008 Table of contents General Chapter I : General Chapter II : Methods IS methods EN standards ASTM methods EPA methods Miscellaneous methods Chapter III : Applications Chapter III-1: Environmental Chapter III-2: Petroleum Chapter III-3: Food safety Chapter III-4: Pharmaceuticals and Forensics Chapter IV : Compounds Chapter V : Indexes

6 Chapter I: General ow to order We need the following information when you order: Catalogue number and product name Quantity Shipping and invoice addresses rders can be placed by telephone, telefax, mail, and on our web page. Chiron AS Stiklestadveien 1 N-7041 Trondheim Norway us at chiron@chiron.no Tel:(+47) Visit our updated web page: Fax(+47) Custom synthesis Through our experience in the reference standards and fine chemicals markets we have acquired a large network of contacts and suppliers. We also have a fully equipped laboratory where we take on custom synthesis jobs and continually work on developing new and innovative products. Chiron is currently involved in several EU-projects and has a unique experience in long term research ventures for the petroleum and pharmaceutical industries. Please contact us for custom synthesis and custom development projects. 4

7 Chiron quality standards Most compounds appearing in this catalogue are synthesized or isolated by Chiron AS. The products are delivered in neat form or as solutions in high purity solvents. The solutions are normally supplied in flame sealed vials but can be delivered with screw cap bottles or in GC-vials upon request. The purity is assigned by capillary GC unless otherwise stated. The identity is assigned by NMR and MS. MSDS and Certificate of Analysis is available on all products. Chiron is currently working according to the international quality standard IS and IS General Special quotations Please contact us for: Bulk deliveries Custom made solutions Custom synthesis For larger quantities; please ask for special quotations. Conditions for sale Complaints All claims must be in writing and made within 60 days of invoice date. No return will be accepted without prior authorization. Prices The prices can be quoted in NK, USD, EUR or GBP. Use of products ur products are offered for LABRATRY USE NLY and may not be used as drugs, cosmetics or food additives. Warranty and compensation claims The stated specifications for each product indicate an average guiding value and may vary for each batch. Any indemnity will be limited to an amount not exceeding the price of the goods. 5

8 Units In this catalogue we have used the following units for concentrations: mg/ml = 10-3 g/ml = 1000µg/mL = 1000ng/µL = 1000ppm µg/ml ng/ml pg/ml ppm: ppb: = 10-6 g/ml = 0.001mg/mL = 1000ng/mL = 1ng/µL = 1ppm = 10-9 g/ml = 10-6 mg/ml = 10-3 µg/ml = 1µg/mL = 10-3 ppm = g/ml = 10-6 ppm = Parts per million 1 ppm = 1µg/mL = 0.001mg/mL = 0.001g/L 1 ppm = 1µg/g = 0.001mg/g = 0.001g/kg Parts per billion 1ppb = 0.001ppm = 10-6mg/mL Note: 1 European billion is 1000 European milliards (= 1000 US billions) Concentrations of Standards can be given as: Weight by total weight: w/w Weight by total volume: wt% Volume by total volume:vol% Weight by volume is most common and usually used by Chiron Sulfur Concentration: Sulfur concentration is given as % weight sulfur by total volume or weight ow exact is your solution? You can make a solution by dissolving the analyte in an exact volume or by weighing the final solution. By using a volumetric flask you will always depend on the temperature in the room. A volumetric flask is equilibrated at an exact temperature and you have to keep the same room temperature in order to make a reproducible concentration. owever, by weighing the solution you will always make a solution in exactly the same way each time, independent of the temperature in the room. Good Laboratory Practice at Chiron is to weigh all solutions. To make an exact solution from the Chiron ampoulle, transfer the content of the vial into your flask and weight to exact volume (use the densities below). Alternatively, but less exact, dilute to a fixed volume in a volumetric flask. 6

9 The following solvent-densities are used for Chiron solutions: Acetone g/ml exane g/ml Acetonitrile g/ml Isooctane g/ml Chlorobenzene g/ml Methanol g/ml Cyclohexane g/ml Pentane g/ml Benzene g/ml Toluene g/ml Dichloromethane g/ml General Updated numbering in our catalogue Numbering for single, pure compounds in solution: Number of carbon atoms Solvent I Unique number for each compound Concentration in ug/ml or ug/g Numbering for single compounds, neat: Number of carbon atoms MG Unique number for each compound Amount Numbering for solutions: Concentration S I Unique number for each solution Solvent 7

10 Concentrations 1 = 1µg/mL, 1.1µg/mL 10 = 10µg/mL 100 = 100µg/mL = 0.1mg/mL K = 1000µg/mL = 1mg/mL 5K = 5000µg/mL = 5mg/mL 0,1Wt% 100µg/g Weight 100 = 100µg/g 0,1Wt% K = 1000µg/g 1Wt% Amounts 10UG = 10µg 10MG = 10mg 100MG = 100mg 1G = 1g 1KG = 1kg 1UL = 1µl Solvents 1,2,3-Trichlorobenzene Acetone Acetonitrile Benzene Benzene d6 Carbon disulfide (CS2) Chlorobenzene Cyclohexane Dichloromethane/Methylene chloride Dioxane DMF DMS Dodecane Ethanol eavy white Mineral oil (70cSt) eptane exane Isooctane Isopropanol TB AC AN B BD CS CB CY DC DI DF DS DD ET W P X I IP Light white Mineral oil (20cSt) Methanol Methyl-tert-butyl ether (MTBE) n-exadecane n-exane n-nonane n-ctane n-pentane Pentane Petroleum ether RFA Gasoline t-butyl methyl ether Toluene Ultralight white Mineral oil (3cSt) Water Xylene Mix of solvents LW ME MT D X NN C PE PE PT RF BM T 3C W XY MX 8

11 Common abbreviations ABS AED ASP ASTM BAF BaP BCF BDE BD BP BSA BSTFA BTEX BZ-system CA CAS No. CD CEN Alkylbenzenesulfonate Atiomic Emission Detection Amnesic Shellfish American Society For Testing and Materials Bioaccumulating Factor Benzo[a]pyrene Bioconcentration Factor Bromodiphenylether Biochemical xygen Demand British Pharmacopeia N,-Bis(trimethylsilyl)acetamide N,-Bis(trimethylsilyl)trifluoroacetamide Benzene, Toluene, Ethylbenzene, Xylenes Numbering system for PCBs according to Ballschitter and Zell Chemical Abstract Chemical Abstract Service Registry Number Circular Dichroism Comite Europeen de NorEuropean Committee for Standardization centi undredth (10-2 ) Ci Curie (Unit) CMR Carcinogenic, mutagenic and toxic to reproduction CoA Coenzyme A CD Chemical xygen Demand CPIND Causing rganophosphate Induced Neuropsyhiatric Disorder CP Chemically Pure CRM Certified Reference Materials DBT Dibutyltin DDD 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane DDE 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethylene DDT 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane deca Tenth (10-1 ) deci Tenth (10-1 ) DA Docosahexaenoic acid DIPE Diidopropyl ether DIS Draft International Standard DMDMP Dimethyldibenzothiophene DMF Dimethylformamide DMN Dimethylnaphthalene DMP Dimethylphenanthrene DMS Dimethyl sulfoxide DNA Deoxyribonucleic Acid DNBP Dinoseb DT Dioctyltin DPA Docosapentaenoic Acid DPT Diphenyltin DR Diesel Range rganics DSP Diarrhetic Shellfish DT50 Degradable Total to 50 % (alf -time) Dutch Seven A mixture of seven commonly occurring PCBs EAG European Association of rganic Geochemists EC European Community ECD Electron Capture Detection EDTA EDXRF EEC EFSA EI ELCD EMEC EN EP EPA EP EAA EAA FAME FID FSA F-PA F-PBDE F-PCB FPD FTCA FT Ethylenediaminetetraacetic acid Energy Dispensive X-ray Fluorescence Spectroscopy European Economic Community The European Food Safety Authority Electron Capture Detection Electrolytic Conductivity Detectors European Meeting on Environmental Chemistry European Norm European Pharmacopeia The US Environmental Protection Agency Extractable Petroleum ydrocarbons Ether-Alcohol-Aromatic European Aluminium Association Fatty Acid Methyl Ester Flame Ionization Detection Perfluorooctane Sulphonamide Fluorinated PAs, Internal Standards Fluorinated PBDEs, Internal Standards Fluorinated PCBs, Internal Standards Flame Photometric Detection Perfluorohexanoic acid Perfluorohexan-1-ol giga Billion, Milliard (10 9 ) GLF General Food Law (EU) GR Gasoline Range rganics hecto undred (102) eptacosa Perfluoro-tri-n-butylamine FBA eptafluorobutyric anhydride MDS 1,1,1,3,3,3-examethyldisilazane RGC igh Resolution GC ICP-AES Inductive Coupled Plasma Atomic Emission Spectroscopy IDF International Dairy Federation IM International Maritime rganisation IMG International Meeting on rganic Geochemistry IRMS Isotope Ratio Mass Spectrometry ISPAC International Society for Polycyclic Aromatic Compounds ISTD Internal Standard ITX Isopropylthioxanthone IUPAC International Union of Pure and Applied Chemistry kilo Thousand (10 6 ) L(E)C50 Lethal Concentration to 50 % LAS Linear Alkylbenzenesulfonates LD Lethal Dose log Kow Partition coefffient octanol/water MAGME Methyl Acrylamido Glycolate Methyl Ether MBT Monobutyltin MCCP Medium Chain Chlorinated Alkanes MCPA 4-Chloro-2-methylphenoxyacetic Acid MDL Method Detection Limit MDMC Minimum Detectable Mutagenic Concentration MDMP Methyldibenzothiophene General 9

12 mega Million (10 6 ) micro Millionth (10-6 ) milli Thousandth (10-3 ) MN Methylnaphthalene MT Monooctyltin MP Methylphenanthrene MPLC Mediium Pressure Liquid Chromatography MPT Monophenyltin MSTFA N-Methyl-N-(trimethylsilyl)trifluoroacetamide MTBE tert-butyl methyl ether MW Molecular Weight nano Billionth, Milliardth (10-9 ) NBA 3-Nitrobenzanthrone NCI Negative Ion Chemical Ionization NIGGA The Norwegian Industry Guide to Geochemical Analysis NIST National Institute for Standards and Technology NMR Nuclear Magnetic Resonance NPD Naphtalenes, Phenanthrenes, Dibenzothiophenes NPE() Nonylphenol Polyethoxylates PE 4-tert-ctylphenol Polyethoxylates RD ptical Rotatory Dispersion SPAR Commision of the Conv. for the Protection of the Marine Env. of the North-East Atlantic PAC Polycyclic Aromatic Compounds = PA PA Polycyclic Aromatic ydrocarbons PAN Nitrogenheterocyclic PAs PAR Precision and Recovery PAS Sulfurheterocyclic PAs PB Inducers Phenobarbital PBB Polybrominated Biphenyls PBDE Polybrominated Diphenylethers PBN Polybrominated Naphthalenes PBN Polybromonaphthalene PBT Persistant Bioaccumulating Toxicants PCA Polychlorinated Alkanes PCB Polychlorinated Biphenylethers PCDD Polychlorinated Dibenzo-p-dioxines PCDF Polychlorinated Dibenzofurans PCN Polychlorinated Naphthalenes PFA Polyfluorinated Alkanes PFAS Polyfluoroalkane Sulfonates PFB Perfluorobenzoyl Derivative PFBBr Perfluorobenzoyl Bromide PFBS Perfluorobutane Sulfonate (sulfonic Acid) PFC Polyfluorinated rganic Compounds PFCA Perfluorocarboxylic Acid PFDA Perfluorodecanoic Acid PFS Perfluorohexane Sulfonate PFNA Perfluorononanoic Acid PFA Perfluorooctanoic Acid PFS Perfluorooctane Sulfonic Acid PFUA Perfluoroundecanoic Acid pico Trillionth, Billionth (10-12 ) PINA Paraffins, Isoparaffins, Naphthenes, Aromatics PINA Paraffins, Isoparaffins, lefins, Naphthenes, Aromatics PMS PNA PNA PP PS ppb ppm PSP PUF PVC QSAR RCRA RNA RR SCCP SCS SETAC SFT SIMDIS SP SRM STP TAME TBT TCDD TCT TDI TE-GC-MS TeMN TEPA TEX TFAI TFAA TC TF TM TLC Tm TMCS TMN TMP TMP TMSI TmTP ToTP TPP TPT TpTP Ts TTP UNEP USP UST VC W XRF Postmitochondrial supernatant Paraffins, Naphthenes, Aromatics Paraffins, lefins, Naphthenes, Aromatics Persistant rganic Pollutants xygenheterocyclic PAs Parts pr billion Parts per million Paralytic Shellfish Polyuretane Foam Polyvinylchloride Quantitatative Structure Activity Relationship Resource, Conservation, and Recovery Act Ribonucleic acid Residue Range rganics Short Chain Chlorinated Alkanes System Calibration Standard Society of Environmental, Toxicology and Chemistry Norwegian Pollution Control Authority Simulated Distillation Standard perating Procedure Standard Reference Materials Sewage Treatment Plant tert-amylmethyl ether Tetrabutyltin (Chloride) 2,3,7,8-Tetrachlorodibenzo-p-dioxin Tricyclohexyltin Tolerable Daily Intake Thermal Extraction Capillary GC-MS Tetramethylnaphthalene Tris-(aziridinyl)-phosphineoxide Toluene-Ethylbenzene-Xylenes 1-(Trifluoroacetyl)imidazole Trifluoroacetic Anhydride Tetrahydrocannabinol Tetrahydrofuran Trihalomethanes Thin Layer Chromatography 17 ()-22,29,30-Trisnorhopane Chlorotrimethylsilane Trimethylnaphthalene Trimethylphenanthrene Trimethylphosphate 1-(Trimethylsilyl)imidazole Tri-m-tolylphosphate Tri-o-tolylphosphate Triphenylphosphate Triphenyltin (Chloride) Tri-p-tolylphosphate 18 ()-22,29,30-Trisnorneohopane Tritolylphosphate (isomer mixture) United National Environment Programme US Pharmacopeia Underwater Storage Tank Volatile rganic Compounds World ealth rganization Wavelength Dispensive X-ray Fluorescence 10

13 Chapter II: Methods Table of contents IS methods EN standards Methods ASTM methods EPA methods Miscellaneus methods

14 12

15 IS methods IS 6468:1996 Water quality - pesticides, PCBs, chlorobenzenes Water quality - Determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes - Gas chromatographic method after liquid-liquid extraction This test method covers the determination of certain organochlorine insecticides, polychlorinated biphenyls (PCBs) and chlorobenzenes (except the mono- and dichlorobenzenes) in drinking waters, ground waters, surface waters and waste waters. Methods Chiron No. Compound Abbr. CAS No. Conc. 1 ml rganochlorine pesticides CY or AN alpha-c (alpha-bc) [ ] 100 µg/ml CY or AN beta-c (beta-bc) [ ] 100 µg/ml CY or AN gamma-c (gamma-bc) Lindane [ ] 100 µg/ml CY or AN delta-c (delta-bc) [ ] 100 µg/ml CY or AN epsilon-c (epsilon-bc) [ ] 100 µg/ml CY or AN 1,1-Dichloro-2-(o-chlorophenyl) -2-(p-chlorophenyl)ethylene o,p -DDE [ ] 100 µg/ml CY or AN 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethylene p,p -DDE [ ] 100 µg/ml CY or AN 1,1-Dichloro-2-(o-chlorophenyl)- 2-(p-chlorophenyl)ethane o,p -TDE [ ] 100 µg/ml CY or AN 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane p,p -TDE [ ] 100 µg/ml CY or AN 1,1,1-Trichloro-2-(o-chlorophenyl)- 2-(p-chlorophenyl)ethane o,p -DDT [ ] 100 µg/ml CY or AN 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane p,p -DDT [ ] 100 µg/ml CY or AN 1,1,1-Trichloro-2,2-bis(p-methoxyphenyl)ethane Methoxychlor [ ] 100 µg/ml CY or AN Aldrin Aldrin [ ] 100 µg/ml CY or AN Dieldrin Dieldrin [ ] 100 µg/ml CY or AN Endrin Endrin [ ] 100 µg/ml CY or AN eptachlor eptachlor [ ] 100 µg/ml CY or AN eptachlor-epoxide (trans) eptachlorepoxide [ ] 100 µg/ml CY or AN alpha-endosulfan [ ] 100 µg/ml CY or AN beta-endosulfan [ ] 100 µg/ml Chlorobenzenes K-I or AN 1,2,3-Trichlorobenzene 123-TrCB [ ] 1000 µg/ml K-I or AN 1,2,4-Trichlorobenzene 124-TrCB [ ] 1000 µg/ml K-I or AN 1,3,5-Trichlorobenzene 135-TrCB [ ] 1000 µg/ml K-I or AN 1,2,3,5-Tetrachlorobenzene 1235-TeCB [ ] 1000 µg/ml K-I or AN 1,2,4,5-Tetrachlorobenzene 1245-TeCB [ ] 1000 µg/ml K-I or AN Pentachlorobenzene PeCB [ ] 1000 µg/ml K-I or AN exachlorobenzene CB [ ] 1000 µg/ml CY or AN Pentachloronitrobenzene (=Quintozene) PCNB [ ] 100 µg/ml 13

16 Polychlorinated biphenyls I or AN 2,4,4 -Trichlorobiphenyl PCB-28 [ ] 100 µg/ml I or AN 2,2,5,5 -Tetrachlorobiphenyl PCB-52 [ ] 100 µg/ml I or AN 2,2,4,5,5 -Pentachlorobiphenyl PCB-101 [ ] 100 µg/ml I or AN 2,2,3,4,4,5 -exachlorobiphenyl PCB-138 [ ] 100 µg/ml I or AN 2,2,4,4,5,5 exachlorobiphenyl PCB-153 [ ] 100 µg/ml I or AN 2,2 3,4,4,5,5 -eptachlorobiphenyl PCB-180 [ ] 100 µg/ml I or AN 2,2,3,3,4,4,5,5 -ctachlorobiphenyl PCB-194 [ ] 100 µg/ml IS :2005 Water quality - Six PAs by TLC Water quality - Determination of polycyclic aromatic hydrocarbons (PA) Part 1: Determination of six PA by high-performance thin-layer chromatography with fluorescence detection after liquid-liquid extraction. This part of IS 7981 specifies the determination of six selected PA in drinking water using high performance TLC. Single-substance stock solutions Chiron No. Name CAS No. Concentration AN Fluoranthene [ ] 10µg/mL AN Benzo[b]fluoranthene [ ] 10µg/mL AN Benzo[a]pyrene [ ] 10µg/mL AN Benzo[k]fluoranthene [ ] 10µg/mL AN Indeno[1,2,3-cd]pyrene [ ] 10µg/mL AN Benzo[ghi]perylene [ ] 10µg/mL KIT IS Single substance Kit 6 samples S-4062-ASS-5AN Multiple-substance stock solution (= 6 priority PA drinking water analysis ) 6 Analytes, each 2-10µg/mL in acetonitrile; unit: 1x5mL Chiron No. Name CAS No. Concentration Fluoranthene [ ] 10µg/mL Benzo[b]fluoranthene [ ] 2µg/mL Benzo[a]pyrene [ ] 2µg/mL Benzo[k]fluoranthene [ ] 2µg/mL Indeno[1,2,3-cd]pyrene [ ] 2µg/mL Benzo[ghi]perylene [ ] 2µg/mL 14

17 IS :2005 Water quality Six PAs by PLC Water quality - Determination of polycyclic aromatic hydrocarbons (PA) - Part 2: Determination of six PA by high-performance liquid chromatography with fluorescence detection after liquid-liquid extraction This part of IS 7981 specifies the determination of six PA in drinking, mineral, table waters and ground and surface waters in mass concentrations 0.005µg/L, by high-performance liquid chromatography (PLC) and fluorescence detection after liquid-liquid extraction. Single-substance stock solutions 1x1mL each Methods Chiron No. Name CAS No. Concentration AN Fluoranthene [ ] 10µg/mL AN Benzo[b]fluoranthene [ ] 10µg/mL AN Benzo[a]pyrene [ ] 10µg/mL AN Benzo[k]fluoranthene [ ] 10µg/mL AN Indeno[1,2,3-cd]pyrene [ ] 10µg/mL AN Benzo[ghi]perylene [ ] 10µg/mL KIT IS Single substance Kit 6 samples S AN Multiple-substance stock solution 6 Analytes, each 10µg/mL in acetonitrile; unit: 1x5mL Chiron No. Name CAS No. Concentration Fluoranthene [ ] 10µg/mL Benzo[b]fluoranthene [ ] 10µg/mL Benzo[a]pyrene [ ] 10µg/mL Benzo[k]fluoranthene [ ] 10µg/mL Indeno[1,2,3-cd]pyrene [ ] 10µg/mL Benzo[ghi]perylene [ ] 10µg/mL Calibrations solutions are made by request according to customer specifications. IS :1999 Water quality - Monovalent phenols Water quality Determination of selected monovalent phenols - Part 1: Gas-chromatographic method after enrichment by extraction This international method specifies a method for determining phenols by a gas chromatographic method. The determination of selected phenols and nitrophenols in drinking water, ground water and surface water. The method provides a procedure for solid-phase extraction of nitrophenols, followed by solvent elution, derivatization with diazomethane and determination by gas chromatography and mass spectrometry. 15

18 S ME IS Phenol Standard Stock Solution 35 Analytes, each 100µg/mL in methanol; unit: 5x1mL Chiron No. Compound CAS No Phenol [ ] Methylphenol (o-cresol) [ ] Methylphenol (m-cresol) [ ] Methylphenol (p-cresol) [ ] ,4-Dimethylphenol [ ] Ethylphenol [ ] ,6-Di-tert-butyl-4-methylphenol [ ] (2,6-Bis(1,1-dimethylethyl)-4-methylphenol) Phenylphenol [ ] Benzylphenol [ ] Benzyl-4-methylphenol [ ] Chorophenol [ ] Chlorophenol [ ] Chlorophenol [ ] Chloro-2-methylphenol [ ] Chloro-3-methylphenol [ ] ,4-Dichloro-3,5-dimethylphenol [ ] Cyclopentyl-4-chlorophenol [ ] Chloro-5-methyl-2- [ ] (1-methylethyl)phenol(6-Chorothymol) ,3-Dichlorophenol [ ] ,4-Dichlorophenol [ ] ,5-Dichlorophenol [ ] ,6-Dichlorophenol [ ] ,4,6-Trichlorophenol [ ] ,3,5-Trichlorophenol [ ] ,4,5-Trichlorophenol [ ] ,3,6-Trichlorophenol [ ] ,3,4,5-Tetrachlorophenol [ ] ,3,4,6-Tetrachlorophenol [ ] ,3,5,6-Tetrachlorophenol [ ] Pentachlorophenol [ ] Naphthol [ ] Naphthol [ ] Chloro-5-methylphenol [ ] (6-Chloro-3-methylphenol) Chloro-4-tert-butylphenol [ ] Chloro-2-benzylphenol [ ] S-4353-K-5AC IS Internal Control Stock Solution 1 1 Internal standard, 1000µg/mL in acetone; unit: 1x5mL ,4-Dibromophenol [ ] Alternative Internal standard: IS Internal Control Stock Standard Solution ,5-Dibromophenol [ ] 16

19 IS :1999 Water quality Monovalent phenols Water quality Determination of selected monovalent phenols Part 2: Method by derivatization and gas chromatography This international method specifies a method for the determination of phenols by gas chromatography, following pentafluorobenzoyl chloride derivatization. It may in particular be applied to the examination of drinking water, ground water and moderately contaminated surface water. S ME IS Phenol Standard Stock Solution 2 33 Analytes, each 300µg/mL in methanol; unit: 5x1mL Methods Prod.No. Compound CAS No Phenol [ ] Methylphenol (o-cresol) [ ] Methylphenol (m-cresol) [ ] Methylphenol (p-cresol) [ ] ,4-Dimethylphenol [ ] Ethylphenol [ ] ,6-Bis(1,1-dimethylethyl)-4-methylphenol [ ] Phenylphenol [ ] Benzylphenol [ ] Benzyl-4-methylphenol [ ] Chorophenol [ ] Chlorophenol [ ] Chlorophenol [ ] Chloro-2-methylphenol [ ] Chloro-3-methylphenol [ ] Chloro-5-methylphenol [ ] (6-Chloro-3-methylphenol) ,4-Dichloro-3,5-dimethylphenol [ ] Chloro-4-tert-butylphenol [ ] Cyclopentyl-4-chorophenol [ ] Chloro-2-benzylphenol [ ] Chloro-5-methyl-2-(1-methylethyl)phenol [ ] ,3-Dichlorophenol [ ] ,4-Dichlorophenol [ ] ,5-Dichlorophenol [ ] ,6-Dichlorophenol [ ] ,4,6-Trichlorophenol [ ] ,3,5-Trichlorophemol [ ] ,4,5-Trichlorophenol [ ] ,3,6-Trichlorophenol [ ] ,3,4,5-Tetrachlorophenol [ ] ,3,4,6-Tetrachlorophenol [ ] ,3,5,6-Tetrachlorophenol [ ] Pentachlorophenol [ ] 17

20 ME IS Internal Control Stock Solution 1 1 Internal standard, 10µg/mL in methanol; unit: 1x5mL 2,4-Dibromophenol [ ] Alternative Internal standard: ME IS Internal Control Stock Solution 2 1 Internal standard, 10µg/mL in methanol; unit: 1x5mL 2,5-Dibromophenol [ ] IS :2000 / IS 9377-MD (SPAR) Water quality ydrocarbons in water Water quality Determination of hydrocarbon oil index Part 2: Method using solvent extraction and gas chromatography IS : ydrocarbon oil index The method of choice for the determination of oil and grease in water is the new standard IS , and is based on extraction with a hydrocarbon solvent like pentane or hexane. This test determines the hydrocarbon oil index in water by means of gas chromatography. The method is suitable for surface water, waste water, and water from sewage treatment plants, and allows the determination of the hydrocarbon oil index in concentrations above 0.1 mg/l. The index is the sum of compounds with retention times between n-decane and n-tetracontane. Substances complying with this definition are long-chain or branched aliphatic, alicyclic, aromatic or alkylsubstituted aromatic hydrocarbons. For the determination of mineral-oil content of soils and sediments, see IS/TR IS Mod: Determination of hydrocarbon oil index down to C7 A modified method for oil in water analysis of produced water from offshore petroleum production installations has recently been taken into force. IS is not applicable for volatile hydrocarbons, and a modification of the method is proposed by the SPAR commission in order to include the determination of certain hydrocarbons with boiling points between 98 and 174 ºC from produced water. The SPAR Reference Method of Analysis for the Determination of the Dispersed il Content in Produced Water: Reference Number

21 IS : Standards available from Chiron for the determination of hydrocarbon oil index S ML IS Mixture of Mineral ils A+B without additives Mixture 1:1 (neat), 1 ml, 5x1 ml Type A: Diesel fuel without additives Type B: Lubricant oil without additives S-4216-SET IS Calibration Mixture of Minerals ils Mineral oils (S-4215) in pentane, set of 6x5 ml 1: Blank 2: 0.2 mg/ml 3: 0.4 mg/ml mg/ml mg/ml mg/ml Methods S-4217-K-AC S K-AC S K-AC IS Quality Control Standard of Mineral ils A+B 1000 µg/ml in acetone (500 µg/ml of each A and B), 1x1mL, 5x1mL, 10x1mL 4000 µg/ml in acetone (2000 µg/ml of each A and B), 1x1mL, 5x1mL, 10x1mL µg/ml in acetone, (5000 µg/ml of each A and B), 1x1mL, 5x1mL, 10x1mL S K-AC IS MD Quality Control Standard of Base il EDC 95/ µg/mL in acetone, 1x1mL, 5x1mL, 10x1mL S PE S PE IS Extraction Solvent Stock Solution I Units: 1x5mL, 5x5mL, 10x5mL extraction solvent stock solution 1x100ml and 5x100mL extraction solvent stock solution n-decane 20 µl n-tetracontane 20 mg Pentane Add to 1000 ml S-4515 IS Extraction solvent standard solution. Dilute of Extraction solvent stock solution (S-4212) 10 times with the extraction solvent (n-pentane) S-4134-ASS-10MX IS Stearyl Stearate Test Solution Units: 1x10 ml, 5x10mL, 10x10 ml Stearyl stearate 200 mg Extraction solvent standard solution (S-4515) 100 ml This solution is used to check the efficiency of the clean-up procedure. 19

22 S K-100MX IS Test for Suitability of Fluorisil 2000µg/mL; unit: 1x100mL Stearyl Stearate in Extraction solvent standard solution (S-4515) Test with stearyl stearate to determine the separation of polar compounds NEW PRDUCT: IS Test for suitability of Fluorosil. Ready to use solution Units: 1x25mL, 5x25mL, 10x25 ml Stearyl stearate test solution, 2 mg/ml (S-4134) 10 ml Extraction solvent (pentane) 15 ml Total of 25 ml to be used in one experiment S K-PE IS Stearyl Stearate Solution for Comparison Unit: 1mL for direct GC-comparison Stearyl stearate test solution, 2 mg/ml (S-4134) Extraction agent (pentane) 0.5 ml 24.5 ml S PE * S PE S CY * S CY IS Standard Mixture of n-alkanes C10-C40 (all even) Determination of ydrocarbon il in Water Index 16 Analytes, each 50 µg/ml in n-pentane; units: 1x1mL, 1x5mL, 10x1mL This standard is also available as 100µg/mL in Cyclohexane Units: 1x1mL, 1x5 ml, 10x1mL n-decane C10 n-exacosane C26 n-dodecane C12 n-ctacosane C28 n-tetradecane C14 n-triacontane C30 n-exadecane C16 n-dotracontane C32 n-ctadecane C18 n-tetratriacontane C34 n-eicosane C20 n-exatriaconatne C36 n-docosane C22 n-ctatriacontane C38 n-tetracosane C24 n-tetracontane C40 S PE * S PE IS Standard Mixture of n-alkanes C20-C40 (all even) Determination of ydrocarbon il in Water Index 11 Analytes, each 50µg/mL in n-pentane, units: 1x1mL, 1x5mL, 10x1mL n-eicosane C20 n-tetratriacontane C34 n-docosane C22 n-exatriaconatne C36 n-tetracosane C24 n-ctatriacontane C38 n-exacosane C26 n-tetracontane C40 n-ctacosane C28 n-triaconatne C30 n-dotracontane C32 *When using the above standards to check column performance, the relative ratio n-tetracontane to n-eicosane should be at least

23 IS Mod: Standards available from Chiron for the determination of hydrocarbon oil index down to C7 S ML IS Mixture of Mineral ils A+B without additives S ML See above for IS S-4216-SET IS Calibration Mixture of Minerals ils See above for IS S K-AC IS MD Quality Control Standard of Base il EDC 95/4 4000µg/mL in acetone S-4217-K-AC IS Quality Control Standard of Mineral ils A+B S K-AC See above for IS S K-AC Methods S PE IS MD Extraction Solvent Stock Solution I 20µL of n-eptane and 20mg of n-tetracontane solved in 1000mL n-pentane Units: 1x5mL, 5x5mL, 10x5mL, 1x100mL and 5x100mL S-4516 IS MD Extraction solvent standard solution. Dilute of Extraction solvent stock solution (S-4415) 10 times with the extraction solvent (n-pentane) S-4517-ASS-10MX IS MD Stearyl Stearate Test Solution 200mg Stearyl stearate in 100mL Extraction solvent standard solution (S-4516) Units: 1x10mL, 5x10mL, 10x10mL S K-100MX IS MD Test for Suitability of Fluorisil 10mL Stearyl stearate test solution (S-4517) with 15mL Extraction solvent (n-pentane) Units: 1x25mL, 5x25mL, 10x25mL, 1x100mL S K-PE IS MD Stearyl Stearate Solution for Comparison 0,5mL Stearyl stearate test solution (S-4517) with 24,5mL Extraction solvent (n-pentane) Unit: 1mL for direct GC-Comparison S PE IS MD Extraction Solvent Stock Solution II Units: 1x100mL and 5x100mL extraction solvent stock solution n-eptan 40 mg n-tetracontane 40 mg Pentane Add to 1000 ml S PE BTEX Mixture 1 S PE 6 Analytes, each 200µg/mL in pentane; units: 1x1mL, 1x5mL Benzene Ethylbenzene m-xylene Toluene o-xylene p-xylene S K-PE BTEX Mixture 2 S K-5PE 6 Analytes, each 2000µg/mL in pentane; units: 1x1mL, 1x5mL Benzene Ethylbenzene m-xylene Toluene o-xylene p-xylene 21

24 S ME BTX Mixture 1 5 Analytes, each 10µg/mL in methanol; unit: 1x2mL screw cap bottle Benzene Toluene o-xylene m-xylene p-xylene S PE S PE IS Mod Standard Mixture of n-alkanes C7+C8+C9+C10-C40 in n-pentane 19 Analytes, each 50µg/mL in n-pentane; units: 1x1mL, 1x5mL, 10x1mL n-eptane C7 n-tetracosane C24 n-ctane C8 n-exacosane C26 n-nonane C9 n-ctacosane C28 n-decane C10 n-triacontane C30 n-dodecane C12 n-dotriacontane C32 n-tetradecane C14 n-tetratriacontane C34 n-exanedecane C16 n-exatriacontane C36 n-ctadecane C18 n-ctatriacontane C38 n-eicosane C20 n-tetracontane C40 n-docosane C22 S CY S CY S PE S PE Also available as 100µg/mL in cyclohexane, Units; 1mL, 1x5mL, 10x1mL IS Mod Standard Mixture of n-alkanes + BTEX I C7+C10+ C20+C40+BTEX in n-pentane Determination of ydrocarbon il in Water Index 12 Analytes, each 50µg/mL in n-pentane; units: 1x1mL, 1x5mL, 10x1mL Benzene B p-xylene p-x Toluene T n-eptane C7 Ethylbenzene E n-decane C10 o-xylene o-x n-eicosane C20 m-xylene m-x n-tetracontane C40 S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX II C7+C8+C9+C10+C20+C40+BTEX in n-pentane Determination of ydrocarbon il in Water Index 10 Analytes, each 50µg/mL in n-pentane; units: 1x1mL, 1x5mL, 10x1mL Benzene B n-eptane C7 Toluene T n-ctane C8 Ethylbenzene E n-nonane C9 o-xylene o-x n-decane C10 m-xylene m-x n-eicosane C20 p-xylene p-x n-tetracontane C40 S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX III C7+C8+C9+C10-C40 (all even)+btex in n-pentane Determination of ydrocarbon il in Water Index 25 Analytes, each 50µg/mL in n-pentane; units: 1x1mL, 1x5mL, 10x1mL 22

25 Benzene B n-ctadecane C18 Toluene T n-eicosane C20 Ethylbenzene E n-docosane C22 o-xylene o-x n-tetracosane C24 m-xylene m-x n-exacosane C26 p-xylene p-x n-ctacosane C28 n-eptane C7 n-triacontane C30 n-ctane C8 n-dotriacontane C32 n-nonane C9 n-tetratriacontane C34 n-decane C10 n-exatriacontane C36 n-dodecane C12 n-ctatriacontane C38 n-tetradecane C14 n-tetracontane C40 n-exanedecane C16 Methods ther n-alkane solutions available from Chiron (See also the Petroleum section page ) S CY n-alkanes, C10-C40 (all even+pristane/phytane), 18 Analytes S CY n-alkanes, C10-C40 (all even and uneven), 31 Analytes -100-CY S CY n-alkanes, C10-C40 (all even and uneven+pristane/phytane), 33 Analytes S-4066-K-I n-alkanes, C14-C32 (all even+pristane/phytane), 12 Analytes S DCM n-alkanes, C10-C40 (all even+unevenc15-27+pristane/phytane), 24 Analytes IS 10382:2002 Soil quality - rganochlorine pesticides and PCBs Soil quality - Determination of organochlorine pesticides and polychlorinated biphenyls Gas chromatographic method with electron capture detection This International standard specifies a method for the quantitative determination of seven polychlorinated biphenyls and seventeen organochlorine pesticides in soil. Chiron No. Compound Abbr. CAS No Conc. 1 ml Polychlorinated biphenyls I 2,4,4 -Trichlorobiphenyl PCB µg/ml I 2,2,5,5 -Tetrachlorobiphenyl PCB µg/ml I 2,2,4,5,5 -Pentachlorobiphenyl PCB µg/ml I 2,3,4,4 5-Pentachlorobiphenyl PCB µg/ml I 2,2,3,4,4,5 -exachlorobiphenyl PCB µg/ml I 2,2,4,4,5,5 exachloirobiphenyl PCB µg/ml I 2,2 3,4,4,5,5 -eptachlorobiphenyl PCB µg/ml rganochlorine pesticides CY or AN exachlorobenzene CB µg/mL CY or AN α-exachlorocyclohexane α-c µg/mL CY or AN β-exachlorocyclohexane β-c µg/mL CY or AN γ-exachlorocyclohexane (Lindane) γ-c µg/mL CY or AN Aldrin µg/mL CY or AN Dieldrin µg/mL CY or AN Endrin µg/mL CY or AN eptachlor µg/mL CY or AN eptachloro epoxide (exo-, cis-) A-isomer µg/mL 23

26 CY or AN eptachloro epoxide (endo-, trans-) B-isomer µg/mL CY or AN α-endosulfan µg/mL CY or AN p,p -DDE µg/mL CY or AN o,p -DDD µg/mL CY or AN o,p -DDT µg/mL CY or AN p,p -DDD µg/mL CY or AN o,p -DDE µg/mL CY or AN p,p -DDT µg/mL Injection standards I 2,2,4,4,6,6-exachlorobiphenyl PCB µg/ml I 2,2,3,4,5,6 -exachlorobiphenyl PCB µg/ml I 2,2,3,3,4,4,5,6,6 -Nonachlorobiphenyl PCB µg/ml S I S I S I IS Multicomponent Stock Solution of PCBs Dutch Seven PCBs in isooctane, 10µg/mL each, 1x1ml, 5x1ml, 10x1ml 100µg/mL each, 1x1ml, 5x1 ml, 10x1 ml 200µg/mL each, 1x1ml, 5x1 ml, 10x1 ml S I IS Multicomponent Solution of PCBs and rganochlorine pesticides PCBs and pesticides as listed above, each 400µg/mL in isooctane; unit: 1x1ml S I IS Multicomponent Solution of PCBs and rganochlorine pesticides + injection standards PCBs and pesticides as listed above + injection standards and , each 400µg/mL in isooctane; unit: 1x1mL IS 12078, IDF 159:2006 Sterols in milk fat Anhydrous milk fat Determination of sterol composition by gas liquid chromatography (Reference method) This International Standard specifies a gas liquid chromatography reference method for the determination of the sterol composition of anhydrous milk fat extracted from diary products DI Betulin, Internal Standard Solution 1x1mL, 1x10mL, 5x10mL 600µg/mL in di-isopropyl ether X Cholesterol standard solution 1x1mL, 1x10mL 600µg/mL in n-hexane X Campesterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X Stigmasterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X β-sitosterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane 24

27 S-4487 Sterol standard mixture for IS Neat mixture in 1mL sealed ampoule (Ref 9.1.2) for qualitative analysis after silylation Cholesterol 600µg Campesterol 100µg Stigmasterol 100µg Sitosterol 100µg Betulin (IS) 600µg Silylating agents ML ML Trimethylchlorosilane examethyldisiazane Methods IS 12228:1999 Sterols in animal and vegetable fats and oil Animal and vegetable fats and oils Determination of individual and total sterols contents Gas Chromatographic method This International Standard specifies a method for gas chromatographic determination of the contents and compositions of sterols in animal and vegetable fats and oils K-AC K-10AC K-AC K-10AC Betulin, Internal standard solution 1.0 mg/ml in acetone; units: 1x1mL, 1x10mL 5α-Cholestan-3β-ol (Cholestanol), Alternative internal standard 1.0 mg/ml in acetone; units: 1x1mL, 1x10mL S-4498-ASS-AC Standard solution for TLC, IS Analytes, each concentration as listed in acetone; unit: 1x1mL Cholesterol 1mg/mL Betutin 5mg/mL Silylating agent ML N-methyl-N-(trimethylsilyl)-heptafluorobutyramide (MSFBA) S I Identification mixture for sterols 10 Analytes, each 50µg/mL in isooctane; unit: 1x1mL Cholesterol Cholestanol Brassicasterol Champesterol Stigmasterol Sitosterol Sitostanol Erythodiol Uvaol Betulin 25

28 IS 13877:1998 Soil quality - 16 PAs by PLC Soil quality - Determination of polynuclear aromatic hydrocarbons - Method using high-performance liquid chromatography This standard describes two methods for quantification of ploynuclear aromatic hydrocarbons (PA) in soil. S AN IS Standard stock solution 16 Analytes, each 50µg/mL in acetonitrile; unit: 1x1.1mL Naphthalene [ ] Acenaphthylene [ ] Acenaphthene [ ] Fluorene [ ] Phenanthrene [ ] Anthracene [ ] Fluoranthene [ ] Pyrene [ ] Benzo[a]anthracene [ ] Chrysene [ ] Benzo[b]fluoranthene [ ] Benzo[k]fluoranthene [ ] Benz[a]pyrene [ ] Dibenzo[a,h]anthracene [ ] Benz[ghi]perylene [ ] Indeno[1,2,3-cd]pyrene [ ] IS 14154:2005 Soil quality Phenols by GC-ECD Soil quality - Determination of some selected chlorophenols Gas Chromatographic method with electron-capture detection The method describes the gas chromatographic determination of 15 chlorophenols (2,3-, 2,4-, 2,5-, 2,6-, 3,4-, and 3,5-dichlorophenol; 2,3,4-, 2,3,5-, 2,3,6-, 2,4,5-, 2,4,6-, and 3,4,5-trichlorphenol; 2,3,4,5- and 2,3,4,6-tetrachlorophenol and pentachlorophenol) in soil samples. This method can also be applied to other solid samples such as sediments and solid wastes. The method provides a procedure for solid/liquid extraction and purification based on successive extractions in basic and acidic aqueous media and hexane. Finally the chlorophenols are derivatized with acetic anhydride and analyzed by gas chromatography with electron capture or mass detection. S ,4,6-Tribromophenol, Internal Standard Stock Solution mg/ml, in ethanol, 5mL Alternative Internal Standards: S ,4-Dibromophenol, Internal Standard Stock Solution S ,6-Dibromophenol, Internal Standard Stock Solution 26

29 S-4364-ASS-ET Chlorophenol Standard, Stock Solution 15 Analytes, each concentration as listed in ethanol; unit: 5x1mL ,3-Dichlorophenol [ ] 400 µg/ml ,4-Dichlorophenol [ ] 400 µg/ml ,5-Dichlorophenol [ ] 400 µg/ml ,6-Dichlorophenol [ ] 400 µg/ml ,4-Dichlorophenol [ ] 400 µg/ml ,5-Dichlorophenol [ ] 400 µg/ml ,3,4-Trichlorophenol [ ] 400 µg/ml ,3,5-Trichlorophenol [ ] 400 µg/ml ,3,6-Trichlorophenol [ ] 400 µg/ml ,4,5-Trichlorophenol [ ] 400 µg/ml ,4,6-Trichlorophenol [ ] 600 µg/ml ,4,5-Trichorophenol [ ] 200 µg/ml ,3,4,5-Tetrachlorophenol [ ] 200 µg/ml ,3,4,6-Tetrachlorophenol [ ] 600 µg/ml Pentachlorophenol [ ] 1000 µg/ml Methods IS 15009:2002 Soil quality Volatile compounds by GC/purge-and-trap Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons Purge-and-trap method with thermal desorption This International Standards specifies a method for quantitative gas-chromatographic determination of volatile hydrocarbons, naphthalene and volatile hydrocarbons in all types of soil. S K-5ME IS Stock internal standard solution for aromatic hydrocarbons 2 Analytes, each 2000µg/mL in methanol; unit: 1x5mL Toluene-d8 [ ] Ethylbenzene-d10 [ ] S K-5ME IS Stock internal standard solution for volatile halogenated hydrocarbons 3 Analytes, each 2000µg/mL in methanol; unit: 1x5mL ,4-Dichlorobutane [ ] α,α,α-trifluorotoluene [ ] Bromofluorobenzene [ ] 27

30 S K-5ME IS Volatile aromatic hydrocarbons 8 Analytes, each 4000µ/mL in methanol; unit: 1x5mL Benzene [ ] Toluene [ ] Ethylbenzene [ ] o-xylene [ ] m-xylene [ ] p-xylene [ ] Styrene [ ] Naphthalene [ ] S K-5ME IS Volatile halogenated hydrocarbons 18 Analytes, each 4000µg/mL in methanol; unit: 1x5mL Dichloromethane [ ] Trichloromethane [ ] Tetrachloromethane [ ] ,1-Dichloroethane [ ] ,2-Dichloroethane [ ] ,1,1-Trichloroethane [ ] ,1,2-Trichloroethane [ ] ,2-Dichloropropane [ ] ,2,3-Trichloropropane [ ] cis-1,3-dichloropropene [ ] trans-1,3-dichloropropene [ ] cis-1,2-dichloroethene [ ] trans-1,2-dichloroethene [ ] Chloropropene [ ] Trichloroethene [ ] Tetrachloroethene [ ] Monochlorobenzene [ ] ,2-Dichlorobenzene [ ] IS 15680:2003 Water quality Volatile compounds by GC/purge-and-trap Water quality - Gas-chromatographic determination of a number of monocyclic aromatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and thermal desorption. This International Standard specifies a general method for the determination of volatile organic compounds (VCs) in water by purge-and-trap isolation and gas chromatography (GC). S K-5ME IS Stock internal standard solution 4 Analytes, each 2000µg/mL in methanol; unit: 1x5mL Fluorobenzene [ ] ,4-Difluorobenzene [ ] Monochlorobenzene-d5 [ ] ,4-Dichlorobenzene-d4 [ ] 28

31 S K-5ME IS Stock calibration standard solution 1 14 Analytes to be used with Internal standard S1, each 2000µg/mL in methanol; unit: 1x5mL Dichlorodifluoromethane [ ] Monochloromethane [ ] Monobromomethane [ ] Monochlorethane [ ] Trichlorofluoromethane [ ] ,1-Dichloroethene [ ] Dichloromethane [ ] trans-1,2-dichloroethene [ ] ,1-Dichloroethane ] ,2-Dichloropropane [ ] cis-1,2-dichloroethene ] Bromochloromethane [ ] Trichloromethane [ ] ,1,1-Trichloroethane [ ] Methods S K-5ME IS Stock calibration standard solution 2 12 Analytes to be used with Internal standard S2, each 2000µg/mL in methanol; unit: 1x5mL Tetrachloromethane [ ] ,1-Dichloropropene [ ] Benzene [ ] ,2-Dichloroethane [ ] Trichloroethene [ ] ,2-Dichloropropane [ ] Dibromomethane [ ] Bromodichloromethane [ ] trans-1,3-dichloropropene [ ] Toluene [ ] cis-1,3-dichloropropene [ ] ,1,2-Trichloroethane [ ] ,2-Dibromoethane [ ] S K-5AN IS Stock calibration standard solution 3 11 Analytes to be used with Internal standard S3, each 2000µg/mL in methanol; unit: 1x5mL Tetrachloroethene [ ] ,3-Dichloropropane [ ] Dibromochloromethane [ ] Monochlorobenzene [ ] ,1,1,2-Tetrachlorethane [ ] Ethylbenzene [ ] m-xylene [ ] p-xylene [ ] o-xylene [ ] Styrene [ ] Tribromomethane [ ] 29

32 S K-5ME IS Stock calibration standard solution 4 22 Analytes to be used with Internal standard S1, each 2000µg /ml in methanol; unit: 1x5mL Isopropylbenzene [ ] Monobromobenzene [ ] ,1,2,2-Tetrabromoethane [ ] ,2,3-Trichloropropane [ ] n-propylbenzene [ ] Chlorotoluene [ ] Chorotoluene [ ] ,3,5-Trimethylbenzene [ ] tert-butylbenzene [ ] ,2,4-Trimethylbenzene [ ] sec-butylbenzene [ ] ,3-Dichlorobenzene [ ] ,4-Dichlorobenzene [ ] Isopropyltoluene [ ] ,2-Dichlorobenzene [ ] n-butylbenzene [ ] ,2-Dibromo-3-chloropropane [ ] ,2,4-Trichlorobenzene [ ] exachlorobutadiene [ ] Naphthalene [ ] ,2,3-Trichlorobenzene [ ] ,3,5-Trichlorobenzene [ ] IS 15753:2006 PAs in animal and vegetable fats and oils Animal and vegetable fats and oils Determination of polycyclic aromatic hydrocarbons This International Standard describes two methods for the determination of 15 polycyclic aromatic hydrocarbons in animal and vegetable fats and oils. The quantification limit is 0.2µg/kg for all compounds, except fluoranthene and benzo[ghi]perylene where the limit is 0.3µg/kg and indeno[1,2,3-cd]pyrene where the limit is 1µg/kg. S T IS Multiple compound standard solution 15 Analytes, each 100µg/mL in toluene; unit: 1x1mL Naphthalene [ ] Acenaphthene [ ] Fluorene [ ] Phenanthrene [ ] Anthracene [ ] Fluoranthene [ ] Pyrene [ ] Benzo[a]anthracene [ ] Chrysene [ ] Benzo[b]fluoranthene [ ] Benzo[k]fluoranthene [ ] Benzo[a]pyrene [ ] Dibenzo[a,h]anthracene [ ] 30

33 Benz[ghi]perylene [ ] Indeno[1,2,3-cd]pyrene [ ] S AN IS Multiple compound stock standard solution 15 analytes, each 200ng/mL in acetonitrile; unit: 1x5mL S MX IS Multiple compound working standard solution 15 analytes, each 50ng/mL in acetonitrile/tf/methanol; unit: 1x5mL S T Alternatively: Standard solution of 16 EPA-PAs may be used, but this mixture also contain acenaphtene EPA 100µg each/ml in toluene; unit: 1x1mL Methods IS :2006 Animal and vegetable fats and oils Determination of stigmastadienes in vegetable oils Part 2: Method using high-performance liquid chromatography (PLC) This part of IS specifies a method for the determination of steradienes, especially stigmastadienes. Steradienes are formed by dehydration of sterols during bleaching and also partially during steam washing and deodorization. The method is also suitable as a screening method to detect the presence of refined vegetable oils in virgin oils such as olive oil. 3,5-Cholestadiene stock solution 1mg/mL in tert-butyl methyl ether 3,5-Cholestadiene External standard solution 10µg/mL (0.01µg/µL) in acetonitrile/ tert-butyl methyl ether 1:1 3,5-Cholestadiene Internal standard solution 2µg/mL in petroleum ether 5α-Cholestane standard solution for GC 1mg/mL in isooctane Reference standards for cholesta-, campesta- and stigmastadienes and stigmastatriene I I I Cholestadiene Stigmastatriene Campestadiene and Stigmastadiene 31

34 IS 17353:2004 rganotin compounds in water Water quality - Determination of selected organotin compounds Gas Chromatographic method This International Standard specifies a method for the identification and quantification of organotin compounds and/or cation in drinking water, surface water and wastewater. The principle is alkylation of the organotin compounds in water with sodium tetraethylborate and extraction with hexane. The tetrasubstituted organotin compounds are separated by GC and detected by Mass spectrometry, FPD or AED. S-4380-K-5ME IS 17353/23161 Multicomponent C* Standard Solution, Stock Solution A 8 Analytes, each 1000µg/mL C in methanol; units: 5x1mL, 5x5mL * C: rganotin cation CT: rganotin compound Prod.No. Compound CAS No. Weight CT Mono-n-butyltin trichloride [ ] 1605 µg/ml Di-n-butyltin dichloride [ ] 1304 µg/ml Tri-n-butyltin chloride [ ] 1122 µg/ml Tetra-n-butyltin [ ] 1000 µg/ml Mono-n-octyltin trichloride [ ] 1458 µg/ml Di-n-octyltin dichloride [ ] 1205 µg/ml Triphenyltin chloride [ ] 1101 µg/ml Tricyclohexyltin chloride [ ] 1096 µg/ml S-4381-K-ME S-4381-K-5ME IS 17353/23161 Internal Standard C, Stock Solution B 4 Analytes, each 1000µg/mL C in methanol; units: 5x1mL, 5x5mL Prod.No. Compound CAS No. Weight CT Di-n-heptyltin dichloride [ ] 1224 µg/ml Mono-n-heptyltin trichloride [ ] 1488 µg/ml Tri-n-propyltin chloride [ ] 1143 µg/ml Tetra-n-propyltin [ ] 1000 µg/ml IS 17495:2001 Water quality - Nitrophenols by GC-MS Water quality - Determination of selected nitrophenols - Method by solid phase extraction and gas chromatography with mass spectrometric detection This international method specifies a method for the determination of selected nitrophenols in drinking water, ground water and surface water. The method provides a procedure for solid-phase extraction of nitrophenols, followed by solvent elution, derivatization with diazomethane and determination by gas chromatography and mass spectrometry. 32

35 S AC IS Methylated Phenols Stock Solution, 14 Analytes, each 500µg/mL in acetone; units: 5x1mL Prod.No. Compound CAS No Nitroanisole [ ] Nitroanisole [ ] Nitroanisole [ ] Methyl-2-nitroanisole [ ] Methyl-4-nitroanisole [ ] Methyl-2-nitroanisole [ ] Methyl-2-nitroanisole [ ] ,4-Dinitroanisole [ ] ,5-Dinitroanisole [ ] ,6-Dinitroanisole [ ] ,4-Dinitro-6-methylanisole [ ] ,6-Dichloro-4-nitroanisole [ ] ,4-Dichloro-6-nitroanisole [ ] ,6-Dimethyl-4-nitroanisole [ ] Methods S AC IS Nonmethylated Phenols Stock Solution, 14 Analytes, each 500µg/mL in acetone; units: 5x1mL Prod.No. Compound CAS No Nitrophenol [ ] Nitrophenol [ ] Nitrophenol [ ] Methyl-2-nitrophenol [ ] Methyl-4-nitrophenol [ ] Methyl-2-nitrophenol [ ] Methyl-2-nitrophenol [ ] ,4-Dinitrophenol [ ] ,5-Dinitrophenol [ ] ,6-Dinitrophenol [ ] ,4-Dinitro-6-methylphenol [ ] ,6-Dimethyl-4-nitrophenol [ ] ,4-Dichloro-6-nitrophenol [ ] ,6-Dichloro-4-nitrophenol [ ] S AC IS Internal Standard Stock Solution 2 Internal standards, each 10µg/mL in acetone; unit: 1x5mL ,4-Dibromophenol [ ] ,4,6-Tribromophenol [ ] The following compounds are suggested as alternative Internal Standards for this method: ,4-Dibromophenol [ ] ,6-Dibromophenol [ ] Deuterated or 13 C-labelled substances 33

36 IS 17858:2007 Water quality - Dioxin-like PCBs Water quality - Determination of dioxin-like polychlorinated biphenyls Method using gas chromatography/mass spectrometry This International Standard specifies a method for the determination of tetra- to hepta- dioxin-like polychlorinated Biphenyls (PCBs) in waters and waste waters using high resolution gas chromatography/high resolution mass spectrometry (RGC/RMS). The method is optimized for dioxin-like PCBs, but may include other co-planar compounds as Polychlorinated Dioxins and Furans. S N Precition and recovery (PAR) standard solution Dioxin-like PCBs each in 20ng/mL solution in n-nonane; unit: 1x1mL Chiron No. Dioxin-like PCBs PCB No. CAS No ,3 4,4 -TetraCB PCB-77 [ ] ,4,4,5-TetraCB PCB-81 [ ] ,3,3,4,4 -PentaCB PCB-105 [ ] ,3,4,4,5-PentaCB PCB-114 [ ] ,3,4,4,5-PentaCB PCB-123 [ ] ,3,4,4,5-PentaCB PCB-126 [ ] ,3,3,4,4,5-exaCB PCB-156 [ ] ,3,3,4,5 -exacb PCB-157 [ ] ,3,4,4,5,5 -exacb PCB-167 [ ] ,3,4,4,5,5 -exacb PCB-169 [ ] ,2,3,4,4 5-eptaCB PCB-170 [ ] ,2,3,3,4,4,5,5 -eptacb PCB-180 [ ] ,3,3,4,4,5,5 -eptacb PCB-189 [ ] S N Labelled compound spiking solution Dioxin-like F-PCBs each in 20ng/mL solution in n-nonane; unit: 1x1mL Chiron No. Dioxin-like IS, FluoroPCBs PCB No F-3,3,4,4 -TetraCB F-PCB F-3,4,4,5-TetraCB F-PCB F-2,3,3,4,4 -PentaCB F-PCB F-2,3,4,4,5-PentaCB F-PCB F-3,3,4,4,5-PentaCB F-PCB F-2,3,3,4,4,5-exaCB F-PCB F-2,3,4,4,5,6-exaCB F-PCB-166 (PCB-167,169) F-2,3,3,4,4,5,6-eptaCB F-PCB-190 (PCB-189) Single F-labelled compounds are available in concentrations µg/mL in isooctane. Single native compounds are available in concentrations 100µg/mL in isooctane. 34

37 IS 17993:2002 Water quality 15 PAs by PLC Water quality - Determination of 15 polycyclic aromatic hydrocarbons (PA) in water by PLC with fluorescence detection after liquid-liquid extraction This International Standard specifies a method using high performance liquid chromatography (PLC) with fluorescence detection after liquid-liquid extraction for the determination of 15 selected PA in drinking water and ground water in mass concentrations greater than 0.005µg/L (for each single compound) and surface water in mass concentrations above 0.01µg/L. S AN IS Multiple compound stock solution 15 Analytes, each 10µg/mL in acetonitrile; unit: 1x1mL Methods Naphthalene [ ] Acenaphthene [ ] Phenanthrene [ ] Fluoranthene [ ] Benzo[a]anthracene [ ] Benzo[b]fluoranthene [ ] Benz[a]pyrene [ ] Dibenzo[a,h]anthracene [ ] Fluorene [ ] Anthracene [ ] Pyrene [ ] Chrysene [ ] Benzo[k]fluoranthene [ ] Indeno[1,2,3-cd]pyrene [ ] Benz[ghi]perylene [ ] AN Additional compound: Methylchrysene [ ] 10 µg/ml in acetonitrile, 1 ml IS 18252, IDF 200:2006 Sterols in milk fat by GC Anhydrous milk fat Determination of sterol composition by gas liquid chromatography (Routine method) This Internal Standard specifies a routine gas liquid chromatography method for the determination of the sterol composition in anhydrous milk fat extracted from dairy products directly on the unsaponifiable matter, without purification and derivatization X 5α-Cholestane (99+%), Internal standard solution 1x1mL, 1x10mL X 600µg/mL in n-hexane/ethanol (1:10) or n-hexane X Cholesterol (99+%) standard solution 1x1mL, 1x10mL X 600µg/mL in n-hexane 35

38 X Campesterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X Stigmasterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X β-sitosterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane S-4494 Sterol standard mixture for IS For Qualitative analysis, neat in 1mL sealed ampoulle Cholesterol 600µg Campesterol 100µg Stigmasterol 100µg Sitosterol 100µg α-Cholestane (IS) 600µg Dissolve in 0.25 ml n-hexane for split injector or 3mL for on-column injector IS : 2005 Water quality - Alkylphenols by GC-MS Water quality - Determination of selected alkylphenols Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection This method specifies a method for the determination of 4-nonylphenol (mixture of isomers) and 4-(1,1,3,3- tetramethylbutyl)phenol in non-filtered samples of drinking water, ground water and surface water. The method provides procedures for the determination of phenols in finished drinking water. This method can also be used on untreated course water and other types of water samples. A large variety of phenols can be determined by this method. S AC IS n-Nonylphenol (ring13c6), Internal standard 1 ng/µl, in acetone, 5 ml AC IS n-Nonylphenol-2,3,5,6-d4, Alternative Int. standard 1 ng/µl, in acetone, 5 ml S T IS n-Nonylphenol solution, Calibration standard 1 ng/µl, in toluene, 5 ml = T S T IS (1,1,3,3-Tetramethylbutyl)phenol solution, Calibration standard 1 ng/µl, in toluene, 5 ml = T 36

39 IS 22032:2006 Water quality - PBDEs by GC-MS Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge Method using extraction and gas chromatography/mass spectrometry. This International standard specifies a method for the determination of selected polybrominated diphenylethers (PBDE) in sediment and sludge using GC and mass spectrometry (GC-MS) in the electron impact (EI) or negative ion chemical ionization (NCI) mode. IS Solutions of single reference substances / internal standards ( 5.7): Chiron No. Compound Abbr. Conc. Natives T 2,2,4,4 -Tetrabromodiphenylether PBDE µg/ml T 2,2,4,4,5-Pentabromodiphenylether PBDE µg/ml T 2,2,4,4,6-Pentabromodiphenylether PBDE µg/ml T 2,2,4,4,5,5 -exabromodiphenylether PBDE µg/ml T 2,2,4,4,5,6 -exabromodiphenylether PBDE µg/ml T 2,2,3,4,4,5,6-eptabromodiphenylether PBDE µg/ml T 2,3,3 4,4,5,5,6-ctabromodiphenylether PBDE µg/ml T Decabromodiphenylether PBDE µg/ml Methods Internal Standards F-PBDEs T 6-Fluoro-2,2,4,4 -tetrabromodiphenylether F-PBDE µg/ml T 5,5 -Difluoro-2,2,4,4 -tetrabromodiphenylether 2F-PBDE µg/ml T 3,6-Difluoro-2,2,4,4 5-pentabromodiphenylether 2F-PBDE µg/ml T 3-Fluoro-2,2 4,4,6-pentabromodiphenylether F-PBDE µg/ml T 4 -Fluoro-2,3,3,4,5,6-hexabromodiphenylether F-PBDE µg/ml T 3 -Fluoro-2,2,3,4,4,5,6-hexaBDE F-PBDE µg/ml T 4,6-Difluoro-2,2,3,3,4,5,5,6-octaBDE 2F-PBDE µg/ml T 4 -Fluoro-2,2,3,3,4,5,5,6,6 -nonabromodiphenylether F-PBDE µg/ml Additional Internal Standards T 3 -Fluoro-2,4-dibromodiphenylether F-PBDE-7 50 µg/ml T 3 -Fluoro-3,4-dibromodiphenylether F-PBDE µg/ml T 4 -Fluoro-2,3,4-tribromodiphenylether F-PBDE µg/ml T 4 -Fluoro-2,3,6-tribromodiphenylether F-PBDE µg/ml T 2 -Fluoro-,2,4,4 -tribromodiphenylether F-PBDE µg/ml T 6-Fluoro-2,3,4,4 -tetrabromodiphenylether F-PBDE µg/ml T 4 -Fluoro-2,3,4,6-tetrabromodiphenyleteher F-PBDE µg/ml T 5,6-Difluoro-2,2,3,4,4 -pentabromodiphenylether 2F-PBDE µg/ml T 3,5-Difluoro-2,3,4,4,6-pentabromodiphenylether F-PBDE µg/ml T 3,3,4,4 -Tetrabromodiphenylether PBDE µg/ml T 2,2 3,4,4,5,6-eptabromodiphenylether PBDE µg/ml For a complete list of internal standards see the Compounds section pages

40 S I Multicomponent Stock Solution of native reference substances ( 5.8) 8 Analytes, each 50µg/mL in isooctane; unit: 1x1mL S-4389-SET Calibration Curve Set, Native Compounds ( 5.9) Set of 7 solutions in isooctane/toluene; unit: 7x1mL Compound Solution 1 Solution 2 Solution 3 Solution 4 Solution 5 Solution 6 Solution 7 ng/ml ng/ml ng/ml ng/ml ng/ml ng/ml ng/ml PBDE PBDE PBDE PBDE PBDE PBDE PBDE PBDE Calibration curve sets S-4389 including fluorinated internal standards of choice are available on request ( 5.9) IS Fluorinated Internal Standard Calibration curve Set and Stock solutions are available on request ( 5.10) IS/DIS 23161: 2007 rganotin compounds in soil by GC Soil quality - Determination of selected organotin compounds Gas Chromatographic method This International Standard specifies a method for the identification and quantification of organotin compounds and/or cations in solids such as soil, sediments and waste. The principle: See IS 17353, page 32. S-4380-K-ME S-4380-K-5ME IS 17353/23161 Multicomponent C* Standard Solution, Stock Solution A 8 Analytes, each 1000µg/mL C in methanol; units: 5x1mL, 5x5mL * C: rganotin cation CT: rganotin compound Prod.No. Compound CAS No. Weight CT Mono-n-butyltin trichloride [ ] 1605 µg/ml Di-n-butyltin dichloride [ ] 1304 µg/ml Tri-n-butyltin chloride [ ] 1122 µg/ml Tetra-n-butyltin [ ] 1000 µg/ml Mono-n-octyltin trichloride [ ] 1458 µg/ml Di-n-octyltin dichloride [ ] 1205 µg/ml Triphenyltin chloride [ ] 1101 µg/ml Tricyclohexyltin chloride [ ] 1096 µg/ml 38

41 S-4381-K-ME S-4381-K-5ME IS 17353/23161 Internal Standard C, Stock Solution B 4 Analytes, each 1000µg/mL C in methanol; units: 5x1mL, 5x5mL Prod.No. Compound CAS No. Weight CT Di-n-heptyltin dichloride [ ] 1224 µg/ml Mono-n-heptyltin trichloride [ ] 1488 µg/ml Tri-n-propyltin chloride [ ] 1143 µg/ml Tetra-n-propyltin [ ] 1000 µg/ml K-ME IS Injection standard K-5ME Tetra-n-pentyltin [ ] 2000µg/mL in methanol; units: 5x1mL, 5x5mL Methods 39

42 EN standards EN 12916:2006 Aromatic compounds in middle distillates Petroleum products Determination of aromatic hydrocarbon types in middle distillates. igh performance liquid chromatography method with refractive index detection. This European Standard specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels that may contain fatty acid methyl esters (FAME) up to 5% (V/V) and petroleum distillates in the boiling range ºC. System calibration standards: S-4491-ASS-5P EN System Calibration Standards 1 (SCS1) 7 Analytes, each concentration as listed in n-heptane; units: 1x5mL or 5x5mL Weight% based on the nearest 0.1mg Cyclohexane (5.1) [ ] 1.0g/100mL Phenyldodecane (5.3) [ ] 0.1g/100mL Dimethylbenzene (5.4) [ ] 0.5g/100mL examethylbenzene (5.5) [ ] 0.01g/100mL Naphthalene (5.6) [ ] 0.01g/100mL Dibenzothiophene (5.9) [ ] 0.05g/100mL Methylanthracene (5.10) [ ] 0.05g/100mL S-4492-ASS-5P EN System Calibration Standards 2 (SCS2) 2 Analytes, each concentration as listed in n-heptane; units: 1x5mL or 5x5mL 3416 FAME (5.12) as Linoleic acid methyl ester ( ) 0.4g/100mL Chrysene (5.11) 0.04g/100mL See EN 14214, page 44. S-4493-ASS-P S-4493-ASS-5P EN Calibration Standards 4 Analytes, each concentration as listed in n-heptane; units: 4x1.5mL Certan bottle, 4x5mL screw cap bottle Calibration 1,2-Dimethylbenzene Fluorene Phenanthrene Standard g/100ml g/100ml g/100ml A B C D

43 EN Additional standards, see the Compounds section and the Applications / Petroleum sections: Nonaromatics: n-paraffin mixtures Cyclohexane mix Naphthene/paraffin mixtures Mono-alkenes Monoaromatics: Alkylbenzene mix Tetralines Indanes Naphthenobenzenes (octahydrophenanthrenes) Thiophenes Styrenes Conjugated polyalkenes Diaromatics: See the PA-section, naphthalenes, biphenyls, acenaphthenes, benzo-and dibenzothiophenes Triaromatics: NDP- and NDP/PA-mixtures PA-section: phenanthrenes, pyrenes,fluoranthenes, chrysenes, triphenylenes, benzanthrenenes, triaromatic steranes Methods Please inquire by fax or for custom made mixes EN 14078:2004 Liquid petroleum products Determination of Fatty Acid Methyl Esters (FAME) in middle distillates - Infrared spectroscopy method This European standard specifies a test method for the determination of Fatty Acid Methyl Ester (FAME) content in diesel fuel or domestic heating fuel by mid infrared spectrometry in the range 1.7% to 22.7% (V/V). FAME calibration solutions S-4495-SET-10CY FAME*, as Linoleic acid methyl ester (Chiron No ), concentration in cyclohexane 1, 2, 4, 6, and 10 g/l; unit: 5x10mL *Fame: EN 14214, page 44. EN 14103:2003 FAME for use in biofuels, diesel fuels Fat and oil derivatives Fatty Acid Methyl Esters (FAME) - Determination of ester and linolenic acid methyl ester contents The purpose of this European Standard is to determine the content of fatty acid methyl esters (FAME) intended for use as biofuels or as a blending component for heating and diesel fuels. It also allows the determination the linolenic acid methyl ester content. It allows one to verify the ester content of FAME is greater than 90% by mass (m/m) and that the linolenic acid content is between 1% and 15%. The method is suitable for FAME which contains methyl esters between C14 and C24. 41

44 Internal standard K-30P Methyl heptadecanoate, 99+% 10 mg/ml in n-heptane, 30 ml S AC FAME Reference Mixture (rape seed methyl esters): 13 Analytes, each 100µg/mL each /ml in acetone; unit: 1x1mL Palmitic C16 [ ] Palmitolic C16:1 [ ] eptadecanoic C17 [ ] Internal standard Steraric C18 [ ] leic C18:1 [ ] Linoleic C18:2 [ ] Linolenic C18:3 [ ] Arachdic C20 [ ] Eicosenoic acid (11c) C20:1 [ ] Behenic C22 [ ] Erucic C22:1 [ ] Lignoceric C24 [ ] Nervonic C24:1 [ ] EN 14105:2003 Fat and oil derivatives Fatty Acid Methyl Esters (FAME) -Determination of free and total glycerol and mono-, di-, triglyceride contents (Reference method) This European Standard specifies a method to determine the free glycerol and residual mono-, di-and triclyceride contents in fatty acid methyl ester (FAME) intended for addition to mineral oils. The total glycerol content is then calculated from the results obtained. This method is suitable for FAME from rapeseed, sunflower and soybean oils, but is not suitable for FAME produced from or containing coconut and palm kernel oils because of overlapping of peaks. Derivatizing agent ML N-methyl-N-trimethylsilyltrifluoroacetamide (MSTFA) G [ ] 1mL, 5 g neat Internal standards ML 1,2,4-Butanetriol (Internal Standard No. 1) [ ] 1mL neat ML 1,2,3-Tricaproylglycerol (tricarpin, Internal Standard No. 2) [ ] 1mL neat 42

45 K-10PY Internal Standard No. 1 stock solution 1000µg/mL in dry pyridine 1x10 ml K-10PY Internal Standard No. 2 stock solution 1000µg/mL in dry pyridine 1x10 ml Reference substances Glycerol [ ] Monooleoylglycerol (monoolein) [ ] ,3-Dioleoylglycerol (diolein) [ ] ,2,3-Trioleoylglycerol (triolein) [ ] Methods PY Glycerol stock solution 500µg/mL in dry pyridine 1x10 ml K-10PY 1-Monooleoylglycerol (monoolein) stock solution 5000µg/mL in dry pyridine 1x10 ml K-10PY 1,3-Dioleoylglycerol (diolein) stock solution 5000µg/mL in dry pyridine 1x10 ml K-10PY 1,2,3-Trioleoylglycerol (triolein) stock solution 5000µg/mL in dry pyridine 1x10 ml S K-10PY Monoglycerides: 3 analytes, each 10 mg/ml in dry pyridine; unit: 1x10 ml Monopalmitoylglycerol (monopalmitin) [ ] Monostearoylglycerol (monostearin) [ ] Monooleoylglycerol (monoolein) [ ] Calibration solutions Calibration solution Syringe, µl µl of glycerol solution µl of monoolein solution µl of diolein solution µl of triolein solution µl of internal standard sol. No µl of internal standard sol. No To be prepared daily from the above solutions 43

46 EN 14214:2003 Automotive fuels - Fatty acid methyl esters (FAME) for diesel engines - Requirements and test methods This European standard exists in parallel with: EN 590 Automotive fuels Diesel Requirements and test methods. EN 14214:2003 Requirements Property Unit Min Max Method Ester content % (m/m) 96.5 EN Density at 15ºC kg/m EN IS 3675 EN IS Viscosity at 40ºC mm2/s EN IS 3104 Flash point ºC pren IS 3679 Sulfur content mg/kg pren IS pren IS Carbon residue % (m/m) - 0,30 EN IS (on 10% distillation residue) Cetane number 51.0 EN IS 5165 Sulfated ash content % (m/m) 0.02 IS 3987 Water content mg/kg EN IS Total contamination mg/kg - 24 EN Copper strip corrosion rating Class 1 EN IS 2160 (3 h at 50ºC) xidation stability, 110ºC hours 6.0 EN Acid value mg K/100 gr 0.50 EN Iodine number gr iodine/100g 120 EN Linolenic acid methyl ester % (m/m) 12.0 EN Polyunsaturated % (m/m) 1 (>=4 double bonds) Methanol content % (m/m) 0.80 EN Monoglyceride cont. % (m/m) 0.80 EN Diglyceride content % (m/m) 0.20 EN Triglyceride cont. % (m/m) 0.20 EN Free glycerol % (m/m) 0.02 EN EN Total glycerol % (m/m) 0.25 EN Gr. I metals (Na+K) mg/kg 5.0 EN EN Gr. II met. (Ca+Mg) mg/kg 5.0 pren Phosphorous cont. mg/kg EN Atmospheric equivalent temperature, 90 % recovered 44

47 ASTM methods ASTM D Acid number of petroleum products by potentiometric titration Standard test method for acid number of petroleum products by potentiometric titration. This test method covers procedures for the determination of acidic constituents in petroleum products and lubricants soluble or nearly soluble in mixtures of toluene and 2-propanol. It is applicable for the determination of acids whose dissociation constants in water are larger than 10-9 ; extremely weak acids whose dissociation are smaller than 10-9 do not interfere. Methods S-4069-S Solvent, ASTM D L and 10x1 L Toluene 50.0 % Isopropanol 49.5 % Water, ionfree 0.5 % S-4069-T Titrant for ASTM D M solution; units. 5x1, 10x1, 20x1 L K in Isopropanol ASTM D Thiophene in benzene Standard test method for traces of thiophene in benzene by spectrophotometry This test method covers the determination of thiophene in benzene in which the thiophene concentration is between 0.1 and 250 mg/kg. S-4059 Thiophene in Benzene See ASTM D ASTM D Sulfur in petroleum products Standard test method for sulfur in petroleum products by wavelength dispersive fluorescence X-Ray spectrometry This test method covers the determination of total sulfur in liquid petroleum products and in solid petroleum products that can be liquefied with moderate heating. ptimum conditions allow the determination of sulfur in paraffinic samples at concentrations exceeding mass % (20 ppm). 45

48 S-4051/S-4052 Calibration Mixtures: Di-n-butyl sulfide in White il (less than 5 mg sulfur/l) Unit : 10 ml screw cap bottle Light White Mineral il eavy White Mineral il (20 cst at 40 C) (70 cst at 40 C) µgs/g (ppm) Wt.% S LW S W Blank 0 S LW S W 10 0,001 S LW S W S LW S W S LW S W S LW S W S LW S W S-4052-K-LW S-4051-K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S-4052-Kit S-4051-Kit Kit of above solutions ASTM D a Boiling range distribution of petroleum fractions Standard test method for boiling range distribution of petroleum fractions by gas chromatography. This test method covers the determination of the boiling range distribution of petroleum products. This test method can be used to petroleum products and fractions having a final boiling point of 538 C (1000 F) or lower at atmospheric pressure as measured by this test method. This test method is limited to samples having a boiling range greater than 55 C (100 F), and having a vapour pressure sufficiently low to permit sampling at ambient temperature. S CS Calibration Mixture C5-C44 (Revised) 18 Analytes, each 100µg/mL in CS2; unit: 1x1mL in Certan bottle Use for assessing column resolution as well as for quantitative analyses. n-pentane C5 n-ctadecane C18 n-exane C6 n-eicosane C20 n-eptane C7 n-tetracosane C24 n-ctane C8 n-ctacosane C28 n-nonane C9 n-dotriacontane C32 n-decane C10 n-exatriacontane C36 n-undecane C11 n-tetracontane C40 n-dodecane C12 n-tetratetracontane C44 n-tetradecane C14 n-exadecane C16 46

49 S MX ydrocarbon Window Defining Standard C8-C40 35 Analytes, each 500 µg/ml in CS2:C2Cl2 (3:1); units: 1x1mL, 1x4.5mL in Certan bottle ctane C8 Nonadecane C19 Triacontante C30 Nonane C9 Phytane C20 n-entriacontane C31 Decane C10 Eicosane C20 Dotriacontane C32 Undecane C11 eneicosane C21 Tritriacontane C33 Dodecane C12 Docosane C22 Tetratriacontane C34 Tridecane C13 Tricosane C23 Pentatriacontane C35 Tetradecane C14 Tetracosane C24 exatriacontane C36 Pentadecane C15 Pentacosane C25 eptatriacontane C37 exadecane C16 exacosane C26 ctatriacontane C38 eptadecane C17 eptacosane C27 Nonatriacontane C39 ctadecane C18 ctacosane C28 Tetracontane C40 Pristane C19 Nonacosane C29 Methods S K-C Column Resolution Test Mix C16-C18 2 Analytes, each 1 mass % in n-octane; unit: 5x1 ml n-exadecane n-ctadecane C16 C18 S K-MX Fuel il Degradation/Retention Time Mix C17-C20 4 Analytes, each 2,0 mg/ml in CS2:C2Cl2 (1:1); unit: 1x4.5mL in Certan Use this standard for the quantification of C17/Pristane and C18/Phytane ratios. eptadecane ctadecane Pristane (2,6,10,14-Tetramethylpentadecane) Phytane (2,6,10,14-Tetramethylhexadecane) C17 C18 C19 C20 ASTM D e1 Sulfur in light liquid petroleum hydrocarbons Standard test method for trace quantities of sulfur in light liquid petroleum hydrocarbons by oxidative microcoulometry This test method covers determination of sulfur in the range ppm (mg/kg) in light liquid hydrocarbons boiling at 26 to 274 C (80 to 525 F). 47

50 S-4050-ASS-I Calibration Mixtures: Di-n-butyl sulfide in Isooctane Unit: 1x10mL screw cap bottle Isooctane µgs/g (ppm) Wt.% S I Blank 0 S I S I S I S I S I S I S I S I S-4050-Kit Kit of above solutions ASTM D Sulfur in petroleum Standard test method for sulfur in petroleum gas by oxidative microcoulometry This test method covers determination of sulfur in the range from 1.5 to 100 mg/kg (ppm by mass) in hydrocarbon products that are gaseous at normal room temperature and pressure. Calibration Mixtures: See ASTM D 3120 above (S-4050 di-n-butyl sulfide in isooctane). ASTM D e1 Benzene and toluene in finished motor and aviation gasolines by GC Standard test method for the determination of benzene and toluene in finished motor and aviation gasoline by gas chromatography. This test method provides for the determination of benzene and toluene in finished motor and aviation gasolines by gas chromatography. S-4164-SET Aromatics Quantitative Calibration Standards (without Internal Standard) 2 Analytes, each Vol.% as listed in isooctane; unit: 7x25mL, one of each Std. Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Std. 7 Calibr. range Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Isooctane

51 S-4206-SET S-4204-ASS-10I Aromatics Quantitative Calibration Standards (with Internal Standard) 3 Analytes, each Vol.% as listed in isooctane; units: 7x1mL, 7x2mL and 5x(7x2)mL, one of each Std. Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Std. 7 Calibr. range Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Isooctane Methylethyl ketone (Int. Std.) Dialy Quality Control Standard (with Internal Standard) 3 Analytes, each Vol.% as listed in isooctane; units: 1x10 ml, 5x10 ml. Name Vol.% Benzene 0.64 Toluene 4.8 Isooctane Methylethylketone (Int.Std.) 4.0 Methods S-4205-ASS-10I Dialy Quality Control Standard (without Internal Standard) 2 Analytes, each Vol.% as listed in isooctane; units: 1x10 ml, 5x10 ml. Name Vol.% Benzene 0.67 Toluene 5.0 Isooctane ASTM D (2004) Boiling range distribution of gasoline and gas fractions by GC Standard test method for boiling range distribution of gasoline and gasoline fractions by gas chromatography This test method covers the determination of the boiling range distribution of gasoline and gasoline components. This test method is applicable to petroleum products and fractions with a final boiling point of 260 C (500 F) or lower as measured by this test method. S ML Calibration Standard 16 Analytes, each Wt.% as listed; units: 1x1mL, 5x1mL neat This standard can be used for qualitative and quantitative analyses. 49

52 Name Wt. % Name Wt. % 2-Methylbutane 10.0 p-xylene 13.0 n-pentane 8.0 n-propylbenzene Methylpentane 6.0 n-decane 4.0 n-exane 6.0 n-butylbenzene 4.0 2,4-Dimethylpentane 6.0 n-dodecane 3.5 n-eptane 10.0 n-tridecane 2.5 Toluene 11.0 n-tetradecane 2.5 n-ctane 6.0 n-pentadecane 2.5 ASTM D p-xylene by GC Standard test method for analysis of p-xylene by gas chromatography This test method covers the determination of known hydrocarbon impurities in, and the purity of p-xylene by gas chromatography. It is generally meant for the analysis of p-xylene of 99% or greater purity. Impurity concentrations can be measured range from to weight %. S ML p-xylene Impurity Standard with Internal Standards 11 Analytes, each Wt.% as listed; units: 1x1mL, 5x1mL + ISTD, neat Name Wt. % Name Wt. % n-pentane 0.15 p-xylene n-ctane 0.15 m-xylene 0.15 Benzene 0.15 o-xylene 0.15 Toluene 0.15 Cumene 0.15 Ethylbenzene 0.15 Propylbenzene 0.15 n-undecane (ITSD) 0.5 g ASTM D Sulfur in petroleum products Standard test method for sulfur in petroleum and petroleum products by energydispersive x-ray fluorescence spectroscopy This test method covers the measurement of sulfur in hydrocarbons such as naphthas, distillates, fuel oils, residues, lubricating base oils and nonleaded gasoline. The concentration range is from to 5.00 mass % (150 to ppm) sulfur. S-4051/S-4052 Sulfur Calibration Mixtures: Di-n-butyl sulfide in White il (less than 20mg/kg S) Unit : 10 ml screw cap bottle 50

53 Light White Mineral il eavy White Mineral il (20 cst at 40 C) (70 cst at 40 C) mgs/g (ppm) Wt.% S LW S W Blank 0 S LW S W S-4052-K-LW S-4051-K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S-4052-Kit S-4051-Kit Kit of above solutions ASTM D Trace nitrogen in petroleum products Methods Standard test method for trace nitrogen in liquid petroleum hydrocarbons by syringe/inlet oxidative combustion and chemiluminescence detection. This test method is used to determine trace total nitrogen naturally found in liquid hydrocarbons boiling point from 50 to 400 C and with viscosities between 0.2 and 10 cst. Use of this method to monitor feed stocks for nitrogen can prevent the poisoning of some process catalysts when trace nitrogenous materials are present. S-4140-ASS-I Nitrogen Calibration Set-Low Boiling Solvents Units: 1x1mL ampoules or 10 ml screw cap bottle Nitrogen introduced using Pyridine Catalogue No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.3 S I 1.0 S I 10 S I 25 S I 50 S I 75 S I 100 S-4141-ASS-I Nitrogen Calibration Set-igh Boiling Solvents Units: 1x1mL ampoules or 10 ml screw cap bottle Nitrogen introduced using Carbazole Catalogue No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.3 S I 1.0 S I 10 S I 25 S I 50 S I 75 S I

54 S-4142-ASS-I Low level Nitrogen Calibration Units: 1x1mL ampoules or 10mL screw cap bottle Nitrogen introduced using Aniline Catalogue No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.5 S I 1.0 S I 2.0 S I 5.0 S I 10.0 S-4143-ASS-B Low level Nitrogen & Sulfur Calibration Set Units: 1x1mL ampoules or 10mL screw cap bottle Nitrogen introduced using Aniline / Sulfur introduced using di-n-butyl Sulfide Catalogue No. Concentration Matrix: Benzene mg/kg (ppm) S B Blank S B 0.25 S B 0.50 S B 1.00 ASTM D Thiophene in refined benzene by GC Standard test method for determination of trace thiophene in refined benzene by gas chromatography This test method covers the determination of thiophene in refined benzene from 0.5 mg/kg to 5.0 mg/kg. S-4059-ASS-LW Thiophene in Thiophene-free Benzene Units: 1x1mL ampoule, 10 ml screw cap bottle Light White Mineral il (20 cst at 40 C) µg thiophene/g (ppm) Wt.% S LW Blank 0 S LW S LW S LW S LW S-4059-Kit Kit of above solutions 52

55 ASTM D Ethers and alcohols in gasoline by GC Standard test method for determination of MTBE, ETBE, TAME, DIPE, tertiary-amyl alcohol and C1 to C4 alcohols in gasoline by gas chromatography. This test method covers the determination of ethers and alcohols in gasolines by gas chromatography. Specific compounds determined are methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), tert-amylmethyl ether (TAME), diisopropyl ether (DIPE), methanol, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol, secbutanol, n-butanol, and tert-pentanol (tert-amylalcohol). S-4174-SET xygenated Quantitative Calibration Mixtures (without Internal Standard) 4 Analytes, each Wt.% as listed in isooctane/xylene (65:35); unit: 5x10mL, one of each Std. Methods Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Ethanol t-butanol Methyl t-butylether t-pentanol Isooctane/Xylene (65:35) S-4175-SET xygenated Quantitative Calibration Mixtures (with Internal Standard) 5 Analytes, each Wt.% as listed in isooctane/xylene (65:35); unit: 5x1mL, one of each Std. Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Ethanol t-butanol Methyl t-butylether t-pentanol ,2-Dimethoxyethane (Int.Std.) Isooctane/Xylene (65:35) Total xygenates & Inter. Std S ML Qualitative Peak ID Mixture 16 Analytes, each Wt.% as listed; units: 1x1 ml and 5x1 ml neat Name Wt. % Name Wt. % Methylcyclopentane 4.0 Diisopropyl ether 4.0 Methanol 7.3 Isobutanol 7.3 Ethanol 7.3 Ethyl tert-butyl ether 4.0 Isopropanol 7.3 tert-pentanol 7.3 tert-butanol 7.3 1,2-Dimethoxyethane 6.0 n-propanol 7.3 n-butanol 7.3 Methyl tert-butyl ether 4.0 Benzene 5.0 sec-butanol 7.3 tert-amyl methyl ether

56 S-4177-ASS-X Valve Timing Mixture 4 Analytes, each Wt.% as listed in n-hexane; units: 1x1mL, 5x1mL Name Wt.% Methylcyclopentane Diisopropyl ether Ethyl tert-butyl ether Methyl tert-butyl ether n-exane ML xygenate Internal Standard mixture Units : 1x1mL, 5x1mL 1,2-Dimethoxyethane (Neat) S ML xygenate Free Refinery Gasoline Blank; unit: 1x10mL, 5x10mL RFA Gasoline (Neat) ASTM D Additives in lubricating oils Standard test method for determination of additive elements in lubricating oils by inductively coupled plasma atomic emission spectrometry This test method covers the quantitative determination of barium, boron, calcium, copper, magnesium, phosphorus, sulfur and zinc in unused lubricating oils. The precision statements are valid for dilutions in which the mass % sample in solvent is held constant in the range 1 to 5 mass % oil. Sulfur can be determined if the instrument can operate at a wavelength of 180 nm. Standards: Di-n-butyl sulfide in solvent of choice (e.g. S-4050, S-4051, S-4052) See the Applications section for sulfur and phosphorous analysis, pages 195 and 204. ASTM D Determination of aromatic content & polynuclear aromatic content by SFC Standard test method for determination of the aromatic content and polynuclear aromatic content of diesel fuels and aviation turbine fuels by supercritical fluid chromatography. This test method covers the determination of the total amount of monoaromatic and polynuclear aromatic hydrocarbon compounds in motor diesel fuels, aviation turbine fuels, and blend stocks by supercritical fluid chromatography (SFC). 54

57 S ML Performance Control Mixture 4 Analytes each Wt.% as listed; units: 1x1 ml, 5x1 ml neat Name Wt. % Name Wt. % n-exadecane 75.0 Tetralin 3.0 Naphthalene 2.0 Toluene 20.0 S-4158-ASS-D Detector Linearity Check Unit: 2x1mL 25 % w/w # 2 Diesel Fuel in n-exadecane 50 % w/w # 2 Diesel Fuel in n-exadecane Methods ASTM D (2002) Boiling range distribution of crude petroleum by GC Standard test method for determination of boiling range distribution of crude petroleum by gas chromatography This test method covers the determination of the boiling range distribution of water-free crude petroleum through 538 C (1000 F). Material boiling above 538 C is reported as residue. This test method is applicable to whole crude samples, which can be solubilized in a solvent to permit sampling by means of a microsyringe. S K-CS Petrochemical Quantitative Standard C10-C44 16 Analytes, each 5000µg/mL in carbon disulfide (CS2); units: 1x1,5 ml, 5x1,5mL Use to determine detector response factors. n-decane C10 n-eicosane C20 n-undecane C11 n-tetracosane C24 n-dodecane C12 n-ctacosane C28 n-tridecane C13 n-dotriacontane C32 n-tetradecane C14 n-exatriacontane C36 n-pentadecane C15 n-tetracontane C40 n-exadecane C16 n-tetratetracontane C44 n-eptadecane C17 n-ctadecane C18 S ML Petrochemical Qualitative Standard C5-C9 5 Analytes, equal Wt.%; unit: 1x1mL neat Use in combination with Petrochemical Quantitative Standard (S-4144) to prepare a calibration mixture covering C5 to C44 for calibrating retention times for boiling point correlation. n-pentane n-exane n-eptane n-ctane n-nonane C5 C6 C7 C8 C9 55

58 S ML Petrochemical Internal Standard C14-C17 4 Analytes, equal Wt.%; unit : 25 ml screw-capped bottle n-tetradecane C14 n-exadecane C16 n-pentadecane C15 n-eptadecane C17 S K-C Column Resolution Test Mix C16-C18 2 Analytes, each 1,0 Wt.% in n-ctane; unit : 5x1 ml n-exadecane n-ctadecane C16 C18 ASTM D (2003)e1 Purity of methyl tert-butyl ether by GC Standard test method for analysis of methyl tert-butyl ether (MTBE) by gas chromatography. This test method provides for determination of the purity of methyl tert-butyl ether (MtBE) by gas chromatography. It also provides a procedure to measure impurities in MtBE such as C4 to C12 olefins, methyl, isopropyl and tert-butyl alcohols, methyl sec-butyl and methyl tert-amyl ethers, acetone, and methyl ethyl ketone. S-4180-K-MT S-4180-K-5MT MTBE Contaminant Standard Low Contaminant Mixture 11 Analytes, each 0,1 Wt.% in MTBE; units: 1x1mL, 5x1mL, 1x5mL, 5x5mL tert-amyl methyl ether 2-Methylbutane trans-2-pentene tert-butanol 2-Methyl-2-butene Triisobutylene tert-butyl ethyl ether Pentane 2,4,4-Trimethyl-1-pentene Methanol cis-2-pentene S K-MT S K-5MT MTBE Contaminant Standard igh Contaminant Mixture 11 Analytes, each 1,0 Wt.% in MTBE; units: 1x1mL, 5x1mL, 1x5mL, 5x5mL tert-amyl methyl ether 2-Methylbutane trans-2-pentene tert-butanol 2-Methyl-2-butene Triisobutylene tert-butyl ethyl ether Pentane 2,4,4-Trimethyl-1-pentene Methanol cis-2-pentene S K-MT S K-5MT MTBE Resolution Test Mixture 3 Analytes, each 1,0 Wt.% in MTBE; units: 1x1mL, 5x1mL, 1x5mL, 5x5mL trans-2-pentene tert-butanol cis-pentene 56

59 S-4184-K-DD Qualitative Standard 32 Analytes, each 0,1 Wt.% in n-dodecane; unit: 1x1mL Methanol n-pentane 3-Methylpentane Isobutylene trans-2-pentene sec-butyl methyl ether n-butane tert-butanol Ethyl tert-butyl ether trans-2-butene cis-2-pentene tert-amyl methyl ether cis-2-butene 2-Methyl-2-butene 3,5-Dimethyl-1-hexene 3-Methyl-1-butene Cyclopentene 2,4,4-Trimethyl-1-pentene Acetone Methyl tert-butyl ether 2,4,4-Trimethyl-2-pentene Isopentane 2,3-Dimethyl-1-butene 3,4,4-Trimethyl-trans-2-pentene 2-Propanol 4-Methyl-cis-2-pentene 2,3,4-Trimethyl-2-pentene 1-Pentene 2-Methylpentane 2,2,4,6,6 -Pentamethyl-3-heptene 2-Methyl-1-butene Methyl ethyl ketone Methods S-4183-K-DD Quantitative Standard 28 Analytes, each 0,1 Wt.% in n-dodecane; unit: 1x1mL Methanol cis-2-pentene Ethyl tert-butyl ether 3-Methyl-1-butene 2-Methyl-2-butene tert-amyl methyl ether Acetone Cyclopentene 3,5-Dimethyl-1-hexene Isopentane Methyl tert-butyl ether 2,4,4-Trimethyl-1-pentene 2-Propanol 2,3-Dimethyl-1-butene 2,4,4-Trimethyl-2-pentene 1-Pentene 4-Methyl-cis-2-pentene 3,4,4-Trimethyl-trans-2-pentene 2-Methyl-1-butene 2-Methylpentane 2,3,4-Trimethyl-2-pentene n-pentane Methyl ethyl ketone 2,2,4,6,6-Pentamethyl-3-heptene trans-2-pentene 3-Methylpentane tert-butanol sec-butyl methyl ether ASTM D (2003)e1 Analysis of petroleum waxes Standard test method for analysis of petroleum waxes by gas chromatography. This test method covers the quantitative determination of the carbon number distribution of petroleum waxes in the range from n-c17 through n-c44 by gas chromatography using internal standardization. In addition, the content of linear and non-linear hydrocarbons for each carbon number is also determined. S CY Quantitative Linearity Wax Mixture C16-C44 Each 0.01 Wt. % in Cyclohexane; unit: 1mL, 5x1mL n-exadecane C16 n-ctacosane C28 n-ctadecane C18 n-triacontane C30 n-eicosane C20 n-dotriacontane C32 n-docosane C22 n-exatriacontane C36 n-tetracosane C24 n-tetracontane C40 n-exacosane C26 n-tetratetracontane C44 57

60 S MG Retention Time Wax Mixture C16-C44 12 Analytes, each 8.3 Wt. % in Cyclohexane; unit: 500 mg neat Use this standard to establishing the retention times from C16 to C44. n-exadecane C16 n-ctacosane C28 n-ctadecane C18 n-triacontane C30 n-eicosane C20 n-dotriacontane C32 n-docosane C22 n-exatriacontane C36 n-tetracosane C24 n-tetracontane C40 n-exacosane C26 n-tetratetracontane C44 S CY Column Resolution Test Mix C20-C24 2 Analytes, each 0,05 Wt.% in cyclohexane; unit : 5x1mL n-eicosane n-tetracosane C20 C24 ASTM D Determination of PNA in distillates Standard test method for paraffin, naphthene, and aromatic hydrocarbon type analysis in petroleum distillates through 200 C by multi-dimensional gas chromatography This test method provides for the determination of paraffins, naphthenes, and aromatics by carbon number in low olefinic hydrocarbon streams having final boiling points of 200 C or less. ydrocarbons with boiling points greater than 200 C and less than 270 C are reported as a single group. lefins, if present, are hydrogenated and the resultant saturates are included in the paraffin and naphthene distribution. Aromatics with the same or higher boiling points than C9 are reported as a single aromatic group. S MG ydrocarbon Test Mixture 28 Analytes, each Wt.% as listed; unit: 500 mg neat Name Wt. % Name Wt. % Cyclopentane 1.0 n-decane 4.5 n-pentane 1.0 n-undecane 3.5 Cyclohexane 2.0 n-dodecane 3.0 2,3-Dimethylbutane 2.0 Benzene 2.5 n-exane 2.0 Toluene exene 1.5 trans-decahydronaphthalene 4.0 Methylcyclohexane 4.5 n-tetradecane Methyl-1-hexene 1.5 Ethylbenzene 4.5 n-eptane 3.5 o-xylene 4.0 1,cis-2-Dimethylcyclohexane 5.0 n-propylbenzene 5.0 Isooctane 5.0 1,2,4-Trimethylbenzene 4.5 n-ctane 5.0 1,2,3-Trimethylbenzene cis-2-cis-4-Trimethylcyclohexane 4.5 1,2,4,5-Tetramethylbenzene 5.0 n-nonane 4.5 Pentamethylbenzene

61 ASTM D Sulfur in light hydrocarbons, motor fuels and oils Standard test method for determination of total sulfur in light hydrocarbons, spark ignition engine fuel, diesel engine fuel, and engine oil by ultraviolet fluorescence This test method covers the determination of total sulfur in liquid hydrocarbons, boiling at 25 C to 400 C, with viscosities between approximately 0.2 and 20 cst at room temperature. This test method is applicable to naphthas, distillates, oils, and motor fuels, such as: gasoline, oxygen enriched gasoline, diesel, biodiesel and jet fuel. Samples containing 1.0 to 8000 mg/kg total sulfur (1 to 8000 ppm) can be analyzed. NB! White il 3 cst is similar to diesel fuel. Methods S-4055 Sulfur Calibr. Mix. Dibenzothiophene in Isooctane S-4159 Sulfur Calibr. Mix. Dibenzothiophene in White oil (3 cst) S-4256 Sulfur Calibr. Mix. Dibenzothiophene in White oil (20 cst) S-4254 Sulfur Calibr. Mix. Dibenzothiophene in Toluene Unit: 10mL screw cap bottle Matrix White oil White il Concentration Isooctane Toluene 3 cst 20 cst µgs/g (ppm) Wt.% S I S T S C S LW Blank 0 S I S T S C S LW S I S T S C S LW S I S T S C S LW S I S T S C S LW S I S T S C S LW S I S T S C S LW S I S T S C S LW S-4055-K-I S-4254-K-T S-4159-K-3C S-4256-K-LW S K-I S K-I S K-I S-4055-Kit S-4254-Kit S-4159-Kit S-4256-Kit Kit of above solutions ASTM D Determination aromatics in gasoline by GC Standard test method for determination of benzene, toluene, ethylbenzene, p/m-xylene, o-xylene, C9 and heavier aromatics, and total aromatics in finished gasoline by gas chromatography. This test method covers the determination of benzene, toluene, ethylbenzene, the xylene, C9 and heavier aromatics, and total aromatics in finished motor gasoline by gas chromatography. S-4165-SET Aromatics Quantitative Calibration Mixes (without Internal Standard) 5 Analytes, each Wt% as listed in isooctane; unit: 5x10mL, one of each Std. 59

62 Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Benzene Toluene Ethylbenzene o-xylene ,2,4-Trimethylbenzene Isooctane S-4166-SET Aromatics Quantitative Calibration Mixes (with Internal Standard) 5 Analytes + 2-hexanone as internal standard, each Wt.% as listed in isooctane; unit: 5x1mL one of each Std. Analyte Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Benzene Toluene Ethylbenzene o-xylene ,2,4-Trimethylbenzene exanone (ISTD) Isooctane S-4167-ASS-10I Valve Timing Calibration Mix (without Internal Standard) 4 Analytes, each Wt.% as listed in isooctane; units: 1x10mL, 5x10 ml Name Wt.% Name Wt.% Benzene 5.0 o-xylene 10.0 Toluene 5.0 Isooctane 70.0 Ethylbenzene 10.0 S-4168-ASS-10I Valve Timing Calibration Mix (with Internal Standard) 5 Analytes, each Wt.% as listed in isooctane; units: 1x10 ml and 5x10 ml Name Wt.% Name Wt.% Benzene 4.5 o-xylene 9.0 Toluene exanone (ISTD) 10.0 Ethylbenzene 9.0 Isooctane ML Internal Standard 2-exanone; units: 1x5ml, 5x5ml neat K-I Selectivity Check Standard n-dodecane, 1,5 Wt.% in isooctane; units: 1x1mL, 5x1mL 60

63 S ML Daily Quality Control Standard (without Internal Standard) 14 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 20 Ethylbenzene 2 n-ctane 15 p-xylene 3 n-decane 10 o-xylene 2 n-dodecane 1 1,2,4-Trimethylbenzene 3 Isooctane 20 1,2,4,5-Tetramethylbenzene 1 Benzene 1 Naphthalene 1 Methods S ML Daily Quality Control Standard (with Internal Standard) 15 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 11 Ethylbenzene 1 n-eptane 19 p-xylene 2 n-ctane 14 o-xylene 1 n-decane 9 1,2,4-Trimethylbenzene 2 n-triadecane 1 1,2,4,5-Tetramethylbenzene 1 Isooctane 19 Naphthalene 1 Benzene 1 2-exanone (ISTD) 10 Toluene 8 ASTM D (2005) Quantitative determination of oxygenates in gasoline by GC Standard test method for determination of oxygenates in gasoline by gas chromatography and oxygen selective flame lonization detection. This test method covers the quantitative determination of organic oxygenated compounds in gasoline having a final boiling point not greater than 220 C and oxygenates having a boiling point limit of 130 C. S-4202-SET xygenates Calibration Curve (with Internal Standard) 14 Analytes, each Wt.% as listed in RFA Gasoline; units: 8x1mL, 5x(8x1)mL, one of each Std. 61

64 Analyte Std.1 Std.2 Std.3 Std.4 Std.5 Std.6 Std.7 Std.8 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Methanol Ethanol Isopropanol t-butanol Propanol MtBE sec-butanol Diisopropyl ether iso-butanol EtBE t-pentanol Butanol TAME ,2-Dimethoxyethane (ISTD) RFA Gasoline Total oxygenates & ISTD S-4201-SET xygenates Calibration Curve (without Internal Standard) 13 Analytes, each Wt.% as listed in RFA Gasoline; unit: 8x10mL, one of each Std. Analyte Std.1 Std.2 Std.3 Std.4 Std.5 Std.6 Std.7 Std.8 Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Methanol Ethanol Isopropanol t-butanol Propanol MtBE sec-butanol Diisopropyl ether iso-butanol EtBE t-pentanol Butanol TAME RFA Gasoline Total oxygenates S-4194-ASS-10RF xygenate Quality Control Standard (without Internal Standard) 13 Analytes, each Wt.% as listed in RFA Gasoline; units: 1x10 ml, 5x10 ml Name Wt.% Name Wt.% Methanol 1 Di-isopropyl ether 3 Ethanol 1 iso-butanol 1 Isopropanol 1 EtBE 3 t-butanol 1 t-pentanol 1 Propanol 1 Butanol 1 MtBE 3 TAME 3 sec-butanol 1 RFA Gasoline 79 62

65 S-4196-ASS-10RF S-4195-ASS-5RF Revised xygenate Quality Control Standard (without Internal Standard) 13 Analytes, each Wt.% as listed in RFA Gasoline; units: 1x10mL, 5x10mL Name Wt.% Name Wt.% Methanol 1 Di-isopropyl ether 1 Ethanol 1 iso-butanol 1 Isopropanol 1 EtBE 3 t-butanol 1 t-pentanol 1 Propanol 1 Butanol 1 MtBE 3 TAME 3 sec-butanol 1 RFA Gasoline 81 xygenate Quality Control Standard (with Internal Standard) 14 Analytes, each Wt.% as listed in RFA Gasoline: units: 1x5mL, 5x5mL Name Wt.% Name Wt.% Methanol 1 Di-isopropyl ether 3 Ethanol 1 iso-butanol 1 Isopropanol 1 EtBE 3 t-butanol 1 t-pentanol 1 Propanol 1 Butanol 1 MtBE 3 TAME 3 sec-butanol 1 RFA Gasoline 79 Methods 1,2-Dimethoxyethane (ISTD) combined with the above 14 compounds in a 4 to 100 weight ratio. S-4197-ASS-10RF Revised xygenate Quality Control Standard (with Internal Standard) 14 Analytes, each Wt.% as listed in RFA Gasoline; units: 1x10mL, 5x10mL Name Wt.% Name Wt.% Methanol 1 Di-isopropyl ether 1 Ethanol 1 iso-butanol 1 Isopropanol 1 EtBE 3 t-butanol 1 t-pentanol 1 Propanol 1 Butanol 1 MtBE 3 TAME 3 sec-butanol 1 RFA Gasoline 81 1,2-Dimethoxyethane (ISTD) combined with the above 14 compounds in a 4 to 100 weight ratio K-10RF ML Gasoline Refinery Blank (with Internal Standard) 1,2-Dimethoxyethane (ISTD), 4 Wt.% in RFA Gasoline or neat; units: 1x10mL, 5x10mL, 1mL neat 63

66 S-4187-SET EPA -FID Quantitative Calibration Mixes (without Internal Standard) 4 Analytes, each Wt.% as listed in RFA Gasoline; unit: 5x10mL, one of each Std. Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibr. range Wt. % Wt. % Wt. % Wt. % Wt. % Methanol Ethanol t-butanol MtBE RFA Gasoline S-4188-SET EPA -FID Quantitative Calibration Mixes (with Internal Standard) 5 Analytes, each Wt.% as listed in RFA Gasoline; unit: 5x1mL, one of each Std. Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Calibr. range Wt. % Wt. % Wt. % Wt. % Wt. % Methanol Ethanol t-butanol MtBE ,2-Dimethoxyethane (ISTD) RFA Gasoline S-4189-ASS-10RF EPA -FID Quantitative Calibration Check Standard (without Internal Standard) 4 Analytes, each Wt.% as listed in RFA Gasoline; units: 1x10mL, 5x10mL Name Wt.% Name Wt.% Methanol 4.0 Methyl tert-butyl ether 12.0 Ethanol 8.0 RFA Gasoline 71.0 tert-butanol 5.0 S-4190-ASS-5RF EPA -FID Quantitative Calibration Check Standard (with Internal Standard) 5 Analytes, each Wt.% as listed in RFA Gasoline; units: 1x5mL, 5x5mL Name Wt.% Name Wt.% Methanol 3.80 Methyl tert-butyl ether Ethanol ,2-Dimethoxyethane (ISTD) 5.00 tert-butanol 4.75 RFA Gasoline S ML EPA -FID Spiking Solution 4 Analytes, each Wt.% as listed; units: 1x5ml, 5x5ml neat Name Wt.% Name Wt.% Methanol 14.3 tert-butanol 14.3 Ethanol 28.6 Methyl tert-butyl ether

67 ML Gasoline Refinery Blank RFA Gasoline; units: 1x10mL, 5x10mL neat ASTM D (2005) Total oxygen in gasoline and methanol by reductive pyrolysis Standard test method for determination of total oxygen in gasoline and methanol fuels by reductive pyroysis. This test method covers the quantitative determination of total oxygen in gasoline and methanol fuels by reductive pyrolysis. Methods S-4185 Standards for Total xygen in Gasoline & Me Fuels by Reductive Pyrolysis 9 Analytes + an RFA gasoline blank, each xygenate Wt.% as listed; units: (2+1)x10mL Cat.No. Description (2x10 ml, + an RFA gasoline blank) xygenate Unit Wt.% S Ethanol in xygenate free RFA gasoline 5.0 3x10ml S Ethanol in xygenate free RFA gasoline x10ml S t-amyl methyl ether in xygenate free RFA gasoline x10ml S t-amyl methyl ether in xygenate free RFA gasoline x10ml S Ethyl t-butyl ether in xygenate free RFA gasoline x10ml S Ethyl t-butyl ether in xygenate free RFA gasoline x10ml S Methyl t-butyl ether in xygenate free RFA gasoline x10ml S Methyl t-butyl ether in xygenate free RFA gasoline x10ml S Methanol & t-butanol in xygenate free RFA gasoline 10.0 & 5.0 3x10ml ML xygenate Free Gasoline Refinery Blank RFA Gasoline; unit : 1x10mL neat ASTM D (2004)e1 Sulfur in light petroleum products by GC Standard test method for sulfur compounds in light petroleum liquids by gas chromatography and sulfur selective detection This test method covers the determination of volatile sulfur-containing compounds in light petroleum liquids. The method is applicable to distillates, gasoline motor fuels (including oxygenates) and other petroleum liquids with a final boiling point of approximately 230 C or lower. The test method is applicable to the determination of individual sulfur species at levels of 0.1 to 100 mg/kg (0.1 to 100 ppm). Internal standards The internal standard should not be an original compound in the sample and should be resolved from sulfur compounds in the sample. The following alternative sulfur compounds are recommended and are available as stock solutions from Chiron. An internal standard stock solution should be in the range g S/kg. Typical GC-purities are given. 65

68 S-4035 Diphenylsulfide (99.3 %) in isooctane S Bromothiophene (99.7 %) in isooctane S Chlorothiophene (99.1 %) in isooctane Units: 5x1mL ampoules or 10 ml screw-capped bottle Catalogue No. Concentration Matrix: Isooctane Diphenyl sulfide 2-Bromothiophene 3-Chlorothiophene mgs/g (ppm) Wt.% S I S I S I Blank 0 S-4035-K-I S-4037-K-I S-4036-K-I S K-I S K-I S K-I S K-I S K-I S K-I System test mixture The system test mixture covers the volatility range of interest for the analysis and is made according to ASTM D S-4038 Sulfur System Test Mixture, 10 ml in Toluene/Isooctane (1:9) S S ppm 0.1 ppm Dimethyl sulfide 100 ppm 0.1 ppm 2-Propanethiol ppm 10 ppm Dimethyl disulfide ppm 100 ppm 3-Methylthiophene ppm 10 ppm Benzothiophene Sulfur compounds standards The sulfur standards are available as test mixtures, neat or as a 1000µg/mL solution of each analyte in isooctane. S ML ASTM D 5623 Sulfur Compounds Standard I 14 Analytes, approximately 7,14 % of each (by weight); unit: 1x1mL neat Prod.nr Compounds Prod.nr Compounds Ethanethiol Methyl-1-propanethiol Dimethyl sulfide Diethyl sulfide Carbon disulfide Butanethiol Methyl-2-propanethiol Dimethyl disulfide Propanethiol Methylthiophene Ethylmethyl sulfide Methylthiophene Thiophene Diethyl disulfide S-4040-K-I ASTM D 5623 Sulfur Compounds Standard II 7 Analytes, each 1000µg /ml in isooctane; unit: 1x1mL Prod.nr Compounds Prod.nr Compounds Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Diphenyl sulfide Methylbenzothiophene 66

69 S I ASTM D 5623 Sulfur Compounds Standard III, Dimethylbenzothiophenes 5 Analytes, each approximately 500µg/mL in isooctane; unit: 1x1mL ,3-Dimethylbenzothiophene ,4-Dimethylbenzothiophene ,5-Dimethylbenzothiophene ,6-Dimethylbenzothiophene ,5-Dimethylbenzothiophene ASTM D il spill analysis by GC Methods Standard practice for oil spill source Identification by gas chromatography and positive ion electron impact low resolution mass spectrometry The scope of the method is to use GC-MS to analyse and compare petroleum oil spills and suspected sources. Naphthalenes (C2-C4), dibenzothiophenes (C0-C3), phenanthrenes/anthracene (C0-C3), steranes (14α() and 14β()), triterpanes, and alkanes are identified. The following products are recommended and are carried by Chiron: MG Perfluorotri-n-butylamine (PFTBA, eptacosa ) for tuning the mass spectrometer Mass spec. grade 500 mg S CY Resolution Test Mixture for ASTM D ng/ml of each in pesticide grade cyclohexane, 10mL Pristane Phytane n-eptadecane n-ctane S CY Mass Discrimination Test Mixture for ASTM D ng/ml in pesticide grade cyclohexane, 10mL Naphthalene Fluoranthene Benzo[ghi]perylene 67

70 Reference compounds for ASTM D 5739 Compound Group m/z Available from Chiron, see the Compounds section Naphthalenes, C2 156 All possible dimethyl- and ethyl- isomers are available Naphthalenes, C Isomers available Naphthalenes, C Isomers available: 2-Butylnaphthalene Eudalene 1,4,6,7-Tetramethylnaphthalene 1,2,5,6-Tetramethylnaphthalene Dibenzothiophene, C0 184 Dibenzothiophene Dibenzothiophenes, C1 198 All monomethyl-isomers available Dibenzothiophenes, C Isomers of dimethyl- and ethyldibenzothiophenes Dibenzothiophenes, C Isomers of trimethyl- and propyldibenzothiophenes Phenanthrene, C0 178 Phenanthrene Phenanthrenes, C1 192 All four possible monomethyl-isomers available Phenanthrenes, C2 206 All dimethyl and two ethylphenanthrenes available Phenanthrenes, C Trimethyl and ethyl-methyl isomers available Anthracene, C0 178 Anthracene Anthracene, C1 192 All three possible monomethyl-isomers available Anthracene, C Isomers available Anthracene, C ,2,4-Trimethylanthracene Steranes, 14α() 217 5α(),14α(),17α(),(20S)-Cholestane (C27) 5α(),14α(),17α(),(20R)-Cholestane (C27) 24-Methyl-5α(),14β(),17β(),(20R)-cholestane(C28) 24-Ethyl-5α(),14α(),17α(),(20S)-cholestane (C29) 24-Ethyl-5α(),14α(),17α(),(20R)-cholestane (C29) Steranes, 14β() 218 5α(),14β(),17β(),(20R)-Cholestane (C27) 24-Ethyl-5α(),14β(),17β(),(20R)-cholestane (C29) Triterpanes α(),21β()-opane (C30) 17β(),21α()-opane (C30) 17β(),21β()-opane (C30) (Several others are available, see the hopane sections) Alkanes 85 Available from C5 to C60 Alkanes and Acyclic isoprenoids 183 See head to tail and tail to tail isoprenoids Benzonaphthothiophenes Isomers available Tri-aromatic steranes compounds available Norhopanes Trisnor-, 2 bisnor- and 6 norhopanes are available Methylhopanes 205 NEW: 2- and 3-methylhopanes available Pyrene/Fluoranthene 202 Both available Methylpyrenes alkylpyrene from C01 to C4 Fluorenes 166 Fluorene and 8 alkylfluorenes available Bicyclonaphthalenes 208 Mixes are available on request 68

71 ASTM D Benzene, toluene, and total aromatics in finished gasolines by GC-MS Standard test method for determination of benzene, toluene, and total aromatics in finished gasolines by gas chromatography/mass spectrometry This test method covers the determination of benzene, toluene, other specified individual aromatic compounds, and total aromatics in finished motor gasoline, including gasolines containing oxygenated blending components, by gas chromatography-mass spectrometry (GC-MS). Chiron AS offers different versions for the standard for calibration and identification. Methods S ML Daily Quality Control Standard (without Internal Standard) 14 Analytes, each Wt.% as listed; units: 1x10 ml, 5x10 ml neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1 The Daily Quality Control Standard is also available with different Internal Standard compositions added. Those options are listed further on in this section I Sensitivity Test Solution 1,4-Diethyl benzene, 100 µg/ml in isooctane; units: 1x1mL, 5x1mL K-I Fragmentation Pattern Standard 1,2,3-Trimethylbenzene, 3,0 Wt.% in isooctane; units: 1x1mL, 5x1mL S K-I Resolution Standard 2 Analytes, each 3,0 Wt.% in isooctane; units: 1x1mL, 5x1mL 1,3,5-Trimethylbenzene 1-Methyl-2-ethylbenzene K-I Mass Scan Range Standard Toluene 3,0 Wt.% in isooctane; units: 1x1mL, 5x1mL S-4178 / S-4179 Aromatics Calibration Standards Kit (without Internal Standard) 24 Analytes, each Vol.% as listed in isooctane; units: 5x10mL Set, one of each Std opt. 1x1 ml (Std. 6) 69

72 Standard 6 of the calibration set is optional. It has been added in order to improve the linearity of the calibration curve. Use of the sixth standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadric fit. S-4178 (Std. 1-5) S-4179 Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Ethylbenzene m-xylene p-xylene o-xylene Isopropylbenzene n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene ,3,5-Trimethylbenzene Methyl-2-ethylbenzene ,2,4-Trimethylbenzene ,2,3-Trimethylbenzene Indan Diethylbenzene n-butylbenzene ,2-Diethylbenzene ,2,4,5-Tetramethylbenzene ,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene Methylnaphthalene Methylnaphthalene The calibration set is supplied with a datasheet listing the weight% for each component in the formulation. S ML 3 Deuterated Compounds Internal Standard Mix 3 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% Benzene-d Naphthalene-d Ethylbenzene-d S ML 4 Deuterated Compounds Internal Standard Mix 4 Analytes, each Wt.% as listed; units: 1x10 ml, 5x10mL neat Name Wt.% Name Wt.% Benzene-d Naphthalene-d8 8.8 Ethylbenzene-d Toluene-d

73 S-4251/ S-4252 Aromatics Calibration Standards Kit (3 Internal Standard Version) 24 Analytes + 3 ISTD, each Vol.% as listed in isooctane; units: 5x1mL Set, one of each Std opt. 1x1mL (Std. 6) To these calibration standards are 3 deuterated Internal Standards added. Standard 6 of the calibration set is optional. It has been added in order to improve the linearity of the calibration curve. Use of the sixth standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadric fit. S-4251 (Std.1-5) S-4252 Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Ethylbenzene m-xylene p-xylene o-xylene Isopropylbenzene n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene ,3,5-Trimethylbenzene Methyl-2-ethylbenzene ,2,4-Trimethylbenzene ,2,3-Trimethylbenzene Indan Diethylbenzene n-butylbenzene ,2-Diethylbenzene ,2,4,5-Tetramethylbenzene ,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene Methylnaphthalene Methylnaphthalene Methods (S-4129) 3 Deuterated Compounds, Internal Standard Mixture Benzene-d Ethylbenzene-d Naphthalene-d The calibration set is supplied with a datasheet listing the weight% for each component in the formulation. 71

74 S ML Daily Quality Control Standard (with 3 Deuterated Compounds Internal Standard) 14 Analytes + 3 ISTD, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1 The 3 Deuterated Compounds Internal Standard Mixture S-4129 is mixed with the 14 Analytes Daily Quality Control Standard S-4130 in a 5 to 100 weight ratio. S-4258/ S-4259 Aromatics Calibration Standards Kit (4 Internal Standard Version) 24 Analytes + 4 ISTD, each Vol.% as listed in isooctane; units: 5x1mL Set, one of each Std opt. 1x1mL (Std. 6) 72 To these calibration standards are 4 deuterated Internal Standards added. ASTM D recommends the use of a fourth internal standard toluene-d8. The use of toluene-d8 improves the analytical results for toluene. Standard 6 of the calibration set is optional. It has been added in order to improve the linearity of the calibration curve. Use of the sixth standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadric fit. S-4258 (Std. 1-5) S-4259 Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Ethylbenzene m-xylene p-xylene o-xylene Isopropylbenzene n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene ,3,5-Trimethylbenzene Methyl-2-ethylbenzene ,2,4-Trimethylbenzene ,2,3-Trimethylbenzene Indan ,4-Diethylbenzene n-butylbenzene ,2-Diethylbenzene ,2,4,5-Tetramethylbenzene Tetramethylbenzene Naphthalene Pentamethylbenzene Methylnaphthalene Methylnaphthalene

75 (S-4161) 4 Deuterated Compounds, Internal Standard Mixture Benzene-d Ethylbenzene-d Naphthalene-d Toluene-d The calibration set is supplied with a datasheet listing the weight% for each component in the formulation. S ML Daily Quality Control Standard (with 4 Deuterated Compounds Internal Standard) 14 Analytes + 4 ISTD, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1 The 4 Deuterated Compounds Internal Standard Mixture S-4161 is mixed with the 14 Analytes Daily Quality Control Standard S-4120 in a 12 to 100 weight ratio. Methods S ML 4 Fluorinated Internal Standard Mix 4 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% Fluorobenzene Fluoronaphthalene Ethyl-1-fluorobenzene Fluorotoluene 57.9 S ML 3 Fluorinated Internal Standard Mix 3 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% Fluorobenzene Fluoronaphthalene Ethyl-1-fluorobenzene 39.3 S-4260/ S-4261 Aromatics Calibration Standards Kit (3 Internal Standard Version) 24 Analytes + 3 ISTD, each Vol.% as listed in isooctane; unit: 5x1mL Set, one of each Std opt. 1x1mL (Std. 6) To these calibration standards are 3 fluorinated Internal Standards added. Standard 6 of the calibration set is optional. It has been added in order to improve the linearity of the calibration curve. Use of the sixth standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadric fit. 73

76 S-4260 (Std. 1-5) S-4261 Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Ethylbenzene m-xylene p-xylene o-xylene Isopropylbenzene n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene ,3,5-Trimethylbenzene Methyl-2-ethylbenzene ,2,4-Trimethylbenzene ,2,3-Trimethylbenzene Indan Diethylbenzene n-butylbenzene ,2-Diethylbenzene ,2,4,5-Tetramethylbenzene ,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene Methylnaphthalene Methylnaphthalene (S-4269) 3 Fluorinated Compounds, Internal Standard Mixture Fluorobenzene Ethyl-1-fluorobenzene Fluoronaphthalene The calibration set is supplied with a datasheet listing the weight% for each component in the formulation. S ML Daily Quality Control Standard (with 3 Fluorinated Compounds Internal Standard) 14 Analytes + 3 ISTD, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1 The 3 Fluorinated Compounds Internal Standard Mixture S-4269 is mixed with the 14 Analytes Daily Quality Control S-4120 in a 5 to 100 weight ratio. 74

77 S-4262/ S-4263 Aromatics Calibration Standards Kit (4 Internal Standard Version) 24 Analytes + 4 ISTD, each Vol.% as listed in isooctane; units: 5x1 ml Set, one of each Std opt. 1x1 ml (Std. 6) To these calibration standards are 4 fluorinated Internal Standards added. ASTM D recommends the use of a fourth internal standard. The use of an extra internal standard with physical properties similar to toluene improves the analytical results for toluene. Standard 6 of the calibration set is optional. It has been added in order to improve the linearity of the calibration curve. Use of the 6th standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadric fit. S-4260 (Std. 1-5) S-4261 Analyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Vol.% Vol.% Vol.% Vol.% Vol.% Vol.% Benzene Toluene Ethylbenzene m-xylene p-xylene o-xylene Isopropylbenzene n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene Trimethylbenzene Methyl-2-ethylbenzene Trimethylbenzene Trimethylbenzene Indan Diethylbenzene n-butylbenzene Diethylbenzene Tetramethylbenzene Tetramethylbenzene Naphthalene Pentamethylbenzene Methylnaphthalene Methylnaphthalene Methods (S-4228) 4 Fluorinated Compounds, Internal Standard Mixture Fluorobenzene Ethyl-1-fluorobenzene Fluoronaphthalene Fluorotoluene The calibration set is supplied with a datasheet listing the weight% for each component in the formulation. 75

78 S ML Daily Quality Control Standard (with 4 Fluorinated Compounds Internal Standard) 14 Analytes + 4 ISTD, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1 The 4 Fluorinated Compounds Internal Standard Mixture S-4228 is mixed with the 14 Analytes Daily Quality Control Standard S-4120 in a 12 to 100 weight ratio. ASTM D (2006) xygenates, benzene, toluene, C8-C12 aromatics and total aromatics in gasoline Standard test method for determination of oxygenates, benzene, toluene, C8-C12 aromatics and total aromatics in finished gasoline by gas chromatography/fourier transform infrared spectroscopy. This test method covers the quantitative determination of oxygenates: methyl-t-butyl ether (MTBE), di-isopropyl ether (DIPE), ethyl-t-butyl ether (ETBE), t-amylmethyl ether (TAME), methanol (Me), ethanol (Et), 2- propanol (2-Pr), t-butanol (t-bu), i-propanol (i-pr), 2-butanol (2-Bu), i-butanol (i-bu), 1- butanol (1-Bu), benzene, toluene and C8-C12 aromatics, and total aromatics in finished motor gasoline by gas chromatography/fourier Transform infrared spectroscopy (GC/FTIR). S ML Daily Quality Control Standard (without Internal Standard) 13 Analytes, each Wt.% as listed; units: 1x10mL, 5x10mL neat Name Wt.% Name Wt.% n-exane 12 Toluene 9 n-eptane 17 m-xylene 3 n-ctane 17 o-xylene 3 n-decane 12 Ethylbenzene 3 n-dodecane 5 1,2,4-Trimethylbenzene 3 2,2,4,-Trimethylpentane 12 1,2,4,5-Tetramethylbenzene 3 Benzene 1 76

79 ASTM D (2003)e1 -PNA in low-olefin spark ignition engine fuels Standard test method for oxygenates and paraffin, olefin, naphthene, aromatic (-PNA) hydrocarbon types in low-olefin spark ignition engine fuels by gas chromatography. This test method provides for the quantitative determination of oxygenates, paraffins, olefins, naphthenes, and aromatics in low-olefin spark-ignition engine fuels by multidimensional gas chromatography. S ML Validation mixture for oxygenates and PNA 33 Analytes, each Wt.% as listed; units: 1x1mL, 5x1mL neat Use this standard to monitor and make adjustments to the total operation of the system. Name Wt.% Name Wt.% Cyclopentane 1.5 Benzene 2.5 n-pentane 1.5 Toluene 2.5 Cyclohexane 2.0 trans-decahydronaphtalene Dimethylbutane 2.0 n-tetradecane 2.0 n-exane 2.0 Ethylbenzene exene 1.5 o-xylene 3.0 Methylcyclohexane 3.5 n-propylbenzene Methyl-1-hexene 1.5 1,2,4-Trimethylbenzene 3.0 n-eptane 3.0 1,2,3-Trimethylbenzene 2.0 cis-1,2-dimethylcyclohexane 4.5 1,2,4,5-Tetramethylbenzene trimethylpentane 4.0 Pentamethylbenzene 2.5 n-ctane 4.0 Ethanol 5.0 cis.cis-1,2,4-trimethylcyclohexane 3.5 tert-butanol 4.0 n-nonane 3.0 MTBE (methyl tert-butyl ether) 8.0 n-decane 3.5 ETBE (ethyl tert-butyl ether) 3.0 n-undecane 2.0 TAME (tert-amyl methyl ether) 5.0 n-dodecane 2.0 Methods S-4132-ASS-MX lefin mixture 5 Analytes, each Wt.% as listed in n-hexane/n-heptane = 1:1; units: 1x1mL, 5x1mL Use this standard to adjust the olefin and Ether-Alcohol-Aromatic (EAA) trap temperatures so that C5 through C9 olefins are quantitative determined. Name Wt.% 1-Pentene exene eptene ctene Nonene

80 S K-MX Paraffin mixture 2 Analytes, each 3 Wt.% in n-exane/n-eptane = 1:1; units: 1x1mL, 5x1mL Use this standard to adjust the olefin and Ether-Alcohol-Aromatic (EAA) trap temperatures. Name Wt.% n-nonane 3.0 n-decane 3.0 ASTM D (2003)e1 Quantitative determination of olefins Standard test method for total olefins in spark-ignition engine fuels by multidimensional gas chromatography. This test method provides for the quantitative determination of total olefins in the C4 to C10 range in spark-ignition engine fuels or related hydrocarbons streams, such as naphthas and cracked naphthas K-I Set Up Mixture 1 MTBE (Methyl tert-butyl ether), 5 Wt.% in isooctane; unit: 1x1mL Use this standard to verify that all instrument components, temperatures, and cut times are accurate K-I Set Up Mixture 2 ETBE (Ethyl tert-butyl ether), 5 Wt.% in isooctane; unit: 1x1mL Use this standard to verify that all instrument components, temperatures, and cut times are accurate. S-4154-ASS-I Calibration standard with MTBE 9 Analytes, each Wt.% as listed in isooctane; units: 1x1mL, 5x1mL Name Wt.% Name Wt.% Pentene 1.0 Decene 1.0 exene 1.0 Undecane 1.0 eptene 1.0 Dodecane 1.0 ctene 1.0 Isooctane 87.0 Nonene 1.0 MTBE 5.0 S-4155-ASS-I Calibration standard with ETBE 10 Analytes, each Wt.% as listed in isooctane; units: 1x1mL, 5x1mL Name Wt.% Name Wt.% Pentene 1.0 Decane 1.0 exene 1.0 Undecane 1.0 eptene 1.0 Dodecane 1.0 ctene 1.0 Isooctane 86.0 Nonene 1.0 ETBE 5. Decene

81 ASTM D Sulfur in aromatic compounds Standard test method for total sulfur in aromatic compounds by hydrogenolysis and sulfur specific difference photometry This test method covers the determination of sulfur in aromatic hydrocarbons and related chemicals having typical sulfur concentrations from to 10 mg/kg (0.05 to 100 ppm). S-4057-K-I Sulfur Calibration Stock Solution Thiophene, 1000 µg/ml in Toluene; unit: 5x1mL ampoules Please request for diluted samples in the range 1 to 1000 ng/ml. Methods ASTM D e1 Boiling range distribution of petroleum distillate fractions by GC Standard test method for boiling range distribution of petroleum distillates in boiling range from 174 C to 700 C by gas chromatography. This test method covers the determination of the boiling range distribution of petroleum distillate fractions. The test method is applicable to petroleum distillates fractions having an initial boiling point greater than 174 C (345 F) and a final boiling point of less than 700 C (1292 F) (C10 C90) at atmospheric pressure as measured by this method. S-4112 Petrochemical Calibration Mixture C6-C44 17 Analytes, each 6,25 Wt.% in carbon disulfide (CS2); units: 100mg, 1g neat Use for assessing column resolution as well as for quantitative analyses. n-exane C6 n-ctadecane C18 n-eptane C7 n-eicosane C20 n-ctane C8 n-tetracosane C24 n-nonane C9 n-ctacosane C28 n-decane C10 n-dotriacotane C32 n-undecane C11 n-exatriacontane C36 n-dodecane C12 n-tetracontane C40 n-tetradecane C14 n-tetratetracontane C44 n-exadecane C16 79

82 S MX S MX ydrocarbon Window Defining Standard C8-C40 35 Analytes, each 500 µg/ml in CS2:C2Cl2 (3:1); units: 1x1mL, 1x5mL ctane C8 Nonadecane C19 Triacontante C30 Nonane C9 Phytane C20 entriacontane C31 Decane C10 Eicosane C20 Dotriacontane C32 Undecane C11 eneicosane C21 Tritriacontane C33 Dodecane C12 Docosane C22 Tetratriacontane C34 Tridecane C13 Tricosane C23 Pentatriacontane C35 Tetradecane C14 Tetracosane C24 exatriacontane C36 Pentadecane C15 Pentacosane C25 eptatriacontane C37 exadecane C16 exacosane C26 ctratriacontane C38 eptadecane C17 eptacosane C27 Nonatriacontane C39 ctadecane C18 ctacosane C28 Tetracontane C40 Pristane C19 Nonacosane C29 S-4151 Column Resolution Test Mix C16-C18 2 Analytes, each 1 % v/v in n-ctane; unit : 5x1mL n-exadecane n-ctadecane C16 C18 ASTM D Aromatic hydrocarbon types in aviation fuels and petroleum distillates by PLC refractive index Standard test method for determination of aromatic hydrocarbon types in aviation fuels and petroleum distillates high performance liquid chromatography method with refractive index detection. This test method covers a high performance liquid chromatographic test method for the determination of monoaromatic and di-aromatic hydrocarbon contents in aviation kerosenes and petroleum distillates boiling in the range from 50 C to 300 C, such as Jet A or Jet A-1 fuels. S-4266-ASS-P IP Resolution Standard 3 Analytes, each Wt.% as listed in n-eptane; units: 1x5mL, 5x5mL Cyclohexane o-xylene 1-Methylnaphtalene 10.0 mg/ml 5.0 mg/ml 0.5 mg/ml S-4267-SET IP Calibration Curve 4 Analytes, each Wt.% as listed in n-eptane; unit: 4x1mL, one of each Std. Analyte Std. 1 Std.2 Std.3 Std.4 (mg/ml) (mg/ml) (mg/ml) (mg/ml) Cyclohexane o-xylene Methylnaphthalene

83 ASTM D lefin content of gasoline by SFC Standard test method for determination of olefin content of gasolines by supercritical-fluid chromatography. This test method is used for the determination of the total amount of olefins in blended motor gasolines and gasoline blending stocks by supercritical-fluid chromatography (SFC). S ML Calibatation mixture for olefines 15 Analytes, each Wt. % as listed; units: 1x1ml, 5x1ml Name: Wt. % 1-Nonene 2.5 Cyclohexene exene ctene Decene Methyl-1,3-butadiene Methyl-1-pentene 5.0 1,5-exadiene Methyl-1,3-pentadiene Methyl-1-butene Methyl-2-pentene eptene Methyl-1-octene Methyl-1-heptene Methyl-1-hexene 10.0 Methods ASTM D Glycerine content by GC Test method for determination of free and total glycerine in B-100 biodiesel methyl esters by gas chromatography This test method provides for the quantitative determination of free and total glycerine in B-100 methyl esters by gas chromatography. The range of the detection for free glycerine is to 0.05 mass %, and total glycerine from 0.05 to 0.5 mass %. Reference: EN 14105:2003, page 42. Derivatizing agent ML N-methyl-N-trimethylsilyltrifluoroacetamide (MSTFA) G [ ] 1 ml, 5g neat 81

84 Stock solutions PY K-10PY K-10PY K-10PY Glycerine (Glycerol, [ ]) stock solution 0.5mg/ml in dry pyridine 10 ml 1-Monooleoylglycerol (monoolein, [ ]) stock solution 5 mg/ml in dry pyridine 10 ml 1,3-Dioleoylglycerol (diolein, [ ]) stock solution 5 mg/ml in dry pyridine 10 ml 1,2,3-Trioleoylglycerol (triolein, [ ]) stock solution 5 mg/ml each in dry pyridine 10 ml Internal standards K-10PY K-10PY Internal Standard No. 1 ((S)-(-)-1,2,4-Butanetriol, [ ]) stock solution 1 mg/ml in dry pyridine 10 ml Internal Standard No. 2 (1,2,3-Tridecanolylglycerol) (tricaprin, [ ]) stock solution 8 mg/ml in dry pyridine 10 ml Calibration solutions Calibration solution Syringe, µl µl of glycerol solution µl of monoolein solution µl of diolein solution µl of triolein solution µl of internal standard sol. No µl of internal standard sol. No To be prepared daily from the above solutions Monoglycerides S K-10PY Monoglycerides 4 analytes, each 10 mg/ml in dry pyridine; unit: 1x10 ml Monopalmitoylglycerol (monopalmitin) [ ] Monostearoylglycerol (monostearin) [ ] Monooleoylglycerol (monoolein) [ ] Monolinoylglycerol (monolinolein) [ ] 82

85 ASTM D Aromatic hydrocarbon types in middle distillates by PLC Standard test method for determination of aromatic hydrocarbon types in middle distillates - high performance liquid chromatography with refractive index detection. This test method is used for the determination of monoaromatic, diaromatic and polyaromatic hydrocarbon contents in diesel fuels and petroleum distillates boiling in the range of C using PLC with refractive index detection. S-4268-ASS-5P IP Performance Standard 4 Analytes, each Wt.% as listed in n-eptane; units: 1x5mL, 5x5mL Methods Cyclohexane o-xylene Dibenzothiophene 9-Methylanthracene 10.0 mg/ml 5.0 mg/ml 0.5 mg/ml 0.5 mg/ml S-4269-SET IP Calibration Curve 4 Analytes, each Wt.% as listed in n-eptane; unit: 4x1mL, one of each Std. Analyte Std. 1 Std.2 Std.3 Std.4 (mg/ml) (mg/ml) (mg/ml) (mg/ml) Cyclohexane o-xylene Methylnaphthalene Phenanthrene ASTM D ydrocarbon compounds in spark ignition engine fuels by GC Standard test method for determination of individual compounds in spark ignition engine fuels by 100 meter capillary high resolution gas chromatography This test method provides procedures for the determination of individual hydrocarbon components of spark-ignition engine fuels and their mixtures containing oxygenate blends (MTBE, ETBE, ethanol, and so forth) with boiling ranges up to 225 ºC. S-4476 D 6729 Calibration Standard Mixtures Reference sample ARC96X from Alberta Research Council, Edmonton, Canada Spark ignition engine fuel standard of known composition and concentration by mass. Individual and mixed components reference materials See the compounds section for individual compounds and the petroleum section for mixed components. Custom mixes are available on order. Please inquire for a quote. 83

86 ASTM D (2006)e1 ydrocarbon compounds in spark ignition engine fuels by GC Standard test method for determination of individual components in spark ignition engine fuels by 100-metre capillary (with precolumn) high resolution gas chromatography This test method provides procedures for the determination of individual hydrocarbon components of spark-ignition engine fuels and their mixtures containing oxygenate blends (MTBE, ETBE, ethanol, and so forth) with boiling ranges up to 225 ºC. S-4477 D6730 Calibration Standard Mixtures Reference sample ARC96X available from Alberta Research Council, Edmonton, Canada Spark ignition engine fuel standard of known composition and concentration by mass. Individual and mixed components reference materials See the compounds section for individual compounds and the petroleum section for mixed components. Custom mixes are available on order. Please inquire for a quote. ASTM D a Biodiesel fuel blend stock for distillate fuels Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels This specification covers biodiesel (B100) Grades S15 and S500 for use as a blend component with middle distillate fuels. D 6751 Requirements Property Method Limits Units Flash Point D min ºC Water and sediment D max % volume Kinematic viscosity D mm 2 /s Sulfated ash D max % mass Sulfur D max % mass Copper strip corrosion D 130 No. 3 max Cetane number D min Cloud point D 2500 Report ºC Carbon residue D max % mass Acid number D max mg K/g Free glycerine D % mass Total glycerine D % mass Phosphorous content D max % mass Distillation temperature D max ºC Atmospheric equivalent temperature, 90 % recovered 84

87 New ASTM standards in development ASTM D (2006) Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence ASTM D (2203) Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Ionization Detection ASTM D Standard Test Method for Total Sulfur in Naphthas, Distillates, Reformulated Gasolines, Diesels, Biodiesels, and Motor Fuels by xidative Combustion and Electrochemical Detection Methods ASTM D Standard Test Method for Simultaneous Measurement of Sulfur Compounds and Minor ydrocarbons in Natural Gas and Gaseous Fuels by Gas Chromatography and Atomic Emission Detection. ASTM D Standard Practice for Gas Chromatograph Based n-line/at-line Analysis for Sulfur Content of Gaseous Fuels ASTM D Standard Practice for Total Sulfur Analyzer Based n-line/at-line for Sulfur Content of Gaseous Fuels. 85

88 UP (ASTM method) Paraffin and naphthene distribution by carbon number of saturated petroleum distillates by GC This method is for determining the distribution of paraffins and naphthenes by carbon number, in hydrocarbon samples having an end-point of 200ºC or less (C3-C11). C12 at concentrations less than 3% can be determined. lefins and aromatics interfere and must be removed prior to analysis by ASTM method D 2002, D 2003 or suitable techniques. S-4478-SET UP 741 igh Naphthene sample 1.5mL neat in Certan bottle. Components PNA igh PNA Low Aromatics Naphthenes Naphthenes in PNA S ML S ML S ML C5 Naphthenes Cyclopentane, C5 Paraffins n-pentane C6 Naphthenes Cyclohexane C6 Paraffins n-exane C7 Naphthenes Methylcyclohexane C7 Paraffins n-eptane C8 Naphthenes Ethylcyclohexane C8 Paraffins n-ctane C9 Naphthenes Isopropylcyclohexane C9 Paraffins n-nonane C10 Naphthenes n-butylcyclohexane C10 Paraffins n-decane C11 Naphthenes n-pentylcyclohexane C11 Paraffins n-undecane C12 Naphthenes n-exylcyclohexane C12 Paraffins n-dodecane Aromatics Benzene Toluene Xylenes Ethyl benzene

89 EPA methods EPA Surfactants (LAS) by colorimetry Methylene blue active substances Available standards: K-ME LAS 12-Na Sodium n-dodecylbenzenesulfonate, 99% pure 1000µg/mL in methanol Methods K-MX LAS Na (tech.) [ ] Sodium dodecylbenzenesulfonate, tech. C10-C µg/mL in methanol, acetonitrile or water This method can not differentiate between LAS, ABS and LAS with benzenesulfonates at the end or in the alkyl chain. EPA 505 Water - organohalide pesticides and PCBs by GC Analysis of organohalide pesticides and commercial polychlorinated biphenyls (PCB) products in water by microextraction and gas chromatography This method is applicable to the determination of the analytes in finished drinking water, drinking water during intermediate stages of treatment, and the raw source water. The method provide qualitative confirmation of results by Gas Chromatography/Mass Spectrometry. For individual standards see the PCB and pesticide sections in the Compounds section, pages 354 and 367. EPA 506 Rev 1.1 Drinking water - phthalates and adipates by GC Determination of phthalate and adipate esters in drinking water by liquid-liquid or liquid-solid extraction by gas chromatography with a photoionization detector After capillary column GC separation, a photoionization detector is required for detection and MDLs are limited to approximately 10µg/L. Phthalates and adipates are among the most common contaminants encountered in the laboratory and extreme care must be taken to ensure clean reagent blanks. 87

90 S-4231-K-I S-4231-K-5I EPA 506 Phathalates and Adipates in Drinking Water 7 Analytes, each 1000µg/mL in isooctane; units: 5x1mL or 5mL screw cap bottle Diethyl phthalate DEP [ ] Bis(2-ethylhexyl) adipate BEA [ ] Di-n-octyl phthalate DNP [ ] Benzyl butyl phthalate BBP [ ] Bis(2-ethylhexyl) phthalate BEP [ ] Dimethyl phthalate BMP [ ] Di-n-butyl phthalate DBP [ ] S-4232-ASS-ME S-4232-ASS-5ME EPA 506 Laboratory Performance Test 7 Analytes, each concentration as listed in methanol; units: 5x1mL, 1x5mL Diethyl phthalate DEP [ ] 100µL/mL Bis(2-ethylhexyl) adipate BEA [ ] 1200µL/mL Di-n-octyl phthalate DNP [ ] 650µL/mL Benzyl butyl phthalate BBP [ ] 250µL/mL Bis(2-ethylhexyl) phthalate BEP [ ] 250µL/mL Dimethyl phthalate BMP [ ] 100µL/mL Di-n-butyl phthalate DBP [ ] 100µL/mL EPA Water - organics and PAs by GC-MS Determination of organic compounds in drinking water by liquid-solid extraction and capillary column gas chromatography-mass spectrometry. This test method provides procedures for determination of organic compounds in finished drinking water, source water, or drinking water in any treatment stage. The method is applicable to a wide range of organic compounds that are efficiently portioned from the water sample onto a C18 organic phase chemically bonded to a solid matrix in a disk or cartridge, and sufficiently volatile and thermally stable for gas chromatography. S AC S AC EPA PA mixture, 13 Compounds in Acetone 13 Analytes, each 100µg/mL in acetone; units: 1x1mL, 1x5mL Acenaphthylene [ ] Anthracene [ ] Benz[a]anthracene [ ] Benzo[b]fluoranthene [ ] Benzo[k]fluoranthene [ ] Benzo[ghi]perylene [ ] Benzo[a]pyrene [ ] Chrysene [ ] Dibenz[a,h]anthracene [ ] Fluorene [ ] Indeno[1,2,3-cd]pyrene [ ] Phenanthrene [ ] Pyrene [ ] For individual pesticides see the Compounds section, pages

91 EPA Drinking water - pesticides and PBDEs by GC-MS Determination of selected pesticides and flame retartdants in drinking water by solid phase extraction and capillary column gas chromatography / mass spectrometry (GC-MS) The Method 527 was developed for the determination of selected semivolatile organic compounds in drinking water. PBDE Congeners of Primary interest (8 compounds, two concentrations; unit: 1x1ml) ( 7.8) EPA 527 Multiple Component Solutions Methods S ME EPA 527 Mix 1, Pesticides A 10 Analytes, each 500µg/mL in Methanol; unit: 1x1mL Atrazine [ ] Bromacil [ ] Esbiol (S-bioalletrin) [ ] Esfenvalerate [ ] Fenvalerate [ ] exazinone [ ] Kepone [ ] Norfluazon [ ] xychlordane [ ] Prometryne [ ] Propazine [ ] S ME EPA 527 Mix 2, Pesticides B 9 Analytes, each 500µg/mL in Methanol; unit: 1x1mL Bifenthrin [ ] Chlorpyrifos (Dursban) [ ] Dimethoate [ ] Malathion [ ] Mirex [ ] Nitrofen [ ] Parathion-ethyl [ ] Terbufos-sulfone [ ] Thiobencarb [ ] Vinclozolin [ ] S I EPA 527 Mix 3, DBE congeners and hexabromobiphenyl 5 Analytes, each 50µg/mL in Isooctane:Ethyl acetate (8:2); unit: 1x1mL ,2,4,4,5,5 -exabromobiphenyl PBB-153 [ ] ,2,4,4 -Tetrabromodiphenyl ether BDE-47 [ ] ,2,4,4,5-Pentabromodiphenyl ether BDE-99 [ ] ,2,4,4,6-Pentabromodiphenyl ether BDE-100 [ ] ,2,4,4,5,5 -exabromodiphenyl ether BDE-153 [ ] 89

92 S AC EPA 527, Internal standard 3 Analytes, each 500µg/mL in Acetone; unit: 1x1mL Acenaphthene-d10 [ ] Phenanthrene-d10 [ ] Chrysene-d12 [ ] S AC EPA 527, Surrogate standard 3 Analytes, each 500µg/mL in Acetone; unit: 1x1mL 3478,8 1,3-Dimethyl-2-nitrobenzene [ ] Triphenylphosphate [ ] Perylene-d12 [ ] EPA Phenols in drinking water by GC-MS Determination of phenols in drinking water by solid phase extraction and capillary column gas chromatography-mass spectrometry. This method provides procedures for the determination of phenols in finished drinking water. This method can also be used on untreated course water and other types of water samples. A large variety of phenols can be determined by this method. EPA 528 rev.1.0 Standard Stock Solutions 12 Single stock solutions, each analyte 5µg/mL in methanol; unit: 1x5mL of each solution ME Phenol [ ] ME 2-Chlorophenol [ ] ME 2-Methylphenol (o-cresol) [ ] ME 2-Nitrophenol [ ] ME 2,4-Dimethylphenol [ ] ME 2,4-Dichlorophenol [ ] ME 4-Chloro-3-methylphenol [ ] ME 2,4,6-Trichlorophenol [ ] ME 2,4-Dinitrophenol [ ] ME 4-Nitrophenol [ ] ME 2-Methyl-4,6-dinitrophenol [ ] ME Pentachlorophenol [ ] KIT Set of 12 stock solutions, 12x5 ml 90

93 S ME EPA 528 rev. 1.0 Primary Dilution Standard Solution 12 Analytes, each 30ng/mL in methanol; unit: 1x5mL Phenol [ ] Chlorophenol [ ] Methylphenol (o-cresol) [ ] Nitrophenol [ ] ,4-Dimethylphenol [ ] ,4-Dichlorophenol [ ] Chloro-3-methylphenol [ ] ,4,6-Trichlorophenol [ ] ,4-Dinitrophenol [ ] Nitrophenol [ ] Methyl-4,6-dinitrophenol [ ] Pentachlorophenol [ ] Methods S-4366-SET-5DC EPA 528 rev.1.0 Calibration Solutions 11 Analytes, 2 Internal Standards and 3 Surrogate Analytes in dichloromethane; unit: 7x5mL Analyte CAL 1 CAL 2 CAL 3 CAL 4 CAL 5 CAL 6 CAL 7 ng/µl ng/µl ng/µl ng/µl ng/µl ng/µl ng/µl Phenol [ ] Chlorophenol [ ] Methylphenol (o-cresol) [ ] Nitrophenol [ ] ,4-Dimethylphenol [ ] Chloro-3-methylphenol [ ] ,4,6-Trichlorophenol [ ] ,4-Dinitrophenol [ ] Nitrophenol [ ] Methyl-4,6-dinitrophenol [ ] Pentachlorophenol [ ] Internal Standards ,2-Dimethyl-3-nitrobenzene [ ] ,3,4,5-Tetrachlorophenol [ ] Surrogate Analytes Chlorophenol-3,4,5,6-d4 [ ] ,4-Dimethylphenol-3,5,6-d3 [ ] ,4,6-Tribromophenol [ ] S DC EPA 528 rev. 1.0 Internal Standard Solution 1 100µg/mL in dichloromethane; unit: 1x5mL ,2-Dimethyl-3-nitrobenzene [ ] S DC EPA 528 rev. 1.0 Internal Standard Solution 2 200µg/mL in dichloromethane; unit: 1x5mL ,3,4,5-Tetrachlorophenol [ ] 91

94 S-4369-ASS-5DC EPA 528 rev. 1.0 Internal Standard Solution 3 2 Analytes, each concentration as listed in dichloromethane; unit: 1x5mL ,2-Dimethyl-3-nitrobenzene [ ] 100µg/mL ,3,4,5-Tetrachlorophenol [ ] 200µg/mL S ME EPA 528 rev. 1.0 Sample Fortification Solution 1 100µg/mL in methanol; unit: 1x5mL Chlorophenol-3,4,5,6-d4 [ ] S AC EPA 528 rev. 1.0 Sample Fortification Solution 2 100µg/mL in acetone; unit: 1x5mL ,4-Dimethylphenol-3,5,6-d3 [ ] S ME EPA 528 rev. 1.0 Sample Fortification Solution 3 200µg/mL in methanol; unit: 1x5mL ,4,6-Tribromophenol [ ] EPA 604 Phenols in wastewater by GC-ECD or GC-FID Methods for organic chemical analysis of municipal and industrial wastewater Phenols This test method describes the procedure for the determination of phenols and phenols derivatives. Underivatized phenols may be analysed by GC-FID. Target phenols may also be derivatized with diazomethane or pentafluorobenzylbromide (PFBBr) and analysed by GC-FID or GC-ECD. S-4247-ASS-ME EPA 604 Calibration Mixture 11 Analytes, each 500µg/mL in methanol; unit: 1x1mL (2,4-Dinitrophenol and 4,6-dinitrocresol at concentration 1000µg/mL) Chloro-3-methylphenol [ ] Chlorophenol [ ] ,4-Dichlorophenol [ ] ,4-Dimethylphenol [ ] ,4-Dinitrophenol [ ] Methyl-4,6-dinitrophenol [ ] Nitrophenol [ ] Nitrophenol [ ] Pentachlorophenol [ ] Phenol [ ] ,4,6-Trichlorophenol [ ] 92

95 ME EPA 604, Surrogate Standard 200 µg/ml in methanol; unit: 1x1mL ,4,6-Tribromophenol [ ] S ME EPA 604 Calibration Mixture as PFB derivatives 11 Analytes, each 200µg/mL in methanol; unit: 1x1mL Chloro-3-methylphenol [ ] Chlorophenol [ ] ,4-Dichlorophenol [ ] ,4-Dimethylphenol [ ] ,4-Dinitrophenol [ ] Methyl-4,6-dinitrophenol [ ] Nitrophenol [ ] Nitrophenol [ ] Pentachlorophenol [ ] Phenol [ ] ,4,6-Trichlorophenol [ ] Methods ME EPA 604, Surrogate Standard as PFB derivatives 200 µg/ml in methanol; unit: 1x1mL ,4,6-Tribromophenol-PFB EPA 606 Phthalate esters in wastewater by GC Methods for organic chemical analysis of municipal and industrial wastewater Phthalate esters Standard test method for the determination of phthalate esters in municipal and industrial wastewater by gas chromatography with electron capture detector. S K-X S K-5X EPA 606 Phthalate Esters in Waste Water by GC-ECD 6 Analytes, each 2000µg/mL in hexane; units: 5x1mL, 1x5mL Bis(2-ethylhexyl) phthalate [ ] Benzyl butyl phthalate [ ] Di-n-butyl phthalate [ ] Diethyl phthalate [ ] Dimethyl phthalate [ ] Di-n-octyl phthalate [ ] 93

96 S-4234-ASS-AC S-4234-ASS-5AC EPA 606 Control Sample Mixture 6 Analytes, each concentration as listed in acetone; units: 5x1mL, 1x5mL Bis(2-ethylhexyl) phthalate [ ] 500µL/mL Benzyl butyl phthalate [ ] 100µL/mL Di-n-butyl phthalate [ ] 250µL/mL Diethyl phthalate [ ] 250µL/mL Dimethyl phthalate [ ] 250µL/mL Di-n-octyl phthalate [ ] 500µL/mL EPA 608/625 rganochlorine pesticides and PCBs by GC and GC-MS in municipal discharges These methods covers the determination of certain organochlorine pesticides and PCBs in municipal and industrial discharges. For individual pesticides and PCBs, see the Compound section, pages 367 and 354. EPA 610 PA in wastewater by PLC and GC Methods for organic chemical analysis of municipal and industrial wastewater PAs Standard test method for the determination of certain polycyclic aromatic hydrocarbons (PA) in municipal and industrial wastewater by both high performance liquid chromatography and gas chromatography. S-4114-ASS-5AN 16 Priority PA, Control Mix 16 Analytes, each concentration as listed in acetonitrile; unit: 1x5mL screw cap bottle Acenaphthene [ ] 100 µg/ml Acenaphthylene [ ] 100 µg/ml Anthracene [ ] 100 µg/ml Benz[a]anthracene [ ] 10 µg/ml Benzo[b]fluoranthene [ ] 100 µg/ml Benzo[k]fluoranthene [ ] 5 µg/ml Benzo[ghi]perylene [ ] 10 µg/ml Benzo[a]pyrene [ ] 10 µg/ml Chrysene [ ] 10 µg/ml Dibenz[a,h]anthracene [ ] 10 µg/ml Fluoranthene [ ] 10 µg/ml Fluorene [ ] 10 µg/ml Indeno[1,2,3-cd]pyrene [ ] 10 µg/ml Naphthalene [ ] 100 µg/ml Phenanthrene [ ] 100 µg/ml Pyrene [ ] 10 µg/ml 94

97 S-4115-ASS-AN Check Mix, EPA Analytes, each concentration as listed in acetonitrile; units: 1x1mL, 5x1mL EPA 1614 PBDEs by RGC/RMS Naphthalene [ ] 100 µg/ml Acenaphthylene [ ] 100 µg/ml Acenaphthene [ ] 100 µg/ml Fluorene [ ] 100 µg/ml Phenanthrene [ ] 100 µg/ml Anthracene [ ] 100 µg/ml Benzo(k)fluoranthene [ ] 5 µg/ml Chrysene [ ] 10 µg/ml Methods Brominated diphenyl ethers in water, soil, sediment, and tissue by RGC/RMS The Method 1614 was developed for determination of the polybrominated diphenyl ether congeners commonly found in environmental samples and resulting from use of brominated flame retardants, by isotope dilution and internal standard high resolution gas chromatography/high resolution mass spectrometry (RGC/RMS). The method is applicable to aqueous, solid, tissue, and multi-phase matrices. S I EPA 1614 Multiple Component Solution S I PBDE Congeners of Primary interest (7 compounds, two concentrations; unit: 1x1mL) ( 7.8) Chiron No. Compound Abbr. CAS No. S I S I µg/ml µg/ml ,4,4 -Tribromodiphenyl ether PBDE-28 [ ] ,2,4,4 -Tetrabromodiphenyl ether PBDE-47 [ ] ,2,4,4,5-Pentabromodiphenyl ether PBDE-99 [ ] ,2,4,4,6-Pentabromodiphenyl ether PBDE-100 [ ] ,2,4,4,5,5 -exabromodiphenyl ether PBDE-153 [ ] ,2,3,4,4,5,6 -eptabromodiphenyl ether PBDE-183 [ ] Decabromodiphenyl ether PBDE-209 [ ] Internal standards F-PBDEs In isooctane or toluene; unit: 1x1mL For a complete list, see the Compound section, pages I 3 -Fluoro-2,4-dibromodiphenyl ether F-PBDE-7 50µg/mL I 3 -Fluoro-3,4-dibromodiphenyl ether F-PBDE-12 50µg/mL I 4 -Fluoro-2,3,6-tribromodiphenyl ether F-PBDE-27 [ ] 50µg/mL T 2 -Fluoro-2,4,4 -Tribromodiphenyl ether F-PBDE-28 [ ] 50µg/mL T 6-Fluoro-2,2,4,4 -tetrabromodiphenyl ether F-PBDE-47 [ ] 50µg/mL I 5,5 -Difluoro-2,2,4,4 -tetrabromodiphenyl ether 2F-PBDE-47 [ ] 50µg/mL I 6-Fluoro-2,3,4,4 -tetrabromodiphenyl ether F-PBDE-66 50µg/mL I 5,6-Difluoro-2,2,3,4,4 -pentabromodiphenyl ether 2F-PBDE-85 50µg/mL I 3,6-Difluoro-2,2,4,4 5-pentabromodiphenyl ether 2F-PBDE-99 [ ] 50µg/mL T 3-Fluoro-2,2,4,4,6-pentabromodiphenyl ether F-PBDE-100 [ µg/mL I 3,5-Difluoro-2,3,4,4,6-pentabromodiphenyl ether 2F-PBDE-119 [ ] 50µg/mL T 4 -Fluoro-2,3,3,4,5,6-hexabromodiphenyl ether F-PBDE-160 [ ] 50µg/mL T 4,6-Difluorooctabromodiphenyl ether 2F-PBDE-201 [ ] 50µg/mL I 4 -Fluoro-2,2,3,3,4,5,5 6,6 - F-PBDE-208 [ ] 50µg/mL nonabromodiphenyl ether 95

98 Labelled Internal Standard Multiple Congeners are made by request based upon choice and requirement, e.g.: Name Congener CS-1 CS-2 CS-3 CS-4 CS-5 Natives ng/ml ng/ml ng/ml ng/ml ng/ml ,4,4 -TrBDE PBDE-28 [ ] ,2,4,4 -TeBDE PBDE-47 [ ] ,2,4,4,5-PeBDE PBDE-99 [ ] ,2,4,4,6-PeBDE PBDE-100 [ ] ,2,4,4,5,5 -ebde PBDE-153 [ ] ,2 3,4,4,5,6-pBDE PBDE-183 [ ] DeBDE PBDE-209 [ ] Labelled Fluoro-2,4,4 -TrBDE F-PBDE-28 [ ] Fluoro-2,2,4,4 -TeBDE F-PBDE ,5 -Difluoro-2,2,4,4 - TeBDE FF-PBDE-47 [ ] Fluoro-2,3,4,4 -TeBDE F-PBDE ,6-Difluoro-2,2,3,4,4 - PeBDE F-PBDE ,6-Difluoro-2,2,4,4 5- PeBDE FF-PBDE-99 [ ] Fluoro-2,2 4,4,6- PeBDE F-PBDE-100 [ ] Fluoro-2,3,3,4,5,6- xbde F-PBDE ,6-Difluoro-cBDE FF-PBDE-201 [ ] Fluoro-2,2,3,3, 4,5,5 6,6 -NoBDE F-PBDE-208 [ ] Labelled clean-up ,5-Difluoro- 2,3,4,4,6-PeBDE F-PBDE-119 [ ] Labelled Injection Internal Fluoro-2,4,6-TrCB F-PCB-30m Fluoro-3,4,4,5-TeCB F-PCB EPA 1653 Chlorinated phenols in pulp and papir industries wastewater Chlorinated phenolics wastewater by in situ acetylation and GC-MS S ME EPA 1653 Chlorophenols 7 Analytes, each 100µg/mL in methanol; units: 1x1mL, 5x1mL Chlorophenol [ ] ,4-Dichlorophenol [ ] ,6-Dichlorophenol [ ] ,4,5-Trichlorophenol [ ] ,4,6-Trichlorophenol [ ] ,3,4,6-Tetrachlorophenol [ ] Pentachlorophenol [ ] 96

99 S ME Me Guaiacol S ME EPA 1653 Chloroguaiacols 8 Analytes, each 100µg/mL in methanol; unit: 1x1mL 4-Chloroguaiacol [ ] 3,4-Dichloroguaiacol 4,5-Dichloroguaiacol 4,6-Dichloroguaiacol 3,4,5-Trichloroguaiacol 3,4,6-Trichloroguaiacol 4,5,6-Trichloroguaiacol Tetrachloroguaiacol EPA 1653 Chlorocathecols 7 Analytes, each 100µg/mL in methanol; unit: 1x1mL 4-Chlorocatechol [ ] 3,4-Dichlorocatechol 3,6-Dichlorocatechol 4,5-Dichlorocatechol [ ] 3,4,5-Trichlorocatechol 3,4,6-Trichlorocatechol Tetrachlorocatechol [ ] Methods S AC Me Cl Cl Me Cl Trichlorosyringol EPA 1653 Chlorovanillines and syringealdehydes 6 Analytes, each 100µg/mL in acetone; unit: 1x1mL 5-Chlorovanillin [ ] 6-Chlorovanillin 5,6-Dichlorovanillin 2-Chlorosyringaldehyde Trichlorosyringol 2,6-Dichlorosyringaldehyde EPA 1668 PCBs by RGC/RMS Revision A: Chlorinated biphenyl congeners in water, soil, sediment, and tissue by RGC/RMS Method 1668 was developed by the U.S. EPA for congener-specific determination of the polychlorinated biphenyl (PCB) congeners designated by W. The toxic PCBs and the beginning and ending level-of-chlorination CBs are determined by isoptope dilution high resolution gas chromatography/high resolution mass spectrometry (RGC/RMS). The remaining PCBs are determined by internal standard RGC/RMS. Method 1668A is applicable to aqueous, solid, tissue, and multiphase matrices. 97

100 EPA 8041 A Phenols and derivatives by GC-ECD or FID Phenols by gas chromatography Standard Test method for analysis of phenols in solid waste and ground water using GC procedures and derivatization. Underivatized phenols may be analysed by GC-FID. Target phenols may also be derivatized with diazomethane or pentafluorobenzylbromide (PFBBr) and analysed by GC-FID or GC-ECD. ther compositions are available, please inquire. CIRN can also offer the PFB derivatives. S-4207-K-IP EPA 8041A RCRA Target Phenols Solution 21 Analytes, each1000µg/ml in isopropanol; unit: 1x1mL Chloro-3-methylphenol [ ] Chlorophenol [ ] Methylphenol [ ] Methylphenol [ ] Methylphenol [ ] Cyclohexyl-4,6-dinitrophenol [ ] ,4-Dichlorophenol [ ] ,6-Dichlorophenol [ ] ,4-Dimethylphenol [ ] ,4-Dinitrophenol [ ] Dinoseb [ ] Methyl-4,6-dinitrophenol [ ] Nitrophenol [ ] Nitrophenol [ ] Pentachlorophenol [ ] Phenol [ ] ,3,4,5-Tetrachlorophenol [ ] ,3,4,6-Tetrachlorophenol [ ] ,3,5,6-Tetrachlorophenol [ ] ,4,5-Trichlorophenol [ ] ,4,6-Trichlorophenol [ ] 98

101 S-4208-K-IP EPA 8041A Non-RCRA Target Phenol Standards 17 Analytes, each 1000µg/mL in isopropanol; unit: 1x1mL Chloro-5-methylphenol [ ] Chloro-2-methylphenol [ ] Chlorophenol [ ] Chlorophenol [ ] ,3-Dichlorophenol [ ] ,5-Dichlorophenol [ ] ,4-Dichlorophenol [ ] ,5-Dichlorophenol [ ] ,3-Dimethylphenol [ ] ,5-Dimethylphenol [ ] ,6-Dimethylphenol [ ] ,4-Dimethylphenol [ ] ,5-Dinitrophenol [ ] Nitrophenol [ ] ,3,4-Trichlorophenol [ ] ,3,5-Trichlorophenol [ ] ,3,6-Trichlorophenol [ ] Methods S-4209-K-IP S-4209-K-5IP EPA 8041A Internal Standard 2 Analytes, each 1000µg/mL in isopropanol; unts: 1x1mL, 5x1mL, 1x5mL ,5-Dibromophenol [ ] ,2,5,5 -Tetrabromobiphenyl [ ] K-I K-5I EPA 8041A Surrogate Standard 1000µg/mL in isopropanol; unts: 1x1mL, 5x1mL, 1x5mL ,4-Dibromophenol [ ] K-I K-5I EPA 8041A Surrogate Standards PFB-derivatives 1000µg/mL in isopropanol; unts: 1x1mL, 5x1mL, 1x5mL ,4-Dibromophenol-PFB EPA 8061 A Phthalates by GC-ECD Phthalate esters by gas chromatography with electron capture detection (GC-ECD). This test method is used to determine the identities and concentration of various phthalate esters in aqueous and solid matrices, including groundwater, leachate, soil, sludge and sediment. 99

102 S-4235-K-I S-4235-K-5I Phthalate Esters in Sludge Matrixes by GC-ECD 16 Analytes, each 1000µg/mL in isooctane; units: 5x1mL, 1x5mL Bis(2-n-butoxyethyl) phthalate [ ] Bis(2-ethoxyethyl) phthalate [ ] Bis(2-ethylhexyl) phthalate [ ] Bis(2-methoxyethyl) phthalate [ ] Bis(4-methyl-2-pentyl) phthalate [ ] Butyl benzyl phthalate [ ] Diamyl phthalate [ ] Di-n-butyl phthalate [ ] Dicyclohexyl phthalate [ ] Diethyl phthalate [ ] Di-n-hexyl phthalate [ ] Diisobutyl phthalate [ ] Dimethyl phthalate [ ] Diisononyl phthalate [ ] Di-n-octyl phthalate [ ] exyl 2-ethylhexyl phthalate [ ] Internal standards EPA Method 8061A 2000µg/mL in hexane; unit: 1x5mL K-5X Benzyl benzoate [ ] Calibration Standards (Surrogate) EPA Method 8061A 3 Analytes, each 100µg/mL in hexane; unit: 1x5mL X Dibenzyl phthalate [ ] X Diphenyl isophthalate [ ] X Diphenyl phthalate [ ] EPA 8082 PCBs by GC-ECD Polychlorinated biphenyls by gas chromathography Method 8082 is used to determine the concentration of polychlorinated biphenyls (PCBs) as Aroclors or as individual PCB congeners in extracts from solid and aqueous matrices. Capillary columns are employed together with electron capture detection (ECD) or electrolytic conductivity detectors (ELCD). 100

103 EPA 8100 PAs in water by GC-FID Polycyclic aromatic hydrocarbons in ground/waste water by GC-FID Standard Test Method for the Determination of certain Polycyclic Aromatic ydrocarbons in Ground/Waste water by GC-FID. This test method is applicable for the determination of ppb levels of certain PAs. The method provides the gas chromatographic conditions for the determination. S-4114-ASS-5AN 16 Priority PA, Control Mix 16 Analytes, each 5 ml in acetonitrile in screw-capped bottle Methods The 16 Analytes are listed under EPA 610. The QC control mixture is applicable to both methods. Surrogate standards K-5DC 2-Fluorobiphenyl [ ] 2000 µg/ml in dichloromethane, 5 ml K-5DC Fluoronaphthalene [ ] 2000 µg/ml in dichloromethane, 5 ml EPA 8260 B Volatile compounds by GC-MS Volatile organic compounds by gas chromatography-mass spectrometry. This method is used to determine volatile organic compounds in a variety of solid waste matrices. S ME EPA 8260 Multiple Component Solution 1 16 Analytes, each 100µg/mL in methanol; unit: 1x1mL Benzene [ ] n-butylbenzene [ ] sec-butylbenzene [ ] tert-butylbenzene [ ] Ethylbenzene [ ] Isopropylbenzene [ ] p-isopropyltoluene [ ] Naphthalene [ ] n-propylbenzene [ ] Styrene [ ] Toluene [ ] ,2,4-Trimethylbenzene [ ] ,3,5-Trimethylbenzene [ ] o-xylene [ ] m-xylene [ ] p-xylene [ ] 101

104 EPA 8270 C Semivolatile compounds by GC-MS Semivolatile organic compounds by gas chromatography-mass spectrometry. This method is used to determine the concentration of semivolatile organic compounds in extracts prepared from many types of solid waste matrices, soils, air sampling media and water samples. S ME EPA 8270 Multiple Component Solution 1 37 Analytes, each 100µg/mL in methanol; unit: 1x1mL Acenaphthene [ ] Acenaphthylene [ ] Acetophenone [ ] Aniline [ ] Anthracene [ ] Benzoic acid [ ] Benz[a]anthracene [ ] Benzo[b]fluoranthene [ ] Benzo[k]fluoranthene [ ] Benzo[ghi]perylene [ ] Benzo[a]pyrene [ ] p-benzoquinone [ ] Benzyl alcohol [ ] Chrysene [ ] Dibenz[a]acridine [ ] Dibenz[a,h]anthracene [ ] Dibenzofuran [ ] Dibenzo[a,e]pyrene [ ] ,12-Dimethylbenz[a]anthracene [ ] ,4-Dimethylphenol [ ] Fluoranthene [ ] Fluorene [ ] ydroquinone [ ] Indeno[1,2,3-cd]pyrene [ ] Isophorone [ ] Methylcholanthrene [ ] Methylnaphthalene [ ] Methylphenol [ ] Methylphenol [ ] Methylphenol [ ] Naphthalene [ ] Perylene [ ] Phenanthrene [ ] Phenol [ ] Picoline [ ] Pyrene [ ] Pyridine [ ] Resorcinol [ ] 102

105 S ME EPA Multiple Component Solution 1, 3 additional compounds Carbazole [ ] Carbon disulfide [ ] Ethylphenol [ ] EPA 8275 A Semivolatile compounds in soils/sludges wastes using TE-GC-MS Semivolatile organic compounds (PAs and PCBs) in soils/sludges and solid wastes using thermal extracion capillary gas chromatographic mass spectrometry. Methods This test method provides a rapid procedure for the quantitative determination of targeted PCBs and PAs in soils, sludges and solid wastes. The procedure is based on a thermal extraction capillary GC-MS. S K-DC Internal standard mixture for EPA 8275A and 8270C 6 Analytes, each 4000µg/mL in dichloromethane; units: 1x1mL, 5x1mL Acenaphthene-d10 [ ] Chrysene-d12 [ ] ,4-Dichlorobenzene-d4 [ ] Naphthalene-d8 [ ] Perylene-d12 [ ] Phenanthrene-d10 [ ] EPA 8310 Polynuclear aromatic hydrocarbons Polycyclic aromatic hydrocarbons (PA) in ground water and wastes by high performance liquid chromatography with ultraviolet and fluorescence detector. This test is used for the quantitative determination of certain polycyclic aromatic hydrocarbons (PA) in ground water and wastes. The method provides PLC conditions for the detection of ppb levels of certain PAs. Surrogate Mix K-5AN Decafluorobiphenyl [ ] 2000µg/mL in acetontirile, 5 ml 103

106 Miscellaneous methods NRDTEST technical reports 497, 498, 499 il spill identification Proposed CEN method, Revision of the Nordtest Methology for il Spill Identification. The project is a collaboration between the National Forensic il Spill Identification laboratories in Finland, Denmark, Norway, Sweden and Battelle Laboratories in the USA. The technical reports summarise the results of an extensive literature study. A database of diagnostic ratios for precently 28 crude oils and oil products has been established. GC chromatograms and ion chromatograms of diagnostic biomarkers for these oils are given. This method is proposed for the CEN system. This report lists biomarkers to be analysed and gives recommendations for internal standards: Internal standards (ISTD) X Surrogate ISTD, o-terphenyl, 2 mg/l, 10 ml Dilute to 200µg/mL working standard in hexane X Recovery ISTD, 5 ()-Androstane, 2 mg/ml, 10 ml Dilute to 200µg/mL working standard in hexane S XY Surrogate ISTD - PA 3 Analytes each 500µg/mL in xylene; unit: 1x1mL d8-naphthalene [ ] d10-phenanthrene [ ] d12-chrysene [ ] S XY Recovery ISTD - PA 3 Analytes each 100µg/mL in xylene; unit: 1x1mL d12-perylene [ ] d10-acenaphthene [ ] d10-fluorene [ ] Analytical standard mixes S X K-I S X S X Analytical Standard for n-alkanes, 10 ml Use 100µg/mL in hexane as a working standard n-c10-c40 + Pristane ther alternative mixes: Analytical standard for phytane Mixture with the n-alkanes + pristane, phytane n-alkane C10-C40 (even+pristane, phytane) 104

107 S CY n-alkane C10-C40 (even and uneven+pristane, phytane) See page 186 in the Petroleum section S-4200-ASS-X Calibration Standard TC 26 Analytes, each concentration as listed in hexane; unit : 6x1mL The working standard concentrations are: o-terphenyl (ITSD) 5a-Androstane (ITSD) n-alkane C10-C40 (even + pristane, phytane) n-alkane C10-C40 (even + pristane, phytane) n-alkane C10-C40 (even + pristane, phytane) n-alkane C10-C40 (even + pristane, phytane) n-alkane C10-C40 (even + pristane, phytane) n-alkane C10-C40 (even + pristane, phytane) 200 µg/ml 200 µg/ml 1 µg/ml 5 µg/ml 10 µg/ml 20 µg/ml 50 µg/ml 100 µg/ml Methods S DC 16 priority PA, cocktail 1 See the Environmental section, page EPA PAS each 100 µg/ml in dichloromethane; unit: 1x5 ml S DC PA - others 13 Analytes, each 100 µg/ml in dichloromethane; unit: 1x5 ml Methylnaphthalene [ ] ,3-Dimethylnaphthalene [ ] Biphenyl [ ] Methylphenanthrene [ ] ,6-Dimethylphenanthrene [ ] Methylfluorene [ ] Ethylfluorene [ ] Dibenzothiophene [ ] ,8-Dimethyldibenzothiophene [ ] Perylene [ ] Dibenzofuran [ ] Benzo[b]thiophene [ ] Decahydronaphthalene (decaline) [ ] Please inquire for details For a complete range of NPDs and PAs standards and mixtures, see pages 143 and 129. Single component standards PAs 58 compounds listed in the standard. All are available from Chiron, see the Compounds section page 295. Biomarkers 38 compounds listed in the standard. More than 30 are available from Chiron, see the Compounds section page

108 FR No Aromatics in produced water S T Aromatic Petroleum Pollutants 6 Analytes, each 200 µg/ml in toluene; units: 1x1 ml, 5x1 ml Methylnaphthalene [ ] ,6-Dimethylnaphthalene [ ] Methylphenanthrene [ ] ,6-Dimethylphenanthrene [ ] Fluoranthene [ ] Benzo[a]pyrene [ ] Concentrations are designed according to customer requirements S-4230-ASS-T Aromatic Petroleum Pollutant IS-Mixtures 3 Analytes, each concentration as listed in toluene; units: 1x1 ml, 5x1 ml Fluoronaphthalene [ ] 400 µg/ml Fluorophenanthrene [ ] 200 µg/ml Fluorofluoranthene [ ] 100 µg/ml NS 9815 PAs by GC Water and Air Analysis Gas Chromatographic Analysis for the Determination of Polycyclic Aromatic ydrocarbons. S T Norwegian Standard (NS 9815) 16 Analytes, each 100 µg/ml in toluene; unit: 1x1 ml Phenanthrene [ ] Anthracene [ ] Fluoranthene [ ] Pyrene [ ] Benzo[a]fluorene [ ] Benzo[b]fluorene [ ] Benz[a]anthracene [ ] Chrysene [ ] Benzo[b]fluoranthene [ ] Benzo[k]fluoranthene [ ] Benzo[a]pyrene [ ] Benzo[e]pyrene [ ] Indeno[1,2,3-cd]pyrene [ ] Dibenz[a,h]anthracene [ ] Benzo[ghi]perylene [ ] Dibenzo[a,e]pyrene [ ] 106

109 Chapter III: Applications Table of contents Chapter III-1: Environmental Applications Chapter III-2: Petroleum applications Chapter III-3: Food safety Chapter III-4: Pharmaceuticals and forensics

110 108

111 Chapter III-1: Environmental applications Table of contents Priority pollutants Dirty dozens EU water policy Pollution from petroleum products il spill identification and biomarker fingerprinting Spills from petroleum production Surfactants Alkylphenol ethoxylates Phthalates and adipates LAS (linear alkylbenzene sulfonates) and ABS (alkylbenzene sulfonates) Linear perfluoroalkyl sufonates, acids and alcohols pfas Phenols and phenol analysis Phenols Alkylated phenols Chloro- and nitrophenol standards PA analysis and PA mixtures Internal standards EPA and 15 EU all-in-one deuterated standards Native single PA-standards, metabolites and derivatives International methods Reference PA-cocktails according to international methods The universal all-in-one 16 EPA-PA solutions from Chiron The universal all-in-one 15 EU-PA solutions from Chiron W/EU PA in drinking water (=IS and 2) ther PA mixes PPS (Persistent organic pollutants) PCBs PBBs (Polybrominated biphenyls) PCNs (Polychlorinated naphthalenes) PBNs (Polybrominated naphthalenes) PBDE flame retardants ther flame retardants Dioxins and furans PCAs, SCCPs, C10-C13 polychloroalkanes Pesticides, herbicides Chlorobenzenes Bromobenzenes Chlorophenols Bromophenols ther VC (Volatile organic compounds) Miscellaneous mixtures rganotin analysis Ethyl derivatives Tin chlorides Phosphates Native standards Determination of the origin of faecal waste Environmental 109

112 Priority pollutants Dirty dozens The Stockholm Convention agreed to phase out 12 important compounds or groups of substances that are causing adverse human effects and that are all considered persitent organic pollutants (PPs). The 12 substances or classes of substances are: PCBs Pages Dioxins Page 358 Dibenzofurans Page 351 exachlorobenzene (CB) Page 286 Various pesticides: Pages Aldrin Chlordane Dichlorodiphenyltrichloroethane (DDT) Dieldrin Endrin eptachlor Mirex Toxaphene EU water policy In the field of water pollution, the EU Commission (European Commission Directive 2000/60/EC) proposes 32 priority substances to be phased out and 11 substances identified as hazardous. In addition to the 12 compound groups listed by the Stockholm convention, these are: alogenated compounds: PBDEs (pentabrominated diphenylether) Pages Chloroalkanes, C10-C13 Page 362 exachlorobenzene Page 286 exachlorobutadiene Page 365 exachlorocyclohexane Page 370 Pentachlorbenzene Page 286 Nonylphenols Page 373 PAs Pages Tributyltin compounds Pages Mercury Cadmium 110

113 Pollution from petroleum products il spills is probably the type of pollution that occurs most widely. undreds of millions of gallons of petroleum has been spilled over the last centuries into landfields and marine waters from tankers, pipelines, production sites and underground storage tanks. Also input from seeps, natural disasters (e.g. Catarina) and wars (The gulf war) play an important role in the total petroleum input to the environment. Typically groups of compounds analyzed in petroleum spill analysis are: - Biomarkers: il Spill Identification - AlkylPAS, ydropas: il spill identification and environmental assessment of productions sites - Total ydrocarbon Analysis: il spill identification, Production sites and waste water analysis - ydrocarbons in water: Production sites and waste water analysis - Phenol, surfactants, production chemicals: Production sites il spill identification and biomarker fingerprinting Petroleum samples from different sources are easily distinguished by their chemical composition. This is used in several aspects of oil spill analysis, like determination of oil spill leakages and identification of illegal marine spills. Also the biodegradation is studied using biomarker analysis due to the legal and huge economic aspects of petroleum spills. Environmental The composition of a spilled oil may vary considerably from the original oil due to evaporization, weathering etc. Several EPA and ASTM methods have been modified in order to improve the specificity and sensitivity of oil and petroleum products analysis. Specific methods have been developed by groups in Europe, Canada and USA. Chiron offers a wide range of specific compounds and mixtures specifically designed for the use in connection with these methods. Custom made mixes are available on order and request at reasonable prices. The type of compounds used are - Biomarkesrs, hopanes and steranes - PAs, alkylpas and dibenzothiophene profiling - n-alkanes, pristane, phytane, monoaromatics - Adamantanes and sesquieterpanes An excellent and recent book has been reported by Wang and Stout: il Spill Environmental Forensics, Fingerprinting and Source Identification, Elsevier Available biomarkers, PAs and alkanes (See the Compounds section for available single hopane and sterane biomarkers, alkylpas and alkanes) Special mixes of biomarkers are made on request For alkylpa mixes, see the PA section below, page 129 or inquire for custom mixes. For alkane mixes, see the Petroleum applications section, page 167. For reference consult the following reference methods and literature: - Wang et al.; Marine Pollution Bulletin 47 (2003) , Journal of Chromatography A, 1038 (2004) NRDTEST Methods (see the Methods section, page 104) - ASTM method D (see the Methods section, page 67) - Check this catalogue for a complete set of alkylated PAs (the Compounds section, page 295 and onward) and Biomarkers (the Compounds section, page 225 and onward). 111

114 Methods - NRDTEST Technical Reports 497, 498, 499: Proposed CEN method Revision of the Nordtest Methology for il Spill Identification. The project is a collaboration between the National Forensic il Spill Identification laboratories in Finland, Denmark, Norway, Sweden and Battelle Laboratories in the USA. The technical reports summarize the results of an extensive literature study. A database of diagnostic ratios for precently 28 crude oils and oil products has been established. GC chromatograms and ion chromatograms of diagnostic biomarkers for these oils are given. This method is proposed for the CEN system. This report lists biomarkers to be analysed and gives recommendations for internal standards: - ASTM D Standard Practice for il Spill Identification by Gas Chromatography and Positive Ion Electron Impact Resolution Mass Spectrometry Spills from petroleum production Waste from offshore operated fields is an increasing concern. Typical pollutants from such installations include: - BTEX - PA/NPD - Phenols - rganic acids - Metals - Radioactive elements - Dispersed oil in water (ydrocarbon il in Water) References: SFT: FR No.1157: LF Recommended Guidelines for produced water: ydrocarbon oil in water iw IS Water Quality Determination of hydrocarbon oil index The method of choice for the determination of oil and grease in water is IS-Standard , based on extraction with a hydrocarbon solvent like pentane or hexane. This test determines the hydrocarbon oil index in water by means of gas chromatography. The method is suitable for surface water, waste water, and water from sewage treatment plants, and allows the determination of the hydrocarbon oil index in concentrations above 0.1 mg/l. The index is the sum of compounds with retention times between n-decane and n-tetracontane. Substances complying with this definition are long-chain or branched aliphatic, alicyclic, aromatic or alkylsubstituted aromatic hydrocarbons. The former method IS/TR from 1994 for the determination of mineral-oil content of soils and sediments has been withdrawn and is replaced by IS IS Mod. This is a modified method for oil in water analysis of produced water from offshore petroleum production installations. IS is not applicable for volatile hydrocarbons, and a modification of the method is proposed by the SPAR commission in order to include the determination of certain hydrocarbons with boiling points between 98 and 174 ºC from produced water. The SPAR Reference Method of Analysis for the Determination of the Dispersed il Content in Produced Water: Reference Number

115 Chiron offers a full range of products for IS and the modified method. Several customized mixes and products which are not listed in the catalogue. Please inquire for a detailed offer. See the Methods section for the details of these two methods, page 18 and onward. PAs, hydropas and thiophenes PAs are typical constituents of petroleum. In particular one finds a range of - Alkylnaphthalenes, -fluorenes, -phenanthrenes, -chrysenes, -pyrenes, -flouranthenes etc. - Large PAs - Tetralines, decalines and hydrogenated 3-7 ring PAs - Alkylated sulfurcontaining compounds like thiophenes, benzothiophenes, dibenzothiophenes etc. Chiron offers the widest range of PAs available, including single components PAs, PASs and PANs, hydroxy-, nitro- and aminopas, internal standards and custom mixes, and recently the John Fetzer Collection of Large PAs and hydropas. (All these compounds are included in the present catalogue.) - AlkylPA and dibenzothiophene and NPD mixes and cocktails: see the PA section, page To view the complete set of PAs available, see the Compounds section, page 295. International PA-methods: ASTM D SFC-method ASTM D Gasoline ASTM D il spill ASTM D Aromatics in gasoline ASTM D Aviation fuels ASTM D Middle distillates IS :2005 Water quality six PAs by tlc IS :2005 Water quality sixpas by PLC IS 15753:2006 PA in Animal and vegetable fats and oils IS 17993:2002 Water quality 15 PAs by PLC EPA Water rganics and PAs by GC EPA 527 Drinking water pesticides and PBDEs by GC/MS EPA 610 PA in wastewater by PLC and GC EPA 8100 PAs in water by GC-FID EPA 8260 Volatile Compounds by GC-MS EPA 8270C Semivolatile Compounds by GC-MS EPA 8310 Polycyclic Aromatic ydrocarbons in Ground water and wastes Environmental Alkylated tetralines and decalines Alkylated decalines occur in oil and are used as indicators of petroleum pollutions in the Norwegian Standard NS, and have to be monitored and reported to the SFT by the production companies. Being the only company, Chiron now offers mixtures and single compounds as calibration standards for alkyldecaline analysis. C1-C8 Decalines: See the Compounds section, page 238 or inquire. 113

116 Tetralines (1,2,3,4-tetrahydronaphthalenes) Cycloalkanoaromatics (naphthenoaromatics) are usually the major constituents of the high boiling fraction of hydrocarbons. Mono- and diaromatics are especially abundant compared to polyaromatics in paraffinic-naphthenic crude oils from detrital sedimentary series Tetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Methyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Methyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Ethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Ethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Ethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,4-Dimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,8-Dimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,6-Dimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,7-Dimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,7-Dimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,1,6-Trimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,5,8-Trimethyltetraline (98%) [ ] 1000µg/mL, 1 ml in isooctane ,5,8-Trimethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane ,2,5,7-Tetramethyltetraline (98%) [ ] 1000µg/mL, 1 ml in isooctane ,7-Diethyl-1,1,4,4-tetramethyltetraline (99%) [ ] 1000µg/mL, 1 ml in isooctane Tetraline Kit ydronaphthalenes and decalines ,2-Dihydronaphthalene (99%) [ ] 1000µg/mL, 1 ml in isooctane exahydronaphthalene (96%) [ ] 1000µg/mL, 1 ml in isooctane cis-decalin (99%) [ ] 1000µg/mL, 1 ml in isooctane trans-decalin (99%) [ ] 1000µg/mL, 1 ml in isooctane Methyldecalin (mixture of isomers) [ ] 500µg/mL, 1 ml in isooctane Isopropyldecalin (mixture of isomers) 500µg/mL, 1 ml in isooctane ,1,4,4,5-Pentamethyldecalin (mix of isomers) 500µg/mL, 1 ml in isooctane ydronaphthalene Kit 7 samples (7 compounds), 1 vial of each Alkylated decalines occur in oil and are used as indicators of petroleum pollution in the Norwegian Standard, and have to be monitored and reported to the SFT by the production companies on the shelf. Chiron now offers mixtures and single compounds as calibration standards for alkyldecaline analysis. C1-C8 Decalines: 2-Alkylated Decalines: Please inquire. 114

117 Alkylphenols Alkylphenols are used as surfactants in the drilling fluid. The alkylphenols can be analyzed directly by GC-FID, GC-MS, GC-ECD etc. Derivatization prior to analysis is common in many standard methods, i.e. to pentafluorobenzoyl esters, methyl ethers and acetates. Chiron offers single pure solutions of alkylphenols, and large range of internal standard, and reagents for derivatization. Custom synthesis and custom manufactured solutions are available on request. Please consult the phenol section below and the Compounds section. Total hydrocarbon analysis TP Petroleum spills from petroleum storage need to be analysed and quantified. The analytical chemists are challenged due to the weathering of the spills in the environment. Also, the spills may be a mixture of several petrochemical products or origin from different sources. Chiron offers the largest range of single pure aromatics, aliphatics and naphthenic compounds on the market. Also, Chiron has prepared a broad range of standard products and special custom designed products for TP analysis: BTEX Benzene, Toluene, Ethylbenzene, Xylenes UST Underwater Storage Tank Remediation GR Gasoline Range rganics DR Diesel Range rganics RR Residual Range rganics EP Extractable Petroleum ydrocarbons Environmental BTEX S ME BTEX Mixture 1 S ME 6 Analytes, each 200 µg/ml in methanol; units:1x1 ml, 1x5 ml Benzene [ ] o-xylene [ ] Toluene [ ] m-xylene [ ] Ethylbenzene [ ] p-xylene [ ] S K-ME BTEX Mixture 2 S K-5ME 6 Analytes, each 2000 µg/ml in methanol; units:1x1 ml, 1x5 ml Benzene [ ] o-xylene [ ] Toluene [ ] m-xylene [ ] Ethylbenzene [ ] p-xylene [ ] S K-ME BTEX Mixture 3 S K-5ME 7 Analytes, each 2000 µg/ml in methanol; units:1x1 ml, 1x5 ml Benzene [ ] o-xylene [ ] Toluene [ ] m-xylene [ ] Ethylbenzene [ ] p-xylene [ ] MTBE [ ] 115

118 S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX I C7+C10+ C20+C40+BTEX in n-pentane Determination of ydrocarbon il in Water Index 10 Analytes, each 50 µg/ml in n-pentane; units: 1x1 ml, 1x5 ml, 1x10 ml Benzene B [ ] p-xylene p-x [ ] Toluene T [ ] n-eptane C7 [ ] Ethylbenzene E [ ] n-decane C10 [ ] o-xylene o-x [ ] n-eicosane C20 [ ] m-xylene m-x [ ] n-tetracontane C40 [ ] S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX II C7+C8+C9+C10+C20+C40+BTEX in n-pentane Determination of ydrocarbon il in Water Index 12 Analytes; each 50 µg/ml in n-pentane; units: 1x1 ml, 1x5 ml, 10x1 ml Benzene B [ ] Ethylbenzene E [ ] Toluene T [ ] n-nonane C9 [ ] o-xylene o-x [ ] n-decane C10 [ ] m-xylene m-x [ ] n-eicosane C20 [ ] p-xylene p-x [ ] n-tetracontane C40 [ ] n-eptane C7 [ ] n-ctane C8 [ ] S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX III C7+C8+C9+C10-C40 (all even)+btex in n-pentane Determination of ydrocarbon il in Water Index 25 Analytes, each 50 µg/ml in n-pentane; units: 1mL, 1x5mL, 10x1mL Benzene B [ ] n-ctadecane C18 [ ] Toluene T [ ] n-eicosane C20 [ ] Ethylbenzene E [ ] n-docosane C22 [ ] o-xylene o-x [ ] n-tetracosane C24 [ ] m-xylene m-x [ ] n-exacosane C26 [ ] p-xylene p-x [ ] n-ctacosane C28 [ ] n-eptane C7 [ ] n-triacontane C30 [ ] n-ctane C8 [ ] n-dotriacontane C32 [ ] n-nonane C9 [ ] n-tetratriacontane C34 [ ] n-decane C10 [ ] n-exatriacontane C36 [ ] n-dodecane C12 [ ] n-ctatriacontane C38 [ ] n-tetradecane C14 [ ] n-tetracontane C40 [ ] n-exadecane C16 [ ] F-BTEX Internal Standards The concept of F-PA is now introduced by Chiron as a complete range of fluorinated internal standards for GC-MS analysis of the BTEX range compounds. 116

119 S K-ME S K-4ME S K-10ME F-BTEX ISTD Mixture 4 Analytes, each 2000 µg/ml in methanol; units: 1x4.5mL, 1x10mL Fluorobenzene [ ] Fluorotoluene [ ] Ethyl-4-fluorobenzene [ ] Fluoro-o-xylene (2,3-Dimethylfluorobenzene) [ ] Gasoline S K-ME GR Mixture 1 S K-5ME 9 Analytes, each 2000 µg/ml in methanol; units:1x1ml, 1x5 ml S K-ME S K-5ME Benzene [ ] Naphthalene [ ] Toluene [ ] Methylpentane [ ] Ethylbenzene [ ] ,2,4-Trimethylbenzene [ ] o-xylene [ ] ,3,5-Trimethylbenzene [ ] m-xylene [ ] GR Mixture 2, PVC 8 Analytes, each 2000 µg/ml in methanol; units:1x1ml, 1x5 ml Environmental Benzene [ ] m-xylene [ ] Toluene [ ] MTBE [ ] Ethylbenzene [ ] ,2,4-Trimethylbenzene [ ] o-xylene [ ] ,3,5-Trimethylbenzene [ ] S-4222-ASS-ME S-4222-ASS-5ME GR Mixture 3, EP Gasoline Range 9 Analytes, each concentration as listed in methanol; units: 1x1 ml, 1x5 ml Benzene [ ] 500 µg/ml Toluene [ ] 1500 µg/ml Ethylbenzene [ ] 1500 µg/ml m-xylene [ ] 1000 µg/ml ,2,4-Trimethylbenzene [ ] 1000 µg/ml eptane [ ] 500 µg/ml Methylpentane [ ] 1500 µg/ml ,2,4-Trimethylpentane [ ] 1500 µg/ml o-xylene [ ] 1000 µg/ml S-4223-K-ME S-4223-K-5ME GR Mixture 4, UST Modified Gasoline Range 10 Analytes, each 1000 µg/ml in methanol; units: 1x1 ml, 1x5 ml Benzene [ ] p-xylene [ ] Toluene [ ] ,2,4-Trimethylbenzene [ ] Ethylbenzene [ ] ,3,5-Trimethylbenzene [ ] o-xylene [ ] MTBE [ ] m-xylene [ ] Naphthalene [ ] 117

120 K-ME Internal Standards for Gasoline Range Analysis: 1-Chloro-4-fluorobenzene, 5000 µg/ml in methanol; units: 1x1 ml, 5x1 ml K-ME Calibration (Surrogate) Standard ααα-trifluorotoluene, µg/ml in methanol; units: 1x1 ml, 5x1 ml Diesel S-4226-K-X DR Mixture 1, UST Modified Diesel Range 10 Analytes, each 1000 µg/ml in hexane; unit: 1x1 ml n-decane [ ] n-eicosane [ ] n-dodecane [ ] n-docosane [ ] n-tetradecane [ ] n-tetracosane [ ] n-exadecane [ ] n-exacosane [ ] n-ctadecane [ ] n-ctacosane [ ] For other hydrocarbon mixtures see the PINA section, page 180 and onward. Internal standards for Diesel Range Analysis K-X 5-α-Androstane 2000 µg/ml in hexane, 1 ml K-DC 1-Chlorooctadecane µg/ml in dichloromethane, 1 ml Calibration (Surrogate) Standards for Diesel Range Analysis K-DC 2-Fluorobiphenyl µg/ml in dichloromethane K-AC o-terphenyl 2000 µg/ml in acetone K-DC o-terphenyl µg/ml in dichloromethane 118

121 Surfactants Surfactants like nonylphenol ethoxylates (NPE), phthalates, adipates and linear alkylbenzene sulfonates (LAS) are common waste water pollutants. Recently perfluorinated carboxylic acids are recognized as potential environmental hazards due to the severe functions and persistency of these compounds. Chiron now offers standards for perfluorinated carboxylic compounds. Alkylphenol ethoxylates C 9 (C 2 C 2 ) n ctyl- and nonylphenol ethoxylates are widely used as surfactants in soap. Due to their potential endocrine disruptive behavior, these compounds are now banned or restricted in several countries. A range of new ethoxylated nonylphenol isomers, pure isomer-mixtures and single n-nonyl derivatives for use as calibration standards, are now available, only from Chiron. These standards are useful as external calibration standards for GC and GC-MS analysis of waste water and waste water sludges. Internal standards I 4-n-ctylphenol-d17 100µg/mL isooctane 1mL K-5IP 4-n-Nonylphenol-2,3,5,6-d4-D [ ] 1000µg/mL isopropanol 5x5mL K-5AC 4-n-Nonylphenol-2,3,5,6-d4-D [ ] 1000µg/mL acetone 5x5mL Environmental Deuterated and 13 C labelled alkylethoxylates: Please inquire Native standards 4-n-ctylphenol ethoxylates K-I 4-n-ctylphenol [ ] 1000µg/mL isooctane 1mL K-I 4-n-ctylphenol E [ ] 1000µg/mL isooctane 1mL K-I 4-n-ctylphenol 2E [ ] 1000µg/mL isooctane 1mL K-I 4-n-ctylphenol 3E [ ] 1000µg/mL isooctane 1mL K-I 4-n-ctylphenol 4E [ ] 1000µg/mL isooctane 1mL KIT n-ctylphenol E Kit (Not including ) Kit 4-tert-ctylphenol ethoxylates K-I 4-tert-ctylphenol [ ] 1000µg/mL isooctane 1mL K-I 4-tert-ctylphenol E, Please inquire [ ] 1000µg/mL isooctane 1mL K-I 4-tert-ctylphenol 2E, Please inquire [ ] 1000µg/mL isooctane 1mL K-I 4-tert-ctylphenol 3E, Please inquire [ ] 1000µg/mL isooctane 1mL Nonylphenol ethoxylates (nonylisomer mixtures) K-I 4-Nonylphenol, mixture of nonyl isomers [ ] 1000µg/mL isooctane 1mL K-I p-nonylphenol E [ ] 1000µg/mL isooctane 1mL K-I p-nonylphenol 2E [ ] 1000µg/mL isooctane 1mL K-I p-nonylphenol 3E [ ] 1000µg/mL Isooctane 1mL K-I p-nonylphenol 4-E [ ] 1000µg/mL Isooctane 1mL KIT Nonylphenol E Kit (5 compounds) Kit 4-n-Nonylphenol ethoxylates K-I 4-n-Nonylphenol [ ] 1000µg/mL isooctane 1mL K-I p-n-nonylphenol E 1000µg/mL Isooctane 1mL K-I p-n-nonylphenol 2E [ ] 1000µg/mL Isooctane 1mL KIT n-nonylphenol ethoxylates Kit Kit 119

122 Metabolites K-I 2-(4-Nonylphenoxy) acetic acid isomer mixture [ ] 1000µg/mL Isooctane 1mL Commercial mixes S MG Imbentin-N/020 (n=0-4) neat 100mg S MG Imbentin-N/040 (n=1-7) neat 100mg S MG Imbentin-N/040 (n=2-9) neat 100mg KIT Imbentin Kit (3 samples) Kit Special mixes Please inquire 120 Phthalates and adipates Chiron offers to prepare mixed solutions of a large number of phthalate and adipate esters. Choose from the compounds listed below. Please inquire if you do not find the compound you need. Phthalates Internal standards I Dimethyl phthalate-3,4,5,6-d4 [ ] 100µg/mL isooctane 1mL K-I Diethyl phthalate-3,4,5,6-d4 [ ] 1000µg/mL isooctane 1mL I Di-n-butyl phthalate-3,4,5,6-d4 [ ] 100µg/mL isooctane 1mL I Di-n-pentyl phthalate-3,4,5,6-d4 [ ] 100µg/mL isooctane 1mL K-I Di-n-pentyl phthalate-3,4,5,6-d4 [ ] 1000µg/mL isooctane 1mL I Benzyl-n-butyl phthalate-3,4,5,6-d4 [ ] 100µg/mL isooctane 1mL I Di-n-octyl phthalate-3,4,5,6-d4 [ ] 100µg/mL isooctane 1mL K-I Bis(2-ethylhexyl) phthalate-3,4,5,6-d4 [ ] 1000µg/mL isooctane 1mL Native standards MG Dimethyl phthalate [ ] neat 10mg MG Diethyl phthalate [ ] neat 10mg MG Di-iso-butyl phthalate [ ] neat 10mg MG Di-n-butyl phthalate [ ] neat 10mg MG Bis(2-methoxyethyl) phthalate [ ] neat 10mg MG Di-n-pentyl phthalate Diamyl phthalate [ ] neat 10mg MG Bis(2-ethoxyethyl) phthalate [ ] neat 10mg MG Butylbenzyl phthalate [ ] neat 10mg X Diphenyl isophthalate [ ] 100µg/mL hexane 1mL X Diphenyl phthalate [ ] 100µg/mL hexane 1mL MG Dicyclohexyl phthalate [ ] neat 10mg MG Bis(4-methyl-2-pentyl) phthalate [ ] neat 10mg MG Di-n-hexyl phthalate [ ] neat 10mg X Dibenzyl phthalate [ ] 100µg/mL hexane 1mL MG exyl 2-ethylhexyl phthalate [ ] neat 10mg MG Bis(2-n-butoxyethyl) phthalate [ ] neat 10mg MG Bis(2-ethylhexyl)phthalate [ ] neat 10mg MG Di-n-octyl phthalate [ ] neat 10mg MG Di-iso-nonyl phthalate (isomer mixture) [ ] neat 10mg MG Di-n-nonyl phthalate [ ] neat 10mg MG Di-iso-decyl phthalate [ ] neat 10mg KIT-MX Mono+Diphthalate Kit Kit

123 Metabolites (phthalate biomarkers) It has been shown that dialkylphthalates are metabolized in the body to endocrine-active monoalkylphthalates. Ref: Stahlhet et.al., Environ. ealth Prospect. Doi: /ehp ( March K-I Monomethyl phthalate [ ] 1000µg/mL isooctane 1mL K-I Monoethyl phthalate [ ] Please inquire K-I Mono-n-butyl phthalate [ ] 1000µg/mL isooctane 1mL K-I Mono-n-hexyl phthalate [ ] 1000µg/mL isooctane 1mL K-I Monobenzyl phthalate [ ] 1000µg/mL isooctane 1mL K-I Mono(2-ethylhexyl) phthalate [ ] 1000µg/mL isooctane 1mL Adipates CR CR Internal standard K-I Bis(2-ethylhexyl) adipate-d8 1000µg/mL isooctane 1mL Native adipates MG Bis(2-ethylhexyl) adipate BEA [ ] neat 10mg K-I Di-n-octyl adipate [ ] 1000µg/mL isooctane 1mL K-I Di-iso-octyl adipate [ ] 1000µg/mL isooctane 1mL K-I Di-n-nonyl adipate [ ] 1000µg/mL isooctane 1mL K-I Di-iso-nonyl adipate [ ] 1000µg/mL isooctane 1mL KIT Adipate Kit Kit Environmental Phtalate and adipate mixes S-4002-K-I Surfactants Mixture 1 S-4002-K-10I 7 Analytes, each 1000µg/mL in isooctane; units: 10x1 ml, 1x10 ml Diethyl phthalate DEP [ ] Bis(2-ethylhexyl) adipate BEA [ ] Di-n-octyl phthalate DNP [ ] Benzyl butyl phthalate BBP [ ] Bis(2-ethylhexyl) phthalate BEP [ ] Diisononyl phthalate DINP [ ] Di-n-butyl phthalate DBP [ ] S T Surfactant Mixture 2 2 Analytes, each 100µg/mL in toluene; unit: 1x5 ml Bis(2-ethylhexyl) phthalate BEP [ ] Di-n-octyl phthalate DNP [ ] 121

124 LAS (linear alkylbenzene sulfonates) and ABS (alkylbenzenesulfonates) C 3 (C 2 ) n S 3 Na, Ca Linear alkylsulfonates (LAS or linear alkylbenzenesulfonates) are man-made surface active agents. LAS are produced with the benzenesulfonate group at the end or in the chain, and it gives rice to different chemical properties. Commercial mixtures typically have an alkyl chain of C10-C14. LAS is often referred to as soft type alkyl benzenesulfonates. LAS are biodegradable due to its linear alkyl chain. Alkyl benzenesulfonates (ABS or branched alkyl benzenesulfonates) have a branched alkyl chain and are not easily biodegraded. ABS are often referred to as a hard type alkylbenzenesulfonate. ABS are essentially replaced by LAS on the surfactant market. LAS and ABS standards ME Sodium p-n-octylbenzenesulfonate [ ] 100µg/mL methanol 1mL ME Sodium p-n-decylbenzenesulfonate [ ] 100µg/mL methanol 1mL ME Sodium p-n-undecylbenzenesulfonate [ ] 100µg/mL methanol 1mL ME Calcium p-n-dodecylbenzenesulfonate [ ] 100µg/mL methanol 1mL ME Sodium p-n-dodecylbenzenesulfonate [ ] 100µg/mL methanol 1mL K-ME Sodium p-n-dodecylbenzenesulfonate [ ] 1000µg/mL methanol 1mL ME Sodium p-n-tridecylbenzenesulfonate [ ] 100µg/mL methanol 1mL K-ME Sodium p-n-tridecylbenzenesulfonate [ ] 1000µg/mL methanol 1mL ME Sodium p-n-tridecylbenzenesulfonate [ ] 100µg/mL methanol 1mL ME Sodium p-n-tetradecylbenzenesulfonate [ ] 100µg/mL methanol 1mL KIT LAS Kit Kit Commercial technical mixes K-ME Dodecylbenzenesulfonic acid, mixture of C12 LAS 12, soft [ ] 1000µg/mL methanol 1mL MG Dodecylbenzenesulfonic acid, mixture of C12 LAS 12, soft [ ] neat 100mg K-ME Sodium dodecylbenzenesulfonate, mixture of C10-C14 ABS Na, ard [ ] 1000µg/mL methanol 1mL MG Sodium dodecylbenzenesulfonate, mixture of C10-C14 ABS Na, ard [ ] neat 100mg K-ME Sodium dodecylbenzenesulfonate, mixture of C10-C14 LAS 10-14, Soft [ ] 1000µg/mL methanol 1mL MG Sodium dodecylbenzenesulfonate, mixture of C10-C14 LAS 10-14, Soft [ ] neat 100mg MG Sodium dodecylbenzenesulfonate, mixture of C10-C14, 38% water LAS 10-14, Soft [ ] neat 100mg International methods (see the Methods section for details) EPA 506 Rev 1.1, page 87. EPA 606, page 93. EPA 8061 A, page

125 Linear perfluoroalkyl sulfonates acids and alcohols PFAs Perfluorooctane sulfonate (PFS) and related perfluorinated compounds, e.g. perfluorohexane sulfonate (PFS), perfluorobutane sulfonate (PFBS), perfluorooctane sulfonamide (FSA) and perfluorooctanoic acid (PFA) have received wide attention during the last three years. The extraordinary strength of the carbon-fluorine bond contributes to the stability of the fluorochemicals. These compounds repel water and oil. PFS etc. also reduce the surface tension for materials such as coatings for textiles, papers, packaging, fire-fighting foams, herbicides and pesticides. F F F F F F F F F F F F F PFS F F F F F F F S 3 F F F F F F F F F F F F F F F F PFA F F F F F F F C F F F F Environmental F F F F F F F S 3 F F F F F F F F S 2 N 2 PFS FSA F F F F F F F F F S 3 F F F F F F F F F F F F F PFBS 6:2 PT Internal standards Internal standards based on deuterium/ 13 C isotope labelling and other cost-efficient standards are under development and will be available. Native standards (for details, see the Compounds section page 383) Chiron offer a large range of standards for all groups of commercial perfluoro alkane derivatives. Metabolites These compounds are extremely stable and degrade very slowly. owever, the current switch to telomeric acids has given rice to studies on the degradation of these substances. Several telomers are available and telomeric metabolites are in development, including internal standards. 123

126 Phenols and phenol analysis Phenols are widely used in the industry as additives as well as intermediates. Alkylphenols are commonly used as surfactants, oil additives, antioxidants, herbicides, insecticides, polymers and polymerization reagents, vitamins etc. Ethoxylated nonylphenols are used as surfactants in detergents. Alkylphenols also occur as by-products of various industrial uses, i. e. pulp and paper processing, coke production and gas liquification. Chlorophenols are formed by the use of chlorine as a bactericide in water treatment plants. Chlorophenols are also added to enhance the anti-bacterial properties of products. owever, due to an increased lipophilicity, the chlorophenols tend to bioaccumulate. This increases the toxicity, and these compounds are thus banned in certain countries. Alkylated derivatives of the nitrophenols are commonly used as herbicides and pesticides. These substances tend to be more toxic than those without the nitrofunction. Toxic and environmental hazards Phenols are toxic compounds. They are easily absorbed via the skin, by inhalation or by ingestion. Being soluble in both polar and non-polar solvents they are highly mobile in soil and in aquatic systems and are suspected endocrine disruptors. Nonylphenol ethoxylates are listed as priority pollutants in water by the EU Commission. The large quantities of detergents used in households, industries and agricultural applications constitute a major issue of concern. Nonionic phenolic surfactants are quite resistant to biodegradation due to the branched carbon alkyl chain, and their metabolites may reach the surface and groundwater. These compounds are commonly found in the waste water and the sludge from waste water treatment plants. Phenolic compounds are extensively used both in the onshore as well as the offshore petroleum industry, and are a hazard of contamination of fresh water and the sea. It is estimated that phenols up to alkyl-c5 contributes with approximately 5 % of the total environmental risk in offshore-operated fields. As a consequence, a number of methods have been developed to test for the content of phenols in drinking water, from water treatment plants, in soil and as industrial waste in onshore as well as off-shore activities. Methods of analysis Low molecular weight phenols are often analyzed by GC-FID, GC-ECD or GC-MS methods, using columns like DB-XLB and DB-5ms columns from Agilent, or similar types. Phenols Derivatization Phenols are often derivatized before determination, and analyzed as pentafluorobenzoyl- (PFB), TMS-ether, or methyl derivatives. In MS the PFB compound will have a molecular ion of m/z 194 units higher than that of the parent compound. F F R + F CCl F F F F R F F F Derivatization by PFBCl before analysis by GC-ECD or GC-MS. 124

127 Derivatizing agent Perfluorobenzoyl chloride 1 g Internal standards Fluorophenol [ ] 1 g Fluoro-3-methylphenol [ ] 1 g Fluoro-2-methylphenol [ ] 1 g ,4,6-Tribromophenol [ ] 1 g ,4-Dibromophenol [ ] 1 g d4-4-ethylphenol [ ] 100 mg Internal standard PFB-derivatives Fluorophenol-PFB 1000µg/mL in isopropanol Fluoro-3-methylphenol-PFB 1000µg/mL in isopropanol Fluoro-2-methylphenol-PFB 1000µg/mL in isopropanol ,4,6-Tribromophenol-PFB [ ] 1000µg/mL in isopropanol ,4-Dibromophenol-PFB [ ] 1000µg/mL in isopropanol d4-4-ethylphenol-pfb [ ] 1000µg/mL in isopropanol Environmental F F F Br F F F Br F F F Br F F D D F D D Please inquire for individual PFB derivatives of additional analytes. F F F F Internal standards Chiron is offering a wide range of nearly fluoro- and deuterated alkylphenols as pure internal standards. See the Compounds section for available internal standards, page 374. Alkylated phenols Chiron is offering a range of nearly 50 alkylphenols and deuterated alkylphenols as pure chemical standards. See the Compounds section for available alkylphenols, page 375. Alkylphenol mixes S-4060-ASS-5AC Alkylated phenol mixture 1 8 Analytes, each concentration as listet in aceton; unit: 1x5 ml p-cresol [ ] mg/ml Ethylphenol [ ] 6.54 mg/ml ,5-Dimethylphenol [ ] 6.54 mg/ml ,4,6-Trimethylphenol [ ] 3.80 mg/ml tert-Butylphenol [ ] 0.37 mg/ml 125

128 tert-Butylphenol [ ] 0.37 mg/ml n-Butylphenol [ ] 0.37 mg/ml Pentylphenol [ ] 1.62 mg/ml S K-I Alkylated phenol mixture 2 29 Analytes, each 5000µg/mL in isooctane, pestipure; units: 1x1 ml, 5x1 ml Prod.no. Compound Purity CAS no Phenol 99.9 % [ ] o-cresol 99.6 % [ ] m-cresol 98.1 % [ ] p-cresol 99.1 % [ ] ,4-Dimethylphenol 99.8 % [ ] ,5-Dimethylphenol >99 % [ ] ,5-Dimethylphenol 99.9 % [ ] Ethylphenol 99.2 % [ ] n-Propylphenol 99.7 % [ ] ,3,5-Trimethylphenol 98+% [ ] n-Propylphenol 98.4 % [ ] ,4,6-Trimethylphenol 99.9 % [ ] tert-Butylphenol 99.5 % [ ] Isopropyl-3-methylphenol 99.8 % [ ] n-Butylphenol 98.0 % [ ] tert-Butyl-4-methylphenol 99.2 % [ ] tert-Butyl-2-methylphenol 98.2 % [ ] n-Pentylphenol 98 % [ ] ,5-Diisopropylphenol 83.9 % [ ] ,6-Diisopropylphenol 99.9 % [ ] tert-Butyl-4-ethylphenol 99.2 % [ ] tert-Butyl-2,4-dimethylphenol (2-tert-Butyl-4,6-dimethylphenol) 99.3 % [ ] n-eptylphenol 99.9 % [ ] tert-ctylphenol 96.5 % [ ] ,6-Di-tert-butylphenol 99.7 % [ ] n-ctylphenol 99.2 % [ ] ,6-Di-tert-butyl-4-methylphenol 99.9 % [ ] n-Nonylphenol 99.3 % [ ] Methyl-4-tert-octylphenol 94.3 % [ ] S I Alkylated phenol mixture 3 31 Analytes, each 100µg/mL in isooctane, pestipure; units: 1x1 ml, 5x1mL Prod.no. Compound Purity CAS no Phenol 99.9 % [ ] o-cresol 99.6 % [ ] m-cresol 98.1 % [ ] p-cresol 99.1 % [ ] ,4-Dimethylphenol 99.8 % [ ] ,5-Dimethylphenol >99 % [ ] ,5-Dimethylphenol 99.9 % [ ] Ethylphenol 99.2 % [ ] n-Propylphenol 99.7 % [ ] ,3,5-Trimethylphenol 98+% [ ] 126

129 n-Propylphenol 98.4 % [ ] ,4,6-Trimethylphenol 99.9 % [ ] tert-Butylphenol 99.5 % [ ] Isopropyl-3-methylphenol 99.8 % [ ] n-Butylphenol 98.0 % [ ] tert-Butyl-4-methylphenol 99.2 % [ ] tert-Butyl-2-methylphenol 98.2 % [ ] n-Pentylphenol 98 % [ ] ,5-Diisopropylphenol 83.9 % [ ] ,6-Diisopropylphenol 99.9 % [ ] tert-Butyl-4-ethylphenol 99.2 % [ ] tert-Butyl-2,4-dimethylphenol (2-tert-Butyl-4,6-dimethylphenol) 99.3 % [ ] n-eptylphenol 99.9 % [ ] tert-ctylphenol 96.5 % [ ] ,6-Di-tert-butylphenol 99.7 % [ ] n-ctylphenol 99.2 % [ ] ,4-Di-sec-butylphenol 92.7 % [ ] ,6-Di-tert-butyl-4-methylphenol 99.9 % [ ] n-Nonylphenol 99.3 % [ ] ,6-Di-tert-butyl-2-methylphenol 99.9 % [ ] Methyl-4-tert-octylphenol 94.3 % [ ] Environmental S I Alkylated Phenol mixture 4 3 Analytes, each 100 µg/ml in isooctane; unit: 1x5mL Prod.no. Compound CAS no. 1437,12 4-n-exylphenol [ ] 1442,14 2,4-Di-tert-butylphenol [ ] 1443,14 2,6-Di-tert-butylphenol [ ] S-4440-ASS-5I Alkylated phenol mixture 5 18 Analytes, each concentration as listet in isooctane; unit: 1x5mL Prod.no. Compound CAS no. Concentration Phenol [ ] 5000µg/mL m-cresol [ ] 2000µg/mL Ethylphenol [ ] 200µg/mL ,4-Dimethylphenol [ ] 200µg/mL ,3,6-Trimethylphenol [ ] 200µg/mL n-Propylphenol [ ] 200µg/mL sec-Butylphenol [ ] 200µg/mL n-Butylphenol [ ] 200µg/mL tert-Butyl-4-methylphenol [ ] 200µg/mL n-Pentylphenol [ ] 200µg/mL n-exylphenol [ ] 200µg/mL tert-Butyl-4-ethylphenol [ ] 200µg/mL Cyclohexyl-5-methylphenol [ ] 200µg/mL n-eptylphenol [ ] 200µg/mL n-ctylphenol [ ] 200µg/mL Di-sec-butylphenol, mixture of isomers [ ] 200µg/mL n-Nonylphenol [ ] 200µg/mL ,6-Di-tert-butyl-4-methylphenol [ ] 200µg/mL 127

130 S-4411-ASS-IP Deuterated alkylphenol mixture 6 Analytes, each concentration in isopropanol; unit: 1x1mL Product description: Prod.no. Compound CAS no. Concentration 2280,7 p-cresol-d8 [ ] 3000 µg/g 2399,8 3,5-Dimethylphenol-2,4,6-d3, D µg/g 2348,9 4-n-Propylphenol-d12 [ ] 2000 µg/g 2282,10 4-tert-Butyl-d9-phenol-2,3,5,6-d4 [ ] 1000 µg/g 2410,11 4-n-Pentyl-d11-phenol µg/g 2327,14 4-n-ctylphenol-d µg/g Chloro- and nitrophenol standards Custom solutions are available from these chloro- and nitrophenolic compounds: Chlorophenol [ ] Chloro-5-methylphenol [ ] ,4-Dichlorophenol [ ] ,5-Dichlorophenol [ ] ,3-Dichlorophenol [ ] Chlorophenol [ ] Chlorophenol [ ] ,6-Dichlorophenol [ ] Chloro-2-methylphenol [ ] Chloro-3-methylphenol [ ] ,3,6-Trichlorophenol [ ] ,3,5-Trichlorophenol [ ] ,3,5,6-Tetrachlorophenol [ ] ,4,5-Trichlorophenol [ ] ,4,6-Trichlorophenol [ ] ,3,4-Trichlorophenol [ ] ,5-Dichlorophenol [ ] ,4-Dichlorophenol [ ] ,3,4,5-Tetrachlorophenol [ ] ,4,5-Trichlorophenol [ ] Pentachlorophenol [ ] Nitrophenol [ ] Nitrophenol [ ] Nitrophenol [ ] ,4-Dinitrophenol [ ] Methyl-4,6-Dinitrophenol [ ] International methods Please consult the Methods section for details. - EPA 528 Rev. 1.0 Phenols in Drinking Water by Solid Phase Extraction and GC-MS, page EPA 8041 A Phenols as PFB Derivatives by GC-ECD or FID, page EPA 604 Phenols by GC-FID and Phenols as PFB Derivatives (GC-ECD), page

131 PA analysis and PA mixtures Polycyclic aromatic hydrocarbons (PAs) and especially the sixteen ones chosen by the EPA as priority pollutants, the so-called EPA-PAs, are analytes that have to be determined very frequently in environmental and food analysis, occupational monitoring and in toxicological studies. The PAs are known to possess highly carcinogenic and mutagenic properties. The toxic effects are related to benzo[a]pyrene which is set to a basis of 1.0. Large variations in the group of PAs are observed. The toxicity is often related to structural patterns, so called QSARs, e.g. in the bay and the fjord regions. The carcinogenic impact can be put down to the metabolites of the corresponding parent PAs. The metabolites are more water soluble, and are formed by epoxidation, hydroxylation, glucuronidation or sulfatation. The initial step is the activation via the Cyt. P450 system. TXICITY F PA-CMPUNDS RELATIVE T BENZ[A]PYRENE Genotoxicity Cancerogen. Ref.1 Ref.2 Ref.3 Ref.4-6 Ref. 8 (Ref 7) (Ref 7) Dibenzo[a,l]pyrene (+) + Dibenzo[a,h]pyrene (+) + Benzo[a]pyrene Dibenzo[a,e]fluoranthene 1.0 Dibenzo[a,e]pyrene Dibenz[a,h]anthracene Anthanthrene Dibenz[a,i]pyrene Benzo[b]fluoranthene Indeno[1,2,3-cd]pyrene Benzo[j]fluoranthene Benz[k]fluoranthene Benz[a]anthracene Dibenz[a,c]anthracene 0.1 Cyclopenta[cd]pyrene Chrysene Methylchrysene + + Benzo[c]phenanthrene (+) + Benzo[e]pyrene (?) Benzo[ghi]perylene Triphenylene + - Acenaphthylene (?) no studies Fluoranthene (?) 1-Methylphenanthrene Coronene (+) (?) Perylene Benzo[ghi]fluoranthene (+) (-) Naphthalene ? Anthracene Acenaphthene (?) (?) Fluorene Phenanthrene (?) (?) Pyrene (?) - Benzo[a]fluorine (?) (?) Benzo[b]fluorine (?) (?) Environmental 129

132 A.. Malcolm and S. Dobson, Department of te Environment, Report No. DoE/MIP/RR/94/041 (1994). F. Kalberlah, N. Frijus-Plessen and M. assauer, Altlasten-Spektrum, 5, pp (1995). P. McClure and R. Scheny, Fifteenth International Symposium on Polycyclic Aromatic Compounds, Belgirate, Italy, Sept 1995, p P. Müller, B. Leece and D. Raha, Fifteenth International Symposium on Polycyclic Aromatic Compounds, Belgirate, Italy, Sept 1995, p P. Müller, B. Leece and D. Raha, Dose Respons Assessment PA. ttawa, ntario Ministry of the Environment and Energy, p. 197 (1995). P. Müller, B. Leece and D. Raha, Scentific Criteria Document for Multimedia Environmetal Standards Development: Polycyclic Aromatic ydrocarbons (PA) Dose Respons Assessment PA. ttawa, ntario Ministry of the Environment and Energy, p. 203 (1996). IPCS (International Programme on Chemical Safety), Environmental ealth Criteria 202, W (1998). US Environmental Protection Agency, Provisional Guidance for Quantitative Risk Assessment of Polycyclic ydrocarbons. EPA/600/R-93/089 (1993). Internal standards F-PAs internal standards Monofluorinated PAs (F-PAs ) are closely similar to the parent PAs in terms of chemical and physical properties. The close similarities between the F-PA and the parent PAs makes them ideal internal standards in a broad range of analytic and mechanistic applications and studies. With the introduction of the mono F-PA standards, Chiron has set a new benchmark in PA-analysis: - Improved and more efficient results - Cheaper than isotopically labelled counterparts, deuterium and 13 C - F-PAs are separated from the parent PA by GC and PLC - F-PAs are easy to detect by MS and UV/Fluorescence - Additional detection information with AED, NMR and MS techniques - There is no scrambling, like sometimes observed with deuterium - There is no known occurrence in nature, like methylated analogous Single components F-PAs (1, 5 or 10x1mL) I 1-Fluoronaphthalene [ ] 10µg/mL isooctane I 1-Fluoronaphthalene [ ] 100µg/mL isooctane T 5-Fluoroacenaphthylene [ ] 10µg/mL toluene T 5-Fluoroacenaphthylene [ ] 100µg/mL toluene I 2-Fluoro-6-methylnaphthalene [ ] 100µg/mL isooctane T 2-Fluorofluorene [ ] 10µg/mL toluene T 2-Fluorofluorene [ ] 100µg/mL toluene T 3-Fluorophenanthrene [ ] 10µg/mL toluene T 2-Fluorophenanthrene [ ] 10µg/mL toluene T 3-Fluorophenanthrene [ ] 100µg/mL toluene T 2-Fluorophenanthrene [ ] 100µg/mL toluene I 3-Fluoro-6-methylphenanthrene [ ] 50µg/mL isooctane T 3-Fluorofluoranthene [ ] 10µg/mL toluene T 3-Fluorofluoranthene [ ] 100µg/mL toluene T 1-Fluoropyrene [ ] 10µg/mL toluene T 1-Fluoropyrene [ ] 100µg/mL toluene T 1-Fluorochrysene 10µg/mL toluene T 1-Fluorochrysene 100µg/mL toluene T 3-Fluorochrysene [ ] 10µg/mL toluene 130

133 T 3-Fluorochrysene [ ] 100µg/mL toluene I 9-Fluoro-5-methylchrysene [ ] 50µg/mL isooctane T 9-Fluorobenzo[k]fluoranthene [ ] 10µg/mL toluene T 9-Fluorobenzo[k]fluoranthene [ ] 100µg/mL toluene Single components deuterated PAs (neat or 1, 5 or 10x1mL for solutions) K-I Naphthalene-d8 [ ] 1000µg/mL isooctane K-T Naphthalene-d8 [ ] 1000µg/mL toluene MG Naphthalene-d8 [ ] neat 10mg K-I 1-Methylnaphthalene-d10 [ ] 1000µg/mL isooctane K-I 2-Methylnaphthalene-d10 [ ] 1000µg/mL isooctane K-I 1,8-Dimethylnaphthalene-d12 [ ] 1000µg/mL isooctane K-I 2,6-Dimethylnaphthalene-d12 [ ] 1000µg/mL isooctane K-T Acenaphthylene-d8 [ ] 1000µg/mL toluene MG Acenaphthylene-d8 [ ] neat 10 mg T Acenaphthene-d10 [ ] 100µg/mL toluene K-T Acenaphthene-d10 [ ] 1000µg/mL toluene MG Acenaphthene-d10 [ ] neat 10mg K-I Fluorene-d10 [ ] 1000µg/mL isooctane MG Fluorene-d10 [ ] neat 10mg K-T Phenanthrene-d10 [ ] 1000µg/mL toluene MG Phenanthrene-d10 [ ] neat 10mg K-T Anthracene-d10 [ ] 1000µg/mL toluene K-I 9-Methylanthracene-d12 [ ] 1000µg/mL isooctane MG Anthracene-d10 [ ] neat 10mg K-T Fluoranthene-d10 [ ] 1000µg/mL toluene MG Fluoranthene-d10 [ ] neat 10mg T Pyrene-d10 [ ] 100µg/mL toluene T Pyrene-d10 [ ] 200µg/mL toluene K-T Pyrene-d10 [ ] 1000µg/mL toluene MG Pyrene-d10 [ ] neat 10mg MG 1-Methylpyrene-d9 [ ] neat 10mg T 1-Methylpyrene-d9 [ ] 100µg/mL toluene T Chrysene-d12 [ ] 100µg/mL toluene T Chrysene-d12 [ ] 200µg/mL toluene K-T Chrysene-d12 [ ] 1000µg/mL toluene K-T Chrysene-d12 [ ] 2000µg/mL toluene MG Chrysene-d12 [ ] neat 10mg T Benz[a]anthracene-d12 [ ] 100µg/mL toluene K-T Benz[a]anthracene-d12 [ ] 1000µg/mL toluene MG Benz[a]anthracene-d12 [ ] neat 10mg K-T Triphenylene-d12 [ ] 1000µg/mL toluene K-T Triphenylene-d12 [ ] 1000µg/mL toluene T Benzo[a]pyrene-d12 [ ] 100µg/mL toluene K-T Benzo[a]pyrene-d12 [ ] 1000µg/mL toluene MG Benzo[a]pyrene-d12 [ ] neat 10mg T Benzo[e]pyrene-d12 [ ] 100µg/mL toluene T Benzo[b]fluoranthene-d12 [ ] 100µg/mL toluene MG Benzo[b]fluoranthene-d12 [ ] neat 10mg T Benzo[k]fluoranthene-d12 [ ] 100µg/mL toluene MG Benzo[k]fluoranthene-d12 [ ] neat 10mg K-T Perylene-d12 [ ] 1000µg/mL toluene MG Perylene-d12 [ ] neat neat Environmental 131

134 T Benzo[ghi]perylene-d12 [ ] 100µg/mL toluene T Benzo[ghi]perylene-d12 [ ] 200µg/mL toluene K-T Benzo[ghi]perylene-d12 [ ] 1000µg/mL toluene MG Benzo[ghi]perylene-d12 [ ] neat 10mg K-T Indeno[1,2,3-cd]pyrene-d12 [ ] 1000µg/mL toluene MG Indeno[1,2,3-cd]pyrene-d12 [ ] neat 10mg I Dibenz[a,h]anthracene-d14 [ ] 100µg/mL isooctane T Dibenz[a,h]anthracene-d14 [ ] 100µg/mL toluene T Dibenz[a,h]anthracene-d14 [ ] 200µg/mL toluene MG Dibenz[a,h]anthracene-d14 [ ] neat 10mg T Coronene-d12 [ ] 100µg/mL toluene K-T Coronene-d12 [ ] 1000µg/mL toluene T Dibenzo[a,i]pyrene-d14 [ ] 100µg/mL toluene K-T Dibenzo[a,i]pyrene-d14 [ ] 1000µg/mL toluene MG Dibenzo[a,i]pyrene-d14 [ ] neat 10mg K-T Biphenyl-d10 [ ] 1000µg/mL toluene MG Biphenyl-d10 [ ] neat 10mg Internal unlabelled standards for GC- and PLC-analysis of PA compounds Concentration: Neat or 1000 µg/ml, 1, 5, 10x1 ml n-exylbenzene [ ] in isooctane or 100mg neat (GC) ,3-Dimethylnaphthalene [ ] in isooctane or 100mg neat (GC) ,6-Dimethylphenanthrene [ ] in isooctane or 10mg neat (GC) ,2 -Binaphthyl [ ] in toluene or 10mg neat (GC) Anthracene [ ] in toluene or 100mg neat (GC) Methylbenzo[a]pyrene [ ] in toluene or 10mg neat (PLC) 132

135 Recommended internal standards Recommended internal standards for GC-MS analysis. The analytes are given in normal and the internal standards in bold letters. Window 1: MW MW Naphthalene Benzo[c]phenanthrene 228 Methylnaphthalene isomers Benz[a]anthracene Fluoronaphthalene Triphenylene Naphthalene-d Chrysene Fluoroflouranthene 220 Window 2: Fluoropyrene 220 Biphenyl Fluorochrysene ,6-Dimethylnaphthalene Pyrene-d Acenaphthylene Benz[a]anthracene-d Acenaphthene Fluoroacenaphthylene 170 Window 5: Fluorobiphenyl Benzo[b]fluoranthene Biphenyl-d Benzo[j]fluoranthene Benzo[k]fluoranthene 252 Window 3: Benzo[a]fluoranthene Fluorene Benzo[e]pyrene Phenanthrene Benzo[a]pyrene Anthracene Perylene Fluorophenanthrene Fluorobenzo[k]fluoranthene Phenanthrene-d Benzo[a]pyrene-d Environmental Window 4: Methylphenanthrene isomers 192 Window 6: Dimethylphenanthrene isomers Dibenz[a,j]anthracene Pentaphene Dibenz[a,h]anthracene Pyrene Dibenz[a,c]anthracene Fluoranthene 202 Benzochrysenes 278 Methylfluoranthene isomers Picene 278 Methylpyrene isomers Indeno[1,2,3-cd]pyrene Cyclopenta[cd]pyrene Benzo[ghi]perylene Benzo[ghi]fluoranthene Benzo[ghi]perylene-d Recommended all-in-one F-PAs cocktails for GC-MS applications S T F-PAs All in ne Cocktail 1, Window Analytes, each 200 µg/ml in toluene; units: 1x1 ml, 5x1 ml Compounds Window Fluoronaphthalene 1 [ ] Fluorobiphenyl 2 [ ] Fluorophenanthrene 3 [ ] Fluoropyrene 4 [ ] Fluorochrysene 4 [ ] 133

136 S-4103-ASS-T F-PAs All in ne Cocktail 2, Window Analytes, each consentration as listed in toluene; units: 1x1 ml, 5x1 ml Compounds Window Fluoronaphthalene 1 [ ] 200 µg/ml Fluorobiphenyl 2 [ ] 200 µg/ml Fluorophenanthrene 3 [ ] 200 µg/ml Fluoropyrene 4 [ ] 200 µg/ml Fluorochrysene 4 [ ] 200 µg/ml Fluorobenzo[k]fluoranthene 5 [ ] 100 µg/ml Recommended internal standards mixtures for GC-FID applications S DC Internal Standard for GC-analysis of PA compounds 4 Analytes, each 500 µg/ml in dichloromethane; unit:1x5 ml Phenylhexane [ ] ,3-Dimethylnaphthalene [ ] ,6-Dimethylphenanthrene [ ] ,2 -Binaphthyl [ ] All-in-one deuterated PAs cocktails for GC-MS Window 1-6: Perdeuterated Internal Standard - PA-Mixture 6 S T 7 Analytes, each 200 µg /ml in toluene; units: 1x1 ml, 1x5 ml S T Compounds Window Naphthalene-d8 1 [ ] Biphenyl-d10 2 [ ] Phenanthrene-d10 3 [ ] Pyrene-d10 4 [ ] Benz[a]anthracene-d12 5 [ ] Benzo[a]pyrene-d10 5 [ ] Benzo[ghi]perylene-d12 6 [ ] Window Perdeuterated Internal Standard - PA-Mixture 1 S K-T 4 Analytes, each 2000 µg/ml in toluene; units:1x1 ml, 1x5 ml S K-5T Compounds Window Naphthalene-d8 1 [ ] Biphenyl-d10 2 [ ] Phenanthrene-d10 3 [ ] Benzo[a]pyrene-d10 5 [ ] 134

137 Window Perdeuterated Internal Standard - PA-Mixture 7 S T 4 Analytes, each 2000 µg/ml in toluene; units:1x1 ml, 1x5 ml S T Compounds Window Naphthalene-d8 1 [ ] Biphenyl-d10 2 [ ] Phenanthrene-d10 3 [ ] Benzo[a]pyrene-d10 5 [ ] Window 1-5: Perdeuterated Internal Standard - PA-Mixture 8 S T 5 Analytes, each 2000 µg/ml in toluene; units:1x1 ml, 1x5 ml S T Compounds Window Naphthalene-d8 1 [ ] Biphenyl-d10 2 [ ] Phenanthrene-d10 3 [ ] Pyrene-d10 4 [ ] Benzo[a]pyrene-d10 5 [ ] See also page 142 for other deuterated PA-mixes. 16 EPA and 15 EU all-in-one deuterated standards Environmental S T Perdeuterated Internal standard - All-in-one 16 EPA priority PAs S T Perdeuterated Internal standard - All-in-one 15 EU priority PAs Native single PA-standards, metabolites and derivatives See the Compounds section, page 295 and onward. 135

138 International methods Priority PA's recommended by various authorities Chiron No. EPA*** W/ EAA NS 9815 Italy** MW EEC* Naphthalene x Acenaphtylene x Acenaphthene x Fluorene x Phenanthrene x x X Anthracene x x X Fluoranthene x x x X Pyrene x x X Benzo[a]fluorene x x Benzo[b]fluorene x x Benz[a]anthracene x x x x Chrysene x x x Triphenylene x Benzo[b]fluoranthene x x x x x Benzo[j]fluoranthene x Benzo[k]fluoranthene x x x x x Benzo[a]pyrene x x x x x Benzo[e]pyrene x x Dibenz[a,h]anthracene x x x x Benzo[ghi]perylene x x x x Indeno[1,2,3-cd]pyrene x x x x Dibenzo[a,e]pyrene x x x Dibenzo[a,h]pyrene x Dibenzo[a,i]pyrene x 302 Chiron No.: S S-4062 S-4113 S-4008 Request 4065 EPA W EEC EAA NS Italy The US Environmental Protection Agency Method 610 etc. World ealth rganisation European Economic Community European Aluminium Association Norwegian Standard Italian National Advisory Toxicological Com. for ealth Related Studies * Drinking water ** Air *** EPA-Methods: International PA-methods: ASTM D SFC-method ASTM D Gasoline ASTM D il spill ASTM D Aromatics in gasoline ASTM D Aviation fuels ASTM D Middle distillates IS :2005 Water quality six PAs by tlc IS :2005 Water quality sixpas by PLC IS 15753:2006 PA in Animal and vegetable fats and oils 136

139 IS 17993:2002 EPA EPA 527 EPA 610 EPA 8100 EPA 8260 EPA 8270C EPA 8310 Water quality 15 PAs by PLC Water rganics and PAs by GC Drinking water pesticides and PBDEs by GC/MS PA in wastewater by PLC and GC PAs in water by GC-FID Volatile Compounds by GC-MS Semivolatile Compounds by GC-MS Polycyclic Aromatic ydrocarbons in Ground water and wastes Reference PA cocktails according to international methods EPA-PAs Single components EPA-PAs Pack sizes for solutions: 1x1mL, 5x1mL, 10x1mL, and neat compound Naphthalene (99%) [ ] 1000 µg/ml 10mg Acenaphthylene (99%) [ ] 1000 µg/ml 10mg Acenaphthene (99%) [ ] 1000 µg/ml 10mg Fluorene (99%) [ ] 1000 µg/ml 10mg Phenanthrene (99%) [ ] 1000 µg/ml 10mg Anthracene (99%) [ ] 1000 µg/ml 10mg Fluoranthene (99%) [ ] 200 µg/ml* 10mg Pyrene (99%) [ ] 200 µg/ml* 10mg Benz[a]anthracene (99%) [ ] 200 µg/ml* 10mg Chrysene (99%) [ ] 200 µg/ml* 10mg Benzo[b]fluoranthene (99%) [ ] 200 µg/ml* 10mg Benzo[k]fluoranthene (99%) [ ] 200 µg/ml* 10mg Benzo[a]pyrene (99%) [ ] 200 µg/ml* 10mg Dibenz[a,h]anthracene (99%) [ ] 200 µg/ml* 10mg Benzo[ghi]perylene (99%) [ ] 200 µg/ml* 10mg Indeno[1,2,3-cd]pyrene (99%) [ ] 200 µg/ml* 10mg Environmental Single EPA-PA Kit Solutions Single EPA-PA Kit Neat, 10 mg each * Also available as 1000 µg/ml 137

140 The universal all-in-one 16 EPA-PA solutions from Chiron Designed for calibration of GC/GC-MS and PLC applications according to EPA metods 550.1/610/8100/8270C/8310 For other blends see page 136. Please inquire for custom blends EPA methods 550.1/610/8100/8270C/8310: S T 16 Priority PA, Cocktail µg of each/ml in toluene, 5 ml in screw cap bottle S CY 16 Priority PA, Cocktail 2 10 µg of each/ml in cyclohexane, 5 ml in screw cap bottle S AN 16 Priority PA, Cocktail 3 10 µg of each/ml in acetonitrile, 5 ml in screw cap bottle 15 EU PAs (2005/108 recommendation) 0201, T Benz[a]anthracene [ ] 200µg/mL 0212, T Chrysene [ ] 200µg/mL 0263, T Benzo[b]fluoranthene [ ] 200µg/mL 0264, T Benzo[j]fluoranthene [ ] 200µg/mL 0265, T Benzo[k]fluoranthene [ ] 200µg/mL 0239, T Benzo[a]pyrene [ ] 200µg/mL 0035, T Cyclopenta[cd]pyrene [ ] 200µg/mL 0203, T Dibenzo[a,h]anthracene [ ] 200µg/mL 0222, T Benzo[ghi]perylene [ ] 200µg/mL 0244, T Dibenzo[a,e]pyrene [ ] 200µg/mL 0242, T Dibenzo[a,h]pyrene [ ] 200µg/mL 0241, T Dibenzo[a,i]pyrene [ ] 200µg/mL 0243, T Dibenzo[a,l]pyrene [ ] 200µg/mL 0277, T Indeno[1,2,3-cd]pyrene [ ] 200µg/mL 0296, T 5-Methylchrysene [ ] 200µg/mL KIT Single 15 EU PA Kit The universal all-in-one 15 EU-PA solutions from Chiron S T 15 EU PA Cocktail 15 Analytes, 100µg/mL each in toluene, 1x1mL ampolle or 1x5mL screw cap bottle. 138

141 W/EU PA in drinking water (=IS and 2) S-4062-ASS-5AN 6 Priority PA in Acetonitrile - drinking water analysis (W/EU) 6 Analytes, each concentration as listed in acetonitrile; units: 1x5mL Fluoranthene [ ] 10 µg/ml Indenopyrene [ ] 2 µg/ml Benzo[b]fluoranthene [ ] 2 µg/ml Benzo[k]fluoranthene [ ] 2 µg/ml Benzo[a]pyrene [ ] 2 µg/ml Benzo[ghi]perylene [ ] 2 µg/ml ther PA mixes Native S-4001-K-T PA-Mixture A 13 Analytes, each 1000 µg/ml in toluene; units: 1x1 ml Environmental Bisphenol A [ ] Methylnaphthalene [ ] Methylnaphthalene [ ] Dibenzothiophene [ ] Methylphenanthrene [ ] ,6-Dimethylphenanthrene [ ] Benzo[a]fluorene [ ] Methylpyrene [ ] Triphenylene [ ] Benzo[e]pyrene [ ] Perylene [ ] ,3,5-Trimethylnaphthalene [ ] ,6-Dimethylnaphthalene [ ] S T PA Mixture D 7 Analytes, each 10 µg/ml in toluene; unit: 1x1.1 ml Prod.no. Compound CAS No. 0201,18 Benz[a]anthracene [ ] 0263,20 Benzo[b]fluoranthene [ ] 0264,20 Benzo[j]fluoranthene [ ] 0265,20 Benzo[k]fluroanthene [ ] 0277,22 Indeno[1,2,3-cd]pyrene [ ] 0203,22 Dibenz[a,h]anthracene [ ] 0239,20 Benzo[a]pyrene [ ] 139

142 S-4413-ASS-T PA Mixture E 25 Analytes, each concentration as listed in toluene; unit: 1x1 ml Prod.no. Compound CAS No. Conc. 0711,10 Naphthalene [ ] 50 µg/ml 0002,12 Acenaphthylene [ ] 200 µg/ml 0732,12 Acenaphthene [ ] 200 µg/ml 0217,13 Fluorene [ ] 200 µg/ml 0816,14 Phenanthrene [ ] 500 µg/ml 1049,14 Anthracene [ ] 500 µg/ml 0260,16 Fluoranthene [ ] 500 µg/ml 0235,16 Pyrene [ ] 500 µg/ml 0201,18 Benz[a]anthracene [ ] 500 µg/ml 0212,18 Chrysene [ ] 500 µg/ml 0263,20 Benzo[b]fluoranthene [ ] 500 µg/ml 0265,20 Benzo[k]fluoranthene [ ] 500 µg/ml 0239,20 Benzo[a]pyrene [ ] 500 µg/ml 0277,22 Indeno[1,2,3-cd]pyrene [ ] 500 µg/ml 0203,22 Dibenz[a,h]anthracene [ ] 500 µg/ml 0222,22 Benzo[ghi]perylene [ ] 500 µg/ml 0264,20 Benzo[j]fluoranthene [ ] 500 µg/ml 0256,22 Anthanthrene [ ] 500 µg/ml 0485,16 Benzo[b]naphtho[2,1-d]thiophene [ ] 500 µg/ml 0027,18 Benzo[c]phenanthrene [ ] 500 µg/ml 0035,18 Cyclopenta[cd]pyrene [ ] 500 µg/ml 0241,24 Dibenzo[a,l]pyrene [ ] 500 µg/ml 0036,20 Cholanthrene [ ] 500 µg/ml 0236,20 Benzo[e]pyrene [ ] 500 µg/ml 0226,24 Coronene [ ] 500 µg/ml S T PA Mixture G 7 Analytes, each 200µg/mL in toluene; unit: 1x1.1 ml Prod.no. Compound CAS.No Benzo[b]naphtho[2,1-d]thiophene [ ] Benzo[c]phenanthrene [ ] Cyclopenta[cd]pyrene [ ] Cholanthrene [ ] Benzo[e]pyrene [ ] Anthanthrene [ ] Dibenzo[a,i]pyrene [ ] S T S T PA Mixture 5 Analytes, each 100µg/mL in toluene; units: 1x1 ml, 1x5 ml Prod.no. Compound CAS.No Benzo[a]fluorene [ ] Benzo[b]fluorene [ ] Dibenzo[a,e]pyrene [ ] Dibenzo[a,h]pyrene [ ] Dibenzo[a,i]pyrene [ ] 140

143 S T PA Mixture I 7 Analytes, each 200µg/mL in toluene; units: 1x1.1mL Prod.no. Compound CAS.No Naphthalene [ ] Methylnaphthalene [ ] Methylnaphthalene [ ] Phenanthrene [ ] Fluroanthene [ ] Pyrene [ ] Benzo[a]pyrene [ ] Alkyl-PA S CY Methyl-PA Mixture 1 7 Analytes, each 40 µg/ml in cyclohexane; unit: 1x1 ml Methylcholanthrene [ ] Methylchrysene [ ] ,9-Dimethylbenz[a]anthracene [ ] ,12-Dimethylbenz[a]anthracene [ ] ,6-Dimethylnaphthalene [ ] ,3-Dimethylphenanthrene [ ] ,5-Dimethylpyrene [ ] Environmental S I Trimethylnaphthalene Mixture 1 6 Analytes, each 500 µg/ml in isooctane; unit: 1x1 ml ,2,3-Trimethylnaphthalene [ ] ,2,4-Trimethylnaphthalene [ ] ,4,5-Trimethylnaphthalene [ ] ,4,6-Trimethylnaphthalene [ ] ,3,5-Trimethylnaphthalene [ ] ,3,6-Trimethylnaphthalene [ ] Deuterated S T S T Deuterated Anthracene in Toluene 1 Analyte, 60 µg/ml in toluene; units: 1x1 ml, 1x5 ml Anthracene-d10 [ ] S-4076-K-T S-4076-K-5T Deuterated Surrogate Standard 5 Analytes, 1000 µg/ml in toluene; units: 1x1 ml, 1x5 ml Naphthalene-d8 [ ] Biphenyl-d10 [ ] Phenanthrene-d10 [ ] Benzo[a]pyrene-d12 [ ] Benzo[ghi]perylene-d12 [ ] 141

144 S T Perdeuterated Internal Standard - PA-Mixture 2 S T 5 Analytes, 100 µg/ml in toluene; units: 1x1 ml, 1x5 ml Naphthalene-d8 [ ] Biphenyl-d10 [ ] Phenanthrene-d10 [ ] Benzo[a]pyrene-d10 [ ] Dibenz[a,h]anthracene-d14 [ ] S-4081-K-CY Perdeuterated Internal Standard - PA-Mixture 3 S-4081-K-5CY 9 Analytes, each 1000 µg/ml in cyclohexane; units: 1x1 ml, 1x5 ml Naphthalene-d8 [ ] Acenaphthylene-d8 [ ] Dibenzothiophene-d8 [ ] Phenanthrene-d10 [ ] Pyrene-d10 [ ] Fluoranthene-d10 [ ] Chrysene-d12 [ ] Benzo[a]pyrene-d12 [ ] Dibenz[a,h]anthracene-d14 [ ] S-4084-K-BD Perdeuterated Internal Standard PA-Mixture 4 S-4084-K-5BD 5 Analytes, each1000 µg/ml in benzene-d6; units: 1x1 ml, 1x5 ml Fluoranthene-d10 [ ] Benzo[b]fluoranthene-d12 [ ] Benzo[k]fluoranthene-d12 [ ] Benzo[ghi]perylene-d12 [ ] Benzo[a]pyrene-d12 [ ] S BD Perdeuterated Internal Standard PA Mixture Analytes, each 100 µg/ml in benzene-d6; unit: 1x1.1mL Prod. No. Compound CAS No. 1524,12 Acenaphthene-d10 [ ] 1336,12 Acenaphthylene-d8 [ ] 0390,14 Anthracene-d10 [ ] 1087,18 Benz[a]anthracene-d12 [ ] 1348,20 Benzo[b]fluoranthene-d12 [ ] 1349,20 Benzo[k]fluoranthene-d12 [ ] 1089,22 Benzo[g,h,i]perylene-d12 [ ] 1088,20 Benzo[a]pyrene-d12 [ ] 1024,18 Chrysene-d12 [ ] 1330,22 Dibenz[a,h]anthracene-d14 [ ] 1337,16 Fluoranthene-d10 [ ] 1530,13 Fluorene-d10 [ ] 1531,22 Indeno[1,2,3-cd]pyrene-d12 [ ] 0978,10 Naphthalene-d8 [ ] 0389,14 Phenanthrene-d10 [ ] 0329,16 Pyrene-d10 [ ] See also deuterated PA mixtures 1, 6, 7 and 8, pages

145 Naphthalene-phenanthrene-dibenzothiophene-mixes NPD S-4034-ASS-I NPD Cocktail 1 20 Analytes, each concentration as listed in isooctane; unit: 1x1 ml Methylnaphthalene [ ] 500 µg/ml Methylnaphthalene [ ] 500 µg/ml ,3-Dimethylnaphthalene [ ] 500 µg/ml ,4-Dimethylnaphthalene [ ] 500 µg/ml ,5-Dimethylnaphthalene [ ] 500 µg/ml ,6-Dimethylnaphthalene [ ] 500 µg/ml ,7-Dimethylnaphthalene [ ] 500 µg/ml ,6-Dimethylnaphthalene [ ] 500 µg/ml ,7-Dimethylnaphthalene [ ] 500 µg/ml Biphenyl [ ] 500 µg/ml Phenanthrene [ ] 500 µg/ml Methylphenanthrene [ ] 250 µg/ml Methylphenanthrene [ ] 250 µg/ml Methylphenanthrene [ ] 250 µg/ml Methylphenanthrene [ ] 250 µg/ml Dibenzothiophene [ ] 250 µg/ml Methyldibenzothiophene [ ] 100 µg/ml Methyldibenzothiophene [ ] 100 µg/ml Methyldibenzothiophene [ ] 100 µg/ml Methyldibenzothiophene [ ] 100 µg/ml Environmental S-4083-K-T NPD Cocktail 2 25 Analytes, each 1000 µg/ml in toluene; unit: 1x1 ml Naphthalene [ ] Methyldibenzothiophene [ ] Methylnaphthalene [ ] Ethyldibenzothiophene [ ] ,6-Dimethylnaphthalene [ ] Propyldibenzothiophene [ ] Isopropylnaphthalene [ ] Fluoranthene [ ] Acenaphthylene [ ] Pyrene [ ] Acenaphthene [ ] Benz[a]anthracene [ ] Fluorene [ ] Chrysene [ ] Phenanthrene [ ] Benzo[b]fluoranthene [ ] Anthracene [ ] Benzo[k]fluoranthene [ ] Methylphenanthrene [ ] Benzo[a]pyrene [ ] Ethylphenanthrene [ ] Indeno[1,2,3-cd]pyrene [ ] ,2,6-Trimethylphenanthrene [ ] Dibenz[a,h]anthracene [ ] Dibenzothiophene [ ] Benzo[ghi]perylene [ ] 143

146 S I NPD Cocktail 3 14 Analytes, each 200 µg/ml in isooctane; unit: 1x1 ml Dibenzothiophene [ ] ,3,6-Trimethylnaphthalene [ ] Methyldibenzothiophene [ ] Fluoranthene [ ] ,8-Dimethyldibenzothiophene [ ] Phenanthrene [ ] ,4,7-Trimethyldibenzothiophene [ ] Methylphenanthrene [ ] Naphthalene [ ] ,6-Dimethylphenanthrene [ ] Methylnaphthalene [ ] ,2,8-Trimethylphenanthrene [ ] ,3-Dimethylnaphthalene [ ] Pyrene [ ] S I NPD Cocktail 4 14 Analytes, each 200 µg/ml in isooctane; unit: 1x1 ml Dibenzothiophene [ ] ,3,6-Trimethylnaphthalene [ ] Methylbenzothiophene [ ] Fluoranthene [ ] ,8-Dimethyldibenzothiophene [ ] Phenanthrene [ ] ,4,7-Trimethyldibenzothiophene [ ] Methylphenanthrene [ ] Naphthalene [ ] ,6-Dimethylphenanthrene [ ] Methylnaphthalene [ ] ,2,8-Trimethylphenanthrene [ ] ,3-Dimethylnaphthalene [ ] Pyrene [ ] S-4007-ASS-AC PA/NPD Stock Solution 21 Analytes, each consentration as listed in acetone; units: 1x1 ml, 5x1 ml Naphthalene [ ] 1.86 µg/ml Methylnaphthalene [ ] 3.36 µg/ml ,3-Dimethylnaphthalene [ ] 3.51 µg/ml Isopropylnaphthalene [ ] 1.87 µg/ml Acenaphthylene [ ] µg/ml Acenaphthene [ ] µg/ml Fluorene [ ] 0.21 µg/ml Phenanthrene [ ] 0.19 µg/ml Methylphenanthrene [ ] 0.31 µg/ml Ethylphenanthrene [ ] 0.27 µg/ml Dibenzothiophene [ ] 0.04 µg/ml Methyldibenzothiophene [ ] 0.09 µg/ml Ethyldibenzothiophene [ ] 0.08 µg/ml Fluoranthene [ ] µg/ml Pyrene [ ] 0.07 µg/ml 144

147 Benz[a]anthracene [ ] µg/ml Chrysene [ ] µg/ml Methylchrysene [ ] 0.02 µg/ml Benzo[b]fluoranthene [ ] µg/ml Benzo[a]pyrene [ ] µg/ml Benzo[ghi]perylene [ ] µg/ml S-4068-ASS-T Calibration Standard PA/NPD Available in the following concentrations or as a complete set of 7x250µL. Concentration: each 200, 100, 80, 40, 20, 10 or 5 µg/ml in toluene Naphthalene [ ] Benzo[b]fluoranthene [ ] Phenylhexane (n-exylbenzene) [ ] Benzo[k]fluoranthene [ ] Methylnaphthalene [ ] Benzo[a]pyrene [ ] Methylnaphthalene [ ] Benzo[e]pyrene [ ] ,3-Dimethylnaphthalene [ ] Perylene [ ] Acenaphthylene [ ] Indeno[1,2,3-cd]pyrene [ ] Dibenzofuran [ ] Dibenz[a,h]anthracene [ ] Fluorene [ ] Benzo[ghi]perylene [ ] Phenanthrene [ ] Dibenzo[a,e]pyrene [ ] Anthracene [ ] Dibenzo[a,h]pyrene [ ] ,6-Dimethylphenanthrene [ ] Dibenzo[a,i]pyrene [ ] Fluoranthene [ ] Anthanthrene [ ] Pyrene [ ] Coronene [ ] Benzo[a]fluorene [ ] Benzo[j]fluoranthene [ ] Benzo[b]fluorene [ ] Benz[a]anthracene [ ] Chrysene [ ] Acenaphthene [ ] ,2'-Binaphthyl [ ] Environmental S-4089-ASS-T S-4089-ASS-5T PA/NPD Control Standard 26 Analytes, each consentration as listed in toluene; units: 1x1 ml, 1x5 ml Naphthalene [ ] 500 µg/ml Methylnaphthalene [ ] 500 µg/ml ,6-Dimethylnaphthalene [ ] 500 µg/ml Isopropylnaphthalene [ ] 300 µg/ml Acenaphthylene [ ] 100 µg/ml Acenaphthene [ ] 100 µg/ml Fluorene [ ] 100 µg/ml Phenanthrene [ ] 100 µg/ml Anthracene [ ] 100 µg/ml Methylphenanthrene [ ] 100 µg/ml Ethylphenanthrene [ ] 100 µg/ml ,2,6-Trimethylphenanthrene [ ] 100 µg/ml Dibenzothiophene [ ] 100 µg/ml Methyldibenzothiophene [ ] 100 µg/ml Ethyldibenzothiophene [ ] 100 µg/ml Propyldibenzothiophene [ ] 100 µg/ml Fluoranthene [ ] 100 µg/ml Pyrene [ ] 100 µg/ml Benz[a]anthracene [ ] 100 µg/ml Chrysene [ ] 100 µg/ml Benzo[b]fluoranthene [ ] 100 µg/ml 145

148 Benzo[k]fluoranthene [ ] 100 µg/ml Benzo[a]pyrene [ ] 100 µg/ml Indeno[1,2,3-cd]pyrene [ ] 100 µg/ml Dibenz[a,h]anthracene [ ] 100 µg/ml Benzo[ghi]perylene [ ] 100 µg/ml S T S T PA/Dibenzothiophenes Mixture 20 Analytes, each 200 µg/ml in toluene; units: 1x1 ml, 1x2mL Prod.no. Compound CAS No. 0712,11 1-Methylnaphthalene [ ] 0713,11 2-Methylnaphthalene [ ] 0725,12 1,6-Dimethylnaphthalene [ ] 0706,13 2,3,5-Trimethylnaphthalene [ ] 0812,15 2-Methylphenanthrene [ ] 0880,16 2,4-Dimethylphenanthrene [ ] 0782,17 1,2,6-Trimethylphenanthrene [ ] 0783,17 1,2,8-Trimethylphenanthrene [ ] 0884,12 Dibenzothiophene [ ] 0886,13 2-Methyldibenzothiophene [ ] 0449,14 2,8-Dimethyldibenzothiophene [ ] 0158,15 2,4,7-Trimethyldibenzothiophene [ ] 0236,20 Benzo[e]pyrene [ ] 0220,20 Perylene [ ] 0001,18 Triphenylene [ ] 0027,18 Benzo[c]phenanthrene [ ] 0264,20 Benxo[j]fluoranthene [ ] 0289,17 1-Methylfluoranthene [ ] 0292,19 1-Methylchrysene [ ] 1508,20 6-Ethylchrysene [ ] S AN PA/NPD Mixture 28 Analytes, each 100 µg/ml in acetonitrile; unit: 1x1.1 ml Prod.no. Compound CAS No. 0002,12 Acenaphthylene [ ] 0732,12 Acenaphthene [ ] 0217,13 Fluorene [ ] 1049,14 Anthracene [ ] 0260,16 Fluoranthene [ ] 0235,16 Pyrene [ ] 0201,18 Benz[a]anthracene [ ] 0212,18 Chrysene [ ] 0263,20 Benzo[b]fluoranthene [ ] 0265,20 Benzo[k]fluoranthene [ ] 0239,20 Benzo[a]pyrene [ ] 0222,22 Benzo[ghi]perylene [ ] 0277,22 Indeno[1,2,3-cd]pyrene [ ] 0203,22 Dibenz[a,h]anthracene [ ] 0711,10 Naphthalene [ ] 0816,14 Phenanthrene [ ] 0884,12 Dibenzothiophene [ ] 0712,11 1-Methylnaphthalene [ ] 146

149 0713,11 2-Methylnaphthalene [ ] 0815,15 9-Methylphenanthrene [ ] 0887,13 4-Methyldibenzothiophene [ ] 0729,12 2,6-Dimethylnaphthalene [ ] 1028,16 9-Ethylphenanthrene [ ] 0148,14 4-Ethyldibenzothiophene [ ] 0716,13 2-Isopropylnaphthalene [ ] 0782,17 1,2,6-Trimethylphenanthrene [ ] 0149,15 4-Propyldibenzothiophene [ ] 2157,6 Bromobenzene [ ] PPs (Persistent organic pollutants) PCBs 4' Cl n 3' 2' 5' 6' Cl m Polychlorinated biphenyls (PCBs) have been the subject of a broad range of studies and investigations because of their environmental persistency and bioaccumulation. Their abundance as pollutants stems from their worldwide manufacture as heavy-used industrial chemicals, e.g. Aroclors with the main application as dielectric fluid in capacitors and transformators. PCBs are formed as mixtures by the addition of chlorine to biphenyl. Environmental PCB congeners can be classified as coplar, dioxinlike with none or one orthosubstitution and nonplanar with substitutions in the ortho-positions. The co-planer PCBs shows a similar toxicity as the dibenzofurans and the dioxins. See also page 354 and onward. )( Cl Cl)( Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Non-planar and coplanar PCBs compared with the conformation of dibenxofurans F-PCBs fluorinated internal standards for PCB analysis a flexible and cost-efficient alternative Mono- and difluorinated PCBs are closely similar to the parent PCBs in terms of physico-chemical properties, and are ideal internal or surrogate standards for GC-MS, GC-ECD, GC-FID and twodimentional GC. The F-PCB internal standards offered by Chiron have several advantages over the more traditionally used 13 C isotopes and unlabelled internal standards: - Cost efficient. Much cheaper than the 13 C isotopes. - Gives one single, pure isotope (F has only one isotope) - Can be used with GC-ECD detection, 13 C can not since they coelute with the native. - Do not discriminate from the native upon work-up. - Designer retention times (ortho-, meta-, para-f) possible for optimal elution rate. 147

150 Dioxin-like F-PCBs Chiron No. Compound PCB No. Conc. /1 ml Fluoro-3,3 4,4 -tetrachlorobiphenyl F-PCB µg/ml Fluoro-3,4,4,5-tetrachlorobiphenyl F-CB µg/ml Fluoro-2,3,3,4,4 -pentachlorobipenyl F-CB µg/ml Fluoro-2,3,4,4,5-pentachlorobiphenyl F-CB µg/ml Fluoro-2,3,4,4,5-pentachlorobiphenyl F-CB µg/ml Fluoro-3,3,4,4,5-pentachlorobiphenyl F-CB µg/ml Fluoro-2,3,3,4,4,5-hexachlorobiphenyl F-CB µg/ml F-PCB internal standards For complete listing see the Compounds section, pages Solutions of single internal standards in isooctane, 1 or 1.1mL Chiron No. Compound PCB No. Conc I 4-Chloro-4 -fluorobiphenyl F-PCB-3 p 100 µg/ml I 3 -Fluoro-3,5-dichlorobiphenyl F-PCB µg/ml I 3-Fluoro-4,4 -dichlorobiphenyl F-PCB µg/ml I 3-Fluoro-2,2,5-trichlorobiphenyl F-PCB-18 m 100 µg/ml I 3 -Fluoro-2,3,4 -trichlorobiphenyl F-PCB-22 m 100 µg/ml I 3 -Fluoro-2,4,4 -trichlorobiphenyl* F-PCB-28 m 100 µg/ml I 3 -Fluoro-2,4,5-trichlorobipehnyl F-PCB-29 m 100 µg/ml I 2 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30 o 100 µg/ml I 3 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30 m 100 µg/ml I 4 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30 p 100 µg/ml I 3 -Fluoro-3,4,4 -trichlorobiphenyl F-PCB-37 m 100 µg/ml v 3 -Fluoro-3,4,5-trichlorobiphenyl F-PCB µg/ml I 3-Fluoro-2,2,5,5 -tetrachlorobiphenyl* F-PCB-52 m 100 µg/ml I 3 -Fluoro-2,3,5,6-tetrachlorobiphenyl F-PCB µg/ml I 4 -Fluoro-2,3,4,5-tetrachlorobiphenyl F-PCB µg/ml I 5-Fluoro-3,3 4,4 -tetrachlorobiphenyl F-PCB µg/ml I 3 -Fluoro-3,4,4,5-tetrachlorobiphenyl F-PCB µg/ml I 5 -Fluoro-2,3,3,4,4 -pentachlorobiphenyl F-PCB µg/ml I 3 Fluoro-2,3,4,4,5-pentachlorobiphenyl F-PCB µg/ml I 3 -Fluoro-2,3,4,5,6-pentachlorobiphenyl F-PCB µg/ml I 5 -Fluoro-2,3,4,4,5-pentachlorobiphenyl F-PCB µg/ml I 5 -Fluoro-3,3,4,4,5-pentachlorobiphenyl F-PCB µg/ml I 5 -Fluoro-2,3,3,4,4,5-hexachlorobiphenyl F-PCB µg/ml I 3 -Fluoro-2,3,4,4,5,6-hexachlorobiphenyl F-PCB µg/ml * Bold items are also on the Dutch Seven list 148

151 Native PCBs Chiron offers single native PCBs in solution and as neat material for analysis and toxicological studies. Mixtures are offered according to international methods and on request. Please inquire for custom synthesis of bulk material. Dutch seven PCBs Solutions of single reference substances, internal standards and multiple component solution, 1 ml. Chiron No. Compound PCB No. Conc I 2,4,4 -Trichlorobiphenyl PCB µg/ml I 2,2,5,5 -Tetrachlorobiphenyl PCB µg/ml I 2,2,4,5,5 -Pentachlorobiphenyl PCB µg/ml I 2,3,4,4 5-Pentachlorobiphenyl PCB µg/ml I 2,2,3,4,4,5 -exachlorobiphenyl PCB µg/ml I 2,2,4,4,5,5 exachlorobiphenyl PCB µg/ml I 2,2 3,4,4,5,5 -eptachlorobiphenyl PCB µg/ml Dioxin-like PCBs S I Dutch Seven PCBs Multiple Comp. Solution 100 µg/ml Chiron No. Compound PCB No. Conc. /1 ml I 3,3 4,4 -Tetrachlorobiphenyl PCB µg/ml I 3,4,4,5-Tetrachlorobiphenyl PCB µg/ml I 2,3,3,4,4 -Pentachlorobiphenyl PCB µg/ml I 2,3,4,4,5-Pentachlorobiphenyl PCB µg/ml I 3,3,4,4,5-Pentachlorobiphenyl PCB µg/ml I 2,3,3,4,4,5-exachlorobiphenyl PCB µg/ml I 2,3,3,4,4,5 -exachlorobiphenyl PCB µg/ml I 2,3,4,4,5,5 -exachlorobiphenyl PCB µg/ml I 3,3,4,4,5,5 -exachlorobiphenyl PCB µg/ml I 2,3,3,4,4,5,5 -eptachlorobiphenyl PCB µg/ml Environmental ptional calibration standards Chiron No. Compound PCB No. Conc. /1 ml I 2,2,3,4,4 5-eptachlorobiphenyl PCB µg/ml I 2,2,3,4,4,5,5 -eptachlorobiphenyl PCB µg/ml S I W Dioxin like PCB mixture, 11 Analytes, each 2 µg/ml in isooctane Chiron No. Compound PCB No I 3,3 4,4 -Tetrachlorobiphenyl PCB I 3,4,4,5-Tetrachlorobiphenyl PCB I 2,3,3,4,4 -Pentachlorobiphenyl PCB I 2,3,4,4,5-Pentachlorobiphenyl PCB I 2,3,4,4,5-Pentachlorobiphenyl PCB I 2,3,4,4,5-Pentachlorobiphenyl PCB I 3,3,4,4,5-Pentachlorobiphenyl PCB I 2,3,3,4,4,5-exachlorobiphenyl PCB I 2,3,3,4,4,5 -exachlorobiphenyl PCB I 2,3,4,4,5,5 -exachlorobiphenyl PCB I 2,3,3,4,4,5,5 -eptachlorobophenyl PCB

152 Technical mixtures Available in concentrations ng/µl in isooctane Chiron No. Name Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor 1260 International standard methods for PCB analysis IS Water quality - Dioxin-like PCBs by GC-MS IS Soil quality rganochlorine pesticided and PCBs by GC-ECD IS Water quality rganochlorine insecticides and PCBs by GC methods EPA rganohalide pesticides and PCBs in water by GC EPA rganochlorine pestisides and PCBs by GC and GC-MS (cf methods 625) in municipal discharges. EPA PCBs from solid and aqueous matices by GC-ECD or GC-ELCD. EPA 1668A-1999 PCB congeners in water, soil, sediments and tissue by RGC/RMS EPA 8270C-1996 Semivolatile compounds from solid waste, soil, air, and water by GC-MS The Dutch Seven PCBs S AN PCB Mixture 1 7 Analytes, each 10µg/mL in acetonitrile; unit: 10x1mL Prod.no. Compound Description CAS No ,4,4 -Trichlorobiphenyl PCB 28 [ ] ,2 5,5 -Tetrachlorobiphenyl PCB 52 [ ] ,2 4,5,5 -Pentachlorobiphenyl PCB 101 [ ] ,2,3,4,4,5-exachlorobiphenyl PCB 138 [ ] ,2 4,4 5,5 -exachlorobiphenyl PCB 153 [ ] ,2,3,4,4,5,5 -eptachlorophenyl PCB 180 [ ] ,2,3,3,4,4,5,5 -ctachlorophenyl PCB 194 [ ] S MG PCB Mixture 2 7 Analytes, each 1 ml neat Prod.no. Compound Description CAS No ,4,4 -Trichlorobiphenyl PCB 28 [ ] ,2,5,5 -Tetrachlorobiphenyl PCB 52 [ ] ,2,4,5,5 -Pentachlorobiphenyl PCB 101 [ ] ,3,4,4,5-Pentachlorobiphenyl PCB 118 [ ] ,2,3,4,4,5-exachlorobiphenyl PCB 138 [ ] ,2,4,4,5,5 -exachlorobiphenyl PCB 153 [ ] ,2,3,4,4,5,5 -eptachlorobiphenyl PCB 180 [ ] 150

153 PBBs (Polybrominated biphenyls) 3' 2' 2 3 4' 4 Br n 5' 6' 6 5 Br m Native standards I 2-Bromobiphenyl PBB-1 [ ] 50µg/mL I 3-Bromobiphenyl PBB-2 [ ] 50µg/mL I 4-Bromobiphenyl PBB-3 [ ] 50µg/mL I 2,2'-Dibromobiphenyl PBB-4 [ ] 50µg/mL I 2,4-Dibromobiphenyl PBB-7 [ ] 50µg/mL I 2,5-Dibromobiphenyl PBB-9 [ ] 50µg/mL I 2,6-Dibromobiphenyl PBB-10 [ ] 50µg/mL I 4,4'-Dibromobiphenyl PBB-15 [ ] 50µg/mL I 2,2',5-Tribromobiphenyl PBB-18 [ ] 50µg/mL I 2,3',5-Tribromobiphenyl PBB-26 [ ] 50µg/mL I 2,4',5-Tribromobiphenyl PBB-31 [ ] 50µg/mL I 2,4,5-Tribromobiphenyl PBB-29 [ ] 50µg/mL I 2,4,6-Tribromobiphenyl PBB-30 [ ] 35µg/mL I 2,4,6-Tribromobiphenyl PBB-30 [ ] 50µg/mL I 3,4,5-Tribromobiphenyl PBB-38 [ ] 50µg/mL I 2,2',4,5'-Tetrabromobiphenyl PBB-49 [ ] 50µg/mL I 2,2',5,5'-Tetrabromobiphenyl PBB-52 [ ] 50µg/mL I 2,2',5,6'-Tetrabromobiphenyl PBB-56 [ ] 50µg/mL I 3,3',5,5'-Tetrabromobiphenyl PBB-80 [ ] 50µg/mL I 2,2',4,5,5'-Pentabromobiphenyl PBB-101 [ ] 50µg/mL I 2,2',4,5',6-Pentabromobiphenyl PBB-103 [ ] 50µg/mL I 2,2',4,4',5,5'-exabromobiphenyl PBB-153 [ ] 50µg/mL I 2,2',4,4',6,6'-exabromobiphenyl PBB-155 [ ] 50µg/mL I 3,3',4,4',5,5'-exabromobiphenyl PBB-169 [ ] 10µg/mL I ctabromodiphenyl, techn. [ ] 50µg/mL I Decabromodiphenyl PBB-209 [ ] 50µg/mL KIT PBB Kit Environmental PCNs (Polychlorinated naphthalenes) 8 1 Cl Cl Cl n (8-n) Cl Cl 2,3,6,7-Tetrachloronaphthalene PCN 48 PCNs are polychlorinated naphthalenes. Although PCNs have been known for about 170 years, and have been commercially produced and used over a period of 100 years, only little attention is paid to their formation, sources, occurrence, fate and effects. Technical mixtures of PCNs have been commercially produced under the brand names alowax (U.S.), Seekay (U.K) and Nibren wax (Germany) for uses similar to PCB mixtures (Aroclor), which also contain PCNs as impurities. There are 75 PCN congeners. 151

154 Individual native PCNs Chiron No. Compound PCN No. CAS No. Conc I 1-Chloronaphthalene PCN-1 [ ] 50µg/mL I 2-Chloronaphthalene PCN-2 [ ] 50µg/mL I 1,4-Dichloronaphthalene PCN-5 [ ] 50µg/mL I 1,5-Dichloronaphthalene PCN-6 [ ] 50µg/mL I 2,3-Dichloronaphthalene PCN-10 [ ] 50µg/mL I 2,6-Dichloronaphthalene PCN-11 [ ] 50µg/mL I 2,7-Dichloronaphthalene PCN-12 [ ] 50µg/mL I 1,2,3,4-Tetrachloronaphthalene PCN-27 [ ] 50µg/mL I Tetrachloronaphthalene, mix 50µg/mL I ctachloronaphthalene PCN-75 [ ] 50µg/mL KIT PCN Kit 50µg/mL in isooctane, 1 or 1.1mL PBNs (Polybrominated naphthalenes) Chiron No. Compound PBN No. CAS. No. Conc I 1-Bromonaphthalene PBN-1 [ ] 50µg/mL I 2-Bromonaphthalene PBN-2 [ ] 50µg/mL I 1,4-Dibromonaphthalene PBN-5 [ ] 50µg/mL I 2,3-Dibromonaphthalene PBN-10 [ ] 50µg/mL I 2,6-Dibromonaphthalene PBN-11 [ ] 50µg/mL I 2,7-Dibromonaphthalene PBN-12 [ ] 50µg/mL KIT PBN Kit PBDE flame retardants 3' 2' 2 3 4' 4 Br n 5' 6' 6 5 Br m PBDEs have been used as flame retardants over the past two decades, and are globally distributed in the environment. PBDEs accumulate in the food chain and there is a strong concern about the health effects of PBDE exposure. Both single and multi-component standards have been developed in convenient concentrations and solvents to assist researchers in this analysis. According to their presence in different technical mixtures and samples, we offer pure standards. Neat material is available for toxicological studies. Please inquire for custom synthesis of bulk material. F-PBDE internal standards Chiron No. Compound PBDE No. Conc I 3 -Fluoro-2,4-dibromodiphenyl ether F-PBDE-7 50 µg/ml I 3 -Fluoro-3,4-dibromodiphenyl ether F-PBDE µg/ml I 4'-Fluoro-2,3',4-tribromodiphenyl ether F-PBDE µg/ml I 4'-Fluoro-2,3',6-tribromodiphenyl ether F-PBDE µg/ml I 3 -Fluoro-,2,4,4 -tribromodiphenyl ether F-PBDE µg/ml I 6-Fluoro-2,2,4,4 -tetrabromodiphenyl ether F-PBDE µg/ml 152

155 I 5,5 -Difluoro-2,2,4,4 -tetrabromodiphenyl ether 2F-PBDE µg/ml I 6-Fluoro-2,3,4,4 -tetrabromodiphenyl ether F-PBDE µg/ml I 4 -Fluoro-2,3,4,6-tetrabromodiphenyl ether F-PBDE µg/ml I 5,6-Difluoro-2,2,3,4,4 -pentabromodiphenyl ether 2F-PBDE µg/ml I 3,6-Difluoro-2,2,4,4, 5-pentabromodiphenyl ether 2F-PBDE µg/ml I 3-Fluoro-2,2,4,4,6-pentabromodiphenyl ether F-PBDE µg/ml I 3-Fluoro-2,3,4,4,6-pentabromodiphenyl ether F-PBDE µg/ml I 3,5-Difluoro-2,3,4,4,6-pentabromodiphenyl ether 2F-PBDE µg/ml I 4 -Fluoro-2,3,3,4,5,6-hexabromodiphenyl ether F-PBDE µg/ml I 2,4 -Difluoro-2,3,3,4,5,5,6,6 -octabromodiphenyl ether 2F-PBDE µg/ml I 4 -Fluoro-2,2,3,3,4,5,5 6,6 -nonabromodiphenyl ether F-PBDE µg/ml References: Korytar et al.: J.Chromatogr. A 1065, (2005); 1100, (2005) Liu et al.: Chemosphere 64, (2006) Fiksdahl et al.: Tetrahedron 62, (2006) Native standards Lake michigan study Solutions of single reference substances KIT: 9 compounds, 50 µg/ml each in isooctane Environmental Chiron No. Compound PBDE No. Conc I 2,4,4 -Tribromodiphenyl ether PBDE µg/ml I 2,2,4,4 -Tetrabromodiphenyl ether PBDE µg/ml I 2,3,4,4 -Tetrabromodiphenyl ether PBDE µg/ml I 2,2,3,4,4 -Pentabromodiphenyl ether PBDE µg/ml I 2,2,4,4,5-Pentabromodiphenyl ether PBDE µg/ml I 2,2,4,4,6-Pentabromodiphenyl ether PBDE µg/ml I 2,2,3,4,4,5 -exabromodiphenyl ether PBDE µg/ml I 2,2,4,4,5,5 -exabromodiphenyl ether PBDE µg/ml I 2,2,4,4,5,6 -exabromodiphenyl ether PBDE µg/ml KIT Lake Michigan Study Kit S I Multiple component solution of the above PBDEs, each 10 µg/ml (1mL) ther relevant PBDEs Solutions of single reference substances KIT: 11 compounds, 50 µg/ml each in isooctane Chiron No. Compound PBDE No. Conc I 2,3,4-Tribromodiphenyl ether PBDE µg/ml I 2,2,4,5 -Tetrabromodiphenyl ether PBDE µg/ml I 2,3,4,6-Tetrabromodiphenyl ether PBDE µg/ml I 2,4,4,6-Tetrabromodiphenyl ether PBDE µg/ml I 3,3,4,4 -Tetrabromodiphenyl ether PBDE µg/ml I 2,3,4,4,5-Pentabromodiphenyl ether PBDE µg/ml I 2,3,4,4,6-Pentabromodiphenyl ether PBDE µg/ml I 2,2,3,4,4,5,6-eptabromodiphenyl ether PBDE µg/ml 153

156 I 2,3,3,4,4,5,6-eptabromodiphenyl ether PBDE µg/ml I 2,2,3,4,4,5,5,6-ctabromodiphenyl ether PBDE µg/ml I 2,3,3,4,4,5,5,6-ctabromodiphenyl ether PBDE µg/ml I Decabromodiphenyl ether PBDE µg/ml KIT PBDE Kit International methods - IS 22032:2006 Water quality PBDEs by GC - IS/DIS 23061:2005 Soil quality PBDEs by GC - EPA 527.1:2005 Drinking water Pesticides and PBDEs by GC-MS - EPA 1614 PBDEs by RGC/RMS ther flame retardants K-IP 4-Chloro-3-methylphenol [ ] 1000µg/mL K-IP 2,4-Dibromophenol [ ] 1000µg/mL I Decabromodiphenylethane [ ] 50µg/mL IP Dibromoneopentylglycol [ ] 50µg/mL I exabromobenzene [ ] 50µg/mL I 1,2,3,4,5,6-exabromocyclohexane [ ] 50µg/mL K-I 1,2,5,6,9,10-exabromocyclododecane [ ] 1000µg/mL I ctabromodiphenyl, techn. [ ] 50µg/mL I Pentabromophenol [ ] 50µg/mL I Pentabromotoluene [ ] 50µg/mL I Tetrabromobisphenol A [ ] 50µg/mL I Tetrabromobisphenol A dimethyl ether [ ] 50µg/mL K-IP 2,4,6-Tribromophenol [ ] 1000µg/mL I Tetrabromophthalic anhydride [ ] 50µg/mL CY Tetradecabromo-1,4-diphenoxybenzene [ ] 50µg/mL Dioxins and furans Cl Cl Cl Cl Cl n (8-n) 7 6 PCDF 4 3 Cl n (8-n) Polychlorinated dioxins (PCDDs) and polychlorinated dibenzofuranes (PCDFs or furans ) are formed during combustion processes, such as waste incineration, fires, and during certain manufacturing processes, but have no industrial applications and are not produced as such. The most toxic of these compounds is 2,3,7,8-tetrachlorodibenzo-p-dioxin, TCDD. There are 75 PCDD congeners and 135 PCDF congeners. PCDDs PCDDs: individual solutions 50 µg/ml in toluene; name according to IUPAC: T Dibenzo-p-dioxin [ ] T 1-Chlorodibenzo-p-dioxin [ ] 154

157 T 2-Chlorodibenzo-p-dioxin [ ] T 2,7-Dichlorodibenzo-p-dioxin [ ] T 1,2,4-Trichlorodibenzo-p-dioxin [ ] T 1,2,3,4-Tetrachlorodibenzo-p-dioxin [ ] T ctachlorodibenzo-p-dioxin [ ] PCDFs PCDFs: individual solutions 50 µg/ml in toluene; name according to IUPAC: T Dibenzofuran [ ] T 2,8-Dichlorodibenzofuran [ ] T ctachlorodibenzofuran [ ] PCAs, SCCPs, C10-C13 polychloroalkanes Polychloro-n-alkanes (PCAs) or chlorinated paraffins are a class of industrial chemicals used as high-temperature lubricants in metal-working machinery and as flame-retardant plasticizers in vinyl plastics. Less common applications include the use as flame-retardants in rubber, paints, adhesives and as sealants. Industrially, the PCAs are synthesized by direct chlorination of n-alkane feedstock with molecular chlorine at elevated temperatures and pressures, and sometimes in the presence of UV-light. PCAs fall into three categories, C10-C13 (short, SCCP ), C14-C17 (medium, MCCP ), and C20-C30 (long, LCCP ). They are further sub-categorized into their weight content of chlorine, 40-50%, 50-60% and 60-70%. Environmental C10-C13 PCA ( SCCPs short-chain-chlorinated-paraffines) Listed as Priority Pollutants in the US, Canada, and Europe In the US, C10-C13 PCAs have been placed on the US Environmental Protection Agency (EPA) Toxic Release Inventory, in Canada they are classified as Track 1 Priority Toxic substances under the Canadian Environmental Protection Act, and in Europe the C10-C13 PCAs are included on the list of priority substances in the field of water policy submitted by the Commision of European Communities for the European Parliament and Council Decision. Analysis of PCAs PCAs are analyzed by GC using ECD detector, or more sophisticated by high resolution gas chromatography/electron capture negative ion-mass spectrometry (RGC/ECNI-MS). Chiron No. Molecular formula Compound % Weight of Cl Dichloro K-I C816Cl2 1,2-Dichlorooctane 38, K-I C918Cl2 1,2-Dichlorononane 36, K-I C1020Cl2 1,2-Dichlorodecane 33, K-I C1122Cl2 1,2-Dichloroundecane 31, K-I C1224Cl2 1,2-Dichlorododecane 29, K-I C1224Cl2 1,12-Dichlorododecane 29, K-I C1326Cl2 1,2-Dichlorotridecane 28, K-I C1428Cl2 1,2-Dichlorotetradecane 26, K-I Dichloroalkane Kit Tetrachloro K-I C814Cl4 1,2,7,8-Tetrachlorooctane 56, K-I C814Cl4 1,1,1,3-Tetrachlorooctane 56,3 155

158 K-I C916Cl4 1,2,8,9-Tetrachlorononane 53, K-I C916Cl4 1,1,1,3-Tetrachlorononane 53, K-I C1018Cl4 1,2,9,10-Tetrachlorodecane 50, K-I C1018Cl4 1,1,1,3-Tetrachlorodecane 50, K-I C1120Cl4 1,2,10,11-Tetrachloroundecane 48, K-I C1120Cl4 1,1,1,3-Tetrachloroundecane 48, K-I C1222Cl4 1,2,11,12-Tetrachlorododecane 46, K-I C1222Cl4 1,1,1,3-Tetrachlorododecane 46, K-I C1324Cl4 1,1,1,3-Tetrachlorotridecane 44, K-I C1426Cl4 1,2,13,14-Tetrachlorotetradecane 42, K-I C1426Cl4 1,1,1,3-Tetrachlorotetradecane 42, K-I Tetrachloroalkane Kit exachloro K-I C914Cl6 1,1,1,3,8,9-exachlorononane 63, K-I C1016Cl6 1,1,1,3,9,10-exachlorodecane 61, K-I C1118Cl6 1,1,1,3,10,11-exachloroundecane 58, K-I C1220Cl6 1,1,1,3,11,12-exachlorododecane 56, K-I C1322Cl6 1,1,1,3,12,13-exachlorotridecane 54, K-I exachloroalkane Kit ctachloro K-I C810Cl8 1,1,1,3,6,8,8,8-ctachlorooctane 72, K-I C1014Cl8 1,1,1,3,8,10,10,10-ctachlorodecane 67, K-I C1116Cl8 1,1,1,3,9,11,11,11-ctachloroundecane 65, K-I C1218Cl8 1,1,1,3,10,12,12,12-ctachlorododecane 63, K-I C1320Cl8 1,1,1,3,11,13,13,13-ctachlorotridecane 61, K-I C1422Cl8 1,1,1,3,12,14,14,14-ctachlorotetradecane 59, Kit ctachloroalkane Kit Kit C8-C9 PCA Kit (8 samples, 1 vial each) Kit C10-C13 PCA (SCCP) Kit (20 samples, 1 vial each) Kit C14 PCA (MCCP) Kit (4 samples, 1 vial each) Pesticides, herbicides Individual native and labelled internal standards are listed in the Compounds section, page 367 and onward. International standards IS 6468: 1996 Water quality, Pesticides, PCBs and chlorobenzenes IS 10381:2002 Soil quality organochlorine pesticides and PCBs EPA 505:1995 Water rganohalide pesticides by GC EPA 527.1:2005 Drinking water Pesticides and PBDEs by GC/MS Special mixes S K-AN S K-2AN Pesticide Mixture 6 Analytes, each µg/ml in acetonitrile; units: 1x1, 1x2mL 156

159 Prod.no. Compound CAS No. 2768,8 Atrazine [ ] 2769,9 Propazine [ ] 2770,7 Simazine [ ] 2771,9 Tertbuthylazine [ ] 2772,6 Atrazine-desethyl [ ] 2773,5 Atrazine-desisopropyl [ ] S CY Chlorinated Pesticides 6 Analytes, each 5 µg/ml in cyclohexane; units: 1x2mL S K-CY S K-2CY Prod.no. Compound CAS No. 2774,12 Aldrin [ ] 2775,12 Dieldrin [ ] 2026,6 Lindane [ ] 2776,10 eptachlor [ ] 2777,10 eptachlor-endo-epoxide (cis-) [ ] 2778,10 epotachlor-exo-epoxide (trans-) [ ] Phosphorous Containing Pesticides 5 Analytes, each 5000 µg/ml in cyclohexane; units: 1x1, 1x2 ml Environmental Prod.no. Compound CAS No. 2779,12 Diazinon [ ] 2780,9 Ethion [ ] 1396,10 Malathion [ ] 2781,9 Fenitrothion [ ] 2782,10 Parathion-ethyl [ ] S ME S ME Conazoles Mixture 4 Analytes, each 100 µg/ml in methanol; units: 1x1 ml, 1x10 ml Prod.no. Compound CAS no. 2319,15 Cyproconazole [ ] 2320,15 Propiconazole [ ] 2318,16 Tebuconazole [ ] 2321,17 Epoxiconazole [ ] Chlorobenzenes Internal standards K-I 1,4-Dichlorobenzene-d4 [ ] 1000µg/mL isooctane I exachlorobenzene- 13 C6 [ ] 100µg/mL isooctane K-ME 1-Chloro-4-fluorobenzene, Internal standard for Gasoline Range Analysis [ ] 1000µg/mL methanol K-ME 1-Chloro-4-fluorobenzene, Internal standard for Gasoline Range Analysis [ ] 1000µg/mL methanol 157

160 Native chlorobenzenes K-I Chlorobenzene [ ] 1000µg/mL isooctane K-I 1,2-Dichlorobenzene [ ] 1000µg/mL isooctane K-I 1,3-Dichlorobenzene [ ] 1000µg/mL isooctane K-I 1,4-Dichlorobenzene [ ] 1000µg/mL isooctane K-I 1,2,3-Trichlorobenzene [ ] 1000µg/mL isooctane K-I 1,2,4-Trichlorobenzene [ ] 1000µg/mL isooctane K-I 1,3,5-Trichlorobenzene [ ] 1000µg/mL isooctane K-I 1,2,3,4-Tetrachlorobenzene [ ] 1000µg/mL isooctane K-I 1,2,3,5-Tetrachlorobenzene [ ] 1000µg/mL isooctane K-I 1,2,4,5-Tetrachlorobenzene [ ] 1000µg/mL isooctane K-I Pentachlorobenzene [ ] 1000µg/mL isooctane K-I exachlorobenzene [ ] 1000µg/mL isooctane KIT-S Chlorobenzene Kit (Natives in solution) Also available in neat form, see the Compounds section, page 286. Bromobenzenes I Bromobenzene [ ] 50µg/mL isooctane I 1,2-Dibromobenzene [ ] 50µg/mL isooctane I 1,3-Dibromobenzene [ ] 50µg/mL isooctane I 1,4-Dibromobenzene [ ] 50µg/mL isooctane I 1,3,5-Tribromobenzene [ ] 50µg/mL isooctane I 1,2,4,5-Tetrabromobenzene [ ] 50µg/mL isooctane I Pentabromotoluene [ ] 50µg/mL isooctane I exabromobenzene [ ] 50µg/mL isooctane KIT Bromobenzene Kit Also available in neat form, see the Compounds section, page 287. Chlorophenols Monochlorophenols K-IP 2-Chlorophenol [ ] 1000µg/mL isopropanol K-IP 3-Chlorophenol [ ] 1000µg/mL isopropanol K-IP 4-Chlorophenol [ ] 1000µg/mL isopropanol K-IP 2-Chloro-5-methylphenol [ ] 1000µg/mL isopropanol K-IP 4-Chloro-2-methylphenol [ ] 1000µg/mL isopropanol K-IP 4-Chloro-3-methylphenol [ ] 1000µg/mL isopropanol K-IP 2-Chloro-4-tert-butylphenol [ ] 1000µg/mL isopropanol K-IP 6-Chloro-5-methyl-2-(1-methylethyl)phenol [ ] 1000µg/mL isopropanol K-IP 2-Cyclopentyl-4-chlorophenol [ ] 1000µg/mL isopropanol K-IP 4-Chloro-2-benzylphenol [ ] 1000µg/mL isopropanol KIT Monochlorophenol Kit 158

161 Dichlorophenols K-IP 2,3-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,4-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,5-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,6-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 3,4-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 3,5-Dichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,4-Dichloro-6-methylphenol [ ] 1000µg/mL isopropanol K-IP 2,4-Dichloro-3,5-dimethylphenol [ ] 1000µg/mL isopropanol K-IP 2,5-Dichloro-4-tert-butylphenol [ ] 1000µg/mL isopropanol KIT Dichlorophenol Kit Trichlorophenols K-IP 2,3,4-Trichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,3,5-Trichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,3,6-Trichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,4,5-Trichlorophenol [ ] 1000µg/mL isopropanol K-IP 2,4,6-Trichlorophenol [ ] 1000µg/mL isopropanol K-IP 3,4,5-Trichlorophenol [ ] 1000µg/mL isopropanol KIT Trichlorophenol Kit Tetra-/ pentachlorophenols K-IP 2,3,4,5-Tetrachlorophenol [ ] 1000µg/mL isopropanol K-I 2,3,4,6-Tetrachlorophenol [ ] 1000µg/mL isooctane K-IP 2,3,5,6-Tetrachlorophenol [ ] 1000µg/mL isopropanol K-I Pentachlorophenol [ ] 1000µg/mL isooctane K-IP Pentachlorophenol [ ] 1000µg/mL isopropanol KIT Tetra-/Pentachlorophenol Kit Environmental Bromophenols K-IP 2-Bromophenol [ ] 1000µg/mL isopropanol K-IP 4-Bromophenol [ ] 1000µg/mL isopropanol K-IP 2,3-Dibromophenol [ ] 1000µg/mL isopropanol K-IP 2,4-Dibromophenol [ ] 1000µg/mL isopropanol K-IP 2,5-Dibromophenol [ ] 1000µg/mL isopropanol K-IP 2,6-Dibromophenol [ ] 1000µg/mL isopropanol K-IP 2,3,4-Tribromophenol [ ] 1000µg/mL isopropanol K-IP 2,3,6-Tribromophenol [ ] 1000µg/mL isopropanol K-IP 2,4,6-Tribromophenol [ ] 1000µg/mL isopropanol K-IP 2,4,5-Tribromophenol [ ] 1000µg/mL isopropanol K-IP 2,3,4,6-Tetrabromophenol [ ] 1000µg/mL isopropanol I Pentabromophenol [ ] 50µg/mL isooctane KIT Bromophenol Kit ther K-I exachloro-1,3-butadiene [ ] 1000µg/mL isooctane 159

162 VC (Volatile organic compounds) S K-ME VC Standard Mixture 1 13 Analytes, each 5000µg/mL in methanol; units: 1x1 ml, 5x1 ml Chloroform [ ] Toluene [ ] ,1,1-Trichloroethane [ ] Ethylbenzene [ ] Tetrachloroethane [ ] m-xylene [ ] Trichloroethylene [ ] p-xylene [ ] Tetrachloroethylene [ ] o-xylene [ ] ,2-Dichloroethane [ ] Naphthalene [ ] Benzene [ ] S-4092-K-5PE VC Chloro-Bromo-methane Mixture 1 4 Analytes, each 1000 µg/ml in n-pentane; unit: 1x 5 ml Bromoform Bromodichloromethane [ ] Chloroform [ ] Chlorodibromomethane [ ] This standard has been made for the determination of volatile halogenated in compounds in the water on offshore platforms S-4420-ASS-2ME V/TM Mixture 6 Analytes, each concentration as listed in methanol; unit: 5x2 ml Prod.no. Compound CAS No. Concentration Chloroform [ ] 1000µg/mL Bromodichloromethane [ ] 1000µg/mL Chlorodibromomethane [ ] 1000µg/mL ,2-Dichloroethane [ ] 1000µg/mL Trichloroethylene [ ] 1000µg/mL Tetrachloroethylene [ ] 100µg/mL 160

163 Miscellaneous mixtures S DC GC-MS Test Mixture 16 Analytes, each 10 µg/ml in dichloromethane; unit: 5x2 ml Trimethylphosphate [ ] n-decane [ ] ,6-Dimethylphenol [ ] n-dodecane [ ] Chloro-2-methylanaline [ ] n-tetradecane [ ] Tributylphosphate [ ] n-exadecane [ ] Dibenzothiophene [ ] n-ctadecane [ ] Malathion [ ] n-eicosane [ ] Methylstearate [ ] n-docosane [ ] n-ctane [ ] n-tetracosane [ ] Environmental S K-AC 3,4-Dimercaptotoluene 5000µg/mL in acetone, 5 x 1 ml S AN Phenone mixture 9 Analytes, each 100µg/mL in acetonitrile; unit: 1x10mL Prod.no. Compound CAS no Acetanilide [ ] Acetophenone [ ] Propiophenone [ ] Butyrophenone [ ] Benzophenone [ ] Valerophenone [ ] exanophenone [ ] eptanophenone [ ] ctanophenone [ ] 161

164 rganotin analysis rganotin compounds are widely applied in the industry due to their antibacterial and fungicidal properties. Applications include preservation of wood, textiles, leather and paper, and as disinfectants. Due to their toxicity the use of trialkyltin compounds in marine antifoulding paints is restricted. The trialkyltin compounds are partly degraded to the di- and monoalkyltin derivatives. Quantification of organotin compounds The principle is based on alkylation of the organotin chlorides to tetrasubstituted compounds which are analyzed by GC and GC/MS. Analyte Internal Analyte Internal standard derivatives standard derivative As a unique source, Chiron offers standards for the derived analytes for use as calibration standards, in addition to the derivatizing agent and the common trialkyltin chloride pollutants. Ethyl derivatives Analytes ethyl derivatives 1000µg/mL in isooctane; units: 1x1 ml, 5x1 ml K-I K-I K-I K-I K-I K-I K-I K-I K-I Ethyltributyltin Di-n-butyl diethyltin Mono-n-butyl triethyltin Di-n-octyl diethyltin Mono-n-octyl triethyltin Ethyltricyclohexyltin Ethyltriphenyltin Diphenyl diethyltin Monophenyl triethyltin Internal standards ethyl derivatives 1000µg/mL in isooctane; units: 1x1 ml, 5x1 ml K-I K-I K-I K-I Kit Ethyltri-n-propyltin Ethyltri-n-pentyltin Di-n-heptyldiethyltin Mono-n-heptyltriethyltin Ethylalkyl/Triaryltin Kit (13 compounds, 13 vials) 162

165 Tin chlorides Analytes: common tin pollutants 1000µg/mL in isooctane or neat as listed Tri-n-butyltin chloride 1 g or 1000µg/mL, 5 ml Di-n-butyltin dichloride 1 g or 1000µg/mL, 5 ml Mono-n-butyltin trichloride 1 g or 1000µg/mL, 5 ml Triphenyltin chloride 1 g or 1000µg/mL, 5 ml Diphenyltin dichloride 1 g or 1000µg/mL, 5 ml Monophenyltin trichloride 1 g or 1000µg/mL, 5 ml Mono-n-octyltin trichloride 1 g or 1000µg/mL, 5 ml Di-n-octyltin dichloride 1 g or 1000µg/mL, 5 ml Tri-n-octyltin chloride 100 mg or 1000µg/mL, 5 ml Tricyclohexyltin chloride 1 g or 1000µg/mL, 5 ml Internal standards 1000µg/mL in isooctane or neat as listed Tri-n-propyltin chloride 1 g or 1000µg/mL, 5 ml Tetra-n-propyltin 1 g or 1000µg/mL, 5 ml Tri-n-pentyltin chloride 1 g or 1000µg/mL, 5 ml Mono-n-heptyltin trichloride 100 mg or 1000µg/mL, 5 ml Di-n-heptyltin dichloride 100 mg or 1000µg/mL, 5 ml Environmental Derivatizing agent MG Sodium tetraethyl borate 1 g KIT rganotin Analysis Kit (16 compounds, 16 vials) S-4335-K-I rganotin Standard Mixture 1 S-4335-K-5I Each 1000µg/mL in isooctane; units: 5x1mL or 5x5mL Prod.No. Compound CAS No Mono-n-butyltin trichloride [ ] Di-n-butyltin dichloride [ ] Mono phenyltin trichloride [ ] Tri-n-butyltin chloride [ ] Triphenyltin chloride [ ] Diphenyltin dichloride [ ] International methods For details and mixtures see the methods section - IS 17353:2004 Water Quality - Determination of selected organotin compound by GC - IS/DIS :2007 Soil Quality - Determination of selected organotin compound gas chromatographic methods For these important methods, see the Methods section, pages 32 and

166 Phosphates rganophosphate compound like those used in hydraulic fluids are belived to posses neurotoxic effect and causing organophosphate induced neuropsyhiatric disorder (CPIND). The potentially most toxic compounds are of the type tri-o-cresylphosphate (tri-o-tolylphosphate). Native standards Chiron No. Compound CAS No. Concentration K-I Trimethyl phosphate TMP [ ] 1000µg/mL K-I Triethyl phosphate [ ] 1000µg/mL K-I Tri-n-propyl phosphate [ ] 1000µg/mL K-I Tri-n-butyl phosphate TBP (TnBP) [ ] 1000µg/mL K-I Triisobutyl phosphate TiBP [ ] 1000µg/mL K-I Triphenyl phosphate TPP [ ] 1000µg/mL K-I Tolyldiphenyl phosphate [ ] 1000µg/mL K-I Tri-o-tolyl phosphate ToTP [ ] 1000µg/mL K-I Tri-m-tolyl phosphate TmTP [ ] 1000µg/mL K-I Tri-p-tolyl phosphate TpTP [ ] 1000µg/mL K-I Tritolyl phosphate (isomer mix) TTP [ ] 1000µg/mL Determination of the origin of faecal waste Sewage waste analysis using faecal sterols Coprostanol epi-coprostanol 164

167 The deterioration of the water quality in rivers, lakes and coastal regions is a major challenge. The use of sterol biomarker fingerprinting as an indicators of types of faecal input has been investigation and developed successfully over the past 25 years. This is an alternative to using microorganisms like E. Coli and Streptococci which have proven to be limited in their applications. Coprostanol (5β()-cholestan-3β-ol) is one of the major sterols present in human faeces and is formed by bacterial reduction of cholesterol. A high value of epi-coprostanol (5β()-choletan-3α-ol) suggest older faecal contaminations. Stanols does not occur naturally in fresh and marine sediments. erbivore faeces (from e.g. cows) typically have a high content of 24-ethylcoprosatnol, while algal input will have high levels sterols derived of typical algal sterols (e.g. ethylstigmastanol). Ref: Environ. Sci.Technol. 2007,41, and references therein. Internal standard Cat No Compound CAS No. Quantity MG 5β()-Cholan-24-ol [ ] 10mg MG 5β()-Cholan-24-ol [ ] 25mg Ref.: Rhys Leming Native standards Cat No Compound CAS No. Quantity MG Cholest-5-en-3β-ol Cholesterol [ ] 10mg Cholest-5-en-3α-ol epi-cholestrol Inquire MG 5α()-Cholestan-3β-ol Cholestanol [ ] 10mg MG 5α()-Cholestan-3α-ol epi-cholestanol [ ] 10mg MG 5β()-Cholestan-3β-ol Coprostanol [ ] 10mg MG 5β()-Cholestan-3α-ol epi-coprostanol [ ] 10mg MG Cholest-4-ene-3-one [ ] 10mg MG 5α()-Cholestan-3-one Cholestanone [ ] 10mg MG 5β()-Cholestan-3-one Coprostanone [ ] 10mg MG 24-Methylcholesta-5,22E-dien-3β-ol Brassicasterol [ ] 5mg MG 24-Ethylcholest-5,22E-dien-3β-ol Stigmasterol [ ] 10mg 24-Ethylcholest-5,22E-dien-3α-ol epi-stigmasterol Inquire MG 24-Ethylcholest-5-en-3β-ol β-sitosterol [ ] 10mg 24-Ethylcholest-5-en-3α-ol epi- β-sitosterol Inquire 24-Ethyl-5α()-cholest-22E-en-3β-ol Inquire 24-Ethyl-5α()-cholest-22E-en-3α-ol Inquire 24-Ethyl-5β()-cholest-22E-en-3β-ol Inquire 24-Ethyl-5β()-cholest-22E-en-3α-ol Inquire MG 24-Ethyl-5α()-cholestan-3β-ol β-sitostanol, Stigmastanol [ ] 10mg MG 24-Ethyl-5α()-cholestan-3α-ol epi-β-sitosterol (24-ethylepicholestanol) epi-stigmastanol ] 10mg MG 24-Ethylcoprostanol [ ] 10mg MG 24-Ethyl-5β()-cholestan-3α-ol 24-Ethyl-epi-coprostanol [ ] 10mg 24-Ethylcholesta-4,22E-dien-3-one Stigmastadienone Inquire Environmental 165

168 166

169 Chapter III-2: Petroleum applications Table of contents Geochemical analysis and petroleum exploration Calibration mixtures and ground separation general Analysis of oils and rocks using internal standards istd Asphaltene precipitation asp Bulk composition of deasphalthened oils or rock extracts by TLC-FID TLC-FID GC analysis of whole (depressurised) fluid and PINA standards wgc GC analysis of the saturated hydrocarbon fraction sat GC GC analysis of the aromatic fraction ar GC GC-MS analysis of oil, EM or saturated hydrocarbon fraction sat/em GC-MS Gas-chromatography isotope-ratio mass-spectrometry (GC-MS) analysis gc-irms References Petroleum analysis and petroleum products PINA, PNA, PNA analysis Sulfur content determination Nitrogen content determination Phosphorous standards rganophosphates Petrochemical products Biodiesel fuels Petroleum 167

170 Geochemical analysis and petroleum exploration Calibration mixtures and group separation General The calibration mixtures described in this chapter are applicable for petroleum and organic geochemical analysis and are applicable to oil spill analysis and other types of petroleum and biomarker analysis. Recommendations made by The Norwegian Industry Guide to Geochemical Analysis (NIGGA) are followed in the preparation of most of these products. Analysis of oils and rocks using internal standards ISTD The rock samples are extracted by Soxhlet extraction in dichloromethane-methanol mixture. The solvents are removed under vacuum, and the remaining extractable organic matter (EM) is added to the required internal standard cocktail before further treatment. Similarly, the crude oil (or oil spill), topped or untopped, is added to the internal standard cocktail before deasphaltening. The deasphaltened sample is separated into saturated, aromatic and polar fractions by MPLC before a detailed GC and GC-MS analysis. In general, it is recommended to add the internal standards as early as possible in the process in order to account for experimental errors. 168

171 Internal standards (NIGGA recommendations) Chiron No. Saturated ydrocarbons CAS No Squalane [ ] n-dodecane-d26 [ ] n-exadecane-d34 [ ] n-eicosane-d42 [ ] n-tetracosane-d50 [ ] Chiron No. Saturated Biomarkers CAS No β()-Cholane [ ] d2 C27 ααα (20R) Cholestane [ ] d4 C27 ααα (20R) Cholestane [ ] d2 C29 ααα (20R) Ethylcholestane d4 C29 ααα (20R) Ethylcholestane d2 Nor-17β(),21α()-hopane, d2 Isoadiantane Chiron No. Aromatics CAS No Fluoronaphthalene, F-PA [ ] Fluoro-6-methylnaphthalene [ ] Fluoro-6-methylphenanthrene [ ] Fluoro-6-methylnaphthalene, F-PA [ ] Fluorophenanthrene, F-PA [ ] Fluoro-6-methylphenanthrene, F-PA [ ] Fluoropyrene, F-PA [ ] Fluorobiphenyl, F-PA [ ] Fluorochrysene, F-PA Fluoro-5-methylchrysene [ ] Fluoro-5-methylchrysene, F-PA [ ] Naphthalene-d8 [ ] Methylnaphthalene-d10 [ ] ,8-Dimethylnaphthalene-d12 [ ] Phenanthrene-d10 [ ] Pyrene-d10 [ ] Biphenyl-d10 [ ] Chrysene-d12 [ ] ,2 -Binaphthyl-d14 [ ] Petroleum Chiron No. Methyldibenzothiophenes CAS No Fluorodibenzothiophene, F-PAS [ ] Dibenzothiophene-d8 [ ] Chiron No. Aromatic Biomarkers CAS No d3 C21 Monoaromatic sterane [ ] d3 C28/C29 Monoaromatic sterane d2 C20 Triaromatic sterane [ ] d2 C27/C28 Triaromatic sterane [-/ ] d2 C28 Triaromatic sterane [ ] 169

172 Internal standard cocktails S-4009-ASS-I Routine Biomarker Internal Standard Cocktail 1 S-4009-ASS-5I 7 Analytes, each concentration as listed in isooctane; units: 10x1mL, 1x5mL, 5x5mL Please inquire for other quantities. Chiron No. Name CAS No. Conc n-dodecane-d26 [ ] 1000 µg/ml n-exadecane-d34 [ ] 1000 µg/ml d2 C27 Cholestane [ ] 50 µg/ml Naphthalene-d8 [ ] 100 µg/ml Phenanthrene-d10 [ ] 100 µg/ml Dibenzothiophene-d8 [ ] 100 µg/ml d2 C28 Triaromatic Sterane [ ] 25 µg/ml S-4079-ASS-I Routine Biomarker Internal Standard Cocktail 3 S-4079-ASS-5I 7 Analytes, each concentration as listed in isooctane; units: 10x1mL, 1x5mL, 5x5mL Please inquire for other quantities. Chiron No. Name CAS No. Conc n-dodecane-d26 [ ] 2000 µg/ml n-exadecane-d34 [ ] 2000 µg/ml β()-Cholane [ ] 12 µg/ml Naphthalene-d8 [ ] 24 µg/ml Biphenyl-d10 [ ] 24 µg/ml Phenanthrene-d10 [ ] 24 µg/ml Chrysene-d12 [ ] 24 µg/ml S-4121-ASS-I Routine Biomarker Internal Standard Cocktail 4 S-4121-ASS-5I 7 Analytes, each concentration as listed in isooctane; units: 10x1mL, 1x5mL, 5x5mL Please inquire for other quantities. Chiron No. Name CAS No. Conc n-dodecane-d26 [ ] 2000 µg/ml n-exadecane-d34 [ ] 2000 µg/ml β()-Cholane [ ] 12 µg/ml Fluoronaphthalene, F-PA [ ] 24 µg/ml Fluorobiphenyl, F-PA [ ] 24 µg/ml Fluorophenanthrene, F-PA [ ] 24 µg/ml Fluorochrysene, F-PA 24 µg/ml S-4253-ASS-I Routine Biomarker Internal Standard Cocktail 5 S-4253-ASS-5I 9 Analytes, each concentration as listed in isooctane; units: 10x1mL, 1x5mL, 5x5mL Please inquire for other quantities. Chiron No. Name CAS No. Conc n-dodecane-d26 [ ] 2000 µg/ml n-exadecane-d34 [ ] 2000 µg/ml β()-Cholane [ ] 12 µg/ml Fluoronaphthalene, F-PA [ ] 24 µg/ml Fluorobiphenyl, F-PA [ ] 24 µg/ml 170

173 Fluorophenanthrene, F-PA [ ] 24 µg/ml Fluorochrysene, F-PA 24 µg/ml Fluorodibenzothiophene, F-PAS [ ] 24 µg/ml d2 C28 Triaromatic Sterane [ ] 12 µg/ml Asphaltene precipitation Chiron offers technical services and expertise: N N N N ASP Isolation and purification of asphaltene standards Separation by chromatography Asphaltene derivatization Characterization The asphaltenes are the pentane/heptane insoluble components of the oil. Asphaltenes are complex mixtures of unknown components, usually highly aromatised, and of high molecular weight. The quantity and the composition of asphaltenes from different sources vary a lot. Better knowlegde of the asphaltenes is important due to their practical and economical impact for the petroleum industry. In most cases, the asphaltenes are not analysed, just weighed. For a more detailed asphaltene analysis, a number of methods can be applied. Asphaltenes can be separated into groups according to polarity by chromatography, and they can be derivatized to simplify analysis. Purified Asphaltenes is available on request. Bulk composition of deasphalthened oils or rock extracts by TLC-FID TLC-FID Petroleum S-4101-ASS-5DC Iatroscan Standard 1 3 Analytes, each concentration as listed in dichloromethane; units: 1x5mL, 5x5mL Chiron No. Name CAS No. Conc Phenanthrene [ ] 5 mg/15 ml Squalane [ ] 100 µl/15 ml Decanol [ ] 200 µl/15 ml S-4105-ASS-5DC Iatroscan Standard 2 3 Analytes, each concentration as listed in dichloromethane; units: 1x5mL, 5x5mL Chiron No. Name CAS No. Conc Phenanthrene [ ] 5 mg/15 ml Squalane [ ] 20 µl/15 ml Decanol [ ] 20 µl/15 ml 171

174 GC analysis of whole (depressurized) fluid and PINA standards WGC GC analysis of the whole fluid will provide the composition of the gasoline-range hydrocarbons. The oil is analysed by GC using a capillary column with a nonpolar stationary phase. Quantitative whole oil standards Procedural Requirements: S ML Whole il Light ydrocarbons C5-C8 by GC ydrocarbons C5-C8, Neat 1 ml, 28 components Relative ratio Chiron No. Name CAS No. (by weight): ,2-Dimethylbutane [ ] Cyclopentane [ ] ,3-Dimethylbutane [ ] Methylpentane [ ] Methylpentane [ ] n-exane [ ] ,2-Dimethylpentane [ ] Methylcyclopentane [ ] ,4-Dimethylpentane [ ] Benzene [ ] ,3-Dimethylpentane [ ] Cyclohexane [ ] Methylhexane [ ] ,3-Dimethylpentane [ ] ,1-Dimethylcyclopentane [ ] Methylhexane [ ] cis-1,3-dimethylcyclopentane [ ] trans-1,3-dimethylcyclopentane [ ] Ethylpentane [ ] trans-1,2-dimethylcyclopentane [ ] n-eptane [ ] cis-1,2-dimethylcyclopentane [ ] Methylcyclohexane [ ] Ethylcyclopentane [ ] Toluene [ ] n-ctane [ ] m-xylene [ ] p-xylene [ ] 2 For n-paraffin mixtures, see S-4135 (page 181) and pages For PINA mixtures, see pages

175 Quantitative control standards (for integration and response factor control) S-4011 Whole il Quantitative Control Standards Set (S-4012+S-4013) S-4012 Pristane/n-eptadecane Control Standard Pristane/n-eptadecane = 1:2 (1000µg Pristane and 2000µg n-eptadecane in 1 ml isooctane) S-4013 Benzene/n-exane Control Standard Benzene/n-exane = 1:2 (Neat 1 ml) Qualitative control standards (baseline separation control) S-4014 Whole il Separation Control Set (S S S-4012) Neat mixtures (0.25 ml) of the Control mixtures 1-3, 1 ml solution of the Control mixture 4 in isooctane solution S-4015 Whole il Control Mixture 1 Relative ratios Chiron No. Name CAS No. by weight: ,2-Dimethylpentane [ ] Methylcyclopentane [ ] ,4-Dimethylpentane [ ] 0.5 S-4016 Whole il Control Mixture 2 Relative ratios Chiron No. Name CAS No. by weight: Benzene [ ] ,3-Dimethylpentane [ ] Cyclohexane [ ] 1.5 Petroleum S-4017 Whole il Control Mixture 3 Relative ratios Chiron No. Name CAS No. by weight: Methylhexane [ ] ,3-Dimethylpentane [ ] ,1-Dimethylcyclopentane [ ] Methylhexane [ ] ,3-cis-Dimethylcyclopentane [ ] ,3-trans-Dimethylcyclopentane [ ] ,2-trans-Dimethylcyclopentane [ ] ,2-cis-Dimethylcyclopentane [ ] 0.2 S-4012 Whole il Control Mixture µg Pristane and 2000µg n-eptadecane in 1 ml isooctane 173

176 GC analysis of the saturated hydrocarbon fraction SAT GC General The GC analysis will provide quantitative information on the molecular composition of the saturated hydrocarbon fraction. Control Standards are available for baseline separation and integration control of the following parameters: Pristane/n-C17 (Integration and baseline separation control) n-c15/n-c20 (Integration control) n-c30/n-c20 (Integration control) n-c17/(n-c17+n-c27) (Integration control) Quantitative control standards (for integration control) S-4019-ASS-I Saturated Fraction GC Control Set (S S-4020) S-4012-ASS-I Pristane/n-eptadecane (Integration and baseline control) 1000µg Pristane and 2000µg n-eptadecane in 1 ml isooctane Pristane/n-eptadecane = 1:2 S-4020-ASS-I n-c15/n-c20, Pentadecane/Eicosane (Integration control) 1500 µg Pentadecane and 1000 µg Eicosane in 1 ml isooctane n-pentadecane/n-eicosane = 3:2 S-4021-ASS-I n-c30/n-c20, n-triacontane/n-eicosane (Integration control) 1000 µg n-triacontane and 2000 µg n-eicosane in 1 ml isooctane n-triacontane/n-eicosane = 1:2 S-4022-ASS-I n-c17/(n-c17 + n-c27) (Integration control) 2000 µg µg in isooctane solution in 1 ml isooctane n-eptadecane/n-eptacosane = 4:1 S-4023-ASS-I Saturated Fraction Integration and Separation Control Standard 6 Analytes, each concentration as listed in isooctane; unit: 1x1mL. Chiron No. Name CAS No. Conc. (mg/ml) n-pentadecane (n-c15) [ ] n-eptadecane (n-c17) [ ] Pristane [ ] n-eicosane (n-c20) [ ] n-eptacosane (n-c27) [ ] 0, n-triacontane (n-c30) [ ] 0,3 174

177 S-4024-SET CPI (1) Control Standards Set S-4025 (mg/ml) S-4026 (mg/ml) S-4027 (mg/ml) C C C C C C C C C CPI (1): CPI (1) = 2(C23 + C25 + C27 + C29) / [C22 + 2(C24+C26+C28) + C30] CPI (1) values significantly above or below (unusual) 1.0 indicate that the oil or extract is immature. Values of 1.0 suggest that the oil or extract is mature. Ref: The Biomarker Guide. GC analysis of the aromatic fraction AR GC The GC analysis will provide a fingerprint of the hydrocarbon fraction. Molecular ratios are provided from the GC-MS data. To be analysed, the aromatic fraction is obtained by liquid chromatography of deasphalthened oil or EM. Single component standards available for GC-FID/GC-FPD of the aromatic fraction: C2-C4 Naphthalenes: C2 All possible isomers available C3 16 Isomers available C4 4 Isomers available: 2-Butylnaphthalene Eudalene 0737,14 1,4,6,7-Tetramethylnaphthalene ,2,5,6-Tetramethylnaphthalene Petroleum C0-C4 Phenanthrenes C0-C2 All possible C0-C2 isomers are available C3 9 Trimethyl and ethylmethyl isomers available C4 Five isomers available including: Retene Butylphenanthrene ,2,6,9-Tetramethylphenanthrene C0-C4 Dibenzothiophenes C0-C1 C2 C3 C4 All isomers available 11 Dimethyl- and ethyldibenzothiophenes 8 Trimethyl- and propyldibenzothiophenes 2- and 4-Butyldibenzothiophene 175

178 GC-MS analysis of oil, EM or saturated hydrocarbon fraction SAT/EM GC-MS The purpose of the GC-MS analysis is to obtain quantitative information on the biomarker composition. It is recommended to monitor the following ions: m/z 177 Terpanes 191 Tri- and tetracyclic diterpanes, pentacyclic triterpanes 205 Pentacyclic hopanelike triterpanes, C Regular and rearranged steranes 218 Regular and rearranged steranes (mainly ββ) Methylsteranes (mainly αα) Methylsteranes (mainly ββ) 253 Monoaromatic steranes (not to be present) 259 Rearranged steranes (diasteranes) Available standards See the Compounds section for details, pages Quantitative NPD-standards NPD = Naphthalene Phenanthrene Dibenzothiophene S-4028-ASS-I Aromatic Fraction Peak eight Control Set (S S-4030) S-4029-ASS-I 1-Methylphenanthrene/Phenanthrene = 1:2 (0,67) µg/ml in isooctane, 1 ml pr. vial S-4030-ASS-I C20 Triaromatic sterane (0857,20)/ C26 Triaromatic sterane (0854,26) = 1:3 (0,33) µg/ml in isooctane, 1 ml pr. vial S-4032-ASS-I Methylphenanthrene Index Cocktail 5 Analytes, each concentration as listed in isooctane; unit: 1x1mL Relative ratios Chiron No. Name Cas.No by weight: Phenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] 1.0 MPI 1 = 1,5(2MP + 3MP) / (P + 1MP + 9MP) MPI 2 = 3(2MP) / (P + 1MP + 9MP) F 1 = (2MP + 3MP) / (2MP + 3MP + 9MP + 1MP) 176

179 S-4033-ASS-I Dibenzothiophene Cocktail 5 Analytes, each concentration as listed in isooctane; unit: 1x1mL Relative ratios Chiron No. Name CAS No. by weight: Dibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] 0.5 S-4034-ASS-I NPD* Cocktail 20 Analytes, each concentration as listed in isooctane; unit: 1x1mL Chiron No. Name CAS No. mg/ml in isooctane: Methylnaphthalene [ ] Methylnaphthalene [ ] ,3-Dimethylnaphthalene [ ] ,4-Dimethylnaphthalene [ ] ,5-Dimethylnaphthalene [ ] ,6-Dimethylnaphthalene [ ] ,7-Dimethylnaphthalene [ ] ,6-Dimethylnaphthalene [ ] ,7-Dimethylnaphthalene [ ] Biphenyl [ ] Phenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] Methylphenanthrene [ ] Dibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] Methyldibenzothiophene [ ] 0.1 Petroleum For other NDP Cocktails: See the Environmental section, pages S-4122-ASS-I NPD Internal Standard Cocktail 3 Analytes, each concentration as listed in isooctane; units: 1x1mL, 5x1mL, 10x1mL Chiron No. Name CAS No. Cons Fluoronaphthalene [ ] 1.0 mg/ml Fluorophenanthrene [ ] 0.5 mg/ml Fluorodibenzothiophene [ ] 0.25 mg/ml 177

180 Common NPD hydrocarbons in oil Naphthalenes/Phenanthrenes/Dibenzothiophenes, relative elution Chiron No.* Name CAS No. Label m/z K-I 2-Methylnaphthalene [ ] 2-MN K-I 1-Methylnaphthalene [ ] 1-MN K-I 2-Ethylnaphthalene [ ] 2-EN K-I 1-Ethylnaphthalene [ ] 1-EN K-I 2,6-Dimethylnaphthalene [ ] 2,6-DMN K-I 2,7-Dimethylnaphthalene [ ] 2,7-DMN K-I 1,3-Dimethylnaphthalene [ ] 1,3-DMN K-I 1,7-Dimethylnaphthalene [ ] 1,7-DMN K-I 1,6-Dimethylnaphthalene [ ] 1,6-DMN K-I 2,3-Dimethylnaphthalene [ ] 2,3-DMN K-I 1,4-Dimethylnaphthalene [ ] 1,4-DMN K-I 1,5-Dimethylnaphthalene [ ] 1,5-DMN K-I 1,2-Dimethylnaphthalene [ ] 1,2-DMN I 1,3,7-Trimethylnaphthalene [ ] 1,3,7-TMN 170 not available 1,3,6-Trimethylnaphthalene 1,3,6-TMN 170 not available 1,3,5-Trimethylnaphthalene 1,3,5-TMN I 1,4,6-Trimethylnaphthalene [ ] 1,4,6-TMN I 2,3,6-Trimethylnaphthalene [ ] 2,3,6-TMN 170 not available 1,6,7-Trimethylnaphthalene (=2,3,8) 1,6,7-TMN 170 not available 1,2,7-Trimethylnaphthalene 1,2,7-TMN I 1,2,6-Trimethylnaphthalene [ ] 1,2,6-TMN I 1,2,4-Trimethylnaphthalene [ ] 1,2,4-TMN I 1,2,5-Trimethylnaphthalene [ ] 1,2,5-TMN K-I Phenanthrene [ ] P K-I 3-Methylphenanthrene [ ] 3-MP K-I 2-Methylphenanthrene [ ] 2-MP K-I 9-Methylphenanthrene [ ] 9-MP K-I 1-Methylphenanthrene [ ] 1-MP 192 not available 2-Ethylphenanthrene 2-EP K-I 9-Ethylphenanthrene [ ] 9-EP I 3,6-Dimethylphenanthrene [ ] 3,6-DMP 206 not available 1-Ethylphenanthrene 1-EP K-I 2,6-Dimethylphenanthrene [ ] / 2,6-DMP 206 [ ] K-I 2,7-Dimethylphenanthrene [ ]/ 2,7-DMP 206 [ ]/ [ ] K-I 3,5-Dimethylphenanthrene [ ] / 3,5-DMP [ ] m/z I 1,3-Dimethylphenanthrene [ ] 1,3-DMP K-I 2,10-Dimethylphenanthrene [ ] / 2,10-DMP 142 [ ] I 3,9-Dimethylphenanthrene [ ] 3,9-DMP I 3,10-Dimethylphenanthrene [ ] 3,10-DMP I 1,6-Dimethylphenanthrene [ ] 1,6-DMP K-I 2,5-Dimethylphenanthrene [ ]/ 2,5-DMP 156 [ ] / [ ] K-I 2,9-Dimethylphenanthrene [ ] / 2,9-DMP 156 [ ] 178

181 K-I 1,7-Dimethylphenanthrene [ ]/ 1,7-DMP 156 [ ] K-I 2,3-Dimethylphenanthrene [ ]/ 2,3-DMP 156 [ ] I 1,9-Dimethylphenanthrene [ ] 1,9-DMP K-I 4,9-Dimethylphenanthrene [ ] / 4,9-DMP 156 [ ] K-I 4,10-Dimethylphenanthrene [ ]/ 4,10-DMP 156 [ ] I 1,8-Dimethylphenanthrene [ ] 1,8-DMP I Retene [ ] Retene I Dibenzothiophene [ ] DBT I 4-Methyldibenzothiophene [ ] 4-MDBT MG 3-Methyldibenzothiophene [ ] 3-MDBT I 2-Methyldibenzothiophene [ ] 2-MDBT T 1-Methyldibenzothiophene [ ] 1-MDBT 170 *Ref. the compounds section for details. Ring C monoaromatic steroid hydrocarbons, m/z 253 Chiron No. Name Isomer CAS No I C21 Monoaromatic sterane 5α(),10β() [ ] / [ ] I C21 Monoaromatic sterane 5α(),10β() [ ] / [ ] I C27 Monoaroamtic sterane 5α(),10β() [ ] / [ ] I C27 Monoaromatic sterane 5α(),10β() [ ] / [ ] I C28 Monoaromatic sterane 5α(),10β() [ ] / [ ] / [ ] / [ ] I C28 Monoaromatic sterane 5α(),10β() [ ]/ [ ]/ [ ]/ [ ] I C29 Monoaromatic sterane 5α(),10β() [ ] / [ ] I C29 Monoaromatic sterane 5α(),10β() [ ] / [ ] Petroleum Ring ABC triaromatic steroid hydrocarbons, m/z 231 Chiron No. Name CAS No C20 Triaromatic sterane [ ] C26 Triaromatic sterane [ ] C27 Triaromatic sterane [ ] / [ ] C28 Triaromatic sterane [ ] 179

182 Gas-chromatography isotope-ratio mass-spectrometry (GC-IRMS) analysis GC-IRMS Cf. Pages 222 and References NIGGA 4, 2000 The Norwegian Industry Guide to rganic Geochemical Analysis, The Biomarker Guide, Volume 1 and 2, Peters, K.E., Walters C.C., and Moldowan, J.M. Cambridge University Press Petroleum analysis and petroleum products ur petroleum standards are listed according to applications, in most cases with a reference to proposed international methods. A complete list of individual compounds is found in the Compounds section, page 223 and onward. Custom made creative solutions from any of the individual components are available on request and demand. Please inquire by fax or and state the requred analytes, concentrations and solvent(s). PINA, PNA, PNA analysis The application of the mixtures is in the petrochemical industry for the quantitative and qualitative determination for components of complex mixtures of hydrocarbons. The mixtures are used to determine retention times, indices, and monitor response factors of crude petroleum and refinery streams. The PINA mixtures are made for a complete analysis of paraffins, isoparaffins, olefines, naphthenes, and aromatics in petroleum. P Paraffins (n-paraffins, n-alkanes) I Isoparaffins (branched alkanes) lefines (alkenes, paraffins with one or several double bonds) N Naphthenes (saturated ring compounds, usually with alkyl substituents) A Aromatics (simple aromatics and alkyl substituted aromatics) Whole oil quantitative standards, PINA MIXTURES S-4127 PINA Mixture 1, C5-C n-paraffins, isoparaffins, olefins, naphthenes and aromatics This standard is composed of the PINA mixtures listed below (S-4135, S-4136, S-4137, S and S-4156). 180

183 Approximate weight percentage: n-paraffins 19% Isoparaffins 19% lefins 18% Naphthenes 20% Aromatics 23% The standard is supplied with a datasheet listing the weight % for each component in the formulation. The composition, as stated on the analytical certificate, may vary slightly from batch to batch. Cost-effective PINA-sets for routine applications are available on request. n-paraffins S ML S ML PINA Mixture 1 - Paraffines 11 n-paraffins with varying Wt% as listed below; units: 0.1mL, 0.5 ml neat. Chiron No. Name: Wt.% Chiron No. Name: Wt.% n-pentane n-undecane n-exane n-dodecane n-eptane n-tridecane n-ctane n-tetradecane n-nonane n-pentadecane n-decane 8 Isoparaffins S ML S ML A number of other n-alkane standards are supplied as specified below, page 186. PINA Mixture 1 - Isoparaffines 37 Isoparaffins with varying Wt.% as listed below; units: 0.1 ml, 0.5 ml neat. Chiron No. Name: Wt.% Chiron No. Name: Wt.% I2-Methylbutane Methylheptane ,3-Dimethylbutane Ethylheptane Methylpentane ,5-Dimethylheptane Methylpentane ,5-Dimethylheptane (D) ,2-Dimethylpentane ,3-Dimethylheptane ,4-Dimethylpentane ,5-Dimethylheptane (L) ,2,3-Trimethylbutane ,3-Dimethylheptane ,3-Dimethylpentane ,4-Dimethylheptane (D) Methylhexane ,4-Dimethylheptane (L) ,3-Dimethylpentane Methyloctane Methylhexane Methyloctane Ethylpentane ,3-Diethylpentane ,2-Dimethylhexane ,2-Dimethyloctane ,5-Dimethylhexane ,3-Dimethyloctane ,2,3-Trimethylpentane ,3-Dimethyloctane ,4-Dimethylhexane Methylnonane ,3-Dimethylhexane Ethyloctane Methylheptane Methylnonane Methylheptane 3.4 Petroleum A number of other n-alkane/isoalkane standards are supplied as specified below, page

184 lefins S ML S ML PINA Mixture 1 - lefins 25 lefins with varying Wt.% as listed below; units: 0.1 ml, 0.5 ml neat Chiron No. Name: Wt.% Chiron No. Name: Wt.% Methyl-1-butene cis-3-eptene Pentene trans-2-eptene Methyl-1-butene cis-2-eptene Methyl-1,3-butadiene ctene trans-2-pentene trans-2-ctene cis-2-pentene cis-2-ctene Methyl-1-pentene Nonene exene trans-3-nonene trans-2-exene cis-3-nonene Methyl-2-pentene trans-2-nonene cis-2-exene cis-2-nonene eptene Decene trans-3-eptene 2.5 A number of other olefin standards are supplied according to ASTM methods specified below and in the Methods section, page 45 and onward. Naphthenes S ML S ML PINA Mixture 1 - Naphthenes 30 Naphthenes with varying Wt.% as listed below; units: 0.1 ml, 0.5 ml neat Chiron No. Name: Wt.% Chiron No. Name: Wt.% Cyclopentane ccc-1,2,3-trimethylcyclopentane Methylcyclopentane Isopropylcyclopentane Cyclohexane cis-1,2-dimethylcyclohexane ,1-Dimethylcyclopentane n-propylcyclopentane cis-1,3-dimethylcyclopentane ccc-1,3,5-trimethylcyclohexane trans-1,2-dimethylcyclopentane ,1,4-Trimethylcyclohexane trans-1,3-dimethylcyclopentane ctt-1,2,4-trimethylcyclohexane Methylcyclohexane ctc-1,2,4-trimethylcyclohexane Ethylcyclopentane ,1,2-Trimethylcyclohexane ctc-1,2,3-trimethylcyclopentane Isobutylcyclopentane cct-1,2,4-trimethylcyclopentane Isopropylcyclohexane ctc-1,2,4-trimethylcyclopentane n-butylcyclopentane trans-1,4-dimethylcyclohexane Isobutylcyclohexane Ethyl-1-methylcyclopentane t-1-methyl-2-propylcyclohexane trans-1,2-dimethylcyclohexane t-1-methyl-2-(4mp)cyclopentane 2.5 A number of other naphthene standards are specified below or supplied according to ASTM methods specified below and in the Methods section, page 45 and onward. 182

185 Aromatics S ML S ML PINA Mixture 1 - Aromatics 37 Aromatics with varying Wt.% as listed below; units: 0.1 ml, 0.5 ml neat Chiron No. Name: Wt.% Chiron No. Name: Wt.% Benzene Ethylbenzene Toluene m-xylene o-xylene p-xylene Isopropylbenzene n-butylbenzene n-propylbenzene ,2-Diethylbenzene Methyl-3-ethylbenzene Methyl-2-n-propylbenzene Methyl-4-ethylbenzene ,4-Dimethyl-2-ethylbenzene ,3,5-Trimethylbenzene ,3-Dimethyl-5-ethylbenzene Methyl-2-ethylbenzene ,2-Dimethyl-4-ethylbenzene ,2,4-Trimethylbenzene ,3-Dimethyl-2-ethylbenzene tert-butylbenzene ,2-Dimethyl-3-ethylbenzene Isobutylbenzene ,2,4,5-Tetramethylbenzene sec-butylbenzene Methylbutylbenzene Methyl-3-isopropylbenzene n-pentylbenzene Methyl-4-isopropylbenzene t-1-butyl-3,5-dimethylbenzene Methyl-2-isopropylbenzene t-1-butyl-4-ethylbenzene Methyl-3-n-propylbenzene ,3,5-Triethylbenzene Methyl-4-n-propylbenzene ,2,4-Triethylbenzene n-exylbenzene 4.7 S ML A number of other aromatic standards are specified below or supplied according to ASTM methods specified below and in the Methods section, page 45 and onward. PINA Mixture 2, C5-C8 (See also Whole il Light ydrocarbons C5-C8 by GC, S-4018 Quantitative Whole il Standard, page 172) ydrocarbons C5-C8, Neat 1 ml, 28 n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. For a detailed composition, see page 172. Approximate weight percentage: n-paraffins 28 % Isoparaffins 33 % Naphthenes 23 % Aromatics 16 % Petroleum The standard is a custom made mixture for the analysis of light hydrocarbons. The standard is supplied with a datasheet listing the weight% for each component in the formulation. 183

186 S ML PINA Mixture 3, C5-C25 ydrocarbons C5-C25, 1 ml neat, n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Prod.no. Compound CAS no. Purity Weight % Isopentane [ ] 99+% n-pentane [ ] 99+% Cyclopentane [ ] 99 % ,3-Dimethylbutane [ ] 99 % Methylpentane [ ] 99+% Methylpentane [ ] 99+% n-exane [ ] 99 % ,2-Dimethylpentane [ ] 99.9 % Methylcyclopentane [ ] 99 % ,4-Dimethylpentane [ ] 99 % Benzene [ ] 99.9 % Cyclohexane [ ] 99.5 % Methylhexane [ ] 98 % ,3-Dimethylpentane [ ] 99 % ,1-Dimethylcyclopentane [ ] 99 % Methylhexane [ ] 99 % ,3-cis-Dimethylcyclopentane [ ] 99.8 % ,3-trans-Dimethylcyclopentane [ ] 99 % Ethylpentane [ ] 98 % ,2,4-Trimethylpentane [ ] 99.5 % n-eptane [ ] 99 % Methylcyclohexane [ ] 99 % Ethylcyclopentane [ ] 99.7 % Toluene [ ] 99.5 % Methylheptane [ ] 99 % n-ctane [ ] 99 % Ethylcyclohexane [ ] 99 % ,6-Dimethylheptane [ ] 99 % ,1,3-Trimethylcyclohexane [ ] 99 % Ethylbenzene [ ] 99 % m-xylene [ ] 99 % p-xylene [ ] 99 % Methyloctane [ ] 99 % o-xylene [ ] 99 % n-nonane [ ] 99 % Propylbenzene [ ] 98 % Ethyl-3-methylbenzene [ ] 99 % Ethyl-4-methylbenzene [ ] 99 % ,3,5-Trimethylbenzene [ ] 98+% ,2,4-Trimethylbenzene [ ] 98 % n-decane [ ] 99 % ,2,3-Trimethylbenzene [ ] 99 % n-undecane [ ] 99 % 5.01 Approximate weight percentage: n-paraffins 50 % Isoparaffins 23 % Naphthenes 13 % Aromatics 14 % 184

187 The standard is a custom made mixture for the analysis of whole oil hydrocarbons. This standard is supplied with a datasheet listing the molecular weights, the densities, the purity of each component (normally 99+%), and the relative retention times on a Varian CP-Sil PNA CB column. PINA Mixture 4 S MG ydrocarbon Test Mixture, ASTM D Analytes with varying Wt% as listed below; unit: 500 mg neat Chiron No. Name Wt.% Chiron No. Name Wt.% Cyclopentane n-decane n-pentane n-undecane Cyclohexane n-dodecane ,3-Dimethylbutane Benzene n-exane Toluene exene trans-decahydronaphthalene Methylcyclohexane n-tetradecane Methyl-1-hexene Ethylbenzene n-eptane o-xylene cis-1,2-dimethylcyclohexane n-propylbenzene Isooctane ,2,4-Trimethylbenzene n-ctane ,2,3-Trimethylbenzene cis,2cis,4-Trimethylcyclohexane ,2,4,5-Tetramethylbenzene n-nonane Pentamethylbenzene 5.0 S ML Calibration Standard ASTM D Analytes, each Wt.% as listed; units: 1x1mL, 5x1 ml neat This standard can be used for qualitative and quantitative analysis. Petroleum Chiron No. Name Wt.% Chiron No. Name Wt.% Methylbutane p-xylene n-pentane n-propylbenzene Methylpentane n-decane n-exane n-butylbenzene ,4-Dimethylpentane n-dodecane n-eptane n-tridecane Toluene n-tetradecane n-ctane n-pentadecane

188 ther n-paraffins mixes ydrocarbon analysis Chiron offers different paraffin mixtures specially made to suit our customers requirements. Different variations are possible. Please inquire by fax or by . In addition to the neat mixture S-4136 above, the following solutions and neat mixtures are available: S-4066-K-I n-alkanes C14-C32 (even + pristane/phytane) 12 Analytes, each 1000 µg/ml in isooctane; units: 1x1mL, 5x1mL, 10x1mL This standard includes all the even n-paraffins + pristane and phytane. S CY n-alkanes C10-C40 (even) 12 Analytes, each 100µg/ml in cyclohexane; units: 1x1mL, 5x1mL, 10x1mL This standard includes all the even n-paraffins. S CY n-alkanes C10-C40 (even + pristane/phytane) 18 Analytes, each 100µg/ml in cyclohexane; units: 1x1mL, 5x1mL, 10x1mL This standard includes all the even n-paraffins + pristane and phytane. S CY n-alkanes C10-C40 (even and uneven) 31 Analytes, each 100µg/mL in cyclohexane; units: 1x1mL, 5x1mL, 10x1mL This standard includes all the n-paraffins C10-C40. S CY n-alkanes C10-C40 (all +pristane/phytane) 33 Analytes, each 100µg/mL in cyclohexane; units: 1x1mL, 5x1mL, 10x1mL This standard includes all the n-paraffins C10-C40 + pristane and phytane. S-4348-K-I n-alkanes C20-C34, all even + pristane/phytane, 10 Analytes, each 1000µg/mL in isooctane; units: 1x1mL, 5x1mL S K-CY n-alkanes C10-C36 (C10,12,16,20,24,25,28,32,34,35,36), 11 Analytes, each 2000µg/mL in cyclohexane; unit: 1x1mL S CY n-alkanes C8-C26, all even and uneven, 19 analytes, each 100µg/mL in cyclohexane; unit: 1x10mL screw cap bottle S I S-4435-K-I n-alkanes C10-C25, all even and uneven, 11 analytes, each 100µg/mL or 1000µg/mL in isooctane; units: 1x1mL, 5x1mL, 10x1mL S K-DC Deuterated n-alkane Mixture 2 (C8,12,16,36), 4 analytes, each 5000µg/mL in dichloromethane; unit: 1x10mL screw cap bottle S-4437-K-I Deuterated n-alkane Mixture 3 (C12,16,20,24,30,32,36), 7 analytes, each 1000µg/mL in isooctane; unit: 1x1mL 186

189 S DC S DC n-alkanes C10-C40 (even + some uneven) 24 Analytes, each 100µg/mL in dichloromethane; units: 1x5mL, 1x10mL in screw-capped bottle. This standard includes all the even n-paraffins C10-C40 + extra addition of some uneven n-paraffins C10-C40. C10 C17 C22 C27 C36 C12 C18 C23 C28 C40 C14 C19 C24 C30 Pristane C15 C20 C25 C32 Phytane C16 C21 C26 C34 S PE S PE S CY S CY IS Standard Mixture of n-alkanes C10-C40 (all even) Determination of ydrocarbon il in Water Index 16 Analytes, each 50 µg/ml in n-pentane; units: 1x1mL, 1x5 ml, 10x1mL This standard is also available as 100µg/mL in Cyclohexane Units: 1x1mL, 1x5 ml, 10x1mL S PE S PE S X S X S PE S PE IS Standard Mixture of n-alkanes C20-C40 (all even) Determination of ydrocarbon il in Water Index 11 Analytes, each 50µg/mL in n-pentane; units: 1x1mL, 1x5mL, 10x1mL This standard is also available as 50µg/mL in n-hexane; units 1x1mL, 1x5mL, 10x1mL Use this standard for system performance evaluation. IS Mod Standard Mixture of n-alkanes + BTEX II C7+C8+C9+C10+C20+C40+BTEX in n-pentane Determination of ydrocarbon il in Water Index 10 Analytes, each 50 µg/ml in n-pentane; units: 1x1mL, 1x5 ml, 10x1mL Chiron No. Name Chiron No. Name Benzene B n-eptane C Toluene T n-ctane C Ethylbenzene E n-nonane C o-xylene o-x n-decane C m-xylene m-x n-eicosane C p-xylene p-x n-tetracontane C40 Petroleum S PE S PE IS Mod Standard Mixture of n-alkanes + BTEX III C7+C8+C9+C10-C40 (all even)+btex in n-pentane Determination of ydrocarbon il in Water Index 25 Analytes, each 50 µg/ml in n-pentane; units: 1x1mL, 1x5mL, 10x1mL Chiron No. Name Chiron No. Name Benzene B n-ctadecane C Toluene T n-eicosane C Ethylbenzene E n-docosane C o-xylene o-x n-tetracosane C m-xylene m-x n-exacosane C p-xylene p-x n-ctacosane C n-eptane C n-triacontane C30 187

190 n-ctane C n-dotriacontane C n-nonane C n-tetratriacontane C n-decane C n-exatriacontane C n-dodecane C n-ctatriacontane C n-tetradecane C n-tetracontane C n-exanedecane C16 S MG Petrochemical Calibration Mixture C6-C44, ASTM D 2887 and D 6352 S G 18 Analytes, each 6.25 Wt.% in carbon disulfide (CS2); units: 1x100mg, 1x1g neat. Use for determining column resolution as well as for quantitative analysis. Chiron No. Name Chiron No. Name n-exane C n-ctadecane C n-eptane C n-eicosane C n-ctane C n-tetracosane C n-nonane C n-ctacosane C n-decane C n-dotriacontane C n-undecane C n-exatriacontane C n-dodecane C n-tetracontane C n-tetradecane C n-tetratetracontane C n-exadecane C16 S MX ydrocarbon Window Defining Standard C8-C40, ASTM D-2887 and D 6352 S MX 35 Analytes, each 500 µg/ml in CS2:C2Cl2 (3:1); units: 1x1mL, 1x5mL Chiron No. Name Chiron No. Name ctane C Tetracosane C Nonane C Pentacosane C Decane C exacosane C Undecane C eptacosane C Dodecane C ctacosane C Tridecane C Nonacosane C Tetradecane C Triacontane C Pentadecane C n-entriacontane C exadecane C Dotriacontane C eptadecane C Tritriacontane C ctadecane C Tetratriacontane C Pristane C Pentatriacontane C Nonadecane C exatriacontane C Phytane C eptatriacontane C Eicosane C ctatriacontane C eneicosane C Nonatriacontane C Docosane C Tetracontane C Tricosane C23 Simulated distillation standard SIM DIS Simulated Distillation (SIM DIS) and Proposed Motor il Volatility Method. The standard can be used for normal temperature analytical requirements when generating boiling point versus retention time calibration curves. 188

191 S ML Stock SIM DIS Paraffin Solution (C5-C18) 14 Analytes, each Wt.% as listed; unit: 1x5 ml neat Chiron No. Name Wt.% Chiron No. Name Wt.% n-pentane n-dodecane n-exane n-tetradecane n-eptane n-pentadecane n-ctane n-exadecane n-nonane n-eptadecane n-decane n-ctadecane n-undecane n-eicosane 6.66 S CY Quantitative Linearity Wax Mixture C16-C44, ASTM D Analytes, each 0.01 Wt. % in Cyclohexane; units: 1x1mL, 5x1mL Chiron No. Name Chiron No. Name n-exadecane C n-ctacosane C n-ctadecane C n-triacontane C n-eicosane C n-dotriacontane C n-docosane C n-exatriacontane C n-tetracosane C n-tetracontane C n-exacosane C n-tetratetracontane C44 S MG Retention Time Wax Mixture C16-C44, ASTM D Analytes, each 8.3 Wt. %; unit: 1x500mg neat Use this standard to establish the retention times from C16 to C44. Chiron No. Name Chiron No. Name n-exadecane C n-ctacosane C n-ctadecane C n-triacontane C n-eicosane C n-dotriacontane C n-docosane C n-exatriacontane C n-tetracosane C n-tetracontane C n-exacosane C n-tetratetracontane C44 Petroleum ther isoparaffin mixtures 2-methyl, 3-methyl and 4-methylalkane mixtures S DC Methylhydrocarbons Mixture C5-C8 (+phytane/pristane) 13 Analytes, each 100 µg/ml in dichloromethane; unit: 1x4.5mL Certan bottle Chiron No. Compound CAS No Methylbutane [ ] Methylpentane [ ] Methylpentane [ ] Methylhexane [ ] Methylhexane [ ] Methylheptane [ ] 189

192 Methylheptane [ ] Methylheptane [ ] Methylcyclopentane [ ] Methylcyclohexane [ ] Methylcycloheptane [ ] Pristane [ ] Phytane [ ] ther naphthene mixtures S-4438-K-I Alkylcycloalkane Mixture 1 9 Analytes, each 1000µg/mL in isooctane; unit: 1x1.1mL Chiron No. Compound CAS.No n-exylcyclohexane [ ] n-eptylcyclohexane [ ] n-ctylcyclohexane [ ] n-nonylcyclohexane [ ] n-decylcyclohexane [ ] n-undecylcyclohexane [ ] n-dodecylcyclohexane [ ] n-tridecylcyclohexane [ ] n-tetradecylcyclohexane [ ] S-4439-K-I Alkylcycloalkane Mixture 2 5 Analytes, each 1000µg/mL in isooctane; unit: 1x1.1mL Chiron No. Compound CAS.No n-pentadecylcyclohexane [ ] n-exadecylcyclohexane [ ] n-eptadecylcyclohexane [ ] n-ctadecylcyclohexane [ ] n-nonadecylcyclohexane [ ] BTEX and other aromatics mixtures S ME S ME BTEX + BaP 6 Analytes, each 100µg/mL in methanol; units: 1x1mL, 1x50mL Chiron No. Compound CAS No Benzene [ ] Toluene [ ] Ethylbenzene [ ] m-xylene [ ] o-xylene [ ] Benzo[a]pyrene [ ] 190

193 S K-2ME BTX Mixture 1 5 Analytes, each 10mg/mL in methanol; unit: 1x2mL Chiron No. Compound CAS No Benzene [ ] Toluene [ ] o-xylene [ ] p-xylene [ ] m-xylene [ ] S-4257: BTX Mixture See the TP part in the Environmental section S-4218: BTX Mixture See the TP part in the Environmental section S-4219: BTX Mixture See the TP part in the Environmental section S CY BTEX Mixture 4 S CY 6 Analytes, each 200µg/mL in cyclohexane; units: 1x1mL, 1x10 ml Chiron No. Compound CAS No Benzene [ ] Toluene [ ] Ethylbenzene [ ] o-xylene [ ] p-xylene [ ] m-xylene [ ] S ME BTEX Mixture 5 5 Analytes, each 100µg/mL in methanol; unit: 1x5mL screw cap bottle Chiron No. Compound CAS No Benzene [ ] Toluene [ ] Ethylbenzene [ ] m-xylene [ ] o-xylene [ ] Petroleum S-4447-K-I n-alkylbenzene Mixture 16 Analytes, each 1000µg/mL in isooctane; unit: 1x1.1mL Chiron No. Compound CAS No n-butylbenzene [ ] n-pentylbenzene [ ] n-exylbenzene [ ] n-eptylbenzene [ ] n-ctylbenzene [ ] n-nonylbenzene [ ] n-decylbenzene [ ] n-undecylbenzene [ ] n-dodecylbenzene [ ] n-tridecylbenzene [ ] n-tetradecylbenzene [ ] n-pentadecylbenzene [ ] 191

194 n-exadecylbenzene [ ] n-eptadecylbenzene [ ] n-ctadecylbenzene [ ] n-nonadecylbenzene [ ] ther olefin mixtures S ML Calibration mixture for olefins, ASTM D Analytes, each Wt.% as listed; units: 1x1mL, 5x1mL neat Chiron No. Name Wt.% Chiron No. Name Wt.% Nonene Methyl-1,3-pentadiene Cyclohexene Methyl-1-butene exene Methyl-2-pentene ctene eptene Decene Methyl-1-octene Methyl-1,3-butadiene Methyl-1-heptene Methyl-1-pentene Methyl-1-hexene ,5-exadiene 3.0 -PNA oxygenates S-4184-K-DD Qualitative Standard MTBE, ASTM D Analytes, each 0.1 Wt.% in n-dodecane; unit: 1x1mL Methanol Acetone n-pentane Methylpentane trans-2-pentene Isobutylene sec-butyl methyl ether tert-butyl methyl ether n-butane ,4,4-Trimethyl-2-pentene tert-butanol Isopentane Ethyl tert-butyl ether ,3-Dimethyl-1-butene trans-2-butene ,4,4-Trimethyl-trans-2-pentene cis-2-pentene Propanol tert-amyl methyl ether Methyl-cis-2-pentene cis-2-butene ,3,4-Trimethyl-2-pentene Methyl-2-butene Pentene ,5-Dimethyl-1-hexene Methylpentane Methyl-1-butene Methyl-1-butene Cyclopentene Methyl ethyl ketone ,4,4-Trimethyl-1-pentene ,2,4,6,6-Pentamethyl-3-heptene S-4183-K-DD Quantitative Standard, ASTM D Analytes, each 0.1 Wt.% in n-dodecane; unit: 1x1mL Methanol ,3-Dimethyl-1-butene Methyl-1-butene Methyl-cis-2-pentene Acetone Methylpentane Isopentane Methyl ethyl ketone Propanol Methylpentane 192

195 Pentene sec-butyl methyl ether Methyl-1-butene Ethyl tert-butyl ether n-pentane tert-amyl methyl ether trans-2-pentene ,5-Dimethyl-1-hexene tert-butanol ,4,4-Trimethyl-1-pentene cis-2-pentene ,4,4-Trimethyl-2-pentene Methyl-2-butene ,4,4-Trimethyl-trans-2-pentene Cyclopentene ,3,4-Trimethyl-2-pentene Methyl tert-butyl ether ,2,4,6,6-Pentamethyl-3-heptene S ML Daily Quality Control Standard, ASTM D 5986 (without Internal Standard) 13 Analytes, each Wt.% as listed; units: 1x10mL, 5x10 ml neat Name: Wt. % Name: Wt. % n-exane Toluene n-eptane m-xylene n-ctane o-xylene n-decane Ethylbenzene n-dodecane ,2,4-Trimethylbenzene ,2,4,-Trimethylpentane ,2,4,5-Tetra-methylbenzene Benzene 1 S ML Validation mixture for oxygenates and PNA, ASTM D Analytes; units: 1x1mL, 5x1mL neat Use this standard to monitor and make adjustments to the total operation of the system. Name: Wt. % Name: Wt. % Cyclopentane Dimethylbutane n-pentane n-exane Cyclohexane exene Methyl-1-hexene Methylcyclohexane n-eptane n-tetradecane cis-1.2-dimethylcyclohexane Ethylbenzene trimethylpentane o-xylene n-ctane n-propylbenzene c,c,c-1,2, Trimethylbenzene 3.0 Trimethylcyclohexane Trimethylbenzene n-nonane Tetramethylbenzene n-decane Pentamethylbenzene n-undecane Ethanol n-dodecane tert-butanol Benzene MTBE (methyl tert-butyl ether) Toluene ETBE (ethyl tert-butyl ether) trans-decahydronaphtalene TAME (tert-amyl methyl ether) 5.0 Petroleum 193

196 S-4404-K-AN Phenone Mixture 9 Analytes, each 1000µg/mL in acetonitrile; unit: 1x1mL Chiron No. Compound CAS no Acetanilide [ ] Acetophenone [ ] Propiophenone [ ] n-butyrophenone [ ] Valerophenone [ ] exanophenone [ ] Benzophenone [ ] eptanophenone [ ] ctanophenone [ ] International methods For details see the Methods section, pages 13 and onward (IS) and 45 and onward (ASTM). - IS and the modified SPAR method: Determination of ydrocarbon il in Water Index - ASTM D a: Determination Boiling Range Distribution of Petroleum Fractions - ASTM D e1: Determination of Benzene and Toluene in Finished Motor and Aviation Gasolines by GC - ASTM D (2004) Determination of Boiling Range Distribution of Gasoline and Gasoline Fractions by GC - ASTM D Determination of Ethers and Alcohols in Gasolines by GC - ASTM D Determination of Aromatic Content & Polynuclear Aromatic Content by SFC -ASTM D (2002) Determination of Boiling Range Distribution - ASTM D (2003)e1 Determination of Purity of Methyl tert-butyl Ether by GC - ASTM D (2003)e1 Analysis of Petroleum Waxes - ASTM D Determination of PNA in Distillates - ASTM D Determination Aromatics in Gasoline - ASTM D Quantitative Determination of Total xygen in Gasoline and Methanol by Reductive Pyrolysis -ASTM D Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by GC-MS -ASTM D (2006) Quantitative Determination of xygenates, Benzene, Toluene, C8-C12 Aromatics and Total Aromatics -ASTM D (2003)e1 Quantitative Determination of -P - ASTM D (2003)e1 Quantitative determination of lefins - ASTM D e1 Determination of the Boiling Range Distribution of Petroleum Distillate Fractions by GC -ASTM D IP Aromatic ydrocarbon Types in Aviation Fuels and Petroleum Distillates by PLC Refractive Index -ASTM D Determination of lefin Content - ASTM D = IP Aromatic ydrocarbon Types in Diesel Fuels and Distillates by PLC Refractive Index. 194

197 Sulfur content determination verview of the Chiron sulfur calibration mixtures (S: Chiron Product No, D: ASTM-method) Matrix Light White Light White eavy White Isooctane Toluene Xylene Benzene Mineral Mineral il Mineral il Compound il (3 cst) (20cSt at 40 C) (70cSt at 40 C) S-4052 S-4051 S-4050 Request Di-n-butyl sulfide D 2622 D 2622 D 3120 D 5453 D 4294 D 4294 D 3246 D 4927 D 4927 D 4927 S-4053 S-4059 S-4057 Thiophene D 6313 D 1685 D 4735 S-4159 S-4055 S-4054 Dibenzothiophene S-4058 D 5453 D 5453 D 6428 Request Benzothiophene D 5453 S Bromothiophene D 5623 Petroleum S Chlorothiophene D 5623 S-4035 Diphenyl sulfide D 5623 Thiophene/ S Methylthiophene D

198 Sulfur calibration standards S-4050 Di-n-butyl sulfide in Isooctane S-4051 Di-n-butyl sulfide in eavy White Mineral il (70 cst at 40 C) S-4052 Di-n-butyl sulfide in Light White Mineral il (20 cst at 40 C) Unit: 10 ml screw cap bottle Chiron No. (Matrix) Concentration Isooctane Light White Mineral il eavy White Mineral il µgs/g Wt.% (20 cst at 40 C) (70 cst at 40 C) (ppm) S I S LW S W Blank 0 S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S LW S W S I S LW S W S I S LW S W S I S LW S W S I S LW S W S-4050-K-I S-4052-K-LW S-4051-K-W S K-I S K-LW S K-W S K-LW S K-W S K-I S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S K-LW S K-W S-4050-Kit S-4052-Kit S-4051-Kit Kit of above 196

199 S-4053 Thiophene in Toluene Units: 5x1mL ampoule, 1x10 ml screw cap bottle Chiron No. Concentration µgs/g (ppm) Wt.% S Blank 0 S-4053-K S K S K S K S K S K S K S K S K S-4053-Kit Kit of above S-4059 Thiophene in Thiophene-free Benzene (ASTM D ) Units: 1x1mL ampoule, 1x10mL screw cap bottle Chiron No. Concentration Light White Mineral il µg thiophene/g (20 cst at 40 C) (ppm) Wt.% S Blank 0 S S S S S-4059-Kit Kit of above solutions Petroleum S-4056 Thiophene/2-Methylthiophene (2:1) in isooctane/toluene(3:1); Units: 5x1mL ampoules, 1x10 ml screw cap bottle Chiron No. Concentration µgs/g (ppm) Wt.% S Blank 0 S S S S S S S S S S-4056-K S-4056-Kit Kit of above solutions 197

200 S-4055 Dibenzothiophene in Isooctane S-4054 Dibenzothiophene in Xylene S-4159 Dibenzothiophene in White il 3 cst Units: 5x1mL ampoule, 1x10mL screw cap bottle Chiron No. (Matrix) Concentration Isooctane Xylene White oil 3 cst µgs/g (ppm) Wt.% S I S XY S C Blank 0 S I S C S I S C S I S C S I S C S I S C S I S C S I S C S-4055-K-I S-4054-K-XY S-4159-K-3C S K-XY S K-3C S K-XY S K-XY S K-3C S K-XY S K-XY S K-XY S K-XY S-4055-Kit S-4054-Kit S-4159-Kit Kit of above solutions Internal standards for GC analysis S-4035 Diphenylsulfide in Isooctane S Bromothiophene in Isooctane S Chlorothiophene in Isooctane Units: 5x1mL ampoule, 1x10mL screw cap bottle Chiron No. Concentration Matrix: Isooctane Diphenyl sulfide 2-Bromothiophene 3-Chlorothiophene µgs/g (ppm) Wt.% S I S I S I Blank 0 S-4035-K-I S-4037-K-I S-4036-K-I S K-I S K-I S K-I S K-I S K-I S K-I Labelled standards for GC-MS analysis MG Thiophene-d4 0.5 g neat T Dibenzothiophene-d8 100 µg/ml in toluene K-I 2-Fluorodibenzothiophene 1000 µg/ml in isooctane 198

201 Standards by ASTM methods - ASTM D Standard Test Method for Traces of Thiophene in Benzene by Spectrophotometry - ASTM D Standard Test Method for Sulfur in Petroleum Products by X-Ray Spectrometry - ASTM D e1 Standard Test Method for Trace Quantities of Sulfur in Light Liquid Petroleum ydrocarbons by xidative Microcoulometry - ASTM D Standard Test Method for Sulfur in Petroleum by xidative Microcoulometry - ASTM D Standard Test method for Sulfur in Petroleum Products by Energy- Dispersive X-ray Fluorescence Spectroscopy - ASTM D Standard Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography - ASTM D Standard Test Method for Determination of Additive Elements in Lubricating ils by Inductively Coupled Plasma Atomic Emission Spectrometry -ASTM D Standard Test Method for Determination of Total Sulfur in Light ydrocarbons, Motor Fuels and ils Ultraviolet Fluorescence -ASTM D Standard Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas (2004)e1 Chromatography and Sulfur Selective Detection -ASTM D 5623 Sulfur Compounds Standard I and II, see below for details -ASTM D Standard Test Method for Total Sulfur in Aromatic Compounds by ydrogenolysis and Sulfur Specific Difference Photometry -ASTM D Standard Test Method for Total Sulphur in Napthenes, Distillates, Reformulated Gasolines, Diesels, Biodiesels, and Motor Fuels by xidative Combustion and Electrochemical Detection (Please inquire) ASTM D (2004)e1 S ML Sulfur Compounds Standard I 14 Analytes, approximately 7,14 % of each (by weight); unit:1x1ml neat Petroleum Chiron No. Compound Ethanediol Dimethyl disulphide Carbon disulphide Methyl-2-propanethiol Propanethiol Ethylmethyl sulfide Thiophene Methyl-1-propanethiol Diethyl sulfide Butanethiol Dimethyl disulfide Methylthiophene Methylthiophene Diethyl disulfide 199

202 S-4040-K-I Sulfur Compounds Standard II 7 Analytes, each 1000µg/mL in isooctane; unit:1x1ml Chiron No. Compound Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Diphenyl sulfide Special sulfur solutions S-4072 Sulfur Standard 1 Unit: 10 ml screw cap bottle Chiron No. Matrix: Methanol Compound Concentration S-4072 Diethyl sulfide 0.5 ppm (w/w) Di-n-butyl sulfide 0.5 ppm (w/w) S-4073 Sulfur Standard 2 Unit: 10 ml screw cap bottle Chiron No. Matrix: Methanol Compound Concentration S-4073 Di-n-propyl sulfide 0.5 ppm (w/w) Di-n-butyl sulfide 0.5 ppm (w/w) S-4078 Sulfur Calibration Standard Unit: 10 ml screw cap bottle or custom-made cylinders Chiron No. Matrix: Methanol Compound Concentration S-4078 Dimethyl sulfide 5 ppm (w/w) Methylethyl sulfide 5 ppm (w/w) Thiophene 5 ppm (w/w) 200

203 S I S I S I S I S I Chisulfmix/1C 10 Analytes, each in 5 different concentrations in isooctane as listed below; units: 5x10mL, one of each concentration Chiron No. Compound Isoamyl mercaptan exathiol ctanethiol Methyl propyl disulfide Diethyl disulfide Methylethyl sulfide Dipropyl sulfide Thiophene Methylthiophene Benzothiophene Concentration µgs/g (ppm) Wt.% S T igh Boiling Sulfur in Toluene for Diesel Fuel Analysis 1 50 ppm S in sulphur-free Toluene; unit: 1x5mL vials Benzo[b]naphtho[2,1-d]thiophene (0485,16) + Benzo[b]naphtho[2,3-d]thiophene (0484,16) (1:1) Petroleum S T igh Boiling Sulfur in White il for Diesel Fuel Analysis 2 50 ppm S in sulfur-free White il (20 cst); units: 1x5mL vials Benzo[b]naphtho[2,1-d]thiophene (0485,16) + Benzo[b]naphtho[2,3-d]thiophene (0484,16) (1:1) Custom prepared sulfur standard-mixtures Compound Matrix Select your preferred matrix (Solvent or white mineral oil with preferred viscosity) Select the analytes you prefer. Pick from the Chiron Sulfur Guide. Request alternative combinations to those given above. Please Specify: Concentration (e.g. ppms, mg/g or µg/ml) or set of concentration for calibration mixtures. Number of and size of vials Type of packaging (ampoules, bottles etc.) 201

204 Methods used for sulfur analysis Abbr. Method ASTM-method Application Chiron No. 1. GC Gas Chromatography and Sulfur D Light Petroleum S-4035 S-4040 Selective Detection (2004) e1 Gas Chromatography and D (2006) Natural Gas Please request Chemiluminescence Gas Chromatography and D 6228 Natural gas Please request Flame Photometric Detection Gas Chromatography D Thiophene in Benzene S GC-MS Coupled Gas Chromatography D il Spill Source S-4041, S-4042, Mass Spectrometry Indentification ICP-AES Inductively Coupled Plasma D Additives in Lubr. ils NIST SRM 1622 Atomic Emission Spectroscopy in white oil 4. xidative Microcoulometry D e1 Light Petroleum S-4052 ydrocarbons xidative Microcoulometry D Petroleum Gas S XRF Wavelength Dispersive X-Ray D Petroleum S-4050, S-4051, Fluorescence S-4056 Wavelength Dispersive X-Ray D Unused Lubricating Please request Fluorescence ils and Additives Wavelength Dispersive X-Ray D Unused Lubricating ils S-4050, S-4051, Fluorescence S-4052 Wavelength Dispersive X-Ray D (2003)e1 Gasoline Please request Fluorescence Spectroscopy 6. EDXRF Energy Dispersive X-Ray D Petroleum Products S-4050, S4051 Fluorescence Spectroscopy Energy Dispersive X-Ray D (2004)e1 Gasoline Please request Fluorescence Spectroscopy 7. Ultraviolet Flourescence D Light ydrocarbons, S-4055 Motor Fuels and ils 8. ydrogenolysis and Sulfur D Aromatic ydrocarbons S-4057 Specific Difference Photometry 9. Lamp Method D (2003)e1 Liquefied Petroleum Gas 10. General Bomb Method D (2005) Petroleum Products, Lubricating ils and Greases 11. Doctor Test D (2007) Mercaptans in Motor Fuels 12. igh-temperature method D Petroleum Products 13. Potentiometric method D a Mercaptan in Gasolines, Kerosines etc. 14. Spectrophotometry D Thiophene in Benzene S-4059, Request Nitrogen content determination ASTM D Standard Test Method for Trace Nitrogen in Liquid Petroleum ydrocarbons by Syringe/Inlet xidative Combustion and Chemiluminescence Detection. See the Methods section, page

205 S-4140 Nitrogen Calibration Set-Low Boiling Solvents Unit: 1x1 ml ampoules or 10 ml screw cap bottle Nitrogen introduced using Pyridine Chiron No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.3 S I 1.0 S I 10 S I 25 S I 50 S I 75 S I 100 S-4141 Nitrogen Calibration Set-igh Boiling Solvents Unit: 1x1mL ampoules or 10 ml screw cap bottle Nitrogen introduced using Carbazole Chiron No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.3 S I 1.0 S I 10 S I 25 S I 50 S I 75 S I 100 Petroleum S-4142 Low level Nitrogen Calibration Unit: 1x1mL ampoules or 10 ml screw cap bottle Nitrogen introduced using Aniline Chiron No. Concentration Matrix: isooctane mg/kg (ppm) S I Blank S I 0.5 S I 1.0 S I 2.0 S I 5.0 S I 10.0 S-4143 Low level Nitrogen & Sulfur Calibration Set Unit: 1x1mL ampoules or 10 ml screw cap bottle Nitrogen introduced using Aniline / Sulfur introduced using di-n-butyl Sulfide Chiron No. Concentration Matrix: Benzene mg/kg (ppm) S B Blank S B 0.25 S B 0.50 S B

206 Phosphorous standards Phosphorus in Light White Mineral il Tri-n-butylphosphate, 99+% (Chiron product nr ) CAS [ ] Matrix: Isooctane or Light White Mineral il, 20cSt Units: 1x25 ml, 1x100 ml Isooctane Light White Concentration Mineral il 20 cst ppm S I S LM Blanc S I S LM 1 S I S LM 2 S I S LM 3 S I S LM 5 S I S LM 10 S I S LM 20 S I S LM 30 S I S LM 50 S I S LM 75 S I S LM 100 S I S LM 200 S I S LM 250 S I S LM 300 S I S LM 400 S I S LM 500 S I S LM 750 S-4502-K-10I S-4503-K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S K-10I S K-10LM S-4502-Kit S-4503-Kit Kit of above Also available in eavy White Mineral il, 70cSt (S-4504), cf. EN

207 rganophosphates Standards for ydraulic Fluid Analysis rganophosphates are extensively used in hydraulic fluids. Recent alarming reports have shown that organophosphates have neurotoxic effects. Chiron No. Name Abbr. CAS No Trimethylphosphate TMP Triethylphosphate Tripropylphosphate Triisobutylphosphate TiBP Tri-n-butylphosphate TnBP (TBP) Triphenylphosphate TPP Tolyldiphenylphosphate Tritolylphosphate (isomeric mixture) TTP Tri-o-tolylphosphate ToTP Tri-m-tolylphosphate TmTP Tri-p-tolylphosphate TpTP Phosphate Kit 1g neat or 1000 µg/ml in isooctane solution, 1.1 ml P P P Petroleum Petrochemical products Methanol, quality control standards S ME Methanol QC Reference Mixture I 4 Analytes, each 100 ppm dissolved in 99.9 % methanol; units: 1x10mL, 10x10mL Chiron No. Name Chiron No. Name Acetone Ethanol Butanone Isopropanol S ME Methanol QC Reference Mixture II 10 Analytes, each 200 ppm in 99.9 % methanol; units: 1x10mL, 5x10mL Chiron No. Name Chiron No. Name Methyl formate Pentanone Butanol eptanol Propanol Pentanol exanol Ethanol ctanol 205

208 S ME Methanol QC Reference Mixture III n-butyl sulfide, 0.5 ppm (weight S by weight) in 99.9 % methanol; units: 1x10mL, 5x10mL S ME Methanol QC Reference Mixture IV 11 Analytes, each 200 ppm in methanol (Spectrograde); unit: 10x10mL Chiron No. Name Chiron No. Name Methyl formate Pentanone Butanol eptanol Propanol Pentanol Butanol Ethanol exano exanone ctanol S ME Methanol QC Reference mixture V Trimethylamine, 50 ppb (weight by weight), in methanol; Unit: 10x10mL Xylene, analysis by GC S-4270 p-xylene Impurity Standard with Internal Standards ASTM D , see the Methods section, page 50. Units: 1x1mL, 5x1mL + ISTD Chiron No. Name Wt. % Name Wt. % n-pentane p-xylene n-ctane m-xylene Benzene o-xylene Toluene Cumene Ethylbenzene Propylbenzene n-undecane (ITSD) 0.5 g Benzene, Thiophene in benzene, see ASTM D , the Methods section, page 52. Biodiesel fuels Biodiesel is produced from vegetable oils, animal and fish fats and recycled grease from restaurants. Biodiesel is methyl esters of fatty acids and are used alone or blended with petroleum based fuels. New international standards test methods for biodiesel are EN 14078, EN 14103, EN and ASTM D The complete requirements of biodiesel fuels are given in EN These methods enable the quantitative determination of free and total glycerine by gas chromatography after silylation with MSTFA. Derivatizing agent Cat.no. Description Package Size ML N-methyl-N-trimethylsilyltrifluoroacetamide (MSTFA) 1 ml G N-methyl-N-trimethylsilyltrifluoroacetamide 5 g (MSTFA) 206

209 Internal standards Internal standards for EN and ASTM D 6584: ML 1,2,4-Butanetriol (Internal Standard No. 1) 1 ml K-10PY Internal Standard No. 1 stock solution 10 ml 1000µg/mL in dry pyridine ML 1,2,3-Tricaproylglycerol 1 ml (tricarpin, Internal Standard No. 2) K-10PY Internal Standard No. 2 stock solution 10 ml 1000µg/mL in dry pyridine K-10PY Internal Standard No. 2 stock solution 10 ml 8000µg/mL in dry pyridine Internal standards for EN 14103: K-30P Methyl heptadecanoate, EN ml 10 mg/ml in n-heptane Reference substances (EN 14105/ASTM D 6584) PY Glycerol stock solution 10 ml 500µg/mL in dry pyridine K-10PY 1-Monooleoylglycerol (monoolein) stock solution 10 ml 5000µg/mL in dry pyridine K-10PY 1,3-Dioleoylglycerol (diolein) stock solution 10 ml 5000µg/mL in dry pyridine K-10PY 1,2,3-Trioleoylglycerol (triolein) stock solution 10 ml 5000µg/mL each in dry pyridine S K-10PY Monoglycerides 10 ml 3 analytes, each 10 mg/ml in dry pyridine Petroleum Monopalmitoylglycerol (monopalmitin) [ ] Monostearoylglycerol (monostearin) [ ] Monooleoylglycerol (monoolein) [ ] S K-10PY Monoglycerides 4 analytes, each 10 mg/ml in dry pyridine; unit: 1x10 ml Monopalmitoylglycerol (monopalmitin) [ ] Monostearoylglycerol (monostearin) [ ] Monooleoylglycerol (monoolein) [ ] Monolinoylglycerol (monolinolein) [ ] Standard for EN S-4495-SET-10CY FAME as linoleic acid methyl ester (Chiron No ) 1, 2, 4, 6, and 10 g/l in cyclohexane; unit: 5x10mL 207

210 Standard for EN S AC FAME EN Reference Mixture (rape seed methyl esters) 13 analytes, each 100µg/mL in acetone; unit: 1x1mL Palmitic C Palmitolic C16: eptadecanoic C17 Internal standard Steraric C leic C18: Linoleic C18: Linolenic C18: Arachdic C Eicosenoic acid (11c) C20: Behenic C Erucic C22: Lignoceric C Nervonic C24:1 Calibration solutions S-4500-SET Calibration solutions (EN 14105) Calibration solution Syringe, µl µl of glycerol solution µl of monoolein solution µl of diolein solution µl of triolein solution µl of internal standard sol. No µl of internal standard sol. No S-4501-SET Calibration solutions (ASTM D 6584) Calibration solution Syringe, µl µl of glycerol solution µl of monoolein solution µl of diolein solution µl of triolein solution µl of internal standard sol. No µl of internal standard sol. No International methods: For details, see the Methods section, pages 45 and onward (ASTM) and 40 and onward (EN). - ASTM D Determination of Free and Total Glycerine in B-100 Biodiesel Methyl Esters by GC - EN 14078:2004 Determination of fatty acid methyl esters (FAME) in middle distillates by IR - EN 14103:2003 FAME for use in biofuels, diesel fuels - EN 14105:2003 Fatty Acid Methyl Esters (FAME) - Determination of free and total glycerol and mono-, di-, triglyceride contents (Reference method) - EN 14214:2003 Fatty acid methyl esters (FAME) for diesel engines - Requirements and test methods

211 Chapter III-3: Food safety Table of contents Contaminants in food Natural toxins Toxic compounds formed by food processing Food packaging contaminants Veterinary drug residues Environmental contaminants Food additives Aroma chemicals, taste and odors (aroma) Food colours Preservatives, antioxidants, sweeteners ther natural products in food Carotenoids Lipids and fatty acids Steroids, sterols Sterols in animal fats, milk fat and vegetable oils Stigmastadiene in vegetable oils/olive oils Food and Pharma 209

212 Contaminants in food The general food law: Regulation (EC) 178/2002 is The General Food Law (GFL) within EU and is laying out the general principles and requirements of the food law and European Food Safety Authority. Council regulation (EEC) N)315/93 of 8.Feb 2003 is laying down the Community procedures for contaminants in food. This regulation does not apply where more specific Community rules exits, such as for pesticides, veterinary drug residues etc. Food contaminants is defined as any substance not intentionally added to food which is present in food as a result of production, manufacture, processing preparation treatment, packing, packaging, transport or holding of such food as a result of environmental contamination Examples of contaminants regulated or to be regulated under 315/93: Mycotoxins: e.g. Aflatoxins, ochratoxin A, patulin, fusarium-toxins, ergot alkaloids Inherent plant toxins: Pyrrozolidine alkaloids, hydrocyanic acid, solanine etc. Processing/industrial contaminants: 3-MCPD (3-Monochloropropandiol), inorganic tin, PAs, acrylamide, furan, ethylcarbamate ther environmental contaminants: Dioxins, dioxin and nondioxin-like PCBs, PAs, BFRs, PFS, tributyltin, iodine eavy metals: Lead, cadmium, mercury, arsenic, methylmercury Nitrates Naturals toxins Mycotoxins Mycotoxins are toxins formed by microorganisms present in food, and should be avoided. Laws in Europa, USA and other regions of the world have strict regulations on the accepted mycotoxin content. For dioxins and aflatoxin M1 the approach to establish the decision limit can made according to Commission Decision 657/2002/EC. See also The following EU recommendations, regulations and decisions apply: Recommendation 2003/598/EC: Patulin in apple juice etc. Recommendation 2006/583/EC: Prevention and reduction of Fusarium toxins Regulation (EC) 1881/2006: Fusarium toxins in maize. Decision 657/2002/EC. For dioxins and aflatoxin M1 the approach to reporting of analytical results establishing the decision limit can made according to Commission Decision 657/2002/EC. See also For individual and mixtures of mycotoxins: See the Compounds section, page

213 Ergot alkaloids Available ergot alkaloids: ME Ergocornine [ ] MW µg/mL in methanol ME Ergocryptine [ ] MW µg/mL in methanol Please inquire for others Toxic pyrrolizidine alkaloids See the Compounds section, page 421. Please inquire if you do not find what you look for. New compounds are under preparation. Solanine MG Solanine, 95%, [ ] MW mg neat MG Solanidine, 98% [ ] MW mg neat Algae/shellfish toxins Please see the Compounds section for available algae toxins, page 423. ther toxic natural food ingredients Coumarin Coumarin is a natural compound with a pleasant vanilla-like sweet odour and is found in a wide variety of plants and plant tissues such as green tea and Chinese cinnamon. In living plants coumarin is mostly present as glycoside, but the coumarin is liberated by enzymes. Use of coumarin in a pure form is forbidden due to its toxicity (European Community Directive 88/388/ECC). In Chinese cinnamon, coumarin occur together with cinnamaldehyde and benzaldehyde, while in Ceylon cinnamon coumarin is replaced by eugenol K-ME Coumarin (1,2-Benzopyrone) [ ] MW µg/mL in methanol K-ME Coumarin-d4 (IS) [ ] MW µg/mL in methanol ML Cinnamaldehyde [ ] MW mL neat ML Benzaldehyde [ ] MW mL neat ML Eugenol [ ] MW mL neat KIT Coumarin kit, one of each, 5x1mL coumarin-d4 Food and Pharma 211

214 Toxic compounds formed by food processing 3-monochloropropandiol (3-MCPD) and chloroesters Chloropropandiols are formed during food processing. Bound 3-chloropropandiol (lipid chloro esters) is found in different foods K-ME 3-Chloro-1,2-propandiol [ ] MW µg/mL in methanol K-ME 3-Chloro-1,2-propane-d5-diol [ ] 1000µg/mL in methanol Esters: Please request Acrylamide G Acrylamide [ ] 1g ME Acrylamide-d5 [ ] 100µg/mL in methanol Furan Furan can be formed from carbohydrates, amino acids and ascorbic acid during food processing. The major precursor is reported to be ascorbic acid under thermal conditions (Maerck et al. J. Agric. Food Chem. 2006, 54, ) G Furan [ ] 1g ME Furan-d4 [ ] 100µg/mL in methanol Stigmastadienes Stigmastadienes are formed by the processing of olive and other vegetable oils. See below for stigmastadiene standards PAs in animal and vegetable fats and oils See IS method 15753: 2006, page 30. S T 15 Selected PAs in toluene S AN 15 Selected PAs in acetonitrile Food packaging contaminants Recycled fibres It has been shown that recycled fibres may contain considerable amounts of diisopropylnaphthalene, diisobutylphthalate and benzophenone. 2,3,5-Trimethylnaphthalene is applied as internal standard: MG DiBP (Diisobutyl phthalate) [ ] K-I DIPN (Diisopropylnaphthalene) [ ] ML Benzophenone [ ] I 2,3,5-Trimethylnaphthalene [ ] 212

215 Plasticizers, phthalates and adipates There are EU-regulations on the content of plasticizers in food as a result of food packaging. Despite of these regulations, high concentrations (with a mean over 200 ppm) of plasticizers have been found in the gaskets of lids of food-jars. ESB (epoxidized soybeen oil, please inquire) MG DEP (diethyl phthtate) [ ] MG DIDP (diisodecyl phthalate) [ ] MG DINP (diisononyl phthalate) [ ] MG DEA (diethylhexyl phthalate) [ ] For details on phthalates and adipates, see the Compounds section, pages Ethylhexanoic acid from jar lids 2-Ethylhexanoic acid (EA) is widely used in the technical sector as an intermediate for production of paint additives, thickening agent for fuels, stabilizers for silicones etc. 2-Ethylhexanoic acid, defined as an hazardous substance, have been found in baby food and fruit juices filled in glass bottles with twist-off lids K-ME 2-Ethylhexanoic acid [ ] MW µg/mL in methanol K-ME 2-Ethylhexanoic acid-d15 [ ] MW µg/mL in methanol Semicarbazide (SEM) Semicarbazide is a metabolite of nitrofurazone (agricultural drug forbidden in Europe) and formed from thermal breakdown of azodicarbonamide. The analysis is performed by transformation to 2-nitrobenzaldehyde G 2-Nitrobenzaldehyde [ ] MW g MG Semicarbazide, 98% [ ] MW mg MG Azodicarbonamide [ ] MW mg MG Nitrofurazone [ ] MW mg (5-Nitro-2-furfurylidene semicarbazone) Ethyl carbamate The World ealth rganisation (W) has officially labelled ethyl carbamate, a compound produced during yeast fermentation, as a Group 2A carcinogen, ranking it alongside other substances likely to cause cancer in humans mg Ethyl carbamate [ ] MW mg Food and Pharma ITX - Isopropylthioxanthone Italian authorities have detected baby milk cartons containing the chemical Isopropylthioxanthone (ITX). ITX is used in printing inks on milk and fruit juice cartons. ITX is a mixture of two isomers to which the US EPA has given a high hazard ranking for environmental effects. The 2-isomer is the dominant ingredient. The European Food Safety Authority (EFSA) has recently undertaken a risk assessment on ITX: K-I MG 2-Isopropylthioxanthone (99+%) [ ], 1000µg/mL in isooctane 10mg neat 213

216 K-I MG 4-Isopropylthioxanthone (99+%) [ ], 1000µg/mL in isooctane 10mg neat Internal standard I MG 1,3,4-d 3-2-Isopropylthioxanthone (98+%), 100 µg/ml, 1.1 ml in isooctane 10mg neat Veterinary drug residues Stilbenes - DES Antithyroid agents thiouracil Steroids boldenone, testosterone etc. Resorcilic acid lactones zearalenol etc. Cortico-steroids dexamethazone, prednisolone etc. Beta-antagonists clenbutenol Please inquire. Environmental contaminants PPs Dioxins, page 358. PFS, PFAs, pages PCBs, pages Pesticides, pages See the Environmental section, page 109 and onward, and the Compounds section, page 223 and onward. Regulation (EC) 333/2007 of 28 March 2007 is applicable to sampling and methods of analysis of metals, 3- MCPD and PA, and replaces former Commission Directives (2001/22/Ec, 2004/16/EC and 2005/10/EC. For dioxins and aflatoxin M1 the approach to establish the decision limit can made according to Commission Decision 657/2002/EC. See also 214

217 Food additives Aroma chemicals, taste and odors (aroma) ff-flavour compounds ME Skatole [ ] Faecal-like ME 2-Methylisoborneol [ ] Earthy, muddy ME (+/-)-Geosmin [ ] Earthy ME 2,4,6-Trichloroanisole [ ] Mouldy-like ME Methional [ ] Sunlight flavour in milk 6-trans-Nonenal Been-like flavour in milk powder cis-1,5-ctadien-3-one [ ] Metallic flavour in milk fat cta-3,5-dien-2-one ay-like in deap frozen peas ME Nootkatone [ ] Grapefruit note in orange juice ME Carvone [ ] Terpene note in orange juice ME 3-Methyl-2-buten-1-thiol [ ] Sunlight flavour in beer Thiazoles ME 2-Acetylthiazole [ ] Cereal, popcorn ME 2-Acetyl-2-thiazoline [ ] Popcorn ME Benzothiazole [ ] Quinoline, rubber ME 2-Isobutylthiazole [ ] Green, tomato, wine Pyrazines K-I 2-sec-Butyl-3-methoxypyrazine µg/mL isooctane Earthy K-I 2,3-Dimethylpyrazine µg/mL isooctane Green, nutty, coffee K-I 2,5-Dimethylpyrazine µg/mL isooctane Chocolate, roasted, earthy K-I 2,6-Dimethylpyrazine µg/mL isooctane Chocolate, roasted nuts, fried potato K-I 2-Ethyl-3,5-dimethylpyrazine µg/mL isooctane Earthy, roasted, nutty K-I 2-Ethyl-3,6-dimethylpyrazine µg/mL isooctane Earthy, roasted K-I 2-Ethyl-3-methoxypyrazine µg/mL isooctane Roasted nuts K-I 2-Ethyl-3-methylpyrazine µg/mL isooctane Potato, roasted, cereal Please inquire 2-Ethyl-5-methylpyrazine Please inquire Nutty, roasted K-I 2-Ethylpyrazine µg/mL isooctane Musty, nutty K-I 2-Isobutyl-3-methoxypyrazine µg/mL isooctane ot paprika K-I 2-Isobutyl-3-methylpyrazine µg/mL isooctane K-I 2-Methoxy-3-isopropylpyrazine µg/mL isooctane Earthy, pepper, vegetable K-I 2-Methoxy-3-methylpyrazine µg/mL isooctane Roasted nuts K-I 2-Methoxypyrazine µg/mL isooctane Nutty, Sweet K-I 2-Methylpyrazine µg/mL isooctane Green, musty, potato K-I 2,3,5-Trimethylpyrazine µg/mL isooctane Earthy, nutty, roasted K-I 2,3,5,6-Tetramethylpyrazine µg/mL isooctane Musty, roasted Food and Pharma 215

218 Phenols G p-cresol [ ] 1g Smoky: Coffee, roated peanuts G 4-Ethylphenol [ ] 1g Woody: Milk, tomatoes, coffee K-I Guaiacol [ ] 1000µg/mL Smoky: Coffee, milk, meat in isooctane K-MX 4-Vinylphenol [ ] arch, smoky: Beer and milk K-I 2-Methoxy-4-vinylphenol [ ] 1000µg/mL Clove-like: Coffee, beer, apple in isooctane ML Eugenol [ ] 1mL Spicy: Tomato paste, brandy K-I Vanillin ] 1000µg/mL Vanilla: Vanilla, rum, coffee in isooctane Terpenes Myrcene trans-cimene cis-cimene Linalool Geraniol Nerol Neroloxide Citronellol Rose oxide otrienol Limonene α-terpinene α-phellandrene β-phellandrene γ-terpinene Menthol Pulegol Please inquire Carveol α-terpineol Perilla alcohol Menthene Pulegone Carvone 1,3-p-Menthadien-7-al 1,8-Cineole 1,4-Cineole Sabiene Thujone (+)-cis-sabiene hydrate (+)-trans-sabiene hydrate α-pinene β-pinene Camphene 3 -Carene Camphor Fenchone trans-α-farnesene cis-α-farnesene β-farnesene Farnesol all-trans-α Sinensal trans,trans,cis-α-sinesal β-bisabolene (-)-Zingiberene (-)-Sesquiphellandrene umulene β-cadinene Valencene (+)-Nootkatoone β-selinene β-caryophyllene Food colours Carotenoids The following carotenoids are produced commercially as food additives (J. Paust in Carotenoids Vol.2, Eds Britton, Liaaen-Jensen and Pfander, Birkhäuser, 1996): MG β,β-carotene [ ] E 160a Margarine, juice, health food MG Canthaxathin [ ] E 161g Poultry, egg york and broiler skin 3902.,40-5MG Astaxanthin [ ] Aquaculture, salmon and trout Ethyl 8 -apo-β-caroten-8 -oate Poultry, egg york and broiler skin MG 8 -Apo-β-caroten-8 -al [ ] E 160e Cheese, dressings Citranaxanthin [ ] Poultry, egg york pigmentation 216

219 Natural carotenoids used or found in food MG Lycopene [ ] E 160d Mayonainnes, ketchup, sauces, tomatoes MG Capxanthin [ ] Pepper, Paprica MG Lutein [ ] Alfalfa MG Zeaxanthin [ ] Maize MG Bixin [ ] E 160b Used in fats and mayonnaise, safran Chlorophylls G Chlorophyll [ ] Green E 140 Edible oils Chlorophyllin [ ] Green E 141 Confectionary, candy, jellies MG Chlorophyll a [ ] MG Chlorophyll b [ ] ther common food colours G Tartrazine [ ] Lemon yellow E 102 Puddings, ice creams etc G Riboflavin [ ] Yellow E 101 Mayonnaise, soups, dessert G Curcumin [ ] Yellow-red E 100 Mustard G Sunset Yellow [ ] range E 110 Beverages, honey like products G Amaranth, Red No 2 [ ] Red, Bluish E 123 Beverages, candy Ponceau 4R [ ] Scarlet-red E 124 Beverages, candy, salmon, cheese G Carmine [ ] Bright red E 120 Alcoholic beverages Anthocyanindin Red-violet E 163 a-f Jams, pop drinks Erythrosine, Red No 3 [ ] Cherry-red E 127 Fruits, jams, candy products G Red 2G [ ] Red, Bluish E 128 Confectionary Indigo Carmine, Blue No 2 [ ] Purple blue E 132 Confectionary, candy G Patent blue V [ ] Blue, greenish E 131 Confectionary, candy Brilliant Blue, Blue No 1 [ ] Blue, greenish E 133 Confectionary, candy Green S, Brilliant Green BS [ ] Green E 142 Black BN Violet, bluish E 151 Fish roe colouring, confectionary Please inquire Food and Pharma Preservatives, antioxidants, sweeteners Please inquire. 217

220 ther natural products in food Carotenoids See Food colours above Lipids and fatty acids See the Compounds section, pages Steroids, sterols See the Compounds section, pages , and below. Sterols in animal fats, milk fat and vegetable oils Animal fats are rich in cholesterol (C27) while plant materials are rich in C29-Sterols like sitosterol and stigmasterol. New IS methods for the analysis of sterols in anhydrous milk fat (IS 18078/IS 18252) and animal and vegetable oils (IS 12228) has recently been introduced: Available products DI Betulin, Internal Standard Solution, IS x1mL, 1x10mL, 5x10mL DI 600µg/mL in di-isopropyl ether K-AC Betulin, Internal standard solution, IS x1mL, 1x10mL K-10AC 1.0 mg/ml in acetone X 5α-Cholestane (99+%), Internal standard solution, IS x1mL, 1x10mL X 600µg/mL in n-hexane/ethanol (1:10) or n-hexane X Cholesterol standard solution 1x1mL, 1x10mL X 600µg/mL in n-hexane K-AC 5α-Cholestan-3-ol (Cholestanol), Alternative internal standard 1x1mL, 1x10mL K-10AC 1.0mg/mL in acetone X Campesterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X Stigmasterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane X β-sitosterol standard solution 1x1mL, 5x1mL 100µg/mL in n-hexane 218

221 S-4487 Sterol standard mixture for IS 12078, neat mixture in 1mL sealed ampoule (Ref in the standard) For Qualitative analysis after silylation Cholesterol 600µg Campesterol 100µg Stigmasterol 100µg Sitosterol 100µg Betulin (IS) 600µg S-4494 Sterol standard mixture for IS For Qualitative analysis, neat in 1 ml sealed ampoulle Cholesterol 600µg Campesterol 100µg Stigmasterol 100µg Sitosterol 100µg a-Cholestane (IS) 600µg Dissolve in 0.25 ml n-hexane for split injector or 3 ml for on-column injector S-4498 Standard solution for TLC, IS Cholesterol 1mg/mL in acetone Betulin 5mg/mL in acetone S-4499 Identification mixture for sterols, IS µg/ml each in isooctane Cholesterol Cholestanol Brassicasterol Campesterol Stigmasterol Sitosterol Sitostanol 3915,30 Erythrodiol Uvaol Betulin Food and Pharma Silylating agents ML Trimethylchlorosilane, TMCS ML examethyldisilazane, MDS ML N-Methyl-N(trimethylsilyl)-trifluoroacetamide, MSTFA G N-Methyl-N(trimethylsilyl)-trifluoroacetamide, MSTFA ML N-Methyl-N-(trimethylsilyl)-heptafluorobutyramide, MSFBA 219

222 Stigmastadiene in vegetable oils/olive oils IS method The steradienes content and especially the stigmastadiene content is determined in vegetable oils because steradienes are formed by dehydration of sterols during bleaching and also partially during steam washing and deodorization. The method is also suitable as a screening method to detect the presence of refined vegetable oils in virgin oils such as olive oil K-BM MX PT K-I Cholesta-3,5-diene stock solution 1mg/mL in tert-butyl methyl ether, 1mL Cholesta-3,5-diene External standard solution 10µg/mL (0.01µg/µL) in acetonitrile/ tert-butyl methyl ether 1:1, 1mL Cholesta-3,5-diene Internal standard solution 2µg/mL in petroleum ether, 1mL 5α-Cholestane standard solution for GC 1mg/mL in isooctane, 1 ml Reference standards I Cholesta-3,5-diene I Stigmastatriene, (24R)-24-Ethylcholesta-3,5,22-triene I Campestadiene, (24R)-24-Methylcholesta-3,5-diene, mix with 24-Ethyl I Stigmastadiene, (24R)-24-Ethylcholesta-3,5-diene IS methods For details, see the Methods section, page 13 and onward. - IS 12078, IDF 159:2006 Sterols in milk fat - IS 18252, IDF 200:2006 Sterols in milk fat - IS 12228:1999 Sterols in animal and vegetable fats and oil - IS :2006 Stigmastadienes in vegetable oils 220

223 Chapter III-4: Pharmaceuticals and forensics Table of contents Pharmaceuticals and forensics Pharmaceutical reference standards Impurities of pharmaceutical products Pharmaceutical and forensic metabolites reference standards GC-IRMS standards for sports, forensic and geochemical applications Food and Pharma 221

224 Pharmaceuticals and forensics For details, see the Compounds section, pages Pharmaceutical reference standards In order to meet the requirements of the different pharmacopeias, Chiron is now offering traceable chemical reference substances (CRMs) for pharmaceuticals analysis. Impurities of pharmaceutical products Common impurities as defined by international pharmacopeias, and in particular the EP (European Pharmacopeia) are now available. The products are carefully analysed for identity and purity, and a certificate is supplied for each product. Pharmaceutical and forensic metabolites reference standards As a new project, Chiron now offers metabolites of common pharmaceuticals and forensic drugs. Such products are important in drug development as well as the surveillance of the pharmaceutical level in patients. Chiron has developed and possesses proprietary technology for production of sulphates and glucuronide metabolites of alcohols and amines, and custom synthesis inquiries are welcome. With the access to parent narcotics on commercial scale, Chiron can now offer standards for important drugs as well as their important metabolites. Drug consumption analysis is important in order to control drug use among patients and the abuse of restricted narcotics. Narcotics controlled substances Several of the listed compounds are subject to narcotics legislation. This means that import and export documentation is required. Please consult your local distributor or contact Chiron for help. Nicotins Chiron now offers solutions of native and labelled standards for common nicotine derivatives, including cotenine, anatabine, and many others. Please contact us for any products you may not find in our catalogue. GC-IRMS standards for sports, forensic and geochemical applications The isotope ratio C12/C13 is individual from sample to sample and is a useful tool for the identification of the origin of different matters. Misuse of synthetic steroids can be determined this way, as well as policing possible mixing of natural and synthetic natural products. The isotope ratio changes with the age of the material, and is therefore used in geochemical determinations. For such application Chiron offers reference standards with an established C12 / C13 ratio. The Chiron standards are straight hydrocarbons from C11 to C40. thers, like several steroids, will be offered. Please inquire or let us know your suggestions. 222

225 Chapter IV: Compounds Table of contents Biomarkers and hydrocarbons Aliphatic alkanes (paraffins) Paraffins C5-C60 complete Alkenes Cyclic hydrocarbons including alkylbenzenes and hydropas Monocyclic compounds Bicyclic compounds Tricyclic compounds Steranes (tetracyclic compounds) Triterpanes/hopanes (pentacyclic compounds) openes Naphthenic acids, cyclic aromatic and aliphatic acids Compounds by functional groups Aliphatic alcohols Ethers/esters Diols, glycols and derivatives Aliphatic ketones Cyclic alcohols and ketones Phenones Amines Aromatic amines Chlorobenzenes Bromobenzenes Ammonium halides Sulfur compounds Thiols Sulfides Polysulfur compounds PAs Internal standards Biphenyls and terphenyls Naphthalenes Acenaphthenes and acenaphthylenes Fluorenes Phenanthrenes elicenes Anthracenes Fluoranthrenes Cholanhrenes Pyrenes Chrysenes Anthanthrenes Perylenes Peropyrenes Picenes Bisanthenes Acenes and phenes Terrylenes Coronenes ther PAs Compounds

226 PANs (Nitrogen-heterocyclic PAs) Quinolines and benzoquinolines Carbazoles PASs (Sulfur-heterocyclic PAs) Thiophenes Benzothiophenes Dibenzotiophenes PAs (xygen-heterocyclic PAs) Benzofurans Dibenzofurans PPs (Persistent organic pollutants) PCBs (Polychlorobiphenyls) PBBs (Polybromobiphenyls) Flame retardants PCNs (Polychloronaphthalenes) PBNs (Polybromonaphthalenes) PCAs (Polychlorinated n-alkanes) PFAs (Perfluorinated alkane acids and alcohols) VC (Volatile organic compounds) Phophates (ydraulic fluids) Pesticides Surfactants and phenols Phenolethoxylates Phenols Phthalates and adipates LAS and ABS (linear alkylbenzene sulfonates and alkylbenzene sulfonates) Metallo-organics Tin-organics rganoleads il-based metal standards Forensics and pharmaceuticals Forensics and drug/pharma metabolites Pharmaceuticals and its impurities Natural products Steroids and sterols Triterpenoids Carotenoids Alkaloids Food safety and analysis Mycotoxins Food impurities and contaminants Algae and shellfish toxins Aroma chemicals Fatty acids and derivatives ygienic products ygienic additives Synthetic musks Reagents Derivatizing agents and reagents GC-IRMS standards Solvents

227 Biomarkers and hydrocarbons Aliphatic alkanes (Paraffines) Deuterated n-alkanes Cat.No. Name Description MW Cas.No. Conc. Solvent Quantity Volume K-ME n-pentane-d [ ] 1000µg/mL methanol 1 1mL G n-pentane-d [ ] neat 1 1g K-ME n-exane-d [ ] 1000µg/mL methanol 1 1mL G n-exane-d [ ] neat 1 1g K-ME n-eptane-d [ ] 1000µg/mL methanol 1 1mL G n-eptane-d [ ] neat 1 1g K-ME n-ctane-d [ ] 1000µg/mL methanol 1 1mL G n-ctane-d [ ] neat 1 1g K-ME n-nonane-d [ ] 1000µg/mL methanol 1 1mL G n-nonane-d [ ] neat 1 1g K-I n-decane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-decane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-decane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-undecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-undecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-undecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-dodecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-dodecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-dodecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-tridecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-tridecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-tridecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-tetradecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-tetradecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-tetradecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-pentadecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-pentadecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-pentadecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-exadecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-exadecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-exadecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-eptadecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-eptadecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-eptadecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-ctadecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-ctadecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-ctadecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-nonadecane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-nonadecane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-nonadecane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-eicosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-eicosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-eicosane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-eneicosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-eneicosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-eneicosane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-docosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-docosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-docosane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-tricosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-tricosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-tricosane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-tetracosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-tetracosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-tetracosane-d [ ] 1000µg/mL isooctane 10 1mL Compounds 225

228 K-I n-pentacosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-pentacosane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-pentacosane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-exacosane-d µg/mL isooctane 1 1mL K-I n-exacosane-d µg/mL isooctane 5 1mL K-I n-exacosane-d µg/mL isooctane 10 1mL K-I n-ctacosane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-triacontane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-triacontane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-triacontane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-dotriacontane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-dotriacontane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-dotriacontane-d [ ] 1000µg/mL isooctane 10 1mL K-I n-exatriacontane-d [ ] 1000µg/mL isooctane 1 1mL K-I n-exatriacontane-d [ ] 1000µg/mL isooctane 5 1mL K-I n-exatriacontane-d [ ] 1000µg/mL isooctane 10 1mL n-alkanes K-ME n-pentane [ ] 1000µg/mL methanol 1 1mL ML n-pentane [ ] neat 1 10mL K-ME n-exane [ ] 1000µg/mL methanol 1 1mL ML n-exane [ ] neat 1 10mL K-ME n-eptane [ ] 1000µg/mL methanol 1 1mL ML n-eptane [ ] neat 1 10mL K-ME n-ctane [ ] 1000µg/mL methanol 1 1mL ML n-ctane [ ] neat 1 10mL K-I n-nonane [ ] 1000µg/mL isooctane 1 1mL ML n-nonane [ ] neat 1 10mL K-I n-decane [ ] 1000µg/mL isooctane 1 1mL ML n-decane [ ] neat 1 10mL K-I n-undecane [ ] 1000µg/mL isooctane 1 1mL MG n-undecane [ ] neat 1 10mg K-I n-dodecane [ ] 1000µg/mL isooctane 1 1mL MG n-dodecane [ ] neat 1 10mg K-I n-tridecane [ ] 1000µg/mL isooctane 1 1mL MG n-tridecane [ ] neat 1 10mg K-I n-tetradecane [ ] 1000µg/mL isooctane 1 1mL MG n-tetradecane [ ] neat 1 10mg K-I n-pentadecane [ ] 1000µg/mL isooctane 1 1mL MG n-pentadecane [ ] neat 1 10mg K-I n-exadecane [ ] 1000µg/mL isooctane 1 1mL MG n-exadecane [ ] neat 1 10mg K-I n-eptadecane [ ] 1000µg/mL isooctane 1 1mL MG n-eptadecane [ ] neat 1 10mg K-I n-ctadecane [ ] 1000µg/mL isooctane 1 1mL MG n-ctadecane [ ] neat 1 10mg K-I n-nonadecane [ ] 1000µg/mL isooctane 1 1mL MG n-nonadecane [ ] neat 1 10mg K-I n-eicosane [ ] 1000µg/mL isooctane 1 1mL MG n-eicosane [ ] neat 1 10mg K-I n-eneicosane [ ] 1000µg/mL isooctane 1 1mL MG n-eneicosane [ ] neat 1 10mg K-I n-docosane [ ] 1000µg/mL isooctane 1 1mL MG n-docosane [ ] neat 1 10mg K-I n-tricosane [ ] 1000µg/mL isooctane 1 1mL MG n-tricosane [ ] neat 1 10mg K-I n-tetracosane [ ] 1000µg/mL isooctane 1 1mL MG n-tetracosane [ ] neat 1 10mg K-I n-pentacosane [ ] 1000µg/mL isooctane 1 1mL MG n-pentacosane [ ] neat 1 10mg K-I n-exacosane [ ] 1000µg/mL isooctane 1 1mL MG n-exacosane [ ] neat 1 10mg 226

229 K-I n-eptacosane [ ] 1000µg/mL isooctane 1 1mL MG n-eptacosane [ ] neat 1 10mg K-I n-ctacosane [ ] 1000µg/mL isooctane 1 1mL MG n-ctacosane [ ] neat 1 10mg K-I n-nonacosane [ ] 1000µg/mL isooctane 1 1mL MG n-nonacosane [ ] neat 1 10mg K-I n-triacontane [ ] 1000µg/mL isooctane 1 1mL MG n-triacontane [ ] neat 1 10mg K-I n-entriacontane [ ] 1000µg/mL isooctane 1 1mL MG n-entriacontane [ ] neat 1 10mg K-I n-dotriacontane [ ] 1000µg/mL isooctane 1 1mL MG n-dotriacontane [ ] neat 1 10mg K-I n-triatriacontane [ ] 1000µg/mL isooctane 1 1mL MG n-triatriacontane [ ] neat 1 10mg K-I n-tetratriacontane [ ] 1000µg/mL isooctane 1 1mL MG n-tetratriacontane [ ] neat 1 10mg K-I n-pentatriacontane [ ] 1000µg/mL isooctane 1 1mL MG n-pentatriacontane [ ] neat 1 10mg I n-exatriacontane [ ] 100µg/mL isooctane 1 1mL MG n-exatriacontane [ ] neat 1 10mg I n-eptatriacontane [ ] 100µg/mL isooctane 1 1mL MG n-eptatriacontane [ ] neat 1 10mg I n-ctatriacontane [ ] 100µg/mL isooctane 1 1mL MG n-ctatriacontane [ ] neat 1 10mg I n-nonatriacontane [ ] 100µg/mL isooctane 1 1mL MG n-nonatriacontane [ ] neat 1 10mg I n-tetracontane [ ] 100µg/mL isooctane 1 1mL MG n-tetracontane [ ] neat 1 10mg MG n-entetracontane [ ] neat 1 10mg MG n-dotetracontane [ ] neat 1 10mg MG n-tetratetracontane [ ] neat 1 10mg MG n-exatetracontane [ ] neat 1 10mg MG n-ctatetracontane [ ] neat 1 10mg MG n-dopentacontane [ ] neat 1 10mg MG n-tetrapentacontane [ ] neat 1 10mg MG n-exapentacontane [ ] neat 1 10mg MG n-exacontane [ ] neat 1 10mg KIT n-alkane Kit (solutions when available/else neat) Kit 2-Methylalkanes (isoalkanes) ML 2-Methylbutane [ ] neat 1 1mL ML 2-Methylpentane [ ] neat 1 1mL ML 2-Methylhexane [ ] neat 1 1mL ML 2-Methylheptane [ ] neat 1 1mL K-CY 2-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL MG 2-Methyloctane [ ] neat 1 100mg K-CY 2-Methylnonane [ ] 1000µg/mL cyclohexane 1 1mL MG 2-Methylnonane [ ] neat 1 100mg K-I 2-Methyldecane [ ] 1000µg/mL isooctane 1 1mL MG 2-Methyldecane [ ] neat 1 100mg K-I 2-Methylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyltetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyleicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylheneicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyldocosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyltricosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylpentacosane [ ] 1000µg/mL isooctane 1 1mL KIT 2-Methylalkane Kit Kit Compounds 227

230 3-Methylalkanes (anteisoalkanes) ML 3-Methylpentane [ ] neat 1 1mL ML 3-Methylhexane [ ] neat 1 1mL ML 3-Methylheptane [ ] neat 1 1mL K-CY 3-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL MG 3-Methyloctane [ ] neat 1 100mg K-CY 3-Methylnonane [ ] 1000µg/mL cyclohexane 1 1mL MG 3-Methylnonane [ ] neat 1 100mg K-I 3-Methyldecane [ ] 1000µg/mL isooctane 1 1mL MG 3-Methyldecane [ ] neat 1 10mg K-I 3-Methylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methyltridecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylpentadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL KIT 3-Methylalkane Kit Kit ther isoalkanes K-CY 4-Methylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 4-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL K-I 4-Methylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 5-Methylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyldodecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyltridecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyltetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methylhexadecane [ ] 1000µg/mL isooctane 1 1mL K-I 10-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL KIT ther Isoalkane Kit Kit Additional Isoalkanes: Please inquire for custom synthesis Isoprenoids, head-to-tail K-CY 2,6-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-I 2,6-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethyldodecane Farnesane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethylpentadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylpentadecane Pristane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylhexadecane Phytane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14,18-Pentamethylheneicosane [ ] 1000µg/mL isooctane 1 1mL KIT ead-to-tail Isoprenoid Kit Kit Isoprenoids, tail-to-tail K-I 2,6,11-Trimethyldodecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,11,15-Tetramethylhexadecane Crocetane [ ] 1000µg/mL isooctane 1 1mL K-I Squalene [ ] 1000µg/mL isooctane 1 1mL K-I Squalane [ ] 1000µg/mL isooctane 1 1mL I ββ-carotane [ ] 500µg/mL isooctane 1 1mL I Lycopane [ ] 500µg/mL isooctane 1 1mL KIT Tail-to-tail Isoprenoids Kit Kit 228

231 Botryococcanes K-I Botryococcane C30-C32 [ /] 1000µg/mL isooctane 1 1mL [ / -] K-I Botryococcane C32-C34 [ ] 1000µg/mL isooctane 1 1mL K-I Botryococcane C [ ] 1000µg/mL isooctane 1 1mL KIT Botryococcane Kit Kit Paraffins C5-C60 complete C5-C6 Paraffins (alkanes) ML n-pentane [ ] neat 1 10mL ML 2-Methylbutane [ ] neat 1 1mL ML n-exane [ ] neat 1 10mL ML 2-Methylpentane [ ] neat 1 1mL ML 3-Methylpentane [ ] neat 1 1mL ML 2,2-Dimethylbutane [ ] neat 1 1mL ML 2,3-Dimethylbutane [ ] neat 1 1mL KIT C5-C6 Alkane Kit Kit C7-C8 Paraffins (alkanes) ML n-eptane [ ] neat 1 10mL ML 2-Methylhexane [ ] neat 1 1mL ML 3-Methylhexane [ ] neat 1 1mL ML 3-Ethylpentane [ ] neat 1 1mL ML 2,2-Dimethylpentane [ ] neat 1 1mL ML 2,3-Dimethylpentane [ ] neat 1 1mL ML 2,4-Dimethylpentane [ ] neat 1 1mL ML 3,3-Dimethylpentane [ ] neat 1 1mL ML n-ctane [ ] neat 1 10mL K-ME 2-Methylheptane [ ] 1000µg/mL methanol 1 1mL K-ME 3-Methylheptane [ ] 1000µg/mL methanol 1 1mL K-ME 4-Methylheptane [ ] 1000µg/mL methanol 1 1mL K-ME 2,2-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 2,3-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 2,4-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 2,5-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 3,3-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 3,4-Dimethylhexane [ ] 1000µg/mL methanol 1 1mL K-ME 2,2,4-Trimethylpentane Isooctane [ ] 1000µg/mL methanol 1 1mL K-ME 2,3,3-Trimethylpentane [ ] 1000µg/mL methanol 1 1mL K-ME 2,3,4-Trimethylpentane [ ] 1000µg/mL methanol 1 1mL KIT C7-C8 Alkane Kit Kit C9 Paraffins (alkanes) ML n-nonane [ ] neat 1 10mL K-CY 2-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL MG 2-Methyloctane [ ] neat 1 100mg K-CY 3-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL MG 3-Methyloctane [ ] neat 1 100mg K-CY 4-Methyloctane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,2-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,3-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,4-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,5-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,6-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 3,3-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL Compounds 229

232 K-CY 3,4-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 3,5-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 4,4-Dimethylheptane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,2,3-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,2,4-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,2,5-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,3,3-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,3,4-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,3,5-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2,4,4-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 3,3,4-Trimethylhexane [ ] 1000µg/mL cyclohexane 1 1mL KIT C9 Alkane Kit Kit C10 Paraffins (alkanes) ML n-decane [ ] neat 1 10mL K-CY 2-Methylnonane [ ] 1000µg/mL cyclohexane 1 1mL MG 2-Methylnonane [ ] neat 1 100mg K-CY 3-Methylnonane [ ] 1000µg/mL cyclohexane 1 1mL MG 3-Methylnonane [ ] neat 1 100mg K-I 4-Methylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 5-Methylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 2,3-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,7-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 3,3-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 3,5-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 3,6-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 4,4-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 4,5-Dimethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,4,6-Trimethylheptane [ ] 1000µg/mL isooctane 1 1mL K-I 3,3,5-Trimethylheptane [ ] 1000µg/mL isooctane 1 1mL K-I 3,4,5-Trimethylheptane [ ] 1000µg/mL isooctane 1 1mL KIT C10 Alkane Kit Kit KIT C5-C10 Paraffin Kit Kit C11-C15 Paraffins (alkanes) K-I n-undecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Ethylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,6,6-Tetramethylheptane [ ] 1000µg/mL isooctane 1 1mL K-I n-dodecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylundecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,3-Dimethyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethyldecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,4,4-Tetramethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,7,7-Tetramethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,4,6,6-Pentamethylheptane [ ] 1000µg/mL isooctane 1 1mL K-I n-tridecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyldodecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethylundecane [ ] 1000µg/mL isooctane 1 1mL K-I n-tetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methyltridecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyltridecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethylundecane [ ] 1000µg/mL isooctane 1 1mL K-I n-pentadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyltetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyltetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethyldodecane Farnesane [ ] 1000µg/mL isooctane 1 1mL 230

233 K-I 2,6,11-Trimethyldodecane [ ] 1000µg/mL isooctane 1 1mL KIT C11-C15 Paraffin Kit Kit C16-C20 Paraffins (alkanes) K-I n-exadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylpentadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,4,4,6,8,8-eptamethylnonane [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,4,4,5,5,7,7-ctamethyloctane [ ] 1000µg/mL isooctane 1 1mL K-I n-eptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methylhexadecane [ ] 1000µg/mL isooctane 1 1mL K-I 5,5-Dibutylnonane [ ] 1000µg/mL isooctane 1 1mL K-I n-ctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10-Trimethylpentadecane [ ] 1000µg/mL isooctane 1 1mL K-I n-nonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14,18-Tetramethylpentadecane Pristane [ ] 1000µg/mL isooctane 1 1mL K-I n-eicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 10-Methylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14,18-Tetramethylhexadecane Phytane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,11,15-Tetramethylhexadecane Crocetane [ ] 1000µg/mL isooctane 1 1mL KIT C16-C20 Paraffin Kit Kit C21-C25 Paraffins (alkanes) K-I n-eneicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyleicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylheptadecane [ ] 1000µg/mL isooctane 1 1mL K-I n-docosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylheneicosane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethyloctadecane [ ] 1000µg/mL isooctane 1 1mL K-I n-tricosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyldocosane [ ] 1000µg/mL isooctane 1 1mL K-I 2,6,10,14-Tetramethylnonadecane [ ] 1000µg/mL isooctane 1 1mL K-I n-tetracosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyltricosane [ ] 1000µg/mL isooctane 1 1mL K-I n-pentacosane [ ] 1000µg/mL isooctane 1 1mL KIT C21-C25 Paraffin Kit Kit C26-C30 Paraffins (alkanes) K-I n-exacosane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylpentacosane [ ] 1000µg/mL isooctane 1 1mL K-I n-eptacosane [ ] 1000µg/mL isooctane 1 1mL K-I n-ctacosane [ ] 1000µg/mL isooctane 1 1mL K-I n-nonacosane [ ] 1000µg/mL isooctane 1 1mL K-I n-triacontane [ ] 1000µg/mL isooctane 1 1mL K-I Squalane [ ] 1000µg/mL isooctane 1 1mL K-I Botryococcane C30-C32 [ /] 1000µg/mL isooctane 1 1mL [ / -] KIT C26-C30 Paraffin Kit Kit Compounds 231

234 C31-C40 Paraffins (alkanes) K-I n-entriacontane [ ] 1000µg/mL isooctane 1 1mL K-I Botryococcane C30-C32 [ /] 1000µg/mL isooctane 1 1mL [ / -] K-I n-dotriacontane [ ] 1000µg/mL isooctane 1 1mL K-I n-triatriacontane [ ] 1000µg/mL isooctane 1 1mL K-I Botryococcane C [ ] 1000µg/mL isooctane 1 1mL K-I Botryococcane C32-C34 [- / ]1000µg/mL isooctane 1 1mL [ / ] K-I n-tetratriacontane [ ] 1000µg/mL isooctane 1 1mL K-I n-pentatriacontane [ ] 1000µg/mL isooctane 1 1mL I n-exatriacontane [ ] 100µg/mL isooctane 1 1mL I n-eptatriacontane [ ] 100µg/mL isooctane 1 1mL I n-ctatriacontane [ ] 100µg/mL isooctane 1 1mL I n-nonatriacontane [ ] 100µg/mL isooctane 1 1mL I n-tetracontane [ ] 100µg/mL isooctane 1 1mL I Lycopane [ ] 500µg/mL isooctane 1 1mL I ββ-carotane [ ] 500µg/mL isooctane 1 1mL KIT C31-C40 Paraffin Kit (15 samples, 17 compounds) Kit C41-C60 Paraffins (alkanes) MG n-entetracontane [ ] neat 1 10mg MG n-dotetracontane [ ] neat 1 10mg MG n-tetratetracontane [ ] neat 1 10mg MG n-exatetracontane [ ] neat 1 10mg MG n-ctatetracontane [ ] neat 1 10mg MG n-dopentacontane [ ] neat 1 10mg MG n-tetrapentacontane [ ] neat 1 10mg MG n-exapentacontane [ ] neat 1 10mg MG n-exacontane [ ] neat 1 10mg KIT C41-C60 Paraffin Kit Kit Alkenes Alkenes ML 1-Pentene [ ] neat 1 1mL ML cis-2-pentene [ ] neat 1 1mL ML trans-2-pentene [ ] neat 1 1mL ML 2-Methyl-1-butene [ ] neat 1 1mL ML 2-Methyl-2-butene [ ] neat 1 1mL ML 3-Methyl-1-butene [ ] neat 1 1mL ML 1-exene [ ] neat 1 1mL ML cis-2-exene [ ] neat 1 1mL ML trans-2-exene [ ] neat 1 1mL ML 2-Methyl-2-pentene [ ] neat 1 1mL ML 4-Methyl-1-pentene [ ] neat 1 1mL ML 4-Methyl-cis-2-pentene [ ] neat 1 1mL ML 1-eptene [ ] neat 1 1mL ML cis-2-eptene [ ] neat 1 1mL ML trans-2-eptene [ ] neat 1 1mL ML cis-3-eptene [ ] neat 1 1mL ML trans-3-eptene [ ] neat 1 1mL ML 5-Methyl-1-hexene [ ] neat 1 1mL ML 1-ctene [ ] neat 1 1mL ME cis-2-ctene [ ] 100µg/mL methanol 1 1mL ME trans-2-ctene [ ] 100µg/mL methanol 1 1mL ME 2-Methyl-1-heptene [ ] 100µg/mL methanol 1 1mL ME 3,5-Dimethyl-1-hexene [ ] 100µg/mL methanol 1 1mL 232

235 ME 2,3,4-Trimethyl-2-pentene [ ] 100µg/mL methanol 1 1mL ME 2,4,4-Trimethyl-1-pentene [ ] 100µg/mL methanol 1 1mL ME 2,4,4-Trimethyl-2-pentene [ ] 100µg/mL methanol 1 1mL ME 3,4,4-Trimethyl-trans-2-pentene [ ] 100µg/mL methanol 1 1mL ME 1-Nonene [ ] 100µg/mL methanol 1 1mL ME cis-2-nonene [ ] 100µg/mL methanol 1 1mL ME trans-2-nonene [ ] 100µg/mL methanol 1 1mL ME cis-3-nonene [ ] 100µg/mL methanol 1 1mL ME trans-3-nonene [ ] 100µg/mL methanol 1 1mL ME 2-Methyl-1-octene [ ] 100µg/mL methanol 1 1mL ME 1-Decene [ ] 100µg/mL methanol 1 1mL ME 4,4-Dimethyl-2-neopentyl-1-pentene [ ] 100µg/mL methanol 1 1mL KIT Alkenes Kit (not including ) Kit Alkadienes ML 2-Methyl-1,3-butadiene Isoprene [ ] neat 1 1mL ML 3-Methyl-1,3-pentadiene [ ] neat 1 1mL ML 1,5-exadiene [ ] neat 1 1mL Compounds 233

236 Cyclic hydrocarbons including alkylbenzenes and hydropas For Cyclic isoprenoids, see page 238 and onward For PAs, see page 295 and onward Monocyclic compounds C0-C2 Alkylcyclopentanes ML Cyclopentane [ ] neat 1 1mL ML Methylcyclopentane [ ] neat 1 1mL ML 1,1-Dimethylcyclopentane [ ] neat 1 1mL ML cis-1,2-dimethylcyclopentane [ ] neat 1 1mL ML trans-1,2-dimethylcyclopentane [ ] neat 1 1mL ML cis-1,3-dimethylcyclopentane [ ] neat 1 1mL ML trans-1,3-dimethylcyclopentane [ ] neat 1 1mL ML Ethylcyclopentane [ ] neat 1 1mL KIT C0-C2 Alkylcyclopentane Kit Kit C3-C4 Alkylcyclopentanes K-CY 1,1,3-Trimethylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY tc-1,2,3-trimethylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cc-1,2,3-trimethylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY ct-1,2,4-trimethylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY tc-1,2,4-trimethylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1-Ethyl-1-methylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY n-propylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY Isopropylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY n-butylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL K-CY Isobutylcyclopentane [ ] 1000µg/mL cyclohexane 1 1mL KIT C3-C4 Alkylcyclopentane Kit Kit C0-C2 Alkylcyclohexanes ML Cyclohexane [ ] neat 1 5mL ML Methylcyclohexane [ ] neat 1 1mL K-CY 1,1-Dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cis-1,2-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY trans-1,2-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cis-1,3-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY trans-1,3-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cis-1,4-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY trans-1,4-dimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY Ethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL KIT C0-C2 Cyclohexane Kit Kit C3 Alkylcyclohexanes K-CY 1,1,3-Trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cc-1,3,5-trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1,1,4-Trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY cc-1,2,4-trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY ct-1,2,4-trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY tc-1,2,4-trimethhylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1,1,2-Trimethylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL KIT C3 Alkylcyclohexane Kit Kit 234

237 C0-C1 Alkylcyclohepanes mL Cycloheptane [ ] neat 1 1mL K-CY Methylcycloheptane [ ] 1000µg/mL cyclohexane 1 1mL.2-KIT C0-C2 Alkylcycloheptane Kit Kit KIT C0-C3 Alkylcycloalkane Kit Kit C4-C19 Alkylcycloalkanes K-CY n-butylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-I n-pentylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-exylcyclohexane [ ] 1000µg/mL isooctane 1 1mL I 2-Methyl-1-hexylcyclohexane [ ] 100µg/mL isooctane 1 1mL K-I 3-Methyl-1-hexylcyclohexane (cis+trans) [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyl-1-hexylcyclohexane (cis+trans) [ ] 1000µg/mL isooctane 1 1mL K-I n-eptylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-ctylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-nonylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-decylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-undecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-dodecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-tridecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-tetradecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-pentadecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-CY n-exadecylcyclohexane [ ] 1000µg/mL cyclohexane 1 1mL K-I n-eptadecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-ctadecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL K-I n-nonadecylcyclohexane [ ] 1000µg/mL isooctane 1 1mL KIT C4-C19 Alkylcycloalkane Kit Kit Cycloalkanes, unsubstituted ML Cyclopentane [ ] neat 1 1mL ML Cyclohexane [ ] neat 1 5mL G Cycloheptane [ ] neat 1 1g K-CY Cyclooctane [ ] 1000µg/mL cyclohexane 1 1mL K-I Cyclododecane [ ] 1000µg/mL isooctane 1 1mL K-I Cyclopentadecane [ ] 1000µg/mL isooctane 1 1mL KIT Cycloalkane Kit Kit Fullerenes MG [5,6]Fullerene-C [ ] neat 1 10mg MG [5,6]Fullerene-C [ ] neat 1 10mg Cycloalkenes ML Cyclopentene [ ] neat 1 1mL ML 1-Methylcyclopentene [ ] neat 1 1mL ML Cyclohexene [ ] neat 1 1mL ML trans, trans, cis-cyclododeca-1,2,9-triene [ ] neat 1 1mL F-BTEX internal standards ML Fluorobenzene [ ] neat 1 1mL ML o-fluorotoluene [ ] neat 1 1mL ML m-fluorotoluene [ ] neat 1 1mL ML p-fluorotoluene [ ] neat 1 1mL UL 1-Ethyl-4-fluorobenzene [ ] neat 1 0,5mL UL 3-Fluoro-o-xylene [ ] neat 1 0,5mL UL 4-Fluoro-o-xylene [ ] neat 1 0,5mL K-ME ααα-trifluorotoluene [ ] 10000µg/mL methanol 1 1mL Compounds 235

238 Calibration (Surrogate) Standard K-ME ααα-trifluorotoluene [ ] 10000µg/mL methanol 5 1mL Calibration (Surrogate) Standard KIT F-BTEX Kit Kit Deuterated BTEX internal standards K-ME Benzene-d [ ] 1000µg/mL methanol 1 1mL ML Benzene-d [ ] neat 1 1mL K-ME Toluene-d [ ] 5000µg/mL methanol 1 1mL K-ME o-xylene-d [ ] 1000µg/mL methanol 1 1mL K-ME m-xylene-d [ ] 1000µg/mL methanol 1 1mL K-ME p-xylene-d [ ] 1000µg/mL methanol 1 1mL K-ME Ethylbenzene-d [ ] 1000µg/mL methanol 1 1mL Deuterated alkylbenzenes K-I n-butylbenzene-d [ ] 1000µg/mL isooctane 1 1mL K-I n-nonylbenzene-2,3,4,5,6-d [ ] 1000µg/mL isooctane 1 1mL K-I n-dodecylbenzene-d [ ] 1000µg/mL isooctane 1 1mL K-I n-pentadecylbenzene-d [ ] 1000µg/mL isooctane 1 1mL C0-C2 Alkylbenzenes (BTEX) K-ME Benzene [ ] 1000µg/mL methanol 1 1mL ML Benzene [ ] neat 1 5mL K-ME Toluene [ ] 1000µg/mL methanol 1 1mL ML Toluene [ ] neat 1 1mL K-ME Styrene [ ] 1000µg/mL methanol 1 1mL ML Styrene [ ] neat 1 1mL K-ME o-xylene 1,2-Dimethylbenzene [ ] 1000µg/mL methanol 1 1mL ML o-xylene 1,2-Dimethylbenzene [ ] neat 1 1mL K-ME m-xylene 1,3-Dimethylbenzene [ ] 1000µg/mL methanol 1 1mL ML m-xylene 1,3-Dimethylbenzene [ ] neat 1 1mL ML m-xylene 1,3-Dimethylbenzene [ ] neat 1 5mL K-ME p-xylene 1,4-Dimethylbenzene [ ] 1000µg/mL methanol 1 1mL ML p-xylene 1,4-Dimethylbenzene [ ] neat 1 1mL K-ME Ethylbenzene [ ] 1000µg/mL methanol 1 1mL ML Ethylbenzene [ ] neat 1 1mL ML Ethylbenzene [ ] neat 1 5mL KIT BTEX Kit (C0-C2 Alkylbenzene Kit) Kit C3 Alkylbenzenes (C9) K-CY n-propylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1,2,3-Trimethylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1,2,4-Trimethylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-I 1,3,5-Trimethylbenzene Mesitylene [ ] 1000µg/mL isooctane 1 1mL K-CY 1-Ethyl-3-methylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-CY 1-Ethyl-4-methylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-CY 2-Ethyl-1-methylbenzene [ ] 1000µg/mL cyclohexane 1 1mL K-CY Isopropylbenzene Cumene [ ] 1000µg/mL cyclohexane 1 1mL KIT C3 Alkylbenzene Kit Kit C4 Alkylbenzenes (C10) K-I n-butylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,3,4-Tetramethylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,3,5-Tetramethylbenzene Indurene [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,4,5-Tetramethylbenzene [ ] 1000µg/mL isooctane 1 1mL K-X 1,2-Dimethyl-3-ethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,2-Dimethyl-4-ethylbenzene [ ] 1000µg/mL hexane 1 1mL 236

239 K-X 1,3-Dimethyl-2-ethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,3-Dimethyl-5-ethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,4-Dimethyl-2-ethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1-Methyl-2-n-propylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1-Methyl-3-n-propylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1-Methyl-4-n-propylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,2-Diethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,3-Diethylbenzene [ ] 1000µg/mL hexane 1 1mL K-I 1,4-Diethylbenzene [ ] 1000µg/mL isooctane 1 1mL K-X o-isopropyltoluene o-cymene [ ] 1000µg/mL hexane 1 1mL K-X m-isopropyltoluene m-cymene [ ] 1000µg/mL hexane 1 1mL I p-isopropyltoluene p-cymene [ ] 500µg/mL isooctane 1 1mL K-X sec-butylbenzene [ ] 1000µg/mL hexane 1 1mL K-X tert-butylbenzene [ ] 1000µg/mL hexane 1 1mL K-X Isobutylbenzene [ ] 1000µg/mL hexane 1 1mL KIT C4 Alkylbenzene Kit Kit C5-C19 Alkylbenzenes (C11-C25) K-X n-pentylbenzene [ ] 1000µg/mL hexane 1 1mL K-T Pentamethylbenzene [ ] 1000µg/mL toluene 1 1mL K-X (2-Methylbutyl)benzene [ ] 1000µg/mL hexane 1 1mL K-I n-exylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I examethylbenzene [ ] 1000µg/mL isooctane 1 1mL K-X 1,2,4-Triethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 1,3,5-Triethylbenzene [ ] 1000µg/mL hexane 1 1mL K-X 5-tert-Butyl-m-xylene [ ] 1000µg/mL hexane 1 1mL K-X 1-tert-Butyl-4-ethylbenzene [ ] 1000µg/mL hexane 1 1mL ME 1-Ethyl-4-(2-methylpropyl)benzene [ ] 100µg/mL methanol 1 1mL K-I n-eptylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-ctylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-nonylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I Dimethylheptylbenzene (Isomer mixture) µg/mL isooctane 1 1mL 1-eptyl-2,3-dimethylbenzene [ / 1-eptyl-2,4-dimethylbenzene / 1-eptyl-3,5-dimethylbenzene / 2-eptyl-1,3-dimethylbenzene / 2-eptyl-1,4-dimethylbenzene / 4-eptyl-1,2-dimethylbenzene ] K-I n-decylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I Methylnonylbenzene (Isomer mixture) µg/mL isooctane 1 1mL 1-Methyl-2-nonylbenzene [ / 1-Methyl-3-nonylbenzene / 1-Methyl-4-nonylbenzene ] K-I n-undecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-dodecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I exaethylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-tridecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-tetradecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-pentadecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-exadecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I 1,4-Bis(2-ethylhexyl)benzene [ ] 1000µg/mL isooctane 1 1mL K-I n-eptadecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-ctadecylbenzene [ ] 1000µg/mL isooctane 1 1mL K-I n-nonadecylbenzene [ ] 1000µg/mL isooctane 1 1mL KIT C5-C19 Alkylbenzenes Kit Kit 237 Compounds

240 Isoprenoid chain attached to cyclohexane or benzene (4,8-Dimethylnonyl)benzene [ ] MW ,3-Dimethyl-2- (3,7-dimethyloctyl)cyclohexane [ ] MW K-I 1000µg/mL isooctane, 1x1mL (4,8-Dimethylnonyl)cyclohexane [ ] MW K-I 1000µg/mL isooctane, 1x1mL ,4-Bis (3,7-dimethyloctyl)benzene [ ] MW K-I 1000µg/mL isooctane, 1x1mL ,3-Dimethyl-2- (3,7-dimethyloctyl)benzene [ ] MW K-I 1000µg/mL isooctane, 1x1mL Ring-Containing Isoprenoid Kit KIT Kit K-I 1000µg/mL isooctane, 1x1mL Bicyclic compounds ydronaphthalenes (dihydro, hexahydro) K-I 1,2-Dihydronaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I exahydronaphthalene [ ] 1000µg/mL isooctane 1 1mL KIT ydronaphthalene Kit Kit Decalines (decahydronaphthalenes) K-I cis-decaline [ ] 1000µg/mL isooctane 1 1mL MG cis-decaline [ ] neat 1 10mg K-I trans-decaline [ ] 1000µg/mL isooctane 1 1mL MG trans-decaline [ ] neat 1 10mg K-I Decaline (cis+trans) [ ] 1000µg/mL isooctane 1 1mL I 1-Methyldecaline [ ] 500µg/mL isooctane 1 1mL 238

241 I 2-Isopropyldecaline [ ] 500 µg/ml isooctane 1 1mL I 1,1,4,4,5-Pentamethyldecaline µg/mL isooctane 1 1mL KIT Decaline Kit Kit KIT Decaline/Dihydro-/exahydronaphthalene Kit Kit Tetralines (tetrahydronaphthalenes) K-I Tetraline [ ] 1000µg/mL isooctane 1 1mL K-I 1-Methyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 5-Methyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 6-Methyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 1,4-Dimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 1,8-Dimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 2,7-Dimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 5,7-Dimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 2-Ethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 5-Ethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 6-Ethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,6-Trimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 1,5,8-Trimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 2,5,8-Trimethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,5,7-Tetramethyltetraline [ ] 1000µg/mL isooctane 1 1mL K-I 6,7-Diethyl-1,1,4,4-tetramethyltetraline [ ] 1000µg/mL isooctane 1 1mL KIT Tetraline Kit, Kit Indanes and indenes MG Inden [ ] neat 1 100mg MG Indan [ ] neat 1 100mg K-I 1-Methylindene [ ] 1000µg/mL isooctane 1 1mL K-I 5-Methylindan [ ] 1000µg/mL isooctane 1 1mL K-I 1,4,7-Trimethylindan [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,5,6-Tetramethylindan [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,3,3,5-Pentamethylindan [ ] 1000µg/mL isooctane 1 1mL K-I 1-Phenyl-1,3,3-trimethylindan [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,3,5-Tetramethyl-3-neopentylindan [ ] 1000µg/mL isooctane 1 1mL KIT Indan/Inden Kit Kit Aminoindanes MG 1-Aminoindan [ ] neat 1 10mg MG 2-Aminoindan [ ] neat 1 10mg MG 5-Aminoindan [ ] neat 1 10mg KIT Aminoindan Kit Kit xyindanes MG 5-ydroxy-1-indanone [ ] neat 1 10mg Compounds 239

242 ther bicyclic compounds Norbornane [ ] MW cis-bicyclo[4.3.0]nonane [ ] MW K-ME 1000µg/mL methanol, 1x1mL K-CY 1000µg/mL cyclohexane, 1x1mL Bicyclo[3.3.0]octane [ ] MW trans-bicyclo[4.3.0]nonane [ ] MW K-CY 1000µg/mL cyclohexane, 1x1mL K-CY 1000µg/mL cyclohexane, 1x1mL Ethylbicyclo[2.2.1]heptane [ ] MW C ,6-Dihydrodicyclopentadiene 3a,4,5,6,7,7a-exahydro- 4,7-methano-1-indene [ ] MW K-CY 1000µg/mL cyclohexane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Tricyclic compounds Deuterated adamantanes K-I Adamantane-d [ ] 1000µg/mL isooctane 1 1mL K-I Adamantane-d [ ] 1000µg/mL isooctane 5 1mL Adamantanes K-I Adamantane [ ] 1000µg/mL isooctane 1 1mL K-I 1-Methyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 1,3-Dimethyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 1-Ethyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 2-Ethyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-/1,4-Dimethyladamantane [ / 1000µg/mL isooctane 1 1mL [ ] K-I 1,3,5-Trimethyladamantane [ ] 1000µg/mL isooctane 1 1mL K-I 1-Ethyl-3-methyladamantane [ ] 1000µg/mL isooctane 1 1mL KIT Adamantane Kit Kit 240

243 Diamantanes K-I Diamantane [ ] 1000µg/mL Isooctane 1 1mL MG Diamantane [ ] neat 1 10mg K-I 1-Methyldiamantane [ ] 1000µg/mL Isooctane 1 1mL ,6-Dimethyldiamantane [ ] Please inquire KIT Diamantane Kit, exclusive of Kit ydrofluorenes K-I Perhydrofluorene [ ] 1000µg/mL Isooctane 1 1mL MG Perhydrofluorene [ ] neat 1 10mg ydrophenanthrenes and hydroanthracenes ,10-Dihydrophenanthrene [ ] MW Dehydroabietine [ ] MW K-I 1000µg/mL isooctane, 1x1mL I 500µg/mL isooctane, 1x1mL ,2,3,4,5,6,7,8- ctahydrophenanthrene [ ] MW Fichtelite [ ] MW I 500µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL α-Methyl-1,2,3,4,9,10- hexahydrophenanthrene (cis/trans) [ ] MW ,10-Dihydroanthracene [ ] MW K µg/mL, isooctane, 1x1 ml Compounds 3 C ydrophenanthrene/ Anthracene Kit K-I 1000µg/mL isooctane, 1x1mL KIT Kit 241

244 Polycyclic compounds (4-7 rings including hydropas) ,2,3,6,7,8-exahydropyrene [ ] MW ,2,3,4,5,6-exahydrochrysene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg T 200µg/mL toluene, 1x1mL ,2,3,3a,4,5-exahydropyrene [ ] MW ,5-Dihydrobenzo[a]pyrene [ ] MW T 200µg/mL toluene 1, 1mL MG neat, 1x10mg exadecahydropyrene Perhydropyrene [ ] MW T 200µg/mL toluene, 1x1mL ,5,7,8,9,10,11,12- ctahydrobenzo[a]pyrene [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL MG neat, 1x10mg ,2,3,4-Tetrahydrochrysene [ ] MW ,2,3,6,7,8,9,10,11,12- Decahydrobenz[e]pyrene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x5mg UG neat, 1x10µg 242

245 ,2,3,3a,4,5,6,7,8,9,9a,10,11,12- Tetradecahydroperylene [ ] MW ,6,7,8,9,10- exahydrobenz[ghi]perylene [ ] MW T MG 200µg/mL toluene 1, 1mL neat, 1x10mg Please Inquire ,4-Dihydrobenzo[ghi]perylene [ ] MW , Tetracosahydrocoronene Perhydrocoronene [ ] MW UG neat, 1x10µg T 200µg/mL toluene, 1x1mL MG neat, 1x10mg Compounds 243

246 Monoterpenoid (monoterpanes) hydrocarbon compounds Azulene [ ] MW (1R)-(+)-trans-Pinane [ ] MW K-X 1000µg/mL hexane, 1x1mL I 500µg/mL isooctane, 1x1mL (1S)-(-)-cis-Pinane [ ] MW Isocamphane [ ] MW C 3 C 3 C K-X 1000µg/mL hexane, 1x1mL C 3 C K-X C µg/mL hexane, 1x1mL (1S)-(-)-trans-Pinane [ ] MW K-X 1000µg/mL hexane, 1x1mL cis-1-isopropyl-4- methylcyclohexane [ ] MW Tricyclene [ ] MW C 3 C C 3 C 3 3 C C K-X 1000µg/mL hexane, 1x1mL K-X 1000µg/mL hexane, 1x1mL trans-1-isopropyl-4- methylcyclohexane [ ] MW Monoterpan Kit KIT Kit K-X 1000µg/mL hexane, 1x1mL (1R)-(+)-cis-Pinane [ ] MW C 3 C 3 C K-X 1000µg/mL hexane, 1x1mL 244

247 Sesquiterpenoid compounds Cadalene [ ] MW (+)-Cyclosativene [ ] MW C 3 3 C 3 C C I 500µg/mL isooctane, 1x1mL I 500µg/mL isooctane, 1x1mL (-)-α-cedrene [ ] MW Guaiazulene [ ] MW C 3 C 3 C 3 3 C I 500µg/mL isooctane, 1x1mL I 500µg/mL isooctane, 1x1mL Chamazulene [ ] MW (+)-Longicyclene [ ] MW C 3 C 3 C 3 C 3 3 C 3 C 3 C K-I 1000µg/mL isooctane, 1x1mL I 500µg/mL isooctane, 1x1mL MG neat, 1x10mg (+)-Cuparene [ ] MW ,6,8-Trimethylazulene [ ] MW C 3 C C 3 3 C 3 C C I 3 C 500µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Sesquiterpenoid Kit KIT Kit Compounds 245

248 Steranes (Tetracyclic compounds) Sterane internal standards d4 Pregnane [ ] MW C d2 C29 ααα (20R)- Ethylcholestane MW I I I I D D C 3 D D C 3 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL 100µg/mL isooctane, 5x1mL 100µg/mL isooctane, 10x1mL I I I I 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL 100µg/mL isooctane, 5x1mL 100µg/mL isooctane, 10x1mL d4 C29 ααα (20R)- Ethylcholestane MW d2 C27 ααα (20R)-Cholestane [ ] MW C 3 3 C C 3 C 3 C I I I 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL 100µg/mL isooctane, 5x1mL 100µg/mL isooctane, 10x1mL I I I I D D 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL 100µg/mL isooctane, 5x1mL 100µg/mL isooctane, 10x1mL d4 C28 (20R)/C29 ααα (20R)- Methyl/Ethylcholestane MW / I I 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL d4 C27 ααα (20R)-Cholestane [ ] MW d3 C21 Monoaromatic Sterane (5α()/5β()) MW D D CD I D D 10µg/mL isooctane, 10x1mL CD I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 5x1mL I 10µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 10x1mL 246

249 d3 C28/C29 Monoaromatic Sterane (5α()/5β()) d2 C28 Triaromatic Sterane [ ] MW D CD 3 CD 3 CD 3 CD 3 D I 10µg/mL isooctane, 1x1mL d2 C20 Triaromatic Sterane [ ] MW C 3 C 3 D I 10µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 5x1mL I 100µg/mL isooctane, 10x1mL d2 C27/C28 Triaromatic Sterane [-/ ] D I 10µg/mL isooctane, 1x1mL I 10µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 5x1mL I 100µg/mL isooctane, 10x1mL d2 C26 Triaromatic Sterane MW D D I I I I 10µg/mL isooctane, 1x1mL 100µg/mL isooctane, 1x1mL 100µg/mL isooctane, 5x1mL 100µg/mL isooctane, 10x1mL Compounds 247

250 Short-chained steranes α()-Androstane [ ] MW Methyl-5α()-pregnane [ ] MW C 3 3 C C 3 C 3 C 3 C I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL α()-Pregnane [ ] MW β()-Cholane [ ] MW C 3 3 C C 3 C 3 C 3 C 3 C I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL β()-Pregnane [ ] MW C Short-chained Sterane Kit KIT Kit C 3 C I 100µg/mL isooctane, 1x1mL 248

251 Cholestane series (C27) A B 6 12 C D ααα (20R)-Cholestane Cholestane [ ] MW C C 3 C 3 C ßαα (20R)-Cholestane Coprostane [ ] MW I C 3 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL ααα (20S)-Cholestane [ ] C C 3 C 3 C 3 C I 100µg/mL isooctane, 1x1mL αββ (20R)-Cholestane [ ] MW C C 3 C 3 C 3 C I 100µg/mL isooctane, 1x1mL Cholestane Isomer Kit KIT Kit Compounds 249

252 Methylcholestanes series (C28) ααα (20R,24R)-24- Methylcholestane [ ] MW αββ (20R,24S)-24- Methylcholestane [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL ααα (20R,24S)-24- Methylcholestane Ergostane [ ] MW Methylcholestane Isomer Kit KIT Kit I 50µg/mL isooctane, 1 x1ml ααα (20R,24R)-24- Methylcholestane and ααα (20R,24R)-24- Ethylcholestane [ /-] MW I Contains: 32% C28, 68% C29 100µg/mL isooctane, 1x1mL 250

253 Ethylcholestanes series (C29) C D A B ααα (20R,24R)-24- Ethylcholestane Stigmastane [ ] αββ (20S,24RS)-24- Ethylcholestane MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL ααα (20S,24RS)-24- Ethylcholestane, 95% [ ] MW βαα (20R,24R)-24- Ethylcholestane [ ] MW I Contains: 48% 24S, 47% 24R 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL Ethylcholestane Isomer Kit αββ (20R,24R)-24- Ethylcholestane [ ] MW KIT Kit I 100µg/mL isooctane, 1x1mL Compounds 251

254 4-Methylsteranes ααα 4α/β-Methylcholestane, 90% [ ] MW ααα (24R)-4α-Methyl-24- ethylcholestane, 93% [ ] MW I Contains: 91% 4α, 8% 4β 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL α-Methyl Sterane Kit KIT Kit Dinosteranes (4,23,24-Trimethylcholestane) ααα (20R,23R,24R)-4α,23,24- Trimethylcholestane (20R, 23R, 24R)-Dinosterane [ ] MW ααα (20R,23R,24S)-4α,23,24- Trimethylcholestane (20R, 23R, 24S)-Dinosterane [ ] MW UG neat, 1x5µg UG neat, 1x5µg Dinosterane Kit Dinosterane Kit KIT Kit C27 Sterenes I Cholest-2-ene [ ] 100µg/mL isooctane 1 1mL I Cholest-3-ene [ ] 100µg/mL isooctane 1 1mL I Cholest-4-ene [ ] 100µg/mL isooctane 1 1mL I Cholest-5-ene [ ] 100µg/mL isooctane 1 1mL I Cholest-8(14)-ene [ ] 100µg/mL isooctane 1 1mL I Cholest-3,5-diene [ ] 100µg/mL isooctane 1 1mL I 3, 5-Cyclocholestane [ ] 100µg/mL isooctane 1 1mL KIT C27 Sterene Kit Kit 252

255 C28-C29 Sterenes I (24S)-24-Methylcholest-8(14)-ene [ ] 100µg/mL isooctane 1 1mL I (24R)-24-Methyl-3,5-cyclocholestane and [ / 200µg/mL isooctane 1 1mL (24R)-24-Ethyl-3,5-cyclocholestane, 5% C28, 61% C ] I (24R)-24-Methylcholest-4-ene and [ / 100µg/mL isooctane 1 1mL (24R)-24-Ethylcholest-4-ene, 7% C28, 83% C ] I (24R)-24-Methylcholest-5-ene and [ / 200µg/mL isooctane 1 1mL (24R)-24-Ethylcholest-5-ene ] I (24S)-24-Ethylcholest-5,22-diene [ ] 100µg/mL isooctane 1 1mL I (24R)-24-Ethylcholest-2-ene, 86% [ ] 100µg/mL isooctane 1 1mL I (24R)-24-Ethylcholest-8(14)-ene [ ] 100µg/mL isooctane 1 1mL I (24S)-24-Ethylcholesta-3,5,22-triene [ ] 100µg/mL isooctane 1 1mL I (24S)-24-Ethyl-3,5-cyclocholest-22-ene µg/mL isooctane 1 1mL I (24R)-24-Methylcholesta-3,5-diene and [ / 200µg/mL isooctane 1 1mL (24R)-24-Ethylcholesta-3,5-diene, 69% C28, 13% C ] I ααα (24R)-24-Methylcholest-3-ene and [ / 100µg/mL isooctane 1 1mL ααα (24R)-24-Ethylcholest-3-ene, 4% C28,, 41% C ] KIT C28/C29 Sterene Kit Kit Diasterenes (20R)-13(17)-Diacholestene [ ] MW (20R,24R)-24-Ethyldiacholest- 13(17)-ene [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL (20S)-13(17)-Diacholestene MW (20S,24R)-24-Ethyldiacholest- 13(17)-ene [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL Compounds Diasterene Kit KIT Kit 253

256 Ring-C monoaromatic steranes C21 Ring-C Monoaromatic sterane (5α(),10β(C3)/5β(),10β(C3)) [ / ] MW C28/C29 Ring-C Monoaromatic sterane (C28 5β(),10β(C3)/5α(), 10β(C3))(C29 5β(), 10β(C3)/5α()10β(C3)) [ / / / ] Contains: 51% 5α, 24% 5β I 100µg/mL isooctane, 1x1mL C21 Ring-C Monoaromatic sterane (5β(),10β(C3)/5α(),10β(C3)) [ / ] MW I Contains: 12% C28 5α, 30% C28 5β 13% C29 5α, 33% C29 5β 100µg/mL isooctane, 1x1mL I Contains: 15% 5α, 59% 5β 100µg/mL isooctane, 1x1mL C27 Ring-C Monoaromatic sterane (5β(),10β(C3)/5α(),10β(C3)) [ / ] MW C29 Ring-C Monoaromatic sterane (5β(),10β(C3)/5α(),10β(C3)) [ / ] MW I Contains: 23% 5α, 46% 5β 100µg/mL isooctane, 1x1mL I Contains: 22% 5α, 53% 5β 100µg/mL isooctane, 1x1mL Ring-C Monoaromatic Sterane Kit KIT Kit 254

257 Diaromatic steranes C26 Diaromatic sterane, 91% [ ] MW Diaromatic Sterane Kit 3 C C KIT Kit C 3 C I 100µg/mL isooctane, 1x1mL C27/C28 Diaromatic steranes [ / ] I Contains: 8% C27, 88% C28 200µg/mL isooctane, 1x1mL Compounds 255

258 Triaromatic steranes C20 Triaromatic sterane [ ] MW C28 Triaromatic ster-14(15)-ene MW C 3 C I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL C26 Triaromatic sterane [ ]MW C28 Triaromatic sterane [ ] MW C 3 3 C C 3 3 C C 3 C 3 C 3 C 3 C I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL C27 Triaromatic ster-14(15)-ene MW Triaromatic Sterane Kit KIT Kit I 100µg/mL isooctane, 1x1mL C27/C28 Triaromatic steranes [ ] / [ ] 3 C C 3 C 3 C 3 C I Contains: 42% C27, 53% C28 200µg/mL isooctane, 1x1mL 256

259 1-Methyl triaromatic sterane C27 1-Methyl triaromatic sterane [ ] MW Methyl Triaromatic Sterane Kit KIT Kit I 100µg/mL isooctane, 1x1mL C28/C29 1-Methyl triaromatic steranes [ / ] I Contains: 8% C28, 74% C29 100µg/mL isooctane, 1x1mL Sterane precursors Cycloartane [ ] MW Lanosterol [ ] MW I 100µg/mL isooctane, 1x1mL Lanostane [ ] MW AN 100µg/mL acetonitrile, 1x1mL Sterol Precursor Kit KIT Kit Compounds I 100µg/mL isooctane, 1x1mL 257

260 Triterpanes/hopanes (Pentacyclic compounds) opane internal standards d2 Isoadiantane MW β(),21β()-opane [ ] MW m/z 193 D D m/z I 10µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL α(),21α()-opane [ ] MW β(),21α()-(22RS)- Pentakishomohopane 35βα 22RS MW I 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1 ml 258

261 C27 opanes (trisnorhopanes) α()-22,29,30-Trisnorhopane Tm [ ] MW β(),21α()-25,28,30- Trisnorhopane 25nor28βα [ ] MW I 100µg/mL isooctane, 1x1mL UG neat, 1x5µg β()-22,29,30-Trisnorhopane βtm [ ] MW β(),21β()-25,28,30- Trisnorhopane 25nor28ββ [ ] MW UG neat, 1x5µg α()-22,29,30- Trisnorneohopane Ts (27Ts) [ ] MW UG neat, 1x5µg Trisnorhopanes Kit KIT Kit UG neat, 1x5µg α(),21β()-25,28,30- Trisnorhopane 25nor28aβ [ ] MW Compounds UG neat, 1x5µg 259

262 C28 opanes (bisnorhopanes) α(),21β()-28,30- Bisnorhopane 28αβ [ ] MW Bisnorhopane Kit KIT Kit UG neat, 1x5µg β(),21α()-28,30- Bisnorhopane 28βα [ ] MW UG neat, 1x5µg 260

263 C29 opanes (norhopanes) α(),21α()-30-Norhopane 29αα [ ] MW α(),21β()-25-Bisnorhopane 25Nor [ ] MW I 50µg/mL isooctane, 1x1mL UG neat, 1x5µg α(),21β()-30-Norhopane 29αβ [ ] MW β(),18α()-28-Norspergulane 29Nsp MW I 50µg/mL isooctane, 1x1mL UG neat, 1x5µg β(),21α()-30-Norhopane 29βα [ ] MW Norhopanes Kit KIT Kit I 100µg/mL isooctane, 1x1mL β(),21β()-30-Norhopane 29ββ [ ] MW UG neat, 1x5µg Compounds 261

264 C30 opanes α(),21α()-opane 30αα [ ] MW α(),21α()-30-Nor-29- methylhopane MW I 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1mL α(),21β()-opane 30αβ [ ] MW α(),21β()-30-Nor-29- methylhopane MW I 100µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1mL β(),21α()-opane 30βα [ ] MW α()-30-Diahopane 30D MW I 100µg/mL isooctane, 1x1mL UG neat, 1x5µg β(),21β()-opane 30ββ [ ] MW β(),21α()-22-Methyl-28- nor-spergulane 30 Nsp MW I 100µg/mL isooctane, 1x1mL UG neat, 1x5µg C30 opane Kit KIT Kit 262

265 C31 opanes (homohopanes) α(),21α()-(22RS)- omohopane 31αα 22RS MW β(),21α()-(22RS)- omohopane 31βα 22RS [ ] MW UG neat, 1x10µg UG neat, 1x10µg α(),21β()-(22R)- omohopane 31αβ 22R [ ] MW β(),21β()-(22RS)- omohopane 31ββ 22RS [ ] MW I 50µg/mL isooctane, 1x1mL UG neat, 1x10µg α(),21β()-(22S)- omohopane 31αβ 22S [ ] MW omohopane Kit KIT Kit I 50µg/mL isooctane, 1x1mL α(),21β()-(22RS)- omohopane 31αβ 22RS [ / ] MW Compounds UG I neat, 1x10µg 50µg/mL isooctane, 1x1mL 263

266 C32 opanes (bishomohopanes) α(),21α()-(22RS)- Bishomohopane 32αα 22RS [ ] MW β(),21β()-(22RS)- Bishomohopane 32ββ 22RS [ ] MW UG neat, 1x10µg UG neat, 1x10µg α(),21β()-(22RS)- Bishomohopane 32αβ 22RS [ ] MW Bishomohopane, Isomer mix MW I 100µg/mL isooctane, 1x1mL Bishopane Kit Including UG neat, 1x10µg KIT Kit I 50µg/mL isooctane, 1x1mL β(),21α()-(22RS)- Bishomohopane 32βα 22RS MW UG neat, 1x5µg 264

267 C33 opanes (trishomohopanes) α(),21α()-(22RS)- Trishomohopane 33αα 22RS [ ] MW β(),21β()-(22RS)- Trishomohopane 33ββ 22RS [ ] MW UG neat, 1x10µg UG neat 1x10µg α(),21β()-(22RS)- Trishomohopane 32αβ 22RS [ ] [ ] MW Trishomohopane Kit KIT Kit I UG 50µg/mL isooctane, 1x1mL neat, 1x10µg Compounds 265

268 C34 opanes (tetrakishomohopanes) α(),21β()-(22R)- Tetrakishomohopane 34αβ 22R [ ] MW β(),21α()-(22R)- Tetrakishomohopane 34βα 22R [ ] MW UG neat, 1x10µg UG neat, 1x10µg α(),21β()-(22S)- Tetrakishomohopane 34αβ 22S [ ] MW β(),21α()-(22S)- Tetrakishomohopane 34βα 22S [ ] MW UG neat, 1x10µg UG neat, 1x5µg α(),21β()-(22RS)- Tetrakishomohopane 34αβ 22RS [ ] MW Tetrakishomohopane Kit KIT Kit UG neat, 1x10µg 266

269 C35 opanes (pentakishomohopanes) α(),21β()-(22RS)- Pentakishomohopane 35aβ 22RS [ ] MW Pentakishomohopane Kit KIT Kit UG neat, 1x10µg Nor- and homohopane kit β(),21α()-(22RS)- Pentakishomohopane 35βα 22RS MW opane Kit (All nor- and homohopane Kits above) KIT Kit UG neat, 1x10µg Rearranged hopanes α()-22,29,30- Trisnorneohopane Ts (27Ts) [ ] MW α()-30-Diahopane 30D MW UG neat, 1x5µg β(),18α()-28-Norspergulane 29Nsp MW UG neat, 1x5µg Rearranged hopane Kit KIT Kit Compounds UG neat, 1x5µg 267

270 2-Methylhopanes α,17α(),21α()-2- Methylhopane [ ] MW α,17β(),21α()-2- Methylhopane MW UG neat, 1x10µg UG neat, 1x10µg α,17α(),21β()-2- Methylhopane MW α,17β(),21β()-2- Methylhopane MW UG neat 1, 10µg UG neat, 1x10µg 3-Methylhopanes α,17α(),21β()-3- Methylhopane MW and 3-Methylhopanes Kit KIT Kit UG neat, 1x10µg 268

271 openes C27 openes (trisnorhopenes) ,29,30-Trisnorhop-17(21)-ene [ ] MW ,29,30-Trisnorneohop- 13(18)-ene [ ] MW I 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x0.5mL C29 openes (norhopenes) β(),21α()-30-Norhop- 2(3)-ene [ ] MW Norhop-17(21)-ene [ ] MW UG neat, 1x10µg I 100µg/mL isooctane. 1x1mL Norneohop-13(18)-ene [ ] MW Nor-spergula-12(13), 17(18)-diene MW I 50µg/mL isooctane, 1x0.5mL UG neat, 1x5µg Compounds 269

272 C30 openes and fernenes op-17(21)-ene [ ] MW Neohop-13(18)-ene [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL α()-30-Diahop-13(14)-ene MW op-21(22)-ene [ ] MW UG neat, 1x5µg Fern-9(11)-ene [ ] MW I 100µg/mL isooctane, 1x1mL op-22(29)-ene [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL C31/C32 openes (homohopenes/bishomohopenes) (22R)-30-omohop-17(21)-ene [ ] MW (22RS)-30-Bishomohop- 17(21)-ene MW I 50µg/mL isooctane, 1x0.5mL UG neat, 1x5µg opene/fernene Kit KIT Kit 270

273 Lupanes Lupane [ ] MW Norlupane (17β()/17α()) [ / ] MW I 100µg/mL isooctane, 1x1mL Contains: 33% 17α, 62% 17β β()-28-Norlupane [ ] MW I 100µg/mL isooctane, 1x1mL Lupane Kit KIT Kit I 100µg/mL isooctane, 1x1mL Lupenes Lup-20(29)-ene, 93% [ ] MW Norlup-17(22)-ene [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL Norlup-16(17)-ene, 94% [ ] MW Lupene Kit KIT Kit Compounds I 100µg/mL isooctane, 1x1mL 271

274 leananes α()-leanane 18α [ ] MW leanane Kit KIT Kit I 100µg/mL isooctane, 1x1mL β()-leanane 18α [ ] MW I 100µg/mL isooctane, 1x1mL Ursenes and oleanenes β()-lean-12(13)-ene [ ] MW Ursene/leanene Kit KIT Kit I MG 100µg/mL isooctane, 1x1mL neat, 1x2mg Urs-12(13)-ene [ ] MW I MG 100µg/mL isooctane, 1x1mL neat, 1x10mg 272

275 Gammacerane Gammacerane G [ ] MW UG neat, 1x10µg ther triterpanes Friedelane, 91% [ ] MW (20R/20S)-Dammarane (50/50) MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL nocerane I (8β(),14α()) [ ] MW Triterpane Kit (ther than hopanes) KIT Kit Contains: 84% onocerane I, 13% onocerane II I 100µg/mL isooctane, 1x1mL nocerane II (8β(),14β()) [ ] MW Contains: 86% onocerane I, 13% onocerane II I 100µg/mL isooctane, 1x1mL Compounds ther petroleum products 1025 Purified Asfalthenes Please inquire ML North sea oil - 1 neat 100mL 273

276 Naphthenic acids, cyclic aromatic and aliphatic acids Monocyclic aliphatic acids Cyclohexanecarboxylic acid [ ] MW ,4-Cyclohexanedicarboxylic acid [ ] MW C C G neat, 1x1g G C neat, 1x1g Cyclohexylacetic acid [ ] MW Cyclohexylpropionic acid [ ] MW C C G neat, 1x1g G neat, 1x1g cis-1,2-cyclohexanedicarboxylic acid [ ] MW Cyclohexylbutyric acid [ ] MW C C C G neat, 1x1g G neat, 1x1g trans-1,2- Cyclohexanedicarboxylic acid [ ] MW tert- Butylcyclohexanecarboxylic acid [ ] MW C C C 3 C 3 C3C G neat, 1x1g G neat, 1x1g 274

277 Cyclohexylpentanoic acid [ ] MW Cyclohexyloctadecanoic acid [ ] MW C C MG neat, 1x100mg MG neat, 1x10mg eptylcyclohexanecarboxylic acid [ ] MW Monocyclic aliphatic acid Kit KIT Kit C MG neat, 1x100mg F n- Dodecylcyclohexanecarboxylic acid [ ] MW C F MG neat, 1x100mg Compounds 275

278 Monocyclic aromatic acids R C 2 C n C G Benzoic acid [ ] neat 1 1g G o-toluic acid [ ] neat 1 1g G m-toluic acid [ ] neat 1 1g G p-toluic acid [ ] neat 1 1g G Phenylacetic acid [ ] neat 1 1g G 2,4-Dimethylbenzoic acid [ ] neat 1 1g G 3-Phenylpropionic acid [ ] neat 1 1g G 4-Ethylbenzoic acid [ ] neat 1 1g G DL-2-Phenylpropionic acid [ ] neat 1 1g G 2-Phenylbutyric acid [ ] neat 1 1g G 3-Phenylbutyric acid [ ] neat 1 1g G 4-n-Propylbenzoic acid [ ] neat 1 1g G 4-Phenylbutyric acid [ ] neat 1 1g G 5-Phenylpentanoic acid [ ] neat 1 1g G 4-n-Butylbenzoic acid [ ] neat 1 1g G 4-n-Pentylbenzoic acid [ ] neat 1 1g MG 6-Phenylhexanoic acid [ ] neat 1 100mg MG 4-n-exylbenzoic acid [ ] neat 1 100mg G 4-n-eptylbenzoic acid [ ] neat 1 1g G 4-n-ctylbenzoic acid [ ] neat 1 1g F MG 4-n-Dodecylbenzoic acid [ ] neat 1 100mg MG 18-Phenyloctadecanoic acid [ ] neat 1 10mg KIT Monocyclic aromatic acid Kit Kit 276

279 Bicyclic aliphatic acid Naphthalene pentanoic acid, decahydro [ ] MW C eptyldecahydronaphthalene- 2-carboxylic acid [ ] MW C MG neat, 1x10mg MG neat, 1x10mg Butyldecahydronaphthalene- 1-carboxylic acid [ ] MW n- Dodecyldecahydronaphthalene- 2-carboxylic acid MW C C C 3 Please inquire MG neat, 1x10mg Decahydronaphthalene pentanoic acid [ ] MW Bicyclic aliphatic acid Kit (Not including ) KIT Kit C MG neat, 1x10mg Compounds 277

280 Bicyclic aromatic acids ,2,3,4-Tetrahydro-2-naphthoic acid [ ] MW ,7-Naphthalenedicarboxylic acid [ ] MW C C C MG neat, 1x100mg G neat, 1x1g Naphthylacetic acid [ ] MW n-eptylnaphthalene-2- carboxylic acid [ ] MW C C G neat, 1x1g MG neat, 1x100mg ,3-Naphthalenedicarboxylic acid [ ] MW n-Dodecylnaphthalene-2- carboxylic acid [ ] MW C C C MG neat, 1x100mg ,6-Naphthalenedicarboxylic acid [ ] MW MG neat, 1x100mg Bicyclic aromatic acid Kit KIT Kit C C MG neat, 1x100mg 278

281 Tricyclic aliphatic acids Dehydroabietic acid [ ] MW Abietic acid [ ] MW K-ME 1000µg/mL methanol, 1x1mL K-ME 1000µg/mL methanol, 1x1mL Tricyclic aromatic acids C MG 1-Anthracenecarboxylic acid [ ] neat 1 100mg MG 2-Anthracenecarboxylic acid [ ] neat 1 100mg G 9-Anthracenecarboxylic acid [ ] neat 1 1g MG 1,8-Anthracenedicarboxylic acid [ ] neat 1 100mg Tetracyclic aliphatic acids β-Cholanic acid [ ] MW C MG neat, 1x10mg Tetracyclic aromatic acids G 1-Pyrenebutyric acid [ ] neat 1 1g C KIT Tri- and tetracyclic aromatic acid Kit Kit KIT Tri- and tetracyclic aliphatic acid Kit Kit Compounds 279

282 Pentacyclic aliphatic acids β-Acetoxybetulinic acid [ ] MW Keto-β-boswellic acid [ ] MW MG neat, 1x10mg MG neat, 1x10mg Betulinic acid [ ] MW Ursolic acid [ ] MW C MG neat, 1x10mg MG neat, 1x10mg β-boswellic acid [ ] MW MG neat, 1x10mg 280

283 Dicarboxylic acids Adipic acid exanedioc acid [ ] MW cis-1,2-cyclohexanedicarboxylic acid [ ] MW C C G neat, 1x1g G neat, 1x1g ,8-Anthracenedicarboxylic acid [ ] MW trans-1,2- Cyclohexanedicarboxylic acid [ ] MW C C C C MG neat, 1x100mg G neat, 1x1g Azelaic acid Nonanedioic acid [ ] MW ,4-Cyclohexanedicarboxylic acid [ ] MW C G neat, 1x1g C G neat, 1x1g ,1-Cyclohexanediacetic acid [ ] MW Glutaric acid Pentadioic acid [ ] MW C C G neat, 1x1g G neat, 1x1g Compounds 281

284 Isophthalic acid 1,3-Benzenedicarboxylic acid [ ] MW Methylsuccinic acid [ ] MW G neat, 1x1g G neat, 1x1g Malonic acid Propanedioic acid [ ] MW ,3-Naphthalenedicarboxylic acid [ ] MW C C G neat, 1x1g MG neat, 1x100mg Methylmalonic acid Methylpropanedioic acid [ ] MW ,6-Naphthalenedicarboxylic acid [ ] MW C C C G neat, 1x1g MG neat, 1x100mg Methylphthalic acid [ ] MW ,7-Naphthalenedicarboxylic acid [ ] MW C C C G neat, 1x1g G neat, 1x1g 282

285 ,8-Naphthalic anhydride [ ] MW Suberic acid ctanedioc acid [ ] MW G neat, 1x1g G neat, 1x1g Pimelic acid eptanedioic acid [ ] MW Succinic acid Butanedioic acid [ ] MW G neat, 1x1g G neat, 1x1g Phthalic acid 1,2-Benzenedicarboxylic acid [ ] MW Terephthalic acid 1,4-Benzenedicarboxylic acid [ ] MW G neat, 1x1g G neat, 1x1g Sorbic acid (E,E)-2,4-exadienoic acid [ ] MW G C 3 neat, 1x1g Compounds 283

286 Tricarboxylic acids Tetracarboxylic acids Trimellitic acid 1,2,4-Benzenetricarboxylic acid [ ] MW ,2,4,5-Benzenetetracarboxylic acid Pyrometillic acid [ ] MW G neat, 1x1g G neat, 1x1g Compounds by functional groups Aliphatic alcohols ML tert-amylalcohol [ ] neat 1 1mL ML 1-Butanol [ ] neat 1 5mL ML sec-butanol [ ] neat 1 5mL ML tert-butanol [ ] neat 1 1mL G 2-Butoxyethanol [ ] neat 1 5g ML 1-Decanol [ ] neat 1 5mL ML Ethanol [ ] neat 1 5mL ML 2-Ethyl-1-hexanol [ ] neat 1 1mL ML 1-eptanol [ ] neat 1 5mL ML 4-eptanol [ ] neat 1 1mL K-I 1-exacosanol [ ] 1000µg/mL isooctane 1 1mL ML 1-exanol [ ] neat 1 5mL ML 2-exanol [ ] neat 1 1mL ML 3-exanol [ ] neat 1 1mL ML Isopropanol [ ] neat 1 10mL ML Methanol [ ] neat 1 5mL ML 2-Methyl-1-propanol [ ] neat 1 1mL ML DL-3-Methyl-2-butanol [ ] neat 1 1mL ML 4-Methyl-1-pentanol [ ] neat 1 1mL K-I 1-ctacosanol [ ] 1000µg/mL isooctane 1 1mL ML 1-ctanol [ ] neat 1 5mL ML 1-Pentanol [ ] neat 1 5mL ML 1-Propanol [ ] neat 1 5mL KIT Aliphatic alcohol Kit Kit Ethers/esters (see also fatty esters, pages ) ML tert-amyl methyl ether [ ] neat 1 1mL K-X Benzyl benzoate [ ] 2000µg/mL hexane 1 1mL G 2-Butoxyethyl acetate [ ] neat 1 1g ML tert-butyl ethyl ether [ ] neat 1 1mL ETBE, Ethyl t-butyl ether ML tert-butyl methyl ether [ ] neat 1 1mL MTBE, Methyl t-butyl ether ML Diisopropyl ether [ ] neat 1 1mL 284

287 G Dimethyl azelate [ ] neat 1 1g ML 2-Ethoxyethyl acetate [ ] neat 1 4mL ML Isopropyl acetate [ ] neat 1 1mL ML Methyl acetate [ ] neat 1 1mL ML Methyl formate [ ] neat 1 1mL F G 2-Methoxy-1-propyl acetate [ ] neat 1 1 ml MG Stearyl stearate [ ] neat 1 100mg Diols, glycols and derivatives G 1,2-Ethanediol Ethylene glycol [ ] neat 1 10g ML 1,2-Propanediol [ ] neat 1 1mL ML 1,2-Butanediol [ ] neat 1 1mL ML 1,2-Pentandiol [ ] neat 1 1mL ML 1,2-exanediol [ ] neat 1 1mL ML 1,2-Dimethoxyethane [ ] neat 1 1mL G 2-Ethoxyethanol [ ] neat 1 1g ML Diethylene glycol [ ] neat 1 5mL ML Triethylene glycol [ ] neat 1 5mL G Methyl acrylamido glycolate methyl ether MAGME [ ] neat 1 1g Aliphatic ketones ML 2-Butanone [ ] neat 1 1mL ML 3-Pentanone [ ] neat 1 1mL ML 2-exanone [ ] neat 1 1mL ML 3-exanone [ ] neat 1 1mL K-ME 4-Methyl-2-pentanone [ ] 2000µg/mL methanol 1 1mL ML 2-eptanone [ ] neat 1 1mL ML 3-eptanone [ ] neat 1 1mL ML 3-ctanone [ ] neat 1 1mL KIT Aliphatic ketone Kit Kit Cyclic alcohols and ketones L-(-)-Borneol [ ] MW (S)-(-)-Verbenone [ ] MW K-I 1000µg/mL isooctane, 1x1mL L-(-)-Fenchone [ ] MW K-I 1000µg/mL isooctane, 1x1mL Compounds K-I 1000µg/mL isooctane, 1x1mL 285

288 Phenones ML Acetophenone [ ] neat 1 1mL ML Propiophenone [ ] neat 1 1mL ML n-butyrophenone [ ] neat 1 1mL ML n-valerophenone Pentanophenone [ ] neat 1 1mL ML n-exanophenone [ ] neat 1 1mL ML Benzophenone [ ] neat 1 1mL ML n-eptanophenone [ ] neat 1 1mL ML n-ctanophenone [ ] neat 1 1mL KIT Phenone Kit Kit Amines ML Acetanilide [ ] neat 1 1mL ML Aniline [ ] neat 1 1mL ML 4-Chloroaniline [ ] neat 1 1mL ML 4-Chloro-2-methylaniline [ ] neat 1 1mL I 2,4-Diaminoanisole [ ] 100µg/mL isooctane 1 1mL MG 2,4-Diaminoanisole [ ] neat 1 10mg K-I Di-(3-phenyl-1-propyl)amine [ ] 1000µg/mL isooctane 1 1mL K-I N-Ethyl,N-(3-phenylpropyl)-3- (4-hydroxyphenyl)propylamine [ ] 1000µg/mL isooctane 1 1mL I 4,4 -Methylenebis(2-chloroaniline) [ ] 100µg/mL isooctane 1 1mL K-I N-(3-Phenylpropyl)-3- (4-hydroxyphenyl)propylamine µg/mL isooctane 1 1mL ML Trimethylamine [ ] neat 1 5mL K-I Tri-(3-phenyl)-1-propylamine [ ] 1000µg/mL isooctane 1 1mL Aromatic amines ML 2,4-Diaminotoluene [ ] neat 1 1mL I 2-Methoxy-5-methylaniline [ ] 100µg/mL isooctane 1 1mL ML o-toluidine [ ] neat 1 1mL I 2,4,5-Trimethylaniline [ ] 100µg/mL isooctane 1 1mL Chlorobenzenes Internal standards 2 C n K-I 1,4-Dichlorobenzene-d [ ] 1000µg/mL Isooctane 1 1mL I exachlorobenzene-13c [ ] 100µg/mL isooctane 1 1mL K-ME 1-Chloro-4-fluorobenzene, Internal standard for Gasoline Range Analysis [ ] 1000µg/mL methanol 1 1mL K-ME 1-Chloro-4-fluorobenzene, Internal standard for Gasoline Range Analysis [ ] 1000µg/mL methanol 5 1mL Native chlorobenzenes K-I Chlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG Chlorobenzene [ ] neat 1 100mg K-I 1,2-Dichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2-Dichlorobenzene [ ] neat 1 100mg K-I 1,3-Dichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,3-Dichlorobenzene [ ] neat 1 100mg K-I 1,4-Dichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,4-Dichlorobenzene [ ] neat 1 100mg K-I 1,2,3-Trichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2,3-Trichlorobenzene [ ] neat 1 100mg 286

289 K-I 1,2,4-Trichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2,4-Trichlorobenzene [ ] neat 1 100mg K-I 1,3,5-Trichlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,3,5-Trichlorobenzene [ ] neat 1 100mg K-I 1,2,3,4-Tetrachlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2,3,4-Tetrachlorobenzene [ ] neat 1 100mg K-I 1,2,3,5-Tetrachlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2,3,5-Tetrachlorobenzene [ ] neat 1 100mg K-I 1,2,4,5-Tetrachlorobenzene [ ] 1000µg/mL Isooctane 1 1mL MG 1,2,4,5-Tetrachlorobenzene [ ] neat 1 100mg K-I Pentachlorobenzene [ ] 1000µg/mL isooctane 1 1mL ML Pentachlorobenzene [ ] neat 1 1mL ML Pentachlorobenzene [ ] neat 1 5mL K-I exachlorobenzene [ ] 1000µg/mL isooctane 1 1mL G exachlorobenzene [ ] neat 1 1g KIT-N Chlorobenzene Kit (Natives neat) Kit KIT-S Chlorobenzene Kit (Natives in solution) Solutions Kit Bromobenzenes I Bromobenzene Monobromobenzene [ ] 50µg/mL isooctane 1 1mL ML Bromobenzene Monobromobenzene [ ] neat 1 1mL I 1,2-Dibromobenzene [ ] 50µg/mL isooctane 1 1mL ML 1,2-Dibromobenzene [ ] neat 1 1mL I 1,3-Dibromobenzene [ ] 50µg/mL isooctane 1 1mL ML 1,3-Dibromobenzene [ ] neat 1 1mL I 1,4-Dibromobenzene [ ] 50µg/mL isooctane 1 1mL ML 1,4-Dibromobenzene [ ] neat 1 1mL I 1,2,4-Tribromobenzene [ ] 50µg/mL isooctane 1 1mL ML 1,2,4-Tribromobenzene [ ] neat 1 1mL I 1,3,5-Tribromobenzene [ ] 50µg/mL isooctane 1 1mL ML 1,3,5-Tribromobenzene [ ] neat 1 1mL I 1,2,4,5-Tetrabromobenzene [ ] 50µg/mL isooctane 1 1mL I Pentabromotoluene [ ] 50µg/mL isooctane 1 1mL I exabromobenzene [ ] 50µg/mL isooctane 1 1mL KIT Bromobenzene Kit Kit Ammonium halides ME Tetramethylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetraethylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetrabutylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetrahexylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetraoctylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetradodecylammonium bromide [ ] 100µg/mL methanol 1 1mL ME Tetraoctadecylammonium bromide [ ] 100µg/mL methanol 1 1mL Compounds 287

290 Sulfur compounds Thiols Alkanethiols ML Ethanethiol [ ] neat 1 1mL ML 1-Propanethiol [ ] neat 1 1mL ML 2-Propanethiol [ ] neat 1 1mL ML 1-Butanethiol [ ] neat 1 1mL ML 2-Butanethiol [ ] neat 1 1mL ML 2-Methyl-1-propanethiol [ ] neat 1 1mL ML 2-Methyl-2-propanethiol [ ] neat 1 1mL ML 1-Pentanethiol [ ] neat 1 1mL ML 2-Methyl-1-butanethiol [ ] neat 1 1mL MG 2-Methyl-2-butanethiol [ ] neat 1 100mg ML 2-Methyl-2-butanethiol [ ] neat 1 5mL ML 3-Methyl-1-butanethiol [ ] neat 1 1mL MG 3-Methyl-2-butanethiol [ ] neat 1 100mg ML 3-Methyl-2-butanethiol [ ] neat 1 5mL MG 1-exanethiol [ ] neat 1 100mg ML 1-exanethiol [ ] neat 1 5mL MG 2,3-Dimethyl-2-butanethiol [ ] neat 1 100mg ML 2,3-Dimethyl-2-butanethiol [ ] neat 1 5mL MG 2-Methyl-2-pentanethiol [ ] neat 1 100mg ML 2-Methyl-2-pentanethiol [ ] neat 1 5mL ML 1-eptanethiol [ ] neat 1 1mL MG 1-eptanethiol [ ] neat 1 100mg ML 1-ctanethiol [ ] neat 1 1mL ML 1-Nonanethiol [ ] neat 1 1mL ML 1-Decanethiol (96%) [ ] neat 1 1mL ML 1-Decanethiol (99%) [ ] neat 1 1mL KIT Alkanethiol Kit (100mg of 83.5/84.5/86.6/87.6/88.6/89.7) Kit Cycloalkanethiols ML Cyclopentanethiol [ ] neat 1 1mL ML Cyclohexanethiol [ ] neat 1 1mL KIT Cycloalkylthiol Kit Kit Thiophenols ML Thiophenol [ ] neat 1 1mL ML alpha-toluenethiol [ ] neat 1 1mL S ML o-thiocresol [ ] neat 1 1mL S ML m-thiocresol [ ] neat 1 1mL MG p-thiocresol [ ] neat 1 100mg MG 2,4-Dimethylthiophenol [ ] neat 1 100mg 3 C S C 3 288

291 MG 2,5-Dimethylthiophenol [ ] neat 1 100mg MG 2,6-Dimethylthiophenol [ ] neat 1 100mg MG 3,4-Dimethylthiophenol [ ] neat 1 100mg 3 C S 3 C MG 3,5-Dimethylthiophenol [ ] neat 1 100mg MG 2-Ethylthiophenol [ ] neat 1 100mg ML 3-Ethylbenzenethiol [ ] neat 1 1mL MG 4-Ethylthiophenol [ ] neat 1 100mg MG 4-Isopropylthiophenol [ ] neat 1 100mg K-AC 3,4-Dimercaptotoluene [ ] 1000µg/mL acteone 1 1mL C 3 S S KIT Thiophenol Kit Kit Sulfides Aliphatic sulfides ML Ethylene sulfide [ ] neat 1 1mL S ML Dimethylsulfide [ ] neat 1 1mL ML Ethylmethylsulfide [ ] neat 1 1mL ML Diethylsulfide [ ] neat 1 1mL ML Methylisopropylsulfide [ ] neat 1 1mL ML Methyl-n-propylsulfide [ ] neat 1 1mL ML Ethyl-n-propylsulfide [ ] neat 1 1mL MG Methyl-n-butylsulfide [ ] neat 1 100mg 3 C S C ML Methyl-n-butylsulfide [ ] neat 1 5mL MG Methyl-tert-butylsulfide [ ] neat 1 100mg ML Methyl-tert-butylsulfide [ ] neat 1 5mL ML Di-n-propylsulfide [ ] neat 1 1mL C 3 S C ML Diisopropylsulfide [ ] neat 1 1mL ML Di-n-butylsulfide [ ] neat 1 1mL ML Di-tert-butylsulfide [ ] neat 1 1mL G Di-n-octylsulfide [ ] neat 1 1g KIT Thioalkane Kit Kit Cycloalkylthioalkanes MG Cyclopentylmethylsulfide [ ] neat 1 100mg Compounds C 3 S ML Cyclopentylmethylsulfide [ ] neat 1 5mL 289

292 Phenylthioalkanes ML Methylphenylsulfide [ ] neat 1 1mL S C ML Ethylphenylsulfide [ ] neat 1 1mL Thiocycloalkanes ML Trimethylenesulfide [ ] neat 1 1mL S ML Tetrahydrothiophene [ ] neat 1 1mL S MG 2-Methyltetrahydrothiophene [ ] neat 1 100mg ML 2-Methyltetrahydrothiophene [ ] neat 1 1mL MG 3-Methyltetrahydrothiophene [ ] neat 1 100mg ML 3-Methyltetrahydrothiophene [ ] neat 1 5mL MG Thiocyclohexane [ ] neat 1 100mg ML Thiocyclohexane [ ] neat 1 5mL KIT Thiocycloalkane Kit Kit I 4,4 -Thiodianiline [ ] 100µg/mL isooctane 1 1mL Diphenylsulfides I Diphenylsulfide [ ] 500µg/mL isooctane 1 1mL I 2-Methyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL S C I 3-Methyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL I 4-Methyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL I 2,4-Dimethyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL C 3 S C I 2,5-Dimethyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL C 3 S C I 3,4-Dimethyldiphenylsulfide [ ] 500µg/mL isooctane 1 1mL C 3 S C KIT Diphenylsulfide Kit Kit 290

293 Polysulfur compounds Polysulfur Kit I Dimethyldisulfide [ ] MW Di-tert-butyldisulfide [ ] MW G neat, 1x1g ML neat, 1x1mL ,3-Dithiane [ ] MW Diisopentyldisulfide Diisoamildisulphide [ ] MW S S S S G neat, 1x1g ,4-Dithiane [ ] MW S G neat, 1x1g K-I 1000µg/mL isooctane, 1x1mL Di-n-pentyldisulfide [ ] MW S G neat, 1x1g G neat, 1x1g Diethyldisulfide [ ] MW ,2,5,2 -Terthiophene [ ] MW G neat, 1x1g S S S Methylpropyldisulfide [ ] MW K-I 1000µg/mL, isooctane, 1x1mL G neat, 1x1g Di-n-propyldisulfide [ ] MW G neat, 1x1g Compounds Di-n-butyldisulfide [ ] MW G neat, 1x1g 291

294 m-difluorodiphenyldisulfide Bis(3-fluorophenyl)disulfide [ ] MW Di-n-decyldisulfide [ ] MW G neat, 1x1g F S S F Di-n-octadecyldisulfide [ ] MW K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Di-n-heptyldisulfide [ ] MW K-I 1000µg/mL isooctane, 1x1mL G neat, 1x1g Polysulfur Kit I KIT Kit Di-n-octyldisulfide [ ] MW C S S C K-I MG 1000µg/mL isooctane, 1x1mL neat, 1x100mg 292

295 Polysulfur Kit II (Methylthio)thiophene [ ] MW (Phenylthio)thiophene [ ] MW S C 3 S S S MG neat, 1x100mg K-I 1000µg/mL isooctane, 1x1mL (Methylthio)thiophene [ ] MW (Phenylthio)thiophene [ ] MW S C K-I 1000µg/mL isooctane, 1x1mL MG S neat, 1x100mg Thianthrene [ ] MW Methylphenyldisulfide [ ] MW S S K-I 1000µg/mL isooctane, 1x1mL G S 3 C S neat, 1x1g Diphenyldisulfide [ ] MW ,2 -Dithienyl [ ] MW K-I 1000µg/mL isooctane, 1x1mL Di(2-thienyl)disulfide [ ] MW S S K-I 1000µg/mL isooctane, 1x1mL S S S S ,4-Dimethylthieno[2,4-b] thiophene [ ] MW K-I 1000µg/mL isooctane, 1x1mL Bis(phenylthio)methane [ ] MW Compounds 3 C C 3 S S S S K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL 293

296 Di-n-hexyldisulfide [ ] MW ,4 -Diphenyltetrathiafulvalene [ ] MW G neat, 1x1g S S ,2-Bis(phenylthio)ethane [ ] MW K-T S 1000µg/mL toluene, 1x1mL S S S Polysulfur Kit II KIT Kit K-I 1000µg/mL isooctane, 1x1mL ,5-Diphenyl-1,6,6atrithiapentalene [ ] MW S S S K-T 1000µg/mL toluene, 1x1mL 294

297 PAs Internal standards F-PAs I 1-Fluoronaphthalene [ ] 10µg/mL isooctane 1 1mL I 1-Fluoronaphthalene [ ] 100µg/mL isooctane 1 1mL I 1-Fluoronaphthalene [ ] 100µg/mL isooctane 5 1mL I 2-Fluoro-6-methylnaphthalene [ ] 100µg/mL isooctane 1 1mL T 5-Fluoroacenaphthylene [ ] 10µg/mL toluene 1 1mL T 5-Fluoroacenaphthylene [ ] 100µg/mL toluene 1 1mL T 5-Fluoroacenaphthylene [ ] 100µg/mL toluene 5 1mL T 2-Fluorofluorene [ ] 10µg/mL toluene 1 1mL T 2-Fluorofluorene [ ] 100µg/mL toluene 1 1mL MG 2-Fluorodiphenylmethane [ ] neat 1 10mg MG 4-Fluorodiphenylmethane [ ] neat 1 10mg T 2-Fluorophenanthrene [ ] 10µg/mL toluene 1 1mL T 2-Fluorophenanthrene [ ] 100µg/mL toluene 1 1mL T 3-Fluorophenanthrene [ ] 10µg/mL toluene 1 1mL T 3-Fluorophenanthrene [ ] 100µg/mL toluene 1 1mL I 3-Fluoro-6-methylphenanthrene [ ] 50µg/mL isooctane 1 1mL T 3-Fluorofluoranthene [ ] 10µg/mL toluene 1 1mL T 3-Fluorofluoranthene [ ] 100µg/mL toluene 1 1mL T 3-Fluorofluoranthene [ ] 100µg/mL toluene 5 1mL T 1-Fluoropyrene [ ] 10µg/mL toluene 1 1mL T 1-Fluoropyrene [ ] 100µg/mL toluene 1 1mL T 1-Fluorochrysene µg/mL toluene 1 1mL T 1-Fluorochrysene µg/mL toluene 1 1mL T 3-Fluorochrysene [ ] 10µg/mL toluene 1 1mL T 3-Fluorochrysene [ ] 100µg/mL toluene 1 1mL I 9-Fluoro-5-methylchrysene [ ] 50µg/mL isooctane 1 1mL T 9-Fluorobenzo[k]fluoranthene [ ] 10µg/mL toluene 1 1mL T 9-Fluorobenzo[k]fluoranthene [ ] 100µg/mL toluene 1 1mL I 5-Fluoro-3-methylbenzo [b]thiophene F-3MBT [ ] 100µg/mL isooctane 1 1mL F C I 5-Fluoro-2,3- dimethylbenzothiophene F-2,3DMBT µg/mL isooctane 1 1mL F S S T 2-Fluorodibenzothiophene F-DBT [ ] 100µg/mL toluene 1 1mL T 2-Fluorodibenzothiophene [ ] 100µg/mL toluene 5 1mL T 2-Fluorodibenzothiophene [ ] 100µg/mL toluene 10 1mL K-I 5-Fluoroindole [ ] 1000µg/mL isooctane 1 1mL F S F Compounds K-I 6-Fluoro-2-methylquinoline [ ] 1000µg/mL isooctane 1 1mL F N N 295

298 ydroxy- and methoxyf-pas MG 3-Fluoro-6-hydroxyphenanthrene neat 1 10mg MG 1-Fluoro-3-hydroxychrysene neat 1 10mg MG 1-Fluoro-4-hydroxychrysene neat 1 10mg MG 3-Fluoro-2-hydroxychrysene neat 1 10mg MG 1-Fluoro-3-methoxychrysene neat 1 10mg MG 3-Fluoro-2-methoxychrysene neat 1 10mg MG 3-Fluoro-4-methoxychrysene neat 1 10mg MG 4-Fluoro-1-methoxychrysene neat 1 10mg MG 6-Fluoro-4-hydroxy-2-methylquinoline [ ] neat 10mg Deuterated PAs and biphenyls MG Naphthalene-1-d [ ] neat 1 100mg MG Naphthalene-1,4-d [ ] neat 1 100mg K-I Naphthalene-d [ ] 1000µg/mL isooctane 1 1mL K-I Naphthalene-d [ ] 1000µg/mL isooctane 5 1mL K-I Naphthalene-d [ ] 1000µg/mL isooctane 10 1mL K-T Naphthalene-d [ ] 1000µg/mL toluene 1 1mL K-T Naphthalene-d [ ] 1000µg/mL toluene 5 1mL K-T Naphthalene-d [ ] 1000µg/mL toluene 10 1mL MG Naphthalene-d [ ] neat 1 10mg K-I 1-Methylnaphthalene-d [ ] 1000µg/mL isooctane 1 1mL K-I 1-Methylnaphthalene-d [ ] 1000µg/mL isooctane 10 1mL K-I 2-Methylnaphthalene-d [ ] 1000µg/mL isooctane 1 1mL K-I 1,8-Dimethylnaphthalene-d [ ] 1000µg/mL isooctane 5 1mL K-I 2,6-Dimethylnaphthalene-d [ ] 1000µg/mL isooctane 1 1mL K-T Acenaphthylene-d [ ] 1000µg/mL toluene 1 1mL K-T Acenaphthylene-d [ ] 1000µg/mL toluene 5 1mL K-T Acenaphthylene-d [ ] 1000µg/mL toluene 10 1mL MG Acenaphthylene-d [ ] neat 1 10mg T Acenaphthene-d [ ] 100µg/mL toluene 1 1mL T Acenaphthene-d [ ] 100µg/mL toluene 5 1mL T Acenaphthene-d [ ] 100µg/mL toluene 10 1mL K-T Acenaphthene-d [ ] 1000µg/mL toluene 1 1mL K-T Acenaphthene-d [ ] 1000µg/mL toluene 5 1mL K-T Acenaphthene-d [ ] 1000µg/mL toluene 10 1mL MG Acenaphthene-d [ ] neat 1 10mg K-I Fluorene-d [ ] 1000µg/mL isooctane 1 1mL K-I Fluorene-d [ ] 1000µg/mL isooctane 5 1mL K-I Fluorene-d [ ] 1000µg/mL isooctane 10 1mL MG Fluorene-d [ ] neat 1 10mg K-T Phenanthrene-d [ ] 1000µg/mL toluene 1 1mL K-T Phenanthrene-d [ ] 1000µg/mL toluene 5 1mL K-T Phenanthrene-d [ ] 1000µg/mL toluene 10 1mL MG Phenanthrene-d [ ] neat neat 1 10mg K-T Anthracene-d [ ] 1000µg/mL toluene 1 1mL K-T Anthracene-d [ ] 1000µg/mL toluene 5 1mL K-T Anthracene-d [ ] 1000µg/mL toluene 10 1mL MG Anthracene-d [ ] neat 1 10mg K-I 9-Methylanthracene-d [ ] 1000µg/mL isooctane 1 1mL K-T Fluoranthene-d [ ] 1000µg/mL toluene 1 1mL K-T Fluoranthene-d [ ] 1000µg/mL toluene 5 1mL K-T Fluoranthene-d [ ] 1000µg/mL toluene 10 1mL MG Fluoranthene-d [ ] neat 1 10mg T Pyrene-d [ ] 100µg/mL toluene 1 1mL T Pyrene-d [ ] 100µg/mL toluene 5 1mL T Pyrene-d [ ] 100µg/mL toluene 10 1mL T Pyrene-d [ ] 200µg/mL toluene 1 1mL T Pyrene-d [ ] 200µg/mL toluene 5 1mL T Pyrene-d [ ] 200µg/mL toluene 10 1mL K-T Pyrene-d [ ] 1000µg/mL toluene 1 1mL 296

299 K-T Pyrene-d [ ] 1000µg/mL toluene 5 1mL K-T Pyrene-d [ ] 1000µg/mL toluene 10 1mL MG Pyrene-d [ ] neat 1 10mg MG 1-Methylpyrene-d [ ] neat toluene 1 10mg T 1-Methylpyrene-d [ ] 100µg/mL toluene 5 1mL T Chrysene-d [ ] 100µg/mL toluene 1 1mL T Chrysene-d [ ] 100µg/mL toluene 5 1mL T Chrysene-d [ ] 100µg/mL toluene 10 1mL T Chrysene-d [ ] 200µg/mL toluene 1 1mL T Chrysene-d [ ] 200µg/mL toluene 5 1mL T Chrysene-d [ ] 200µg/mL toluene 10 1mL K-T Chrysene-d [ ] 1000µg/mL toluene 1 1mL K-T Chrysene-d [ ] 1000µg/mL toluene 5 1mL K-T Chrysene-d [ ] 1000µg/mL toluene 10 1mL K-T Chrysene-d [ ] 2000µg/mL toluene 1 1mL MG Chrysene-d [ ] neat 1 10mg T Benz[a]anthracene-d [ ] 100µg/mL toluene 1 1mL T Benz[a]anthracene-d [ ] 100µg/mL toluene 5 1mL T Benz[a]anthracene-d [ ] 100µg/mL toluene 10 1mL K-T Benz[a]anthracene-d [ ] 1000µg/mL toluene 1 1mL K-T Benz[a]anthracene-d [ ] 1000µg/mL toluene 5 1mL K-T Benz[a]anthracene-d [ ] 1000µg/mL toluene 10 1mL MG Benz[a]anthracene-d [ ] neat 1 10mg K-T Triphenylene-d [ ] 1000µg/mL toluene 1 1mL K-T Triphenylene-d [ ] 1000µg/mL toluene 5 1mL T Benzo[a]pyrene-d [ ] 100µg/mL toluene 1 1mL T Benzo[a]pyrene-d [ ] 100µg/mL toluene 5 1mL T Benzo[a]pyrene-d [ ] 100µg/mL toluene 10 1mL K-T Benzo[a]pyrene-d [ ] 1000µg/mL toluene 1 1mL MG Benzo[a]pyrene-d [ ] neat 1 10mg T Benzo[e]pyrene-d [ ] 100µg/mL toluene 1 1mL T Benzo[e]pyrene-d [ ] 100µg/mL toluene 5 1mL T Benzo[e]pyrene-d [ ] 100µg/mL toluene 10 1mL T Benzo[b]fluoranthene-d [ ] 100µg/mL toluene 1 1mL T Benzo[b]fluoranthene-d [ ] 100µg/mL toluene 5 1mL T Benzo[b]fluoranthene-d [ ] 100µg/mL toluene 10 1mL MG Benzo[b]fluoranthene-d [ ] neat 1 10mg T Benzo[k]fluoranthene-d [ ] 100µg/mL toluene 1 1mL T Benzo[k]fluoranthene-d [ ] 100µg/mL toluene 5 1mL T Benzo[k]fluoranthene-d [ ] 100µg/mL toluene 10 1mL MG Benzo[k]fluoranthene-d [ ] neat 1 10mg K-T Perylene-d [ ] 1000µg/mL toluene 1 1mL K-T Perylene-d [ ] 1000µg/mL toluene 5 1mL K-T Perylene-d [ ] 1000µg/mL toluene 10 1mL MG Perylene-d [ ] neat 1 10mg T Benzo[ghi]perylene-d [ ] 100µg/mL toluene 1 1mL T Benzo[ghi]perylene-d [ ] 100µg/mL toluene 5 1mL T Benzo[ghi]perylene-d [ ] 100µg/mL toluene 10 1mL T Benzo[ghi]perylene-d [ ] 200µg/mL toluene 1 1mL T Benzo[ghi]perylene-d [ ] 200µg/mL toluene 5 1mL T Benzo[ghi]perylene-d [ ] 200µg/mL toluene 10 1mL K-T Benzo[ghi]perylene-d [ ] 1000µg/mL toluene 1 1mL K-T Benzo[ghi]perylene-d [ ] 1000µg/mL toluene 5 1mL K-T Benzo[ghi]perylene-d [ ] 1000µg/mL toluene 10 1mL MG Benzo[ghi]perylene-d [ ] neat 1 10mg T Indeno[1,2,3,-cd]fluoranthene-d [ ] 100µg/mL toluene 5 1mL T Indeno[1,2,3-cd]pyrene-d [ ] 100µg/mL toluene 1 1mL T Indeno[1,2,3-cd]pyrene-d [ ] 100µg/mL toluene 5 1mL T Indeno[1,2,3-cd]pyrene-d [ ] 100µg/mL toluene 10 1mL K-T Indeno[1,2,3-cd]pyrene-d [ ] 1000µg/mL toluene 1 1mL K-T Indeno[1,2,3-cd]pyrene-d [ ] 1000µg/mL toluene 5 1mL K-T Indeno[1,2,3-cd]pyrene-d [ ] 1000µg/mL toluene 10 1mL MG Indeno[1,2,3-cd]pyrene-d [ ] neat 1 10mg Compounds 297

300 I Dibenz[a,h]anthracene-d [ ] 100µg/mL isooctane 1 1mL I Dibenz[a,h]anthracene-d [ ] 100µg/mL isooctane 5 1mL I Dibenz[a,h]anthracene-d [ ] 100µg/mL isooctane 10 1mL T Dibenz[a,h]anthracene-d [ ] 100µg/mL toluene 1 1mL T Dibenz[a,h]anthracene-d [ ] 100µg/mL toluene 5 1mL T Dibenz[a,h]anthracene-d [ ] 100µg/mL toluene 10 1mL T Dibenz[a,h]anthracene-d [ ] 200µg/mL toluene 1 1mL T Dibenz[a,h]anthracene-d [ ] 200µg/mL toluene 5 1mL T Dibenz[a,h]anthracene-d [ ] 200µg/mL toluene 10 1mL MG Dibenz[a,h]anthracene-d [ ] neat 1 10mg T Coronene-d [ ] 100µg/mL toluene 1 1mL T Coronene-d [ ] 100µg/mL toluene 5 1mL T Coronene-d [ ] 100µg/mL toluene 10 1mL K-T Coronene-d [ ] 1000µg/mL toluene 1 1mL K-T Coronene-d [ ] 1000µg/mL toluene 5 1mL K-T Coronene-d [ ] 1000µg/mL toluene 10 1mL T Dibenzo[a,i]pyrene-d [ ] 100µg/mL toluene 1 1mL T Dibenzo[a,i]pyrene-d [ ] 100µg/mL toluene 5 1mL T Dibenzo[a,i]pyrene-d [ ] 100µg/mL toluene 10 1mL K-T Dibenzo[a,i]pyrene-d [ ] 1000µg/mL toluene 1 1mL MG Dibenzo[a,i]pyrene-d [ ] neat 1 10mg K-T Biphenyl-d [ ] 1000µg/mL toluene 1 1mL MG Biphenyl-d [ ] neat 1 10mg T o-terphenyl-d [ ] 100µg/mL toluene 1 1mL T o-terphenyl-d [ ] 100µg/mL toluene 5 1mL T o-terphenyl-d [ ] 100µg/mL toluene 10 1mL K-T o-terphenyl-d [ ] 1000µg/mL toluene 1 1mL K-T o-terphenyl-d [ ] 1000µg/mL toluene 5 1mL K-T o-terphenyl-d [ ] 1000µg/mL toluene 10 1mL T m-terphenyl-d [ ] 100µg/mL toluene 1 1mL T m-terphenyl-d [ ] 100µg/mL toluene 5 1mL T m-terphenyl-d [ ] 100µg/mL toluene 10 1mL K-T m-terphenyl-d [ ] 1000µg/mL toluene 1 1mL K-T m-terphenyl-d [ ] 1000µg/mL toluene 5 1mL K-T m-terphenyl-d [ ] 1000µg/mL toluene 10 1mL T p-terphenyl-d [ ] 100µg/mL toluene 1 1mL T p-terphenyl-d [ ] 100µg/mL toluene 5 1mL T p-terphenyl-d [ ] 100µg/mL toluene 10 1mL K-T p-terphenyl-d [ ] 1000µg/mL toluene 1 1mL K-T p-terphenyl-d [ ] 1000µg/mL toluene 5 1mL K-T p-terphenyl-d [ ] 1000µg/mL toluene 10 1mL T 2,2 -Binaphthyl-d [ ] 100µg/mL toluene 5 1mL Deuterated PANs K-T Carbazole-d [ ] 1000µg/mL toluene 1 1mL K-T Carbazole-d [ ] 1000µg/mL toluene 5 1mL K-T Carbazole-d [ ] 1000µg/mL toluene 10 1mL K-T Acridine-d [ ] 1000µg/mL toluene 1 1mL Deuterated PAs, dioxins and PASs I Dibenzo-p-dioxin-d [ ] 100µg/mL isooctane 1 1mL I Dibenzofuran-d [ ] 100µg/mL isooctane 1 1mL MG Thiophene-d [ ] neat 1 100mg K-I Dibenzothiophene-d [ ] 1000µg/mL isooctane 1 1mL K-I Dibenzothiophene-d [ ] 1000µg/mL isooctane 5 1mL MG Dibenzothiophene-d [ ] neat 1 10mg Deuterated hydroxypas MG 1-ydroxypyrene-d [ ] neat 1 10mg 298

301 Deuterated nitropas K-T 1-Nitronaphthalene-d [ ] 1000µg/mL toluene 1 1mL K-T 1-Nitronaphthalene-d [ ] 1000µg/mL toluene 5 1mL K-T 1-Nitronaphthalene-d [ ] 1000µg/mL toluene 10 1mL MG 1-Nitronaphthalene-d [ ] neat 1 10mg T 2-Nitrofluorene-d [ ] 100µg/mL toluene 1 1mL T 2-Nitrofluorene-d [ ] 100µg/mL toluene 5 1mL T 2-Nitrofluorene-d [ ] 100µg/mL toluene 10 1mL K-T 2-Nitrofluorene-d [ ] 1000µg/mL toluene 1 1mL T 9-Nitroanthracene-d [ ] 100µg/mL toluene 1 1mL T 9-Nitroanthracene-d [ ] 100µg/mL toluene 5 1mL T 9-Nitroanthracene-d [ ] 100µg/mL toluene 10 1mL K-T 9-Nitroanthracene-d [ ] 1000µg/mL toluene 1 1mL I 1-Nitropyrene-d [ ] 100µg/mL isooctane 1 1mL T 1-Nitropyrene-d [ ] 100µg/mL toluene 1 1mL T 1-Nitropyrene-d [ ] 100µg/mL toluene 5 1mL T 1-Nitropyrene-d [ ] 100µg/mL toluene 10 1mL T 3-Nitrofluoranthene-d [ ] 100µg/mL toluene 1 1mL T 3-Nitrofluoranthene-d [ ] 100µg/mL toluene 5 1mL T 3-Nitrofluoranthene-d [ ] 100µg/mL toluene 10 1mL K-T 3-Nitrofluoranthene-d [ ] 1000µg/mL toluene 1 1mL T 6-Nitrochrysene-d [ ] 100µg/mL toluene 1 1mL T 6-Nitrochrysene-d [ ] 100µg/mL toluene 5 1mL T 6-Nitrochrysene-d [ ] 100µg/mL toluene 10 1mL K-T 6-Nitrochrysene-d [ ] 1000µg/mL toluene 1 1mL T 6-Nitrobenzo[a]pyrene-d [ ] 100µg/mL toluene 1 1mL T 6-Nitrobenzo[a]pyrene-d [ ] 100µg/mL toluene 5 1mL T 6-Nitrobenzo[a]pyrene-d [ ] 100µg/mL toluene 10 1mL Deuterated aminopas K-T 1-Aminonaphthalene-d µg/mL toluene 1 1mL K-T 1-Aminonaphthalene-d µg/mL toluene 5 1mL K-T 1-Aminonaphthalene-d µg/mL toluene 10 1mL K-I 2-Aminonaphthalene-d [ ] 1000µg/mL isooctane 1 1mL K-I 2-Aminonaphthalene-d [ ] 1000µg/mL isooctane 5 1mL K-I 2-Aminonaphthalene-d [ ] 1000µg/mL isooctane 10 1mL K-T 2-Aminobiphenyl-d [ ] 1000µg/mL toluene 5 1mL K-T 2-Aminobiphenyl-d [ ] 1000µg/mL toluene 10 1mL K-T 4-Aminobiphenyl-d [ ] 1000µg/mL toluene 5 1mL K-T 4-Aminobiphenyl-d [ ] 1000µg/mL toluene 10 1mL K-T 2-Aminofluorene-d [ ] 1000µg/mL toluene 5 1mL K-T 2-Aminofluorene-d [ ] 1000µg/mL toluene 10 1mL EPA/EU PA Kits (see also the application sections, PAs) K-I Single 16 EPA-PA Kit, isooctane-1000µg/ml [ ] 1000µg/mL isooctane 1 Kit K-T Single 16 EPA-PA Kit, toluene-1000µg/ml [ ] 1000µg/mL toluene 1 Kit KIT-I Single 16 EPA-PA Kit, isooctane-mix conc. Mix 200 and 1000µg/mL isooctane Kit KIT-T Single 16 EPA-PA Kit, toluene-mix conc. Mix 200 and 1000µg/mL toluene Kit KIT-N Single 16 EPA-PA Kit Neat, 10mg neat Kit S T EPA-PAs, Cocktail 1 100µg/mL toluene 5 ml S CY EPA-PAs, Cocktail 2 10µg/mL cyclohexane 5 ml S AN EPA-PAs, Cocktail 3 10µg/mL acetonitrile 5 ml S T Deuterated 16 EPA PA-mix 100µg/mL toluene 1 ml S T Deuterated 15 EU PA-mix 100µg/mL toluene 1 ml S-4062-ASS-5AN W Mix assorted acetonitrile 5 ml S T 15 EU PA Cocktail 100µg/mL toluene 5 ml KIT Single 15 EU PA Kit Kit Compounds 299

302 Biphenyls and terphenyls Biphenyl and alkylbiphenyls 3' 2' 4' 5' 6' K-I Biphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 2,2 -Dimethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 3,3 -Dimethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4,4 -Dimethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-Ethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Propylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 2,2,5,5 -Tetramethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 3,3,4,4 -Tetramethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 3,3,5,5 -Tetramethylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Butylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Pentylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-exylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-eptylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-ctylbiphenyl [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Nonylbiphenyl [ ] 1000µg/mL isooctane 1 1mL KIT Alkylbiphenyl Kit Kit 300

303 Terphenyls o-terphenyl [ ] MW p-quaterphenyl [ ] MW K-T 1000µg/mL toluene, 1x1mL K-I MG 1000µg/mL isooctane, 1x1mL neat, 1x10mg m-quinquiphenyl [ ] MW m-terphenyl [ ] MW K-I MG 1000µg/mL isooctane, 1x1mL neat, 1x5mg K-T 1000µg/mL toluene, 1x1mL p-quinquiphenyl [ ] MW K-T 1000µg/mL toluene, 1x1mL p-terphenyl [ ] MW p-sexiphenyl [ ] MW K-T 1000µg/mL toluene, 1x1mL K-T 1000µg/mL toluene, 1x1mL o-quarterphenyl [ ] MW Quaterrylene [ ] MW K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x5mg m-quarterphenyl [ ] MW K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x5mg MG neat, 1x2mg T 100µg/mL toluene, 1x1mL Terphenyl Kit KIT Kit Compounds 301

304 ydroxy biphenyls MG 4,4 -Dihydroxybiphenyl [ ] neat 1 10mg Nitrobiphenyls and terphenyl T 2-Nitrobiphenyl [ ] 100µg/mL toluene 1 1mL MG 2-Nitrobiphenyl [ ] neat 1 10mg T 4-Nitrobiphenyl [ ] 100µg/mL toluene 1 1mL MG 4-Nitrobiphenyl [ ] neat 1 10mg T 2,2 -Dinitrobiphenyl [ ] 100µg/mL toluene 1 1mL MG 2,2 -Dinitrobiphenyl [ ] neat 1 10mg T 4,4 -Dinitrobiphenyl [ ] 100µg/mL toluene 1 1mL K-T 3,3 -Dinitrobenzidine [ ] 1000µg/mL toluene 1 1mL T 4,4 -Dinitro-p-terphenyl [ ] 100µg/mL toluene 1 1mL MG 4,4 -Dinitro-p-terphenyl [ ] neat 1 10mg KIT Nitrobiphenyl (Solutions) Kit Kit 302

305 Aminobiphenyls Aminobiphenyl [ ] MW ,3 -Diaminobenzidine [ ] MW N K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL ,3 -Dimethoxybenzidine [ ] MW Aminobiphenyl [ ] MW ML neat, 1x1mL MG neat, 1x10mg ,3 -Dichlorobenzidine [ ] MW Aminobiphenyl [ ] MW I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL F ,3-Diaminobiphenyl 2Cl [ ] MW ,4 -Diaminobiphenyl Benzidine [ ] MW N N 2 2 Cl 2 N N 2 F MG neat, 1x100mg K-I 1000µg/mL isooctane,1x1ml F ,4-Diaminobiphenyl 2Cl [ ] MW ,3 -Dimethylbenzidine [ ] MW N 2 N 2 2 Cl N 2 2 N C 3 F MG neat, 1x100mg C I 100µg/mL isooctane, 1x1mL Compounds 303

306 Diphenyl methanes, Bibenzyls Methyldiphenylmethane [ ] MW ,4 -Dimethylbibenzyl [ ] MW C 3 C 3 3 C MG neat, 1x10mg K-I 1000µg/mL isooctane, 1x1mL Methyldiphenylmethane [ ] MW C MG neat, 1x10mg Aminodiphenylmethanes ,4 -Methylenedianiline [ ] MW ,3 -Dimethyl- 4,4 -diaminodiphenylmethane [ ] MW C C 3 2 N N 2 2 N N ML neat, 1x1mL I 100µg/mL isooctane, 1x1mL Naphthalenes C0-C1 Naphthalenes K-I Naphthalene [ ] 1000µg/mL isooctane 1 1mL MG Naphthalene [ ] neat 1 10mg K-I 1-Methylnaphthalene 1-MN [ ] 1000µg/mL isooctane 1 1mL MG 1-Methylnaphthalene 1-MN [ ] neat 1 10mg K-I 2-Methylnaphthalene 2-MN [ ] 1000µg/mL isooctane 1 1mL MG 2-Methylnaphthalene 2-MN [ ] neat 1 10mg KIT C0-C1 Naphthalene Kit Kit C2 Naphthalenes K-I 1,2-Dimethylnaphthalene 1,2-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1,3-Dimethylnaphthalene 1,3-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1,4-Dimethylnaphthalene 1,4-DMN [ ] 1000µg/mL isooctane 1 1mL 304

307 K-I 1,5-Dimethylnaphthalene 1,5-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1,6-Dimethylnaphthalene 1,6-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1,7-Dimethylnaphthalene 1,7-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1,8-Dimethylnaphthalene 1,8-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 2,3-Dimethylnaphthalene 2,3-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethylnaphthalene 2,6-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 2,7-Dimethylnaphthalene 2,7-DMN [ ] 1000µg/mL isooctane 1 1mL K-I 1-Ethylnaphthalene 1-EN [ ] 1000µg/mL isooctane 1 1mL K-I 2-Ethylnaphthalene 2-EN [ ] 1000µg/mL isooctane 1 1mL KIT C2 Naphthalene Kit Kit C3 Naphthalene I 1,2,3-Trimethylnaphthalene 1,2,3-TMN [ ] 500µg/mL isooctane 1 1mL I 1,2,4-Trimethylnaphthalene 1,2,4-TMN [ ] 500µg/mL isooctane 1 1mL I 1,2,5-Trimethylnaphthalene 1,2,5-TMN [ ] 500µg/mL isooctane 1 1mL I 1,2,6-Trimethylnaphthalene 1,2,6-TMN [ ] 500µg/mL isooctane 1 1mL I 1,3,7-Trimethylnaphthalene 1,3,7-TMN [ ] 500µg/mL isooctane 1 1mL I 1,4,5-Trimethylnaphthalene 1,4,5-TMN [ ] 500µg/mL isooctane 1 1mL I 1,4,6-Trimethylnaphthalene 1,4,6-TMN [ ] 500µg/mL isooctane 1 1mL I 2,3,5-Trimethylnaphthalene 2,3,5-TMN [ ] 500µg/mL isooctane 1 1mL I 2,3,6-Trimethylnaphthalene 2,3,6-TMN [ ] 500µg/mL isooctane 1 1mL I 2,4,5-Trimethylnaphthalene 2,4,5-TMN [ ] 500µg/mL isooctane 1 1mL K-I 1-n-Propylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-Propylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 1-Isopropylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Isopropylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Ethyl-6-methylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-Dihydro-3,5,8-trimethylnaphthalene [ ] 1000µg/mL isooctane 1 1mL KIT C3 Naphthalene Kit Kit C4+ Naphthalenes I 1,2,5,6-Tetramethylnaphthalene 1,2,5,6-TeMN [ ] 500µg/mL isooctane 1 1mL I 1,4,6,7-Tetramethylnaphthalene 1,4,6,7-TeMN [ ] 500µg/mL isooctane 1 1mL I 7-Isopropyl-1-methylnaphtalene Eudalene [ ] 500µg/mL isooctane 1 1mL K-I 2-Butylnaphthalene [ ] 1000µg/mL isooctane 1 1mL I 4-Isopropyl-1,6-dimethylnaphtalene Cadalene [ ] 500µg/mL isooctane 1 1mL I 1,4-Dimethyl-5-propylnaphthalene [ ] 500µg/mL isooctane 1 1mL K-I 2,6-Diisopropylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 6-Butyl-2,3-dimethylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 1-n-exylnaphthalene [ ] 1000µg/mL isooctane 1 1mL I 2,3-Dimethyl-5-(4-methylpentyl)naphthalene [ ] 500µg/mL isooctane 1 1mL K-I 2,7-Di-tert-butylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 1-n-Dodecylnaphthalene [ ] 1000µg/mL isooctane 1 1mL KIT C4+ Naphthalene Kit Kit KIT Tri- and Tetramethylnaphthalene Kit Kit KIT Naphthalene and Monosubstituted Naphthalene Kit Kit Phenylnaphthyls/binaphthyls K-I 1-Phenylnaphthalene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Phenylnaphthalene [ ] 1000µg/mL Isooctane 1 1mL K-I 1,1 -Binaphthyl [ ] 1000µg/mL isooctane 1 1mL I 1,2 -Binaphthyl [ ] 200µg/mL isooctane 1 1mL I 2,2 -Binaphthyl [ ] 200µg/mL isooctane 1 1mL KIT Phenylnaphthyl/Binaphthyl Kit Kit Compounds Naphthols K-IP 1-Naphthol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2-Naphthol [ ] 1000µg/mL isopropanol 1 1mL 305

308 MG 2,3-Dihydroxynaphthalene [ ] neat 1 10mg MG trans-1,2-dihydroxy-1,2-dihydronaphthalene [ ] neat 1 10mg I 1-Methyl-2-naphthol [ ] 100µg/mL isooctane 1 1mL I 2-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 3-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 3-Methyl-2-naphthol [ µg/mL isooctane 1 1mL I 4-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 4-Methyl-2-naphthol [ µg/mL isooctane 1 1mL I 5-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 5-Methyl-2-naphthol [ µg/mL isooctane 1 1mL I 6-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 6-Methyl-2-naphthol [ µg/mL isooctane 1 1mL I 7-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 7-Methyl-2-naphthol [ ] 100µg/mL isooctane 1 1mL I 8-Methyl-1-naphthol [ ] 100µg/mL isooctane 1 1mL I 8-Methyl-2-naphthol [ ] 100µg/mL isooctane 1 1mL KIT Methylnaphthol Kit Kit KIT Naphthol Kit Kit cis-4-(2-ydroxyphenyl)-2-oxobut-3-enoic acid (Naphthalene metabolite) [ ] Please inquire Ketonaphthalenes ,8-Dihydro- 1,4-naphthoquinone [ ] MW ydroxy-1-phenalen-1-one [ ] MW MG neat, 1x10mg MG neat, 1x10mg Methyl-1,4-naphthoquinone [ ] MW (2-Naphthyl)-butanone [ ] MW C MG neat, 1x10mg K-I 1000µg/mL isooctane, 1x1mL Perinaphthenone [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg 306

309 Nitronaphthalenes T 1-Nitronaphthalene [ ] 100µg/mL toluene 1 1mL MG 1-Nitronaphthalene [ ] neat 1 10mg T 2-Nitronaphthalene [ ] 100µg/mL toluene 1 1mL MG 2-Nitronaphthalene [ ] neat 1 10mg ME 1-Methyl-4-nitronaphthalene [ ] 100µg/mL methanol 1 1mL K-ME 1-Methyl-4-nitronaphthalene [ ] 1000µg/mL methanol 1 1mL ME 1-Methyl-5-nitronaphthalene [ ] 100µg/mL methanol 1 1mL K-ME 1-Methyl-5-nitronaphthalene [ ] 1000µg/mL methanol 1 1mL ME 1-Methyl-6-nitronaphthalene [ ] 100µg/mL methanol 1 1mL K-ME 1-Methyl-6-nitronaphthalene [ ] 1000µg/mL methanol 1 1mL ME 2-Methyl-1-nitronaphthalene [ ] 100µg/mL methanol 1 1mL K-ME 2-Methyl-1-nitronaphthalene [ ] 1000µg/mL methanol 1 1mL ME 2-Methyl-4-nitronaphthalene [ ] 100µg/mL methanol 1 1mL K-ME 2-Methyl-4-nitronaphthalene [ ] 1000µg/mL methanol 1 1mL T 1,5-Dinitronaphthalene [ ] 100µg/mL toluene 1 1mL MG 2,4-Dinitro-1-naphthol [ ] neat 1 10mg KIT Nitronaphthalene Kit Kit Aminonaphthalenes MG 1-Aminonaphthalene [ ] neat 1 10mg MG 2-Aminonaphthalene [ ] neat 1 10mg MG 1-Amino-2-methylnaphthalene [ ] neat 1 10mg MG 1,5-Diaminonaphthalene [ ] neat 1 10mg MG 1,8-Diaminonaphthalene [ ] neat 1 10mg MG 2,3-Diaminonaphthalene [ ] neat 1 10mg MG 5-Amino-1-naphthol [ ] neat 1 10mg MG 8-Amino-2-naphthol [ ] neat 1 10mg KIT Aminonaphthalene Kit Kit Chloronaphthalenes: See the PCNs in the PP section, page 361. Bromonaphthalenes: See the PBNs in the PP section, page 361. Acenaphthenes and acenaphthylenes Acenaphthenes and acenaphthylenes, unsubstituted K-I Acenaphthylene [ ] 1000µg/mL isooctane 1 1mL MG Acenaphthylene [ ] neat 1 10mg K-I Acenaphthene [ ] 1000µg/mL isooctane 1 1mL MG Acenaphthene [ ] neat 1 10mg K-I 3,4,5,11-Tetrahydroacenaphthene [ ] 1000µg/mL isooctane 1 1mL KIT Acenaphthene / acenaphthylene Kit Kit ther acenaphthenes MG 1-Acenaphthenol [ ] neat 1 10mg MG Acenaphthenequinone [ ] neat 1 10mg T 5-Nitroacenaphthene [ ] 100µg/mL toluene 1 1ml MG 5-Nitroacenaphthene [ ] neat 1 10mg Compounds 307

310 Fluorenes Fluorene/alkylfluorenes K-T Fluorene [ ] 1000µg/mL toluene 1 1mL MG Fluorene [ ] neat 1 10mg K-I 1-Methylfluorene [ ] 1000µg/mL isooctane 1 1mL K-T 2-Methylfluorene [ ] 1000µg/mL toluene 1 1mL K-I 4-Methylfluorene [ ] 1000µg/mL isooctane 1 1mL K-I 9-Methylfluorene [ ] 1000µg/mL isooctane 1 1mL MG 9-Methylfluorene [ ] neat 1 10mg I 1,7-Dimethylfluorene [ ] 500µg/mL isooctane 1 1mL K-I 9-Ethylfluorene [ ] 1000µg/mL isooctane 1 1mL K-I 9-n-Propylfluorene [ ] 1000µg/mL isooctane 1 1mL K-I 9-n-Butylfluorene [ ] 1000µg/mL isooctane 1 1mL K-I 9,9 -Bifluorenylidene [ ] 1000µg/mL isooctane 1 1mL K-I 9,9-Di-n-octylfluorene [ ] 1000µg/mL isooctane 1 1mL KIT Fluorene / Alkylfluorene Kit Kit Benzofluorenes K-T 11-Benzo[a]fluorene [ ] 1000µg/mL toluene 1 1mL MG 11-Benzo[a]fluorene [ ] neat 1 10mg T 11-Benzo[b]fluorene [ ] 200µg/mL toluene 1 1mL MG 11-Benzo[b]fluorene [ ] neat 1 10mg T 7-Benzo[c]fluorene [ ] 200µg/mL toluene 1 1mL K-I 9-Phenylfluorene [ ] 1000µg/mL isooctane 1 1mL KIT Benzo- / Phenylfluorenes Kit Kit ydroxy- / Ketofluorenes K-I 9-Fluorenone [ ] 1000µg/mL isooctane 1 1mL MG 2-ydroxyfluorene [ ] neat 1 10mg MG 9-ydroxyfluorene [ ] neat 1 10mg MG 1-ydroxy-9-fluorenone [ ] neat 1 10mg MG 2-ydroxy-9-fluorenone [ ] neat 1 10mg T Benzo[a]fluoren-11-one [ ] 200µg/mL toluene 1 1mL T Benzo[b]fluoren-11-one [ ] 200µg/mL toluene 1 1mL KIT ydroxy-/ketofluorene Kit Kit MG Truxenone [ ] neat 1 10mg 308

311 Nitrofluorenes T 2-Nitrofluorene [ ] 100µg/mL toluene 1 1mL MG 2-Nitrofluorene [ ] neat 1 10mg MG 2,7-Dinitrofluorene [ ] neat 1 10mg T 2,7-Dinitrofluorene [ ] 100µg/mL toluene 1 1mL T 2-Nitro-9-fluorenone [ ] 100µg/mL toluene 1 1mL KIT Nitrofluorene Kit Kit Aminofluorenes MG 2-Aminofluorene [ ] neat 1 10mg MG 2-Amino-9-fluorenone [ ] neat 1 10mg MG 2,7-Diaminofluorene [ ] neat 1 10mg MG 9-Aminofluorene hydrochloride [ ] neat 1 10mg KIT Aminofluorene Kit Kit Phenanthrenes C0-C1 Phenanthrenes K-I Phenanthrene [ ] 1000µg/mL isooctane 1 1mL MG Phenanthrene [ ] neat 1 10mg K-I 1-Methylphenanthrene 1-MP [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylphenanthrene 2-MP [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylphenanthrene 3-MP [ ] 1000µg/mL isooctane 1 1mL I 4-Methylphenanthrene 4-MP [ ] 500µg/mL isooctane 1 1mL K-I 9-Methylphenanthrene 9-MP [ ] 1000µg/mL isooctane 1 1mL KIT C0-C1 Phenanthrenes Kit Kit C2 Phenanthrenes I 1,2-Dimethylphenanthrene 1,2-DMP [ ] 500µg/mL isooctane 1 1mL I 1,3-Dimethylphenanthrene 1,3-DMP [ ] 500µg/mL isooctane 1 1mL I 1,4-Dimethylphenanthrene 1,4-DMP [ ] 500µg/mL isooctane 1 1mL K-I 1,5-/1,7-Dimethylphenanthrene 1,5-/1,7-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL I 1,6-Dimethylphenanthrene 1,6-DMP [ ] 500µg/mL isooctane 1 1mL I 1,7-Dimethylphenanthrene 1,7-DMP [ ] 500 µg/ml isooctane 1 1mL I 1,8-Dimethylphenanthrene 1,8-DMP [ ] 500µg/mL isooctane 1 1mL I 1,9-Dimethylphenanthrene 1,9-DMP [ ] 500µg/mL isooctane 1 1mL K-I 2,3-/3,4-Dimethylphenanthrene (49/45%) 2,3-/3,4-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL I 2,4-Dimethylphenanthrene 2,4-DMP [ ] 500µg/mL isooctane 1 1mL I 2,5/2,7-Dimethylphenanthrene (60/40%) 2,5/2,7-DMP [ ] 500µg/mL isooctane 1 1mL K-I 2,5-/2,7-/4,5-Dimethylphenanthrene [ /] (56/24/2%) 2,5-/2,7-/4,5-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-/3,5-Dimethylphenanthrene 2,6/3,5-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL I 2,7-Dimethylphenanthrene 2,7-DMP [ ] 500µg/mL isooctane 1 1mL K-I 2,9-/4,9-Dimethylphenanthrene 2,9-/4,9-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL K-I 2,10-/4,10-Dimethylphenanthrene 2,10-/4,10-DMP [ /] [ ] 1000µg/mL isooctane 1 1mL I 3,6-Dimethylphenanthrene 3,6-DMP [ ] 500µg/mL isooctane 1 1mL I 3,9-Dimethylphenanthrene 3,9-DMP [ ] 500µg/mL isooctane 1 1mL 309 Compounds

312 I 3,10-Dimethylphenanthrene 3,10-DMP [ ] 500µg/mL isooctane 1 1mL I 9,10-Dimethylphenanthrene 9,10-DMP [ ] 500µg/mL isooctane 1 1mL I 3-Ethylphenanthrene 3-EP [ ] 500µg/mL isooctane 1 1mL K-I 9-Ethylphenanthrene 9-EP [ ] 1000µg/mL isooctane 1 1mL KIT C2 Phenanthrene Kit Kit KIT Dimethylphenanthrene Kit Kit C3 Phenanthrenes I 1,2,4-Trimethylphenanthrene 1,2,4-TMP [ ] 200µg/mL isooctane 1 1mL K-I 1,2,5-/1,2,7-Trimethylphenanthrene 1,2,5-/1,2,7-TMP [ / ] 1000µg/mL isooctane 1 1mL I 1,2,6-Trimethylphenanthrene 1,2,6-TMP [ ] 500µg/mL isooctane 1 1mL I 1,2,8-Trimethylphenanthrene 1,28-TMP [ ] 500µg/mL isooctane 1 1mL I 1,2,9-Trimethylphenanthrene 1,2,9-TMP [ ] 500µg/mL isooctane 1 1mL I 1,3,4-Trimethylphenanthrene 1,3,4-TMP [ ] 200µg/mL isooctane 1 1mL I 2,6,9-Trimethylphenanthrene 2,6,9-TMP [ ] 200µg/mL isooctane 1 1mL K-I 9-n-Propylphenanthrene 9-n-PrP [ ] 1000µg/mL isooctane 1 1mL KIT C3 Phenanthrene Kit Kit C4+ Phenanthrenes I 1,2,6,9-Tetramethylphenanthrene [ ] 500µg/mL isooctane 1 1mL I 9-n-Butylphenanthrene [ ] 500µg/mL isooctane 1 1mL I 1-Methyl-7-isopropylphenanthrene Retene [ ] 500µg/mL isooctane 1 1mL I 1,9-Dimethyl-7-ethylphenanthrene/ 1,9-Dimethyl-5-ethylphenanthrene [-/ ] 500µg/mL isooctane 1 1mL KIT Tri- and tetramethylphenanthrene Kit Kit KIT C4+ Phenanthrene Kit Kit ther phenanthrenes Cyclopenta[def]- phenanthrene [ ] MW Benzo[c]phenanthrene (4)elicene [ ] MW I MG 500 µg/ml isooctane, 1x1mL neat, 1x10mg T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Cyclopenta[l]phenanthrene [ ] MW Methylcyclopenta[l]- phenanthrene [ ] MW I 500 µg/ml isooctane, 1x1mL I C µg/ml isooctane, 1x1mL 310

313 Phenanthryl-9--glucuronide [ ] MW Please inquire Phenanthro- [3,4-c]phenanthrene [ ] MW Triphenylene [ ] MW T 200µg/mL toluene, 1x1mL UG T C 3 neat, 1x10µg 100µg/mL toluene, 1x1mL ydroxyphenanthrenes MG 1-ydroxyphenanthrene [ ] neat 1 10mg MG 2-ydroxyphenanthrene [ ] neat 1 10mg MG 3-ydroxyphenanthrene [ ] neat 1 10mg MG 4-ydroxyphenanthrene [ ] neat 1 10mg MG 9-ydroxyphenanthrene [ ] neat 1 10mg trans-1,2-dihydroxy-1,2-dihydrophenanthrene [ ] Please inquire MG trans-9,10-dihydroxy-9,10-dihydrophenanthrene [ ] neat 1 10mg KIT ydroxyphenanthrene Kit (without 1925,14) Kit Methoxyphenanthrenes K-I 1-Methoxyphenanthrene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methoxyphenanthrene [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methoxyphenanthrene [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methoxyphenanthrene [ ] 1000µg/mL isooctane 1 1mL K-I 9-Methoxyphenanthrene [ ] 1000µg/mL isooctane 1 1mL KIT Methoxyphenanthrene Kit Kit Compounds 311

314 Ketophenanthrenes Cyclopenta[def] phenanthren-4-one [ ] MW Benzo[c]phenanthrene- [1,4]quinone [ ] MW MG neat, 1x10mg MG neat, 1x10mg Phenanthrene-1,4-dione [ ] MW Benzo[c]phenanthrene[5,6]- quinone [ ] MW MG neat, 1x10mg MG neat, 1x10mg Nitro-/ Aminophenanthrenes K-I 2-Nitrophenanthrene [ ] 1000µg/mL isooctane 1 1mL I 3-Nitrophenanthrene [ ] 300µg/mL isooctane 1 1mL K-I 9-Nitrophenanthrene [ ] 1000µg/mL isooctane 1 1mL MG 9-Nitrophenanthrene [ ] neat 1 10mg T 5-Nitrobenzo[c]phenanthrene [ ] 100µg/mL toluene 1 1mL MG 5-Nitrobenzo[c]phenanthrene [ ] neat 1 10mg MG 9-Aminoflourene [ ] neat 1 10mg elicenes (5)elicene [ ] MW (6)elicene [ ] MW UG neat, 1x10µg UG neat, 1x10µg MG 1x10mg 312

315 Anthracenes C0-C1 Anthracenes K-I Anthracene [ ] 1000µg/mL isooctane 1 1mL MG Anthracene [ ] neat 1 10mg K-I 1-Methylanthracene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylanthracene [ ] 1000µg/mL isooctane 1 1mL MG 2-Methylanthracene [ ] neat 1 10mg K-I 9-Methylanthracene [ ] 1000µg/mL isooctane 1 1mL KIT C0-C1 Anthracene Kit Kit C2 Anthracenes T 1,2-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL T 1,3-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL T 1,4-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL T 1,5-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL T 2,3-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL T 2,7-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL MG 9,10-Dimethylanthracene [ ] neat 1 10mg T 9,10-Dimethylanthracene [ ] 200µg/mL toluene 1 1mL K-I 2-Ethylanthracene [ ] 1000µg/mL isooctane 1 1mL KIT Dimethylanthracene Kit Kit KIT C2 Anthracene Kit Kit C3-C4 Anthracenes T 1,2,4-Trimethylanthracene [ ] 200µg/mL toluene 1 1mL T 1,2,3,4-Tetramethylanthracene [ ] 200µg/mL toluene 1 1mL T 2,3,6,7-Tetramethylanthracene [ ] 200µg/mL toluene 1 1mL T 2,3,9,10-Tetramethylantracene [ ] 200µg/mL toluene 1 1mL K-I 2-(tert-Butyl)anthracene [ ] 1000µg/mL isooctane 1 1mL KIT C3-C4 Anthracene Kit Kit Benz[a]anthracenes T 7 Benz[a]anthracene [ ] 200µg/mL toluene 1 1mL T Benz[a]anthracene [ ] 500 µg/ml toluene 1 1mL MG Benz[a]anthracene [ ] neat 1 10mg T 1-Methylbenz[a]anthracene [ ] 50 µg/ml neat 1 1mL T 5-Methylbenz[a]anthracene [ ] 200µg/mL toluene 1 1mL T 6-Methylbenz[a]anthracene [ ] 200µg/mL toluene 1 1mL T 7-Methylbenz[a]anthracene [ ] 50µg/mL toluene 1 1mL T 10-Methylbenz[a]anthracene [ ] 200µg/mL toluene 1 1mL Methylbenz[a]anthracene [ ] Please inquire T 3,9-Dimethylbenz[a]anthracene [ ] 200µg/mL toluene 1 1mL T 7,12-Dimethylbenz[a]anthracene [ ] 200µg/mL toluene 1 1mL KIT C0-C2 Benzanthracene Kit (not including ) Kit Compounds 313

316 Dibenz- / Naphthanthracenes MG Dibenz[a,c]anthracene [ ] neat 1 10mg T Dibenz[a,h]anthracene [ ] 200µg/mL toluene 1 1mL MG Dibenz[a,h]anthracene [ ] neat 1 10mg T Dibenz[a,j]anthracene [ ] 200µg/mL toluene 1 1mL T Napht[1,2-a]anthracene Napht-(1.2,1.2)-anthracene [ ] 200µg/mL toluene 1 1mL MG Napht[1,2-a]anthracene Napht-(1.2,1.2)-anthracene [ ] neat 1 5mg T Tetrabenz[a,c,h,j]anthracene [ ] 200µg/mL toluene 1 1mL MG Tetrabenz[a,c,h,j]anthracene [ ] neat 1 5mg KIT Benzanthracene/ Dibenzanthracene/ Naphthoanthracene Kit Kit KIT Dibenz- / Naphthoanthracene Kit Kit ther anthracenes Benzo[a]tetracene [ ] MW ,9 -Bianthracene [ ] MW MG neat, 1x10mg ,10-Diphenylanthracene [ ] MW K-T 1000µg/mL toluene, 1x1mL ,3.4,5.6,7.8-Tetra- (peri-naphthylene)anthracene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Dibenzo[b,k]chrysene [ ] MW T 200µg/mL toluene, 1x1mL ther Anthracenes Kit KIT Kit T 200µg/mL toluene, 1x1mL 314

317 ydroxy-/ ketoanthracenes ,4-Anthraquinone [ ] MW ydroxy-9,10-anthraquinone [ ] MW MG neat, 1x10mg MG neat, 1x10mg ,3-Dihydroxy-9,10- anthraquinone [ ] MW Methyl-9,10-anthraquinone [ ] MW MG neat, 1x10mg MG neat, 1x10mg ,3-Dimethyl-9,10- anthraquinone [ ] MW MG neat, 1x10mg Ethyl-9,10-anthraquinone MG [ ] MW neat, 1x10mg ,10-Anthraquinone [ ] MW ,4-Dihydroxy-9,10- anthraquinone Quinizarin [ ] MW MG neat, 1x10mg ,5-Dihydroxy-9,10- anthraquinone Anthrarubin [ ] MW MG neat, 1x10mg MG neat, 1x10mg ,8-Dihydroxy-9,10- anthraquinone [ ] MW MG neat, 1x10mg ydroxyanthracene [ ] MW MG neat, 1x10mg ,6-Dihydroxy-9,10- anthraquinone Anthraflavic acid [ ] MW Compounds MG neat, 1x10mg 315

318 ,2,4-Trihydroxy-9,10- anthraquinone Purpurin [ ] MW ,4-Dihydrobenzo[a]anthracene- 1(2)-one [ ] MW MG neat, 1x10mg MG neat, 1x10mg Aceanthracenequinone MW ,6,8,9- Tetrahydrobenz[a]anthracen- 11(10)-one [ ] MW MG neat, 1x10mg MG neat, 1x10mg ,8-Bis(hydroxymethyl) anthracene [ ] MW ,2-Benz[a]anthraquinone [ ] MW K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x10mg MG neat, 1x10mg Nitroanthracenes T 2-Nitroanthracene [ ] 200µg/mL toluene 1 1mL MG 2-Nitroanthracene [ ] neat 1 10mg T 9-Nitroanthracene [ ] 100µg/mL toluene 1 1mL T 9-Methyl-10-nitroanthracene [ ] 100µg/mL toluene 1 1mL MG 2,9-Dinitroanthracene [ ] neat 1 10mg T 9,10-Dinitroanthracene [ ] 100µg/mL toluene 1 1mL MG 9,10-Dinitroanthracene [ ] neat 1 10mg KIT Nitroanthracene Kit (Not including ) Kit Nitrobenzanthracenes T 7-Nitrobenz[a]anthracene [ ] 100µg/mL toluene 1 1mL MG 7-Nitrobenz[a]anthracene [ ] neat 1 10mg T 7-Nitrobenz[a,h]anthracene [ ] 100µg/mL toluene 1 1mL MG 7-Nitrobenz[a,h]anthracene [ ] neat 1 10mg KIT Nitrobenzanthracene Kit Kit 316

319 Aminoanthracenes MG 1-Aminoanthracene [ ] neat 1 10mg MG 2-Aminoanthracene [ ] neat 1 10mg MG 7-Aminobenz[a]anthracene [ ] neat 1 10mg KIT Aminoanthracene Kit (Not including ) Kit Bromobenzanthracenes MG 7-Bromobenz[a]anthracene [ ] neat 1 10mg Fluoranthrenes Fluoranthene and alkylfluoranthenes T Fluoranthene [ ] 200µg/mL toluene 1 1mL MG Fluoranthene [ ] neat 1 10mg T 1,2,3,10b-Tetrahydrofluoranthene [ ] 200µg/mL toluene 1 1mL T 1-Methylfluoranthene [ ] 200µg/mL toluene 1 1mL T 2-Methylfluoranthene [ ] 200µg/mL toluene 1 1mL T 3-Methylfluoranthene [ ] 200µg/mL toluene 1 1mL T 3-Ethylfluoranthene [ ] 200µg/mL toluene 1 1mL KIT Fluoranthene and Alkylfluoranthene Kit Kit Benzofluoranthene and phenylfluoranthene T Benzo[a]fluoranthene [ ] 200µg/mL toluene 1 1mL MG Benzo[b]fluoranthene [ ] neat 1 10mg T Benzo[b]fluoranthene [ ] 200µg/mL toluene 1 1mL ME Benzo[j]fluoranthene [ ] 100µg/mL methanol 1 1mL T Benzo[j]fluoranthene [ ] 200µg/mL toluene 1 1mL T Benzo[k]fluoranthene [ ] 200µg/mL toluene 1 1mL MG Benzo[k]fluoranthene [ ] neat 1 10mg T Benzo[ghi]fluoranthene [ ] 200µg/mL toluene 1 1mL T 2-Phenylfluoranthene [ ] 200µg/mL toluene 1 1mL MG 2-Phenylfluoranthene [ ] neat 1 10mg KIT Benzofluoranthene and Phenylfluoranthene Kit Kit Indeno- / dibenzofluoranthenes T Indeno[1,2,3-cd]fluoranthene [ ] 200µg/mL toluene 1 1mL Compounds MG Indeno[1,2,3-cd]fluoranthene [ ] neat 1 10mg MG Dibenzo[b,ghi]fluoranthene [ ] neat 1 10mg 317

320 T Dibenzo[a,e]fluoranthene [ ] 200µg/mL toluene 1 1mL MG Dibenzo[a,e]fluoranthene [ ] neat 1 10mg MG Dibenzo[a,k]fluoranthene [ ] neat 1 10mg MG Dibenzo[b,k]fluoranthene [ ] neat 1 10mg MG Dibenzo[j,l]fluoranthene [ ] neat 1 10mg KIT Indeno- and Dibenzofluoranthenes Kit Kit Phenylbenzofluoranthene MG 2-Phenylbenzo[b]fluoranthene [ ] neat 1 10mg MG 2-Phenylbenzo[j]fluoranthene [ ] neat 1 10mg MG 5-Phenylbenzo[j]fluoranthene [ ] neat 1 10mg MG 4,7-Diphenylbenzo[ghi]fluoranthene [ ] neat t 1 10mg KIT Phenylbenzofluoranthene Kit Kit Naphthofluoranthenes Naphtho[1,2-b]fluoranthene [ ] MW Naphtho[2,3-j]fluoranthene [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL MG neat, 1x10mg MG neat, 1x10mg Naphtho[2,3-b]fluoranthene [ ] MW Naphtho[2,3-k]fluoranthene [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL MG neat, 1x10mg MG neat, 1x10mg Naphthofluoranthene Kit KIT Kit 318

321 ther fluoranthenes Rubicene [ ] MW Periflanthene [ ] MW MG neat, 1x10mg MG neat, 1x10mg Benzo[cde]rubicene MW Decacyclene [ ] MW Please inquire Dibenzo[cde:opq]rubicene [ ] MW MG neat, 1x10mg T 50µg/mL toluene, 1x1mL Nitrofluoranthrenes T 1-Nitrofluoranthene [ ] 100µg/mL toluene 1 1mL MG 1-Nitrofluoranthene [ ] neat 1 2mg MG 1-Nitrofluoranthene [ ] neat 1 10mg T 2-Nitrofluoranthene [ ] 100µg/mL toluene 1 1mL MG 2-Nitrofluoranthene [ ] neat 1 2mg MG 2-Nitrofluoranthene [ ] neat 1 5mg T 3-Nitrofluoranthene [ ] 100µg/mL toluene 1 1mL MG 3-Nitrofluoranthene [ ] neat 1 10mg KIT Nitrofluoranthene Kit Kit Compounds Aminofluoranthenes MG 3-Aminofluoranthene [ ] neat 1 10mg 319

322 Cholanthrenes T Cholanthrene [ ] 200µg/mL toluene 1 1mL T 3-Methylcholanthrene [ ] 200µg/mL toluene 1 1mL MG 3-Methylcholanthrene [ ] neat 1 10mg KIT Cholanthrene solutions Kit Kit Pyrenes Pyrene and alkylpyrenes T Pyrene [ ] 200µg/mL toluene 1 1mL MG Pyrene [ ] neat 1 10mg T 1-Methylpyrene [ ] 200µg/mL toluene 1 1mL T 2-Methylpyrene [ ] 10µg/mL toluene 1 1mL T 4-Methylpyrene [ ] 200µg/mL toluene 1 1mL T 2,7-Dimethylpyrene [ ] 200µg/mL toluene 1 1mL T 4,5-Dimethylpyrene [ ] 200µg/mL toluene 1 1mL T 1-Ethylpyrene [ ] 200µg/mL toluene 1 1mL K-T 1-n-Propylpyrene [ ] 1000µg/mL toluene 1 1mL T 1-n-Butylpyrene [ ] 200µg/mL toluene 1 1mL K-T 1-n-Butylpyrene [ ] 1000µg/mL toluene 1 1mL KIT Pyrene and Alkylpyrene Kit Kit Benzo- / Dibenzopyrenes T Benzo[a]pyrene [ ] 200µg/mL toluene 1 1mL MG Benzo[a]pyrene [ ] neat 1 10mg T Benzo[e]pyrene [ ] 200µg/mL toluene 1 1mL MG Benzo[e]pyrene [ ] neat 1 10mg T 6-Methylbenzo[a]pyrene [ ] 200µg/mL toluene 1 1mL T 7-Methylbenzo[a]pyrene [ ] 200µg/mL toluene 1 1mL T 7,10-Dimethylbenzo[a]pyrene [ ] 50µg/mL toluene 1 1mL MG Dibenzo[a,e]pyrene [ ] neat 1 10mg T Dibenzo[a,e]pyrene [ ] 200µg/mL toluene 1 1mL T Dibenzo[a,h]pyrene [ ] 200µg/mL toluene 1 1mL MG Dibenzo[a,h]pyrene [ ] neat 1 10mg T Dibenzo[a,i]pyrene [ ] 200µg/mL toluene 1 1mL T Dibenzo[a,l]pyrene [ ] 200µg/mL toluene 1 1mL 320

323 T Dibenzo[e,l]pyrene [ ] 200µg/mL toluene 1 1mL KIT Benzo- / and Dibenzopyrene Kit Kit Cyclopenta- / Indeno- / Naphthopyrenes T Cyclopenta[cd]pyrene [ ] 200µg/mL toluene 1 1mL MG Cyclopenta[cd]pyrene [ ] neat 1 10mg T Indeno[1,2,3-cd]pyrene [ ] 200µg/mL toluene 1 1mL MG Indeno[1,2,3-cd]pyrene [ ] neat 1 10mg T Naphtho[2,3-a]pyrene [ ] 200µg/mL toluene 1 1mL T Naphtho[2,3-e]pyrene [ ] 200µg/mL toluene 1 1mL T 2.3-Peri-naphthylene-pyrene [ ] 200µg/mL toluene 1 1mL T 2.3,7.8-Di-(peri-naphthylene)-pyrene [ ] 200µg/mL toluene 1 1mL KIT Cyclopenta- / Indeno- / Naphthopyrene Kit Kit ydropyrenes T 4,5,9,10-Tetrahydropyrene [ ] 200µg/mL toluene 1 1mL Compounds T 1,2,3,3a,4,5-exahydropyrene [ ] 200µg/mL toluene 1 1mL MG 1,2,3,3a,4,5-exahydropyrene [ ] neat 1 10mg 321

324 T 1,2,3,6,7,8-exahydropyrene [ ] 200µg/mL toluene 1 1mL MG 1,2,3,6,7,8-exahydropyrene [ ] neat 1 10mg T exadecahydropyrene [ ] 200µg/mL toluene 1 1mL MG exadecahydropyrene [ ] neat 1 10mg T 4,5-Dihydrobenzo[a]pyrene [ ] 200µg/mL toluene 1 1mL T 4,5,7,8,9,10,11,12-ctahydrobenzo[a]pyrene [ ] 200µg/mL toluene 1 1mL T 1,2,3,6,7,8,9,10,11,12- Decahydrobenz[e]pyrene [ ] 200µg/mL toluene 1 1mL MG 1,2,3,6,7,8,9,10,11,12- Decahydrobenz[e]pyrene [ ] neat 1 5mg ydroxy- / Methoxy- / Ketopyrenes T 1-ydroxypyrene [ ] 200µg/mL toluene 1 1mL MG 1-ydroxypyrene [ ] neat 1 10mg T 3-ydroxybenzo[a]pyrene [ ] 200µg/mL toluene 1 1mL MG 3-ydroxybenzo[a]pyrene [ ] neat 1 2mg Pyrenyl-1--glucuronide [ ] Please inquire MG 7,8,9,10-Tetrahydro-benzo[a}pyren-7-ol [ ] neat 1 10mg MG 1-Methyoxypyrene [ ] neat 1 10mg 322

325 MG 1,6-Pyrenequinone [ ] neat 1 10mg MG Cyclopenta[cd]pyren-3(4)-one [ ] neat 1 10mg T 6-Benzo[cd]pyren-6-one [ ] 200µg/mL toluene 1 1mL MG 6-Benzo[cd]pyren-6-one [ ] neat 1 10mg MG 9,10-Dihydrobenzo[a]pyren-7(8)-one [ ] neat 1 10mg MG Dibenzo[a,i]pyrene[5,8]quinone [ ] neat 1 10mg MG Pyrene-1-sulfonic acid sodium salt [ ] neat 1 10mg Na S Nitropyrenes T 1-Nitropyrene [ ] 100µg/mL toluene 1 1mL MG 1-Nitropyrene [ ] neat 1 10mg T 2-Nitropyrene [ ] 100µg/mL toluene 1 1mL MG 2-Nitropyrene [ ] neat 1 10mg T 4-Nitropyrene [ ] 100µg/mL toluene 1 1mL MG 4-Nitropyrene [ ] neat 1 10mg T 1,3-Dinitropyrene [ ] 100µg/mL toluene 1 1mL MG 1,3-Dinitropyrene [ ] neat 1 10mg T 1,6-Dinitropyrene [ ] 100µg/mL toluene 1 1mL MG 1,6-Dinitropyrene [ ] neat 1 5mg T 1,8-Dinitropyrene [ ] 100µg/mL toluene 1 1mL MG 1,8-Dinitropyrene [ ] neat 1 5mg KIT Nitropyrene Kit Kit Compounds 323

326 Nitrobenzo[a]- and nitrobenzo[e]pyrenes T 1-/3-Nitrobenzo[a]pyrene [ /] [ ] 200µg/mL toluene 1 1mL MG 1-/3-Nitrobenzo[a]pyrene [ /] [ ] neat 1 2mg T 6-Nitrobenzo[a]pyrene [ ] 100µg/mL toluene 1 1mL MG 6-Nitrobenzo[a]pyrene [ ] neat 1 10mg T 1-/3-Nitrobenzo[e]pyrene [ ]/ [ ] 200µg/mL toluene 1 1mL MG 1-/3-Nitrobenzo[e]pyrene [ /] [ ] neat 1 5mg KIT Nitrobenzo[a]pyrene neat Kit Kit KIT Nitrobenzo[a]- and nitrobenzo[e]pyrene solutions Kit Kit Aminopyrenes MG 1-Aminopyrene [ ] neat 1 10mg MG 2-Aminopyrene [ ] neat 1 10mg MG 4-Aminopyrene [ ] neat 1 10mg MG 1,3-Diaminopyrene [ ] neat 1 10mg MG 1,6-Diaminopyrene [ ] neat 1 5mg MG 1,8-Diaminopyrene [ ] neat 1 5mg Aminobenzo[a]pyrene [ ] Please inquire 1 10mg Aminobenzo[e]pyrene Please inquire Aminobenzo[e]pyrene [ ] Please inquire KIT Aminopyrene-/ Aminobenzopyrene Kit (Not including 1788, ) Kit Chrysenes C0-C1 Chrysenes T Chrysene [ ] 200µg/mL toluene 1 1mL MG Chrysene [ ] neat 1 10mg T 1-Methylchrysene [ ] 200µg/mL toluene 1 1mL T 2-Methylchrysene [ ] 200µg/mL toluene 1 1mL T 3-Methylchrysene [ ] 200µg/mL toluene 1 1mL T 4-Methylchrysene [ ] 200µg/mL toluene 1 1mL T 5-Methylchrysene [ ] 200µg/mL toluene 1 1mL T 6-Methylchrysene [ ] 200µg/mL toluene 1 1mL KIT C0-C1 Chrysene Kit Kit C2+ Chrysenes K-T 6-Ethylchrysene [ ] 1000µg/mL toluene 1 1mL K-I 1,3,6-Trimethylchrysene µg/mL isooctane 1 1mL K-T 6-n-Propylchrysene [ ] 1000µg/mL toluene 1 1mL K-T 6-n-Butylchrysene [ ] 1000µg/mL toluene 1 1mL KIT C2+ Chrysene Kit Kit 324

327 Benzochrysenes Picene Benzo[a]chrysene [ ] MW Dibenzo[b,def]chrysene Dibenzo[a,h]pyrene [ ] MW MG T neat, 1x2mg 100µg/mL toluene, 1x1mL T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Benzo[b]chrysene [ ] MW Dibenzo[b,k]chrysene [ ] MW T 200µg/mL toluene, 1x1mL T MG 200µg/mL toluene, 1x1mL neat, 1x5mg Benzo[c]chrysene [ ] MW Dibenzo[g,p]chrysene [ ] MW T 200µg/mL toluene, 1x1mL Benzo[g]chrysene [ ] MW T 200µg/mL toluene, 1x1mL UG neat, 1x10µg Benzochrysene Kit KIT Kit T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Compounds 325

328 ther chrysenes ,2,3,4-Tetrahydrochrysene [ ] MW Diindeno [4,3,2,1-cdef;1,2,3 -hi]chrysene [ ] MW UG neat, 1x10µg UG neat, 1x5µg ,2,3,4,5,6-exahydrochrysene [ ] MW Benzo[p]naphtho [1,8,7-ghi]chrysene [ ] MW T 200µg/mL toluene, 1x1mL Cyclopent[hi]indeno [4,3,2,1-cdef]chrysene MW UG neat, 1x10µg UG neat, 1x10µg 326

329 ydroxychrysenes MG 1-ydroxychrysene [ ] neat 1 10mg MG 2-ydroxychrysene [ ] neat 1 10mg MG 3-ydroxychrysene [ ] neat 1 10mg MG 4-ydroxychrysene [ ] neat 1 10mg UG Chrysene-trans-1,2-dihydrodiol [ ] neat 1 10µg UG Chrysene-trans-3,4-dihydrodiol [ ] neat 1 10µg UG Chrysene-trans-5,6-dihydrodiol [ ] neat 1 10µg Methoxychrysenes MG 1-Methoxychrysene [ ] neat 1 10mg MG 2-Methoxychrysene [ ] neat 1 10mg MG 3-Methoxychrysene [ ] neat 1 10mg MG 4-Methoxychrysene [ ] neat 1 10mg KIT Methoxychrysenes solution Kit Kit Ketochrysenes MG 1,4-Chrysenequinone [ ] neat 1 10mg MG 5,6-Chrysenequinone [ ] neat 1 10mg Nitrochrysenes T 6-Nitrochrysene [ ] 100µg/mL toluene 1 1mL MG 6-Nitrochrysene [ ] neat 1 10mg Aminochrysenes MG 2-Aminochrysene [ ] neat 1 10mg MG 6-Aminochrysene [ ] neat 1 10mg Anthanthrenes T Anthanthrene [ ] 200µg/mL toluene 1 1mL MG Anthanthrene [ ] neat 1 10mg T 6-Methylanthanthrene [ ] 200µg/mL toluene 1 1mL MG 6-Methylanthanthrene [ ] neat 1 10mg T 6-Nitroanthanthrene [ ] 100µg/mL toluene 1 1mL MG 6-Nitroanthanthrene [ ] neat 1 10mg MG Pyranthrene [ ] neat 1 10mg MG 1.2,3.4,5.6,10.11-Tetrabenzanthanthrene [ ] neat 1 10mg Compounds 327

330 Perylenes Perylene and alkylpyrenes Perylene [ ] MW ,6,7,8,9,10- exahydrobenz[ghi]perylene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Please inquire ,2,3,3a,4,5,6,7,8,9,9a,10,11,12- Tetradecahydroperylene [ ] MW Benzo[b]perylene [ ] MW T 200µg/mL toluene, 1x1mL Dibenzo[b,ghi]perylene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Benzo[ghi]perylene [ ] MW T 200µg/mL toluene, 1x1mL T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Dibenzo[e,ghi]perylene [ ] MW ,4-Dihydrobenzo[ghi]perylene [ ] MW T 200µg/mL toluene, 1x1mL Naphtho[8,1,2-bcd]perylene [ ] MW UG neat, 1x10µg T 200µg/mL toluene, 1x1mL 328

331 Naphtho[1,2,3,4-ghi]perylene [ ] MW Benzo[pgr]dinaphtho [8,1,2-bcd:2,1,8 -lmn]perylene [ ] MW T 200µg/mL toluene, 1x1mL n-exylperylene [ ] MW T 200µg/mL toluene, 1x1mL UG neat, 1x10µg Perylene solutions Kit (Not including ) Dibenzo[cd,n]naphtho [3,2,1,8-pqra]perylene [ ] MW KIT Kit UG neat, 1x10µg Nitro- / Aminoperylenes T 1-Nitroperylene [ ] 100µg/mL toluene 1 1mL MG 1-Nitroperylene [ ] neat 1 10mg T 3-Nitroperylene [ ] 100µg/mL toluene 1 1mL MG 3-Nitroperylene [ ] neat 1 10mg UG 1-Aminoperylene [ ] neat 1 100µg UG 3-Aminoperylene [ ] neat 1 100µg KIT Nitroperylene Kit Kit KIT Nitro-/Aminoperylene Kit Kit Compounds 329

332 Peropyrenes Peropyrene [ ] MW Isoviolanthrene [ ] MW T 200µg/mL toluene, 1x1mL MG neat, 1x10mg MG neat, 1x10mg Dibenzo[h,s]peropyrene [ ] MW Circobiphenyl [ ] MW MG neat, 1x10mg MG neat, 1x10mg Picenes Picene [ ] MW Benzo[b]picene [ ] MW T 50µg/mL toluene, 1x1mL T 100µg/mL toluene, 1x1mL Methylpicene [ ] MW UG neat, 1x10µg ,9-Dimethylpicene [ ] MW T 100µg/mL toluene, 1x1mL 330

333 Bisanthenes Bisanthene (Phenanthro[1,10,9,8-opqra]perylene) [ ] MW Dibenzo[cd,pg]bisanthene ( 3.4,11.12-Dibenzobisanthene) [ ] MW MG neat, 1x10mg UG neat, 1x10µg MG neat, 1x10mg Dibenzo[bc,ef]coronene ( 1.14-Benzobisanthene) [ ] MW Benzodinaphtho[1.7,2.4], [7.1,11.13]bisanthene [ ] MW T 100µg/mL toluene, 1x1mL MG neat, 1x10mg MG neat, 1x10mg valene [ ] MW Bisanthone [ ] MW MG neat, 1x10mg T 100µg/mL toluene, 1x1mL Compounds 331

334 Acenes and phenes Tetracene Naphthacene [ ] MW Benzo[a]naphtha [8,1,2-cde]naphthacene [ ] MW MG neat, 1x10mg T 100µg/mL toluene, 1x1mL Pentacene [ ] MW Dibenzo[h,rst]pentaphene [ ] MW MG neat, 1x10mg Pentaphene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x5mg Dinaphtho [2,1,8,7-defg;2,1,8,7 -ijkl] pentaphene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x5mg Dibenz[a,c]pentacene MW Please inquire UG neat, 1x10µg Dinaphtho [2,1,8,7-defg;2,1,8,7 - opqr]pentacene [ ] MW UG neat, 1x10µg 332

335 Naphtho[8,1,2-hij]hexaphene [ ] MW Dibenzo[a,j]tetracene [ ] MW Please inquire MG neat, 1x10mg Tetrabenzo [de,h,kl,rst]pentaphene [ ] MW Dibenzo[a,l]tetracene [ ] MW MG neat, 1x10mg Dibenzo[a,c]pentacene [ ] MW Please inquire eptaphene [ ] MW T 200µg/mL toluene, 1x1mL UG neat, 1x5µg Dibenzo[a,l]pentacene ( 1,2:8,9-Dibenzopentacene) [ ] MW Benzo[a]tetracene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg T 200µg/mL toluene, 1x1mL MG neat, 1x5mg Benzo[a]pentacene [ ] MW Rubrene 5,6,11,12-Tetraphenylnaphthacene [ ] MW Compounds T 100µg/mL toluene, 1x1mL MG neat, 1x10mg 333

336 ,12-Naphthacenequinone [ ] MW ,7,12,14-Pentacenetetrone [ ] MW MG neat, 1x10mg MG neat, 1x10mg Terrylenes Terrylene [ ] MW Quaterrylene [ ] MW UG neat, 1x10µg MG neat, 1x10mg UG neat, 1x10µg 334

337 Coronenes Coronene and benzo/naphthocoronenes Coronene [ ] MW Dibenz[bc,kl]coronene [ ] MW T MG 100µg/mL toluene, 1x1mL neat, 1x10mg Please inquire Methylcoronene [ ] MW Naphtho[8,1,2-abc]coronene (Naphtho[2.8,2.4]coronene) [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg Benzo[a]coronene [ ] MW ML MG neat, 1x1mL neat, 1x10mg MG neat, 1x10mg Dibenzo[a,j]coronene [ ] MW Naphtho[2,3-a]coronene [ ] MW T 200µg/mL toluene, 1x1mL MG neat, 1x5mg Dibenzo[bc,ef]coronene (1.14-Benzobisanthene) [ ] MW T 200µg/mL toluene, 1x1mL MG neat, 1x5mg Anthraceno[2.3-a]coronene [ ] MW Compounds MG neat, 1x10mg MG neat, 1x5mg 335

338 Dinaphtho- [8,1,2-abc;8,1,2 -jkl]coronene [ ] MW ,2.3,4.5,6.7,8.9, exabenzocoronene [ ] MW UG neat, 1x10µg T MG 200µg/mL toluene, 1x1mL neat, 1x5mg Dibenzo[lmbrs]naphtha- [3,2,1,8,7-defgh]phenanthro- [3,4,5-yzab]pyranthrene [ ] MW Dicoronylene [ ] MW T 200µg/mL toluene, 1x1mL T 100µg/mL toluene, 1x1mL MG neat, 1x10mg Dicoronylene (mixture w/coronylovalene) [ ] MW Difluorantheno- [3.5,4.6],[4.6,9.11]coronene [ ] MW MG MG neat, 1x10mg neat, 1x100mg Coronylovalene (mixture w/dicoronylene) [ ] MW MG MG neat, 1x10mg neat, 1x100mg MG neat, 1x10mg Tetracosahydrocoronene Perhydrocoronene [ ] MW T MG 200µg/mL toluene, 1x1mL neat, 1x10mg 336

339 Nitrocoronenes Nitrocoronene [ ] MW T MG 100µg/mL toluene, 1x1mL neat, 1x10mg ther PAs ,2,3,4-Tetraphenyl-1,3- cyclopentadiene [ ] MW Tetrabenzo[def,lm,grs,yz]- pyranthrene [ ] MW K-T 1000µg/mL toluene, 1x1mL Dibenzo[lm,yz]pyranthrene [ ] MW UG neat, 1x10µg Rubrene (5,6,11,12-Tetraphenylnaphthacene) [ ] MW Please inquire T 200µg/mL toluene, 1x1mL Compounds 337

340 ther ketopas Benzanthrone [ ] MW ,16-Pyranthrenedione Pyranthrone [ ] MW MG neat, 1x10mg (10)-Acridone [ ] MW N T 200µg/mL toluene, 1x1mL MG neat, 1x10mg Isoviolanthrone [ ] MW MG neat, 1x10mg ,2,3,6,7,8,11,12- ctahydrobenzo[e]pyren- 9(10)-one [ ] MW T 200µg/mL toluene, 1x1mL MG neat, 1x10mg Violanthrone [ ] MW MG neat, 1x10mg T MG 200µg/mL toluene, 1x1mL neat, 1x10mg ther KetoPA Kit KIT Kit ther nitropas Nitrobenzanthrone NBA [ ] MW N T MG 100µg/mL toluene, 1x1mL neat, 1x10mg 338

341 PANs (Nitrogen-heterocyclic PAs) Quinolines and benzoquinolines C0-C1 Quinolines K-I Quinoline [ ] 1000µg/mL isooctane 1 1mL K-I Decahydroquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylquinoline Quinaldine [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methylquinoline Lepidine [ ] 1000µg/mL isooctane 1 1mL K-I 6-Methylquinoline p-toluquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 7-Methylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 8-Methylquinoline o-toluquinoline [ ] 1000µg/mL isooctane 1 1mL KIT C0-C1Quinoline Kit Kit C2-C3 Quinolines N K-I 2,3-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 2,4-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 2,6-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 2,7-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 2,8-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 4,6-Dimethylquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 4,6,8-Trimethylquinoline [ ] 1000µg/mL isooctane 1 1mL KIT C2-C3 Quinoline Kit Kit ther quinolines MG 3,4-Dihydro-6-methyl-2(1)-quinolinone isomer mixture (unidentified isomers) [ ] neat 1 10mg K-I 4-Methyl-8-nitroquinoline [ ] 1000µg/mL isooctane 1 1mL Isoquinolines N K-I Isoquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 1-Methylisoquinoline [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylisoquinoline [ ] 1000µg/mL isooctane 1 1mL MG 5-ydroxyisoquinoline [ ] neat 1 10mg KIT Isoquinoline Kit Kit Compounds 339

342 Benzoquinolines Benzo[c]quinoline 3,4-Benzoquinoline [ ] MW Methylbenzo[f]quinoline [ ] MW N N K-T 1000µg/mL toluene, 1x1mL I 100µg/mL isooctane, 1x1mL Benzo[f]quinoline 5,6-Benzoquinoline [ ] MW ,4-Dimethylbenzo[h]quinoline [ ] MW N N I 100µg/mL isooctane, 1x1mL K-T 1000µg/mL toluene, 1x1mL Benzoquinoline Kit Benzo[h]quinoline 7,8-Benzoquinoline [ ] MW KIT Kit N T 200µg/mL toluene, 1x1mL 340

343 Acridines I Acridine [ ] 200µg/mL isooctane 1 1mL I 2-Methylacridine [ ] 200µg/mL isooctane 1 1mL I 9-Methylacridine [ ] 200µg/mL isooctane 1 1mL I Benz[a]acridine [ ] 200µg/mL isooctane 1 1mL T Benz[c]acridine [ ] 200µg/mL toluene 1 1mL T 7,9-Dimethylbenz[c]acridine [ ] 200µg/mL toluene 1 1mL K-T 7,10-Dimethylbenz[c]acridine [ ] 1000µg/mL toluene 1 1mL T Dibenz[a,c]acridine [ ] 200µg/mL toluene 1 1mL T Dibenz[a,h]acridine [ ] 200µg/mL toluene 1 1mL T Dibenz[a,i]acridine [ ] 200µg/mL toluene 1 1mL T Dibenz[a,j]acridine [ ] 200µg/mL toluene 1 1mL T Dibenz[c,h]acridine [ ] 200µg/mL toluene 1 1mL KIT Acridine / Benzacridine Kit Kit K-I 9-Aminoacridine hemihydrate [ ] 1000µg/mL isooctane 1 1mL Carbazoles N Carbazole and alkylcarbazoles N K-T Carbazole 9-Carbazole [ ] 1000µg/mL toluene 1 1mL MG Carbazole 9-Carbazole [ ] neat 1 10mg K-T 1,2,3,4-Tetrahydrocarbazole [ ] 1000µg/mL toluene 1 1mL T 2-Methylcarbazole 2-Me-9-Carbazole [ ] 200µg/mL toluene 1 1mL T 3-Methylcarbazole 3-Me-9-Carbazole [ ] 200µg/mL toluene 1 1mL K-T 9-Methylcarbazole 9-Me-9-Carbazole [ ] 1000µg/mL toluene 1 1mL K-T 3-Ethylcarbazole 3-Et-9-Carbazole [ ] 1000µg/mL toluene 1 1mL K-T 9-Ethylcarbazole 9-Et-9-Carbazole [ ] 1000µg/mL toluene 1 1mL K-T 9-Isopropylcarbazole 9-Isopropyl-9-Carbazole [ ] 1000µg/mL toluene 1 1mL K-T 9-n-ctylcarbazole 9-n-ctyl-9-Carbazole [ ] 1000µg/mL toluene 1 1mL KIT Carbazole Kit Kit Compounds 341

344 Benzocarbazoles Benzo[b]carbazole [ ] MW ,6,6a,11a-Tetrahydro-11benzo[a]carbazole [ ] MW N N T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Benzo[c]carbazole [ ] MW Benzocarbazole Kit KIT Kit N T 200µg/mL toluene, 1x1mL Benzo[a]carbazole [ ] MW N T 200µg/mL toluene, 1x1mL 342

345 Alkyl- / Phenylcarbazoles Methyl-11()- benzo[a]carbazole [ ] MW Methyl-11()- benzo[a]carbazole MW C N N T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Methyl-7()-benzo[c]carbazole [ ] MW Methyl-7()- benzo[c]carbazole [ ] MW C 3 N 3 C N I 200µg/mL isooctane, 1x1mL I 200µg/mL isooctane, 1x1mL Methyl-11()- benzo[a]carbazole MW Ethyl-7- methylbenzo[b]carbazole [ ] MW N N C 3 3C T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Methyl-7()- benzo[c]carbazole [ ] MW Phenylcarbazole [ ] MW N I 3 C N 200µg/mL isooctane, 1x1mL K-T 1000µg/mL toluene, 1x1mL Compounds Alkyl/ phenylbenzocarbazoles Kit KIT Kit Benzocarbazole and alkyl/ phenyl benzocarbazole Kit KIT Kit 343

346 Dibenzocarbazoles ()-Dibenzo[a,i]carbazole [ ] MW Dibenzo[c,g]carbazole [ ] MW N N T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Dibenzocarbazole Kit KIT Kit ydroxycarbazoles ydroxycarbazole [ ] MW I 100µg/mL isooctane, 1x1mL ydroxy-5,6,7,8-tetrahydro-9- methylcarbazole MW ydroxycarbazole [ ] MW N I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL ydroxy-5,6,7,8- tetrahydrocarbazole [ ] MW ydroxy-11-indolo [2,3-f]naphthalene [ ] MW N N I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL 344

347 ,6-Dihydro-4-hydroxy- 11-indolo[2,3-f]naphthalene MW Bromo-5,6-dihydro-4- hydroxy-11-indolo [2,3-f]napththalene MW N Br N I 100µg/mL isooctane, 1x1mL I 100µg/mL isooctane, 1x1mL ydroxy-5,6,6a,11atetrahydro-11benzo[a]carbazole MW ydroxycarbazole Kit KIT Kit N I 100µg/mL isooctane, 1x1mL ther carbazoles K-I 3,6-Diaminocarbazole [ ] 1000µg/mL isooctane 1 1mL K-I 3-Amino-9-ethylcarbazole [ ] 1000µg/mL isooctane 1 1mL K-T N-Ethylcarbazole-3-carboxaldehyde [ ] 1000µg/mL toluene 1 1mL K-T 9-Ethyl-3-nitrocarbazole [ ] 1000µg/mL toluene 1 1mL Dibenzazepines / porphines ,11-Dihydro-5-dibenz[b,f] azepine [ ] MW ,3,7,8,12,13,17,18- ctaethylporphine [ ] MW N N N N N Compounds K-I 1000µg/mL isooctane, 1x1mL AN 100µg/mL acetonitrile, 1x1mL 345

348 PASs (Sulfur-heterocyclic PAs) Thiophenes Thiophene and alkylthiophenes MG Thiophene [ ] neat 1 100mg MG 2-Methylthiophene [ ] neat 1 100mg MG 3-Methylthiophene [ ] neat 1 100mg K-I 2,3-Dimethylthiophene [ ] 1000µg/mL isooctane 1 1mL MG 2,4-Dimethylthiophene [ ] neat 1 10mg MG 2,5-Dimethylthiophene [ ] neat 1 100mg K-I 3,4-Dimethylthiophene [ ] 1000µg/mL isooctane 1 1mL MG 2-Ethylthiophene [ ] neat 1 100mg MG 3-Ethylthiophene [ ] neat 1 100mg MG 2,3,5-Trimethylthiophene [ ] neat 1 10mg MG 2-Ethyl-5-methylthiophene [ ] neat 1 100mg MG 2-n-Propylthiophene [ ] neat 1 100mg MG 3-n-Propylthiophene [ ] neat 1 100mg ,3,4,5-Tetramethylthiophene [ ] Please inquire 1 100mg MG 2-n-Butylthiophene [ ] neat 1 100mg MG 2-n-Amylthiophene [ ] neat 1 100mg K-I 2-Phenylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-Phenylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-Butyl-5-ethylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-exylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-eptylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-ctylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-ctylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-Nonylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-Decylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-Undecylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-Dodecylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-Tetradecylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-exadecylthiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-n-ctadecylthiophene [ ] 1000µg/mL isooctane 1 1mL KIT Thiophene Kit (Not including ) Kit ther thiophene G 3-Chlorothiophene [ ] neat 1 1g G 2-Bromothiophene [ ] neat 1 1g K-I 3-Bromothiophene [ ] 1000µg/mL isooctane 1 1mL Benzothiophenes C0-C1 Benzothiophenes (Benz[b]thiophenes, Thionaphthenes) K-I Benzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 5-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 6-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 7-Methylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL KIT C0-C1 Benzothiophene Kit Kit 346

349 C2 Benzothiophenes K-I 2,3-Dimethylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2,4-/2,6-Dimethylbenzothiophene [ /] [ ] 1000µg/mL isooctane 1 1mL K-I 2,5-Dimethylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 3,5-Dimethylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL KIT Dimethylbenzothiophene Kit Kit C3 Benzothiophenes K-I 2,3,4-/2,3,6-Trimethylbenzothiophene [ /] [ ] 1000µg/mL isooctane 1 1mL K-I 2,5,7-Trimethylbenzothiophene [ ] 1000µg/mL isooctane 1 1mL KIT Trimethylbenzothiophene Kit Kit KIT Benzothiophene Kit Kit Benzo[c]thiophenes ,3-Diphenylbenzo[c]thiophene [ ] MW S K-I 1000µg/mL isooctane, 1x1mL Dibenzothiophenes C0-C1 Dibenzothophenes I Dibenzothiophene [ ] 500µg/mL isooctane 1 1mL T 1-Methyldibenzothiophene 1-MDMP [ ] 10µg/mL toluene 1 1mL I 2-Methyldibenzothiophene 2-MDMP [ ] 500µg/mL isooctane 1 1mL I 3-Methyldibenzothiophene 3-MDMP [ ] 50µg/mL isooctane 1 1mL I 4-Methyldibenzothiophene 4-MDMP [ ] 500µg/mL isooctane 1 1mL KIT C0-C1 Dibenzothiophene Kit Kit C2 Dibenzothiophenes I 1,2-Dimethyldibenzothiophene 1,2-DMDMP [ ] 500µg/mL isooctane 1 1mL I 1,3-Dimethyldibenzothiophene 1,3-DMDMP [ ] 500µg/mL isooctane 1 1mL I 1,4-Dimethyldibenzothiophene 1,4-DMDMP [ ] 500µg/mL isooctane 1 1mL I 2,3-Dimethyldibenzothiophene 2,3-DMDMP [ ] 500µg/mL isooctane 1 1mL I 2,4-Dimethyldibenzothiophene 2,4-DMDMP [ ] 500µg/mL isooctane 1 1mL I 2,6-Dimethyldibenzothiophene 2,6-DMDMP [ ] 500µg/mL isooctane 1 1mL I 2,8-Dimethyldibenzothiophene 2,8-DMDMP [ ] 500µg/mL isooctane 1 1mL I 3,6-Dimethyldibenzothiophene 3,6-DMDMP [ ] 100µg/mL isooctane 1 1mL I 4,6-Dimethyldibenzothiophene 4,6-DMDMP [ ] 500µg/mL isooctane 1 1mL Compounds 347

350 I 2-Ethyldibenzothiophene 2-EDMP [ ] 500µg/mL isooctane 1 1mL I 4-Ethyldibenzothiophene 4-EDMP [ ] 500µg/mL isooctane 1 1mL KIT Dimethyldibenzothiophene Kit Kit KIT C2 Dibenzothiophene Kit Kit C3 Dibenzothiophenes I 2,3,7-/2,3,8-Trimethyldibenzothiophene [ /] [ ] 500µg/mL isooctane 1 1mL I 2,4,6-Trimethyldibenzothiophene 2,4,6-TDMP [ ] 100µg/mL isooctane 1 1mL I 2,4,7-Trimethyldibenzothiophene 2,4,7-TDMP [ ] 500µg/mL isooctane 1 1mL I 2,4,8-Trimethyldibenzothiophene 2,4,8-TDMP [ ] 100µg/mL isooctane 1 1mL I 4-Ethyl-6-methyldibenzothiophene 4-E-6-MDMP [ ] 500µg/mL isooctane 1 1mL I 2-n-Propyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 4-n-Propyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL KIT Trimethyldibenzothiophene Kit Kit KIT C3 Dibenzothiophene Kit Kit C4+ Dibenzothiophenes I 4,6-Diethyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 2-n-Butyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 4-n-Butyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 2-n-Pentyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 4-n-Pentyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL KIT C4+ Dibenzothiophene Kit Kit Phenyldibenzothiophenes I 1-Phenyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 2-Phenyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 3-Phenyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL I 4-Phenyldibenzothiophene [ ] 500µg/mL isooctane 1 1mL KIT Phenyldibenzothiophene Kit Kit 348

351 Benzo-/ Naphtho-/ Acenaphthylenothiophenes Benzo[b]naphtho[1,2-d] thiophene [ ] MW Methylbenzo[b] naphtho[2,3-d]thiophene [ ] MW S S C T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Benzo[b]naphtho[2,3-d] thiophene [ ] MW Methylbenzo[b] naphtho[2,3-d]thiophene [ ] MW T 200µg/mL toluene, 1x1mL T S 200µg/mL toluene, 1x1mL Dinaphtho[2,1-b;1,2 -d] thiophene [ ] MW Benzo[b]naphtho[2,1-d] thiophene [ ] MW S T 200µg/mL toluene, 1x1mL T S 200µg/mL toluene, 1x1mL Diacenaphthyleno [1,2-b;1,2 -d]thiophene [ ] MW ,8,9,10-Tetrahydrobenzo[b] naphtho[2,3-d]thiophene [ ] MW S T S 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Dibenzo[2,3;10,11]peryleno [1,12-bcd]thiophene [ ] MW Compounds S CB 20µg/mL chlorobenzene, 1x1mL 349

352 Diphenanthro [9,10-b;9,10 -d]thiophene [ ] MW Benzo/Naphtho/ Acenaphthylenothiophene Kit KIT Kit S MG T neat, 1x1mg 200µg/mL toluene, 1x1mL ydroxydibenzothiophenes T 2-ydroxydibenzothiophene [ ] 100µg/mL toluene 1 1mL Bromodibenzothiophenes K-I 2-Bromodibenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 4-Bromodibenzothiophene [ ] 1000µg/mL isooctane 1 1mL K-I 2,8-Dibromodibenzothiophene [ ] 1000µg/mL isooctane 1 1mL KIT Bromodibenzothiophene Kit Kit ther dibenzothiophenes Dibenzothiophene sulfone [ ] MW ϒ-xo-α-methyl-2- dibenzothiophenebutyric acid [ ] MW S S MG neat, 1x100mg AN 100µg/mL acetonitrile, 1x1mL 350

353 PAs (xygen-heterocyclic PAs) Benzofurans Benzofuran and alkylbenzofurans K-X Benzofuran [ ] 1000µg/mL n-hexane 1 1mL K-X 2,3-Dihydrobenzofuran [ ] 1000µg/mL n-hexane 1 1mL K-I 2-Methylbenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 3-Methylbenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 2,3-Dihydro-2-methylbenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 2-Ethylbenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-Butylbenzofuran [ ] 1000µg/mL isooctane 1 1mL KIT Benzofuran Kit Kit Dibenzofurans Dibenzofuran and methyldibenzofuranes K-I Dibenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 1-Methyldibenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyldibenzofuran [ ] 1000µg/mL isooctane 1 1mL K-I 4-Methyldibenzofuran [ ] 1000µg/mL isooctane 1 1mL KIT Dibenzofuran / Methyldibenzofuran Kit Kit ydroxydibenzofurans MG 2-ydroxydibenzofuran [ ] neat 1 10mg alodibenzofurans T 2,8-Dichlorodibenzofuran [ ] 50µg/mL toluene 1 1mL T ctachlorodibenzofuran [ ] 50µg/mL toluene 1 1mL ME 2-Bromodibenzofuran [ ] 50µg/mL methanol 1 1mL Phenyldibenzofurans I 1-Phenyldibenzofuran [ ] 500µg/mL isooctane 1 1mL I 2-Phenyldibenzofuran [ ] 500µg/mL isooctane 1 1mL I 4-Phenyldibenzofuran [ ] 500µg/mL isooctane 1 1mL KIT Phenyldibenzofuran Kit Kit Compounds 351

354 Benzonaphthofurans Benzo[b]naphtho[1,2-d]furan [ ] MW Benzo[b]naphtho[2,3-d]furan [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Benzo[b]naphtho[2,1-d]furan [ ] MW T 200µg/mL toluene, 1x1mL 352

355 Dinaphthofurans Dinaphtho[1,2-b;1,2 -d]furan [ ] MW Dinaphtho[2,1-b;2,3 -d]furan [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Dinaphtho[1,2-b;2,1 -d]furan [ ] MW Dinaphtho[2,3-b;2,3 -d]furan [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Dinaphtho[1,2-b;2,3 -d]furan [ ] MW Benzo- and Dibenzonaphthofuran Kit KIT Kit T 200µg/mL toluene, 1x1mL Benzo[1,2-b;4,5-b ] bisbenzofuran [ ] MW Dinaphtho[2,1-b;1,2 -d]furan [ ] MW T 200µg/mL toluene, 1x1mL T 200µg/mL toluene, 1x1mL Compounds 353

356 PPs (Persistent organic pollutants) PCBs (Polychlorobiphenyls) F-PCBs, Internal standards for PCBs MG 2-Fluorobiphenyl [ ] neat 1 100mg MG 4-Fluorobiphenyl F-PCB-0p [ ] neat 1 100mg I 4-Chloro-4 -fluorobiphenyl F-PCB-3p-3p [ ] 100µg/mL isooctane 1 1mL I 3 -Fluoro-3,5-dichlorobiphenyl F-PCB [ ] 100µg/mL isooctane 1 1mL I 3-Fluoro-4,4 -dichlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3-Fluoro-2,2,5- trichlorobiphenyl F-PCB-18m µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,4 - trichlorobiphenyl F-PCB-22m µg/mL isooctane 1 1mL I 3 -Fluoro-2,4,4 -trichlorobiphenyl F-PCB-28m [ ] 100µg/mL isooctane 1 1mL I 3 -Fluoro-2,4,5-trichlorobiphenyl F-PCB-29m µg/mL isooctane 1 1mL I 2 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30o [ ] 100µg/mL isooctane 1 1mL I 3 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30m [ ] 100µg/mL isooctane 1 1mL I 4 -Fluoro-2,4,6-trichlorobiphenyl F-PCB-30p [ ] 100µg/mL isooctane 1 1mL I 3 -Fluoro-3,4,4 - trichlorobiphenyl F-PCB -37 m µg/mL isooctane 1 1mL I 3 -Fluoro-3,4,5-trichlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3-Fluoro-2,2,4,4 - tetrachlorobiphenyl F-PCB [ ] 100µg/mL isooctane 1 1mL I 3-Fluoro-2,2,5,5 - tetrachlorobiphenyl F-PCB-52m [ ] 100µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,5,6- tetrachlorobiphenyl F-PCB [ ] 100µg/mL isooctane 1 1mL I 4 -Fluoro-2,3,4,5-tetrachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3 -Fluoro-2,4,4,5- tetrachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5-Fluoro-3,3,4,4 - tetrachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3 -Fluoro-3,4,4,5- tetrachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5 -Fluoro-2,3,3,4,4 - pentachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,4,4,5- pentachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,4,5,6- pentachlorobiphenyl F-PCB [ ] 10µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,4,5,6- pentachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5 -Fluoro-2,3,4,4,5- pentachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5 -Fluoro-3,3,4,4,5- pentachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5 -Fluoro-2,3,3,4,4,5- hexachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 2 -Fluoro-2,3,3,4,5,6- hexachlorobiphenyl F-PCB-160o µg/mL isooctane 1 1mL I 4 -Fluoro-2,3,3,4,5,6- hexachlorobiphenyl F-PCB-160p µg/mL isooctane 1 1mL 354

357 I 5 -Fluoro-2,3,3,4,5,6- hexachlorobiphenyl F-PCB-160m µg/mL isooctane 1 1mL I 3 -Fluoro-2,3,4,4,5,6- hexachlorobiphenyl F-PCB µg/mL isooctane 1 1mL I 5 -Fluoro-2,3,3,4,4,5,6- heptachlorobiphenyl F-PCB µg/mL isooctane 1 1mL K-AN Decafluorobiphenyl [ ] 2000µg/mL acetonitrile 1 1mL MG Decafluorobiphenyl [ ] neat 1 100mg Native PCBs I 3,5-Dichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 4,4 -Dichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,2,5-Trichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,4 -Trichlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL I 2,4,4 -Trichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,4,4 -Trichlorobiphenyl PCB [ ] neat 1 10mg I 2,4,6-Trichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 10mL I 2,4,5-Trichlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 3,4,4 -Trichlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL I 3,4,5-Trichlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL I 2,2,3,4 -Tetrachlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL I 2,2,3,5 -Tetrachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,2,4,4 -Tetrachlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL I 2,2,5,5 -Tetrachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,2,5,5 -Tetrachlorobiphenyl PCB [ ] neat 1 10mg I 2,3,4,5-Tetrachlorobiphenyl PCB [ ] 100µg/mL isooctane 1 1mL ME 2,3,5,6-Tetrachlorobiphenyl PCB [ ] 100µg/mL methanol 1 1mL I 2,4,4,5-Tetrachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,4,4,5-Tetrachlorobiphenyl PCB [ ] neat 1 10mg I 3,3,4,4 -Tetrachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 3,4,4,5-Tetrachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 3,4,4,5-Tetrachlorobiphenyl PCB [ ] neat 1 5mg I 2,2,3,5,6-Pentachlorobiphenyl PCB [ ] 100µg/mL Isooctane 1 1mL MG 2,2,3,5,6-Pentachlorobiphenyl PCB [ ] neat 1 10mg I 2,2,4,5,5 -Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,2,4,5,5 -Pentachlorobiphenyl PCB [ ] neat 1 10mg I 2,3,3,4,4 -Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,3,5,5 -Pentachlorobiphenyl PCB [ ] 100 µg/ml isooctane 1 1mL I 2,3,4,4,5-Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,4,5,6-Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,4,4,5-Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,3,4,4,5-Pentachlorobiphenyl PCB [ ] neat 1 10mg I 2,3,4,4,5-Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 3,3,4,4,5-Pentachlorobiphenyl PCB [ ] neat 1 5mg I 3,3,4,4,5-Pentachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,2,3,4,4,5-exachlorobiphenyl PCB [ ] 100 µg/ml isooctane 1 1mL MG 2,2,3,4,4,5-exachlorobiphenyl PCB [ ] neat 1 10mg I 2,2,3,4,4,5 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,2,3,4,4,5 -exachlorobiphenyl PCB [ ] neat 1 10mg I 2,2,3,4,5,6 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,2,3,4,5,6-exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,2,4,4,5,5 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL MG 2,2,4,4,5,5 -exachlorobiphenyl PCB [ ] neat 1 10mg I 2,2,4,4,6,6 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,3,4,4,5-exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,3,4,4,5 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,4,4,5,5 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 2,3,4,4,5,6-exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL I 3,3,4,4,5,5 -exachlorobiphenyl PCB [ ] 100 µg/ml Isooctane 1 1mL Compounds 355

358 I 2,2,3,3,4,4,5- eptachlorobiphenyl PCB [ ] 100 αg/ml Isooctane 1 1mL I 2,2,3,4,4,5,5 - eptachlorobiphenyl PCB [ ] 100 αg/ml Isooctane 1 1mL MG 2,2,3,4,4,5,5 - eptachlorobiphenyl PCB [ ] neat 1 10mg I 2,3,3,4,4,5,5 - eptachlorobiphenyl PCB [ ] 100 αg/ml Isooctane 1 1mL I 2,3,3,4,4,5,6- eptachlorobiphenyl PCB [ ] 100 αg/ml Isooctane 1 1mL I 2,2,3,3,4,4,5,5 - ctachlorobiphenyl PCB [ ] 100 αg/ml Isooctane 1 1mL I 2,2,3,4,4,5,6,6 - ctachlorobiphenyl PCB [ ] 100 µg/ml isooctane 1 1mL I 2,2,3,3,4,4,5,6,6 - Nonachlorobiphenyl PCB [ ] AminoPCBs K-I 2,2,5,5 -Tetrachlorobenzidine [ ] 1000µg/mL isooctane 1 1mL Arochlors I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL 356

359 I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor [ ] 10µg/mL isooctane 1 1mL I Arochlor [ ] 100µg/mL isooctane 1 1mL K-I Arochlor [ ] 1000µg/mL isooctane 1 1mL I Arochlor [ ] 10µg/mL isooctane 5 1mL I Arochlor [ ] 100µg/mL isooctane 5 1mL K-I Arochlor [ ] 1000µg/mL isooctane 5 1mL I Arochlor [ ] 10µg/mL isooctane 10 1mL I Arochlor [ ] 100µg/mL isooctane 10 1mL K-I Arochlor [ ] 1000µg/mL isooctane 10 1mL I Arochlor µg/mL isooctane 1 1mL I Arochlor µg/mL isooctane 1 1mL K-I Arochlor µg/mL isooctane 1 1mL I Arochlor µg/mL isooctane 5 1mL I Arochlor µg/mL isooctane 5 1mL K-I Arochlor µg/mL isooctane 5 1mL I Arochlor µg/mL isooctane 10 1mL I Arochlor µg/mL isooctane 10 1mL K-I Arochlor µg/mL isooctane 10 1mL PBBs (Polybromobiphenyls) F-PBBs (Fluoro-bromobiphenyl internal standards) K-DC 4,4 -Dibromooctafluorobiphenyl F-PBB [ ] 2000µg/mL DCM 1 1mL I 4,4 -Dibromooctafluorobiphenyl F-PBB [ ] 100µg/mL isooctane 1 1mL Native PBBs (polybromobiphenyls) I 2-Bromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 3-Bromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 4-Bromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2 -Dibromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,4-Dibromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,5-Dibromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,6-Dibromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 4,4 -Dibromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,5-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,3,5-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,4,5-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,4,6-Tribromobiphenyl PBB [ ] 35µg/mL isooctane 1 1mL I 2,4,6-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,4,5-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 3,4,5-Tribromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,4,5 -Tetrabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,5,5 -Tetrabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,5,6 -Tetrabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 3,3,5,5 -Tetrabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL Compounds 357

360 I 2,2,4,5,5 -Pentabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,4,5,6-Pentabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,4,4,5,5 -exabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 2,2,4,4,6,6 -exabromobiphenyl PBB [ ] 50µg/mL isooctane 1 1mL I 3,3,4,4,5,5 -exabromobiphenyl PBB [ ] 10µg/mL isooctane 1 1mL I ctabromodiphenyl, techn. PBB [ ] 50µg/mL isooctane 1 1mL I Decabromodiphenyl PBB [ ] 50µg/mL isooctane 1 1mL KIT PBB Kit Kit Dioxins T Dibenzo-p-dioxin-d [ ] 50µg/mL toluene 1 1mL T Dibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T 1-Chlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T 2-Chlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T 2,7-Dichlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T 1,2,4-Trichlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T 1,2,3,4-Tetrachlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL T ctachlorodibenzo-p-dioxin [ ] 50µg/mL toluene 1 1mL 358 Flame retardants F-PBDE internal standards I 2-Fluorodiphenyl ether F-PBDE-0 ortho [ ] 50µg/mL isooctane 1 1mL I 4-Fluorodiphenyl ether F-PBDE-0 para [ ] 50µg/mL isooctane 1 1mL K-I 2,4 -Difluorodiphenyl ether [ ] 1000µg/mL isooctane 1 1mL K-I 3,3 -Difluorodiphenyl ether [ ] 1000µg/mL isooctane 1 1mL I 3-Bromo-4 - fluorodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL I 3 -Fluoro-2,4- dibromodiphenyl ether F-PBDE µg/mL isooctane 1 1mL I 3 -Fluoro-3,4- dibromodiphenyl ether F-PBDE µg/mL isooctane 1 1mL I 4 -Fluoro-2,3,4- tribromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL I 4 -Fluoro-2,3,6- tribromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL T 2 -Fluoro-2,4,4 - tribromodiphenyl ether F-PBDE [ ] 50µg/mL toluene 1 1mL T 6-Fluoro-2,2,4,4 - tetrabromodiphenyl ether F-PBDE [ ] 50µg/mL toluene 1 1mL I 5,5 -Difluoro-2,2,4,4 - tetrabromodiphenyl ether (2,2,4,4 -Tetrabromo-5,5 - difluorodiphenyl ether) 2F-PBDE [ ] 50µg/mL isooctane 1 1mL I 6-Fluoro-2,3,4,4 - tetrabromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL I 4 -Fluoro-2,3,4,6- tetrabromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL I 5,6-Difluoro-2,2,3,4,4 - pentabromodiphenylether (2,2,3,4,4 -Pentabromo-5,6- difluorodiphenyl ether) 2F-PBDE [ ] 50µg/mL isooctane 1 1mL I 3,6-Difluoro-2,2,4,4,5- pentabromodiphenyl ether (2,2,4,4,5-Pentabromo-3,6- difluorodiphenyl ether) 2F-PBDE [ ] 50µg/mL isooctane 1 1mL T 3-Fluoro-2,2,4,4,6- pentabromodiphenyl ether F-PBDE [ ] 50µg/mL toluene 1 1mL I 3-Fluoro-2,3,4,4,6- pentabromodiphenyl ether F-PBDE [ ] 50µg/mL Isooctane 1 1mL

361 I T T T I 3,5-Difluoro-2,3,4,4,6- pentabromodiphenyl ether (2,3,4,4,6-Pentabromo-3,5- difluorodiphenyl ether) 2F-PBDE [ ] 50µg/mL isooctane 1 1mL 4 -Fluoro-2,3,3,4,5,6- hexabromodiphenyl ether F-PBDE [ ] 50µg/mL toluene 1 1mL 3-Fluoro-2,2,4,4,5,5,6- heptabromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL 2,4 -Difluoro-2,3,3,4,5,5,6,6 - ctabromodiphenyl ether 2F-PBDE [ ] 50µg/mL toluene 1 1mL 4 -Fluoro-2,2,3,3,4,5,5,6,6 - nonabromodiphenyl ether F-PBDE [ ] 50µg/mL isooctane 1 1mL Native PBDEs I 2,3,4-Tribromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,3,4-Tribromodiphenyl ether PBDE [ ] neat 1 5mg I 2,4,4 -Tribromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,4,4 -Tribromodiphenyl ether PBDE [ ] neat 1 5mg I 3,3,4-Tribromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I 2,2,4,4 -Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I 2,2,4,4 -Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 10 1mL I 2,2,4,4 -Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 20 1mL MG 2,2,4,4 -Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,4,5 -Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,4,5 -Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,3,4,4-Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,3,4,4-Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,3,4,6-Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,3,4,6-Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,4,4,6-Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,4,4,6-Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 3,3,4,4 -Tetrabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 3,3,4,4 -Tetrabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,3,4,4 -Pentabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,3,4,4 -Pentabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,4,4,5-Pentabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,4,4,5-Pentabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,4,4,6-Pentabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,4,4,6-Pentabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,3,4,4,5-Pentachlorobiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I 2,3,4,4,6-Pentabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,3,4,4,6-Pentabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,3,4,4,5- exabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,3,4,4,5- exabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,4,4,5,5 - exabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,4,4,5,5 - exabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,4,4,5,6 - exabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,4,4,5,6 - exabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,3,4,4,5,6- eptabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I 2,2,3,4,4,5,6 - eptabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG 2,2,3,4,4,5,6 - eptabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,3,3,4,4,5,6- eptabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL 359 Compounds

362 MG 2,3,3,4,4,5,6- eptabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,2,3,3,4,4,5,6- ctabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I 2,2,3,4,4,5,5,6 - ctabromodiphenyl ether PBDE [ ] 50µg/mL Isooctane 1 1mL MG 2,2,3,4,4,5,5,6 - ctabromodiphenyl ether PBDE [ ] neat 1 5mg I 2,3,3,4,4,5,5,6- ctabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL I Decabromodiphenyl ether PBDE [ ] 50µg/mL isooctane 1 1mL MG Decabromodiphenyl ether PBDE [ ] neat 1 5mg I Lake Michigan Study PBDEs (Kit w/single solutions) 50µg/mL isooctane 1 Kit I ther relevant PBDEs (Kit w/single solutions) 50µg/mL isooctane 1 Kit KIT PBDE solutions Kit Kit Aminodiphenyl ethers ML 4-Aminodiphenyl ether [ ] neat 1 1mL ther brominated flame retardants Chloro-3-methylphenol [ ] MW Dibromoneopentylglycol [ ] MW K-IP 1000µg/mL isopropanol, 1x1mL Br Decabromodiphenyl PBB-209 [ ] MW IP Br 50µg/mL isopropanol, 1x1mL I 50µg/mL isooctane, 1x1mL Decabromodiphenylethane [ ] MW ,4-Dibromophenol [ ] MW K-IP 1000µg/mL isopropanol, 1x1mL Br Br Br Br Br C 3 Br Br Br Br Br exabromobenzene [ ] MW I 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1mL ,2,5,6,9,10- exabromocyclododecane [ ] MW Br Br Br K-I Br Br Br 1000µg/mL isooctane, 1x1mL 360

363 ,2,3,4,5,6- exabromocyclohexane [ ] MW Tetrabromobisphenol A dimethyl ether [ ] MW I 50µg/mL isooctane, 1x1mL Br Br C 3 3 C C ctabromodiphenyl, techn. PBB [ ] MW I C 3 Br Br 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1mL Tetrabromophthalic anhydride [ ] MW Pentabromophenol [ ] MW I 50µg/mL isooctane, 1x1mL I 50µg/mL isooctane, 1x1mL Pentabromotoluene [ ] MW I 50µg/mL isooctane, 1x1mL Tetrabromobisphenol A [ ] MW Br Br Tetradecabromo- 1,4-diphenoxybenzene [ ] MW CY 50µg/mL cyclohexane, 1x1mL ,4,6-Tribromophenol K-IP [ ] MW µg/mL isopropanol, 1x1mL C 3 Br C 3 Br I 50µg/mL isooctane, 1x1mL PCNs (Polychloronaphthalenes) I 1-Chloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 2-Chloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 1,4-Dichloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 1,5-Dichloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 2,3-Dichloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 2,6-Dichloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 2,7-Dichloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I 1,2,3,4-Tetrachloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL I Tetrachloronaphthalene, mix 50µg/mL Isooctane 1 1mL I ctachloronaphthalene PCN [ ] 50µg/mL Isooctane 1 1mL KIT PCN Kit Kit Compounds PBNs (Polybromonaphthalenes) I 1-Bromonaphthalene PBN [ ] 50µg/mL Isooctane 1 1mL I 2-Bromonaphthalene PBN [ ] 50µg/mL Isooctane 1 1mL I 1,4-Dibromonaphthalene PBN [ ] 50µg/mL Isooctane 1 1mL I 2,6-Dibromonaphthalene PBN [ ] 50µg/mL Isooctane 1 1mL 361

364 I 2,7-Dibromonaphthalene PBN [ ] 50µg/mL Isooctane 1 1mL I 1,2,3,4,6,7-exabromonaphthalene PBM µg/mL Isooctane 1 1mL KIT PBN Kit Kit PCAs (Polychlorinated n-alkanes) C8-C9 PCAs K-I 1,2-Dichlorooctane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorooctane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,7,8-Tetrachlorooctane [ ] 1000µg/mL isooctane 1 1mL ,1,1,3,7,8-exachlorooctane Please inquire K-I 1,1,1,3,6,8,8,8-ctachlorooctane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-Dichlorononane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorononane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,8,9-Tetrachlorononane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,8,9-exachlorononane [ ] 1000µg/mL isooctane 1 1mL ,1,1,3,7,9,9,9-ctachlorononane [ ] Please inquire KIT C8-C9 PCA Kit (Not including 1657,8 and 1655,9) Kit C10-C13 PCAs (SCCA) K-I 1,2-Dichlorodecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorodecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,9,10-Tetrachlorodecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,9,10-exachlorodecane isomer mixture [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,8,10,10,10-ctachlorodecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-Dichloroundecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachloroundecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,10,11-Tetrachloroundecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,10,11-exachloroundecane isomer mixture [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,9,11,11,11-ctachloroundecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-Dichlorododecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,12-Dichlorododecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorododecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,11,12-Tetrachlorododecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,11,12-exachlorododecane isomer mixture [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,10,12,12,12-ctachlorododecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2-Dichlorotridecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorotridecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,12,13-exachlorotridecane isomer mixture [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,11,13,13,13-ctachlorotridecane [ ] 1000µg/mL isooctane 1 1mL KIT C10-C13 PCA Kit Kit C14+ PCAs (MCCA) K-I 1,2-Dichlorotetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3-Tetrachlorotetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,2,13,14-Tetrachlorotetradecane [ ] 1000µg/mL isooctane 1 1mL K-I 1,1,1,3,12,12,12,14-ctachlorotetradecane [ ] 1000µg/mL isooctane 1 1mL K-DC 1-Chlorooctadecane [ ] 10000µg/mL dichloromethane1 1mL KIT C14 PCA Kit Kit KIT Dichloroalkane Kit Kit KIT Tetrachloroalkane Kit Kit KIT exachloroalkane Kit Kit KIT ctachloroalkane Kit Kit 362

365 Chlorinated fatty acids ME 9-Chloro- /10-Chlorooctadecanoic acid µg/mL methanol 1 1mL ME 7,8-Dichlorohexadecanoic acid [ ] 100µg/mL methanol 1 1mL ME 9,10-Dichlorooctadecanoic acid [ ] 100µg/mL methanol 1 1mL ME 9,10-/, 9,13-/, 10,12-/, 10,13- Dichlorooctadecane µg/mL methanol 1 1mL ME 9,10,12,13-Tetrachlorooctadecanoic acid [ ] 100µg/mL methanol 1 1mL PFAs (Perfluorinated alkane acids and alcohols) PFA Sulphonic acids ME Perfluorobutane sulphonic acid [ ] 50 ug/ml methanol 1 1mL ME Perfluorobutane sulphonylfluoride [ ] 50µg/mL methanol 1 1mL ME Perfluorobutane sulphonate, potassium salt [ ] 50µg/mL methanol 1 1mL ME Perfluorohexane sulphonylfluoride [ ] 50µg/mL methanol 1 1mL ME Perfluoro-4-ethyl-cyclohexane sulphonic acid, potassium salt [ ] 50µg/mL methanol 1 1mL ME Perfluorooctane sulphonic acid [ ] 50ug/ml methanol 1 1mL ME Perfluorooctane sulphonic acid, potassium salt [ ] 50µg/mL methanol 1 1mL Telomeric PFA Sulphonic acid ME 1,1,2,2-Perfluorooctanesulphonic acid [ ] 50µg/mL methanol 1 1mL PFA Sulphonamides AN Perfluorooctane sulfonamide [ ] 50 ug/ml acetonitrile 1 1mL PFA Acids ME Propanoic acid, pentafluoro-, sodium salt [ ] 50µg/mL methanol 1 1mL ME eptafluorobutyric acid [ ] 50µg/mL methanol 1 1mL ME Butanoic acid, heptafluoro-, sodium salt [ ] 50µg/mL methanol 1 1mL ME 5-ctafluoropentanoic acid 5 PFBA [ ] 50µg/mL methanol 1 1mL ME n-nonafluoropentanoic acid PFPA [ ] 50µg/mL methanol 1 1mL ME Perfluorohexanoic acid [ ] 50µg/mL methanol 1 1mL ME Perfluorocyclohexanoic acid PFCyxA [ ] 50µg/mL methanol 1 1mL ME 7-Perfluoroheptanoic acid 7 PFPA [ ] 50µg/mL methanol 1 1mL ME n-perfluoroheptanoic acid PFpA [ ] 50µg/mL methanol 1 1mL ME n-perfluorooctanoic acid [ ] 50µg/mL methanol 1 1mL ME n-perfluorooctanoic acid, ammonium salt PFA-N [ ] 50µg/mL methanol 1 1mL ME Pentafluoropropionic acid sodium salt [ ] 50µg/mL methanol 1 1mL ME 9-Perfluorononanoic acid 9 PFNA [ ] 50µg/mL methanol 1 1mL ME Perfluorononanoic acid PFNA [ ] 50µg/mL methanol 1 1mL ME n-perfluorodecanoic acid PFDA [ ] 50µg/mL methanol 1 1mL ME Perfluoro-3,7-dimethyloctanoic acid PF3,7DiMeA [ ] 50µg/mL methanol 1 1mL ME 11-Perfluoroundecanoic acid 11 PFUndA [ ] 50µg/mL methanol 1 1mL ME Perfluoroundecanoic acid PFUndA [ ] 50µg/mL methanol 1 1mL ME n-perfluorododecanoic acid PFDodA [ ] 50µg/mL methanol 1 1mL ME Perfluorotetradecanoic acid PFTedA [ ] 50µg/mL methanol 1 1mL ME Perfluorohexadecanoic acid PFxdA [ ] 50µg/mL methanol 1 1mL ME Perfluorooctadecanoic acid PFdA [ ] 50µg/mL methanol 1 1mL Compounds Telomeric acids ME 2,2,3,3- Perfluorohexanoic acid 3:3 FTCA [ ] 50µg/mL methanol 1 1mL 363

366 ME ME Unsaturated telomeric acid ME 2,3-Perfluorohex-2-enoic acid 3:3 FTUCA [ ] 50µg/mL methanol 1 1mL PFA Acid Internal standards ME 5-ctafluoropentanoic acid 5 PFBA [ ] 50µg/mL methanol 1 1mL ME 7-Perfluoroheptanoic acid 7 PFPA [ ] 50µg/mL methanol 1 1mL ME 9-Perfluorononanoic acid 9 PFNA [ ] 50µg/mL methanol 1 1mL ME 11-Perfluoroundecanoic acid 11 PFUndA [ ] 50µg/mL methanol 1 1mL PFA amides ME eptafluorobutyramide [ ] 50µg/mL methanol 1 1mL ME Perfluorooctanamide [ ] 50µg/mL methanol 1 1mL PFA alcohols 2,2,3,3- Perfluorononanoic acid 6:3 FTCA [ ] 50µg/mL methanol 1 1mL 1,1-Perfluoro-3,5,5-trimethylhexanoic acid 3,5,5-TriMe 5:1 FTCA [ ] 50µg/mL methanol 1 1mL Telomeric alcohols ME 3,3,4,4,4-Pentafluorobutan-1-ol 2:2 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,5- ctafluoropentan-1-ol 5 4:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2,3,3- Perfluorohexan-1-ol 3:3 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorohexan-1-ol 5:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,7- Perfluoroheptan-1-ol 7 6:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluoroheptan-1-ol 6:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2- Perfluorooctan-1-ol 6:2 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,8- Perfluorooctane-1-ol 8 7:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorooctane-1-ol 7:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2,3,3- Perfluorononan-1-ol 6:3 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2-Perfluoro-7- methyloctan-1-ol 7Me 6:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,9- Perfluorononan-1-ol 9 8:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorononan-1-ol 8:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,10,10-Perfluoro-1,10- decanediol 1:8:1 FTdi [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2- Perfluorodecan-1-ol 8:2 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorodecan-1-ol 9:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluoro-3,7- dimethyloctane-1-ol 3,7-DiMe 7:1 FT µg/mL methanol 1 1mL ME 1,1,2,2-Perfluoro-9- methyldecan-1-ol 9Me 8:2 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,11- Perfluoroundecan-1-ol 11 10:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluoroundecan-1-ol 10:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,2,2- Perfluorododecan-1-ol 10:2 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,13- Perfluorotridecan-1-ol 13 12:1 FT [ ] 50µg/mL 1 1mL ME 1,1-Perfluorotetradecan-1-ol 13:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorohexadecan-1-ol 15:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1-Perfluorooctadecan-1-ol 17:1 FT [ ] 50µg/mL methanol 1 1mL 364

367 Allylic alkohols ME ME 1,1,2,3-Perfluorohex- 2-en-1-ol Allylic 3:3 FT [ ] 50µg/mL methanol 1 1mL 1,1,2,3-Perfluoronon- 2-en-1-ol Allylic 6:3 FT [ ] 50µg/mL methanol 1 1mL Internal Standards ME 1,1,5- ctafluoropentan-1-ol 5 4:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,7- Perfluoroheptan-1-ol 7 6:1 FT [ ] 50µg/mL methanol 1 1mL ME 1,1,8- Perfluorooctane-1-ol 8 7:1 FT [ ] 50µg/mL methanol 1 1mL PFA aldehydes ME 7-Perfluoroheptanal [ ] 50µg/mL methanol 1 1mL VC (Volatile organic compounds) ML Bromochloromethane [ ] neat 1 1mL ML 2-Bromo-2-chloro-1,1,1-trifluoroethane [ ] neat 1 1mL ML Bromodichloromethane, in Certan bottle [ ] neat 1 1mL ML 2-Bromofluorobenzene [ ] neat 1 1mL ML Bromoform, in Certan bottle [ ] neat 1 1mL ML Carbon disulfide, in Certan bottle [ ] neat 1 1mL ML Chlorodibromomethane, in Certan bottle [ ] neat 1 1mL ML Chloroform, in Certan bottle [ ] neat 1 1mL ML 5-Chloro-2-methylaniline [ ] neat 1 1mL ML 3-Chloropropane [ ] neat 1 1mL ML 2-Chlorotoluene [ ] neat 1 1mL ML 4-Chlorotoluene [ ] neat 1 1mL ML 1,2-Dibromo-3-chloropropane [ ] neat 1 1mL ML Dibromomethane [ ] neat 1 1mL ML 1,4-Dichlorobutane [ ] neat 1 1mL ML 1,2-Dibromoethane, in Certan bottle [ ] neat 1 1mL ML 1,1-Dichloroethane [ ] neat 1 1mL ML 1,2-Dichloroethane, in Certan bottle [ ] neat 1 1mL ML 1,1-Dichloroethylene, in Certan bottle Vinylidene chloride [ ] neat 1 1mL ML cis-1,2-dichloroethene [ ] neat 1 1mL ML trans-1,2-dichloroethene [ ] neat 1 1mL ML Dichlorodifluoromethane [ ] neat 1 1mL ML Dichloromethane, in Certan bottle [ ] neat 1 1ml ML 1,2-Dichloropropane [ ] neat 1 1mL ML 1,3-Dichloropropane [ ] neat 1 1mL ML 2,2-Dichloropropane [ ] neat 1 1mL ML 1,1-Dichloropropene [ ] neat 1 1mL ML cis-1,3-dichloropropene [ ] neat 1 1mL ML trans-1,3-dichloropropene [ ] neat 1 1mL ML 1,4-Fluoropropane [ ] neat 1 1mL K-I exachloro-1,3-butadiene [ ] 1000µg/mL isooctane 1 1mL K-T ydrogensulfide [ ] 2000µg/mL toluene 1 1mL mL Monobromomethane [ ] neat 1 1mL ML Monochlorobenzene-d [ ] neat 1 1mL ML Monochloroethane [ ] neat 1 1mL Monochloromethane [ ] Please inquire, sylinder ML Tetrachloromethane [ neat 1 1mL ML Tetrachloroethylene, in Certan bottle [ ] neat 1 1mL ML 1,1,1,2-Tetrachloroethane [ ] neat 1 1mL ML 1,1,2,2-Tetrabromoethane [ ] neat 1 1mL Compounds 365

368 ML 1,1,2-Trichloroethane [ ] neat 1 1mL ML Trichloroethylene, in Certan bottle [ ] neat 1 1mL ML 1,1,1-Trichloroethane, in Certan bottle [ ] neat 1 1mL ML Trichlorofluoromethane [ ] neat 1 1mL ML 1,2,3-Trichloropropane [ ] neat 1 1mL K-ME Vinyl chloride [ ] 2000µg/mL methanol 1 1mL Phosphates (ydraulic fluids) Trimethyl phosphate [ ] MW Tolyldiphenyl phosphate [ ] K-I 3 C P C 3 C µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Tri-o-tolyl phosphate [ ] MW C Triethyl phosphate [ ] MW C 3 P C K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Tri-n-propyl phosphate [ ] MW Tri-m-tolyl phosphate [ ] MW K-I 1000µg/mL isooctane, 1x1mL P C 3 3 C Tri-n-butyl phosphate [ ] MW K-I C µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Triisobutyl phosphate [ ] MW Tri-p-tolyl phosphate [ ] MW C P C K-I 1000µg/mL isooctane, 1x1mL Triphenyl phosphate [ ] MW K-I C µg/mL isooctane, 1x1mL P K-I 1000µg/mL isooctane, 1x1mL 366

369 Tritolyl phosphate (isomer mix) [ ] MW P Phosphate Kit KIT Kit K-I 1000µg/mL isooctane, 1x1mL Pesticides Isotope labelled pesticides Acetochlor-d11 (2-ethyl-6-methylphenyl-d11) [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL I Alachlor -d13 (2,6-diethylphenyl-d13) [ ] 100µg/mL isooctane 1 1mL I Atrazine-d5 (ethyl-d5) [ ] 100µg/mL isooctane 1 1mL I Carbaryl-d7 (naphtyl-d7) [ ] 100µg/mL isooctane 1 1mL I Carbofuran-d3 (N-methyl-d3) µg/mL isooctane 1 1mL I 4-Chloro-2-methylphenoxy-d3- acetic Acid MCPA [ ] 100µg/mL isooctane 1 1mL I 2-(4-Chloro-2-methylphenoxy-d3) propionic acid Mecoprop [ ] 100µg/mL isooctane 1 1mL I Chlorpyriphos-d10 (,-diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I Cyanazine-d5 (N-ethyl-d5) µg/mL isooctane 1 1mL I Desethylterbuthylazine-d9 (tert-butyl-d9) µg/mL isooctane 1 1mL I Desisopropylatrazine-d5 (ethyl-d5) µg/mL isooctane 1 1mL I Diazinon-d10 (diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I 3,5-Dibromo-4- hydroxybenzonitrile-2,6-d2 Bromoxynil [ ] 100µg/mL isooctane 1 1mL I 1,1-Dichloro-2,2-bis (4-Chlorophenyl-d4)ethane 4,4 -DDD [ ] 100µg/mL isooctane 1 1mL I 1,1-Dichloro-2,2-bis (4-Chlorophenyl-d4)ethylene 4,4 -DDE [ ] 100µg/mL isooctane 1 1mL I 3,6-Dichloro-2-methoxy-d3- benzoic Acid Dicamba [ ] 100µg/mL isooctane 1 1mL I 2,4-Dichlorophenoxy-3,5,6-d3- acetic Acid 2,4-D [ ] 100µg/mL isooctane 1 1mL I 2,4-Dichlorophenoxy-3,5,6-d3- acetic-d2 Acid 2,4-D [ ] 100µg/mL isooctane 1 1mL I 4-(2,4-Dichlorophenoxy-3,5,6-d3) butyric Acid 2,4-DB µg/mL isooctane 1 1mL I Dichlorvos-d6 (dimethyl-d6) [ ] 100µg/mL isooctane 1 1mL I Diflufenican-d3 (3-trifluoromethylphenoxy-2,4,6-d3) µg/mL isooctane 1 1mL I Dimethoate-d6 (,-dimethyl-d6) µg/mL isooctane 1 1mL I Dimethyl-d6 tetrachloroterephthalate Dacthal [ ] 100µg/mL isooctane 1 1mL I Diquat dibromide-d [ ] 100µg/mL isooctane 1 1mL I Diuron-d6 (dimethyl-d6) µg/mL isooctane 1 1mL I Endosulfan-I-d [ ] 100µg/mL isooctane 1 1mL I Endosulfan-II-d [ ] 100µg/mL isooctane 1 1mL I EPTC-d14 (dipropyl-d14) [ ] 100µg/mL isooctane 1 1mL I Ethyl viologen-d8 dichloride (rings-d8) µg/mL isooctane 1 1mL I Fenitrooxon-d6 (,-dimethyl-d6) µg/mL isooctane 1 1mL I Fenitrothion-d6 (,-dimethyl-d6) [ ] 100µg/mL isooctane 1 1mL 367 Compounds

370 I Fenthion-d6 (,-dimethyl-d6) µg/mL isooctane 1 1mL I a-1,2,3,4,5,6-exachlorocyclohexane-d [ ] 100µg/mL isooctane 1 1mL I gamma-1,2,3,4,5,6- exachlorocyclohexane-d6 Lindane [ ] 100µg/mL isooctane 1 1mL I Iprodione-d3(3,5-dichlorophenyl-2,4,6-d3) µg/mL isooctane 1 1mL I Isoproturon-d3 (N-methyl-d3) [ ] 100µg/mL isooctane 1 1mL I Linuron-d6 (dimethyl-d6) µg/mL isooctane 1 1mL I Malathion-d6 (dimethyl-d6) µg/mL isooctane 1 1mL I Malathion-d7 (dimethyl-d6;3-d1) µg/mL isooctane 1 1mL I Malathion-d10 (diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I Methamidophos-d6 (dimethyl-d6) µg/mL isooctane 1 1mL I Methyl 2,4-dichlorophenoxy- 3,5,6-d3-acetate 2,4-D methyl ester [ ] 100µg/mL isooctane 1 1mL I Methyl parathion-d6 (dimethyl-d6) [ ] 100µg/mL isooctane 1 1mL I Methyl viologen-d8 dichloride (rings-d8) Paraquat Dichloride [ ] 100µg/mL isooctane 1 1mL I Metolachlor-d6 (propyl-d6) µg/mL isooctane 1 1mL I Parathion-d10 (diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I Pendimethalin-d5 [N-(1-ethyl-1`,1`-d2;propyl-1,2,2-d3)] µg/mL isooctane 1 1mL I Phorate-d10 (,-diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I Propazine-d14 (di-iso-propyl-d14) µg/mL isooctane 1 1mL I Propoxur-d3 (N-methyl-d3) µg/mL isooctane 1 1mL I Propyzamide-d3 (phenyl-2,4,6-d3) µg/mL isooctane 1 1mL I Simazine-d10 (diethyl-d10) [ ] 100µg/mL isooctane 1 1mL I Temephos-d12 (,,, -tetramethyl-d12) µg/mL isooctane 1 1mL I Terbuthylazine-d5 (ethyl-d5) [ ] 100µg/mL isooctane 1 1mL I Thiobencarb-d10 (diethyl-d10) µg/mL isooctane 1 1mL I 1,1,1-Trichloro-2,2-bis (4-chlorophenyl-d4)ethane 4,4 -DDT [ ] 100µg/mL isooctane 1 1mL I 1,1,1-Trichloro-2(2-chlorophenyl-d4)- 2-(4-chlorophenyl-d4)ethane 2,4 -DDT [ ] 100µg/mL isooctane 1 1mL I 2,4,5-Trichlorophenoxy-3,6- d2-acetic-d2 Acid 2,4,5-T [ ] 100µg/mL isooctane 1 1mL I Trifluralin-d14 (di-n-propyl-d14) [ ] 100µg/mL isooctane 1 1mL Pesticides (native) Acephate rthene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Aclonifen [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Alachlor Lasso [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Aldicarb [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Aldicarb sulfone Temic [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Aldicarb sulfoxide [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Aldrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Allethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ametryne [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Anilazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Atrazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Atrazine-desethyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Atrazine-desisopropyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Azinphos methyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Azinphos-methyl-oxon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Benfluralin Balan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Bentazone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Benthiocarb Thiobencarb [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL BC: See C Bifenox Modown [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Bifenthrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Bromacil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Bromoxynil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Cadusafos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Captafol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL 368

371 Captan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Carbaryl Sevin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Carbofuran [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Carbofuran-3-hydroxy [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-ME Chlordane [ ] 2000µg/mL methanol 1 1mL Chlordane [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlordane, cis-alpha [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlordane, oxy [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlordane, trans-gamma [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorfenson [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorfenvinphos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlormephos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorobenzilate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorobenzyl mercaptan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorothalonil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chloroxuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorpropham [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorpyrifos Dursban,ethyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Chlorpyrifos-methyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Clopyralid [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Coumaphos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Crimidine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Cyanazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL beta-cyfluthrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL beta-cypermethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Cypermethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Cyproconazole [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4-D [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4-D methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4-DB [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4-DB methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDD (=TDE) o,p -DDD [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDD (=TDE) p,p -DDD [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDE o,p -DDE [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDE p,p -DDE [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDT o,p -DDT [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4 -DDT p,p -DDT [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I 4,4 -DDT p,p -DDT [ ] 1000µg/mL isooctane 1 1mL Deltamethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Demeton S Systox [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diazinon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dicamba [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlobenil Casaron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlofenthion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlofluanid [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichloran Botran [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlorprop [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlorprop methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dichlorvos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diclobenil 2,6-Dichlorobenzonitrile [ ] 100µg/mL c.hexane or ac.nitrile 1 10mL Dicofol Kaltane [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dicrotophos Didrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dieldrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diflufenican [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dimethoate Cygon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dinoseb 2-sec-Butyl-4,6-dinitrophenol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I Dinoseb 2-sec-Butyl-4,6-dinitrophenol [ ] 1000µg/mL isooctane 1 1mL K-IP Dinoseb 2-sec-Butyl-4,6-dinitrophenol [ ] 1000µg/mL isopropanol 1 1mL Compounds 369

372 Dinoterb 2-tert-Butyl-4,6-dinitrophenol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Dioxathion Delnav [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diphenylamine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diquat Dibromide monohydrate Naled [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Disulfoton Disyston [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Diuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I Diuron [ ] 1000µg/mL isooctane 1 1mL Endosulfan Thiodan I [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL alpha-endosulfan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL beta-endosulfan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Endosulfan alcohol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Endosulfan sulfate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Endrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I Endrin [ ] 1000µg/mL isooctane 1 1mL EPN [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Epoxiconazole [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Esfenvalerate Asana [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ethalfluralin Sonalan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ethion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ethoprop Mocap,Ethoprophos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL IP Etinofen 2-Ethoxymethyl-4,6-dinitrophenol [ ] 100µg/mL isopropanol 1 1mL K-IP Etinofen 2-Ethoxymethyl-4,6-dinitrophenol [ ] 1000µg/mL isopropanol 1 1mL Fenamiphos sulfoxide Nemacur [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenitrothion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenoprop [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenoprop methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenpropathrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenson [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenthion Baytex [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fenvalerate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ferbam [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fluazifop [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fluometuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Flurochloridone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL tau-fluvalinate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Folpet [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Fonofos Dyfonate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL aloxyfop [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL alpha-c (BC) Benzahex [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL beta-c (BC) [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL gamma-c (BC) Lindane [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL AN gamma-c Lindane [ ] 10 ug/ml acetonitrile 1 10mL delta-c (BC) [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL epsilon-c (BC), (100ug/ml in toluene) [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL eptachlor [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL eptachlor-endo-epoxide (trans-) isomer A [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL eptachlor-exo-epoxide (cis-) isomer B [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL exachlorobenzene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL I exachlorophene [ ] 50µg/mL isooctane 1 1mL exazinone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Imazalil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ioxynil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Iprodione Rovral [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Isobenzan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL 370

373 Isodrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Isofenphos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Isofenphos-des-N-isopropyl ftanol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Isoproturon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Lindane: see gamma-c [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I Lindane see gamma-c [ ] 1000µg/mL isooctane 1 1mL Imidan Phosmet [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Linuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Malathion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-I Malathion [ ] 1000µg/mL isooctane 1 1mL Mancozeb [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Maneb Dithane M [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL MCPA [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL MCPA-methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL MCPB [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL MCPB-methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Mecoprop [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Mecoprop methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metalaxyl Ridomyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metamitron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metazachlor [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methabenzthiazuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methacrifos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methamidophos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methidathion Supracide [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methiocarb Mesurol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL DL-Methionine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methomyl Lannate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methoxychlor [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL o,p -Methoxychlor [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Methyl parathion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metiram [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metobromuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metolachlor Dual [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metoxuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Metribuzin Sencor [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL cis-mevinphos Phosdrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Mirex [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Molinate rdram [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Monolinuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Monuron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Myclobutanil Rally [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Nabam [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Naled Dibrom [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL K-IP 1-Naphthol [ ] 1000µg/mL isopropanaol 1 1mL Nitrofen TK [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL xadiazon-hydroxy Ronstar µg/mL c.hexane or ac.nitrile 1 1mL xamyl Vydate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL xyfluorfen Goal [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Parathion Parathion-ethyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Parathion methyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pendimethalin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pentachloroaniline [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pentachlorobenzene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pentachloronitrobenzene Quintozene, PCNB [ ] 100ug/ml acetonitrile 1 1mL Permethrin Ambush [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Perthane Ethylan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL d-(cis-trans)-phenothrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL o-phenylphenol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Phorate Thimet [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Phorate-oxon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Phosalone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL 371 Compounds

374 Phosphamidon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Picloram [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pirimicarb [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Pirimiphos-methyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Prochloraz [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Procymidone [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Profenofos Curacron [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Profluralin Tolban [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Prometryne [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propetamphos Safrotin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propham [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propiconazole [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propoxur Baygon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Propyzamide [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Quintozene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Resmethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Ronnel Fenchlorphos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Sebuthylazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Simazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4,5-T [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,4,5-T-methyl ester [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tebuconazole [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tecnazene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Terbacil [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Terbuthylazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Terbuthylazine-desethyl [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Terbutryne [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,2,4,5-Tetrachlorobenzene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tetrachlorvinphos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tetradifon Tedion [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tetramethrin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Tetrasul [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Thiabendazole [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Thionazin--analog Zinophos [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Thiram [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Toxaphene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL MG Toxaphene [ ] neat 1 100mg Triadimefon [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Triadimenol [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL ,2,4-Trichlorobenzene [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Trichloronate [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Triclopyr [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Trietazine [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Trifluralin [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL I Tris-(aziridinyl)- phosphineoxide TEPA [ ] 100µg/mL isooctane 1 1mL K-I Tris-(aziridinyl)- phosphineoxide TEPA [ ] 1000µg/mL isooctane 1 1mL MG Tris-(aziridinyl)- phosphineoxide TEPA [ ] neat 1 10mg MG Tris-(aziridinyl)- phosphineoxide TEPA [ ] neat 1 100mg G Tris-(aziridinyl)- phosphineoxide TEPA [ ] neat 1 1g Vinclozolin Ronilan [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL Zineb [ ] 100µg/mL c.hexane or ac.nitrile 1 1mL 372

375 Surfactants and phenols Phenolethoxylates Internal standards Deuterated and 13C labelled ethoxylates: Please inquire I 4-n-ctylphenol-d µg/mL isooctane 1 1mL K-5IP 4-n-Nonylphenol-2,3,5,6-d4-D [ ] 1000µg/mL isopropanol 5 5mL K-5AC 4-n-Nonylphenol-2,3,5,6-d4-D [ ] 1000µg/mL acetone 5 5mL 4-n-ctylphenol ethoxylates K-I 4-n-ctylphenol [ ] 1000µg/mL isooctane 1 1mL K-I Ethylene glycol mono (p-n-octylphenyl)ether 4-n-ctylphenol E [ ] 1000µg/mL isooctane 1 1mL K-I Diethylene glycol mono (p-n-octylphenyl)ether 4-n-ctylphenol 2E [ ] 1000µg/mL isooctane 1 1mL K-I Triethylene glycol mono (p-n-octylphenyl)ether [ ] 1000µg/mL isooctane 1 1mL K-I Tetraethylene glycol mono (p-n-octylphenyl)ether [ ] 1000µg/mL isooctane 1 1mL KIT n-ctylphenol E Kit (Not including ) Kit 4-tert-ctylphenol ethoxylates K-I 4-tert-ctylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 4-tert-ctylphenol E, Please inquire [ ] 1000µg/mL isooctane 1 1mL K-I 4-tert-ctylphenol 2E, Please inquire [ ] 1000µg/mL isooctane 1 1mL K-I 4-tert-ctylphenol 3E, Please inquire [ ] 1000µg/mL isooctane 1 1mL Nonylphenol ethoxylates (nonylisomer mixtures) K-I 4-Nonylphenol, mixture of nonyl isomers [ ] 1000µg/mL isooctane 1 1mL K-I Ethylene glycol mono(p-nonylphenyl) ether p-nonylphenol E [ ] 1000µg/mL isooctane 1 1mL K-I Diethylene glycol mono(p-nonylphenyl) ether p-nonylphenol 2E [ ] 1000µg/mL isooctane 1 1mL K-I Triethylene glycol mono(p-nonylphenyl) ether isomer mix p-nonylphenol 3E [ ] 1000µg/mL Isooctane 1 1mL K-I Tetraethylene glycol mono(p-nonylphenyl) ether isomer mix p-nonylphenol 4-E [ ] 1000µg/mL Isooctane 1 1mL KIT Nonylphenol E Kit Kit 4-n-Nonylphenol ethoxylates K-I 4-n-Nonylphenol [ ] 1000µg/mL isooctane 1 1mL K-I Ethylene glycol mono(p-n-nonylphenyl) ether p-n-nonylphenol E µg/mL Isooctane 1 1mL K-I Diethylene glycol mono(p-nonylphenyl) ether p-n-nonylphenol 2E [ ] 1000µg/mL Isooctane 1 1mL KIT n-nonylphenol ethoxylates Kit Kit K-I 2-(4-Nonylphenoxy)acetic acid isomer mixture [ ] 1000µg/mL Isooctane 1 1mL S MG Imbentin-N/020 (n=0-4) neat 1 100mg S MG Imbentin-N/040 (n=1-7) neat 1 100mg S MG Imbentin-N/040 (n=2-9) neat 1 100mg KIT Imbentin Kit Kit Compounds 373

376 Phenols F-Phenol internal standards K-IP 2-Fluorophenol [ ] 1000µg/mL isopropanol 1 1mL G 2-Fluorophenol [ ] neat 1 1g K-IP 4-Fluoro-2-methylphenol [ ] 1000µg/mL isopropanol 1 1mL G 4-Fluoro-2-methylphenol [ ] neat 1 1g K-IP 4-Fluoro-3-methylphenol [ ] 1000µg/mL isopropanol 1 1mL G 4-Fluoro-3-methylphenol [ ] neat 1 1g Deuterated phenols K-IP Bisphenol-A-2,2,6,6 -d [ ] 1000µg/mL isopropanol 5 1mL K-IP Bisphenol-A-3,3,5,5 -d [ ] 1000µg/mL isopropanol 5 1mL K-IP Bisphenol-A-d [ ] 1000µg/mL isopropanol 5 1mL K-IP Bisphenol-A-2,2,3,3,5,5,6,6 -d [ ] 1000µg/mL isopropanol 5 1mL K-IP Bisphenol-A-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-Bromophenol-2,3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-n-Butylphenol-2,3,5,6-d4, D µg/mL isopropanol 5 1mL K-IP 4-tert-Butyl-d9-phenol-2,3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2-Chlorophenol-3,4,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-Chlorophenol-2,3,5,6-d4, D [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-Chloro-3-methylphenol-2,6-d [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Chloro-2-methylphenol-3,5,6-d [ ] 1000µg/mL isopropanol 1 1mL K-IP o-cresol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP m-cresol-d [ ] 1000µg/mL isopropanol 5 1mL K-T p-cresol-d [ ] 1000µg/mL toluene 5 1mL ,4-Dibromophenol-3,5,6-d Please inquire K-IP 2,6-Di-(tert-butyl-1-d1)- 4-methyl-d3-phenol-3,5-d µg/mL isopropanol 5 1mL K-IP 2,6-Di-(tert-butyl-d9)- 4-methylphenol-3,5-d2, D [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,6-Di-tert-butyl-4-methylphenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4-Dichlorophenol-3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4-Dimethylphenol-3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,6-Dimethylphenol-3,5,6-d3, D [ ] 1000µg/mL isopropanol 5 1mL K-IP 3,4-Dimethylphenol-2,5,6-d3, D [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4-Dimethylphenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4-Dinitrophenol-3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-I 4-Ethylphenol-2,3,5,6-d4, D [ ] 1000µg/mL Isooctane 5 1mL K-IP 4-Ethylphenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2-Isopropylphenol-d µg/mL isopropanol 5 1mL K-IP 3-Isopropylphenol-d µg/mL isopropanol 5 1mL K-IP 4-Isopropylphenol-d µg/mL isopropanol 5 1mL K-IP 2-Nitrophenol-3,4,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-Nitrophenol-2,3,5,6-d [ ] 1000µg/mL isopropanol 5 1mL K-5IP 4-n-Nonylphenol-2,3,5,6-d4, D [ ] 1000µg/mL isopropanol 5 5mL K-5AC 4-n-Nonylphenol-2,3,5,6-d4, D [ ] 1000µg/mL acetone 5 5mL I 4-n-ctylphenol-d µg/mL isooctane 1 1mL K-IP 4-n-Pentylphenol-d µg/mL isopropanol 5 1mL K-IP Phenol, D [ ] 1000µg/mL isopropanol 5 1mL K-IP Phenol-3,5-d [ ] 1000µg/mL isopropanol 5 1mL K-IP Phenol-2,4,6-d3, D [ ] 1000µg/mL isopropanol 5 1mL K-T Phenol-2,3,4,5,6-d [ ] 1000µg/mL toluene 5 1mL K-IP Phenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 4-n-Propylphenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4,6-Tribromophenol-3,5-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,3,6-Trichlorophenol-4,5-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4,5-Trichlorophenol-3,6-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4,6-Trichlorophenol-3,5-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,3,5-Trimethylphenol-d [ ] 1000µg/mL isopropanol 5 1mL 374

377 K-IP 2,3,6-Trimethylphenol-d [ ] 1000µg/mL isopropanol 5 1mL K-IP 2,4,6-Trimethylphenol-d [ ] 1000µg/mL isopropanol 5 1mL C0-C1 Phenols K-W Phenol [ ] 1000µg/mL water 1 1mL G Phenol [ ] neat 1 1g G o-cresol [ ] neat 1 1g G m-cresol [ ] neat 1 1g G p-cresol [ ] neat 1 1g KIT Phenol C0-C1 Kit (neat) Kit C2 Phenols G 2,3-Dimethylphenol [ ] neat 1 1g G 2,4-Dimethylphenol [ ] neat 1 1g G 2,5-Dimethylphenol [ ] neat 1 1g G 2,6-Dimethylphenol [ ] neat 1 1g G 3,4-Dimethylphenol [ ] neat 1 1g G 3,5-Dimethylphenol [ ] neat 1 1g G 2-Ethylphenol [ ] neat 1 1g G 3-Ethylphenol [ ] neat 1 1g G 4-Ethylphenol [ ] neat 1 1g KIT Phenol C2 Kit Kit C3 Phenols G 2,3,5-Trimethylphenol [ ] neat 1 1g G 2,3,6-Trimethylphenol [ ] neat 1 1g G 2,4,6-Trimethylphenol Mesitol [ ] neat 1 1g MG 3,4,5-Trimethylphenol [ ] neat 1 250mg K-I 3-Ethyl-5-methylphenol [ ] 1000µg/mL isooctane 1 1mL G 2-Isopropylphenol [ ] neat 1 1g MG 3-Isopropylphenol [ ] neat 1 250mg G 4-Isopropylphenol [ ] neat 1 1g G 2-n-Propylphenol [ ] neat 1 1g G 3-n-Propylphenol [ ] neat 1 1g G 4-n-Propylphenol [ ] neat 1 1g KIT Phenol C3 Kit Kit C4 Phenols G 4-n-Butylphenol [ ] neat 1 1g G 2-sec-Butylphenol [ ] neat 1 1g G 4-sec-Butylphenol [ ] neat 1 1g G 2-tert-Butylphenol [ ] neat 1 1g G 3-tert-Butylphenol [ ] neat 1 1g G 4-tert-Butylphenol [ ] neat 1 1g G 2-Isopropyl-5-methylphenol Thymol [ ] neat 1 1g G 4-Isopropyl-3-methylphenol [ ] neat 1 1g MG 5-Isopropyl-2-methylphenol Carvacrol [ ] neat 1 250mg G 5-Isopropyl-3-methylphenol [ ] neat 1 1g KIT Phenol C4 Kit Kit Compounds C5 Phenols MG 4-n-Pentylphenol [ ] neat 1 250mg K-I 2-(1-Methylbutyl)phenol [ ] 1000µg/mL isooctane 1 1mL K-I 4-Isopentylphenol [ ] 1000µg/mL isooctane 1 1mL G 4-tert-Amylphenol [ ] neat 1 1g G 2-tert-Butyl-4-methylphenol [ ] neat 1 1g G 2-tert-Butyl-5-methylphenol [ ] neat 1 1g 375

378 G 2-tert-Butyl-6-methylphenol [ ] neat 1 1g G 4-tert-Butyl-2-methylphenol [ ] neat 1 1g K-I 5-tert-Butyl-2-methylphenol [ ] 1000µg/mL isooctane 1 1mL KIT Phenol C5 Kit Kit C6 Phenols G 2-Phenylphenol [ ] neat 1 1g G 3-Phenylphenol [ ] neat 1 1g G 4-Phenylphenol [ ] neat 1 1g G 2-/4-Cyclohexylphenol [ ] neat 1 1g G 4-Cyclohexylphenol [ ] neat 1 1g K-I 2,4-Diisopropylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 2,5-Diisopropylphenol [ ] 1000µg/mL isooctane 1 1mL MG 2,6-Diisopropylphenol [ ] neat 1 250mg G 2-tert-Butyl-4,6-dimethylphenol [ ] neat 1 1g G 2-tert-Butyl-4-ethylphenol [ ] neat 1 1g G 4-n-exylphenol [ ] neat 1 1g KIT Phenol C6 Kit Kit C7 Phenols G 2-Benzylphenol [ ] neat 1 1g G 4-Benzylphenol [ ] neat 1 1g MG 2-Cyclohexyl-5-methylphenol [ ] neat 1 250mg 3 C K-I 2-Methyl-4-tert-hexylphenol [ ] 1000µg/mL isooctane 1 1mL G 4-n-eptylphenol [ ] neat 1 1g KIT Phenol C7 Kit Kit C8 Phenols K-IP 2-Benzyl-4-methylphenol [ ] 1000µg/mL isopropanol 1 1mL K-I 2,4-Di-sec-butylphenol [ ] 1000µg/mL isooctane 1 1mL G 2,6-Di-sec-butylphenol [ ] neat 1 1g G 2,4-Di-tert-butylphenol [ ] neat 1 1g G 2,6-Di-tert-butylphenol [ ] neat 1 1g G 3,5-Di-tert-butylphenol [ ] neat 1 1g G 4-n-ctylphenol [ ] neat 1 1g G 4-tert-ctylphenol [ ] neat 1 1g KIT Phenol C8 Kit Kit C9 Phenols K-I 2,6-Di-tert-butyl-4-methylphenol (2,6-Bis(1,1-dimethylethyl)-4-methylphenol) [ ] 1000µg/mL isooctane 1 1mL K-I 4,6-Di-tert-butyl-2-methylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 2-Methyl-4-tert-octylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Nonylphenol [ ] 5000µg/mL isooctane 1 1mL K-I 4-Nonylphenol, mixture of isomers [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Nonylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 4-Nonylphenol, mixture of isomers, Type B [ ] 1000µg/mL isooctane 1 1mL KIT Phenol C9 Kit Kit 376

379 C10+ Phenols G 4-tert-Butyl-2-phenylphenol [ ] neat 1 1g MG 2,4-Bis(1-methylbutyl)phenol [ ] neat 1 250mg K-I 2,4-Dimethyl-6-isooctylphenol [ ] 1000µg/mL isooctane 1 1mL G 2,4-Di-tert-pentylphenol [ ] neat 1 1g G 2,6-Di-tert-butyl-4-ethylphenol [ ] neat 1 1g MG 4-tert-Butyl-2,6-diisopropylphenol [ ] neat 1 100mg K-I 2-n-Dodecylphenol [ ] 1000µg/mL isooctane 1 1mL K-I 2-n-Dodecyl-p-cresol [ ] 1000µg/mL isooctane 1 1mL K-I 4-n-Dodecyl-o-cresol [ ] 1000µg/mL isooctane 1 1mL KIT Phenol C10 Kit Kit Compounds 377

380 ther phenols Acetosyringone [ ] MW Methylguaiacol [ ] MW C 3 C 3 C3 3 C C K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Bisphenol A [ ] MW C 3 C Syringaldehyde [ ] MW C C K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Catechol [ ] MW Totarol [ ] MW K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Ethylguaiacol [ ] MW Vanillin [ ] MW C3 C 3 C K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Guaiacol [ ] MW ther Phenols kit KIT Kit C K-I 1000µg/mL isooctane, 1x1mL 378

381 Anisols K-IP 2,6-Dibromoanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dichloro-6-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dichloro-4-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dimethyl-4-anisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dinitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,5-Dinitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dinitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dinitro-6-methylanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Methyl-2-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Methyl-4-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Methyl-2-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 5-Methyl-2-nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2-Nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Nitroanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,6-Tribromoanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3,6-Trichloroanisole [ ] 1000µg/mL isopropanol 1 1mL KIT Anisol Kit Kit F Phenol PFB (perfluorobenzoyl) derivatives R F 1 2 F F F K-IP 2,4-Dibromophenol-PFB µg/mL isopropanol 1 1mL K-IP 2,4-Dibromophenol-PFB µg/mL isopropanol 5 1mL K-5IP 2,4-Dibromophenol-PFB µg/mL isopropanol 1 5mL K-IP 2,5-Dibromophenol-PFB µg/mL isopropanol 1 1mL K-IP 4-Ethylphenol-d4-PFB [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Ethylphenol-d9-PFB µg/mL isopropanol 1 1mL K-IP 2-Fluorophenol-PFB µg/mL isopropanol 1 1mL K-IP 4-Fluoro-2-methylphenol-PFB µg/mL isopropanol 1 1mL K-IP 4-Fluoro-3-methylphenol-PFB µg/mL isopropanol 1 1mL K-IP 2,4,6-Tribromophenol-PFB µg/mL isopropanol 1 1mL K-5IP 2,4,6-Tribromophenol-PFB µg/mL isopropanol 1 5mL KIT Phenol PFB derivative Kit Kit Nitrophenols K-IP 2-Amino-5-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-I 2-sec-Butyl-4,6-dinitrophenol Dinoseb [ ] 1000µg/mL isooctane 1 1mL tert-Butyl-4,6-dinitrophenol Dinoterb [ ] 100µg/mL c.hexane or 1 1mL ac.nitrile K-IP 2-Cyclohexyl-4,6-dinitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dichloro-6-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dichloro-4-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dimethyl-4-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4,6-Dinitro-2-methylphenol (2-Methyl-4,6-dinitrophenol) 4,6-Dinitro-o-cresol [ ] 1000µg/mL isopropanol 1 1mL K-T 2,4-Dinitrophenol [ ] 1000µg/mL toluene 1 1mL K-IP 2,5-Dinitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dinitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2-Ethoxymethyl-4,6-dinitrophenol Etinofen [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Methyl-2-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Methyl-4-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Methyl-2-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 5-Methyl-2-nitrophenol [ ] 1000µg/mL isopropanol 1 1mL K-T 2-Nitrophenol [ ] 1000µg/mL toluene 1 1mL K-T 3-Nitrophenol [ ] 1000µg/mL toluene 1 1mL K-ME 4-Nitrophenol [ ] 1000µg/mL methanol 1 1mL KIT Nitrophenol Kit Kit 379 Compounds

382 Aminophenols K-ME 4-Aminophenol [ ] 1000µg/mL methanol 1 1mL MG 4-Aminophenol [ ] neat 1 500mg Chlorophenols Monochlorophenols K-IP 2-Chlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 3-Chlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Chlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2-Chloro-5-methylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Chloro-2-methylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Chloro-3-methylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2-Chloro-4-tert-butylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 6-Chloro-5-methyl-2-(1-methylethyl)phenol [ ] 1000µg/mL isopropanol 1 1mL Cl K-IP 2-Cyclopentyl-4-chlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Chloro-2-benzylphenol [ ] 1000µg/mL isopropanol 1 1mL KIT Monochlorophenol Kit Kit Dichlorophenols K-IP 2,3-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,5-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 3,4-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 3,5-Dichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dichloro-6-methylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dichloro-3,5-dimethylphenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,5-Dichloro-4-tert-butylphenol [ ] 1000µg/mL isopropanol 1 1mL KIT Dichlorophenol Kit Kit Trichlorophenols K-IP 2,3,4-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3,5-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3,6-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,5-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,6-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 3,4,5-Trichlorophenol [ ] 1000µg/mL isopropanol 1 1mL KIT Trichlorophenol Kit Kit Tetra-/ Pentachlorophenols K-IP 2,3,4,5-Tetrachlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-I 2,3,4,6-Tetrachlorophenol [ ] 1000µg/mL isooctane 1 1mL K-IP 2,3,5,6-Tetrachlorophenol [ ] 1000µg/mL isopropanol 1 1mL K-I Pentachlorophenol [ ] 1000µg/mL isooctane 1 1mL K-IP Pentachlorophenol [ ] 1000µg/mL isopropanol 1 1mL KIT Tetra/, Pentachlorophenol Kit Kit 380

383 Bromophenols K-IP 2-Bromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 4-Bromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3-Dibromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dibromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,5-Dibromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dibromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3,4-Tribromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,3,6-Tribromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,5-Tribromophenol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,6-Tribromophenol [ ] 1000µg/mL isopropanol 1 1mL K-5IP 2,4,6-Tribromophenol [ ] 5000µg/mL isopropanol 1 5mL K-IP 2,3,4,6-Tetrabromophenol [ ] 1000µg/mL isopropanol 1 1mL I Pentabromophenol [ ] 50µg/mL isooctane 1 1mL KIT Bromophenol Kit Kit Bromoanisols K-IP 3-Bromoanisol [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4-Dibromoanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,6-Dibromoanisole [ ] 1000µg/mL isopropanol 1 1mL K-IP 2,4,6-Tribromoanisole [ ] 1000µg/mL isopropanol 1 1mL KIT Bromoanisol Kit Kit Phthalates and adipates Deuterated phthalates I Dimethyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 1 1mL I Dimethyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 5 1mL K-I Diethyl phthalate-3,4,5,6-d [ ] 1000µg/mL isooctane 1 1mL I Di-iso-butyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 5 1mL I Di-n-butyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 1 1mL I Di-n-butyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 5 1mL I Di-n-pentyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 1 1mL K-I Di-n-pentyl phthalate-3,4,5,6-d [ ] 1000µg/mL isooctane 1 1mL I Benzyl-n-butyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 5 1mL I Di-n-octyl phthalate-3,4,5,6-d [ ] 100µg/mL isooctane 5 1mL K-I Bis(2-ethylhexyl) phthalate-3,4,5,6-d [ ] 1000µg/mL isooctane 1 1mL Phthalates Monoalkylphthalates (metabolites) K-I Monomethyl phthalate [ ] 1000µg/mL isooctane 1 1mL K-I Monoethyl phthalate [ ] Please inquire K-I Monobutyl phthalate [ ] 1000µg/mL isooctane 1 1mL K-I Monobenzylphthalate [ ] 1000µg/mL isooctane 1 1mL K-I Mono-n-hexyl phthalate [ ] 1000µg/mL isooctane 1 1mL K-I Mono(2-ethylhexyl) phthalate [ ] 1000µg/mL isooctane 1 1mL KIT Monoalkyl phthalate Kit Kit Compounds Dialkyl phthalates MG Dimethyl phthalate [ ] neat 1 10mg MG Dimethyl phthalate [ ] neat 1 100mg MG Diethyl phthalate [ ] neat 1 10mg N Di-iso-butyl phthalate [ ] 100mg/mL nonane 1 1mL MG Di-iso-butyl phthalate [ ] neat 1 10mg 381

384 MG Di-iso-butyl phthalate [ ] neat 1 100mg MG Di-n-butyl phthalate [ ] neat 1 10mg MG Di-n-butyl phthalate [ ] neat 1 100mg MG Di(2-methoxyethyl) phthalate [ ] neat 1 10mg MG Di(2-methoxyethyl) phthalate [ ] neat 1 100mg MG Diamyl phthalate Di-n-pentylphthalate [ ] neat 1 10mg MG Diamyl phthalate Di-n-pentylphthalate [ ] neat 1 100mg MG Di(2-ethoxyethyl) phthalate [ ] neat 1 10mg MG Di(2-ethoxyethyl) phthalate [ ] neat 1 100mg MG Butylbenzyl phthalate [ ] neat 1 10mg X Diphenyl isophthalate [ ] 100µg/mL hexane 1 1mL X Diphenyl phthalate [ ] 100µg/mL hexane 1 1mL MG Dicyclohexyl phthalate [ ] neat 1 10mg MG Dicyclohexyl phthalate [ ] neat 1 100mg MG Di(4-methyl-2-pentyl) phthalate [ ] neat 1 10mg MG Di(4-methyl-2-pentyl) phthalate [ ] neat 1 100mg MG Di-n-hexyl phthalate [ ] neat 1 10mg MG Di-n-hexyl phthalate [ ] neat 1 100mg X Dibenzyl phthalate [ ] 100µg/mL hexane 1 1mL MG exyl 2-ethylhexyl phthalate [ ] neat 1 10mg MG exyl 2-ethylhexyl phthalate [ ] neat 1 100mg MG Di(2-n-butoxyethyl) phthalate [ ] neat 1 10mg MG Di(2-n-butoxyethyl) phthalate [ ] neat 1 100mg MG Di(2-ethylhexyl)phthalate [ ] neat 1 10mg MG Di(2-ethylhexyl)phthalate [ ] neat 1 100mg MG Di(2-ethylhexyl)isophthalate [ ] neat 1 10mg MG Di(2-ethylhexyl)isophthalate [ ] neat 1 100mg MG Di-n-octyl phthalate [ ] neat 1 10mg MG Di-n-octyl phthalate [ ] neat 1 100mg MG Di-iso-nonyl phthalate (isomer mixture) [ ] neat 1 10mg MG Di-iso-nonyl phthalate (isomer mixture) [ ] neat 1 100mg MG Di-n-nonyl phthalate [ ] neat 1 10mg MG Di-n-nonyl phthalate [ ] neat 1 100mg MG Di-iso-decyl phthalate [ ] neat 1 10mg KIT Mono+Dialkylphthalate Kit Kit All dialkylphthalates are also available as 1000µg/mL in isooctane Deuterated adipates K-I Di(2-ethylhexyl) adipate-d µg/mL isooctane 1 1mL Adipates MG Di(2-ethylhexyl) adipate [ ] neat 1 10mg K-I Di-n-octyl adipate [ ] 1000µg/mL isooctane 1 1mL K-I Di-iso-octyl adipate [ ] 1000µg/mL isooctane 1 1mL K-I Di-n-nonyl adipate [ ] 1000µg/mL isooctane 1 1mL K-I Di-iso-nonyl adipate [ ] 1000µg/mL isooctane 1 1mL KIT Adipate Kit Kit KIT Phthalate and adipate Kit ( ) Kit 382

385 LAS and ABS (Linear alkylbenzene sulfonates and alkylbenzene sulfonates) Pure isomers ME Sodium p-n-octylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL S Na ME Sodium p-n-decylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL ME Sodium p-n-undecylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL ME Calcium p-n-dodecylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL ME Sodium p-n-dodecylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL K-ME Sodium p-n-dodecylbenzenesulfonate [ ] 1000µg/mL methanol 1 1mL K-ME Sodium p-n-tridecylbenzenesulfonate [ ] 1000µg/mL methanol 1 1mL ME Sodium p-n-tridecylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL ME Sodium p-n-tetradecylbenzenesulfonate [ ] 100µg/mL methanol 1 1mL KIT LAS Kit (methanol) Kit Technical mixtures K-ME Dodecylbenzenesulfonic acid, mixture of C12 LAS 12, soft [ ] 1000µg/mL methanol 1 1mL MG Dodecylbenzenesulfonic acid, mixture of C12 LAS 12, soft [ ] neat 1 100mg K-ME Sodium dodecylbenzenesulfonate, mixture of C10-C14 ABS Na, ard [ ] 1000µg/mL methanol 1 1mL MG Sodium dodecylbenzenesulfonate, mixture of C10-C14 ABS Na, ard [ ] neat 1 100mg K-ME Sodium dodecylbenzenesulfonate, mixture of C10-C14 LAS 10-14, Soft [ ] 1000µg/mL methanol 1 1mL MG Sodium dodecylbenzenesulfonate, mixture of C10-C14 LAS 10-14, Soft [ ] neat 1 100mg MG Sodium dodecylbenzenesulfonate, mixture of C10-C14, 38% water LAS 10-14, Soft [ ] neat 1 100mg K-ME Dodecene-1 LAS [ ] 1000µg/mL methanol 1 1mL Compounds 383

386 Metallo-organics Tin-organics Tin chlorides (common pollutants) K-5I Mono-n-butyltin trichloride [ ] 1000µg/mL isooctane 1 5mL G Mono-n-butyltin trichloride [ ] neat 1 1g K-5I Di-n-butyltin dichloride [ ] 1000µg/mL isooctane 1 5mL G Di-n-butyltin dichloride [ ] neat 1 1g K-5I Tri-n-butyltin chloride [ ] 1000µg/mL isooctane 1 5mL G Tri-n-butyltin chloride [ ] neat 1 1g K-ME Mono-n-octyltin trichloride [ ] 1000µg/mL methanol 1 1mL G Mono-n-octyltin trichloride [ ] neat 1 1g K-ME Di-n-octyltin dichloride [ ] 1000µg/mL methanol 1 1mL G Di-n-octyltin dichloride [ ] neat 1 1g K-5I Tri-n-octyltin chloride [ ] 1000µg/mL isooctane 1 5mL MG Tri-n-octyltin chloride [ ] neat 1 100mg K-5I Monophenyltin trichloride [ ] 1000µg/mL isooctane 1 5mL G Monophenyltin trichloride [ ] neat 1 1g K-5I Diphenyltin dichloride [ ] 1000µg/mL isooctane 1 5mL G Diphenyltin dichloride [ ] neat 1 1g K-5I Triphenyltin chloride [ ] 1000µg/mL isooctane 1 5mL G Triphenyltin chloride [ ] neat 1 1g K-ME Tricyclohexyltin chloride [ ] 1000µg/mL methanol 1 1mL G Tricyclohexyltin chloride [ ] 1 1g KIT Butyltin chlorides Kit (solutions, , , ) Kit KIT Butyltin chlorides Kit (neat, , , ) Kit KIT Phenyltin chlorides Kit (solutions, , , ) Kit KIT Phenyltin chlorides Kit (neat, , , ) Kit KIT Tin Chlorides Kit (neat) Kit 384

387 Internal standards (tin chlorides) Tri-n-propyltin chloride [ ] MW Tri-n-pentyltin chloride [ ] MW Sn Cl Cl Sn K-ME G 1000µg/mL methanol, 1x1mL neat, 1x1g K-ME G 1000µg/mL methanol, 1x1mL neat, 1x1g Tetra-n-propyltin [ ] MW Di-n-heptyltin dichloride [ ] MW Sn Cl Sn Cl K-I G 1000µg/mL isooctane, 1x1mL neat, 1x1g K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg Mono-n-heptyltin trichloride [ ] MW Tetra-n-pentyltin [ ] MW Cl Cl Sn Cl K-ME G 1000µg/mL methanol, 1x1mL neat, 1x1g K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg Compounds 385

388 Analytes ethyl derivatives Mono-n-butyltriethyltin [ ] MW Ethyltricyclohexyltin [ ] MW Sn Sn K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Di-n-butyldiethyltin [ ] MW Monophenyltriethyltin [ ] MW Sn Sn K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Ethyltri-n-butyltin [ ] MW Diphenyldiethyltin [ ] MW Sn Sn K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Mono-n-octyltriethyltin [ ] MW Ethyltriphenyltin [ ] MW Sn Sn K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL Di-n-octyldiethyltin [ ] MW Sn K-I 1000µg/mL isooctane, 1x1mL 386

389 Internal standards ethyl derivatives Ethyltri-n-propyltin [ ] MW Di-n-heptyldiethyltin [ ] MW C Sn 3 C C 3 Sn C K-I 1000µg/mL Isooctane, 1x1mL K-I 1000µg/mL isooctane, 1X1mL Ethyltripentyltin [ ] MW Ethylalkyl-/ Ethylaryltin Kit KIT Kit Sn K-I 1000µg/mL isooctane, 1x1mL Mono-n-heptyltriethyltin [ ] MW Sn K-I 1000µg/mL isooctane, 1x1mL Derivatizing agents and other G Sodium tetraethylborate [ ] neat 1 1g K-I Tetra-n-butyltin [ ] 1000µg/mL isooctane 1 1mL KIT-S rganotin Analysis Kit (one of each of the above, solution when available) Kit KIT-N rganotin Analysis Kit (one of each of the above, neat when available) Kit rganoleads Compounds K-I Tetraethyllead (contains trace of xylenes) [ ] 1000µg/mL isooctane 1 1mL K-10I Tetraethyllead (contains trace of xylenes) [ ] 1000µg/mL isooctane 1 10mL il-based metal standards Please inquire 387

390 Forensics and pharmaceuticals Forensics and drug/pharma metabolites Alverine Alverine [ ] MW N-(3-Phenylpropyl)acetamide [ ] MW N N K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x10mg Di-(3-phenyl-1-propyl)amine [ ] MW N-Ethyl,N-(3-phenylpropyl)-3- (4-hydroxyphenyl)propylamine [ ] MW N N K-I 1000µg/mL isooctane, 1x1mL K-I 1000µg/mL isooctane, 1x1mL N-(3-Phenylpropyl)-3- (4-hydroxyphenyl)propylamine MW N K-I 1000µg/mL isooctane, 1x1mL Buprenorphine K-I Buprenorphine [ ] 1000µg/mL isooctane 1 1mL K-I Norbuprenorphine [ ] 1000µg/mL isooctane 1 1mL 388

391 Cathinone Cathinone [ ] MW N 2 C 3 Please inquire Ethanol d5-ethyl-β-d-6-glucuronide MW D D D D D MG neat, 1x10mg Ethyl-β-D-6-triacetyl glucuronic acid methyl ester MW MG neat, 1x10mg Ethyl-β-D-6-glucuronide [ ] MW MG neat, 1x10mg Lamotrigine Lamotrigine Lamotrigine-2N-glucuronide [ ] MW [ ] Cl Cl Cl Cl N N N N + 2 N N N 2 2 N N N 2 Compounds Please inquire Please inquire 389

392 Nicotines N-Nitrosonornicotine [ ] MW (N-Methyl-N-nitrosoamino)-1- (3-pyridyl)-1-butanone [ ] MW N N N N N N K-AN 1000µg/mL acetonitrile, 1x1mL K-2AN 1000µg/mL acetonitrile, 1x2mL K-AN 1000µg/mL acetonitrile, 1x1mL K-2AN 1000µg/mL acetonitrile, 1x2mL DL-N-Nitrosonornicotine-d4 MW D D N N D N D K-AN 1000µg/mL acetonitrile, 1x1mL K-2AN 1000µg/mL acetonitrile, 1x2mL K-4AN 1000µg/mL acetonitrile, 1x4mL MG neat, 1x10mg (N-Methyl-N-nitrosamino)-1- (3-pyridyl)-1-butanone-d4 MW K-AN K-4AN MG 1000µg/mL acetonitrile, 1x1mL 1000µg/mL acetonitrile, 1x4mL neat, 1x10mg N-Nitroso-di-n-hexylamine [ ] MW (RS)-N-Nitrosoanatabine [ ] MW N N N N N K-IP 1000µg/mL isopropanol, 1x1mL K-AN K-2AN 1000µg/mL acetonitrile, 1x1mL 1000µg/mL acetonitrile, 1x2mL (RS)-N-Nitrosoanabasine [ ] MW N N N K-AN K-2AN 1000µg/mL acetonitrile, 1x1mL 1000µg/mL acetonitrile, 1x2mL 390

393 Morphine MG Morphine-6-glucuronide neat neat 1 10mg lanzapine lanzapine [ ] MW N N C 3 N lanzapine 10-N-glucuronide MW N N N N S C 3 N S MG MG G neat, 1x100mg neat, 1x250mg neat, 1x1g Please inquire C Pethidine Pethidine Please inquire [ ] MW Norpethidine Please inquire [ ] Pethidinic acid [ ] MW C 3 N MG neat, 1x10mg Compounds 391

394 Pharmaceuticals and its impurities Acetaminophene Acetaminophene (Paracetamol) 4-Acetaminophenol [ ] MW Chloroacetanilide Imp. J (EP) [ ] MW C N 3 C N Cl K-ME 1000µg/mL methanol, 1x1mL K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x500mg MG neat, 1x100mg N-(4-ydroxyphenyl)- propionamide Imp. B (EP) [ ] MW C N Aminophenol Imp. K (EP) [ ] MW K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x500mg ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Nitrophenol Imp. F (EP) [ ] MW K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg N,-Diacetyl-4-aminophenol Imp. (EP) [ ] MW N ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg 392

395 Acetylsalicylic acid Acetylsalicylic acid (Aspirin) [ ] MW Acetylsalicylsalicylic acid Imp. D (EP) [ ] MW C C K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x500mg ydroxybenzoic acid Imp. A (EP) [ ] MW K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x100mg ME 100µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg MG neat, 1x100mg Acetylsalicylic anhydride Imp. F (EP) [ ] MW C ydroxyisophthalic acid (4-ydroxybenzene- 1,3-dicarboxylic acid) Imp. B (EP) [ ] MW ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg K-ME MG C C 1000µg/mL methanol, 1x1mL neat, 1x100mg (2,4-Dihydroxybenzoyl) benzoic acid [ ] MW ME 100µg/mL methanol, 1x1mL Salicylic acid (2-ydroxybenzoic acid) Imp. C (EP) [ ] MW C Compounds K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x500mg 393

396 Alverine Alverine [ ] MW N K-I MG 1000µg/mL isooctane, 1x1mL neat, 1x10mg Amitriptyline Amitriptyline hydrochloride [ ] MW Nortriptyline hydrochloride Imp. C (EP) [ ] MW Cl Cl K-ME N 1000µg/mL methanol, 1x1mL N MG neat, 1x100mg ME 100µg/mL methanol, 1x1mL MG neat, 1x100mg Dibenzosuberone Imp. A (EP) [ ] MW (3-Dimethylaminopropyl)- 10,11-dihydro-5dibenzo[a,d]cyclohepten-5-ol Imp. D (EP) [ ] MW ME 100µg/mL methanol, 1x1mL ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Cyclobenzaprine hydrochloride Imp. B (EP) [ ] MW ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg 394

397 Aripiprazole Aripiprazole [ ] MW N N N AN Cl Cl 100µg/mL acetonitrile, 1x1mL Atenolol Atenolol [ ] MW N C 3 C 3 2 N [4-[(2RS)-3-chloro-2-hydrox ypropoxy]phenyl]acetamide Imp. D (EP) [ ] MW Cl K-ME 1000µg/mL methanol, 1x1mL 2 N MG neat, 1x500mg ME 100µg/mL methanol, 1x1mL (4-ydroxyphenyl)acetamide Imp. A (EP) [ ] MW [4-[(2RS)-2-ydroxy-3 [(1-methylethyl)amino] propoxy]phenyl]acetonitrile Imp. (EP) [ ] MW N N K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg NC [4-[[(2RS)-2-xiran-2- yl]methoxy]phenyl]acetamide Imp. C (EP) [ ] MW N ME 100µg/mL methanol, 1x1mL MG neat, 1x100mg ydroxyphenylacetic acid [ ] MW K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x100mg Compounds I 100µg/mL isooctane, 1x1mL 395

398 Betamethasone Betamethasone [ ] MW MG F neat, 1x5mg Caffeine Caffeine [ ] MW C 3 3 C N N Isocaffeine (1,3,9- Trimethylxanthine) Imp. C (EP) [ ] MW N C 3 N C 3 N N K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x500mg Theophylline Imp. A (EP) [ ] MW C 3 N N N N C 3 C K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg Paraxanthine [ ] MW N 3 C N N N ME 100µg/mL methanol, 1x1mL N N MG neat, 1x500mg K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg MG neat, 1x50mg 396

399 Carbetocin Carbetocin [ ] MW MG neat, 1x5mg Cimetidine Cimetidine (free base) [ ] MW N N S N N CN N Cimetidine guanidine derivative (N-Methyl-N -[2-[[(5-methyl-- imidazol-4-yl)-methyl]-thiol]- ethyl]-guanidine dihydrochloride) Imp. D (EP) [ ] MW K-ME MG MG MG 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg N N S N N N 2 Cl Cimetidine hydrochloride [ ] MW ME MG MG 100µg/mL methanol, 1x1mL neat, 1x25mg neat, 1x100mg K-ME MG MG MG MG 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg neat, 1x500mg Cimetidine sulphoxide dihydrochloride Imp. E (EP) [ ] MW N Cimetidine carboxamide dihydrochloride (free base) Imp. C (EP) [ ] MW ME N N S N N N 100µg/mL methanol, 1x1mL ME MG MG 100µg/mL methanol, 1x1mL neat, 1x25mg neat, 1x100mg Cyanoguanidine N N S N [ ] MW N N 2 Cl Compounds MG MG neat, 1x25mg neat, 1x100mg K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg 397

400 Codeine Codeine (free base) [ ] MW C Dimethyl pseudomorphine Imp. C (EP) [ ] MW N C 3 Me N K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x10mg N Me MG neat, 1x100mg MG neat, 1x250mg ME 100µg/mL methanol, 1x1mL MG neat, 1x10mg Methylcodeine phosphate MW MG MG neat, 1x100mg neat, 1x250mg ME MG MG MG MG P N 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg ydroxycodeine (7,8-Didehydro-4,5a-epoxy-3- methoxy-17-methylmorphinan- 6a,10-diol) Imp. E (EP) [ ] MW Morphine (free base) Imp. B (EP) [ ] MW ME MG MG MG MG N 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg N C K-ME MG MG MG MG G 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg neat, 1x2g 398

401 ydroxycodeine (7,8-Didehydro-4, 5a-epoxy-3-methoxy-17- methylmorphinan-6a,14-diol) Imp. F (EP) [ ] MW ME MG MG MG 3 C N C 3 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg Codeinone [ ] MW C N C ME 100µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg MG neat, 1x100mg MG neat, 1x250mg Dicodeine sulfate [ ] MW Thebaine Me Imp. G (EP) [ ] MW N 1/2 2 S ME MG MG 3 C 3 C N C 3 100µg/mL methanol, 1x1mL neat, 1x25mg neat, 1x50mg K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x100mg MG neat, 1x250mg Methylcodeine [ ] MW Norcodeine [ ] MW C N K-ME MG MG MG N 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg MG MG MG neat, 1x10mg neat, 1x100mg neat, 1x250mg Compounds 399

402 Codeine-N-oxide (free base) [ ] MW C Acetylcodeine [ ] MW N + C 3 N Cl ME 100µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg MG neat, 1x100mg MG neat, 1x250mg Norcodeine hydrochloride [ ] MW ME 100µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x25mg Pseudomorphine (free base) [ ] MW N N N Cl ME 100µg/mL methanol, 1x1mL K-ME MG MG MG 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg MG MG MG MG neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg 400

403 Codeine hydrochloride dihydrate Codeine hydrochloride [ ] MW K-ME MG MG MG N Cl 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg Codeine phosphate hemihydrate Codeine phosphate hemihydrate MW N P K-ME MG MG MG 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg Dexamethasone Dexamethasone [ ] MW F Compounds MG neat, 1x100mg 401

404 Diazepam Diazepam [ ] MW C N Cl N Nordiazepam Desmethyldiazepam [ ] MW N Cl N K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x25mg ME 100µg/mL methanol, 1x1mL MG neat, 1x100mg Chloro-2- (methylamino)benzophenone [ ] MW C 3 N Cl K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg Dihydrocodeine hydrogen tartrate Codeine (free base) Imp. A (EP) [ ] MW C Morphine (free base) Imp. B (EP) [ ] MW N C 3 N C K-ME 1000µg/mL methanol, 1x1mL K-ME 1000µg/mL methanol, 1x1mL MG neat, 1x10mg MG neat, 1x10mg MG neat, 1x100mg MG neat, 1x25mg MG neat, 1x250mg MG neat, 1x100mg MG neat, 1x250mg G neat, 1x2g 402

405 Flumethasone Flumethasone [ ] MW MG F F neat, 1x5mg Ibuprofen Ibuprofen [ ] MW C 3 C 3 3 C Ethyl-4-(2-methylpropyl) benzene Imp. B2 (EP) [ ] MW C 3 C K-ME 1000µg/mL methanol, 1x1mL 3 C MG MG neat, 1x100mg neat, 1x500mg ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Dibenzosuberone Imp. A (EP) [ ] MW (2RS)-2-[4-(2-Methylpropyl) phenyl]propanamide Imp. C (EP) [ ] MW N MG neat, 1x100mg (2RS)-2-(4-Butylphenyl) propanoic acid Imp. B (EP) [ ] MW ME 100µg/mL methanol, 1x1mL Compounds ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg 403

406 (2RS)-2-(4-Methylphenyl) propanoic acid Imp. D (EP) [ ] MW (2RS)-2-(4-Ethylphenyl) propanoic acid Imp. N (EP) [ ] MW C K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg ME MG 100µg/mL methanol, 1x1mL neat, 1x25mg MG neat, 1x100mg (1-ydroxyethyl)-4- (2-methylpropyl)benzene Imp. D2 (EP) [ ] MW (2RS)-2-[4-(2-Methylpropyl) phenyl]propan-1-ol Imp. P (EP) [ ] MW C C 3 C ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg [4-(2-Methylpropyl) phenyl]ethanone Imp. E (EP) [ ] MW ME 100µg/mL methanol, 1x1mL MG neat, 1x25mg MG neat, 1x100mg Isobutylbenzoic acid Imp. S (EP) [ ] MW C 3 C 3 3 C C 3 C ME 100µg/mL methanol, 1x1mL 3 C MG MG neat, 1x25mg neat, 1x100mg ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Methyl-2-[4-(2-methylpropyl) phenyl]propanoate Imp. F2 (EP) [ ] MW Acetylbenzoic acid Imp. U (EP) [ ] MW C C ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg MG neat, 1x100mg 404

407 Methyl-1-[4-(1-methylethyl) phenyl]-1-propanone Imp. W (EP) [ ] MW (2RS)-2-(4-n-Propylphenyl) propanoic acid [ ] MW C 3 C 3 C C 3 C ME 100µg/mL methanol, 1x1mL ME MG 100µg/mL methanol, 1x1mL neat, 1x25mg MG MG neat, 1x25mg neat, 1x100mg MG neat, 1x100mg Lorazepam Lorazepam [ ] MW N Cl N Chloro-4-(2-chlorophenyl)-2- quinazoline carboxaldehyde Imp. C( EP) [ ] ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Amino-2,5- dichlorobenzophenone Imp. A (EP) [ ] MW Cl ME MG Cl Cl N N 100µg/mL methanol, 1mL neat, 25mg N 2 Cl Cl ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg Compounds 405

408 Metformin hydrochloride Metformin hydrochloride [ ] MW N 2 N ,3,5-Triazine-2,4,6-triamine Melamine Imp. D (EP) [ ] MW N N N C 3 C 3 Cl N N 2 N K-ME MG MG G G G 1000µg/mL methanol, 1x1mL neat, 1x100mg neat, 1x250mg neat, 1x1g neat, 1x5g neat, 1x10g Dicyanodiamide ME MG MG MG Cyanoguanidine Imp. A (EP) [ ] MW N N 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg ,4-Diamino-6-dimethylamino- 1,3,5-triazine N,N-Dimethyl-1,3,5-triazine- 2,4,6-triamine Imp. C (EP) [ ] MW N N N 2 N N 2 N N N ME 100µg/mL methanol, 1x1mL MG neat, 1x100mg Dimethylamine Imp. F (EP) [ ] MW C N C K-MX 1000µg/mL water/metanol, 1x1mL ME 90µg/mL methanol, 1x1mL MG neat, 1x100mg ,1-Dimethylguanidine [ ] MW N 3 C N N 2 3 C Please inquire Dimethylguanidine [ ] MW N 2 N C 3 N C 3 N 3 C N N C ME 100µg/mL methanol, 1x1mL MG neat, 1x100mg ME 100µg/mL methanol, 1x1mL MG neat, 1x25mg MG neat, 1x100mg MG neat, 1x250mg 406

409 Morphine hydrochloride Morphine hydrochloride [ ] MW N Cl MG neat, 1x10mg MG neat, 1x100mg MG neat, 1x250mg Morphine (free base) [ ] MW Codeine phosphate hemihydrate Reference solution MW K-ME MG MG MG N 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg P K-ME MG MG MG MG G 1000µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg neat, 1x2g Codeine Imp. A (EP), see page Pseudomorphine (free base) Imp. B (EP) [ ] MW ME MG MG MG MG 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x25mg neat, 1x100mg neat, 1x250mg Ethylmorphine hydrochloride Ethylmorphine hydrochloride [ ] MW MG MG MG Et N Cl neat, 1x10mg neat, 1x100mg neat, 1x250mg Compounds 407

410 Morphine sulfate Dimorphine sulfate MW /2 2 S 4 N Pseudomorphine (free base) Imp. B (EP) [ ] MW N MG neat, 1x10mg N MG MG neat, 1x100mg neat, 1x250mg ME MG 100µg/mL methanol, 1x1mL neat, 1x10mg Codeine phosphate hemihydrate Reference solution, see page MG MG MG neat, 1x25mg neat, 1x100mg neat, 1x250mg Codeine Imp. A (EP), see page 398 Naproxen Naproxen [ ] MW Acetyl-6-methoxynaphthalene Imp. L (EP) [ ] MW C 3 C C ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg (6-Methoxy-2-naphthyl) acetic acid Imp. I (EP) [ ] MW Methoxynaphthalene Imp. M (EP) [ ] MW C C 3 3 C MG neat, 1x100mg ME MG 100µg/mL methanol, 1x1mL neat, 1x100mg 408

411 lanzapine lanzapine [ ] MW C 3 N N N N S C MG MG G neat, 1x100mg neat, 1x250mg neat, 1x1g xazepam xazepam [ ] MW Amino-5-chlorobenzophenone [ ] MW N N 2 Cl N Cl K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x10mg K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg MG neat, 1x25mg Phenazepam Phenazepam [ ] MW K-T MG MG MG N Br N Cl 1000µg/mL toluene, 1x1mL neat, 1x10mg neat, 1x50mg neat, 1x100mg Compounds 409

412 Pholcodine Pholcodine [ ] MW Pholcodine-N-oxide [ ] MW N N N C 3 N + C ME MG MG MG 100µg/mL methanol, 1x1mL neat, 1x10mg neat, 1x100mg neat, 1x250mg MG MG MG neat, 1x5mg neat, 1x25mg neat, 1x100mg Proguanil hydrochloride Proguanil hydrochloride [ ] MW Cl N N N N N Cl ,5-Bis-(1-methylethyl)- biguanide [ ] MW C 3 N N N C 3 C 3 N N C MG MG MG neat, 1x10mg neat, 1x100mg neat, 1x250mg ME MG MG 100µg/mL methanol, 1x1mL neat, 1x25mg neat, 1x100mg Phenol Imp. C (EP) [ ] MW ,5-Bis-(4-chlorophenyl)- biguanide Cl [ ] MW N N N Cl N N Cl K-ME G 1000µg/mL methanol, 1x1mL neat, 1x1g ME MG 100µg/mL methanol, 1x1mL neat, 1x25mg MG neat, 1x100mg 410

413 Salicylic acid Salicylic acid 2-ydroxybenzoic acid [ ] MW C ydroxyisophthalic acid 4-ydroxybenzene-1,3-dicarboxylic acid Imp. B (EP) [ ] MW C C K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x500mg ydroxybenzoic acid Imp. A (EP) [ ] MW K-ME MG Phenol 1000µg/mL methanol, 1x1mL neat, 1x100mg Imp. C (EP) [ ] MW K-ME G 1000µg/mL methanol, 1x1mL neat, 1x1g K-ME MG 1000µg/mL methanol, 1x1mL neat, 1x100mg Stanozol Stanozol [ ] MW C 3 C3 C 3 N N MG neat, 1x100mg Tramadol hydrochloride Tramadol hydrochloride [ ] MW N Cl ME 100µg/mL methanol, 1x1mL Vasopressin (Arg8)-Vasopressin acetate salt N 2 N 2 N MG N N [ ] MW N N 2 N N N 2 neat, 1x1mg S S N N N 2 N N Ph Compounds 411

414 Natural products Steroids and sterols Diethylstilbestrol [ ] MW C α-Ethynylestradiol [ ] MW C MG neat, 1x100mg MG neat, 1x10mg α()-Androstan-17-one [ ] MW β-ethynylestradiol [ ] MW MG neat, 1x10mg MG neat, 1x10mg α()-Androstan-3β-ol [ ] MW Stanozol [ ] MW C 3 C3 C 3 N N MG neat, 1x10mg MG neat, 1x100mg Norethandrolone [ ] MW Dexamethasone [ ] MW F MG neat, 1x100mg MG neat, 1x100mg 412

415 Betamethasone [ ] MW β()-Cholan-24-ol [ ] MW F MG neat, 1x5mg MG neat, 1x10mg MG neat, 1x25mg Flumethasone [ ] MW β()-Cholanic acid [ ] MW C MG neat, 1x5mg Chlormadinone acetate G [ ] MW C 3 neat, 1x1g Medroxyprogesterone acetate Cl F F C 3 C 3 C 3 [ ] MW MG neat, 1x10mg MG neat, 1x100mg G neat, 1x1g Cholest-4-ene-3-one [ ] MW MG neat, 1x10mg α()-Cholestan-3-one [ ] MW MG neat, 1x100mg β()-Cholane [ ] MW MG neat, 1x10mg β()-Cholestan-3-one [ ] MW Compounds K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x10mg 413

416 Cholest-5-en-3β-ol Cholesterol [ ] MW β()-Cholestan-3α-ol epi-coprostanol [ ] MW MG neat, 1x10mg MG neat, 1x10mg α(),17α(),(20R)-3β- Acetoxycholest-8(14)-ene [ ] MW β()-Cholestan-3β-ol Coprostanol [ ] MW K-I 1000µg/mL isooctane, 1x1mL MG neat, 1x10mg α()-Cholestan-3α-ol epi-cholestanol [ ] MW Brassicasterol [ ] MW MG neat, 1x10mg MG I neat, 1x5mg 100µg/mL isooctane, 1x1mL α()-Cholestan-3β-ol Cholestanol [ ] MW Campesterol [ ] MG neat, 1x10mg X 100µg/mL hexane, 1x1mL 414

417 α(),17α(),(20R)-3β- Acetoxyergost-8(14)-ene MW Ethyl-5α()-cholestan-3β-ol α-sitostanol Stigmastanol [ ] MW I 100µg/mL isooctane, 1x1mL Stigmasterol [ ] MW MG neat, 1x10mg Ethyl-5β()-cholestan-3α-ol 24-Ethyl-epi-coprostanol [ ] MW MG neat, 1x10mg Ethylcholest-5-en-3β-ol α-sitosterol [ ] MW MG neat, 1x10mg Ethyl-5β()-cholestan-3β-ol 24-Ethylcoprostanol [ ] MW MG neat, 1x10mg Ethyl-5α()-cholestan-3α-ol 24-ethylepicholestanol epi-stigmastanol [ ] MW MG neat, 1x10mg MG neat, 1x10mg Compounds 415

418 Triterpenoids β-Acetoxybetulinic acid [ ] MW Betulin diacetate [ ] MW C MG neat, 1x10mg MG neat, 1x10mg α-amyrine [ ] MW Betulinic Acid [ ] MW C MG neat, 1x10mg MG neat, 1x10mg β-amyrine [ ] MW β-boswellic acid [ ] MW MG neat, 1x10mg β-Benzoyloxy-18β()- olean-12-one [ ] MG neat, 1x10mg MG neat, 1x10mg Cerin [ ] MW C C Betulin [ ] MW C 3 C 3 C 3 C 3 C 3 C MG neat, 1x10mg MG neat, 1x10mg 416

419 Cerin acetate [ ] MW β()-op-21(22)-en-3-one [ ] MW I 100µg/mL isooctane, 1x1mL MG neat, 1x10mg Friedelan-3α-ol [ ] MW α(),17β(),21β()-3- ydroxyhopane [ ] MW MG neat, 1x2mg I 100µg/mL isooctane, 1x1mL Friedelan-3β-ol [ ] MW β(),17β(),21β()-3- ydroxyhopane MW MG neat, 1x2mg I 100µg/mL isooctane, 1x1mL Friedelin [ ] MW (3α()+3β()),17β(), 21β()-3-ydroxyhopane [ ] MW MG neat, 1x10mg β(),21β()- op-22(29)-en-3-one [ ] MW I 100µg/mL isooctane, 1x1mL Compounds I 100µg/mL isooctane, 1x1mL 417

420 β(),21β()-22- ydroxyhopane [ ] MW Lupeol [ ] MW MG neat, 1x1mg MG neat, 1x10mg ydroxyhopanone [ ] MW Methyl ursolate [ ] MW I 100µg/mL isooctane, 1x1mL MG neat, 1x10mg Isoadiantone [ ] MW β()-lean-12-en-3-one [ ] MW I 100µg/mL isooctane, 1x1mL MG neat, 1x2mg Keto-β-boswellic acid [ ] MW lean-12-en-11-one [ ] MW MG neat, 1x10mg MG neat, 1x2mg Lup-3-one [ ] MW α-nocera-8,14-dien-3,21-dione p [ ] MW MG neat, 1x5mg MG neat, 1x2mg 418

421 α-nocerin [ ] MW Ursolic acid [ ] MW MG neat, 1x10mg MG neat, 1x10mg α-nocerin diacetate [ ] MW Uvaol [ ] MW MG neat, 1x10mg MG neat, 1x10mg ,29,30-Trisnor- 17α()-hopan-21-one [ ] MW Zeorine [ ] MW I 100µg/mL isooctane, 1x1mL Urs-12-en-3-one [ ] MW MG MG neat, 1x5mg neat, 1x10mg MG Carotenoids neat, 1x10mg Compounds See the Food safety section, pages Alkaloids See Pyrrolizidine- and ergot alkaloids, page

422 Food safety and analysis Mycotoxins AN 3-Acetyldeoxynivalenol 3-AcDN [ ] 100µg/mL acetonitrile 1 1mL AN 3-Acetyldeoxynivalenol 3-AcDN [ ] 100µg/mL acetonitrile 1 5mL MG 3-Acetyldeoxynivalenol 3-AcDN [ ] neat 1 5mg MG 3-Acetyldeoxynivalenol 3-AcDN [ ] neat 1 10mg AN U{13C17}-3-Acetyl-dexoynivalenol 25µg/mL acetonitrile 1 1.2mL AN 15-Acetyldeoxynivalenol 15-AcDN [ ] 100µg/mL acetonitrile 1 1mL AN 15-Acetyldeoxynivalenol 15-AcDN [ ] 100µg/mL acetonitrile 1 5mL MG 15-Acetyldeoxynivalenol 15-AcDN [ ] neat 1 5mg MG 15-Acetyldeoxynivalenol 15-AcDN [ ] neat 1 10mg AN Aflatoxin B1 AFB [ ] 2µg/mL acetonitrile 1 1mL AN Aflatoxin B1 AFB [ ] 2µg/mL acetonitrile 1 5mL MG Aflatoxin B1 - BSA conjugate neat 1 2mg AN Aflatoxin B2 AFB [ ] 0.5 µg/ml acetonitrile 1 1mL AN Aflatoxin B2 AFB [ ] 0.5 µg/ml acetonitrile 1 5mL AN Aflatoxin G1 AFG [ ] 2µg/mL acetonitrile 1 1mL AN Aflatoxin G1 AFG [ ] 2µg/mL acetonitrile 1 5mL AN Aflatoxin G2 AFG [ ] 0.5µg/ml acetonitrile 1 1mL AN Aflatoxin G2 AFG [ ] 0.5µg/ml acetonitrile 1 5mL AN Aflatoxin M1 AFM [ ] 0.5 µg/ml acetonitrile 1 1mL AN Aflatoxin M1 AFM [ ] 0.5 µg/ml acetonitrile 1 5mL MG Aflatoxin M2 AFM [ ] neat 1 1mg S AN MIX 1Aflatoxin mixture 2µg/ml acetonitrile 1 1mL S AN MIX 1Aflatoxin mixture 2µg/ml acetonitrile 1 5mL S AN MIX2 Aflatoxins 0.25µg/ml acetonitrile 1 1mL S AN MIX2 Aflatoxins 0.25 µg/ml acetonitrile 1 5mL AN Deepoxydeoxynivalenol DM [ ] 25µg/mL acetonitrile 1 1mL AN Deepoxydeoxynivalenol DM [ ] 25µg/mL acetonitrile 1 5mL AN Deoxynivalenol DN [ ] 100µg/mL acetonitrile 1 1mL AN Deoxynivalenol DN [ ] 100µg/mL acetonitrile 1 5mL MG Deoxynivalenol DN [ ] neat 1 5mg MG Deoxynivalenol DN [ ] neat 1 10mg MG Deoxynivalenol - BSA Conjugate neat 1 2mg AN Deoxynivalenol-3-glucoside [ ] 50µg/mL acetonitrile 1 1mL AN U{13C15}-Dexoynivalenol 25µg/mL acetonitrile 1 1.2mL G Maize fluor, dexoxynivalenol µg/kg neat 1 100g AN Diacetoxyscirpenol DAS [ ] 100 µg/ml acetonitrile 1 1mL AN Diacetoxyscirpenol DAS [ ] 100 µg/ml acetonitrile 1 5mL MX Fumonisin B1 FB [ ] 50µg/mL acetonitrile/ water (50/50) 1 1mL MX Fumonisin B1 FB [ ] 50µg/mL acetonitrile/ water (50/50) 1 5mL MG Fumonisin B1 FB [ ] neat 1 5mg MG Fumonisin B1 FB [ ] neat 1 10mg AN U{13C34}Fumonisin B1 25µg/mL acetonitrile 1 1.2mL MX Fumonisin B2 FB [ ] 50µg/mL acetonitrile/ water (50/50) 1 1mL MX Fumonisin B2 FB [ ] 50µg/mL acetonitrile/ water (50/50) 1 5mL MX Fumonisin B3 FB [ ] 50µg/mL acetonitrile/ water (50/50) 1 1mL S MX Fumosinin Mixture FB1&FB2 50µg/mL acetonitrile/ 1 1mL (FB1 & FB2) water (50/50) S MX Fumosinin Mixture FB1&FB2 50µg/mL acetonitrile/ (FB1 & FB2) water (50/50) 1 5mL AN Fusarenon-X FusX [ ] 100µg/mL acetonitrile 1 1mL AN Fusarenon-X FusX [ ] 100µg/mL acetonitrile 1 5mL MG Fusarenon-X FusX [ ] neat 1 5mg 420

423 MG Fusarenon-X FusX [ ] neat 1 10mg AN T-2 Toxin T [ ] 100 µg/ml acetonitrile 1 1mL AN T-2 Toxin T [ ] 100 µg/ml acetonitrile 1 5mL AN U{13C22}-T-2 Toxin µg/mL acetonitrile 1 1.2mL AN Neosolaniol NE [ ] 100 µg/ml acetonitrile 1 1mL AN Neosolaniol NE [ ] 100 µg/ml acetonitrile 1 5mL MG Neosolaniol NE [ ] neat 1 5mg MG Neosolaniol NE [ ] neat 1 10mg AN Nivalenol NIV [ ] 100µg/mL acetonitrile 1 1mL AN Nivalenol NIV [ ] 100µg/mL acetonitrile 1 5mL MG Nivalenol hydrate NIV [ ] neat 1 5mg MG Nivalenol hydrate NIV [ ] neat 1 10mg AN chratoxin A [ ] 10 µg/ml acetonitrile 1 1mL AN chratoxin A [ ] 10 µg/ml acetonitrile 1 5mL MG chratoxin A [ ] neat 1 5mg MG chratoxin A [ ] neat 1 10mg AN U{13C20}-chratoxin A 25µg/mL acetonitrile 1 1.2mL MG chratoxin A -BSA Conjugate neat 1 2mg AN Patulin [ ] 100µg/mL acetonitrile 1 1mL AN Patulin [ ] 100µg/mL acetonitrile 1 5mL AN T-2 Tetraol [ ] 50µg/mL acetonitrile 1 1mL AN T-2 Toxin T [ ] 100 µg/ml acetonitrile 1 1mL AN T-2 Toxin T [ ] 100 µg/ml acetonitrile 1 5mL MG T-2 Toxin T [ ] neat 1 5mg MG T-2 Toxin T [ ] neat 1 10mg AN U{13C24}-T-2 Toxin 25µg/mL acetonitrile 1 1.2mL MG T-2 Toxin - BSA Conjugate neat 1 2mg S AN MIX4 A+B-trichothecenes 10µg/mL acetonitrile 1 1mL S AN MIX4 A+B-trichothecenes 10µg/mL acetonitrile 1 5mL S AN MIX2 B-trichothecene mixture 100µg/mL acetonitrile 1 1mL S AN MIX2 B-trichothecene mixture 100µg/mL acetonitrile 1 5mL AN T-2 Triol [ ] 50µg/mL acetonitrile 1 1mL AN α-zearalenol [ ] 10 µg/ml acetonitrile 1 5mL AN β-zearalenol [ ] 10 µg/ml acetonitrile 1 5mL MG β-zearalanol [ ] neat 1 1mg AN Zearalanone [ ] 10 µg/ml acetonitrile 1 5mL AN Zearalenone ZN [ ] 100µg/mL acetonitrile 1 1mL AN Zearalenone ZN [ ] 100µg/mL acetonitrile 1 5mL MG Zearalenone ZN [ ] neat 1 5mg MG Zearalenone ZN [ ] neat 1 10mg MG Zearalenone - BSA Conjugate neat 1 2mg G Maize fluor, zearalenone neat 1 100g Toxic pyrrolizidine alkaloids Crotaline Monocrotaline [ ] Please inquire eliotrine [ ] Please inquire Lasiocarpine [ ] Please inquire ME Retrorcine [ ] 100µg/mL methanol 1 1mL ME Senecionine [ ] 100µg/mL methanol 1 1mL ME Seneciphylline [ ] 100µg/mL methanol 1 1mL Ergot alkaloids ME Ergocornine [ ] 100µg/mL methanol 1 1mL ME Ergocryptine [ ] 100µg/mL methanol 1 1mL Compounds Solanine MG Solanine [ ] neat 1 ml MG Solanidine [ ] neat 1 ml 421

424 Coumarin K-ME Coumarin 1,2-Benzophenone [ ] 1000µg/mL methanol 1 1mL K-ME Coumarin-d [ ] 1000µg/mL methanol 1 1mL ML Cinnamaldehyde [ ] neat 1 ml ML Benzaldehyde [ ] neat 1 ml ML Eugenol [ ] neat 1 ml KIT Coumarin Kit Food impurities and contaminants ITX, Thioxanthones ,3,4-d3-2- Isopropylthioxanthone ITX MW D Thioxanthone [ ] MW S S D D K-I 1000µg/mL isooctane, 1x1mL I MG 100µg/mL isooctane, 1x1mL neat, 1x10mg Methylthiochroman-4-one [ ] MW Isopropylthioxanthone ITX [ ] MW C K-I 1000µg/mL isooctane, 1x1mL Chlorothioxanthone [ ] MW S C 3 Cl S K-I 1000µg/mL isooctane, 1x1mL MG MG neat, 1x10mg neat, 1x100mg K-I 1000µg/mL isooctane, 1x1mL Isopropylthioxanthone ITX [ ] MW ,4-Diethylthioxanthone [ ] MW S S 3 C C K-I 1000µg/mL isooctane, 1x1mL K-I MG 1000µg/mL isooctane, 1x1mL neat, 1x10mg 422

425 Thioxanthone 64 [ ] MW S MG neat, 1x10mg ther food related impurities and contaminates K-ME 3-Chloro-1,2-propandiol [ ] 1000µg/mL methanol 1 1mL K-ME 3-Chloro-1,2-propane-d5-diol [ ] 1000µg/mL methanol 1 1mL G Acylamide [ ] neat 1 1g ME Acrylamide-d [ ] 100µg/mL methanol 1 1mL ME Acrylamide-1-13C [ ] 100µg/mL methanol 1 1mL G Furan [ ] neat 1 1g ME Furan-d [ ] 100µg/mL methanol 1 1mL K-ME 2-Ethylhexanoic acid [ ] 1000µg/mL methanol 1 1mL K-ME 2-Ethylhexanoic acid-d [ ] 1000µg/mL methanol 1 1mL G 2-Nitrobenzaldehyde [ ] neat 1 1g MG Semicarbazide Cl [ ] neat 1 100mg MG Azodicarbonamide [ ] neat 1 100mg MG Nitrofurazone [ ] neat 1 100mg (5-Nitro-2-furfurylidene semicarbazone) MG Ethyl carbamate [ ] neat 1 100mg Algae and shellfish toxins Amnesic shellfish (ASP) toxins MXDomoic acid CRM-DA-e [ ] 99.4µM AN/water 1 0.2mL G Myticus edulis, homogenized (Domoic acid) CRM-ASP-Mus-c 99.4µg/g hom. Mussel 1 8g G Myticus edulis, homogenized (Domoic acid) RM-ASP-Mus 98µg/g hom. Mussel 1 15g Diarrhetic shellfish (DSP) and lipophilic toxins ME kadaic acid CRM-A-b [ ] 30µM methanol 1 0.5mL G Blue mussel, homogenized (kadaic acid) CRM-DSP-Mus-b [ ] 10.1µg/g hom. blend 1 4g UG Dinophysis toxin 1 [ ] 100µg neat 1 neat ME Pectenotoxin CRM-PTX2 [ ] 10.0µM methanol 1 0.5mL Pectenotoxin-2 seco acid CRM-PTX2sa [ ] ME 13-Desmethyl Spirolide C CRM-SPX [ ] 10.2µM methanol 1 0.5mL ME Gymnodimine CRM-GYM [ ] 9.9µM methanol 1 0.5mL ME Yessotoxin CRM-YTX [ ] 4.6µM methanol 1 0.5mL 8102.X-1-05ME Azaspirazide1 CRM-AZA1 methanol 1 0.5mL Compounds 423

426 Paralytic shellfish (PSP) toxins C Saxitoxin dihydrochloride CRM-STX-e [ ] 65µM 10-3M Cl 1 0.5mL C Neosaxitoxin CRM-NE-b [ ] 65µM 10-3M Cl 1 0.5mL C Descarbamoylsaxitoxin CRM-dcSTX 62µM 10-3M Cl 1 0.5mL C Gonyautoxin-1 and -4 CRM-GTX1&4-b [ ]/ [ ] µM Cl/Ac(Aq) 1 0.5mL C Gonyautoxin-2 and -3 CRM-GTX2&3-b [ ]/ µM Cl/Ac(Aq) 1 0.5mL [ ] C Gonyautoxin-5 (akab1) CRM-GTX5-b [ ] 65µM Cl p5 (aq) 1 0.5mL C Descarbamoylgonyautoxin-2 and -3 CRM-dcGTX2& µM Cl/Ac(Aq) 1 0.5mL W Descarbamoylneosaxitoxin CRM-dcNE 30µM water 1 0.5mL C N-Sulfocarbamoyl- CRM-C1& [ ]/ µM Cl p5 (aq) 1 0.5mL gonyautoxin-2 and -3 [ ] Freshwater and cyanobacterial toxins W Cylindrospermopsin CRM-CYN [ ] 30µM water 1 0.5mL MG Anatoxin A [ ] neat 1 1mg Aroma chemicals ff-favour compounds ME Skatole [ ] 100µg/mL methanol 1mL ME 2-Methylkisoboreneol [ ] 100µg/mL methanol 1mL ME (+/-)-Geosmine [ ] 100µg/mL methanol 1mL ME 2,4,6-Trichloroanisole [ ] 100µg/mL methanol 1mL ME Methional [ ] 100µg/mL methanol 1mL ME 2,5-Dibromobiphenyl [ ] 100µg/mL methanol 1mL ME Carvone [ ] 100µg/mL methanol 1mL ME 3-Methyl-2-buten-1-thiol [ ] 100µg/mL methanol 1mL Thiazoles ME 2-Acetylthiazole [ ] 100µg/mL methanol 1mL ME 2-Acetyl-2-thiazoline [ ] 100µg/mL methanol 1mL ME Benzothiazole [ ] 100µg/mL methanol 1mL ME 2-Isobutylthiazole [ ] 100µg/mL methanol 1mL Pyrazines K-I 2-sec-Butyl-3-methoxypyrazine [ ] 1000µg/mL isooctane 1mL K-I 2,3-Dimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2,5-Dimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2,6-Dimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethyl-3,5-dimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethyl-3,6-dimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethyl-3-methoxypyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethyl-3-methylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethyl-5-methylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Ethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Isobutyl-3-methoxypyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Isobutyl-3-methylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Methoxy-3-isopropylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Methoxy-3-methylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Methoxypyrazine [ ] 1000µg/mL isooctane 1mL K-I 2-Methylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2,3,5-Trimethylpyrazine [ ] 1000µg/mL isooctane 1mL K-I 2,3,5,6-Tetramethylpyrazine [ ] 424

427 Phenols G p-cresol [ ] neat 1g G 4-Ethylphenol [ ] neat 1g K-I Guaiacol [ ] 1000µg/mL isooctane 1mL K-MX 4-Vinylphenol [ ] 10 % propylene glycol 1mL K-I 2-Methoxy-4-vinylphenol [ ] 1000µg/mL isooctane 1mL ML Eugenol [ ] neat 1mL K-I Vanillin [ ] 1000µg/mL isooctane 1mL Food colors: See the Food safety section Fatty acids and derivatives Saturated fatty acids K-I Trianoic acid (Propionic) C3: [ ] 1000µg/mL isooctane 1 1mL K-I Tetranoic acid (Butyric) C4: [ ] 1000µg/mL isooctane 1 1mL K-I Pentanoic acid (Valeric) C5: [ ] 1000µg/mL isooctane 1 1mL K-I exanoic acid (Caproic) C6: [ ] 1000µg/mL isooctane 1 1mL K-I eptanoic acid (Enantic) C7: [ ] 1000µg/mL isooctane 1 1mL K-I ctanoic acid (Caprylic) C8: [ ] 1000µg/mL isooctane 1 1mL K-I Nonanoic acid (Pelargonic) C9: [ ] 1000µg/mL isooctane 1 1mL K-I Decanoic acid (Capric) C10: [ ] 1000µg/mL isooctane 1 1mL K-I Undecanoic acid (endecanoic) C11: [ ] 1000µg/mL isooctane 1 1mL K-I Dodecanoic acid (Lauric) C12: [ ] 1000µg/mL isooctane 1 1mL K-I Tridecanoic acid C13: [ ] 1000µg/mL isooctane 1 1mL K-I Tetradecanoic acid (Myristic) C14: [ ] 1000µg/mL isooctane 1 1mL K-I Pentadecanoic acid C15: [ ] 1000µg/mL isooctane 1 1mL K-I exadecanoic acid (Palmitic) C16: [ ] 1000µg/mL isooctane 1 1mL K-I eptadecanoic acid (Margaric) C17: [ ] 1000µg/mL isooctane 1 1mL K-I ctadecanoic acid (Stearic) C18: [ ] 1000µg/mL isooctane 1 1mL K-I Nonadecanoic acid C19: [ ] 1000µg/mL isooctane 1 1mL K-I 12-ydroxystearic acid C18: [ ] 1000µg/mL isooctane 1 1mL K-I Eicosanoic acid (Arachidic) C20: [ ] 1000µg/mL isooctane 1 1mL K-I eneicosanoic acid C21: [ ] 1000µg/mL isooctane 1 1mL K-I Docosanoic acid (Behenic) C22: [ ] 1000µg/mL isooctane 1 1mL K-I Tricosanoic acid C23: [ ] 1000µg/mL isooctane 1 1mL K-I Tetracosanoic acid (Lignoceric) C24: [ ] 1000µg/mL isooctane 1 1mL Saturated fatty acids methyl esters Deuterated K-X Methyl hexadecanoate-d31 (Methyl palmitate) [ ] 1000µg/mL n-hexane 5 1mL K-X Methyl hexadecanoate-d31 (Methyl palmitate-d31) [ ] 1000µg/mL n-hexane 5 1mL K-X Methyl octadecanoate-d [ ] 1000µg/mL n-hexane 5 1mL Native FAMEs K-I Methyl trianoate (Methyl propionate) C3: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl tetranoate (Methyl butyrate) C4: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl isobutyrate [ ] 1000µg/mL isooctane 1 1mL K-I Methyl pentanoate (Methyl valerate) C5: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl hexanoate (Methyl caproate) C6: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl heptanoate (Methyl enantate) C7: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octanoate (Methyl caprylate) C8: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl nonanoate (Methyl pelargonate) C9: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl decanoate (Methyl caprate) C10: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl undecanoate (Methyl hendecanoate) C11: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl dodecanoate (Methyl laurate) C12: [ ] 1000µg/mL isooctane 1 1mL Compounds 425

428 K-I Methyl tridecanoate C13: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl tetradecanoate (Methyl myrististate) C14: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl pentadecanoate C15: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl hexadecanoate (Methyl palmitate) C16: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl heptadecanoate C17: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecanoate (Methyl stearate) C18: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12-hydroxystearate C18: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl nonadecanoate C19: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl eicosanoate (Methyl arachidate) C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl heneicosanoate C21: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl docosanoate (Methyl behenate) C22: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl tricosanoate C23: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl tetracosanoate (Methyl lignocerate) C24: [ ] 1000µg/mL isooctane 1 1mL Saturated fatty acids ethyl esters K-I Ethyl propanoate C3:0,Ethyl trianoate [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl butanoate C4:0,Ethyl tetranoate [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl pentanoate C5: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl hexanoate C6: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl heptanoate C7: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl octanoate C8: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl nonanoate C9: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl decanoate C10: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl undecanoate C11: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl dodecanoate C12: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl tridecanoate C13: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl tetradecanoate C14: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl pentadecanoate C15: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl hexadecanoate C16: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl heptadecanoate C17: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl octadecanoate C18: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl 12-hydroxystearate C18: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl nonadecanoate C19: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl eicosanoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl heneicosanoate C21: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl docosanoate C22: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl tricosanoate C23: [ ] 1000µg/mL isooctane 1 1mL K-I Ethyl tetracosanoate C24: [ ] 1000µg/mL isooctane 1 1mL Unsaturated fatty acids K-I 10-Undecenoic acid C11:1,endecenoic [ ] 1000µg/mL isooctane 1 1mL K-I 11-Dodecenoic acid C12: [ ] 1000µg/mL isooctane 1 1mL K-I 12-Tridecenoic acid C13: [ ] 1000µg/mL isooctane 1 1mL K-I 9-Tetradecenoic acid C14:1,Myristoleic [ ] 1000µg/mL isooctane 1 1mL K-I 9-trans-Tetradecenoic acid C14:1T,Myristelaidic [ ] 1000µg/mL isooctane 1 1mL K-I 10-Pentadecenoic acid C15: [ ] 1000µg/mL isooctane 1 1mL K-I 10-trans-Pentadecenoic acid C15:1T [ ] 1000µg/mL isooctane 1 1mL K-I 14-Pentadecenoic acid C15: [ ] 1000µg/mL isooctane 1 1mL K-I 9-exadecenoic acid C16:1,Palmitoleic [ ] 1000µg/mL isooctane 1 1mL K-I 9-trans-exadecenoic acid C16:1T,Palmitelaidic [ ] 1000µg/mL isooctane 1 1mL K-I 10-eptadecenoic acid C17: [ ] 1000µg/mL isooctane 1 1mL K-I 10-trans-eptadecenoic acid C17:1T [ ] 1000µg/mL isooctane 1 1mL K-I 6-ctadecenoic acid C18:1,Petroselenic [ ] 1000µg/mL isooctane 1 1mL K-I 6-trans-ctadecenoic acid C18:1T,Petroselaidic [ ] 1000µg/mL isooctane 1 1mL K-I 9-ctadecenoic acid C18:1,leic [ ] 1000µg/mL isooctane 1 1mL 426

429 K-I 9-trans-ctadecenoic acid C18:1T,Eleaidic [ ] 1000µg/mL isooctane 1 1mL K-I 11-ctadecenoic acid C18:1,Vaccenic [ ] 1000µg/mL isooctane 1 1mL K-I 11-trans-ctadecenoic acid C18:1T,Transvaccenic [ ] 1000µg/mL isooctane 1 1mL K-I 9,12-ctadecadienoic acid C18:2,Linoleic [ ] 1000µg/mL isooctane 1 1mL K-I 9-trans-12-trans-ctadecadienoic acid C18:2TT,Linoelaidic [ ] 1000µg/mL isooctane 1 1mL K-I 9-cis-12-trans-ctadecadienoic acid C18:2,Conjugated [ ] 1000µg/mL isooctane 1 1mL K-I 10-trans-ctadecadienoic acid C18:2,Conjugated [ ] 1000µg/mL isooctane 1 1mL K-I ctadecadienoic acid (9, ,12 c+tr) (Conjugated) C18:2,Conjugated µg/mL isooctane 1 1mL K-I 6,9,12-ctadecatrienoic acid C18:3,Gamma Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I 9,12,15-ctadecatrienoic acid C18:3,Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I 12-ydroxyoctadecenoic acid C18:1,Ricinoleic [ ] 1000µg/mL isooctane 1 1mL K-I 12-ydroxyoctadecenoic acid C18:1T,Ricinelaidic [ ] 1000µg/mL isooctane 1 1mL K-I 7-Nonadecenoic acid C19: [ ] 1000µg/mL isooctane 1 1mL K-I 7-trans-Nonadecenoic acid C19:1T [ ] 1000µg/mL isooctane 1 1mL K-I 10-trans-Nonadecenoic acid C19:1T [ ] 1000µg/mL isooctane 1 1mL K-I 10-Nonadecenoic acid C19: [ ] 1000µg/mL isooctane 1 1mL K-I 10,13-Nonadecadienoic acid C19: [ ] 1000µg/mL isooctane 1 1mL K-I 5-Eicosenoic acid C20: [ ] 1000µg/mL isooctane 1 1mL K-I 8-Eicosenoic acid C20: [ ] 1000µg/mL isooctane 1 1mL K-I 11-Eicosenoic acid C20:1,Gadolenic [ ] 1000µg/mL isooctane 1 1mL K-I 11-trans-Eicosenoic acid C20:1T [ ] 1000µg/mL isooctane 1 1mL K-I 11,14-Eicosadienoic acid C20: [ ] 1000µg/mL isooctane 1 1mL K-I 8,11,14-Eicosatrienoic acid C20:3,omogamma Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I 11,14,17-Eicosatrienoic acid C20: [ ] 1000µg/mL isooctane 1 1mL K-I Arachidonic acid C20:4,Eicosatetraenoic acid [ ] 1000µg/mL isooctane 1 1mL K-I Eicosapentaenoic acid C20:5 EPA [ ] 1000µg/mL isooctane 1 1mL K-I 12-eneicosenoic acid C21: [ ] 1000µg/mL isooctane 1 1mL K-I 12,15-eneicosadienoic acid C21: [ ] 1000µg/mL isooctane 1 1mL K-I 13-Docosenoic acid C22:1,Erucic [ ] 1000µg/mL isooctane 1 1mL K-I 13-trans-Docosenoic acid C22:1T,Brassidic [ ] 1000µg/mL isooctane 1 1mL K-I 13,16-Docosadienoic acid C22: [ ] 1000µg/mL isooctane 1 1mL K-I 13,16,19-Docosatrienoic acid C22: [ ] 1000µg/mL isooctane 1 1mL K-I 7,10,13,16-Docosatetraenoic acid C22: [ ] 1000µg/mL isooctane 1 1mL K-I 4,7,10,13,16-Docosapentaenoic acid C22: [ ] 1000µg/mL isooctane 1 1mL K-I Docosapentaenoic acid C22:5 DPA µg/mL isooctane 1 1mL K-I Docosahexaenoic acid C22:6 DA [ ] 1000µg/mL isooctane 1 1mL K-I 14-Tricosenoic acid C23: [ ] 1000µg/mL isooctane 1 1mL K-I 15-Tetracosenoic acid C24:1,Nervonic [ ] 1000µg/mL isooctane 1 1mL Unsaturated fatty esters K-I Ethyl 4-trans-decenoate C10:4C [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-undecenoate C11:1,endecenoic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11-dodecenoate C12: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12-tridecenoate C13: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 9-tetradecenoate C14:1,Myristoleic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 9-trans-tetradecenoate C14:T,Myristoleic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-pentadecenoate C15: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-trans-pentadecenoate C15:1T [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 14-pentadecenoate C15: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 9-hexadecenoate C16:1,Palmitoleic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 9-trans-hexadecenoate C16:1T,Palmiteladic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-heptadecenoate C17: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-trans-heptadecenoate C17:1T [ ] 1000µg/mL isooctane 1 1mL Compounds 427

430 K-I Methyl octadecenoate C18:1 Petroselinic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 6-trans-octadecenoate C18:1T, Petroselaiolic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 9-trans-octadecenoate C18:1T [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecenoate C18:1,leic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecenoate C18:1,Vaccenic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11-trans-octadecenoate C18:1T,Transvaccenic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12- hydroxy-9-octadecenoate C18:1,Ricinoleic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12-hydroxy-9-trans-octadecenoate C18:1T,Ricinelaidic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecadienoate (9, ,12 c+tr) C18:2,Conjugated µg/mL isooctane 1 1mL K-I Methyl octadecadienoate (9c,11tr) C18:2,Conjugated [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecadienoate (10tr,12c) C18:2,Conjugated [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecadienoate (9c,12c) C18:2,Linoleic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecatrienoate (6c, 9c, 12c) C18:3,Gamma Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecatrienoate (9c, 12c, 15c) C18:3,Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl octadecadienoate (9tr,12tr) C18:2TT,Linoelaidic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 7-nonadecenoate C19: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 7-trans-nonadecenoate C19:1T µg/mL isooctane 1 1mL K-I Methyl 10-nonadecenoate C19: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10-trans-nonadecenoate C19:1T [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 10,13-nonadecadienoate C19: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 5-eicosenoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 8-eicosenoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11-eicosenoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11-trans-eicosenoate C20:1T [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11,14-eicosadienoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 8,11,14-eicosatrienoate C20:3,omogamma Linolenic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 11,14,17-eicosatrienoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl arachidonoate C20: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 5,8,11,14,17- eicosapentaenoate C20:5 EPA [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12-heneicosenoate C21: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 12,15-heneicosadienoate C21: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 13-docosenoate C22:1,Erucic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 13-trans-docosenoate C22:1T,Brassidic [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 13,16-docosadienoate C22: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 13,16,19-docosatrienoate C22: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 7,10,13,16-docosatetraenoate (all-cis) C22: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 4,7,10,13,16-docosapentaenoate C22: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 5,8,11,14,17-docosapentaenoate C22:5 DPA µg/mL isooctane 1 1mL K-I Methyl-4,7,10,13,16,19- docosahexaenoate C22:6 DA [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 14-tricosenoate C23: [ ] 1000µg/mL isooctane 1 1mL K-I Methyl 15-tetracosenoate C24:1,Nervonic [ ] 1000µg/mL isooctane 1 1mL 428

431 ygienic products ygienic additives G α-d(+)-melibiose hydrate [ ] neat 1 1g MG Sodium hyaluronate [ ] neat 1 100mg Synthetic musks K-I Musk ambrette [ ] 1000µg/mL isooctane 1 1mL K-I Musk moskene [ ] 1000µg/mL isooctane 1 1mL K-I Musk tibeten [ ] 1000µg/mL isooctane 1 1mL K-I Musk xylene [ ] 1000µg/mL isooctane 1 1mL K-I Cashmeran DPMI [ ] 1000µg/mL isooctane 1 1mL K-I Celestolide ADBI [ ] 1000µg/mL isooctane 1 1mL K-I Galaxolide CB [ ] 1000µg/mL isooctane 1 1mL K-I Phantolide AMI [ ] 1000µg/mL isooctane 1 1mL K-I Tonalide ATN [ ] 1000µg/mL isooctane 1 1mL K-I Traseolide ATII [ ] 1000µg/mL isooctane 1 1mL Reagents Derivatizing agents and reagents ML Acetic anhydride [ ] neat 1 1mL ML Acetic anhydride [ ] neat 10 1mL ML N,-Bis(trimethylsilyl)acetamide BSA [ ] neat 1 1mL ML N,-Bis(trimethylsilyl)acetamide BSA [ ] neat 10 1mL ML N,-Bis(trimethylsilyl)acetamide BSA [ ] neat 1 25mL ML N,-Bis(trimethylsilyl) trifluoroacetamide BSTFA [ ] neat 1 1mL ML N,-Bis(trimethylsilyl) trifluoroacetamide BSTFA [ ] neat 10 1mL G N,-Bis(trimethylsilyl) trifluoroacetamide BSTFA [ ] neat 1 50g ML Boron trifluoride, 12% in methanol [ ] neat 10 1mL ML Chlorotrimethylsilane TMCS neat 5mL MG Dansylchloride-d [ ] neat 1 10mg MG Dansylchloride-d [ ] neat 25mg ML N,N-Dimethylformamide dimethyl acetal [ ] neat 5 1mL ML eptafluorobutyric anhydride FBA [ ] neat 1 1mL ML eptafluorobutyric anhydride FBA [ ] neat 10 1mL ML 1,1,1,3,3,3-examethyldisilazane MDS [ ] neat 1 10mL K-I ydrindantin (reduced form of ninhydrin) [ ] 1000µg/mL isooctane 1 1mL MG ydrindantin (reduced form of ninhydrin) [ ] neat 1 100mg ML N-Methylbis(trifluoroacetamide) [ ] neat 1 1mL ML N-Methyl-N-(trimethylsilyl) trifluoroacetamide MSTFA [ ] neat 1 1mL G N-Methyl-N-(trimethylsilyl) trifluoroacetamide MSTFA [ ] neat 1 5g G N-Methyl-N-(trimethylsilyl) trifluoroacetamide MSTFA [ ] neat 1 25g ML Pentafluorobenzoyl chloride [ ] neat 1 1mL ML Pentafluorobenzoyl chloride [ ] neat 5 1mL ML Pentafluorobenzoyl chloride [ ] neat 1 5mL ML Pentafluorobenzoyl chloride [ ] neat 1 25mL Compounds 429

432 ML Pentafluoropropionic anhydride [ ] neat 1 1mL ML Pentafluoropropionic anhydride [ ] neat 10 1mL G Perfluorokerosene (bp ) neat 1 1g MG Perfluoro-tri-n-butylamine eptacosa [ ] neat 1 500mg G Perfluoro-tri-n-butylamine eptacosa [ ] neat 1 5g G Sodium tetraethylborate [ ] neat 1 1g ML Trifluoroacetic anhydride TFAA [ ] neat 1 1mL ML Trifluoroacetic anhydride TFAA [ ] neat 10 1mL ML 1-(Trifluoroacetyl)imidazole TFAI [ ] neat 1 1mL ML 1-(Trifluoroacetyl)imidazole TFAI [ ] neat 5 1mL ML 1-(Trimethylsilyl)imidazole TMSI [ ] neat 1 1mL ML 1-(Trimethylsilyl)imidazole TMSI [ ] neat 5 1mL G 1-(Trimethylsilyl)imidazole TMSI [ ] neat 1 50g G p-toluenesulfonyl-n-methyl-n-nitrosamide [ ] neat 1 10g GC-IRMS standards K-I n-decane GC-IRMS Standard [ ] 1000µg/mL isooctane 1 1mL K-I n-decane GC-IRMS Standard [ ] 1000µg/mL isooctane 5 1mL K-I n-decane GC-IRMS Standard [ ] 1000µg/mL isooctane 10 1mL CY n-undecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-undecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-undecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-dodecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-dodecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-dodecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-tridecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-tridecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-tridecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-tetradecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-tetradecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-tetradecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-pentadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-pentadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-pentadecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-exadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-exadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-exadecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-eptadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-eptadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-eptadecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-ctadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-ctadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-ctadecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-nonadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-nonadecane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-nonadecane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-eicosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-eicosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-eicosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-eneicosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-eneicosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-eneicosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-docosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-docosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-docosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-tricosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-tricosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-tricosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-tetracosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-tetracosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-tetracosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL 430

433 CY n-pentacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-pentacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-pentacosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-exacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-exacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-exacosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-eptacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-eptacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-eptacosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-ctacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-ctacosane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-ctacosane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-triacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-triacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-triacontane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-dotriacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-dotriacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-dotriacontane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-exatriacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-exatriacontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-exatriacontane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL CY n-tetracontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 1 1mL CY n-tetracontane GC-IRMS Standard [ ] 150µg/mL cyclohexane 5 1mL CY n-tetracontane GC-IRMS Standard [ ] 150ug/ml cyclohexane 10 1mL KIT GC-IRMS Standard Kit Kit CY GC-IRMS Standards (C11, C15, C20) 150µg/mL cyclohexane 1 1mL CY GC-IRMS Standards (C11, C15, C20) 150µg/mL cyclohexane 5 1mL CY GC-IRMS Standards (C11, C15, C20) 150µg/mL cyclohexane 10 1mL CY GC-IRMS Standards (C15, C20, C25) 150µg/mL cyclohexane 1 1mL CY GC-IRMS Standards (C15, C20, C25) 150µg/mL cyclohexane 5 1mL CY GC-IRMS Standards (C15, C20, C25) 150µg/mL cyclohexane 10 1mL CY GC-IRMS Standards (C25, C30, C36) 150µg/mL cyclohexane 1 1mL CY GC-IRMS Standards (C25, C30, C36) 150µg/mL cyclohexane 5 1mL CY GC-IRMS Standards (C25, C30, C36) 150µg/mL cyclohexane 10 1mL CY GC-IRMS Standards (C25, C30, C36, C40) 150µg/mL cyclohexane 1 1mL CY GC-IRMS Standards (C25, C30, C36, C40) 150µg/mL cyclohexane 5 1mL CY GC-IRMS Standards (C25, C30, C36, C40) 150µg/mL cyclohexane 10 1mL Compounds 431

434 Solvents K-MX Acetone 2-Propanone [ ] 2000µg/mL 9:1 Methanol/water or Methanol 1 1mL ML Benzene [ ] neat 1 5mL K-ME Chlorobenzene [ ] 2000µg/mL Methanol 1 1mL ML Chloroform, 99+% [ ] neat 1 5mL ML Ethanol [ ] neat 1 5mL K-ME Ethyl acetate [ ] 2000µg/mL Methanol 1 1mL ML Ethyl acetate [ ] neat 1 1mL K-ME Ethyl ether [ ] 2000µg/mL Methanol 1 1mL K-ME n-eptane [ ] 1000µg/mL Methanol 1 1mL ML n-eptane [ ] neat 1 10mL K-ME n-exane [ ] 1000µg/mL Methanol 1 1mL ML n-exane [ ] neat 1 10mL ML Isopropanol [ ] neat 1 10mL ML Methanol [ ] neat 1 5mL K-ME n-pentane [ ] 1000µg/mL Methanol 1 1mL ML n-pentane [ ] neat 1 10mL ML 1-Propanol [ ] neat 1 5mL ML Pyridine [ ] neat 1 1mL ML Styrene [ ] neat 1 2mL K-I Toluene, 3 Wt% in Isooctane [ ] 30mg/mL isooctane 1 1mL K-I Toluene, 3 Wt% in Isooctane [ ] 30mg/mL isooctane 5 1mL ML Toluene [ ] neat 1 1mL ML Toluene [ ] neat 1 5mL ML o-xylene [ ] neat 1 1mL ML o-xylene [ ] neat 1 5mL ML m-xylene [ ] neat 1 1mL ML p-xylene [ ] neat 1 1mL ML Benzene, sulfurdepleted [ ] neat 1 25mL ML Isooctane, sulfurdepleted [ ] neat 1 25mL 1205.MX-25ML Isooctane/Toluene 9:1, sulfurdepleted [ ]/ [ ] neat 1 25mL 1206.MX-25ML Isooctane/Toluene 3:1, sulfurdepleted [ ]/ [ ] neat 1 25mL ML eavy White Mineral il, sulfurdepleted neat 1 25mL ML Light White Mineral il, sulfurdepleted neat 1 25mL ML Toluene, sulfurdepleted [ ] neat 1 25mL ML Xylene, low sulfur [ ] neat 1 25mL 432

435 Chapter V: Indexes Table of contents Alphabetic index Chiron No. index CAS No. index Mixture No. index Standard methods Indexes 433

436 Alphabetic index Product name Pg. Product name Pg. Product name Pg. Abietic acid Acenaphthene Acenaphthene-d Acenaphthenequinone Acenaphthenol Acenaphthylene Acenaphthylene-d Acephate Acetaminophene Acetaminophenol Acetanilide Acetic anhydride Acetochlor-d11 (2-ethyl-6-methylphenyl-d11) Acetone Acetophenone Acetosyringone β-Acetoxybetulinic acid , 416 5α(),17α(),(20R)-3β- Acetoxycholest-8(14)-ene α(),17α(),(20R)-3β- Acetoxyergost-8(14)-ene Acetylbenzoic acid Acetylcodeine Acetyldeoxynivalenol Acetyldeoxynivalenol U{13C17}-3-Acetyl-dexoynivalenol Acetyl-6-methoxynaphthalene Acetylsalicylic acid Acetylsalicylic anhydride Acetylsalicylsalicylic acid Acetylthiazole Acetyl-2-thiazoline Aclonifen Acridine Acridine / Benzacridine Kit Acridine-d (10)-Acridone Acrylamide-d Acylamide Adamantane Adamantane-d Adamantane Kit Adipate Kit Adipic acid Aflatoxin B Aflatoxin B1 - BSA conjugate Aflatoxin B Aflatoxin G Aflatoxin G Aflatoxin M Aflatoxin M Alachlor Alachlor -d13 (2,6-diethylphenyl-d13) Aldicarb Aldicarb sulfone Aldicarb sulfoxide Aldrin Aliphatic alcohol Kit Aliphatic ketone Kit C10 Alkane Kit C5-C6 Alkane Kit C7-C8 Alkane Kit C9 Alkane Kit n-alkane Kit n-alkane Kit (solutions when available/else neat) Alkanethiol Kit Alkenes Kit C3 Alkylbenzene Kit C4 Alkylbenzene Kit C0-C2 Alkylbenzene Kit C5-C19 Alkylbenzenes Kit Alkylbiphenyl Kit C0-C3 Alkylcycloalkane Kit C0-C2 Alkylcycloheptane Kit C3 Alkylcyclohexane Kit C0-C2 Alkylcyclopentane Kit C3-C4 Alkylcyclopentane Kit Allethrin Alverine , 394 Ambush Ametryne Aminoacridine hemihydrate Aminoanthracene Aminoanthracene Aminoanthracene Kit Aminobenz[a]anthracene Aminobenzo[e]pyrene Aminobenzo[e]pyrene Aminobenzo[a]pyrene Aminobiphenyl Aminobiphenyl Aminobiphenyl Aminobiphenyl-d Aminobiphenyl-d Amino-5-chlorobenzophenone Aminochrysene Aminochrysene Aminodiphenyl ether Amino-9-ethylcarbazole Aminoflourene Aminofluoranthene Aminofluorene Aminofluorene-d Aminofluorene hydrochloride Aminofluorene Kit Amino-9-fluorenone Aminoindan Aminoindan Aminoindan Aminoindan Kit Amino-2-methylnaphthalene Aminonaphthalene Aminonaphthalene Aminonaphthalene-d Aminonaphthalene-d Aminonaphthalene Kit Amino-1-naphthol Amino-2-naphthol Amino-5-nitrophenol Aminoperylene Aminoperylene Aminophenol , Aminopyrene Aminopyrene Aminopyrene Aminopyrene-/ Aminobenzopyrene Kit Amitriptyline hydrochloride tert-amylalcohol tert-amyl methyl ether tert-Amylphenol n-Amylthiophene β-amyrine α-amyrine (+/-)-Anatoxin A α()-Androstane α()-Androstan-17-one α()-Androstan-3β-ol Anilazine Aniline Anisol Kit Anthanthrene Anthracene Anthracenecarboxylic acid Anthracenecarboxylic acid Anthracenecarboxylic acid Anthracene-d ,8-Anthracenedicarboxylic acid..279, 281 C0-C1 Anthracene Kit C3-C4 Anthracene Kit Anthraceno[2.3-a]coronene Anthraflavic acid ,4-Anthraquinone ,10-Anthraquinone Anthrarubin C2 Naphthalene Kit Arachidonic acid Arochlor Arochlor Arochlor Arochlor Arochlor Arochlor , 357 Arochlor Arochlor Asana Aspirin Atenolol Atrazine Atrazine-desethyl Atrazine-desisopropyl Atrazine-d5 (ethyl-d5) Azelaic acid Azinphos methyl Azinphos-methyl-oxon Azodicarbonamide Azulene Balan Baygon Baytex Benfluralin Bentazone Benthiocarb Benz[a]acridine Benz[c]acridine Benzahex Benzaldehyde Benz[a]anthracene Benz[a]anthracene-d ,2-Benz[a]anthraquinone Benzanthrone Benzene , 432 Benzene-d ,4-Benzenedicarboxylic acid ,2,4,5-Benzenetetracarboxylic acid ,2,4-Benzenetricarboxylic acid Benzidine Benzo- and dibenzonaphthofuran Kit

437 Product name Pg. Product name Pg. Product name Pg. Benzo[1,2-b Benzo[a]carbazole Benzo[b]carbazole Benzo[c]carbazole Benzocarbazole and alkyl/- phenyl benzocarbazole Kit Benzocarbazole Kit , 343 Benzo[b]chrysene Benzo[c]chrysene Benzo[g]chrysene Benzochrysene Kit Benzo[a]coronene Benzodinaphtho[1.7,2.4], [7.1,11.13]bisanthene Benzo[pgr]dinaphtho [8,1,2-bcd:2,1,8 -lmn]perylene Benzo[a]fluoranthene Benzo[b]fluoranthene Benzo[ghi]fluoranthene Benzo[j]fluoranthene Benzo[k]fluoranthene Benzofluoranthene and phenylfluoranthene Kit Benzo[b]fluoranthene-d Benzo[k]fluoranthene-d Benzo[a]fluorene Benzo[b]fluorene Benzo[c]fluorene Benzo[a]fluoren-11-one Benzo[b]fluoren-11-one Benzofuran Benzofuran Kit Benzoic acid , 393 Benzo[a]naphtha[8,1,2-cde] naphthacene Benzo[b]naphtho[1,2-d]furan Benzo[b]naphtho[2,1-d]furan Benzo[b]naphtho[2,3-d]furan Benzo[b]naphtho[1,2-d]thiophene Benzo[b]naphtho[2,1-d]thiophene Benzo[b]naphtho[2,3-d]thiophene Benzo[a]pentacene Benzo[b]perylene Benzo[ghi]perylene Benzo[ghi]perylene-d Benzo[c]phenanthrene , 312 Benzo[c]phenanthrene[1,4]quinone Benzo[c]phenanthrene[5,6]quinone Benzophenone , 402 1,2-Benzophenone Benzo[b]picene Benzo[a]pyrene Benzo[e]pyrene Benzo[a]pyrene-d Benzo[e]pyrene-d Benzo[cd]pyren-6-one Benzo[c]quinoline Benzo[f]quinoline Benzo[h]quinoline ,6-Benzoquinoline ,8-Benzoquinoline Benzoquinoline Kit Benzo[cde]rubicene Benzo[a]tetracene , 333 Benzothiazole Benzothiophene , 347 Benzothiophene Kit , 347 C0-C1 Benzothiophene Kit β-Benzoyloxy-18β()-olean-12-one Benzyl benzoate Benzyl-n-butyl phthalate-3,4,5,6-d Benzyl-4-methylphenol Benzylphenol Benzylphenol Betamethasone , 413 Betulin Betulin diacetate Betulinic acid , 416 9,9 -Bianthracene Bicyclic aliphatic acid Kit Bicyclic aromatic acid Kit cis-bicyclo[4.3.0]nonane trans-bicyclo[4.3.0]nonane Bicyclo[3.3.0]octane Bifenox Bifenthrin ,9 -Bifluorenylidene ,1 -Binaphthyl ,2 -Binaphthyl ,2 -Binaphthyl ,2 -Binaphthyl-d Biphenyl Biphenyl-d Bisanthene (Phenanthro [1,10,9,8-opqra]perylene Bisanthone ,5-Bis-(4-chlorophenyl)- biguanide Cl ,4-Bis(2-ethylhexyl)benzene Bis(2-ethylhexyl) phthalate- 3,4,5,6-d Bis(3-fluorophenyl)disulfide α(),21β()-(22RS)-Bishomohopane β(),21β()-(22RS)-Bishomohopane α(),21α()-(22RS)-Bishomohopane β(),21α()-(22RS)-Bishomohopane 264 Bishomohopane, Isomer mix Bishopane Kit ,8-Bis(hydroxymethyl)anthracene ,4-Bis(1-methylbutyl)phenol ,5-Bis-(1-methylethyl)-biguanide β(),21α()-28,30-Bisnorhopane α(),21β()-28,30-Bisnorhopane α(),21β()-25-Bisnorhopane Bisnorhopane Kit Bisphenol A Bisphenol-A-2,2,3,3,5,5,6,6 -d Bisphenol-A-2,2,6,6 -d Bisphenol-A-3,3,5,5 -d Bisphenol-A-d Bisphenol-A-d ,2-Bis(phenylthio)ethane Bis(phenylthio)methane N,-Bis(trimethylsilyl)acetamide N,-Bis(trimethylsilyl) trifluoroacetamide Blue mussel, homogenized (kadaic acid) L-(-)-Borneol Boron trifluoride β-boswellic acid , 416 Botran Botryococcane C , 232 Botryococcane C30-C , 231, 232 Botryococcane C32-C , 232 Botryococcane Kit Brassicasterol Brassidic , 428 Bromacil Bromoanisol Bromoanisol Kit Bromobenz[a]anthracene Bromobenzene Bromobenzene Kit Bromobiphenyl Bromobiphenyl Bromobiphenyl Bromochloromethane Bromo-2-chloro-1,1,1- trifluoroethane Bromodibenzofuran Bromodibenzothiophene Bromodibenzothiophene Bromodibenzothiophene Kit Bromodichloromethane Bromofluorobenzene Bromo-4 -fluorodiphenyl ether Bromoform Bromonaphthalene Bromonaphthalene Bromophenol Bromophenol Bromophenol-2,3,5,6-d Bromophenol Kit Bromothiophene Bromothiophene Bromoxynil , 368 Buprenorphine ,2-Butanediol Butanethiol Butanethiol Butanoic acid, heptafluoro-, sodium salt Butanol sec-butanol tert-butanol Butanone Butoxyethanol Butoxyethyl acetate n-butylbenzene sec-butylbenzene tert-butylbenzene n-butylbenzene-d n-Butylbenzofuran n-Butylbenzoic acid Butylbenzyl phthalate n-Butylbiphenyl n-Butylchrysene n-butylcyclohexane n-butylcyclopentane n-Butyldibenzothiophene n-Butyldibenzothiophene tert-Butyl-2,6-diisopropylphenol Butyl-2,3-dimethylnaphthalene tert-Butyl-4,6-dimethylphenol sec-Butyl-4,6-dinitrophenol , tert-Butyl-4,6-dinitrophenol , sec-Butyl-4,6-dinitrophenol , tert-Butyl-4,6-dinitrophenol , tert-Butyl-4-ethylbenzene tert-butyl ethyl ether tert-Butyl-4-ethylphenol n-Butyl-5-ethylthiophene n-Butylfluorene sec-Butyl-3-methoxypyrazine tert-butyl methyl ether tert-Butyl-4-methylphenol Indexes 435

438 Product name Pg. Product name Pg. Product name Pg. 2-tert-Butyl-5-methylphenol tert-Butyl-6-methylphenol tert-Butyl-2-methylphenol tert-Butyl-2-methylphenol Butylnaphthalene n-Butylphenanthrene sec-Butylphenol tert-Butylphenol tert-Butylphenol n-Butylphenol sec-Butylphenol tert-Butylphenol tert-Butyl-d9-phenol-2,3,5,6-d n-Butylphenol-2,3,5,6-d4, D tert-Butyl-2-phenylphenol (2RS)-2-(4-Butylphenyl) propanoic acid n-Butylpyrene n-Butylthiophene Butyltin chlorides Kit (neat, , , ) Butyltin chlorides Kit tert-Butyl-m-xylene Butyric n-butyrophenone Cadalene , 305 Cadusafos Caffeine Calcium p-ndodecylbenzenesulfonate Campesterol Caprylic Captafol Captan Carbaryl Carbazole Carbazole Carbazole-d Carbazole Kit Carbetocin Carbofuran Carbofuran-d3 (N-methyl-d3) Carbofuran-3-hydroxy Carbon disulfide ββ-carotane ββ-carotene Carvacrol Carvone Casaron Cashmeran Catechol Cathinone (-)-α-cedrene Celestolide Cerin , 417 Cerin acetate Chamazulene Chlordane Chlordane, cis-alpha Chlordane, oxy Chlordane, trans-gamma Chlorfenson Chlorfenvinphos Chlormadinone acetate Chlormephos Chloroacetanilide Chloroaniline Chlorobenzene , 432 Chlorobenzene Kit Chlorobenzilate Chlorobenzyl mercaptan Chloro-2-benzylphenol Chloro-4-tert-butylphenol Chlorodibenzo-p-dioxin Chlorodibenzo-p-dioxin Chlorodibromomethane Chloro-4-fluorobenzene Chloro-4 -fluorobiphenyl Chloroform , Chloro-2-(methylamino) benzophenone Chloro-2-methylaniline Chloro-2-methylaniline Chloro-5-methyl-2-(1- methylethyl)phenol Chloro-5-methylphenol Chloro-2-methylphenol Chloro-3-methylphenol , Chloro-2-methylphenol-3,5,6-d Chloro-3-methylphenol-2,6-d (4-Chloro-2-methylphenoxy-d3) propionic acid Chloronaphthalene Chloronaphthalene Chlorooctadecane Chloro- /10- chlorooctadecanoic acid Chlorophenol Chlorophenol Chlorophenol Chlorophenol-3,4,5,6-d Chlorophenol-2,3,5,6-d4, D Chloro-1,2-propandiol Chloropropane Chloro-1,2-propane-d5-diol Chlorothalonil Chlorothiophene Chlorothioxanthone Chlorotoluene Chlorotoluene Chlorotrimethylsilane Chloroxuron Chlorpropham Chlorpyrifos Chlorpyrifos-methyl Chlorpyriphos-d10 (,-diethyl-d10) β()-Cholane , 413 5β()-Cholanic acid β-Cholanic acid β()-Cholan-24-ol Cholanthrene Cholanthrene solutions Kit d2 C27 ααα (20R)-Cholestane d4 C27 ααα (20R)-Cholestane βαα (20R)-Cholestane , 249 αββ (20R)-Cholestane , 249 ααα (20R)-Cholestane , 249 ααα (20S)-Cholestane Cholestane , 249 Cholestane isomer Kit β()-Cholestan-3α-ol α()-Cholestan-3β-ol α()-Cholestan-3α-ol Cholestanol epi-cholestanol β()-Cholestan-3-one α()-Cholestan-3-one β()-Cholestan-3β-ol Cholest-3,5-diene Cholest-2-ene Cholest-3-ene Cholest-4-ene Cholest-5-ene Cholest-8(14)-ene Cholest-4-ene-3-one Cholesterol Chrysene Chrysene-d Chrysene-trans-1,2-dihydrodiol Chrysene-trans-3,4-dihydrodiol Chrysene-trans-5,6-dihydrodiol C2+ Chrysene Kit ,4-Chrysenequinone ,6-Chrysenequinone Cimetidine carboxamide dihydrochloride (free base) Cimetidine (free base) Cimetidine guanidine derivative Cimetidine hydrochloride Cimetidine sulphoxide dihydrochloride Cinnamaldehyde Circobiphenyl Clopyralid Codeine (free base) , 402 Codeine hydrochloride Codeine-N-oxide (free base) Codeine phosphate hemihydrate...401, 407 Codeinone Coprostane Coprostanol Coronene Coronene-d Coronylovalene Coumaphos Coumarin Coumarin-d Coumarin Kit m-cresol o-cresol p-cresol , 425 m-cresol-d o-cresol-d p-cresol-d Crimidine Crocetane , 231 Crotaline Cumene (+)-Cuparene Curacron Cyanazine Cyanazine-d5 (N-ethyl-d5) Cyanoguanidine , 406 Cyanoguanidine , 406 Cycloalkane Kit Cycloalkylthiol Kit Cycloartane Cyclobenzaprine hydrochloride , 5-Cyclocholestane Cyclododecane trans, trans, cis-cyclododeca-1,2,9- triene Cycloheptane Cyclohexane Cyclohexanecarboxylic acid ,1-Cyclohexanediacetic acid

439 Product name Pg. Product name Pg. Product name Pg. 1,4-Cyclohexanedicarboxylic acid.274, 281 cis-1,2-cyclohexanedicarboxylic acid , 281 C0-C2 Cyclohexane Kit Cyclohexanethiol Cyclohexene Cyclohexylacetic acid Cyclohexylbutyric acid Cyclohexyl-4,6-dinitrophenol Cyclohexyl-5-methylphenol Cyclohexyloctadecanoic acid Cyclohexylpentanoic acid /4-Cyclohexylphenol Cyclohexylphenol Cyclohexylpropionic acid Cyclooctane Cyclopentadecane Cyclopentane , 235 Cyclopentanethiol Cyclopenta[l]phenanthrene Cyclopenta[def]phenanthrene Cyclopenta[def] phenanthren-4-one Cyclopenta[cd]pyrene Cyclopenta[cd]pyren-3(4)-one Cyclopentene Cyclopent[hi]indeno[4,3,2,1- cdef]chrysene Cyclopentyl-4-chlorophenol Cyclopentylmethylsulfide (+)-Cyclosativene beta-cyfluthrin Cygon Cylindrospermopsin m-cymene o-cymene p-cymene beta-cypermethrin Cypermethrin Cyproconazole ,4-D , 369 (20R/20S)-Dammarane (50/50) Dansylchloride-d ,4-DB , 369 2,4-DB methyl ester o,p -DDD ,4 -DDD ,4 -DDD , 369 2,4 -DDE ,4 -DDE , 369 o,p -DDE ,4 -DDT , 369 4,4 -DDT , 369 o,p -DDT Decabromodiphenyl , 360 Decabromodiphenylethane Decabromodiphenyl ether Decacyclene Decafluorobiphenyl Decahydronaphthalene pentanoic acid Decahydroquinoline cis-decaline trans-decaline Decaline (cis+trans) Decaline Kit n-decane , 230, 430 n-decane-d Decanethiol (96%) Decanethiol (99%) Decanoic acid (Capric) Decanol Decene n-decylbenzene n-decylcyclohexane n-Decylthiophene Deepoxydeoxynivalenol Dehydroabietic acid Dehydroabietine Delnav Deltamethrin Demeton S Deoxynivalenol Deoxynivalenol - BSA Conjugate Deoxynivalenol-3-glucoside Descarbamoylgonyautoxin-2 and Descarbamoylneosaxitoxin Descarbamoylsaxitoxin Desethylterbuthylazine-d9 (tert-butyl-d9) Desisopropylatrazine-d5 (ethyl-d5) Desmethyldiazepam Desmethyl spirolide C Dexamethasone , 412 U{13C15}-Dexoynivalenol DA , 428 Diacenaphthyleno[1,2-b Diacetoxyscirpenol N,-Diacetyl-4-aminophenol (20R)-13(17)-Diacholestene (20S)-13(17)-Diacholestene α()-30-Diahopane , α()-30-Diahop-13(14)-ene Diamantane Diamantane Kit ,4-Diaminoanisole ,3 -Diaminobenzidine ,4 -Diaminobiphenyl ,3-Diaminobiphenyl 2Cl ,4-Diaminobiphenyl 2Cl ,6-Diaminocarbazole ,7-Diaminofluorene ,5-Diaminonaphthalene ,8-Diaminonaphthalene ,3-Diaminonaphthalene ,3-Diaminopyrene ,6-Diaminopyrene ,8-Diaminopyrene ,4-Diaminotoluene Diamyl phthalate C26 Diaromatic sterane Diaromatic sterane Kit C27/C28 Diaromatic steranes Diasterene Kit Diazepam Diazinon Diazinon-d10 (diethyl-d10) Dibenz[a,c]acridine Dibenz[a,h]acridine Dibenz[a,i]acridine Dibenz[a,j]acridine Dibenz[c,h]acridine Dibenz[a,c]anthracene Dibenz[a,h]anthracene Dibenz[a,j]anthracene Dibenz[a,h]anthracene-d Dibenz[bc,kl]coronene Dibenzo[cd,pg]bisanthene ()-Dibenzo[a,i]carbazole Dibenzo[c,g]carbazole Dibenzocarbazole Kit Dibenzo[b,def]chrysene Dibenzo[b,k]chrysene , 325 Dibenzo[g,p]chrysene Dibenzo[a,j]coronene Dibenzo[bc,ef]coronene , 335 Dibenzo-p-dioxin Dibenzo-p-dioxin-d , 358 Dibenzo[a,e]fluoranthene Dibenzo[a,k]fluoranthene Dibenzo[b,ghi]fluoranthene Dibenzo[b,k]fluoranthene Dibenzo[j,l]fluoranthene Dibenzofuran Dibenzofuran-d Dibenzo[lmbrs]naphtha[3,2,1,8,7- defgh]phenanthro[3,4,5-yzab] pyranthrene Dibenzo[cd,n]naphtho [3,2,1,8-pqra]perylene Dibenzo[a,c]pentacene Dibenzo[a,l]pentacene Dibenzo[h,rst]pentaphene Dibenzo[h,s]peropyrene Dibenzo[b,ghi]perylene Dibenzo[e,ghi]perylene Dibenzo[2, Dibenzo[lm,yz]pyranthrene Dibenzo[a,e]pyrene Dibenzo[a,h]pyrene , 325 Dibenzo[a,i]pyrene , 323 Dibenzo[a,l]pyrene Dibenzo[e,l]pyrene Dibenzo[a,h]pyrene , 325 Dibenzo[a,i]pyrene-d Dibenzo[a,i]pyrene[5,8]quinone Dibenzo[cde:opq]rubicene Dibenzosuberone , 403 Dibenzo[a,j]tetracene Dibenzo[a,l]tetracene Dibenzothiophene Dibenzothiophene-d C0-C1 Dibenzothiophene Kit C3 Dibenzothiophene Kit C4+ Dibenzothiophene Kit Dibenzothiophene sulfone Dibenz[a,c]pentacene Dibenzyl phthalate Dibrom ,4-Dibromoanisole ,6-Dibromoanisole , 381 1,2-Dibromobenzene ,3-Dibromobenzene ,4-Dibromobenzene ,2 -Dibromobiphenyl ,4-Dibromobiphenyl ,5-Dibromobiphenyl , 424 2,6-Dibromobiphenyl ,4 -Dibromobiphenyl ,2-Dibromo-3-chloropropane ,8-Dibromodibenzothiophene ,2-Dibromoethane Dibromomethane ,4-Dibromonaphthalene ,6-Dibromonaphthalene ,7-Dibromonaphthalene Dibromoneopentylglycol Indexes 437

440 Product name Pg. Product name Pg. Product name Pg. 4,4 -Dibromooctafluorobiphenyl ,3-Dibromophenol ,4-Dibromophenol , 381 2,5-Dibromophenol ,6-Dibromophenol ,4-Dibromophenol-3,5,6-d ,4-Dibromophenol-PFB ,5-Dibromophenol-PFB Di-n-butyldiethyltin Di-n-butyldisulfide Di-tert-butyldisulfide ,6-Di-(tert-butyl-1-d1)- 4-methyl-d3-phenol-3,5-d ,6-Di-(tert-butyl-d9)-4- methylphenol-3,5-d2, D ,6-Di-tert-butyl-4-ethylphenol ,6-Di-tert-butyl-2-methylphenol ,6-Di-tert-butyl-4-methylphenol ,6-Di-tert-butyl-4-methylphenol-d ,7-Di-tert-butylnaphthalene ,5-Dibutylnonane ,4-Di-sec-butylphenol ,4-Di-tert-butylphenol ,6-Di-sec-butylphenol ,6-Di-tert-butylphenol ,5-Di-tert-butylphenol Di-n-butyl phthalate Di-n-butyl phthalate-3,4,5,6-d Di-n-butylsulfide Di-tert-butylsulfide Di-n-butyltin dichloride Dicamba , 369 Dichlobenil Dichlofenthion Dichlofluanid Dichlone Dichloran Dichloroalkane Kit ,2-Dichlorobenzene ,3-Dichlorobenzene ,4-Dichlorobenzene ,4-Dichlorobenzene-d ,3 -Dichlorobenzidine ,6-Dichlorobenzonitrile ,5-Dichlorobiphenyl ,4 -Dichlorobiphenyl ,1-Dichloro-2,2-bis (4-Chlorophenyl-d4)ethane ,1-Dichloro-2,2-bis (4-Chlorophenyl-d4)ethylene ,4-Dichlorobutane ,5-Dichloro-4-tert-butylphenol ,2-Dichlorodecane ,7-Dichlorodibenzo-p-dioxin ,8-Dichlorodibenzofuran Dichlorodifluoromethane ,4-Dichloro-3,5-dimethylphenol ,12-Dichlorododecane ,2-Dichlorododecane ,1-Dichloroethane ,2-Dichloroethane cis-1,2-dichloroethene trans-1,2-dichloroethene ,1-Dichloroethylene ,8-Dichlorohexadecanoic acid Dichloromethane , 365 2,4-Dichloro-6-methylphenol ,4-Dichloronaphthalene ,5-Dichloronaphthalene ,3-Dichloronaphthalene ,6-Dichloronaphthalene ,7-Dichloronaphthalene ,4-Dichloro-6-nitroanisole ,6-Dichloro-4-nitroanisole ,4-Dichloro-6-nitrophenol ,6-Dichloro-4-nitrophenol ,2-Dichlorononane ,10-Dichlorooctadecanoic acid ,2-Dichlorooctane ,3-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol ,6-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol ,4-Dichlorophenol-3,5,6-d Dichlorophenol Kit (2,4-Dichlorophenoxy-3,5,6-d3) butyric Acid ,2-Dichloropropane ,3-Dichloropropane ,2-Dichloropropane ,1-Dichloropropene cis-1,3-dichloropropene trans-1,3-dichloropropene ,2-Dichlorotetradecane ,2-Dichlorotridecane ,2-Dichloroundecane Dichlorprop Dichlorprop methyl ester Dichlorvos Dichlorvos-d6 (dimethyl-d6) Diclobenil Dicodeine sulfate Dicofol Dicoronylene Dicoronylene Dicrotophos Dicyanodiamide Dicyclohexyl phthalate Di-n-decyldisulfide Didrin Dieldrin ,2-Diethylbenzene ,3-Diethylbenzene ,4-Diethylbenzene ,6-Diethyldibenzothiophene Diethyldisulfide Diethylene glycol , 373 Diethylene glycol mono (p-nonylphenyl) ether Diethylene glycol mono(p-noctylphenyl)ether Diethyl phthalate Diethyl phthalate-3,4,5,6-d Diethylstilbestrol Diethylsulfide ,7-Diethyl-1,1,4,4- tetramethyltetraline ,4-Diethylthioxanthone Diflufenican Diflufenican-d3 (3-trifluoromethylphenoxy-2,4,6-d3) Difluorantheno [3.5,4.6],[4.6,9.11]coronene m-difluorodiphenyldisulfide ,4 -Difluorodiphenyl ether ,3 -Difluorodiphenyl ether ,4 -Difluoro-2,3,3,4,5,5,6,6 - ctabromodiphenyl ether ,5 -Difluoro-2,2,4,4 - tetrabromodiphenyl ether Di-n-heptyldiethyltin Di-n-heptyldisulfide Di-n-heptyltin dichloride Di-n-hexyldisulfide Di-n-hexyl phthalate ,10-Dihydroanthracene ,3-Dihydrobenzofuran ,4-Dihydrobenzo[ghi]perylene...243, 328 4,5-Dihydrobenzo[a]pyrene , 322 9,10-Dihydrobenzo [a]pyren-7(8)-one ,11-Dihydro-5-dibenz[b,f]azepine ,6-Dihydrodicyclopentadiene ,3-Dihydro-2-methylbenzofuran ,4-Dihydro-6-methyl- 2(1)-quinolinone ,2-Dihydronaphthalene ,10-Dihydrophenanthrene ,2-Dihydro-3,5,8- trimethylnaphthalene (2,4-Dihydroxybenzoyl) benzoic acid ,4 -Dihydroxybiphenyl trans-1,2-dihydroxy-1,2- dihydronaphthalene trans-1,2-dihydroxy-1,2- dihydrophenanthrene trans-9,10-dihydroxy-9,10- dihydrophenanthrene ,3-Dihydroxynaphthalene Diindeno[4,3,2,1-cdef Di-iso-butyl phthalate , 382 Di-iso-butyl phthalate-3,4,5,6-d Di-iso-decyl phthalate Di-iso-nonyl adipate Di-iso-nonyl phthalate (isomer mixture) Di-iso-octyl adipate Diisopentyldisulfide Diisopropyl ether ,6-Diisopropylnaphthalene ,4-Diisopropylphenol ,5-Diisopropylphenol ,6-Diisopropylphenol Diisopropylsulfide ,4-Dimercaptotoluene Dimethoate Dimethoate-d6 (,-dimethyl-d6) ,3 -Dimethoxybenzidine ,2-Dimethoxyethane ,2-/1,4-Dimethyladamantane ,3-Dimethyladamantane Dimethylamine ,6-Dimethyl-4-anisole ,2-Dimethylanthracene ,3-Dimethylanthracene ,4-Dimethylanthracene ,5-Dimethylanthracene ,3-Dimethylanthracene ,7-Dimethylanthracene ,10-Dimethylanthracene Dimethylanthracene Kit Dimethyl azelate ,10-Dimethylbenz[c]acridine ,9-Dimethylbenz[c]acridine

441 Product name Pg. Product name Pg. Product name Pg. 3,9-Dimethylbenz[a]anthracene ,12-Dimethylbenz[a]anthracene ,2-Dimethylbenzene ,3-Dimethylbenzene ,4-Dimethylbenzene ,3 -Dimethylbenzidine ,4-Dimethylbenzoic acid ,10-Dimethylbenzo[a]pyrene ,4-Dimethylbenzo[h]quinoline ,3-Dimethylbenzothiophene ,4-/2,6-Dimethylbenzothiophene ,5-Dimethylbenzothiophene ,5-Dimethylbenzothiophene Dimethylbenzothiophene Kit ,4 -Dimethylbibenzyl ,2 -Dimethylbiphenyl ,3 -Dimethylbiphenyl ,4 -Dimethylbiphenyl ,2-Dimethylbutane ,3-Dimethylbutane ,3-Dimethyl-2-butanethiol ,1-Dimethylcyclohexane cis-1,2-dimethylcyclohexane cis-1,3-dimethylcyclohexane cis-1,4-dimethylcyclohexane trans-1,2-dimethylcyclohexane trans-1,3-dimethylcyclohexane trans-1,4-dimethylcyclohexane ,1-Dimethylcyclopentane cis-1,2-dimethylcyclopentane cis-1,3-dimethylcyclopentane trans-1,2-dimethylcyclopentane trans-1,3-dimethylcyclopentane ,3-Dimethyldecane ,6-Dimethyldecane ,6-Dimethyldiamantane ,2-Dimethyldibenzothiophene ,3-Dimethyldibenzothiophene ,4-Dimethyldibenzothiophene ,3-Dimethyldibenzothiophene ,4-Dimethyldibenzothiophene ,6-Dimethyldibenzothiophene ,8-Dimethyldibenzothiophene ,6-Dimethyldibenzothiophene ,6-Dimethyldibenzothiophene Dimethyldibenzothiophene Kit ,4-Dimethyldiphenylsulfide ,5-Dimethyldiphenylsulfide ,4-Dimethyldiphenylsulfide Dimethyldisulfide Dimethyl-d6 tetrachloroterephthalate ,2-Dimethyl-3-ethylbenzene ,2-Dimethyl-4-ethylbenzene ,3-Dimethyl-2-ethylbenzene ,3-Dimethyl-5-ethylbenzene ,4-Dimethyl-2-ethylbenzene ,9-Dimethyl-7-ethylphenanthrene/ 1,9-Dimethyl-5-ethylphenanthrene ,7-Dimethylfluorene N,N-Dimethylformamide dimethyl acetal ,1-Dimethylguanidine Dimethylguanidine ,2-Dimethylheptane ,3-Dimethylheptane ,4-Dimethylheptane ,5-Dimethylheptane ,6-Dimethylheptane , 229 3,3-Dimethylheptane ,4-Dimethylheptane ,5-Dimethylheptane ,4-Dimethylheptane Dimethylheptylbenzene (Isomer mixture) ,2-Dimethylhexane ,3-Dimethylhexane ,4-Dimethylhexane ,5-Dimethylhexane ,3-Dimethylhexane ,4-Dimethylhexane ,5-Dimethyl-1-hexene ,4-Dimethyl-6-isooctylphenol ,3-Dimethyl-5-(4-methylpentyl) naphthalene ,2-Dimethylnaphthalene ,3-Dimethylnaphthalene ,4-Dimethylnaphthalene ,5-Dimethylnaphthalene ,6-Dimethylnaphthalene ,7-Dimethylnaphthalene ,8-Dimethylnaphthalene ,3-Dimethylnaphthalene ,6-Dimethylnaphthalene ,7-Dimethylnaphthalene ,8-Dimethylnaphthalene-d ,6-Dimethylnaphthalene-d ,4-Dimethyl-2-neopentyl-1-pentene ,6-Dimethyl-4-nitrophenol ,3-Dimethyloctane ,6-Dimethyloctane , 230 2,7-Dimethyloctane ,3-Dimethyloctane ,5-Dimethyloctane ,6-Dimethyloctane ,4-Dimethyloctane ,5-Dimethyloctane ,2-Dimethylpentane ,3-Dimethylpentane ,4-Dimethylpentane ,3-Dimethylpentane ,2-Dimethylphenanthrene ,3-Dimethylphenanthrene ,4-Dimethylphenanthrene ,5-/1,7-Dimethylphenanthrene ,6-Dimethylphenanthrene ,7-Dimethylphenanthrene ,8-Dimethylphenanthrene ,9-Dimethylphenanthrene ,10-/4,10-Dimethylphenanthrene ,4-Dimethylphenanthrene ,6-/3,5-Dimethylphenanthrene ,7-Dimethylphenanthrene ,9-/4,9-Dimethylphenanthrene ,10-Dimethylphenanthrene ,6-Dimethylphenanthrene ,9-Dimethylphenanthrene ,10-Dimethylphenanthrene ,3-/3,4-Dimethylphenanthrene ,5/2,7-Dimethylphenanthrene ,5-/2,7-/4,5-Dimethylphenanthrene Dimethylphenanthrene Kit ,3-Dimethylphenol ,4-Dimethylphenol ,5-Dimethylphenol ,6-Dimethylphenol ,4-Dimethylphenol ,5-Dimethylphenol ,4-Dimethylphenol-3,5,6-d ,4-Dimethylphenol-d ,6-Dimethylphenol-3,5,6-d ,4-Dimethylphenol-2,5,6-d Dimethyl phthalate Dimethyl phthalate-3,4,5,6-d ,9-Dimethylpicene ,4-Dimethyl-5-propylnaphthalene Dimethyl pseudomorphine ,3-Dimethylpyrazine ,5-Dimethylpyrazine ,6-Dimethylpyrazine ,7-Dimethylpyrene ,5-Dimethylpyrene ,3-Dimethylquinoline ,4-Dimethylquinoline ,6-Dimethylquinoline ,7-Dimethylquinoline ,8-Dimethylquinoline ,6-Dimethylquinoline Dimethylsulfide ,4-Dimethyltetraline ,8-Dimethyltetraline ,6-Dimethyltetraline ,7-Dimethyltetraline ,7-Dimethyltetraline ,4-Dimethylthieno[2,4-b]thiophene ,3-Dimethylthiophene ,4-Dimethylthiophene ,5-Dimethylthiophene ,4-Dimethylthiophene ,4-Dimethylthiophenol ,5-Dimethylthiophenol ,6-Dimethylthiophenol ,4-Dimethylthiophenol ,5-Dimethylthiophenol ,6-Dimethylundecane , 230 Dimorphine sulfate Dinaphtho[8,1,2-abc Dinaphtho[1,2-b Dinaphtho[1,2-b Dinaphtho[1,2-b Dinaphtho[2,1-b Dinaphtho[2,1-b Dinaphtho[2,3-b Dinaphtho[2,1,8,7-defg Dinaphtho[2,1,8,7-defg Dinaphtho[2,1-b ,4-Dinitroanisole ,5-Dinitroanisole ,6-Dinitroanisole ,9-Dinitroanthracene ,10-Dinitroanthracene ,3 -Dinitrobenzidine ,2 -Dinitrobiphenyl ,4 -Dinitrobiphenyl ,6-Dinitro-o-cresol ,7-Dinitrofluorene ,4-Dinitro-6-methylanisole ,6-Dinitro-2-methylphenol ,5-Dinitronaphthalene ,4-Dinitro-1-naphthol ,4-Dinitrophenol ,5-Dinitrophenol ,6-Dinitrophenol ,4-Dinitrophenol-3,5,6-d ,3-Dinitropyrene ,6-Dinitropyrene ,8-Dinitropyrene ,4 -Dinitro-p-terphenyl Indexes 439

442 Product name Pg. Product name Pg. Product name Pg. Di-n-nonyl adipate Di-n-nonyl phthalate Dinophysis toxin Dinoseb , 379 Dinoseb , 379 (20R,23R,24R)-Dinosterane (20R,23R,24S)-Dinosterane Dinosterane Dinosterane Kit Dinosterane Kit Dinoterb , 379 Dinoterb , 379 Di-n-octadecyldisulfide Di-n-octyl adipate Di-n-octyldiethyltin Di-n-octyldisulfide ,9-Di-n-octylfluorene Di-n-octyl phthalate Di-n-octyl phthalate-3,4,5,6-d Di-n-octylsulfide Di-n-octyltin dichloride Dioxathion Di-n-pentyldisulfide ,4-Di-tert-pentylphenol Di-n-pentylphthalate Di-n-pentyl phthalate-3,4,5,6-d ,7.8-Di-(peri-naphthylene)-pyrene Diphenanthro[9,10-b Diphenylamine ,10-Diphenylanthracene ,7-Diphenylbenzo[ghi]fluoranthene ,3-Diphenylbenzo[c]thiophene Diphenyldiethyltin Diphenyldisulfide Diphenyl isophthalate Diphenyl phthalate Di-(3-phenyl-1-propyl)amine , 388 Diphenylsulfide Diphenylsulfide Kit ,4 -Diphenyltetrathiafulvalene Diphenyltin dichloride Di-n-propyldisulfide Di-n-propylsulfide Diquat dibromide-d Diquat Dibromide monohydrate Disulfoton Disyston Dithane M ,3-Dithiane ,4-Dithiane ,2 -Dithienyl Di(2-thienyl)disulfide Diuron Diuron-d6 (dimethyl-d6) ,4-D methyl ester , ,16-Docosadienoic acid Docosahexaenoic acid n-docosane , 231, 430 n-docosane-d Docosanoic acid (Behenic) ,7,10,13,16-Docosapentaenoic acid Docosapentaenoic acid ,16,19-Docosatrienoic acid Docosenoic acid trans-Docosenoic acid n-dodecane , 230, 430 n-dodecane-d Dodecanoic acid (Lauric) Dodecene-1 LAS Dodecenoic acid n-dodecylbenzene n-dodecylbenzene-d Dodecylbenzenesulfonic acid, mixture of C n-Dodecylbenzoic acid n-Dodecyl-p-cresol n-Dodecyl-o-cresol n-dodecylcyclohexane n-Dodecylnaphthalene n-Dodecylphenol n-Dodecylthiophene Domoic acid n-dopentacontane , 232 n-dotetracontane , 232 n-dotriacontane , 232, 431 n-dotriacontane-d Dual Dursban,ethyl Dyfonate ,14-Eicosadienoic acid n-eicosane , 231, 430 n-eicosane-d Eicosanoic acid (Arachidic) Eicosapentaenoic acid Eicosatetraenoic acid ,11,14-Eicosatrienoic acid Eicosenoic acid Eicosenoic acid Eicosenoic acid trans-Eicosenoic acid Eleaidic alpha-endosulfan beta-endosulfan Endosulfan Endosulfan alcohol Endosulfan-I-d Endosulfan-II-d Endosulfan sulfate Endrin EPA , 428 EPA-PAs, Cocktail EPA-PAs, Cocktail EPA-PAs, Cocktail EPN Epoxiconazole EPTC-d14 (dipropyl-d14) Ergocornine Ergocryptine Ergostane Erucic , 428 Esfenvalerate Ethalfluralin ,2-Ethanediol Ethanethiol Ethanol , α-Ethinylestradiol , β-Ethinylestradiol Ethion Ethoprop Ethoprophos Ethoxyethanol Ethoxyethyl acetate Ethoxymethyl-4,6-dinitrophenol.370, Ethoxymethyl-4,6-dinitrophenol.370, 379 Ethyl acetate Ethyladamantane Ethyladamantane Ethylalkyl-/ Ethylaryltin Kit Ethylan Ethylanthracene Ethyl-9,10-anthraquinone Ethylbenzene Ethylbenzene-d Ethylbenzenethiol Ethylbenzofuran Ethylbenzoic acid Ethylbicyclo[2.2.1]heptane Ethylbiphenyl Ethyl butanoate Ethyl t-butyl ether Ethyl carbamate Ethylcarbazole Ethylcarbazole N-Ethylcarbazole-3-carboxaldehyde d2 C29 ααα (20R)-Ethylcholestane d4 C29 ααα (20R)-Ethylcholestane βαα (20R,24R)-24-Ethylcholestane αββ (20R,24R)-24-Ethylcholestane αββ (20S,24RS)-24-Ethylcholestane ααα (20R,24R)-24-Ethylcholestane , 251 ααα (20S,24RS)-24-Ethylcholestane Ethylcholestane isomer Kit Ethyl-5β()-cholestan-3β-ol Ethyl-5β()-cholestan-3α-ol Ethyl-5α()-cholestan-3α-ol Ethyl-5α()-cholestan-3β-ol (24S)-24-Ethylcholesta-3,5,22-triene (24S)-24-Ethylcholest-5,22-diene (24R)-24-Ethylcholest-2-ene (24R)-24-Ethylcholest-8(14)-ene Ethylcholest-5-en-3β-ol Ethylchrysene Ethylcoprostanol Ethyl-epi-coprostanol (24S)-24-Ethyl-3,5-cyclocholest-22-ene.253 Ethylcyclohexane Ethylcyclopentane Ethyl decanoate Ethyl 4-trans-decenoate Ethyldibenzothiophene Ethyldibenzothiophene Ethyl-3,5-dimethylpyrazine Ethyl-3,6-dimethylpyrazine Ethyl docosanoate Ethyl dodecanoate Ethyl eicosanoate Ethylene glycol Ethylene glycol mono (p-n-nonylphenyl) ether Ethylene glycol mono (p-nonylphenyl) ether Ethylene glycol mono (p-n-octylphenyl)ether Ethylene sulfide Ethylepicholestanol Ethyl ether Ethylfluoranthene Ethylfluorene d5-ethyl-β-d-6-glucuronide Ethyl-β-D-6-glucuronide Ethyl-4-fluorobenzene Ethylguaiacol Ethyl heneicosanoate Ethyl heptadecanoate Ethyl heptanoate Ethyl hexadecanoate

443 Product name Pg. Product name Pg. Product name Pg. Ethyl hexanoate Ethylhexanoic acid Ethylhexanoic acid-d Ethyl-1-hexanol Ethyl 12-hydroxystearate Ethyl-3-methoxypyrazine Ethyl-3-methyladamantane Ethyl-3-methylbenzene Ethyl-4-methylbenzene Ethyl-1-methylbenzene Ethyl-1-methylcyclopentane Ethyl-6-methyldibenzothiophene Ethyl-6-methylnaphthalene Ethyl-5-methylphenol Ethyl-4-(2-methylpropyl)benzene 237, Ethyl-3-methylpyrazine Ethyl-5-methylpyrazine Ethylmethylsulfide Ethyl-5-methylthiophene Ethylmorphine hydrochloride Ethylnaphthalene Ethylnaphthalene Ethyl-3-nitrocarbazole Ethyl nonadecanoate Ethylnonane Ethyl nonanoate N-Ethyl,N-(3-phenylpropyl)-3- (4-hydroxyphenyl)propylamine...286, 388 Ethyl octadecanoate Ethyl octanoate Ethyl pentadecanoate Ethylpentane Ethyl pentanoate Ethylphenanthrene Ethylphenanthrene Ethylphenol Ethylphenol Ethylphenol , Ethylphenol-d Ethylphenol-2,3,5,6-d4, D Ethylphenol-d4-PFB Ethylphenol-d9-PFB (2RS)-2-(4-Ethylphenyl)propanoic acid.404 Ethylphenylsulfide Ethyl propanoate Ethyl-n-propylsulfide Ethylpyrazine Ethylpyrene Ethyl tetracosanoate Ethyl tetradecanoate Ethyltetraline Ethyltetraline Ethyltetraline Ethyl tetranoate Ethylthiophene Ethylthiophene Ethylthiophenol Ethylthiophenol Ethyl-β-D-6-triacetyl glucuronic acid methyl ester Ethyl trianoate Ethyltri-n-butyltin Ethyl tricosanoate Ethyltricyclohexyltin Ethyl tridecanoate Ethyltripentyltin Ethyltriphenyltin Ethyltri-n-propyltin Ethyl undecanoate Ethyl viologen-d8 dichloride (rings-d8).367 Etinofen , 379 Etinofen , 379 Eudalene Eugenol , 425 Farnesane , 230 F-BTEX Kit Fenamiphos sulfoxide Fenchlorphos L-(-)-Fenchone Fenitrothion Fenitrothion-d6 (,-dimethyl-d6) Fenoprop Fenoprop methyl ester Fenpropathrin Fenson Fenthion Fenthion-d6 (,-dimethyl-d6) Fenuron Fenvalerate Ferbam Fern-9(11)-ene Fichtelite Fluazifop Flumethasone , 413 Fluometuron Fluoranthene Fluoranthene and Alkylfluoranthene Kit.317 Fluoranthene-d Fluorene Fluorene-d Fluorenone Fluoroacenaphthylene Fluorobenzene Fluorobenzo[k]fluoranthene Fluorobiphenyl Fluorobiphenyl Fluorochrysene Fluorochrysene Fluorodibenzothiophene Fluoro-3,5-dichlorobiphenyl Fluoro-4,4 -dichlorobiphenyl Fluorodiphenyl ether Fluorodiphenyl ether Fluorodiphenylmethane Fluorodiphenylmethane Fluorofluoranthene Fluorofluorene Fluoro-3-hydroxychrysene Fluoro-4-hydroxychrysene Fluoro-2-hydroxychrysene Fluoro-4-hydroxy-2-methylquinoline Fluoro-6-hydroxyphenanthrene Fluoroindole Fluoro-3-methoxychrysene Fluoro-2-methoxychrysene Fluoro-4-methoxychrysene Fluoro-1-methoxychrysene Fluoro-3-methylbenzo[b]thiophene Fluoro-5-methylchrysene Fluoro-6-methylnaphthalene Fluoro-6-methylphenanthrene Fluoro-2-methylphenol Fluoro-3-methylphenol Fluoro-2-methylphenol-PFB Fluoro-3-methylphenol-PFB Fluoro-2-methylquinoline Fluoronaphthalene Fluoro-2,2,3,3,4,5,5,6,6 - nonabromodiphenyl ether Fluoro-2,3,3,4,4 - pentachlorobiphenyl Fluorophenanthrene Fluorophenanthrene Fluorophenol Fluorophenol-PFB ,4-Fluoropropane Fluoropyrene Fluoro-2,2,4,4 - tetrabromodiphenyl ether Fluoro-2,3,4,4 - tetrabromodiphenyl ether Fluoro-2,2,5,5 -tetrachlorobiphenyl Fluoro-3,3,4,4 -tetrachlorobiphenyl Fluoro-2,2,4,4 -tetrachlorobiphenyl Fluoro-2,3,4,5-tetrachlorobiphenyl..354 m-fluorotoluene o-fluorotoluene p-fluorotoluene Fluoro-2,4,4 -tribromodiphenyl ether Fluoro-2,3,4 -trichlorobiphenyl Fluoro-3,4,4 -trichlorobiphenyl Fluoro-3,4,5-trichlorobiphenyl Fluoro-2,4,4 -trichlorobiphenyl Fluoro-2,4,5-trichlorobiphenyl Fluoro-2,4,6-trichlorobiphenyl Fluoro-2,4,6-trichlorobiphenyl Fluoro-2,4,6-trichlorobiphenyl Fluoro-o-xylene Fluoro-o-xylene Flurochloridone tau-fluvalinate Folpet Fonofos Friedelane Friedelan-3β-ol Friedelan-3α-ol Friedelin [5,6]Fullerene-C [5,6]Fullerene-C Fumonisin B Fumonisin B Fumonisin B U{13C34}Fumonisin B Fumosinin Mixture (FB1 & FB2) Furan Furan-d Fusarenon-X , 421 Gadolenic Galaxolide Gammacerane Gamma Linolenic , 428 GC-IRMS Standard Kit GC-IRMS Standards (C11, C15, C20)..431 GC-IRMS Standards (C15, C20, C25)..431 GC-IRMS Standards (C25, C30, C36)..431 GC-IRMS Standards (C25, C30, C36, C40) (+/-)-Geosmine Glutaric acid Goal Gonyautoxin-5 (akab1) Gonyautoxin-1 and Gonyautoxin-2 and Guaiacol , 425 Guaiazulene Gymnodimine aloxyfop Indexes 441

444 Product name Pg. Product name Pg. Product name Pg. epsilon-c (BC) alpha-c (BC) beta-c (BC) delta-c (BC) gamma-c (BC) ead-to-tail Isoprenoid Kit eavy White Mineral il, sulfurdepleted (5)elicene (6)elicene (4)elicene eliotrine C2 Phenanthrene Kit endecanoic ,15-eneicosadienoic acid n-eneicosane , 231, 430 n-eneicosane-d eneicosanoic acid eneicosenoic acid n-entetracontane , 232 n-entriacontane , 232 2,2,3,4,4,5,6 - eptabromodiphenyl ether eptachlor eptachlor-endo-epoxide (trans-) eptachlor-exo-epoxide (cis-) ,2,3,4,4,5,5 -eptachlorobiphenyl ,3,3,4,4,5,5 -eptachlorobiphenyl eptacosa n-eptacosane , 231, 431 n-eptadecane , 231, 430 n-eptadecane-d eptadecanoic acid (Margaric) eptadecenoic acid trans-eptadecenoic acid n-eptadecylbenzene n-eptadecylcyclohexane eptafluorobutyramide eptafluorobutyric acid eptafluorobutyric anhydride ,2,4,4,6,8,8-eptamethylnonane n-eptane , 229, 432 n-eptane-d eptanethiol eptanoic acid (Enantic) eptanol eptanol eptanone eptanone n-eptanophenone eptaphene n-eptatriacontane , eptene cis-2-eptene cis-3-eptene trans-2-eptene trans-3-eptene n-eptylbenzene n-eptylbenzoic acid n-eptylbiphenyl n-eptylcyclohexane eptylcyclohexanecarboxylic acid n-eptylphenol n-eptylthiophene exabromobenzene , 360 2,2,4,4,5,5 -exabromobiphenyl ,2,4,4,6,6 -exabromobiphenyl ,3,4,4,5,5 -exabromobiphenyl ,2,4,4,5,5 -exabromodiphenyl ether.359 2,2,4,4,5,6 -exabromodiphenyl ether.359 exachloroalkane Kit exachlorobenzene , 370 exachlorobenzene-13c ,2,3,4,4,5 -exachlorobiphenyl ,2,3,4,4,5-exachlorobiphenyl ,2,3,4,5,6-exachlorobiphenyl ,2,3,4,5,6 -exachlorobiphenyl ,2,4,4,5,5 -exachlorobiphenyl ,2,4,4,6,6 -exachlorobiphenyl ,3,3,4,4,5 -exachlorobiphenyl ,3,3,4,4,5-exachlorobiphenyl ,3,4,4,5,5 -exachlorobiphenyl ,3,4,4,5,6-exachlorobiphenyl ,3,4,4,5,5 -exachlorobiphenyl exachloro-1,3-butadiene ,1,1,3,9,10-exachlorodecane ,1,1,3,11,12-exachlorododecane ,1,1,3,8,9-exachlorononane ,1,1,3,7,8-exachlorooctane exachlorophene ,1,1,3,12,13-exachlorotridecane ,1,1,3,10,11-exachloroundecane n-exacontane , 232 n-exacosane , 231, 431 n-exacosane-d exacosanol exadecahydropyrene , 322 n-exadecane , 231, 430 n-exadecane-d exadecanoic acid (Palmitic) exadecenoic acid trans-exadecenoic acid n-exadecylbenzene n-exadecylcyclohexane n-exadecylthiophene ,5-exadiene ,4-exadienoic acid exaethylbenzene ,2,3,4,5,6-exahydrochrysene , 326 exahydronaphthalene , 239 1,2,3,3a,4,5-exahydropyrene , 321 1,2,3,6,7,8-exahydropyrene , 322 examethylbenzene ,1,1,3,3,3-examethyldisilazane n-exane , 229, 432 n-exane-d ,2-exanediol exanethiol exanoic acid (Caproic) exanol exanol exanol exanone exanone n-exanophenone n-exapentacontane , 232 n-exatetracontane , 232 n-exatriacontane , 232, 431 n-exatriacontane-d exazinone exene cis-2-exene trans-2-exene n-exylbenzene n-exylbenzoic acid n-exylbiphenyl n-exylcyclohexane exyl 2-ethylhexyl phthalate n-exylnaphthalene n-exylperylene n-exylphenol n-exylthiophene omogamma Linolenic , β(),21β()-(22RS)-omohopane β(),21α()-(22RS)-omohopane α(),21β()-(22R)-omohopane α(),21β()-(22RS)-omohopane α(),21β()-(22S)-omohopane α(),21α()-(22RS)-omohopane..263 omohopane Kit , 267 (22R)-30-omohop-17(21)-ene β(),21β()-opane , β(),21α()-opane α(),21β()-opane α(),21α()-opane , 262 C30 opane Kit opane Kit , 267 op-17(21)-ene op-21(22)-ene op-22(29)-ene opene/fernene Kit β(),21β()-op-22(29)-en-3-one β()-op-21(22)-en-3-one T-2 Toxin U{13C22}-T-2 Toxin U{13C24}-T-2 Toxin ydrindantin ydrogensulfide ydroxy-9,10-anthraquinone ydroxybenzoic acid , ydroxybenzo[a]pyrene ydroxycarbazole ydroxycarbazole ydroxycarbazole Kit ydroxychrysene ydroxychrysene ydroxychrysene ydroxychrysene ydroxycodeine ydroxycodeine ydroxydibenzofuran ydroxydibenzothiophene (1-ydroxyethyl)-4- (2-methylpropyl)benzene ydroxyfluorene ydroxyfluorene ydroxy-9-fluorenone ydroxy-9-fluorenone (3α()+3bβ()),17β(),21β()-3- ydroxyhopane β(),21β()-22-ydroxyhopane β(),17β(),21β()-3-ydroxyhopane β(),21β()-22-ydroxyhopane ydroxyhopanone ydroxy-1-indanone ydroxy-11-indolo[2,3-f] naphthalene ydroxyisophthalic acid , ydroxyisoquinoline ydroxyoctadecenoic acid ydroxy-1-phenalen-1-one ydroxyphenanthrene ydroxyphenanthrene ydroxyphenanthrene ydroxyphenanthrene ydroxyphenanthrene ydroxyphenanthrene Kit

445 Product name Pg. Product name Pg. Product name Pg. 2-(4-ydroxyphenyl)acetamide ydroxyphenylacetic acid cis-4-(2-ydroxyphenyl)- 2-oxobut-3-enoic acid N-(4-ydroxyphenyl)-propionamide [4-[(2RS)-2-ydroxy-3[(1-methylethyl) amino]propoxy]phenyl]acetonitrile ydroxypyrene ydroxypyrene-d ydroxystearic acid C2 Dibenzothiophene Kit Ibuprofen Imazalil Imbentin Kit Imbentin-N/020 (n=0-4) Imbentin-N/040 (n=1-7) Imbentin-N/040 (n=2-9) Imidan Indan Indeno- and dibenzofluoranthenes Kit..318 Indeno[1,2,3-cd]fluoranthene Indeno[1,2,3,-cd]fluoranthene-d Indeno[1,2,3-cd]pyrene Indeno[1,2,3-cd]pyrene-d Indurene Ioxynil Iprodione d2 Isoadiantane Isoadiantone Isobenzan Isobutylbenzene Isobutylbenzoic acid Isobutylcyclopentane Isobutyl-3-methoxypyrazine Isobutyl-3-methylpyrazine Isobutylthiazole Isocaffeine Isocamphane Isodrin Isofenphos Isofenphos-des-N-isopropyl Isooctane/Toluene 3:1, sulfurdepleted Isooctane/Toluene 9:1, sulfurdepleted Isooctane, sulfurdepleted Isopentylphenol Isophthalic acid Isoprene Isopropanol , 432 Isopropyl acetate Isopropylbenzene Isopropylbenzene Isopropylcarbazole Isopropyl-9-Carbazole Isopropylcyclopentane Isopropyldecaline Isopropyl-5-methylphenol Isopropyl-3-methylphenol Isopropyl-2-methylphenol Isopropyl-3-methylphenol Isopropylnaphthalene Isopropylnaphthalene Isopropylphenol Isopropylphenol Isopropylphenol Isopropylphenol-d Isopropylphenol-d Isopropylphenol-d Isopropylthiophenol Isopropylthioxanthone Isopropylthioxanthone Isoproturon Isoproturon-d3 (N-methyl-d3) Isoquinoline Isoquinoline Kit Isoviolanthrene Isoviolanthrone ITX Kaltane Keto-β-boswellic acid , 418 Lake Michigan Study PBDEs (Kit w/single solutions) Lamotrigine Lamotrigine-2N-glucuronide Lannate Lanostane Lanosterol Lasiocarpine LAS Kit Lasso Lepidine Light White Mineral il, sulfurdepleted.432 Lignoceric Lindane , 370, 371 Lindane , 370, 371 Linoelaidic , 428 Linoleic , 428 Linolenic , 428 Linuron Linuron-d6 (dimethyl-d6) (+)-Longicyclene Lorazepam Lupane Lupane Kit Lup-20(29)-ene Lupene Kit Lupeol Lup-3-one Lycopane , 232 MAGME Malathion Malathion-d10 (diethyl-d10) Malathion-d6 (dimethyl-d6) Malonic acid Mancozeb Maneb MCPB MCPB-methyl ester Mecoprop , 371 Mecoprop methyl ester Medroxyprogesterone acetate α-d(+)-melibiose hydrate Mesitol Mesitylene Mesurol Metalaxyl Metamitron Metazachlor Metformin hydrochloride Methabenzthiazuron Methacrifos Methamidophos Methamidophos-d6 (dimethyl-d6) Methanol , 432 Methidathion Methiocarb Methional DL-Methionine Methomyl Methoxychlor o,p -Methoxychlor Methoxychrysene Methoxychrysene Methoxychrysene Methoxychrysene Methoxy-3-isopropylpyrazine Methoxy-5-methylaniline Methoxy-3-methylpyrazine Methoxynaphthalene (6-Methoxy-2-naphthyl)acetic acid Methoxyphenanthrene Methoxyphenanthrene Methoxyphenanthrene Methoxyphenanthrene Methoxyphenanthrene Methoxyphenanthrene Kit Methoxy-1-propyl acetate Methoxypyrazine Methoxy-4-vinylphenol d4 C28 ααα (20R)/C29 ααα (20R)- Methyl/Ethylcholestane Methyl acetate Methylacridine Methylacridine Methyl acrylamido glycolate methyl ether Methyladamantane Methyladamantane Methylalkane Kit Methylalkane Kit Methylanthanthrene Methylanthracene Methylanthracene Methylanthracene Methylanthracene-d Methyl-9,10-anthraquinone Methyl arachidate Methyl arachidonoate Methyl behenate Methylbenz[a]anthracene Methylbenz[a]anthracene Methylbenz[a]anthracene Methylbenz[a]anthracene Methylbenz[a]anthracene Methylbenz[a]anthracene Methyl-11()-benzo[a]carbazole Methyl-7()-benzo[c]carbazole Methyl-11()-benzo[a]carbazole Methyl-7()-benzo[c]carbazole Methyl-11()-benzo[a]carbazole Methyl-7()-benzo[c]carbazole Methylbenzofuran Methylbenzofuran Methylbenzo[b]naphtho[2,3-d] thiophene Methylbenzo[b]naphtho[2,3-d] thiophene Methylbenzo[a]pyrene Methylbenzo[a]pyrene Methylbenzo[f]quinoline Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbenzothiophene Methylbiphenyl Methylbiphenyl Indexes 443

446 Product name Pg. Product name Pg. Product name Pg. 4-Methylbiphenyl N-Methylbis(trifluoroacetamide) Methyl-1,3-butadiene Methylbutane , Methyl-1-butanethiol Methyl-2-butanethiol Methyl-1-butanethiol Methyl-2-butanethiol DL-3-Methyl-2-butanol Methyl-1-butene Methyl-2-butene Methyl-1-butene Methyl-2-buten-1-thiol (2-Methylbutyl)benzene Methyl t-butyl ether (1-Methylbutyl)phenol Methyl-n-butylsulfide Methyl-tert-butylsulfide Methyl butyrate Methyl caprate Methyl caproate Methyl caprylate Methylcarbazole Methylcarbazole Methylcarbazole Methylcholanthrene αββ (20R,24S)-24-Methylcholestane ααα (20R,24R)-24-Methylcholestane..250 ααα (20R,24S)-24-Methylcholestane ααα 4α/β-Methylcholestane ααα (20R,24R)-24-Methylcholestane and ααα (24R,24R)-24-Ethylcholestane Methylcholestane isomer Kit (24S)-24-Methylcholest-8(14)-ene ααα (24R)-24-Methylcholest-3-ene and ααα (24R)-Ethylcholest-3-ene Methylchrysene Methylchrysene Methylchrysene Methylchrysene Methylchrysene Methylchrysene Methylcodeine , Methylcodeine phosphate Methylcoronene Methylcycloheptane Methylcyclohexane Methylcyclopentane Methylcyclopenta[l]phenanthrene Methylcyclopentene Methyldecaline Methyldecane , Methyldecane , Methyldecane , 230 Methyl decanoate Methyldiamantane Methyldibenzofuran Methyldibenzofuran Methyldibenzofuran Methyldibenzothiophene Methyldibenzothiophene Methyldibenzothiophene Methyldibenzothiophene Methyldiphenylmethane Methyldiphenylmethane Methyldiphenylsulfide Methyldiphenylsulfide Methyldiphenylsulfide Methyl 13,16-docosadienoate Methyldocosane , 231 Methyl docosanoate Methyl 4,7,10,13,16-docosapentaenoate.428 Methyl 5,8,11,14,17-docosapentaenoate.428 Methyl 7,10,13,16-docosatetraenoate Methyl 13,16,19-docosatrienoate Methyl 13-docosenoate Methyl 13-trans-docosenoate Methyldodecane , 230 Methyl dodecanoate Methyl 11-dodecenoate Methyl 11,14-eicosadienoate Methyleicosane , 231 Methyl eicosanoate Methyl 11,14,17-eicosatrienoate Methyl 8,11,14-eicosatrienoate Methyl 11-eicosenoate Methyl 5-eicosenoate Methyl 8-eicosenoate Methyl 11-trans-eicosenoate Methyl enantate ,4 -Methylenebis(2-chloroaniline) ,4 -Methylenedianiline ααα (24R)-4α-Methyl-24- ethylcholestane Methylfluoranthene Methylfluoranthene Methylfluoranthene Methylfluorene Methylfluorene Methylfluorene Methylfluorene Methyl formate Methylguaiacol Methyl hendecanoate Methyl 12,15-heneicosadienoate Methylheneicosane , 231 Methyl heneicosanoate Methyl 12-heneicosenoate Methylheptadecane , Methylheptadecane , 231 Methyl heptadecanoate Methylheptane , Methylheptane , Methylheptane , 229 Methyl heptanoate Methyl-1-heptene Methylhexadecane , 231 Methyl hexadecanoate-d31 (Methyl palmitate) Methyl hexadecanoate-d31 (Methyl palmitate-d31) Methyl hexadecanoate α-Methyl-1,2,3,4,9,10- hexahydrophenanthrene (cis/trans) Methylhexane , Methylhexane , 229 Methyl hexanoate Methyl-1-hexene Methyl-1-hexylcyclohexane Methyl-1-hexylcyclohexane (cis + trans) Methyl-1-hexylcyclohexane (cis + trans) Methyl-4-tert-hexylphenol α,17α(),21β()-2-Methylhopane α,17α(),21α()-2-Methylhopane α,17β(),21β()-2-Methylhopane α,17β(),21α()-2-Methylhopane and 3-Methylhopanes Kit Methyl 12- hydroxy-9-octadecenoate Methyl 12-hydroxy-9-transoctadecenoate Methyl 12-hydroxystearate Methylindan Methylindene Methyl isobutyrate Methylisopropylsulfide Methylisoquinoline Methylisoquinoline Methylkisoboreneol Methyl laurate Methyl lignocerate Methylmalonic acid Methyl myrististate Methylnaphthalene Methylnaphthalene Methylnaphthalene-d Methylnaphthalene-d Methyl-2-naphthol Methyl-1-naphthol Methyl-1-naphthol Methyl-2-naphthol Methyl-1-naphthol Methyl-2-naphthol Methyl-1-naphthol Methyl-2-naphthol Methyl-1-naphthol Methyl-2-naphthol Methyl-1-naphthol Methyl-2-naphthol Methyl-1-naphthol Methyl-2-naphthol Methylnaphthol Kit Methyl-1,4-naphthoquinone Methyl-2-nitroanisole Methyl-4-nitroanisole Methyl-2-nitroanisole Methyl-2-nitroanisole Methyl-10-nitroanthracene Methyl-4-nitronaphthalene Methyl-5-nitronaphthalene Methyl-6-nitronaphthalene Methyl-1-nitronaphthalene Methyl-4-nitronaphthalene Methyl-2-nitrophenol Methyl-4-nitrophenol Methyl-2-nitrophenol Methyl-2-nitrophenol Methyl-8-nitroquinoline (N-Methyl-N-nitrosamino)- 1-(3-pyridyl)-1-butanone-d (N-Methyl-N-nitrosoamino)- 1-(3-pyridyl)-1-butanone Methyl 10,13-nonadecadienoate Methylnonadecane , Methylnonadecane , Methylnonadecane , 231 Methyl nonadecanoate Methyl 10-nonadecenoate Methyl 7-nonadecenoate Methyl 10-trans-nonadecenoate Methyl 7-trans-nonadecenoate Methylnonane , Methylnonane , Methylnonane , Methylnonane , 230 Methyl nonanoate

447 Product name Pg. Product name Pg. Product name Pg. Methylnonylbenzene (Isomer mixture) β(),21α()-22-Methyl- 28-nor-spergulane Methyl octadecadienoate (9, ,12 c+tr) Methyl octadecadienoate (9c,12c) Methyl octadecadienoate (9c,11tr) Methyl octadecadienoate (10tr,12c) Methyl octadecadienoate (9tr,12tr) Methyloctadecane , Methyloctadecane , 231 Methyl octadecanoate-d Methyl octadecanoate Methyl octadecatrienoate Methyl octadecatrienoate Methyl octadecenoate Methyl 9-trans-octadecenoate Methyl 11-trans-octadecenoate Methyl 6-trans-octadecenoate Methyloctane , Methyloctane , Methyloctane , 229 Methyl octanoate Methyl-1-octene Methyl-4-tert-octylphenol Methyl palmitate , 426 Methyl parathion Methyl parathion-d6 (dimethyl-d6) Methyl pelargonate Methylpentacosane , Methylpentadecane , 231 Methyl pentadecanoate Methyl 10-pentadecenoate Methyl 10-trans-pentadecenoate Methyl-1,3-pentadiene Methylpentane , Methylpentane , Methyl-2-pentanethiol Methyl pentanoate Methyl-1-pentanol Methyl-2-pentanone Methyl-2-pentene Methyl-1-pentene Methyl-cis-2-pentene Methylphenanthrene Methylphenanthrene Methylphenanthrene Methylphenanthrene Methylphenanthrene Methylphenyldisulfide (2RS)-2-(4-Methylphenyl)propanoic acid404 Methylphenylsulfide Methylphthalic acid Methylpicene Methyl-5α()-pregnane Methyl-1-propanethiol Methyl-2-propanethiol Methyl-2-[4-(2-methylpropyl) phenyl]propanoate Methyl-1-propanol Methyl-1-[4-(1-methylethyl)phenyl]- 1-propanone Methyl propionate Methyl-2-n-propylbenzene Methyl-3-n-propylbenzene Methyl-4-n-propylbenzene Methylpropyldisulfide [4-(2-Methylpropyl)phenyl]ethanone.404 (2RS)-2-[4-(2-Methylpropyl) phenyl]propanamide (2RS)-2-[4-(2-Methylpropyl) phenyl]propan-1-ol Methyl-n-propylsulfide Methylpyrazine Methylpyrene Methylpyrene Methylpyrene Methylpyrene-d Methylquinoline Methylquinoline Methylquinoline Methylquinoline Methylquinoline Methylquinoline Methyl stearate α-Methyl sterane Kit Methylsuccinic acid Methyl tetracosanoate Methyl 15-tetracosenoate Methyltetradecane , Methyltetradecane , 230 Methyl tetradecanoate Methyl 9-trans-tetradecenoate Methyltetrahydrothiophene Methyltetrahydrothiophene Methyltetraline Methyltetraline Methyltetraline Methyl tetranoate Methylthiochroman-4-one Methylthiophene Methylthiophene (Methylthio)thiophene (Methylthio)thiophene Methyl trianoate C27 1-Methyl triaromatic sterane Methyl triaromatic sterane Kit C28/C29 1-Methyl triaromatic steranes Methyltricosane , 231 Methyl tricosanoate Methyl 14-tricosenoate Methyltridecane , Methyltridecane , 230 Methyl tridecanoate N-Methyl-N-(trimethylsilyl) trifluoroacetamide Methylundecane , Methylundecane , 230 Methyl undecanoate Methyl 10-undecenoate Methyl ursolate Methyl valerate Methyl viologen-d8 dichloride (rings-d8) Methyoxypyrene Metiram Metobromuron Metolachlor Metolachlor-d6 (propyl-d6) Metoxuron Metribuzin cis-mevinphos Mirex MIX4 A+B-trichothecenes MIX 1Aflatoxin mixture MIX2 Aflatoxins MIX2 B-trichothecene mixture Mocap Modown Molinate Monoalkyl phthalate d3 C21 Monoaromatic Sterane (5α()/5β()) d3 C28/C29 Monoaromatic sterane (5α()/5β()) Monobromobenzene Monobromomethane Monobutyl phthalate Mono-n-butyltin trichloride Mono-n-butyltriethyltin Monochlorobenzene-d Monochloroethane Monochloromethane Monochlorophenol Kit Monocrotaline Monocyclic aliphatic acid Kit Monocyclic aromatic acid Kit Mono(2-ethylhexyl) phthalate Monoethyl phthalate Mono-n-heptyltin trichloride Mono-n-heptyltriethyltin Mono-n-hexyl phthalate Monolinuron Monomethyl phthalate Mono-n-octyltin trichloride Mono-n-octyltriethyltin Monophenyltin trichloride Monophenyltriethyltin Monuron Morphine (free base) , 402, 407 Morphine-6-glucuronide Morphine hydrochloride MSTFA MTBE Musk ambrette Musk moskene Musk tibeten Musk xylene Myclobutanil Myristelaidic Myristic Myristoleic , 427 Myticus edulis, homogenized (Domoic acid) Nabam Naled , 371 Naled , 371 Napht[1,2-a]anthracene Napht-(1.2,1.2)-anthracene Naphthacene ,12-Naphthacenequinone Naphthalene Naphthalene and Monosubstituted Naphthalene Kit Naphthalene-1,4-d Naphthalene-1-d Naphthalene-d ,3-Naphthalenedicarboxylic acid..278, 282 2,6-Naphthalenedicarboxylic acid..278, 282 2,7-Naphthalenedicarboxylic acid..278, 282 C0-C1 Naphthalene Kit C3 Naphthalene Kit C4+ Naphthalene Kit Naphthalene pentanoic acid, decahydro ,8-Naphthalic anhydride Naphtho[2,3-a]coronene Indexes 445

448 Product name Pg. Product name Pg. Product name Pg. Naphtho[8,1,2-abc]coronene Naphtho[1,2-b]fluoranthene Naphtho[2,3-b]fluoranthene Naphtho[2,3-j]fluoranthene Naphtho[2,3-k]fluoranthene Naphthofluoranthene Kit Naphtho[8,1,2-hij]hexaphene Naphthol , Naphthol Naphthol Kit Naphtho[1,2,3,4-ghi]perylene Naphtho[8,1,2-bcd]perylene Naphtho[2,3-a]pyrene Naphtho[2,3-e]pyrene Naphthylacetic acid Naproxen Nemacur Neohop-13(18)-ene Neosaxitoxin Neosolaniol Nervonic , Nitroacenaphthene Nitroanisole Nitroanisole Nitroanisole Nitroanthanthrene Nitroanthracene Nitroanthracene Nitroanthracene-d Nitroanthracene Kit Nitrobenzaldehyde Nitrobenz[a,h]anthracene Nitrobenz[a]anthracene Nitrobenzanthracene Kit Nitrobenzanthrone Nitrobenzo[c]phenanthrene /3-Nitrobenzo[a]pyrene /3-Nitrobenzo[e]pyrene Nitrobenzo[a]pyrene Nitrobenzo[a]pyrene-d Nitrobiphenyl Nitrobiphenyl Nitrochrysene Nitrochrysene-d Nitrocoronene Nitrofen Nitrofluoranthene Nitrofluoranthene Nitrofluoranthene Nitrofluoranthene-d Nitrofluoranthene Kit Nitrofluorene Nitrofluorene-d Nitrofluorene Kit Nitro-9-fluorenone Nitrofurazone Nitro-2-furfurylidene semicarbazone Nitronaphthalene Nitronaphthalene Nitronaphthalene-d Nitronaphthalene Kit Nitroperylene Nitroperylene Nitroperylene Kit Nitrophenanthrene Nitrophenanthrene Nitrophenanthrene Nitrophenol Nitrophenol Nitrophenol , Nitrophenol-3,4,5,6-d Nitrophenol-2,3,5,6-d Nitrophenol Kit Nitropyrene Nitropyrene Nitropyrene Nitropyrene-d Nitropyrene Kit (RS)-N-Nitrosoanabasine (RS)-N-Nitrosoanatabine N-Nitroso-di-n-hexylamine N-Nitrosonornicotine DL-N-Nitrosonornicotine-d Nivalenol Nivalenol hydrate ,2,3,3,4,4,5,6,6 -Nonachlorobiphenyl 356 n-nonacosane , ,13-Nonadecadienoic acid n-nonadecane , 231, 430 n-nonadecane-d Nonadecanoic acid Nonadecenoic acid Nonadecenoic acid trans-Nonadecenoic acid trans-Nonadecenoic acid n-nonadecylbenzene n-nonadecylcyclohexane n-nonafluoropentanoic acid n-nonane , 229 n-nonane-d Nonanethiol Nonanoic acid n-nonatriacontane , Nonene cis-2-nonene cis-3-nonene trans-2-nonene trans-3-nonene n-nonylbenzene n-nonylbenzene-2,3,4,5,6-d n-Nonylbiphenyl n-nonylcyclohexane n-Nonylphenol , 376 p-n-nonylphenol 2E p-nonylphenol 2E p-nonylphenol 3E p-nonylphenol 4-E p-n-nonylphenol E p-nonylphenol E Nonylphenol E Kit n-nonylphenol ethoxylates Kit Nonylphenol, mixture of isomers Nonylphenol, mixture of isomers, Type B Nonylphenol, mixture of nonyl isomers n-Nonylphenol-2,3,5,6-d4-D (4-Nonylphenoxy) acetic acid isomer mixture n-Nonylthiophene Norbornane Norbuprenorphine Norcodeine , 400 Norcodeine hydrochloride Nordiazepam Norethandrolone β(),21β()-30-Norhopane β(),21α()-30-Norhopane α(),21β()-30-Norhopane α(),21α()-30-Norhopane Norhopanes Kit β(),21α()-30-Norhop-2(3)-ene Norhop-17(21)-ene β()-28-Norlupane Norlupane (17β()/17α()) Norlup-16(17)-ene Norlup-17(22)-ene α(),21β()-30-Nor-29- methylhopane α(),21α()-30-Nor-29- methylhopane Norneohop-13(18)-ene Norpethidine Nor-spergula-12(13),17(18)-diene β(),18α()-28-Nor-spergulane North sea oil C2 Anthracene Kit chratoxin A U{13C20}-chratoxin A chratoxin A -BSA Conjugate ,2,3,4,4,5,5,6 - ctabromodiphenyl ether ctabromodiphenyl, techn , 361 ctachloroalkane Kit ,2,3,3,4,4,5,5 -ctachlorobiphenyl ,2,3,4,4,5,6,6 -ctachlorobiphenyl ,1,1,3,8,10,10,10-ctachlorodecane ctachlorodibenzo-p-dioxin ctachlorodibenzofuran ,1,1,3,10,12,12,12- ctachlorododecane ctachloronaphthalene ,1,1,3,7,9,9,9-ctachlorononane ,1,1,3,6,8,8,8-ctachlorooctane ,1,1,3,12,12,12,14- ctachlorotetradecane ,1,1,3,11,13,13,13-ctachlorotridecane 362 1,1,1,3,9,11,11,11-ctachloroundecane.362 n-ctacosane , 231, 431 n-ctacosane-d ctacosanol ,12-ctadecadienoic acid ctadecadienoic acid (9, ,12 c+tr) (Conjugated) trans-ctadecadienoic acid n-ctadecane , 231, 430 n-ctadecane-d ctadecanoic acid ctadecenoic acid ctadecenoic acid ctadecenoic acid trans-ctadecenoic acid trans-ctadecenoic acid trans-ctadecenoic acid n-ctadecylbenzene n-ctadecylcyclohexane n-ctadecylthiophene ctafluoropentanoic acid , 364 4,5,7,8,9,10,11,12- ctahydrobenzo[a]pyrene ,2,4,4,5,5,7,7-ctamethyloctane n-ctane , 229 n-ctane-d ctanethiol ctanoic acid ctanol ctanone

449 Product name Pg. Product name Pg. Product name Pg. n-ctanophenone n-ctatetracontane , 232 n-ctatriacontane , ctene cis-2-ctene trans-2-ctene n-ctylbenzene n-ctylbenzoic acid n-ctylbiphenyl n-ctylcarbazole n-ctyl-9-Carbazole n-ctylcyclohexane n-ctylphenol , tert-ctylphenol , n-ctylphenol 2E n-ctylphenol-d , n-ctylphenol E n-ctylphenol E Kit tert-ctylphenol 2E tert-ctylphenol 3E tert-ctylphenol E n-ctylthiophene n-ctylthiophene ftanol kadaic acid lanzapine , 409 lanzapine 10-N-glucuronide β()-leanane α()-leanane leanane Kit β()-lean-12(13)-ene β()-lean-12-en-3-one lean-12-en-11-one leic , 428 α-nocera-8,14-dien-3,21-dione nocerane I (8β(),14α()) nocerane II (8β(),14β()) α-nocerin α-nocerin diacetate rdram rganotin Analysis Kit rthene ther anthracenes Kit ther Isoalkane Kit ther relevant PBDEs valene xadiazon-hydroxy xamyl xazepam γ-xo-α-methyl-2- dibenzothiophenebutyric acid xyfluorfen EU PA Cocktail Palmiteladic Palmitelaidic Palmitoleic , 427 C16-C20 Paraffin Kit C26-C30 Paraffin Kit C41-C60 Paraffin Kit C5-C10 Paraffin Kit C31-C40 Paraffin Kit Parathion Parathion-d10 (diethyl-d10) Parathion-ethyl Parathion methyl Paraxanthine Patulin PBB Kit PBDE solutions Kit PBN Kit C10-C13 PCA Kit C14 PCA Kit C8-C9 PCA Kit PCN Kit Pectenotoxin Pectenotoxin-2 seco acid Pelargonic Pendimethalin Pendimethalin-d ,2,4,5,5 -Pentabromobiphenyl ,2,4,5,6-Pentabromobiphenyl ,2,4,4,5-Pentabromodiphenyl ether ,2,4,4,6-Pentabromodiphenyl ether ,3,4,4,6-Pentabromodiphenyl ether Pentabromophenol , 381 Pentabromotoluene , 361 Pentacene , 333 5,7,12,14-Pentacenetetrone Pentachloroaniline Pentachlorobenzene , 371 2,2,3,5,6-Pentachlorobiphenyl ,2,4,5,5 -Pentachlorobiphenyl ,3,3,4,4 -Pentachlorobiphenyl ,3,3,5,5 -Pentachlorobiphenyl ,3,4,4,5-Pentachlorobiphenyl , 359 2,3,4,4,5-Pentachlorobiphenyl...355, 359 2,3,4,4,5-Pentachlorobiphenyl...355, 359 2,3,4,5,6-Pentachlorobiphenyl ,3,4,4,5-Pentachlorobiphenyl ,3,4,4,5-Pentachlorobiphenyl ether Pentachloronitrobenzene Pentachlorophenol n-pentacosane , 231, 431 n-pentacosane-d n-pentadecane , 230, 430 n-pentadecane-d Pentadecanoic acid Pentadecenoic acid Pentadecenoic acid trans-Pentadecenoic acid n-pentadecylbenzene n-pentadecylbenzene-d n-pentadecylcyclohexane Pentafluorobenzoyl chloride ,3,4,4,4-Pentafluorobutan-1-ol Pentafluoropropionic acid sodium salt..363 Pentafluoropropionic anhydride β(),21α()-(22RS)- Pentakishomohopane , α(),21β()-(22RS)- Pentakishomohopane Pentakishomohopane Kit Pentamethylbenzene ,1,4,4,5-Pentamethyldecaline ,6,10,14,18-Pentamethylheneicosane ,2,4,6,6-Pentamethylheptane ,1,3,3,5-Pentamethylindan ,2-Pentandiol n-pentane , 229, 432 n-pentane-d Pentanethiol Pentanoic acid , Pentanol Pentanone Pentanophenone Pentaphene , 333 n-pentatriacontane , Pentene cis-2-pentene trans-2-pentene n-pentylbenzene n-Pentylbenzoic acid n-Pentylbiphenyl n-pentylcyclohexane n-Pentyldibenzothiophene n-Pentyldibenzothiophene n-Pentylphenol n-Pentylphenol-d Perfluorobutane sulphonate, potassium salt Perfluorocyclohexanoic acid n-perfluorodecanoic acid ,1-Perfluorodecan-1-ol Perfluoro-3,7-dimethyloctanoic acid n-perfluorododecanoic acid Perfluoro-4-ethyl-cyclohexane sulphonic acid, potassium salt Perfluoroheptanal Perfluoroheptanoic acid , 364 n-perfluoroheptanoic acid ,1-Perfluoroheptan-1-ol Perfluorohexadecanoic acid ,1-Perfluorohexadecan-1-ol Perfluorohexanoic acid ,1-Perfluorohexan-1-ol ,3-Perfluorohex-2-enoic acid Perfluorokerosene Perfluorononanoic acid , 364 Perfluorononanoic acid ,1-Perfluorononan-1-ol Perfluorooctadecanoic acid ,1-Perfluorooctadecan-1-ol Perfluorooctanamide ,1-Perfluorooctane-1-ol Perfluorooctane sulfonamide Perfluorooctane sulphonic acid, potassium salt n-perfluorooctanoic acid n-perfluorooctanoic acid, ammonium salt Perfluorotetradecanoic acid ,1-Perfluorotetradecan-1-ol Perfluoro-tri-n-butylamine ,1-Perfluoro-3,5,5- trimethylhexanoic acid Perfluoroundecanoic acid , 364 Perfluoroundecanoic acid ,1-Perfluoroundecan-1-ol Perhydrocoronene , 336 Perhydrofluorene Periflanthene Perinaphthenone Peri-naphthylene-pyrene Permethrin Peropyrene Perthane Perylene Perylene-d Perylene solutions Kit Pethidinic acid Petroselaidic Phantolide Phenanthrene Phenanthrene-d Phenanthrene-1,4-dione C3 Phenanthrene Kit C4+ Phenanthrene Kit Indexes 447

450 Product name Pg. Product name Pg. Product name Pg. Phenanthryl-9--glucuronide Phenazepam Phenol , 410, 411 Phenol C10+ Kit Phenol C0-C1 Kit Phenol C2 Kit Phenol C3 Kit Phenol C4 Kit Phenol C5 Kit Phenol C6 Kit Phenol C7 Kit Phenol C8 Kit Phenol C9 Kit Phenol-2,3,4,5,6-d Phenol-3,5-d Phenol-d Phenol-2,4,6-d3, D Phenol, D Phenol PFB derivative Kit Phenone Kit d-(cis-trans)-phenothrin Phenylacetic acid Phenylbenzo[b]fluoranthene Phenylbenzo[j]fluoranthene Phenylbenzo[j]fluoranthene Phenylbenzofluoranthene Kit Phenylbutyric acid Phenylbutyric acid Phenylbutyric acid Phenylcarbazole Phenyldibenzofuran Phenyldibenzofuran Phenyldibenzofuran Phenyldibenzofuran Kit Phenyldibenzothiophene Phenyldibenzothiophene Phenyldibenzothiophene Phenyldibenzothiophene Phenyldibenzothiophene Kit Phenylfluoranthene Phenylfluorene Phenylhexanoic acid Phenylnaphthalene Phenylnaphthalene Phenyloctadecanoic acid Phenylpentanoic acid Phenylphenol Phenylphenol Phenylphenol o-phenylphenol Phenylpropionic acid DL-2-Phenylpropionic acid N-(3-Phenylpropyl)acetamide N-(3-Phenylpropyl)- 3-(4-hydroxyphenyl)propylamine..286, Phenylthiophene Phenylthiophene (Phenylthio)thiophene (Phenylthio)thiophene Phenyltin chlorides Kit Phenyl-1,3,3-trimethylindan Pholcodine Pholcodine-N-oxide Phorate Phorate-d10 (,-diethyl-d10) Phorate-oxon Phosalone Phosdrin Phosmet Phosphamidon Phosphate Kit Phthalate and adipate Kit Phthalic acid Phytane , 231 Picene , 330 Picloram Pimelic acid (1R)-(+)-cis-Pinane (1R)-(+)-trans-Pinane (1S)-(-)-cis-Pinane (1S)-(-)-trans-Pinane Pirimicarb Pirimiphos-methyl Polysulfur Kit I , 292 Polysulfur Kit II , 294 5β()-Pregnane α()-Pregnane d4 Pregnane Pristane , 231 Prochloraz Procymidone Profenofos Profluralin Proguanil hydrochloride Prometryne ,2-Propanediol Propanethiol Propanethiol Propanoic acid, pentafluoro-, sodium salt Propanol , Propanone Propazine Propazine-d14 (di-iso-propyl-d14) Propetamphos Propham Propiconazole Propiophenone Propoxur Propoxur-d3 (N-methyl-d3) n-propylbenzene n-Propylbenzoic acid n-Propylbiphenyl n-Propylchrysene n-propylcyclopentane n-Propyldibenzothiophene n-Propyldibenzothiophene n-Propylfluorene n-Propylnaphthalene n-Propylnaphthalene n-Propylphenanthrene n-Propylphenol n-Propylphenol n-Propylphenol n-Propylphenol-d (2RS)-2-(4-n-Propylphenyl) propanoic acid n-Propylpyrene n-Propylthiophene n-Propylthiophene Propyzamide Propyzamide-d3 (phenyl-2,4,6-d3) Pseudomorphine (free base)..400, 407, 408 Purified asfalthenes Purpurin Pyranthrene ,16-Pyranthrenedione Pyranthrone Pyrene Pyrene and alkylpyrene Kit Pyrenebutyric acid Pyrene-d , 297 1,6-Pyrenequinone Pyrene-1-sulfonic acid sodium salt Pyrenyl-1--glucuronide Pyridine Pyrometillic acid m-quarterphenyl o-quarterphenyl p-quaterphenyl Quaterrylene , 334 Quinaldine Quinizarin Quinoline , 340 C0-C1Quinoline Kit C2-C3 Quinoline Kit Quinone , 323 m-quinquiphenyl p-quinquiphenyl Quintozene , 372 Quintozene , 372 Rally Rearranged hopane Kit Resmethrin Retene Retrorcine Ricinelaidic , 428 Ricinoleic , 428 Ridomyl C28/C29 Ring-C Monoaromatic sterane 254 C27 Ring-C Monoaromatic sterane Ring-C monoaromatic sterane Kit C21 Ring-C Monoaromatic sterane C29 Ring-C Monoaromatic sterane C21 Ring-C Monoaromatic sterane Ring-containing isoprenoid Kit Ronilan Ronnel Ronstar Rovral Rubicene Rubrene , 337 Rubrene , 337 Safrotin Salicylic acid , 411 Saxitoxin dihydrochloride Sebuthylazine Semicarbazide Cl Sencor Senecionine Seneciphylline Sesquiterpenoid Kit Sevin p-sexiphenyl Short-chained sterane Kit Simazine Simazine-d10 (diethyl-d10) Single 16 EPA-PA Kit α-sitostanol α-sitosterol Skatole Sodium dodecylbenzenesulfonate, mixture of C10-C Sodium dodecylbenzenesulfonate, mixture of C10-C14, 38% water Sodium hyaluronate Sodium p-n-decylbenzenesulfonate

451 Product name Pg. Product name Pg. Product name Pg. Sodium p-n-dodecylbenzenesulfonate..383 Sodium p-n-octylbenzenesulfonate Sodium p-n-tetradecylbenzenesulfonate.383 Sodium p-n-tridecylbenzenesulfonate Sodium p-n-undecylbenzenesulfonate..383 Sodium tetraethylborate , 430 Solanidine Solanine Sonalan Sorbic acid Squalane , 231 Squalene Stanozol , 412 Stearic Stearyl stearate C27 Sterene Kit C28/C29 Sterene Kit Sterol Precursor Kit Stigmastane epi-stigmastanol Stigmastanol Stigmasterol Styrene , 432 Suberic acid Succinic acid Supracide Syringaldehyde Systox ,4,5-T , 372 Tail-to-tail isoprenoids Kit Tebuconazole Tecnazene Tedion Temephos-d12 (,,, - tetramethyl-d12) Temic TEPA Terbacil Terbuthylazine Terbuthylazine-desethyl Terbuthylazine-d5 (ethyl-d5) Terbutryne Terephthalic acid m-terphenyl o-terphenyl p-terphenyl m-terphenyl-d o-terphenyl-d p-terphenyl-d Terphenyl Kit Terrylene ,2,5,2 -Terthiophene ,3.4,5.6,10.11-Tetrabenzanthanthrene 327 Tetrabenz[a,c,h,j]anthracene Tetrabenzo[de,h,kl,rst]pentaphene Tetrabenzo[def,lm,grs,yz]pyranthrene ,2,4,5-Tetrabromobenzene ,2,4,5 -Tetrabromobiphenyl ,2,5,5 -Tetrabromobiphenyl ,2,5,6 -Tetrabromobiphenyl ,3,5,5 -Tetrabromobiphenyl ,2,4,4 -Tetrabromodiphenyl ether ,2,4,5 -Tetrabromodiphenyl ether ,3,4,4-Tetrabromodiphenyl ether ,3,4,6-Tetrabromodiphenyl ether ,4,4,6-Tetrabromodiphenyl ether ,3,4,4 -Tetrabromodiphenyl ether ,1,2,2-Tetrabromoethane ,3,4,6-Tetrabromophenol Tetrabromophthalic anhydride Tetrabutylammonium bromide Tetra-n-butyltin Tetracene Tetrachloroalkane Kit ,2,3,4-Tetrachlorobenzene ,2,3,5-Tetrachlorobenzene ,2,4,5-Tetrachlorobenzene , 372 2,2,5,5 -Tetrachlorobenzidine ,2,3,4 -Tetrachlorobiphenyl ,2,3,5 -Tetrachlorobiphenyl ,2,4,4 -Tetrachlorobiphenyl ,2,5,5 -Tetrachlorobiphenyl ,3,4,5-Tetrachlorobiphenyl ,3,5,6-Tetrachlorobiphenyl ,4,4,5-Tetrachlorobiphenyl ,3,4,4 -Tetrachlorobiphenyl ,4,4,5-Tetrachlorobiphenyl ,1,1,3-Tetrachlorodecane ,2,9,10-Tetrachlorodecane ,2,3,4-Tetrachlorodibenzo-p-dioxin ,1,1,3-Tetrachlorododecane ,2,11,12-Tetrachlorododecane ,1,1,2-Tetrachloroethane Tetrachloroethylene, in Certan bottle Tetrachloromethane ,2,3,4-Tetrachloronaphthalene Tetrachloronaphthalene, mix ,1,1,3-Tetrachlorononane ,2,8,9-Tetrachlorononane ,10,12,13-Tetrachlorooctadecanoic acid 363 1,1,1,3-Tetrachlorooctane ,2,7,8-Tetrachlorooctane ,3,4,5-Tetrachlorophenol ,3,4,6-Tetrachlorophenol ,3,5,6-Tetrachlorophenol ,1,1,3-Tetrachlorotetradecane ,2,13,14-Tetrachlorotetradecane ,1,1,3-Tetrachlorotridecane ,1,1,3-Tetrachloroundecane ,2,10,11-Tetrachloroundecane Tetrachlorvinphos n-tetracontane , 232, 431 Tetracosahydrocoronene , 336 n-tetracosane , 231, 430 n-tetracosane-d Tetracosanoic acid Tetracosenoic acid n-tetradecane , 230, 430 n-tetradecane-d Tetradecanoic acid trans-Tetradecenoic acid n-tetradecylbenzene n-tetradecylcyclohexane n-Tetradecylthiophene Tetradifon Tetradodecylammonium bromide Tetraethylammonium bromide Tetraethylene glycol mono (p-nonylphenyl) ether isomer mix Tetraethylene glycol mono (p-n-octylphenyl)ether Tetraethyllead Tetrahexylammonium bromide ,4,5,11-Tetrahydroacenaphthene ,8,9,10-Tetrahydrobenzo[b] naphtho[2,3-d]thiophene ,8,9,10-Tetrahydro-benzo[a]pyren-7-ol.322 1,2,3,4-Tetrahydrocarbazole ,2,3,4-Tetrahydrochrysene , 326 1,2,3,10b-Tetrahydrofluoranthene ,2,3,4-Tetrahydro-2-naphthoic acid ,5,9,10-Tetrahydropyrene Tetrahydrothiophene β(),21α()-(22R)- Tetrakishomohopane β(),21α()-(22S)- Tetrakishomohopane α(),21β()-(22R)- Tetrakishomohopane α(),21β()-(22RS)- Tetrakishomohopane α(),21β()-(22S)- Tetrakishomohopane Tetrakishomohopane Kit Tetraline Tetraline Kit Tetramethrin Tetramethylammonium bromide ,2,3,4-Tetramethylanthracene ,3,6,7-Tetramethylanthracene ,3,9,10-Tetramethylantracene ,2,3,4-Tetramethylbenzene ,2,3,5-Tetramethylbenzene ,2,4,5-Tetramethylbenzene ,2,5,5 -Tetramethylbiphenyl ,3,4,4 -Tetramethylbiphenyl ,3,5,5 -Tetramethylbiphenyl ,6,10,14-Tetramethylheptadecane.228, 231 2,2,6,6-Tetramethylheptane ,6,10,14,18-Tetramethylhexadecane ,6,10,14-Tetramethylhexadecane ,6,11,15-Tetramethylhexadecane..228, 231 1,1,5,6-Tetramethylindan ,2,5,6-Tetramethylnaphthalene ,4,6,7-Tetramethylnaphthalene ,1,3,5-Tetramethyl-3-neopentylindan ,6,10,14-Tetramethylnonadecane.228, 231 2,6,10,14-Tetramethyloctadecane..228, 231 2,2,4,4-Tetramethyloctane ,2,7,7-Tetramethyloctane ,6,10,14,18-Tetramethylpentadecane ,6,10,14-Tetramethylpentadecane ,2,6,9-Tetramethylphenanthrene ,3,5,6-Tetramethylpyrazine ,2,5,7-Tetramethyltetraline ,3,4,5-Tetramethylthiophene Tetranoic acid Tetraoctadecylammonium bromide Tetraoctylammonium bromide n-tetrapentacontane , 232 Tetra-n-pentyltin ,3.4,5.6,7.8-Tetra(perinaphthylene)anthracene ,6,11,12-Tetraphenylnaphthacene.333, 337 Tetra-n-propyltin Tetrasul n-tetratetracontane , 232 n-tetratriacontane , 232 Thebaine Theophylline Thiabendazole Thianthrene Thimet Thioalkane Kit Thiobencarb Thiobencarb-d10 (diethyl-d10) m-thiocresol Indexes 449

452 Product name Pg. Product name Pg. o-thiocresol p-thiocresol Thiocycloalkane Kit Thiocyclohexane Thiodan I ,4 -Thiodianiline Thionazin--analog Thiophene , 347 Thiophene-d Thiophene Kit Thiophenol , 289 Thiophenol Kit Thioxanthone , 423 Thioxanthone Thiram Thymol Tin Chlorides Kit Tm ,4,5-T-methyl ester Tolban Toluene , 432 Toluene-d p-toluenesulfonyl-n-methyl- N-nitrosamide Toluene, sulfurdepleted alpha-toluenethiol Toluene, 3 Wt% in Isooctane m-toluic acid o-toluic acid p-toluic acid o-toluidine o-toluquinoline p-toluquinoline Tonalide Totarol Toxaphene Tramadol hydrochloride Transvaccenic , 428 Traseolide n-triacontane , 231, 431 n-triacontane-d Triadimefon Triadimenol Tri- and tetracyclic aliphatic acid Kit Tri- and tetracyclic aromatic acid Kit Tri- and Tetramethylnaphthalene Kit Tri- and tetramethylphenanthrene Kit Trianoic acid (Propionic) C20 Triaromatic sterane , 256 C26 Triaromatic sterane , 256 C28 Triaromatic sterane , 256 d2 C20 Triaromatic Sterane d2 C26 Triaromatic Sterane d2 C27/C28 Triaromatic Sterane d2 C28 Triaromatic Sterane Triaromatic sterane Kit , 257 C27/C28 Triaromatic steranes C27 Triaromatic ster-14(15)-ene C28 Triaromatic ster-14(15)-ene n-triatriacontane , 232 1,3,5-Triazine-2,4,6-triamine ,4,6-Tribromoanisole , 381 1,2,4-Tribromobenzene ,3,5-Tribromobenzene ,2,5-Tribromobiphenyl ,3,5-Tribromobiphenyl ,4,5-Tribromobiphenyl ,4,5-Tribromobiphenyl ,4,6-Tribromobiphenyl ,4,5-Tribromobiphenyl ,3,4-Tribromodiphenyl ether ,4,4 -Tribromodiphenyl ether ,3,4-Tribromophenol ,3,6-Tribromophenol ,4,5-Tribromophenol ,4,6-Tribromophenol , 381 2,4,6-Tribromophenol-3,5-d ,4,6-Tribromophenol-PFB Tri-n-butyltin chloride ,3,6-Trichloroanisole ,4,6-Trichloroanisole ,2,3-Trichlorobenzene ,2,4-Trichlorobenzene , 372 1,3,5-Trichlorobenzene ,2,5-Trichlorobiphenyl ,3,4 -Trichlorobiphenyl ,4,4 -Trichlorobiphenyl ,4,5-Trichlorobiphenyl ,4,6-Trichlorobiphenyl ,4,4 -Trichlorobiphenyl ,4,5-Trichlorobiphenyl ,1,1-Trichloro-2,2-bis (4-chlorophenyl-d4)ethane ,1,1-Trichloro-2(2-chlorophenyl-d4)- 2-(4-chlorophenyl-d4)ethane ,2,4-Trichlorodibenzo-p-dioxin ,1,2-Trichloroethane ,1,1-Trichloroethane Trichloroethylene Trichlorofluoromethane Trichloronate ,3,4-Trichlorophenol ,3,5-Trichlorophenol ,3,6-Trichlorophenol ,4,5-Trichlorophenol ,4,6-Trichlorophenol ,4,5-Trichlorophenol ,3,6-Trichlorophenol-4,5-d ,4,5-Trichlorophenol-3,6-d ,4,6-Trichlorophenol-3,5-d Trichlorophenol Kit ,2,3-Trichloropropane Triclopyr n-tricosane , 231, 430 n-tricosane-d Tricosanoic acid Tricosenoic acid Tricyclene Tricyclohexyltin chloride n-tridecane , 230, 430 n-tridecane-d Tridecanoic acid Tridecenoic acid n-tridecylbenzene n-tridecylcyclohexane Trietazine ,2,4-Triethylbenzene ,3,5-Triethylbenzene Triethylene glycol , 373 Triethylene glycol mono (p-nonylphenyl) ether isomer mix Triethylene glycol mono (p-n-octylphenyl)ether Trifluoroacetic anhydride (Trifluoroacetyl)imidazole ααα-trifluorotoluene , 236 Trifluralin Trifluralin-d14 (di-n-propyl-d14) Trimellitic acid ,3,5-Trimethyladamantane Trimethylamine ,4,5-Trimethylaniline ,2,4-Trimethylanthracene ,6,8-Trimethylazulene ,2,3-Trimethylbenzene ,2,4-Trimethylbenzene ,3,5-Trimethylbenzene ,3,4-/2,3,6-Trimethylbenzothiophene ,5,7-Trimethylbenzothiophene Trimethylbenzothiophene Kit ααα (20R,23R,24R)-4α,23,24- Trimethylcholestane ααα (20R,23R,24S)-4α,23,24- Trimethylcholestane ,3,6-Trimethylchrysene ,1,2-Trimethylcyclohexane ,1,3-Trimethylcyclohexane ,1,4-Trimethylcyclohexane ,1,3-Trimethylcyclopentane ,3,7-/2,3,8-Trimethyldibenzothiophene.348 2,4,6-Trimethyldibenzothiophene ,4,7-Trimethyldibenzothiophene ,4,8-Trimethyldibenzothiophene Trimethyldibenzothiophene Kit ,6,10-Trimethyldodecane , 230 2,6,11-Trimethyldodecane , 231 Trimethylenesulfide ,4,6-Trimethylheptane ,3,5-Trimethylheptane ,4,5-Trimethylheptane ,2,3-Trimethylhexane ,2,4-Trimethylhexane ,2,5-Trimethylhexane ,3,3-Trimethylhexane ,3,4-Trimethylhexane ,3,5-Trimethylhexane ,4,4-Trimethylhexane ,3,4-Trimethylhexane ,4,7-Trimethylindan ,2,3-Trimethylnaphthalene ,2,4-Trimethylnaphthalene ,2,5-Trimethylnaphthalene ,2,6-Trimethylnaphthalene ,3,7-Trimethylnaphthalene ,4,5-Trimethylnaphthalene ,4,6-Trimethylnaphthalene ,3,5-Trimethylnaphthalene ,3,6-Trimethylnaphthalene ,4,5-Trimethylnaphthalene ,6,10-Trimethylpentadecane , 231 2,2,4-Trimethylpentane ,3,3-Trimethylpentane ,3,4-Trimethylpentane ,2,4-Trimethylpentane ,3,4-Trimethyl-2-pentene ,4,4-Trimethyl-1-pentene ,4,4-Trimethyl-2-pentene ,4,4-Trimethyl-trans-2-pentene ,2,4-Trimethylphenanthrene ,2,5-/1,2,7-Trimethylphenanthrene ,2,6-Trimethylphenanthrene ,2,8-Trimethylphenanthrene ,2,9-Trimethylphenanthrene ,3,4-Trimethylphenanthrene ,6,9-Trimethylphenanthrene ,3,5-Trimethylphenol ,3,6-Trimethylphenol

453 2,4,6-Trimethylphenol ,4,5-Trimethylphenol ,3,5-Trimethylphenol-d ,3,6-Trimethylphenol-d ,4,6-Trimethylphenol-d ,3,5-Trimethylpyrazine ,6,8-Trimethylquinoline (Trimethylsilyl)imidazole ,1,6-Trimethyltetraline ,5,8-Trimethyltetraline ,5,8-Trimethyltetraline ,3,5-Trimethylthiophene ,6,10-Trimethylundecane , 230 Tri-n-octyltin chloride Tri-n-pentyltin chloride Triphenylene Triphenylene-d Triphenyltin chloride Tri-n-propyltin chloride Tris-(aziridinyl)-phosphineoxide α(),21α()-(22RS)-Trishomohopane265 17β(),21β()-(22RS)-Trishomohopane α(),21β()-(22RS)- Trishomohopane Trishomohopane Kit β(),21β()-25,28,30-Trisnorhopane β(),21α()-25,28,30-Trisnorhopane β()-22,29,30-Trisnorhopane α(),21β()-25,28,30-Trisnorhopane α()-22,29,30-Trisnorhopane Trisnorhopanes Kit ,29,30-Trisnor-17α()-hopan-21-one α()-22,29,30-Trisnorneohopane 259, ,29,30-Trisnorhop-17(21)-ene Triterpane Kit Truxenone Ts , 267 T-2 Tetraol T-2 Toxin T-2 Toxin - BSA Conjugate T-2 Triol n-undecane , 230, 430 n-undecane-d Undecanoic acid Undecenoic acid n-undecylbenzene n-undecylcyclohexane n-Undecylthiophene Urs-12(13)-ene Ursene / oleanene Kit Urs-12-en-3-one Ursolic acid , 419 Uvaol Vaccenic , 428 Valeric n-valerophenone Vanillin , 425 (Arg8)-Vasopressin acetate salt (S)-(-)-Verbenone Vinclozolin Vinyl chloride Vinylidene chloride Vinylphenol Violanthrone Vydate W Mix m-xylene , 432 o-xylene , 432 p-xylene , 432 m-xylene-d o-xylene-d p-xylene-d Xylene, low sulfur Yessotoxin β-zearalanol Zearalanone α-zearalenol β-zearalenol Zearalenone - BSA Conjugate Zeorine Zineb Zinophos Indexes 451

454 Chiron No. index Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , ,

455 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , 231, , , , , , , , , , , , , , , , , , , , , , , , Indexes 453

456 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , , , , , , , , , , , , 229, , , , , 229, , , , , , , , , , , , , , 229, , , , , ,

457 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , 410, , , , , , , , , 407, , 402, , , Indexes 455

458 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , , , , , , , , , ,

459 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , , , , , , , , , , , , Indexes 457

460 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , , , , , , , , , , , 328, , , , , , , , , , , , , , , , , , ,

461 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , , Indexes 459

462 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , ,

463 Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg. Chiron No. Pg , , , , , X X X , , S S , 299 S , 299 S , 299 S S S S S S S S S , 299 F F F F F Indexes 461

464 CAS No. index CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg , , , , , , , , , , , 407, , , , , , , , , , , , , , , , 231, ,

465 CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg , , , , 230, , , , , , , , , , , , , , , , Indexes 463

466 CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg , , , , 232, , , , , , , , , , , , , , , , , , , , , ,

467 CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg , , , , , , , , , , , , , , , , , , , Indexes 465

468 CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg. CAS No. Pg , , , , , , , , , , , , , , , , , ,

469 CAS No. Pg. CAS No. Pg Indexes 467

470 Mixture No. index Mixture No. Pg. Mixture No. Pg. Mixture No. Pg. Mixture No. Pg. S S S S S S , 136 S S S , 174 S S S S S S , 183 S S S S S S S S S S S S S S S , 177 S , 195, 198, 202 S , 195, 198 S , 195, 198 S S , 199 S , 200 S , 202 S , 202 S S S S , 144 S S S S , 195, 196, 202 S , 50, 195, 196, 202 S , 50, 195, 196, 202 S , 197 S , 198 S , 195, 198, 202 S , 197, 202 S , 195, 202 S S , 52, 195, 197, 202 S S , 136, 139 S , 136, 138 S , 138 S , 138 S , 186 S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S , 186 S , 187 S , 186, 187 S S , 186 S , 79, 188 S S S S S S S S S S S S S S , 185 S S S , 193 S S S S S S S , 192 S , 189 S , 203 S , 203 S , 203 S , 203 S S S S , 185 S S , 80, 188 S S , 56, 80 S , 189 S S S S S S , 72 S , 72, 195, 198 S S S , 193 S S S S S S S S S S S S S S S S S S S , 192 S , 192 S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S , 115 S S S S S S S S S S S S S S S S S S S S S S S S S S S , 115 S S S S S S S S S S , 83 S , 206 S S S S S S S S S S S S S S S S S S S S S S S S S S S S , 38 S , 39 S S S S S , 116,

471 Mixture No. Pg. Mixture No. Pg. S , 191 S S S S S , 194 S S S S S S S S S S S S S S S , 116 S , 116, 187 S S S S S S S S S S S S S S , 21 S S S S S S S S S S S S S S , 212 S S S S S S , 207 S S S S S S S S S , 219 S S S S S S S , 219 S , 207 S , 208 S , 207 S , 219 S , 219 S S S S S S S S S S S S Indexes 469

472 Standard methods Methods Pg. Methods Pg. ASTM D ASTM D , 199 ASTM D , 199 ASTM D a , 194 ASTM D e , 199 ASTM D , 199 ASTM D e , 194 ASTM D (2004) , 194 ASTM D , 206 ASTM D , 199 ASTM D , 202 ASTM D , 45, 199, 206 ASTM D , 194 ASTM D , 199 ASTM D , 113, 136, 194 ASTM D (2002) , 194 ASTM D (2003)e , 194 ASTM D (2003)e , 194 ASTM D , 194 ASTM D , 199 ASTM D (2006) ASTM D , 113, 136, 194 ASTM D (2005) ASTM D (2005) ASTM D (2004)e , 199 ASTM D , 112, 113, 136 ASTM D , 113, 136 ASTM D (2006) ASTM D (2203) ASTM D (2003)e , 194 ASTM D (2003)e , 194 ASTM D , 199 ASTM D e , 194 ASTM D , 194 ASTM D ASTM D , 208 ASTM D , 113, 136, 194 ASTM D ASTM D (2006)e ASTM D a ASTM D , 199 ASTM D ASTM D ASTM D UP (ASTM method) EN 12916: EN 14078: , 208 EN 14103: , 208 EN 14105: , 42, 208 EN 14214: , 208 EPA EPA , 87 EPA 506 Rev , 87 EPA , 137, 88 EPA , 156, 89 EPA EPA , 93, 128 EPA , 94, 122 EPA 608/ EPA , 95, 101, 113, 137 EPA , 95 EPA , 97 EPA EPA 8041 A , 98 EPA 8061 A , 99 EPA EPA , 113, 137 EPA 8260 B EPA 8270 C EPA 8275 A EPA , 113, 137 FR No IS 6468: , 156 IS : IS : IS : IS : IS :2000/IS 9377-MD (SPAR) IS 10382: IS 12078, IDF 159: , 220 IS 12228: , 220 IS 13877: IS 14154: IS 15009: IS 15680: IS 15753: , 113, 136 IS : , 220 IS 17353: , 163 IS 17495: IS 17858: IS 17993: , 113, 137 IS 18252, IDF 200: , 220 IS : IS 22032: , 154 IS/DIS 23161: NRDTEST technical reports 497, 498, , 112 NS , 136 UP (ASTM method)

473 Innovative Standards Creative Solutions Reference standards Petro, Pharma, Food, Environment Joint Project Focus

474 Campro Scientific Gmb - Germany P.. Box Berlin Phone +49(0) Fax +49(0) info@campro.eu Campro Scientific Gmb - The Netherlands P.. Box 316 NL-3900 A Veenendaal Phone +31(0) Fax +31(0) info.nl@campro.eu